DE102007019372A1 - Liquid textile treatment agent - Google Patents

Abstract

There are described liquid textile treatment compositions containing photocatalytic material and cationic surfactant. These allow cleaning, care, equipment, softening and / or conditioning of textiles using light in the wavelength range of 10-1200 nm. a. Elimination, deactivation or reduction of microorganisms in textiles to a harmless level and a reduction in the fiber adhesion of dirt. Furthermore, they can prevent the development of fetid odors on the textiles and equip them with a self-cleaning ability.

Description

The The present invention relates to a liquid textile treatment agent, containing photocatalytic material and cationic surfactant. Further it relates to a method of applying photocatalytic material on textiles, as well as a process for cleaning, care, equipment, Softening and / or conditioning of textiles.

By Cleanliness and hygiene could improve the quality of life and life expectancy the people are decisively improved. An important contribution this provide textile treatment agents such. B. detergent for cleaning of textiles. Textile treatment agents are therefore in the most varied Embodiments for the commercial and technical Demand as well as household needs of households provided by the industry.

While the removal of dirt and unpleasant odors the textiles for the consumer with his senses perceptible As a rule, he can not verify the elimination of microorganisms. The consumer nevertheless has a strong interest in the textile treatment a germ reduction on a health to reach safe level. He is therefore general interested in textile treatment agents, which is a good laundry hygiene enable.

The It is an object of the present invention to provide an agent ready to help, which contributes to a good laundry hygiene to enable.

Of the The invention relates to a liquid textile treatment agent, preferably textile aftertreatment agents, in particular fabric softeners, containing photocatalytic material and cationic surfactant.

The contained photocatalytic material, which is preferably fine particulate is, that is preferably has particle sizes <500 nm, uses electromagnetic radiation of a suitable wavelength range, by which a general cleaning performance provided is, by virtue of which z. As contaminants or microbes by photocatalytic or photochemical reaction, eg. B. by Oxidation or reduction, degradable, deactivatable or reducible are.

The photocatalytic material is particularly a daylight active Material, especially a daylight active bleaching uses that is, the electromagnetic radiation of daylight. For a preferred unfolding of the effectiveness of the photocatalytic Material is the presence of preferably oxygen and / or Water required. This is sufficient z. B. the present in water, dissolved oxygen or the water contained in the air (Humidity).

The photocatalytic activity of the photocatalytic material advantageously refers to natural or artificial Light in the wavelength range of 10-1200 nm, preferably from 300-1200 nm, in particular between 380 and 800 nm. When the photocatalytic material in particular those of the human Eye perceptible radiation of the visible region of the spectrum with wavelengths between 380 and 800 nm for the o. g. Purposes of degradation, deactivation or reduction exploits contaminants, then is a preferred embodiment of the invention. Even UV light is very beneficial.

advantageously, even the light passes through glass windows in closed Living spaces come in (diffused daylight), to the desired photocatalytic activity of the photocatalytic material. Even Light from technical light sources (artificial light), such as. B. from commercial Incandescent (incandescent) bulbs, halogen lamps, fluorescent tubes, Compact fluorescent lamps (energy-saving lamps) and light sources based on light-emitting diodes, is sufficient to the desired Effect. In particular, the natural sunlight leads to very good effects.

The Photocatalytic material can be used in several ways the textile treatment unfold their effect.

First, the effect in the textile treatment bath is called. If you z. B. the textiles to be treated in a tub containing a wash liquor, in which previously the textile treatment agent according to the invention were given, and then exposes this textile treatment bath, for example light, z. B. in the sun, then unfolds the photocatalytic material in the textile treatment bath a general cleaning performance. Such is also possible in the textile treatment in an automatic washing machine which has a viewing window (porthole), as is customary at least in front loaders and / or in Waschma machine with internal light source.

To the the second is the effect of drying the textile. The im Textile treatment on the textiles to be dried photocatalytic material can interact with light, z. Sunlight from drying on a leash outdoors, to develop a general cleaning performance. Such is also possible in the case of textile drying in an automatic Clothes dryer with internal light source.

To the the third is the effect after drying the textile. The Dried textiles are not real in the true sense dry, but contain a residual moisture, which is in equilibrium with the ambient humidity is (room humidity, body moisture).

These Conditions are sufficient to avoid exposure to light, for. By sunlight, a general cleaning performance, caused by that the textiles deposited photocatalytic material to unfold. This latter effect is particularly advantageous because the treated garments as it were with a long-term protection be provided so that the clothes with a self-cleaning ability is equipped.

This Self-cleaning capacity is z. B. advantageous to the Emerge fetid odors, which counteract on the clothes z. For example, after sweaty activities Form (eg sports activities) quickly. This self-cleaning ability is z. B. advantageous to the colonization of microbes on textiles to prevent or at least complicate. This self-cleaning ability is z. B. advantageous to a winding and firm adhesion of In particular, to ward off colored stains on fibers or to difficult.

advantageously, is also the Wiederauswaschbarkeit of colored soiling Textiles containing the textile treatment agent according to the invention were washed, relieved. Usually at the distance from stains on textiles fast action the highest bid, because the fresher a stain, the easier it is he takes off. A drying of stains or other dirt, For example, blood, coffee, tea, ballpoint pen, fruit, red wine or tar stains, especially over several days should usually be avoided so it does not become one irreversible fiber adhesion comes. The present invention brings here relief, because textiles with inventive Textile treatment agents were treated, showed that the Fiber adhesion of stains or other contaminants so toned became easier to wash out again.

The photocatalytically active material is therefore beneficial to the Wiederauswaschbarkeit to improve from colored stains. The photocatalytic active material is able to act under the influence of light the structure of in particular colored stains (dyes) z. B. to destroy by oxidation.

The conjugated double bonds that in the dyes for the absorption of visible light and thus for the coloring are responsible, are split or hydroxylated. The dye loses its coloring properties and also its strong Fiber adhesion. At the same time, the water solubility elevated. So it can be prevented that a colored stain, as it were, into the textile and this permanently devalued.

Furthermore is determined by the application of the invention Textile treatment agent in the textile treatment also a uniform Drawing the photocatalytic material onto the textiles to be treated allows. We could find that presence of cationic surfactant, in particular in the form of esterquat, in the Textile treatment agents to a very good and uniform Aufziehverhalten the photocatalytic material on the treated Textiles leads. The cationic surfactant, in particular esterquat, leads also to an increased adhesion of the photocatalytic Material on the textiles, thus extending its duration of action. Overall, this will improve the cleaning performance allows.

The textile treatment agent according to the invention allows Furthermore, a very textile-friendly textile treatment, eg. B. stain treatment.

Another advantage of the textile treatment agent according to the invention, as already mentioned, is that it contributes to the reduction, elimination or neutralization of fetid odors. The fetid odor can be advantageously reduced so that a previously existing odor nuisance not more present. The development of fetid odors can be prevented for a longer period of time. This is also a great advantage since, overall, a general cleaning performance can be combined with the elimination of harmful microbes in one treatment step and, in addition, a blocking or prevention of foul odors with long-term effect is provided. This goes beyond the function of previous textile treatment means significantly. The formation of bad odors can thus be reduced.

advantageously, is not only the elimination of conventional pollution, but also the elimination, deactivation, denaturing or Reduction of microbes, especially germs, fungi, yeasts, Mites, preferably house dust mites, or more generally of (indoor) Noxen with allergenic potential.

Under Noxa is understood here as a factor affecting the human organism harm, or at least the person in his well-being can affect. These are in particular the factors just mentioned, especially microbiological factors like viruses, bacteria, fungi etc.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B. aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften,
• – farbige Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben.

The unfolding of the general cleaning effect, which can be observed in the application of the textile treatment agent according to the invention, is particularly effective with respect to colored impurities or soiling, which in particular decrease

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B. green grasses,
• - technical dyes of cosmetics, inks, color pencils,
• - colored metabolites and / or excretory products of mold or other micro flora or microbial growth or microbes.

The Textile treatment agent according to the invention comes also contrary to today's washing habits of consumers. These increasingly prefer washing at lower temperatures, e.g. B. <40 ° C. However, a significant dying of germs begins only at Temperatures> 40 ° C, only above a temperature of 55 ° C are the most Killed bacteria. So only for a long time Washed at 30 ° C, may be no longer guarantee sufficient hygienic purity. The application the textile treatment agent according to the invention allows the consumer the consistent washing at T <40 ° C with improved hygiene effect.

One inventive textile treatment agent combined also preferably the benefits of a Hygienülülülers and a softener in a supply form and facilitates The consumer thereby the textile care and treatment, since he instead of two different aftertreatment agents only a single, namely the textile treatment agent according to the invention if it is a softening and hygiene-promoting Aftertreatment of his laundry considers necessary. The softness performance is advantageously provided by the cationic surfactant provided.

The Contain textile treatment agent according to the invention namely as a mandatory ingredient cationic surfactant. cationic surfactants are known in the art. These are surface-active Compounds, usually from an optionally substituted Hydrocarbon scaffold, with one or more cationic (positively charged) groups in aqueous solution preferably dissociate, advantageously at interfaces adsorb and preferably above the critical micelle concentration aggregate to positively charged micelles.

Known Examples of cationic surfactants are especially quaternary Ammonium compounds with one or two hydrophobic alkyl radicals.

at Cationic surfactants with two hydrophobic groups that have ester bonds with a quaternized di (tri-) ethanolamine or an analogous Connection are linked, one speaks of Esterquats. These are particularly preferred according to the invention. Other examples of cationic surfactants are e.g. Eg quaternary Phosphonium salts, tertiary sulfonium salts, imidazolinium salts or N-alkylpyridinium salts. Cationic surfactants can also by protonation of primary fatty amines or fatty amine N-oxides to be obtained.

At the However, most preferred are according to the invention quaternary ammonium compounds such as monoalk (en) yltrimethylammonium compounds, Dialk (en) yldimethylammonium compounds, mono-, di- or triesters of fatty acids with alkanolamines.

wobei in (I) R für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R¹ für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R² und R³ entweder gleich R oder R¹ sind oder für einen aromatischen Rest stehen. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (I) sind Monotalgtrimethylammoniumchlorid, Monostearyltrimethylammoniumchlorid, Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples of quaternary ammonium compounds are shown, for example, in the formulas (I) and (II):

wherein in (I) R is an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{1 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ² and R ^{3 are} either R or R ¹ or are an aromatic radical , X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (I) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (II), (III) and (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. In formula (II) R ^{4 is} an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these anions. Preference is given to compounds in which R ^{5 represents} the group O (CO) R ⁷ . Particular preference is given to compounds in which R ^{5 is} the group O (CO) R ⁷ and R ⁴ and R ^{7 are} alk (en) yl radicals having 16 to 18 carbon atoms. Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (I) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyloxyethyl) ammonium methosulfate, bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate, 1,2-bis - [tallowloxy] -3-trimethylammonium propane chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulphate.

