DE102007014874A1 - Anti-mite agent - Google Patents

Abstract

The present invention is concerned with the elimination, deactivation, inhibition or reduction of (indoor) noxae with allergenic potential, in particular house dust mites and their excrements. For this purpose, a liquid agent based on a photocatalytic material and a humectant is applied. The agent is widely used and easy to apply, for example, accompanying the textile washing and drying. In particular, spray applications of the antimicrobial agent are advantageous.

Description

The The present invention relates to a liquid agent for Elimination, deactivation or reduction of (indoor) pollutants with allergenic potential. It contains photocatalytic Material and humectants. It relates to a method of disposal, Deactivation, inhibition or reduction of (indoor) pollutants with allergenic potential. It relates to the use of an inventive Treatment agent for the prophylaxis treatment of surfaces and substrates in the form of an anticipatory settlement defense and Inhibition of (interior) Noxa with allergenic potential. It concerns the use of a treatment agent according to the invention to prevent the multiplication of mites and allergens in house dust.

always increasing parts of the population suffer from allergies, especially the natural occurring allergens such as pollen or z. As house dust mites, mushrooms and their spores can cause significant stress.

Especially house dust, which generally consists of several organic and inorganic compounds is formed, including fibers, mold spores, Pollen grains, insects and insect excrement, dander and skin Mites and mite faeces, can easily lead to allergic reactions and so severely reduce the quality of life of those affected.

Just the house dust mites and their excretions represent a significant Loading is. It is z. B. assumed that the faeces of two special Dust mite species, Dermatophagoides farinae (known as Der-f) and Dermatophagoides pteronyssinus (known as der-p), immune reactions of the body that lead to particularly strong ones lead to allergic symptoms.

you assumes that in a single mattress almost to to find a home for one million house dust mites. Since a mite in her life up to 200 times its own weight can produce excrement and just this for the common house dust allergy are responsible, it is not It is surprising that many sufferers have a considerable suffering feel. For example, pillows can after some Occupy up to 400,000 mites. Because mites are just fine Live mites and mite corpses in such a live 6 weeks Cushions up to 10% of its total weight, while still a very considerable amount of excrement is added, contribute significantly to the overall weight of the pillow.

When Consequence of this significant contamination with mites and their excrements then usually occur in those affected symptoms such as asthma, hay fever, atopic dermatitis, rhinitis and conjunctivitis.

Unfortunately are the means of the state of the art, which against the mite plague can be used, limited.

Known are z. B. substances which the mites by a chemical action should destroy, for. Benzyl benzoate, pyrethroids, pirimiphosmethyl or bromopol. On the one hand, however, their effect is in expert circles controversial, on the other hand, offers the use of chemical antimic means always also dangers to the affected people, in particular with a view of children. In any case, their effect is expandable.

Also Fungicides are used against house dust mites. Nipagin, to one To name an example, suppresses the growth of mushrooms, with which the house dust mites live in symbiosis, so that the Dust mites do not reuse the dander in house dust can. However, fungicides are enough to fight the house dust mite is not out, as the food sources in house dust so diverse are that the mites also without their Mushroom symbionts can live. It will as well assumed that the fungal symbionts in the body of the Mite are also protected from the fungicide.

Known are also biological substances used to mitigate mites be such. B. neem oil. Their effect is controversial and is highly doubted in professional circles. That's what Neemöl does the mites are merely incapable of reproduction but not before the settlement of new mite colonies, which from the outside be registered regularly. Furthermore The neem oil does not work against the mite droppings.

Against this background, it was an object of the invention to provide a means which helps counteract the disturbances of human well-being caused by mites and mite faeces ken.

• a) photokatalytisches Material,
• b) Feuchthaltemittel.

This problem is solved by the subject matter of the invention, namely a liquid agent comprising:

• a) photocatalytic material,
• b) humectants.

These Means allows the elimination, deactivation, denaturation or reduction not only of mites, preferably house dust mites, Mite eggs, mite larvae, mite faeces, allergens contained therein Enzymes, but also from other (indoor) pollutants with allergenic Potential, preferably germs, arachnids, fungi, molds, Yeasts, spores, pet hair, pollen, algae, blue-green algae, lichens, parasites preferably lice, especially dress lice, their eggs, their excreta, moths, their larvae, their excrements, Ticks and other disease-transmitting microorganisms.

Under Noxa is understood here as a factor affecting the human organism harm, or at least the person in his well-being can affect. These are in particular the factors just mentioned, especially microbiological factors like viruses, bacteria, fungi etc.

The in the composition of the invention contained photocatalytic Material uses electromagnetic radiation of a suitable Wavelength range, by which the mites, Mite faeces or other undesirable factors due to photocatalytic or photochemical reaction, e.g. By oxidation or by reduction, degradable, deactivatable or reducible. The photocatalytic In particular, material is a daylight-active material, in particular a daylight active bleach, so uses the electromagnetic Radiation of daylight.

The photocatalytic activity of the photocatalytic material advantageously refers to natural or artificial Light with a wavelength in the range of 300-1200 nm, preferably between 380 and 800 nm. When the photocatalytic Material, in particular, the radiation perceivable by the human eye the visible region of the spectrum with wavelengths between 380 and 800 nm for the o. g. Purposes of mining, deactivation or reduction of mites, mite excrement or exploits other unwanted factors, then lies one preferred embodiment of the invention.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften,

besonders wirksam ist.Advantageously, at the same time a general cleaning effect is deployed, so that the agent according to the invention also in the reduction or removal of stains and stains, in particular stains which go back to:

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B, from green grasses,
• - technical dyes of cosmetics, inks, color pencils,

is particularly effective.

This is a big advantage as a general cleaning performance with a mite defense or destruction in one treatment step can be combined. This goes over the function of previous ones Antimicrobial agent significantly.

The Mite defense or destruction is also not on the immediate Limited treatment time, but stops by the deposition of the photocatalytic material on the treated Substrates also for some time. This long-term effect is over the function of previous antimicrobials significantly.

advantageously, The light passes through glass windows in closed living spaces occurs (diffused daylight) to the desired Anti-mite action (including the action against other noxious agents) and to achieve a general cleaning effect. Even light off technical light sources (artificial light), such. B. from commercial Incandescent (incandescent) bulbs, halogen lamps, fluorescent tubes, Compact fluorescent lamps (energy-saving lamps) and light sources based on light-emitting diodes, is sufficient to the desired Effect.

One further advantage of the agent according to the invention is that it is for the reduction, elimination or Neutralization contributes to fetid odors. The fetid odor can advantageously be so reduced that a previously existing odor nuisance no longer available. The emergence of fetid odors can be prevented for a longer period of time. This is also a big advantage, as overall a general Cleaning performance with a mite defense or destruction in one Treatment step can be combined and in addition Blocking or preventing fetid odors Long-term effect is provided. This goes over the function previous antimic means significantly out.

When photocatalytic material is according to a preferred embodiment of the invention contain titanium dioxide, in particular a modified one Titanium dioxide, preferably a carbon-modified titanium dioxide.

The photocatalytic material, in particular the (preferably modified) Titanium dioxide, according to a preferred embodiment the invention in the agent according to the invention in amounts of advantageously 0.0001 to 30 wt .-%, preferably 0.001 to 20 wt .-%, advantageously 0.01 to 15 wt .-%, in a further advantageous manner 0.1 to 10 wt .-%, even more advantageous 1 to 5 wt .-%, based on the total agent.

To a preferred embodiment is in the (preferably modified) titanium dioxide around with carbon modified titanium dioxide. But it can also be modified differently Titanium dioxides are used, for example, modified with nitrogen Titanium dioxide or z. B. doped with rhodium and / or platinum ions Titanium dioxide. However, it is particularly according to the invention preferably that it is non-metal modified titanium dioxide is.

The carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt. -%, in particular from 0.4 to 0.8 wt .-% are. Advantageously, the TiO ₂ content of the carbon-modified titanium dioxide z. B. over 95 wt .-%, 96 wt .-%, 97 wt .-%, 98 wt .-% or 99 wt .-%, based on the total carbon-modified titanium dioxide.

If the carbon only in a surface layer of the titanium dioxide particles is embedded, so is a preferred embodiment in front. The modified titanium dioxide may advantageously additionally Contain nitrogen.

If the specific surface of the titanium dioxide, preferably of the modified titanium dioxide, according to BET (BET advantageously determined according to DIN ISO 9277: 2003-05, preferably also simplified according to DIN 66132: 1975-07) preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in a further advantageous manner 200 to 350 m ² / g, in particular 250 to 300 m ² / g, so is also a preferred embodiment.

The carbon-modified titanium dioxide may according to a preferred embodiment, for. Example, be obtained by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m ² / g by BET, with an organic carbon compound and the mixture is thermally treated at a temperature of up to 350 ° C. The carbonaceous substance which can be used in this case can, according to a preferred embodiment, be a carbon compound which contains at least one functional group, preferably selected from OH, CHO, COOH, NHx, SHx. In particular, the carbon compound may be a compound selected from ethylene glycol, glycerol, succinic acid, pentaerythritol, carbohydrates, sugars, starch, alkyl polyglucosides, organoammonium hydroxides or mixtures thereof. It is also possible for carbon black or activated carbon to be used as the carbonaceous substance.

It may also be preferred that the carbonaceous substance, which is advantageously mixed with the titanium compound, after the thermal treatment to the modified titanium dioxide to reach a decomposition temperature of at most 400 ° C. preferably <350 ° C and particularly preferably <300 ° C having.

The Preferably used for the preparation of the modified titanium dioxide Titanium compound which according to the aforementioned preferred embodiment with an organic carbon compound intimately mixed can be an amorphous, semi-crystalline or crystalline Titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate, which in turn is a preferred embodiment equivalent.

The thermal treatment of the mixture of the titanium compound and the Carbon compound can according to a preferred embodiment advantageously in a continuously operated calcining unit, preferably a rotary kiln are performed. The modified titanium dioxide can be, in particular in the context of the previously described, preferably z. B. obtained thereby, that a titanium dioxide (eg with a particle size in the range between 2 to 600 nm or z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. 200 to 400 nm), such as commercially available in powder or mud form, takes and from this a suspension in a liquid, preferably water. To the suspension is then advantageously a carbonaceous Substance added and it is mixed. Mixing can be supported be through the use of ultrasound. The mixing process (eg Stirring) may preferably last several hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer. Based on the solids of the suspension is the amount of the carbon compound advantageously 1-40 wt .-%, accordingly, the amount the titanium compound is preferably 60-99% by weight.

After that the liquid is removed, for example by filtration, Evaporate in vacuo or decant, and the residue is preferably dried (eg, preferably at temperatures from 70-200 ° C, advantageously over several hours, for example at least 12 hours) and then calcined, for example at a temperature of at least 260 ° C, preferably z. B. at 300 ° C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours. The calcination can advantageously take place in a closed vessel.

It may be advantageous that the calcination temperature, z. B. 300 ° C, within an hour is reached (slow Heating to 300 ° C).

there is preferably a color change of the powder from white to dark brown to beige or slightly yellowish-brownish. Too long a heating leads to inactive, colorless powders. The expert can estimate this with a few routine experiments. The calcination can, for. B. advantageously done so long, until after a color change of the powder from white over dark brown another color change to beige or slightly yellowish-brownish takes place.