If quaternized compounds of the formula (II) are used which have unsaturated alkyl chains, the acyl groups are preferred whose corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio (in% by weight) of greater than 30:70, preferably greater than 50:50 and in particular equal to or greater than 60:40. Commercial examples are sold by Stepan under the tradename Stepantex ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under Dehyquart ^® Cognis products, known under Rewoquat ^® products from Degussa or those known under Tetranyl ^® products of Kao. Further preferred compounds are the diesterquats corresponding to formula (III) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

Instead of the ester group O (CO) R, where R is a long chain Alk (en) ylrest can, softening compounds can be used, which have the following groups: RO (CO), N (CO) R or RN (CO), of which N (CO) R groups are preferred are.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.Suitable cationic surfactants are, for example, also quaternary imidazolinium compounds of the formula (IV)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt, X^– ein Anion ist und r eine Zahl zwischen 0 und 5 ist. Ein bevorzugtes Beispiel einer kationischen Abscheidungshilfe gemäß Formel (V) ist 2,3-Bis[talgacyloxy]-3-trimethylammoniumpropanchlorid.Further particularly preferred cationic surfactants are described by formula (V)

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group, X ^{- is} an anion and r is a number between 0 and 5. A preferred example of a cationic deposition aid according to formula (V) is 2,3-bis [tallowacyloxy] -3-trimethylammoniumpropane chloride.

Further provide cationic surfactants that can be used according to the invention the quaternized protein hydrolysates or protonated amines.

Furthermore, cationic polymers can also be used according to the invention as cationic surfactant. Suitable cationic polymers include the polyquaternium polymers as described in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, Polyquaternium, also referred to as Merquats. 10 polymers (Polymer JR, LR and KG series from Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyltriammonium chloride, and similar quaternized guar Derivatives (eg Cosmedia Guar from Cognis or the Jaguar series from Rhodia), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. As the commercial product Glucquat ^® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers and copolymers.

Also suitable for use as cationic surfactants according to the invention Polyquaternized polymers (for example Luviquat ^® Care from BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Some said cationic polymers additionally have skin and / or textile care properties, which is advantageous.

Also usable cationic surfactants are compounds of the formula (VI),

R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl and X ^- is an anion.

Further Suitable cationic surfactants include protonated or quaternized polyamines.

Particularly preferred cationic surfactants are alkylated quaternary ammonium compounds, of which at least one alkyl chain is interrupted by an ester group and / or amido group. Most notably preferred are N-methyl-N- (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate or bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate.

To a preferred embodiment of the invention contains an inventive textile treatment agent as cationic surfactant a quaternary ammonium compound, in particular Esterquat, preferably in amounts of> 0.1 wt .-%, advantageously 1 to 40 wt .-%, in particular 3 to 30 wt .-%, wt .-% based on the entire textile treatment agent.

meaningful Upper limits for the amount of cationic surfactant used may also be at 25 wt%, 20 wt%, 15 wt% or 10 % By weight.

meaningful Lower limits for the amount of cationic surfactant used may also be 4% by weight, 5% by weight or 10% by weight, % By weight, based in each case on the entire textile treatment agent.

When photocatalytic material is according to a preferred embodiment of the invention contain titanium dioxide, in particular a modified one Titanium dioxide, preferably a carbon-modified titanium dioxide.

The photocatalytic material, in particular the (preferably modified) Titanium dioxide, according to a preferred embodiment the invention in the textile treatment agent according to the invention in amounts of advantageously 0.0001 to 30 wt .-%, preferably 0.001 to 20 wt .-%, advantageously 0.01 to 15 wt .-%, in a further advantageous manner 0.1 to 10 wt .-%, even more advantageous 1 to 5 wt .-%, wt .-% based on the total fabric treatment agent.

To a preferred embodiment is in the (preferably modified) titanium dioxide around with carbon modified titanium dioxide. But it can also be modified differently Titanium dioxides are used, for example, modified with nitrogen Titanium dioxide or z. B. doped with rhodium and / or platinum ions Titanium dioxide. However, it is particularly according to the invention preferably that it is non-metal modified titanium dioxide is.

The carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt. -%, in particular from 0.4 to 0.8 wt .-% are. Advantageously, the TiO ₂ content of the carbon-modified titanium dioxide z. B. over 95 wt .-%, 96 wt .-%, 97 wt .-%, 98 wt .-% or 99 wt .-%, based on the total carbon-modified titanium dioxide.

If the carbon only in a surface layer of the titanium dioxide particles is embedded, so is a preferred embodiment in front. The modified titanium dioxide may advantageously additionally Contain nitrogen.

If the specific surface of the titanium dioxide, preferably of the modified titanium dioxide, after BET (BET advantageously after DIN ISO 9277: 2003-05 determined, preferably also simplified after DIN 66132: 1975-07 ) preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in a further advantageous manner 200 to 350 m ² / g, in particular 250 to 300 m ² / g, so is also a preferred embodiment.

The carbon-modified titanium dioxide may according to a preferred embodiment, for. Example, be obtained by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m ² / g by BET, with an organic carbon compound and the mixture is thermally treated at a temperature of up to 350 ° C.

The thereby usable carbonaceous substance can according to a preferred Embodiment be a carbon compound, which contains at least one functional group, preferably selected from OH, CHO, COOH, NHx, SHx. In particular, can it is in the carbon compound is a compound of the Group ethylene glycol, glycerine, succinic acid, pentaerythritol, Carbohydrates, sugars, starch, alkylpolyglucosides, organoammonium hydroxides or mixtures thereof. It is also possible that used as the carbonaceous substance carbon black or activated carbon becomes.

It may also be preferable that the carbonaceous substance advantageously mixed with the titanium compound is added to the modified titanium dioxide after the thermal treatment has a decomposition temperature of at most 400 ° C, preferably <350 ° C and particularly preferably <300 ° C.

The Preferably used for the preparation of the modified titanium dioxide Titanium compound which according to the aforementioned preferred embodiment with an organic carbon compound intimately mixed can be an amorphous, semi-crystalline or crystalline Titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate, which in turn is a preferred embodiment equivalent.

The thermal treatment of the mixture of the titanium compound and the Carbon compound can according to a preferred embodiment advantageously in a continuously operated calcining unit, preferably a rotary kiln are performed. The modified titanium dioxide can be, in particular in the context of the previously described, preferably z. B. obtained thereby, that a titanium dioxide (eg with a particle size in the range between 2 to 500 nm or z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. 200 to 400 nm), such as commercially available in powder or mud form, takes and from this a suspension in a liquid, preferably water. To the suspension is then advantageously a carbonaceous Substance added and it is mixed. Mixing can be supported be through the use of ultrasound. The mixing process (eg Stirring) may preferably last several hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer. Based on the solids of the suspension is the amount of the carbon compound advantageously 1-40 wt .-%, accordingly, the amount the titanium compound is preferably 60-99% by weight.

After that the liquid is removed, for example by filtration, Evaporate in vacuo or decant, and the residue is preferably dried (eg, preferably at temperatures from 70-200 ° C, advantageously over several hours, for example at least 12 hours) and then calcined, for example at a temperature of at least 260 ° C, preferably z. B. at 300 ° C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours. The calcination can advantageously take place in a closed vessel.

It may be advantageous that the calcination temperature, z. B. 300 ° C, within an hour is reached (slow Heating to 300 ° C).

there is preferably a color change of the powder from white to dark brown to beige or slightly yellowish-brownish. Too long a heating leads to inactive, colorless powders. The expert can estimate this with a few routine experiments. The calcination can, for. B. advantageously done so long, until after a color change of the powder from white over dark brown another color change to beige or slightly yellowish-brownish takes place.

A maximum temperature of 350 ° C should preferably not be exceeded. In the thermal treatment there is a decomposition of the organic carbon compound on the surface of the titanium compound, so preferably a modified titanium dioxide is formed, preferably 0.005-4 Wt .-% carbon.

After the thermal treatment, the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill. The grain fineness to be achieved depends on the grain size of the starting titanium compound. The particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt. The desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as with TiO ₂ pigments, but may also be below or above.

The contained in the textile treatment agent according to the invention photocatalytic material, preferably modified titanium dioxide may advantageously have a particle size in the Have range between 2 to 500 nm, ie z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. B. 200 to 400 nm. The particle size of the photocatalytic material, preferably modified titanium dioxide, Although preferably in the range of 100-500 nm, advantageously 200-400 nm lie. It may also be preferred that the Particle size is very small, z. B. in the area from 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or z. B. 5-50 nm or z. B. 8-30 nm or z. B. 10-20 nm. Very small particles, eg. With a particle size of in particular 2, 3, 4, 5 or 10 nm are preferably included, these can also form agglomerates with each other, which then correspondingly larger are, for. B. up to 600 nm or up to 500 nm or up to 400 nm or up to 300 nm in size, etc.

The Particle size can z. B. advantageously at Values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. In particular, very small particle sizes below 50 nm, below 40 nm, below 30 nm or below 20 nm be preferred. It may be advantageous in the manufacture of the modified titanium dioxide from micronised titanium dioxide, that is, titanium dioxide with a very small particle size, z. B. between 2 and 150 nm or z. b. between 5 and 100 nm. The Particle size can then z. B. advantageously at values such as 2 nm, 3 nm, 4 nm, 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The Bulk density of the preferably modified titanium dioxide is preferably in the range of 100 to 800 g / l, advantageously from 200 to 600 g / l, especially from 300 to 500 g / l. For example the bulk density may be 350 g / l, 400 g / l or 500 g / l.

To In a preferred embodiment, this is (preferably modified) titanium dioxide in the anatase crystal modification.

The The modified titanium dioxide described above is characterized a very good photocatalytic activity, in particular using daylight, off. Especially those of the human Eye perceptible radiation of the visible region of the spectrum with wavelengths between 380 and 800 nm are used for the purposes of mining, deactivating or reducing Impurities from the described modified titanium dioxide very well used. Also the UV radiation between 10-380 nm can be used very well.

To a preferred embodiment of the invention the textile treatment agent of the invention Humectants, preferably glycerol, dimers and trimers of Glycerol, ethylene glycol, propylene glycol, sugar alcohols, as preferably Glucitol, xylitol, mannitol, alkylpolyglucosides, fatty acid glucamides, Sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, hydrogenated glucose syrup and / or Mixtures of the abovementioned, preferably in quantities of 0.01 to 10 Wt .-%, advantageously 0.1 to 5 wt.%, In particular 0.5 to 2 wt .-%, wt .-% in each case based on the entire textile treatment agent.

It could found that if moisturizers contained is a further improved deposit of finely divided photoactive Material in the context of a conventional textile treatment on the textiles resulted. A particularly suitable humectant is glycerin as well as its dimers and trimers and / or mixtures thereof. We could find that in the presence of, preferably Organic, humectant means a very good effect the agent against impurities resulted, especially at Use of glycerin.

• a) photokatalytisches Material, vorzugsweise solches, wie zuvor beschrieben, insbesondere in Mengen wie zuvor beschrieben
• b) Kationtensid, vorzugsweise solches, wie zuvor beschrieben, insbesondere in Mengen wie zuvor beschrieben
• c) optional Riechstoffe, vorzugsweise in Mengen > 0,01 Gew.-%, vorteilhafterweise 0,05 bis 10 Gew.-%, insbesondere 0,1 bis 5 Gew.-%,
• d) Wasser, vorzugsweise in Mengen > 50 Gew.-%, vorteilhafterweise > 60 Gew.-%, insbesondere > 70 Gew.-%
• e) optional Lösungsmittel, vorzugsweise einwertige Alkohole, insbesondere 2-Propanol, vorteilhafterweise in Mengen von 0,05 bis 5 Gew.-%, vorzugsweise 0,1 bis 4 Gew.-%, insbesondere 0,3–3 Gew.-%,
• f) optional Feuchthaltemittel, vorzugsweise solches, wie zuvor beschrieben, insbesondere in Mengen wie zuvor beschrieben,
• g) optional Emulgatoren, vorzugsweise Niotenside, vorteilhafterweise in Mengen von 0 bis 8 Gew.%, insbesondere 0,1 bis 5 Gew.-%
• h) optional pH-Stellmittel, vorzugsweise 0,01 bis 5 Gew.-%, insbesondere 0,02 bis 1 Gew.-%
• i) optional Elektrolyte, vorzugsweise aus der Gruppe der anorganischen Salze, vorteilhafterweise MgCl₂ oder NaCl, 0,01 bis 5 Gew.-%, insbesondere 0,05 bis 2 Gew.-%,
• j) optional hautpflegende Aktivstoffe, vorzugsweise in einer Menge von 0 bis 15 Gew.-%, vorteilhafterweise 0,1–10 Gew.-%, insbesondere 0,5 bis 5 Gew.-%,
• j) optional Verdicker, z. B. auf Polyacrylat-Basis, vorzugsweise in Mengen von 0,01 bis 3 Gew.-%, insbesondere 0,1 bis 1 Gew.-%,

Gew.-% jeweils bezogen auf das gesamte Textilbehandlungsmittel.According to a preferred embodiment, the textile treatment agent according to the invention contains

• a) photocatalytic material, preferably such, as described above, in particular in amounts as described above
• b) cationic surfactant, preferably such as described above, in particular in amounts as described above
• c) optional fragrances, preferably in amounts of> 0.01% by weight, advantageously 0.05 to 10% by weight, in particular 0.1 to 5% by weight,
• d) water, preferably in amounts of> 50% by weight, advantageously> 60% by weight, in particular> 70% by weight
• e) optionally solvents, preferably monohydric alcohols, in particular 2-propanol, advantageously in amounts of 0.05 to 5 wt .-%, preferably 0.1 to 4 wt .-%, in particular 0.3-3 wt .-%,
• f) optionally humectants, preferably those as described above, in particular in amounts as described above,
• g) optionally emulsifiers, preferably nonionic surfactants, advantageously in amounts of from 0 to 8% by weight, in particular from 0.1 to 5% by weight
• h) optionally pH adjusting agent, preferably 0.01 to 5 wt .-%, in particular 0.02 to 1 wt .-%
• i) optionally electrolytes, preferably from the group of inorganic salts, advantageously MgCl ₂ or NaCl, 0.01 to 5 wt .-%, in particular 0.05 to 2 wt .-%,
• j) optional skin-care active substances, preferably in an amount of 0 to 15 wt .-%, advantageously 0.1-10 wt .-%, in particular 0.5 to 5 wt .-%,
• j) optional thickener, z. B. polyacrylate-based, preferably in amounts of 0.01 to 3 wt .-%, in particular 0.1 to 1 wt .-%,

% By weight, based in each case on the entire textile treatment agent.

Preferably in a textile treatment agent according to the invention according to the above embodiment usable thickener, skin care active ingredients, electrolytes, pH regulators, solvents, Fragrances and / or nonionic surfactants will become available later described.

The Textile treatment agent, preferably aftertreatment agent, in particular Softener, may also preferably nonionic plasticizing components, especially polyoxyalkylene glycol alkanoates, Polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, Alkyl polyglucosides, in particular sorbitan mono, di- and triesters, and fatty acid esters of polycarboxylic acids. But also a softening clay (for example bentonite) can be included.

As optional nonionic surfactants it is possible to use preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol residue is linear or preferably methyl-branched in the 2-position may be or contain linear and methyl-branched radicals in the mixture, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for example of coconut, palm, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. The preferred ethoxylated alcohols include, for example, C _12-14 alcohols with 3 EO, 4 EO or 7 EO, C _9-11 alcohols with 7 EO, C _13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C _12-18 -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C _12-14 -alcohol with 3 EO and C _12-18 -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO. Nonionic surfactants containing EO and PO groups together in the molecule can also be used according to the invention. Here, block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers. Of course, it is also possible to use mixed alkoxylated nonionic surfactants in which EO and PO units are not distributed in blocks, but randomly. Such products are available by the simultaneous action of ethylene and propylene oxide on fatty alcohols.

In addition, as further optional nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol representing a glycose moiety having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; preferably x is 1.2 to 1.4. Alkyl glycosides are known, mild surfactants and are therefore preferably used in the surfactant mixture.

A another class of preferred, optional nonionic Surfactants, either as the sole nonionic surfactant or can be used in combination with other nonionic surfactants, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably with 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl ester.

Also nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide may be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated Fatty alcohols, especially not more than half of them.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R1 für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable surfactants are polyhydroxy fatty acid amides of the formula (VII)

in which RCO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 1 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which are usually prepared by reductive amination of a reducing Sugar can be obtained with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R¹ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R² für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the formula (VIII)

in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{1 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{2 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.

[Z] is preferably obtained by reductive amination of a sugar, for example, glucose, fructose, maltose, lactose, galactose, mannose or xylose. The N-alkoxy or N-aryloxy-substituted compounds can then by reaction with fatty acid methyl esters in the presence of an alkoxide as a catalyst in the desired Polyhydroxyfatty acid amides are transferred.

The nonionic surfactants can in the inventive Textile treatment agents, in particular fabric softeners, preferably be contained in amounts of 0-8 wt .-%. However it is also possible, especially if it concerns the textile treatment agents should act to liquid detergent that this example 5 to 30 wt .-%, preferably 7 to 20 wt .-% and in particular 9 may contain up to 15% by weight of nonionic surfactant,% by weight in each case based on the entire textile treatment agent. This is less prefers.

To a preferred embodiment of the invention are also Skin care or skin care active ingredients in the inventive Textile treatment agents, in particular in amounts> 0.01% by weight,% by weight based on the entire textile treatment agent.

Skin care products (skin-care active ingredients) can in particular those Be agents that give the skin a sensory benefit, z. By delivering lipids and / or moisturizing factors. Skin care products may, for. Proteins, amino acids, Lecithins, lipids, phosphatides, plant extracts, vitamins; also fatty alcohols, fatty acids, fatty acid esters, Waxes, Vaseline, paraffins act as skin care products.

• a) Wachse wie beispielsweise Carnauba, Spermaceti, Bienenwachs, Lanolin und/oder Derivate derselben und andere.
• b) Hydrophobe Pflanzenextrakte
• c) Kohlenwasserstoffe wie beispielsweise Squalene und/oder Squalane
• d) Höhere Fettsäuren, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurinsäure, Stearinsäure, Behensäure, Myristinsäure, Palmitinsäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure und/oder mehrfach ungesättigte Fettsäuren und andere.
• e) Höhere Fettalkohole, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol, Cholesterol und/oder 2-Hexadecanaol und andere.
• f) Ester, vorzugsweise solche wie Cetyloctanoate, Lauryllactate, Myristyllactate, Cetyllactate, Isopropylmyristate, Myristylmyristate, Isopropylpalmitate, Isopropyladipate, Butylstearate, Decyloleate, Cholesterolisostearate, Glycerolmonostearate, Glyceroldistearate, Glyceroltristearate, Alkyllactate, Alkylcitrate und/oder Alkyltartrate und andere.
• g) Lipide wie beispielsweise Cholesterol, Ceramide und/oder Saccharoseester und andere
• h) Vitamine wie beispielsweise die Vitamine A und E, Vitaminalkylester, einschließlich Vitamin C Alkylester und andere.
• i) Sonnenschutzmittel
• j) Phospholipide
• k) Derivate von alpha-Hydroxysäuren
• m) Germizide für den kosmetischen Gebrauch, sowohl synthetische wie beispielsweise Salicylsäure und/oder andere als auch natürliche wie beispielsweise Neemöl und/oder andere
• n) Silikone

sowie Mischungen jeglicher vorgenannter Komponenten.Skin-care active substances are all those active substances which give the skin a sensory and / or cosmetic advantage. Skin-care active substances are preferably selected from the following substances:

• a) waxes such as carnauba, spermaceti, beeswax, lanolin and / or derivatives thereof and others.
• b) Hydrophobic plant extracts
• c) hydrocarbons such as squalene and / or squalane
• d) Higher fatty acids, preferably those having at least 12 carbon atoms, for example lauric acid, stearic acid, behenic acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and / or polyunsaturated fatty acids and others.
• e) Higher fatty alcohols, preferably those having at least 12 carbon atoms, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cholesterol and / or 2-hexadecanol and others.
• f) esters, preferably such as cetyloctanoates, lauryl lactates, myristyl lactates, cetyl lactates, isopropyl myristates, myristyl myristates, isopropyl palmitates, isopropyl adipates, butyl stearates, decyl oleates, cholesterol stearates, glycerol monostearates, glycerol distearates, glycerol tristearates, alkyl lactates, alkyl citrates and / or alkyl tartrates and others.
• g) lipids such as cholesterol, ceramides and / or sucrose esters and others
• h) vitamins such as vitamins A and E, vitamin C esters, including vitamin C alkyl esters and others.
• i) sunscreen
• j) phospholipids
• k) derivatives of alpha hydroxy acids
• m) Germicides for cosmetic use, both synthetic such as salicylic acid and / or others as well as natural such as neem oil and / or others
• n) silicones

as well as mixtures of any of the aforementioned components.