A maximum temperature of 350 ° C should preferably not be exceeded. In the thermal treatment there is a decomposition of the organic carbon compound on the surface of the titanium compound, so preferably a modified titanium dioxide is formed, preferably 0.005-4 Wt .-% carbon.

After the thermal treatment, the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill. The grain fineness to be achieved depends on the grain size of the starting titanium compound. The particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt. The desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as with TiO ₂ pigments, but may also be below or above.

The in the composition of the invention contained photocatalytic Material, preferably modified titanium dioxide can advantageously a particle size in the range of 2 to 600 nm, ie z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. B. 200 to 400 nm. The particle size of the photocatalytic material, preferably modified titanium dioxide, although preferably in the range of 100-500 nm, advantageously 200-400 nm lie. It may also be preferred that the particle size is very small, z. In the range 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or z. B. 5-50 nm or z. B. 8-30 nm or z. B. 10-20 nm is located. The particle size can be z. B. advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. In particular, very small particle sizes below 50 nm, below 40 nm, below 30 nm or below 20 nm be preferred.

It may be advantageous in the preparation of the modified titanium dioxide micronized titanium dioxide, that is, titanium dioxide with very small particle size, e.g. B. between 2 and 150 nm or z. b. between 5 and 100 nm. The particle size can then z. Advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The BET specific surface area for the preferably modified titanium dioxide is advantageously 50-500 m ² / g, preferably 100 to 400 m ² / g, more preferably 200 to 350 m ² / g, in particular in particular 250 to 300 m ² / g.

The Bulk density of the preferably modified titanium dioxide is preferably in the range of 100 to 800 g / l, advantageously from 200 to 600 g / l, especially from 300 to 500 g / l. For example the bulk density may be 350 g / l, 400 g / l or 500 g / l. According to a preferred embodiment, this is (preferably modified) titanium dioxide in the anatase crystal modification.

In a preferred embodiment of the invention contains the agent according to the invention as a humectant Glycerol, dimers and trimers of glycerine, ethylene glycol, propylene glycol, sugar alcohols, preferably glucitol, xylitol, mannitol, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, orthophosphoric acid, Citric acid, urea, alums, hydrates of aluminum salts, hydrogenated glucose syrup and / or mixtures of the aforementioned, preferably in amounts of 0.01 to 50 wt .-%, advantageously 0.1 to 40 Wt .-%, in a further advantageous manner 0.5-30 wt .-%, in more advantageously 1-20 wt .-%, in even more advantageous Way 1.5-10 wt .-%, in particular 2-5 wt .-%, Wt .-% based on the total agent.

We could find that by the, preferably organic, Humectant resulted in an improved effect of the agent, especially when using glycerol. The anti-mite effect could versus formulations that are not organic humectants contained, continued to improve and also lasted longer.

To a further preferred embodiment of the invention contains the agent according to the invention Nonionic surfactant, preferably from the group of alkoxylated alcohols, the alkylphenol polyglycol ether, the alkoxylated fatty acid alkyl ester, the polyhydroxy fatty acid amides, the alkyl glycosides, the Alkyl polyglucosides, the amine oxides, the fatty acid glucamides, and / or the long-chain alkyl sulfoxides, preferably in amounts of in amounts of 0.01 to 30 wt .-%, advantageously 0.1 to 20 Wt .-%, more preferably 0.5-15 wt .-%, in more advantageously, 1-10% by weight, in even more advantageous Way 1.5-5 wt .-%, in particular 2-4 wt .-%, wt .-% based on the total mean.

Also Here we could find that through the nonionic surfactant one further improved effect of the agent resulted, especially when used of amine oxide. The anti-mite effect compared to formulations, that did not contain nonionic surfactant, should be further improved.

Especially advantageous are formulations which contain a, preferably organic, Humectants and nonionic surfactant, in particular the combination from glycerine and amine oxide.

• (a) chemische Noxenminderer, wie z. B. Benzylbenzot, 2-Propanol, 6-Isopropyl-m-cresol, Diazolidinylharnstoff, anionisches Natriumdioctylsulfosuccinat, Pyrethroidpemethrin, d-Allethrin, Piperonylbutoxid, Fungizide, z. B. in Mengen > 0,001 Gew.-%, Gew.-% bezogen auf das gesamte Mittel, und/oder
• (b) biologische Noxenminderer, wie z. B. Neemöl, Teebaumöl, Farnesol, Tannin(säure), etherische Öle, Terpene, wie insbesondere Citral, Limonen, Beta-Ionon, Linalool, Geraniol, Eugenol, Myrcen oder Carvon, z. B. in Mengen > 0,001 Gew.-%, Gew.-% bezogen auf das gesamte Mittel.

The agent according to the invention may additionally comprise further ingredients. According to a further preferred embodiment of the invention, it additionally contains

• (A) chemical Noxenminderer, such as. Benzylbenzot, 2-propanol, 6-isopropyl-m-cresol, diazolidinyl urea, anionic sodium dioctyl sulfosuccinate, pyrethroid pemethrin, d-allethrin, piperonyl butoxide, fungicides, e.g. B. in amounts> 0.001 wt .-%, wt .-% based on the total agent, and / or
• (B) biological Noxenminderer, such as. As neem oil, tea tree oil, farnesol, tannin (acid), essential oils, terpenes, in particular citral, limonene, beta-ionone, linalool, geraniol, eugenol, myrcene or carvone, z. B. in amounts> 0.001 wt .-%, wt .-% based on the total agent.