Prefers usable skin-care active substances are preferably also essential oils, in particular selected from the group of Angelica fine - Angelica archangelica, anise - Pimpinella anisum, Benzoin siam - Styrax tokinensis, cabreuva - myrocarpus fastigiatus, cajeput - melaleuca leucadendron, Cistrose - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltannennadel - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle Helichrysum ang., Ginger extra - Zingiber off., St. John's wort - Hypericum perforatum, jojoba, chamomile German - Matricaria recutita, chamomile blue fine - Matricaria chamomilla, chamomile roman - Anthemis nobilis, chamomile wild - Ormensis multicaulis, carrot - Daucus carota, mountain pine - Pinus mugho, Lavandin - Lavendula hybrida, Litsea Cubeba - (May Chang), Manuka - Leptospermum scoparium, Melissa - Melissa officinalis, sea pine - Pinus pinaster, myrrh - Commiphora molmol, myrtle - Myrtus communis, Neem - Azadirachta, Niaouli - (MQV) Melaleuca quin. viridiflora, Palmarosa - Cymbopogom martini, patchouli - Pogostemon patchouli, Peru balsam - Myroxylon balsamum var. pereirae, Raventsara aromatica, rosewood - Aniba pink odora, sage - Salvia officinalis Horsetail - Equisetaceae, Yarrow extra - Achilles millefolia, plantain - Plantago lanceolata, Styrax - Liquidambar orientalis, Tagetes (Marigold) Tagetes patula, Tea Tree - Melaleuca alternifolia, Tolu Balsam - Myroxylon Balsamum L., Virginia Cedar - Juniperus virginiana, Frankincense (Olibanum) - Boswellia carteri, silver fir - Abies alba. The use of essential oils corresponds to one preferred embodiment of the invention.

preferred usable skin-care active substances are preferably also skin-protecting oils, in particular selected from the group algae oil Oleum Phaeophyceae, Aloe Vera Oil Aloe vera brasiliana, Apricot kernel oil Prunus armeniaca, arnica Arnica montana, avocado oil Persea americana, borage oil Borago officinalis, calendula oil Calendula officinalis, Camellia oil Camellia oleifera, safflower oil Carthamus tinctorius, peanut oil Arachis hypogaea, hemp oil Cannabis sativa, hazelnut oil Corylus avellana /, St. John's wort oil Hypericum perforatum, jojoba oil Simondsia chinensis, carrot oil Daucus carota, coconut oil Cocos nucifera, pumpkin seed oil Curcubita pepo, kukui nut oil Aleurites moluccana, macadamia nut oil macadamia ternifolia, almond oil Prunus dulcis, olive oil Olea europaea, peach kernel Prunus persica, rapeseed oil Brassica oleifera, castor oil Ricinus communis, black cumin oil Nigella sativa, sesame oil Sesamium indicum, sunflower oil Helianthus annus, grape seed oil Vitis vinifera, walnut oil Juglans regia, wheat germ oil Triticum sativum. The use of skin-protecting oils corresponds to a preferred one Embodiment of the invention.

The optional contained skin-care active ingredients go to the textile during the textile treatment and then turn from the textile to the skin when the textile comes in contact with the skin, z. B. when wearing clothes. On In this way, skin-care active ingredients in the inventive Textile treatment agents of the skin of the consumer to the advantage. When using textile treatment agents according to the invention, which optionally contain skin care active ingredients, in a manual Textile treatment processes, the skin-care active ingredients the skin of the consumer directly to the advantage, namely upon contact of the hand with the wash liquor. The use of skin care Active substances is purely optional.

Prefers it is when the textile treatment agent according to the invention contained in an opaque packaging. This corresponds to a preferred embodiment of the invention. Also preferred are disposable portions, z. b. in the form of pouches.

One Another object of the invention is a method for applying photocatalytic material on textiles by treating this Textiles in a textile treatment bath containing an inventive Textile treatment agents. It is also possible that textile to contact directly with the textile treatment agent.

The invention further provides a process for the cleaning, care, finishing, softening and / or conditioning of textiles by treating these textiles in a textile treatment bath comprising a textile treatment agent according to the invention, at and / or following exposure of the textiles to light in the wavelength range of 10 -1200 nm. It is also possible that textile directly with the textile to contact treatment agents.

If the method according to the invention for the removal, Deactivation or reduction of microorganisms, in particular Bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm, so is a preferred Embodiment of the invention before.

One Inventive method for the prophylaxis treatment of textiles in the form of an anticipatory defense and inhibition of Stains and stains using light in the wavelength range of 10-1200 nm again constitutes a preferred embodiment of the invention.

One Inventive method for equipment of textiles with photocatalytic material for relief the removability of colored dirt (colored spots) of textiles using light in the wavelength range of 10-1200 nm also represents a preferred embodiment of the invention represents.

One Inventive method for equipment of textiles with photocatalytic material to reduce the Fiber adhesion of dirt, preferably colored Stains on textiles using light imt wavelength range 10-1200 nm is also a preferred embodiment of the Invention.

One Inventive method for equipment of textiles with photocatalytic material to increase the water solubility of dirt, preferably colored Stains on textiles, using light imt wavelength range 10-1200 nm again constitutes a preferred embodiment of the invention.

One Inventive method for equipment of textiles with photocatalytic material to prevent the Forming fetid smells on the textiles, using light in the wavelength range of 10-1200 nm corresponds to a further preferred embodiment the invention.

One Inventive method for equipment of textiles with photocatalytic material to equip the Textiles with a self-cleaning capacity, using of light in the wavelength range of 10-1200 nm also provides a preferred embodiment of the invention represents.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B. aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften
• – farbige Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben,

unter Einsatz von Licht im Wellenlängenbereich von 10–1200 nm,
stellt wiederum eine bevorzugte Ausführungsform der Erfindung dar.A method according to the invention for removing or reducing colored stains or stains on textiles, which in particular originate from:

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B. green grasses,
• - Technical dyes from cosmetics, inks, color pencils
• - colored metabolites and / or excretions of mold or other micro flora or microbial growth or microbes,

using light in the wavelength range of 10-1200 nm,
again represents a preferred embodiment of the invention.

One inventive method using a automatic washing machine, preferably an automatic washing machine with light source, wherein the textile treatment agent in particular in Rinsing is added, again provides a preferred Embodiment of the invention.

One inventive method, which is at a manual process which takes place in an open tub is executed, in particular hand wash and / or Soaking, taking the tub after the textiles to be treated are penetrated with the wash liquor, light in the wavelength range of 10-1200 nm, especially sunlight, preferably for a period> 5 Minutes, also constitutes a preferred embodiment of the invention.

All the methods described above are particularly effective utilizing light in the visible range (380-800 nm) and / or in the UV range (10-380 nm). It corresponds, so, in relation to all aforementioned method, each of a preferred embodiment, when light in the wavelength range 380-800 nm and / or in the range 10-380 is used.

The Textile treatment agents according to the invention can in addition to the mandatory components cationic surfactant and photocatalytic Material contains other optional ingredients. These will in the following z. T. described in more detail.

One Textile treatment agent according to the invention optionally also include anionic surfactant, although less so is preferred. It is more preferred if an inventive Textile treatment agent is free of anionic surfactant, so less than 5 wt .-%, 2 wt .-% or 1 wt .-% of anionic surfactant, in particular but 0 wt .-% of anionic surfactant, wt .-% based on the entire textile treatment agent.

As anionic surfactant, for example, those of the sulfonate type and sulfates can be used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise suitable are the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters As well as their mixtures to understand, as in the production through Esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation of saturated fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, Lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. Also 2,3-alkyl sulfates, which can be obtained as commercial products of Shell Oil Company under the name DAN ^® , are suitable anionic surfactants.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO are suitable.

Further suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and in particular ethoxylated fatty alcohols. Preferred sulfosuccinates contain C _8-18 fatty alcohol residues or mixtures of these. Particularly preferred sulfosuccinates contain a fatty alcohol residue derived from ethoxylated fatty alcohols, which in themselves constitute nonionic surfactants (see description below). Sulfosuccinates, whose fatty alcohol residues are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are again particularly preferred. Likewise, it is also possible to use alk (en) ylsuccinic acid having preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.

Especially preferred anionic surfactants are soaps. Suitable are saturated and unsaturated fatty acid soaps, such as the salts lauric, myristic, palmitic, Stearic acid, (hydrogenated) erucic acid and behenic acid and in particular from natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids, derived soap mixtures.

The anionic surfactants including the soaps may be in the form of their sodium, potassium or ammo niumsalze and as soluble salts of organic bases, such as mono-, di- or triethanolamine. The anionic surfactants are preferably present in the form of their sodium or potassium salts, in particular in the form of the sodium salts.

Should it is desirable to use anionic surfactants in the fabric treatment agent so could the content of such textile treatment agents on anionic surfactants in particular embodiments z. B. 2 to 30 wt .-%, preferably 4 to 25 wt .-% and in particular From 5 to 22% by weight, based in each case on the entire textile treatment agent, be. Preferably, in the inventive However, textile treatment agents contain no anionic surfactants, which corresponds to a preferred embodiment of the invention.

Also the use of amphoteric surfactants comprising ampholytes and betaines, is possible, for. B. in amounts> 0.01 wt .-%, based on the total Textile treatment agents. Suitable amphoteric surfactants are, for. B. N- (acylamidoalkyl) betaine, N-alkyl-β-aminopropionates, N-alkyl-β-iminopropionates as well as those commonly associated with detergents usable amphoteric surfactants. In a preferred embodiment of Invention is the textile treatment agent according to the invention but completely free of amphoteric surfactant.

Also the use of gemini surfactants is possible, for. B. in amounts> 0.01 wt .-%, based on the entire textile treatment agent. Gemini surfactants are surfactants, each two hydrophobic and hydrophilic groups in the molecule contain. They are characterized by an unusually high Interfacial activity. In a preferred Embodiment of the invention is the inventive Textile treatment agent but completely free Gemini surfactants.

additionally to the cationic surfactant and photocatalytic material the textile treatment agents according to the invention Optionally, other ingredients, which z. T. also already called were, such. As humectants, in particular those optional ingredients which are the application and / or aesthetic Properties of the textile treatment agent further improve. in the The present invention includes preferred textile treatment agents additionally one or more substances from the group of Builders, bleaches, bleach activators, Enzymes, electrolytes, humectants, non-aqueous Solvents, pH adjusters, perfumes, perfume carriers, Fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils, Anti redeposition agents, optical brighteners, grayness inhibitors, Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, Preservatives, corrosion inhibitors, antistatic agents, bittering agents, Ironing aids, repellents and impregnating agents, Swelling and anti-slip agents, neutral filler salts as well if necessary UV absorber.

When Builders that are optional in the textile treatment products may be included, for example, silicates, aluminum silicates (especially zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.

Suitable crystalline layered sodium silicates have the general formula NaMSi _x O _{2x + 1} .H ₂ O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2, 3 or 4 are. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Preferably, however, the textile treatment agent according to the invention is free of crystalline, layered sodium silicates, ie preferably contains less than 3 wt .-%, 2 wt .-% or 1 wt .-% of crystalline, layered sodium silicates, in particular is no crystalline, layered sodium silicate, ie 0 wt .-%, wt .-%, based on the total textile treatment agent.

It is also possible to use amorphous sodium silicates with a Na ₂ O: SiO ₂ modulus of from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which Delayed and have secondary washing properties. The dissolution delay compared with conventional amorphous sodium silicates may have been caused in various ways, for example by surface treatment, compounding, compaction / densification or by overdrying. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products microcrystalline areas of the Size 10 to have a few hundred nm, with values up to a maximum of 50 nm and in particular to a maximum of 20 nm are preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.