As anionic sodium dioctylsulfosuccinate, one of the following formula may preferably be used:

Chemical noxa reducers, in particular benzyl benzoate, 2-propanol, 6-isopropyl-m-cresol, diazolidinyl urea, anionic sodium dioctyl sulfosuccinate, pyrethroid pemethrin, d-allethrin, piperonyl butoxide, fungicides, are preferably present in amounts of up to 25% by weight. The upper limit may also be values of 20% by weight, 15% by weight, 10% by weight, 5% by weight, 1% by weight, based on the total agent. According to another preferred embodiment of the invention are no chemical Noxenminderer, in particular Benzylbenzot, 2-propanol, 6-isopropyl-m-cresol, Diazolidinylharnstoff, anioni sodium dioctylsulfosuccinate, pyrethroid pemethrin, d-allethrin, piperonyl butoxide, fungicides.

biological Noxenminderer, in particular neem oil, tea tree oil, Tannin (acid), essential oils, terpenes, in particular Citral, limonene, beta-ionone, linalool, geraniol, eugenol, myrcene or carvone, are preferably contained in amounts up to a maximum of 25 wt .-%. The upper limit can also be set at values of 20% by weight, 15% by weight, 10 Wt .-%, 5 wt .-%, 1 wt .-% are, wt .-% based on the total Medium. According to another preferred embodiment are no biological Noxenminderer included.

To a further preferred embodiment of the invention the agent according to the invention contains fragrances, preferably in amounts of 0.01 to 10 wt .-%, wt .-% based on the entire remedy. The fragrances promote acceptance the product to the consumer and convey a feeling the cleanliness. Suitable fragrances are described below. In particular in combination with the humectant and the nonionic surfactant could a particularly long-lasting odor effect of the fragrances to be watched. This concerns both the means as such the substrates treated with it.

• a) photokatalytisches Material, vorzugsweise solches der oben genannten Art, vorzugsweise in oben genannten Mengen,
• b) Feuchthaltemittel, vorzugsweise solches der oben genannten Art, vorzugsweise in oben genannten Mengen,
• c) Niotensid, vorzugsweise solches der oben genannten Art, vorzugsweise in oben genannten Mengen,
• d) optional Kationtensid, vorzugsweise Benzalkoniumchlorid, vorzugsweise 0 bis 5 Gew.-%
• e) optional chemische und/oder biologische Noxenminderer, vorzugsweise solche der oben genannten Art, vorzugsweise in oben genannten Mengen,
• f) optional Riechstoff(e), vorzugsweise in einer Menge von 0 Gew.-% bis 5 Gew.-%, mehr bevorzugt von 0,1 Gew.-% bis 2 Gew.-%;
• g) optional weiteres oberflächenaktives Mittel, vorzugsweise in einer Menge von 0 Gew.-% bis 20 Gew.-%, insbesondere 0,1 Gew.-% bis 10 Gew.-%;
• h) optional ein antimikrobielles Mittel, z. B. Alkyldimethylbenzylammoniumsaccharinat, vorzugsweise in einer Menge von 0 Gew.-% bis 3 Gew.-%, insbesondere von 0,01 Gew.-% bis 1 Gew.-%;
• i) optional einen Korrosionshemmstoff, z. B. Natriumnitrit, Natriumbenzoat, Triethanolamin oder Ammoniumhydroxid, vorzugsweise in einer Menge von 0 Gew.-% bis 20 Gew.-%, insbesondere 0,01 Gew.-% bis 10 Gew.-%
• j) optional Lösemittel
• k) optional Wasser

stellt eine bevorzugte Ausführungsform der Erfindung dar, wobei Gew.-% jeweils bezogen ist auf das gesamte Mittel.An inventive agent containing

• a) photocatalytic material, preferably of the type mentioned above, preferably in the abovementioned amounts,
• b) humectants, preferably those of the abovementioned type, preferably in the abovementioned amounts,
• c) nonionic surfactant, preferably of the type mentioned above, preferably in the abovementioned amounts,
• d) optionally cationic surfactant, preferably benzalkonium chloride, preferably 0 to 5% by weight
• e) optionally chemical and / or biological Noxenminderer, preferably those of the above type, preferably in the above amounts,
• f) optionally fragrance (s), preferably in an amount of from 0% to 5%, more preferably from 0.1% to 2% by weight;
• g) optionally further surfactant, preferably in an amount of 0 wt .-% to 20 wt .-%, in particular 0.1 wt .-% to 10 wt .-%;
• h) optionally an antimicrobial agent, e.g. B. Alkyldimethylbenzylammoniumsaccharinat, preferably in an amount of 0 wt .-% to 3 wt .-%, in particular from 0.01 wt .-% to 1 wt .-%;
• i) optionally a corrosion inhibitor, for. As sodium nitrite, sodium benzoate, triethanolamine or ammonium hydroxide, preferably in an amount of 0 wt .-% to 20 wt .-%, in particular 0.01 wt .-% to 10 wt .-%
• j) optional solvent
• k) optional water

represents a preferred embodiment of the invention, wherein wt .-% each based on the total agent.

To a preferred embodiment is the inventive Agent provided as a spray, for example in the form of an aerosol composition, which is also a propellant gas and optionally a solvent contains.

suitable Aerosol composition may, for. B. 4 to 50 wt .-% propellant gas and solvents in amounts of 0 to 90 wt .-%. Suitable propellant is preferably selected from a C1-4 alkane, air, nitrogen or carbon dioxide. Suitable solvent is preferably selected from C 1-6 -alcohols, preferably Ethanol, and water.