Preferably is the textile treatment agent according to the invention but free of amorphous sodium silicates, so contains preferably less than 3 wt .-%, 2 wt .-% or 1 wt .-% of amorphous Sodium silicates, in particular, is not at all, so 0 wt .-% amorphous sodium silicate, wt .-% based on the entire textile treatment agent

A usable finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P zeolite MAP ^® (commercial product from Crosfield) is particularly preferred. Also suitable, however, are zeolite X and mixtures of A, X and / or P. Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) which is sold by SASOL under the brand name VEGOBOND AX ^® and by the formula), nNa ₂ O · (1 - n) K ₂ O · Al ₂ O ₃ · (2-2.5) SiO ₂ · (3.5-5.5) H ₂ O n = 0.90-1.0
can be described. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols having 2 to 5 ethylene oxide groups , C ₁₂ -C ₁₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of less than 10 μm (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.

Preferably is the textile treatment agent according to the invention however, free of zeolite, so preferably contains less as 3 wt .-%, 2 wt .-% or 1 wt .-% of zeolite, in particular is at all none, ie 0 wt .-%, zeolite, wt .-% based on the total Textile treatment agents.

Of course it is also possible to use the generally known phosphates as builders, if such use is not for environmental reasons should be avoided. Particularly suitable are the sodium salts the orthophosphates, the pyrophosphates and in particular the tripolyphosphates.

Preferably is the textile treatment agent according to the invention but free of phosphate, so preferably contains less than 3% by weight, 2% by weight or 1% by weight of phosphate, in particular, none at all, ie 0 wt .-%, phosphate, wt .-% based on the total Textile treatment agents.

organic Builders which may be present in the textile treatment agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, Polyaspartates and monomeric polycarboxylates such as citrates, gluconates, Succinates or malonates, which are preferably used as sodium salts. If builders are to be used then they are organic builders to prefer.

It is also possible to use additional bleach. Among the compounds serving as bleaches in water H ₂ O ₂ , sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperacid or diperdodecanedioic acid.

Preferably is the textile treatment agent according to the invention however, free of additional bleach So preferably less than 3 wt .-%, 2 wt .-% or 1 wt .-% of additional bleach, in particular, is at all none, ie 0 wt.%, containing additional bleach, Wt .-% based on the total textile treatment agent.

In order to achieve an improved bleaching effect when washing at temperatures of 60 ° C and below, bleach activators can be incorporated into the fabric treatment agents. As bleach activators, it is possible to use compounds which, under perhydrolysis conditions, have aliphatic peroxycarboxylic acids with preference se 1 to 10 carbon atoms, in particular 2 to 4 carbon atoms, and / or optionally substituted perbenzoic acid, can be used. Suitable substances are those which carry O- and / or N-acyl groups of the stated C atom number and / or optionally substituted benzoyl groups. Preference is given to polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, in particular tetraacetylglycoluril (TAGU), N- Acylimides, in particular N-nonanoylsuccinimide (NOSI), acylated phenolsulfonates, in particular n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular phthalic anhydride, acylated polyhydric alcohols, in particular triacetin, ethylene glycol diacetate and 2,5-diacetoxy- 2,5-dihydrofuran. However, the textile treatment agents according to the invention preferably contain no bleach activators.

additionally to the conventional bleach activators or in their place also so-called bleach catalysts in the textile treatment agent be incorporated. These substances are bleach-enhancing transition metal salts or transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Also Mn, Fe, Co, Ru, Mo, Ti, V, and Cu complexes containing nitrogen Tripod ligands and Co, Fe, Cu and Ru ammine complexes are known as Bleach catalysts usable. Preferably, the inventive Textile treatment agent but no bleach catalysts.

One Textile treatment agent according to the invention contain a thickener. This corresponds to a preferred one Embodiment of the invention. The thickener can for example, a polyacrylate thickener, xanthan gum, gellan Gum, guar gum, alginate, carrageenan, carboxymethyl cellulose, bentonites, Wellan Gum, locust bean gum, agar-agar, tragacanth, gum arabic, Pectins, polyoses, starch, dextrins, gelatin and casein include. But also modified natural substances such as modified starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and propylcellulose as well Called Kernmehlether, can be used as a thickener become.

Examples of polyacrylic and polymethacrylic thickeners include the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to the International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry and Fragrance Association (CTFA) ": carbomer), also referred to as carboxyvinyl polymers. Such polyacrylic acids are inter alia from the company. 3 V Sigma under the trade name Polygel ^® , z. B. Polygel DA, and from the company. BF Goodrich under the trade name Carbopol ^® available, z. Carbopol 940 (molecular weight about 4,000,000), Carbopol 941 (molecular weight about 1,250,000) or Carbopol 934 (molecular weight about 3,000,000). Furthermore, the following acrylic acid copolymers are included: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple ester, preferably formed with C _1-4 -alkanols (INCI acrylates copolymer), such as the copolymers of methacrylic acid, butyl acrylate and methyl methacrylate (CAS - name according to Chemical Abstracts service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) and, for example, by the company Rohm & Haas under the trade names Aculyn ^®. and Acusol ^®, and from Degussa (Goldschmidt) under the trade name Tego ^® polymer, z. The anionic non-associative polymers Aculyn 22, Aculyn 28, Aculyn 33 (crosslinked), Acusol 810, Acusol 820, Acusol 823 and Acusol 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C _10-30 alkyl acrylates with one or more monomers selected from the group of acrylic acid, methacrylic acid and their simple, preferably with C _1-4 Alkanols formed, esters (INCI acrylates / C _10-30 alkyl acrylate crosspolymer) and which are available, for example, from the company. BF Goodrich under the trade name Carbopol ^® , z. B. the hydrophobic Carbopol ETD 2623 and Carbopol 1382 (INCI Acrylates / C _10-30 alkyl acrylate crosspolymer) and Carbopol Aqua 30 (formerly Carbopol EX 473).

One Another preferred polymeric thickener is Xanthan gum, a microbial anionic heteropolysaccharide, which of Xanthomonas campestris and some other species under aerobic Conditions is produced and a molecular weight of 2 to 15 million Dalton has. Xanthan is made from a chain bound with β-1,4 Glucose (cellulose) with side chains formed. The structure of Subgroups consists of glucose, mannose, glucuronic acid, Acetate and pyruvate, where the number of pyruvate units is the viscosity of xanthan gum.

In particular, a fatty alcohol is also suitable as thickener. Fatty alcohols may be branched or unbranched, of native origin or of petrochemical origin. Preferred fatty alcohols have a C chain length of 10 to 20 C atoms, preferably 12 to 18. Mixtures are preferred gene of different C-chain lengths, such as tallow fatty alcohol or coconut fatty alcohol used. Examples are Lorol ^® Special (C _12-14 -ROH) or Lorol ^® Technical (C _12-18 -ROH) (both ex Cognis).

preferred Contain textile treatment agent according to the invention based on the entire textile treatment agent advantageously 0.01 to 3% by weight and preferably 0.1 to 1% by weight of thickener. The Amount of thickener used is dependent on the type of thickener and the desired Degree of thickening.

The Textile treatment agent may be enzymes in encapsulated form and / or contained directly in the textile treatment agent. As enzymes come especially those from the classes of hydrolases such as proteases, Esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, β-glucanases, Oxidases, peroxidases, perhydrolases and / or laccases and mixtures the enzymes mentioned in question. All of these hydrolases carry in the Laundry to remove stains such as protein, grease and or starchy stains and grayness. Cellulases and other glycosyl hydrolases may be over it By removing pilling and microfibrils for color retention and to increase the softness of the textile. to Bleaching or to inhibit color transfer can also Oxireduktasen be used. Particularly well suited from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens recovered enzymatic agents. Preferably, proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular Interest. Examples of such lipolytic acting Enzymes are the known cutinases. Also peroxidases or oxidases have proven to be suitable in some cases. To the suitable amylases include in particular α-amylases, Iso-amylases, pullulanases and pectinases. Being cellulases preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures of these used. Because different types of cellulase are affected by their CMCase and avicelase activities by targeted mixtures of cellulases the desired Activities are discontinued. Is particularly advantageous it, if the Textilbehandlggsggs Mannanase included, and in particular incorporated in micro-chips and / or speckles. This corresponds to a preferred embodiment of the invention It has been found that mannanase in combination with the photocatalytic material a particularly good effect in the soil removal of galactomannanhaltigen residues on textiles. The use of tannase is also preferred.

The Enzymes may be adsorbed to carriers, to protect against premature decomposition. The amount the enzymes, the enzyme liquid formulation (s) or the enzyme granules directly in the textile treatment agent, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.

It but is more preferred that the textile treatment agent does not contain any enzymes. This corresponds to a preferred one Embodiment.

As electrolytes from the group of inorganic salts, a wide number of different salts can be used. Preferred cations are the alkali and alkaline earth metals, preferred anions are the halides and sulfates. From a production point of view, the use of NaCl or MgCl ₂ in the textile treatment agents is preferred. The proportion of electrolytes in the textile treatment agent may, for. B. usually be 0.1 to 5 wt .-%.

Non-aqueous solvents which can be used in the textile treatment agents according to the invention are derived, for example, from the group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers. Preferably, the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, diglycol, propyl or butyldiglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether Propylene glycol methyl, ethyl or propyl ether, dipropylene glycol monomethyl or ethyl ether, di-isopropylene glycol monomethyl or ethyl ether, methoxy, ethoxy or Butoxytriglykol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures of these solvents. Non-aqueous solvents may be used in the textile according to the invention are preferably used in amounts between 0.5 and 15 wt.%, But preferably below 12 wt .-% and in particular below 9 wt .-%.

The Viscosity of the textile treatment agents according to the invention (especially in the form of liquid detergents or softeners) can by standard methods (for example, Brookfield viscometer LVT-II at 20 rpm and 20 ° C, spindle 3) and is especially preferred for liquid detergents in the range of 500 to 5000 mPas. Preferred textile treatment agents in the form of liquid detergents have viscosities of preferably 700 to 4000 mPas, wherein values between 1000 and 3000 mPas are particularly preferred. The viscosity of textile treatment agents according to the invention in Form of fabric softeners which are preferred according to the invention are preferably 20 to 4000 mPas, with values between 40 and 2000 mPas are particularly preferred. Especially preferred is the viscosity of fabric softeners from 40 to 1000 mPas.

Around the pH of the textile treatment agents according to the invention can bring in the desired area, the use can be displayed by pH adjusters. Can be used here all known acids or alkalis, unless their use for application or ecological reasons or for reasons of consumer protection. Usually exceeds the amount of these adjusting agents 7 wt .-% or preferably 5 wt .-% the overall formulation is not.

Of the pH value of the textile treatment agent according to the invention in the form of a liquid detergent is preferably between 4 and 10 and preferably between 5.5 and 8.5. The pH of the textile treatment agent according to the invention in the form of a fabric conditioner, which is preferred according to the invention is preferably between 1 and 6 and preferably between 1.5 and 3.5.