To A preferred embodiment is the provision the agent according to the invention is provided in spray cans, which are equipped with valves of very different design which the removal of the agent as mist, foam, Allow paste or jet of liquid. additionally can in the hollow body steel balls, minerals, Stones small size up to max. 1 cm in diameter, Granules of plastics, be included.

To A preferred embodiment is the provision the agent according to the invention in propellant-free mechanically operated pump atomizers (pump sprays) provided in particular with optional similar embodiment with respect to the interior based on the aforementioned Spray can. For commercial use have large-volume reservoir with mechanical and / or motorized pump drive proven. In a special Embodiment becomes the dispersant mixed before applying.

To a preferred embodiment, the inventive Agent as dispersion, emulsion, microemulsion, PIT emulsion (PIT = Phase inversion temperature), suspension, aerosol, foam or paste be provided.

To a preferred embodiment, the inventive Agent also provided as cleaning, care and / or detergent be, in which case the cleaning, care and / or detergent in addition the cleaning, care and / or washing effect in addition an anti-mite function (including other noxious agents) in the sense of this Invention.

One Another object of the present invention is a method for elimination, deactivation, inhibition or reduction of (indoor) noxae with allergenic potential, such as preferably germs, mites, preferably Dust mites, mite eggs, mite larvae, mite faeces, fungi, molds, Spores, pet hair, pollen, algae, parasites such as preferably lice, Clothing lice, their eggs, moths, their larvae, ticks, disease transmitting microorganisms, including application of a composition according to the invention (hereinafter "treatment agent") called) on a substrate which requires this, preferably by spraying, at and / or followed by exposure of the substrate to light having a wavelength in the range of 300-1200 nm, preferably 400-800 nm.

For a preferred development of the effectiveness of the treatment agent is the presence of preferably oxygen and / or water (eg from air, ie air humidity) required. That's enough z. As the present in water, dissolved oxygen or the dissolved oxygen in the moisture or atmospheric oxygen. The exposure can also be done in a treatment bath.

In a further preferred embodiment of the invention The process becomes the substrate treated with a treating agent during and / or after completion of light exposure subjected to a mechanical treatment, as preferably a knocking, suction and / or brushing.

Prefers is also the run of a double cycle, i. H. Treatment of the Target substrate with the treatment agent, mechanical treatment like knocking or vacuuming and then repeating the processes. This leads to a very good renovation already with mites contaminated substrates.

To a further preferred embodiment of the invention these are the ones to be treated according to the invention Substrates to textile substrates, preferably textile clothing items or textile utensils such as bedding, pillows, Duvets, covers, upholstery, rugs, curtains, Sleeping bags, car interior textiles, cuddly toys.

In a further preferred embodiment of the invention First, a primary treatment of the treated Substrates with the agent according to the invention according to a Process according to the invention, this application repeated twice at intervals of 6-8 weeks. After that preferably one treatment is done every 6 months. Such Treatment sequence leads to a very good reduction of mite load and allergen exposure over long periods of time.

One Another advantage of the treatment agent according to the invention and method lies in their substrate friendliness. That's how it usually is for the removal of house dust mites and their allergens z. B. at the textile washing washing temperatures of over 60 ° C. required. Many textiles tolerate these high temperatures but not. They shrink z. B. or dissolve. Other Objects, we z. B. feather pillow can not to be washed in the washing machine at all. The invention Treatment agent, however, allows all textiles, especially all temperature-sensitive textiles such as garments, pillows, Duvets, blankets, cuddly toys, sleeping bags and upholstery, that can only be treated cold or lukewarm or washed off, to mitigate mites and allergens, for example by mere spraying at or followed by light exposure.

The The method according to the invention thus offers the advantages a good color and textile protection, a general substrate protection. It also removes stains and stains caused by the treated substrates, which is a great Advantage over conventional antimicrobial agents is.

According to a preferred embodiment of the invention, the application of the treatment agent is carried out by soaking, dipping, soaking, brushing, gluing or in particular by spraying. To Ver Spraying can be used on all Versprühlösungen that holds the state of the art ready.

The Spraying allows easy treatment such substrates, which are z. B. bad or not at all Washing machine, namely pillows, duvets, Mattresses, upholstery etc.

In a further preferred embodiment of the invention the application of the treatment agent takes place in the context of textile washing, preferably in an automatic washing machine, in particular at T ≤ 60 ° C, advantageously in an automatic Washing machine with light source.

at In this washing process, the photocatalytic material pulls on the to be treated substrate and can develop its effect hereafter.

In Another preferred embodiment is the treatment agent applied as a detergent in an automatic washing machine. In this way, a particularly effective deposition of the photocatalytic Materials on the laundry reached.

If the application of the treatment agent in the context of textile drying takes place, preferably in an automatic tumble dryer, in particular with a light source, this is another preferred embodiment in front.

If First, the wet, to be dried laundry in the automatic Tumble dryer, in particular with light source, is placed, then spray the agent into the tumble dryer chamber and finally the drying process is started, such is another preferred embodiment. By the spraying achieves a very good distribution of the Treatment agent on the textiles. The high temperatures at Drying also acts against the mites.

In In another preferred embodiment, the wet, to be dried laundry first hung on a leash, especially outdoors and then sprayed with the agent. This also leads to good results in mite defense and destruction.

The Use of a treatment agent according to the invention for elimination, deactivation, inhibition or reduction of (indoor) noxae, preferably with allergenic potential, such as preferably germs, mites, preferably house dust mites, mite eggs, mite larvae, mite faeces, Mushrooms, molds, spores, pet hair, pollen, algae, parasites preferably lice, clothes lice, their eggs, Moths, their larvae, ticks, disease-transmitting micro-organisms, using light with a wavelength in the range from 300-1200 nm, is another object of this invention.