In a preferred embodiment contains the Textile treatment agent optionally one or more perfumes (Perfume oils, fragrances) in an amount of usually to 10% by weight, preferably 0.01 to 5% by weight, in particular 0.05 to 3 wt .-%, particularly preferably 0.1 to 2 wt .-% and extremely preferably from 0.4 to 0.8% by weight. Here is the amount of used Perfume also depends on the type of textile treatment agent.

When Perfume oils (fragrances, fragrances) can individual fragrance compounds, eg. B. the synthetic products of the type of esters, ethers, aldehydes, ketones, alcohols and hydrocarbons be used. However, mixtures of various are preferred Fragrances are used, which together create an appealing fragrance produce. Such perfume oils can also contain natural fragrance mixtures, such as those from vegetable Sources are accessible.

With The term perfume oil are preferably in themselves meant perfume compositions which commonly be used for product scenting and in particular for human Discretion are fragrant. This will be explained with an example. Will a professional z. B. make a detergent fragrant, He usually does not just do that for him a (well) smelling substance, but a collective (well) smelling Substances. Such a collective usually exists from a variety of individual fragrances, eg. B. more than 10 or 15, preferably up to 100 or more. These fragrances form interacting a desired fragrant, harmonious Smell image.

One usable perfume oil can be individual fragrance compounds, z. As the synthetic products of the ester, ether, aldehyde, Ketones, alcohols and hydrocarbons. fragrance compounds the type of ester are z. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethyl acetate, benzyl acetate, ethylmethylphenylglycinate, allylcyclohexyl-propionate, Styrallyl propionate, benzyl salicylate, cyclohexyl salicylate, floramate, Melusat and Jasmecyclat. For example, the ethers include Benzyl ethyl ether and Ambroxan, to the aldehydes z. B. the linear Alkanals with 8-18 C atoms, citral, citronellal, citronellyloxy-acetaldehyde, Cyclamenaldehyde, Lilial and Bourgeonal, to the ketones z. B. the Jonone, α-isomethylionone and methyl cedryl ketone, to the Alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the terpenes like limonene and pinene. However, mixtures are preferred different fragrances used, which together create an appealing Generate fragrance of the perfume oil formed.

The perfume oils can also contain natural fragrance mixtures, as they are available from plant sources, eg. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, Wa cholderberry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as orange blossom oil, neroliol, orange peel oil and sandalwood oil. In order to be perceptible, a fragrance must be volatile, with molecular weight also playing an important role in addition to the nature of the functional groups and the structure of the chemical compound. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note", "middle note or body" and "base note "(end note or dry out) divided.

Tenacious Fragrances, in the context of the present invention advantageously can be used, for example, the essential oils like angelica root oil, aniseed oil, arnica blossom oil, Basil oil, bay oil, Champacablütenöl, Edling fir oil, Edel fir cone oil, Elemiöl, Eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, Geranium oil, ginger grass oil, guaiac wood oil, Gurjun Balm Oil, Helichrysum Oil, Ho Oil, Ginger oil, iris oil, cajeput oil, calamus oil, Chamomile oil, camphor oil, kanga oil, cardamom oil, Cassia oil, pine needle oil, Kopaïva balsam oil, Coriander oil, spearmint oil, caraway oil, Cumin oil, lemongrass oil, musk kernel oil, Myrrh oil, clove oil, neroli oil, niaouli oil, Olibanum oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, peppermint oil, allspice oil, pine oil, Rose oil, rosemary oil, sandalwood oil, celery oil, Star anise, thuja oil, thyme oil, verbena oil, Vetiver oil, juniper berry oil, wormwood oil, Wintergreen Oil, Ylang Ylang Oil, Hyssop Oil, Cinnamon oil, cinnamon leaf oil and cypress oil.

But also the higher-boiling or solid fragrances natural or of synthetic origin may be within the scope of the present invention Invention advantageously as adherent fragrances or fragrance mixtures be used. These connections include the following mentioned compounds and mixtures thereof: ambrettolide, α-amyl cinnamic aldehyde, Anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, Acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, Benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, Farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, Heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, Hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, Iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmone, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, Methyl n-amyl ketone, methyl anthranilate, p-methyl acetophenone, Methylchavikol, p-methylquinoline, methyl-β-naphthylketone, Methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, Nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethylacetal, phenylacetic acid, pulegone, Safrol, salicylic acid isoamyl ester, salicylic acid methyl ester, salicylic acid hexyl ester, Salicylic acid cyclohexyl ester, santalol, skatole, terpineol, Thymen, thymol, γ-undelactone, vanilin, veratrum aldehyde, Cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, Zimtsäurebenzylester.

To the more volatile odoriferous substances, which are part of the present invention can be used advantageously include especially the lower-boiling fragrances natural or synthetic origin, used alone or in mixtures can be. Examples of more volatile Fragrances are alkyl isothiocyanates (alkyl mustard), butanedione, Limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The above-mentioned fragrances are alone or in a mixture according to present invention can be used with the advantages already mentioned.

Especially can also scents from the group of allyl alcohol esters, Esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof.

Allyl alcohol esters are the esters of allyl alcohol, which has the following structural feature, C (OH) -C = C. Examples of Allylalkohlester are in particular allyl amyl glycolate, Allylanthranilat, allyl benzoate, allyl butyrate, Allylcaprat, allyl caproate, allyl cinnamate, Allylcyclohexanacetat, Allylcyclohexanbutyrat, Allylcyclohexanpropionat, allyl heptoate, Allylnonanoat, Allylsalicylat, Amylcinnamylacetat, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, Geranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbutyrat , Methallylcaproat, neryl acetate, Nerylbutyrat, Amylcinnamylformiat, Alphamethylcinnamylacetat, Methylgeranyl tiglat, Mertenylacetat, farnesyl acetate, fenchyl acetate, Geranylanthranilat, geranyl butyrate, Gerany iso-butyrate, Geranylcaproat, Geranylcaprylat, Geranylethylcarbonat, geranyl formate, Geranylfuroat, Geranylheptoat, Geranylmethoxyacetat, Geranylpelargonat, geranyl phenylacetate, Geranylphthalat, Geranyl propionate, geranyl iso-propoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans 2-hexenyl valerate, beta-pentenyl acetate, alpha-phenylallyl acetate, prenyl acetate, trichloromethylphenylcarbinyl acetate and / or mixtures thereof. Allyl alcohol esters may preferably be contained in the textile treatment agent according to the invention.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are in particular ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2 Methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-ylacetate, prenylacetate, 4-tert-butylcyclohexylacetate, 2-tert-butylcyclohexylacetate, Vertenex (4-tert-butylcyclohexylacetate); butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, laevomenthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate, menthyl-i so-butyrate, menthyl formate, laevo-menthylphenyl acetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexylphenyl acetate, Cyclohexyl propionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methyl amyl acetate, methyl benzyl carbinyl acetate, methyl butyl cyclohexanyl acetate, 5-methyl-3-butyltetrahydropyran-4-yl acetate, methyl citrate, methyl isophosphate, 2-methylcyclohexyl acetate, 4-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinylacetate , Methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformiate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methylphen ylcarbinyl-isobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinylcinnamate, methylphenylcarbinylformate, methylphenylcarbiriylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octyl-iso-butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, phenylethylmethylcarbinyl-iso-valerate, phenylethylene glycol diphenylacetate, phenylethylethyl carbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, isopropylcaprate, isopropylcaproate, isophoractylcaprylate, isopropylcinnamate , para-isopropylcyclohexanylacetate, propylglycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl-n-hegt-1-yne carbonate, isopropyl pelargonate, isopropylpropionate, isopropylundecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate, iso pulegyl acetate, isopulegyl acetoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate, vanillin triacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures thereof. These esters may preferably be contained in the textile treatment agent of the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate Dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-eu genyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallyl formate, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat , Linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, methylcyclopentenolone butyrate, methylcyclopentenolone propionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis-ocimenylacetate, phenylsalicylate, terpinylacetate, terpinylanthranilate, terpinylbenzoate, terpinyl-n- butyrate, terpinyl isobutyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the textile treatment agent of the invention.

Some Fragrance esters can be both ester allylic and secondary or allylic and tertiary alcohols, in particular Amyl vinyl carbinyl acetate, amyl vinyl carbinyl propionate, hexyl vinyl carbinyl acetate, 3-nonenyl acetate, 4-hydroxy-2-hexenyl acetate, linallylanthranilate, linallyl benzoate, Linallyl butyrate, linallyl butadate, linallyl carproate, linallyl caprylate, Linallyl cinnamate, linallyl citronellate, linallyl formate, linallylheptoate, Linallyl-N-methylanthranilate, linallylmethyltiglate, linallyl pelargonate, Linalinallyl phenylacetate, linallyl propionate, linallyl pyruvate, linallylsalicylate, Linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, Nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters may also be preferred contained in the textile treatment agent according to the invention be.

allylic Ketones are characterized by the following structural feature C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, Allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, Alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), Alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2-one), Beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one), Gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones can preferably in the textile treatment agent according to the invention be included.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propyl acetal, cinnamic aldehyde dimethyl acetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde diiso amyl acetal, acetaldehyde diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde di-n- propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde phenylethyl-n-propyl acetal, acetylvinyl dimethyl acetal, alpha-amyl cinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, Anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiole., Benzaldehyde diethyl acetal, benzaldehyde di (ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene glycol acetal, benzaldehyde, and the like yceryl acetal, Benzaldehydpropylenglycolacetal, Cinnamicaldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha-Methylcinnamicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, phenylacetaldehyde 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldeglyceryl acetal, citronellal cyclomonoglycol acetal, citronellaldiethyl acetal, citronellaldimethyl acetal, citronellaldiphenyl ethyl acetal, geranoxyacetaldehyde diethyl acetal and / or mixtures thereof. Acetals may preferably be included in the textile treatment agent according to the invention.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be contained in the textile treatment agent according to the invention.

preferred Examples of condensation products of amines and aldehydes are anisaldehydemethylanthranilate, aurantiol (hydroxycitronellalmethylanthranilate), Verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalane anthranilate, Hydroxycitronellallinallylanthranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, Vanillin methyl anthranilate and / or mixtures thereof. condensates of amines and aldehydes may preferably be used in the invention Be contained textile treatment agent.