The Use of a treatment agent according to the invention for the prophylaxis treatment of surfaces and substrates in the form of an anticipatory settlement defense and inhibition of (Interior) Noxen, preferably with allergenic potential, as preferably Germs, mites, preferably house dust mites, mite eggs, mite larvae, Mite feces, fungi, molds, spores, pet dander, pollen, algae, Parasites such as preferably lice, lice, their eggs, moths, their larvae, ticks, disease-transmitting Microorganisms, using light of one wavelength in the range of 300-1200 nm, is another object this invention.

The Use of a treatment agent according to the invention to prevent the multiplication of mites in house dust of light having a wavelength in the range of 300-1200 nm, is another object of this invention.

The use of the combination of photocatalytic material and humectant to enhance the effectiveness of chemical and / or biological Noxenminderer using light having a wavelength in the range of 300-1200 nm is a further object of this invention According to a preferred embodiment, the inventive treatment agent at least one further, preferably several ingredients, in particular washing, care and / or cleaning active ingredients, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, Acidifizierungsmittel, alkalizing, anti-wrinkle compounds, antibacterial agents, antioxidants, Anti Redepositionsmittel , Antistatics, builders, bleaches, bleach activators, bleach stabilizers, bleach catalysts, ironing aids, cobuilders, dispersants, anti-shrinkage agents, electrolytes, enzymes, colorants, colorants l, dyes, color transfer inhibitors, fluorescers, fungici de, germicides, odor-complexing substances, auxiliaries, hydrotropes, rinse aids, complexing agents, preservatives, corrosion inhibitors, optical brighteners, perfume carriers, pearlescers, pH stabilizers, repellents and impregnating agents, polymers, fragrance (s) (perfume (oil)), swelling agents and slip agents, foam inhibitors, phyllosilicates, soil repellents, silver protectants, silicone oils, UV protectants, viscosity regulators, thickeners, discoloration inhibitors, grayness inhibitors, vitamins and / or fabric softeners.

In the following, preferred ingredients of the compositions of the invention, which may optionally be included, are described in more detail. Anionic surfactants are preferably contained in the agents according to the invention. As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates), z. As the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids suitable.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters As well as their mixtures to understand, as in the production through Esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation of saturated fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, Lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are preferably used only in relatively small amounts, for example in amounts of from 1 to 5% by weight, in detergents in particular. The agents according to the invention may preferably be free of sulfuric acid monoester.

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by the reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: R ¹⁰ O- (CH ₂ -CH ₂ -O) _p -CH ₂ -COOH with R ¹⁰ = C ₁ -C ₁₈ and p = 0.1 to 20. Ethercarboxylic acids are water hardness insensitive and have excellent surfactant properties on.

suitable anionic surfactants are, for example, the partial esters of Di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the EO adducts of maleic anhydride at least monounsaturated carboxylic acids having a chain length from 10 to 25 carbon atoms with an acid number of 10 to 140.

In addition to an unbranched or branched, saturated or unsaturated, aliphatic or aromatic, acyclic or cyclic, optionally alkoxylated alkyl radical, preferred anionic surfactants have 4 to 28, preferably 6 to 20, in particular 8 to 18, particularly preferably 10 to 16, most preferably 12 to 14 carbon atoms, two or more anionic, in particular two, acid groups, preferably carboxylate, sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group on. Examples of these compounds are the alpha-sulfofatty acid salts, the acylglutamates, the monoglyceride disulfates and the alkyl ethers of the glycerol disulfate, and in particular the monove described below Restored sulfosuccinates.

Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,

at the salts are preferably alkali metal salts, ammonium salts and mono-, di- or Trialkanolammoniumsalze, for example, mono-, Di- or triethanolammonium salts, in particular to lithium, sodium, Potassium or ammonium salts, particularly preferably sodium or ammonium salts, extremely preferably sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurylpolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic preferably with a primary or secondary amine containing a or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22, preferably 6 to 20, especially 8 to 18, particularly preferably 10 to 16, extremely preferably 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 sulfosuccinates, disodium C12-15 pareth sulfosuccinates, disodium deceth-5 sulfosuccinates, disodium deceth-6 sulfosuccinates, disodium dihydroxyethyl sulfosuccinyl undecylenates, disodium dimethi Disodium Isostearamido MEA Sulfosuccinate, Disodium Isostearamido MIPA Sulfosuccinate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA Sulfosuccinate, Disodium Oleamido MIPA- Sulfosuccinates, disodium oleamido PEG-2 sulfosuccinates, disodium oleth-3 sulfosuccinates, disodium oleyl sulfosuccinates, disodium palmitamido PEG-2 sulfosuccinates, disodium palmitoleeamido PEG-2 sulfosuccinates, disodium PEG-4 cocamido MIPA sulfosuccinates, disodium PEG-5 lauryl citrate sulfosuccinates, disodium PEG-8 Palm Gl Disodium Stearyl Sulfosuccinate, Disodium Stearyl Sulfosuccinate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccinate, Disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido, Disodium Stearamido MEA Sulfosuccinate, Disodium Stearamido MEA Sulfosuccinate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 sulfosuccinates, di-TEA-Ole-amido PEG-2 Sulfosuccinates, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Another suitable class of compounds are anionic surfactant-cation complexes, the cation itself initially having surfactant properties. Examples are transesterification products of LAS acid with amines, amine derivatives containing a C chain with> 2 C atoms, preferably C ₁₂ -C ₁₆ . These can be z. B. be oxidized on nitrogen, ie, for example, transesterification of LAS acid with amine oxide C _12-14 .

Of the Content of the inventive agent of anionic Surfactants, preferably on said anionic surfactants, can vary widely. Thus, an inventive Contain very large amounts of anionic surfactant, preferably up to an order of 40, 50 or 60% by weight or more. Likewise, an inventive Means contain only very small amounts of anionic surfactant, for example less than 15 or 10 wt% or less than 5 wt% or 2 wt% or even less. Advantageously, in the inventive However, anionic surfactants in amounts of 0.1 to 40 wt .-% and especially 5 to 30 wt .-%, with concentrations above of 10% by weight and even above 15% by weight of particular preference can find. According to a preferred embodiment the agent according to the invention contains anionic Surfactants, preferably in amounts of at least 0.01 wt .-%, based on the entire remedy. According to another preferred embodiment the agent according to the invention can be completely free from Be anionic surfactant.

additionally to the said anionic surfactants, but also independently Of these, in the invention Means soaps are included. Particularly suitable are saturated Fatty acid soaps, such as the salts of lauric acid, Myristic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural fatty acids, eg. Coconut, palm kernel or tallow fatty acids, derived soap mixtures. The salary the amount of soaps is independent of other anionic surfactants, preferably not more than 3 wt .-% and in particular 0.5 to 2.5 wt .-%, based on the total agent. In another preferred embodiment this is inventive agent of soap completely free.

advantageously, can nonionic surfactants in the inventive Be included means. For example, their salary can be up to 2 or 3 or 5 wt .-% amount. It can also larger Amounts of nonionic surfactant may be included, for example bis to 5% by weight or 10% by weight or 15% by weight or 20% by weight, 30% by weight, 40% by weight, 50% by weight or even more if it is is appropriate. Meaningful lower limits can at values of 0.01, 0.1, 1, 2, 3 or 4 wt .-%, based wt .-% on the entire remedy.

Preferably however, the nonionic surfactants are larger in size Quantities, ie up to 50 wt .-%, advantageously from 0.1 to 40 Wt .-%, particularly preferably from 0.5 to 30 and in particular of 2 to 25 wt .-%, each based on the total agent included. In a preferred embodiment, this includes agents according to the invention nonionic surfactants, preferably in amounts of at least 0.1 wt .-%, based on the entire means. According to another preferred embodiment the agent according to the invention can also be completely free to be from Niotensid.

advantageously, may be any nonionic known in the art Surfactants in the inventive compositions be. Preferred nonionic surfactants are presented below.

The agents according to the invention may preferably also contain cationic surfactants. Suitable cationic surfactants are for example surface-active quaternary compounds, especially with an ammonium, sulfonium, phosphonium, iodonium or arsonium group. Through the use of quaternary Surface-active compounds with antimicrobial activity the agent can be designed with an antimicrobial effect or its optionally due to other ingredients already existing antimicrobial effect can be improved.

Particularly preferred cationic surfactants are the quaternary, z. T. antimicrobial ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _{1 -22-} alkyl radicals C _7-28 -Aralkyl radicals or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in the pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For an op maximum antimicrobial activity preferably has at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are by reaction of tertiary amines with alkylating agents, such as Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, even the quaternization of tertiary Amines with two long residues and one methyl group can help with of methyl chloride under mild conditions become. Amines containing three long alkyl radicals or hydroxy-substituted alkyl radicals are poorly reactive and are preferred with dimethyl sulfate quaternized.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as N-decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, 1-cetylpyridiniumchloride (CAS No. 123-03 -5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities of the antimicrobial cationic surfactants with in the inventive Agents possibly contained anionic surfactants are possible aniontensidverträgliches and / or possibly as possible little cationic surfactant used or in a particular embodiment The invention dispenses entirely with cationic surfactants.

Further below will be particularly related to conditioning agents and plasticizers further cationic surfactants, as well as quaternary Ammonium compounds described. These can also be preferred be included in the inventive compositions.

The agents according to the invention can or more cationic surfactants, advantageously in Amounts, based on the total composition, from 0 to 30 wt .-%, even more preferably greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5 wt .-%. Suitable minimum values can also at 0.5, 1, 2 or 3 wt .-% are. After a preferred Embodiment contains the inventive Medium cationic surfactants, preferably in amounts of at least 0.1% by weight, based on the total agent. After another preferred Embodiment, the inventive Agent be completely free of cationic surfactant.

As well the agents according to the invention, also contain amphoteric surfactants. These will be below in particular even closer in the context of conditioning agents and plasticisers described.

The agents according to the invention can be one or contain several amphoteric surfactants, advantageously in amounts, based on the total composition, from 0 to 30 wt .-%, still more preferably greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5 wt .-%. After another preferred embodiment, the inventive Agent be completely free of amphoteric surfactants.

To a particular embodiment, the inventive Means contain very little total surfactant, z. B. can the total amount of surfactant below 20% by weight, 15% by weight, 10% by weight or 5% by weight, advantageously even below 3 wt .-% or below 1 wt .-%, in particular even below 0.5 wt .-% or less than 0.1 wt .-%, wt .-% in each case on the entire remedy. Preferably, the total surfactant content but at least 0.01 wt .-%, 0.1 wt .-% or 1 wt .-%, based on the entire remedy.

Further Ingredients of the compositions according to the invention can if appropriate, be inorganic and organic builders.

Suitable examples are soda, citrates, SKS-6, citric acid, MGDA (methyl glycine diacetic acid), triphosphates, phosphonates, aliphatic dicarboxylic acids (eg adipic, glutaric, succinic acid), Trilon A, Trilon B. After another preferred embodiment, the agent according to the invention free of Buil to be his.