In particular, it is advantageous if fragrances such. B. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3 -cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B ] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene brasylate , Eucalyptol, eugenol, exaltolide (cyclopentadecanolide), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8- hexamethylcyclopen ta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, hexylacetate, hexylcinnamaldehyde, hexylsalicylate, hydroxyambrane (2-cyclododecyl-propanol ), Hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyl di -isoamylene), lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl benzoic acid, methyl ester), Lyral (4- (4-hydroxy-4-methylpentyl) 3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, methyl cedryl (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2 -propen-1-yl-benzene), methyl dihydrojasmonate, methylnonylacetaldehyde, musk-indanone (4-acetyl-6-tert-butyl-1,1-dimethylindane), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-trimethyl-cyclohexyl) -3-hexano l), PT Bucinal (2-methyl-3 (para tert-butylphenyl) propionaldehyde), para-hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), polysantol (3.3 -Dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), rosaphene (2-methyl-5-phenylpentanol), sandalwood, alpha-terpinene, Tonalid / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyl tetralin), undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecyl aldehyde or undecenealdehydes, vanillin and / or Mixtures are contained in the textile treatment agent according to the invention.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentyl-methylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, o-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, Iobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butyl methyl butyrat, Pentenal, Isopentyldimethyl pyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha,γ-dimethylallylalcohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limo nenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide, Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetrahydro-3,6-dimethyl-benzofuran, Epoxγ-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol (–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, o-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nufartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder l-Menthol oder
• (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
• (II) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxγ-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Eiemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar-(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten.

enthalten.The textile treatment agent according to the invention can according to a preferred embodiment, in particular fragrances

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenalpentyl-methyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
• (c) citrusy odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, op-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6-trimethyl-pyrane 3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cimene, (E) -liminene oxide, dihydroterpinylacetate, (+) - limonene , (Epoxymethylbutyl) -methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) fruit odor such as, preferably, ethyl phenylacetate, geranyl valerate, γ-heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, iobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, Linalylacetat, Myllygeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehyl methyl pyrazine, ethyl acetate, cetronellyl butyrate, heyl acetate, nonyl acetate, butyl methyl butyrate, pentenal, isopentyl dimethyl pyrazine, p-menth-1-en-9-ol, hexadecanone, octyl acetate, γ-dodecalactone, epoxy-β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate , Cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3,5-octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α- Ocimene, butanediol, ethyl valerate, pentanol, isopiperone, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, butyl hexanoate, isopropyl butanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxaline, sesquiphenoids, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or Citronellylisobutyrate or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) a grape-like odor such as preferably ethyl decanoate and / or hexanone or (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -Limoene oxide, cis-isocitral, dimethyloctadienal, bornyl formate, bornyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, ( +) - cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl) -methylf uranium, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1 , 5,9,9-tetramethyl-12-oxabicyclododeca-4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, hydroxypentanone, (Z) -Ocimene, β-elemene, δ-cadinol, (E) -β-Ocimene, (Z) -dihydrocarvone, α-cadinol, calamenene, (Z) -piperitol , Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquipellandrene, citronellyl valerate, bornyl isovalerate, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxγ-p-menthene, geranial, (methylbutenyl) -methylfuran, dihydrocarvylacetate , β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, Piperitone, 2,3-dehydro-1,8-cineol, o-terpineol, DL-carvone and / or α-phellandrenes or
• (ff) Novel odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or l-menthol or
• (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphenoids, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate , Isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabine hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxγ-β-ionone, germacrene D, bicyclo-mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-Eiemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-seleneins, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
• (vv) mixtures of the above.

contain.

In a preferred embodiment contains the Certain textile treatment agents according to the invention Minimal values of perfume oil (fragrances), namely at least 0.00001% by weight, advantageously at least 0.0001% by weight, in a considerably advantageous manner at least 0.001% by weight, more preferably at least 0.01 wt .-%, in more advantageous Way at least 0.1 wt .-%, even more advantageously, at least 0.2 wt .-%, in a very advantageous manner at least 0.3 wt .-%, in particularly advantageously at least 0.4 wt .-%, in particular advantageously at least 0.45 wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in a very advantageous manner at least 0.55 wt .-%, in an extremely advantageous manner at least 0.6 wt .-%, most advantageously at least 0.65 Wt .-%, most advantageously at least 0.7 wt .-%, in exceptionally advantageous manner at least 0.75 wt .-%, in exceptional advantageously at least 0.8 wt.%, in extraordinary advantageously at least 0.85 wt .-%, in particular at least 0.9 wt .-% of perfume oil, based on the total Textile treatment agents.

In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, more preferably less than 6, more preferably less than 5, more preferably less than 4, even more preferably less than 3, preferably less than 2, especially no fragrances from the list Amylcinnamal, Amylcinnamylalkohol, Benzylalcohol, Benzylsalicylat, Cinnamylalkohol, Cinnamal, Citral, Cumarin, Eugenol, Geraniol, Hydroxycitronellal, Hydroxymethylpentylcyclohexencarboxaldehyde, Isoeugenol, Anisylalkohol, Benzylbenzoat, Benzylcinnamat, Citronellol, Farnesol, Hexylcinnamaldehyd, Lilial, d-Limonen, Linalool , Methyl heptane carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohe xen-1-yl) -3-buten-2-one, oak moss extract, tree moss extract.

To In another specific embodiment, the inventive Textile treatment agent completely free of perfume oil (Fragrances) be. However, it is much more preferred that fragrances are included.

Around the aesthetic impression of textile treatment agents too they can be dyed with suitable dyes become. Preferred dyes, the selection of which the expert no Difficulty, possess a high storage stability and insensitivity to the other ingredients the textile treatment agent and against light and no pronounced Substantivity to textile fibers to this not to dye.

When Foam inhibitors used in textile treatment agents Soaps, paraffins, for example, come from or silicone oils, optionally on support materials can be applied.

suitable Soil-release polymers, also called "anti-redeposition agents" are, for example, nonionic cellulose ethers such as methylcellulose and methylhydroxypropylcellulose with a proportion at methoxy groups of 15 to 30 wt .-% and hydroxypropyl groups from 1 to 15 wt .-%, each based on the nonionic cellulose ether as well as the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular Polymers of ethylene terephthalates and / or polyethylene and / or Polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives of these. Suitable derivatives include the sulfonated derivatives of phthalic and terephthalic acid polymers.

optical Brighteners (so-called "whiteners") can be added to the textile treatment agents to graying and Yellowing of the treated textile fabrics too remove. These substances are absorbed by the fiber and cause a Brightening and fake bleaching effect by invisible Ultraviolet radiation in visible longer wavelength light with the ultraviolet absorbed from sunlight Light is emitted as a faint bluish fluorescence and with the yellow of the grayed or yellowed linen pure white results. Suitable compounds are derived, for example from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (Flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, Coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, Benzoxazole, benzisoxazole and benzimidazole systems and the by Heterocycles substituted pyrene derivatives. The optical brightener are usually used in amounts between 0% and 0.3% by weight, based on the entire textile treatment agent used.

To Another preferred embodiment is the invention Textile treatment agent completely free of optical brightener.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, glue, gelatin, Salts of ether sulfonic acids of starch or Cellulose or salts of acidic sulfuric acid esters of Cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the starch products mentioned above, for example degraded starch, aldehyde starches etc. Also, polyvinylpyrrolidone is useful. However, preference is given Cellulose ethers such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures in amounts of from 0.1 to 5% by weight, based on the textile treatment agents, used.

To Another preferred embodiment is the invention Textile treatment agent completely free of grayness inhibitors.

In order to effectively suppress dye release and / or dye transfer to other fabrics during washing and / or cleaning of dyed fabrics, the fabric treatment agent may contain a dye transfer inhibitor. It is preferred that the dye transfer inhibitor is a polymer or copolymer of cyclic amines such as vinylpyrrolidone and / or vinylimidazole. Suitable color transfer inhibiting polymers include polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI), copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI), polyvinylpyridine-N-oxide, poly-N-carboxymethyl-4-vinylpyridium chloride, and mixtures thereof. Particularly preferred are polyvinylpyrrolidone (PVP), polyvinylimidazole (PVI) or copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used as a color transfer inhibitor. The polyvinylpyrrolidone (PVP) preferably have an average molecular weight of from 2,500 to 400,000, and are commercially available from ISP Chemicals as PVP K 15, PVP K 30, PVP K 60 or PVP K 90 or from BASF as Sokalan ^® HP 50 or Sokalan ^® HP 53 available. The copolymers of vinylpyrrolidone and vinylimidazole (PVP / PVI) used preferably have a molecular weight in the range from 5,000 to 100,000. A commercially available PVP / PVI copolymer is, for example, by BASF under the name Sokalan ^® HP 56th

The Amount of usable color transfer inhibitor based on the total amount of the textile treatment agent ranges z. B. preferably from 0.01 to 2% by weight, preferably from 0.05 to 1% by weight and more preferably from 0.1 to 0.5% by weight. According to another preferred embodiment is the textile treatment agent according to the invention completely free of color transfer inhibitors.

alternative but may also be enzymatic systems comprising a peroxidase and hydrogen peroxide or hydrogen peroxide in water Substance, be used as a color transfer inhibitor. The addition of a mediator compound for the peroxidase, for example, an acetosyringone, a phenol derivative or a Phenotiazines or phenoxazines, is preferred in this case, as well additionally the above-mentioned polymeric color transfer inhibitors can be used.

There textile fabrics, in particular of rayon, rayon, Cotton and its blends may tend to wrinkle, because the individual fibers against bending, bending, pressing and squeezing are sensitive to the grain direction, the textile treatment agents contain synthetic crease inhibitor. Which includes for example, synthetic products based on fatty acids, Fatty acid esters, fatty acid amides, alkyl esters, alkylolamides or fatty alcohols, which are usually reacted with ethylene oxide are, or products based on lecithin or modified Organophosphate.

to further control of microorganisms the textile treatment agents additionally antimicrobial Contain active ingredients. Here one differentiates depending upon antimicrobial Spectrum and mechanism of action between bacteriostats and bactericides, Fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and Phenolmercuriacetat, wherein the erfindungemäßen Textile treatment agents also entirely on these compounds can be waived.

The textile treatment agents according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative provides the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl K 500 ^® from Schuelke & Mayr), which can be used in a pH range up. 7 In particular, preservatives based on organic acids and / or their salts are suitable for preserving the skin-friendly textile treatment agents according to the invention.

Around undesirable, by oxygen action and other oxidative Processes caused changes to the textile treatment agents and / or to prevent the treated fabrics the textile treatment agents contain antioxidants. To this Class of connection includes, for example, substituted ones Phenols, hydroquinones, catechols and aromatic amines as well organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and Vitamin E. According to another preferred embodiment is the textile treatment agent according to the invention completely free of antioxidants.

One increased wearing comfort can from the additional Use of antistatic agents resulting in the textile treatment agents additionally be attached. Enlarge antistatic agents the surface conductivity and allow thus an improved drainage of formed charges. Outer Antistatic agents are usually substances with at least one hydrophilic Molecule ligands and give on the surfaces a more or less hygroscopic film. These mostly surface-active Antistatic agents can be in nitrogenous (amines, amines, quaternary Ammonium compounds), phosphorus (phosphoric acid esters) and Sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic subdivide. Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatics for textile fabrics or as an additive to textile treatment agents, in addition a softening effect is achieved.

to Improvement of the rewettability of the treated textile Fabrics and to facilitate ironing the treated fabrics can used in the textile treatment agents, for example, silicone derivatives become. These additionally improve the rinsing behavior the textile treatment agent by their foam-inhibiting properties. Preferred silicone derivatives are, for example polydialkyl or Alkylarylsiloxanes in which the alkyl groups one to five Have C atoms and are completely or partially fluorinated. preferred Silicones are polydimethylsiloxanes which may optionally be derivatized can and then be amino-functional or quaternized or Si-OH, Si-H and / or Si-Cl bonds. The viscosities the preferred silicones are in the range between 25 ° C 100 and 100,000 mPas, the silicones preferably in quantities between 0.2 and 5 wt .-%, based on the total fabric treatment agent can be used.

After all the textile treatment agents may also contain UV absorbers, which are applied to the treated textile fabrics and improve the light fastness of the fibers. Links, which have these desired properties are, for example the compounds which are active by radiationless deactivation and Derivatives of benzophenone with substituents in the 2- and / or 4-position. Furthermore, substituted benzotriazoles, in the 3-position phenyl-substituted Acrylates (cinnamic acid derivatives), optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural products like umbelliferone and the body's own urocanic acid suitable. According to another preferred embodiment is the textile treatment agent according to the invention but completely free of such UV absorbers.

Around the catalyzed by heavy metals decomposition of certain detergent ingredients To avoid substances can be used, the heavy metals complex. Suitable heavy metal complexing agents are, for example the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.

A preferred class of complexing agents are the phosphonates, which in preferred textile treatment agents in amounts of advantageously 0.01 to 2.5 wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1.5 wt .-% may be included. To this preferred compounds include in particular organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), Aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine-penta (methylenephosphonic acid) (DTPMP or DETPMP) as well as 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM), which are mostly in the form of their ammonium or alkali metal salts be used.

Suitable in particular the following are designated according to INCI Complexing agents, for example, in the International Cosmetic Ingredient Dictionary and Handbook are described in more detail: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic acid, dipotassium EDTA, disodium azacycloheptane diphosphonates, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactaric Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl cyclodextrin, pentapotassium triphosphates, pentasodium aminotrimethylene phosphonates, Pentasodium Ethylenediamine Tetramethylene Phosphonate, Pentasodium Pentetates, pentasodium triphosphates, pentetic acid, phytic acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetriamine Pentamethylene phosphonates, Sodium dihydroxyethyl glycinates, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphates, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonate, Sodium trimetaphosphate, TEA-EDTA, TEA-polyphosphate, tetrahydroxyethyl Ethylenediamine, Tetrahydroxypropyl Ethylenediamine, Tetrapotassium Etidronates, tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium Etidronates, Tetrasodium pyrophosphates, Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and trisodium phosphates.

preferred Chelating agents are tertiary amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both amino as well as Hydroxγ- and / or ether groups as functional Groups. Particularly preferred tertiary alkanolamines are Tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis- (2-hydroxy-propyl) -ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and possibly solvents are described in the prior art.

A particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1,1-diphos phonic acid, 1-hydroxyethane-1,1-diphosphonic acid, HEDP, acetophosphonic acid, INCI etidronic acid), including their salts. In a preferred embodiment, the textile treatment agent according to the invention accordingly contains etidronic acid and / or one or more of its salts as complexing agent.

In a particular embodiment contains the inventive Textile treatment agent a complexing agent combination of a or more tertiary amines and one or more further complexing agents, preferably one or more complexing acids or their salts, in particular triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of its salts.

The Production of the textile treatment agents according to the invention can be prepared by all techniques known to those skilled in the art made of liquid textile treatment agents.

The Preparation of a fabric softener according to the invention can therefore according to the skilled worker techniques for the production of fabric conditioners. This can be, for example by mixing the raw materials, if necessary using high shear mixing equipment, done. It is recommended Melting of the plasticizing component (s) and a subsequent Dispersing the melt in a solvent, preferably Water. The other ingredients including z. B. of the photocatalytic Materials can be added by simply adding in the softener to get integrated.

The Preparation of a liquid according to the invention Detergent as a textile treatment agent, for example, by means of conventional and known methods and methods in which, for example, the components are simple are mixed in stirred tanks, with water, possibly non-aqueous Solvents and surfactants, conveniently be submitted and the other ingredients including z. B. of added photocatalytic material in portions become. A separate heating in the production is not required, if it is desired, the temperature should be of the mixture does not exceed 80 ° C.

Examples

• #: Als photokatalytisches Material wurde ein feinpartikuläres, mit Kohlenstoff modifiziertes Titandioxid eingesetzt, mit einer Teilchengröße < 50 nm, mit TiO₂-Gehalt von ca. 97 Gew.-%.

I) esterquat: 13% by weight 2-propanol: 1.3% by weight formic acid: 0.05% by weight Photokat. Material ^# : 0.1% by weight MgCl ₂ : 0.09% by weight Water: to 100% by weight II) esterquat: 13% by weight 2-propanol: 1.3% by weight formic acid: 0.05% by weight Photokat. Material ^# 1% MgCl ₂ : 0.09% by weight polyacrylate: 0.1% by weight Water: to 100% by weight

• #: The photocatalytic material used was a fine particulate, carbon-modified titanium dioxide with a particle size <50 nm, with a TiO ₂ content of about 97% by weight.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited non-patent literature

• - DIN ISO 9277: 2003-05 [0054]
• - DIN 66132: 1975-07 [0054]

Claims (21)

Liquid textile treatment agent, characterized in that it contains photocatalytic material and cationic surfactant. Textile treatment agent according to claim 1, characterized characterized in that a cationic surfactant is a quaternary ammonium compound, in particular esterquat, preferably in amounts of> 0.1 wt .-%, advantageously 1 to 40 wt .-%, in particular 3 to 30 wt .-%, based on the total Textile treatment agents. Textile treatment agent according to claim 1 or 2, characterized characterized in that as photocatalytic material titanium dioxide is contained, in particular a modified titanium dioxide, preferably a carbon-modified titanium dioxide. Textile treatment agent according to one of the claims 1-3, characterized in that the preferably modified Titanium dioxide in amounts of 0.0001 to 30 wt .-%, preferably 0.01 to 15 wt .-%, based on the total textile treatment agent. Textile treatment agent according to one of the claims 1-4, characterized in that the carbon content of the carbon-modified titanium dioxide in the range of 0.01 to 10% by weight, preferably from 0.05 to 5.0% by weight, advantageously from 0.3 to 1.5% by weight, in particular from 0.4 to 0.8% by weight, based on the modified titanium dioxide. Textile treatment agent according to any one of claims 1-5, characterized in that the BET specific surface area of the modified titanium dioxide is preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in particular 200 to 350 m ² / g. Textile treatment agent according to one of the claims 1-6, characterized in that the particle size of the modified titanium dioxide is in the range of 2-500 nm. Textile treatment agent according to one of the claims 1-7, characterized in that a humectant preferably glycerol, dimers and trimers of glycerol, Ethylene glycol, propylene glycol, sugar alcohols, as preferably Glucitol, xylitol, mannitol, alkylpolyglucosides, fatty acid glucamides, Sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, hydrogenated glucose syrup and / or mixtures of the abovementioned, preferably in amounts of 0.01 to 10 wt .-%, advantageously 0.1 to 5 wt .-%, in particular 0.5 to 2 wt .-%, wt .-% in each case based on the total agent. Textile treatment agent according to one of the claims 1-8 containing a) photocatalytic material b) cationic c) optional fragrances, preferably in amounts> 0.01 wt .-%, advantageously From 0.05 to 10% by weight, in particular from 0.1 to 5% by weight, d) water, preferably in amounts> 50 Wt .-%, advantageously> 60 Wt .-%, in particular> 70 Wt .-% e) optionally solvent, preferably monovalent Alcohols, especially 2-propanol, advantageously in amounts from 0.05 to 5 wt .-%, in particular 0.1 to 4 wt .-%, in particular 0.3 to 3% by weight, f) optional humectants g) optional Emulsifiers, preferably nonionic surfactants, advantageously in amounts from 0 to 8% by weight, in particular from 0.1 to 5% by weight h) optional pH adjusting agent, preferably 0.01 to 5 wt .-%, in particular 0.02 up to 1% by weight i) optionally electrolytes, preferably from the Group of inorganic salts, advantageously MgCl2 or NaCl, From 0.01 to 5% by weight, in particular from 0.05 to 2% by weight, j) optional skin-care active substances, preferably in an amount of 0 to 15 wt .-%, advantageously 0.1-10 wt .-%, in particular 0.5 to 5% by weight, j) optional thickener, z. B. polyacrylate-based, preferably in amounts of 0.01 to 3 wt .-%, in particular 0.1 to 1% by weight, % By weight, based in each case on the entire textile treatment agent. Method for applying photocatalytic material on textiles by treating these textiles in a textile treatment bath containing a textile treatment agent according to one of the claims 1-9. Process for cleaning, care, equipment, Conditioning and / or conditioning of textiles by treatment these textiles in a textile treatment bath containing a textile treatment agent according to any one of claims 1-9, at and / or followed of an exposure of the textiles to light in the wavelength range from 10-1200 nm. Method according to one of the preceding claims 10 or 11 for elimination, deactivation or reduction of Microorganisms, in particular bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 10 to 12 for the prophylaxis of textiles in the form of an anticipatory Defense and inhibition of stains and stains under use of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 10 to 13 for the equipment of textiles with photocatalytic Material to facilitate the removal of colored dirt (colored spots) of textiles using light in the wavelength range from 10-1200 nm. Method according to one of the preceding claims 10 to 14 for finishing textiles with photocatalytic Material for reducing the fiber adhesion of Dirt, preferably colored spots, on textiles under use of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 10 to 15 for finishing textiles with photocatalytic Material for increasing the water solubility of Dirt, preferably colored spots, on textiles, using of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 10 to 16 for finishing textiles with photocatalytic Material for preventing the development of fetid odors on textiles, using light in the wavelength range from 10-1200 nm. Method according to one of the preceding claims 10 to 17 for the equipment of textiles with photocatalytic Material for furnishing the textiles with a self-cleaning capacity, using light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 10 to 18 to remove or reduce stains and stains on textiles, which in particular go back to: - Red to blue anthocyanin dyes, such as. B. cyanidin, z. B. from cherries or blueberries, - red betanidine from the red beds, - orange-red carotenoids such. Lycopene, beta-carotene, e.g. From tomatoes or carrots, - yellow Curcuma dyes, such as. B. curcumin, z. From curry and mustard, - brown Tannins, e.g. B. from tea, fruit, red wine - deep brown Humic acid, e.g. B. from coffee, tea, cocoa, - green Chlorophyll, z. B. green grasses, - technical Dyes made from cosmetics, inks, colored pencils - colored Metabolites and / or excretions of mold fungi or other micro flora or microbial growth or microbes, under Use of light in the wavelength range of 10-1200 nm. Method according to one of the claims 10 to 19 using an automatic washing machine, preferably an automatic washing machine with light source, wherein the textile treatment agent in particular added in the rinse cycle. Method according to one of the claims 10 to 19, characterized in that it is a manual Process is carried out in an open tub being, in particular hand washing and / or soaking, being one the tub, after the textiles to be treated with the wash liquor are penetrated, light in the wavelength range of 10-1200 nm exposes, in particular sunlight, preferably for a period> 5 Minutes.