Further Suitable builders are polyacetals, which by reaction of dialdehydes with polyolcarboxylic acids, which are 5 to 7 C atoms and at least 3 hydroxyl groups can be obtained. Preferred polyacetals are selected from dialdehydes such as glyoxal, glutaraldehyde, Terephthalaldehyde and mixtures thereof and from Polyolcarbonsäuren such as gluconic acid and / or glucoheptonic acid.

Further suitable organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes. Preferably, it is hydrolysis products having average molecular weights in the range of 400 to 500,000 g / mol. In this case, a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30 is preferred, DE being a common measure of the reducing action of a polysaccharide compared to dextrose, which has a DE of 100 , is. Usable are both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 and so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30,000 g / mol. A preferred dextrin is in the British Patent Application 94 19 091 described. The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.

Also Oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate other suitable cobuilders. This is ethylenediamine-N, N'-disuccinate (EDDS) preferably used in the form of its sodium or magnesium salts. Also preferred in this context are glycerol disuccinates and glycerol trisuccinates. Suitable quantities can for example at 0.1 to 15% by weight, based on the total agent, lie.

Further useful organic cobuilders are, for example, acetylated Hydroxycarboxylic acids or their salts, which optionally may also be present in Lactonform and which at least 4 carbon atoms and at least one hydroxy group and maximum contain two acid groups.

A another substance class with cobuilder properties are the phosphonates These are in particular hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkane phosphonates is 1-hydroxyethane-1,1-diphosphonate (HEDP) of particular importance as a co-builder. It is preferably used as the sodium salt, wherein the disodium salt neutral and the tetrasodium salt is alkaline (pH 9). As aminoalkanephosphonates preferably ethylenediamine tetramethylenephosphonate (EDTMP), Diethylenetriaminepentamethylenephosphonate (DTPMP) and their higher Homologous in question. They are preferably in the form of neutral reacting Sodium salts, e.g. B. as hexasodium salt of EDTMP or hepta- and octa-sodium salt of DTPMP. As a builder will be there from the class of phosphonates preferred HEDP used. The aminoalkane phosphonates also have a pronounced Schwermetallbindeabmögen. Accordingly, it may, especially if the means also bleach be preferred, Aminoalkanphosphonate, in particular DTPMP, to use or mixtures of the phosphonates mentioned.

In Cases in which a phosphate content is tolerated can Phosphates are also used, in particular pentasodium triphosphate, optionally also pyrophosphates and orthophosphates, the first Line act as a precipitant for calcium salts.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as a dihydrate (density 1.91 gcm ^-3 , melting point 60 °) and as a monohydrate (density 2.04 gcm ^-3 ). Both salts are white powders which are very soluble in water and which lose their water of crystallization when heated and at 200 ° C into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below). NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (primary or monobasic potassium phosphate, potassium biphosphate, KDP), KH ₂ PO ₄ , is a white salt of density 2.33 gcm ^-3 a melting point 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _x ] and is readily soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 mol. (Density 2.066 gcm ^-3 , water loss at 95 °), 7 mol (density 1.68 gcm ^-3 , melting point 48 ° with loss of 5 H ₂ O) and 12 mol. Water (density 1.52 gcm ^-3 , melting point 35 ° with the loss of 5 H ₂ O), becomes anhydrous at 100 ° C. and on more intense heating passes into the diphosphate Na ₄ P ₂ O ₇ . Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Di-potassium hydrogen phosphate (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals which have a density of 1.62 gcm ^-3 as dodecahydrate and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 gcm ^-3 . Trisodium phosphate is readily soluble in water under alkaline reaction and is prepared by evaporation of a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH. Tripotassium phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 gcm ^-3 , has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It arises z. Example, when heating Thomasschlacke with coal and potassium sulfate. Despite the higher price, the more soluble, therefore highly effective, potassium phosphates are often preferred over the corresponding sodium compounds in the detergent industry.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 gcm ^-3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1.815-1.836 gcm ^-3 , melting point 94 ° with loss of water) , Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed on heating of disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dewatering the solution by spraying. The decahydrate complexes heavy metal salts and hardness agents and therefore reduces the hardness of the water. Potassium diphosphate (potassium pyrophosphate), K ₄ P ₂ O ₇ , exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 gcm ^-3 , which is soluble in water, the pH being 1% Solution at 25 ° 10.4.

Condensation of the NaH ₂ PO ₄ or the KH ₂ PO ₄ results in high-molecular-weight sodium and potassium phosphates, in which one can distinguish cyclic representatives, the sodium or potassium metaphosphates, and the chain-like types, the sodium or potassium polyphosphates. In particular, for the latter are a variety of names in use: hot or cold phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ O ₁₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphosphat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example, in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH: (NaPO ₃ ) ₃ + 2KOH → Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are used according to the invention exactly as sodium tripolyphosphate, potassium tripolyphosphate or mixtures of these two; Mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate are also suitable can be used accordingly.

In a preferred embodiment of the invention as inorganic builder substances, in particular carbonates and silicates used.

Particularly noteworthy here are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2x + 1} .yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Such compounds are commercially available, for example, under the name ^SKS® (from Clariant). Thus, it is mainly SKS-6 ^® is a δ-sodium having the formula Na ₂ Si ₂ O ₅ · yH ₂ O, SKS-7 ^® primarily the β-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) gives kanemite NaHSi ₂ O ₅ .yH ₂ O, commercially available under the names SKS- ^9® or SKS- ^10® (from Clariant) from the δ-sodium disilicate. It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have altered crystal morphologies in comparison with the δ-sodium disilicate, dissolve more rapidly and show increased calcium binding capacity in comparison with δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula xNa ₂ O.ySiO ₂ .zP ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z is a number from 1.75 to 1200 and the ratio y to z is equivalent to a number from 4 to 2800 known. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. Also compounds from the crystalline layer silicates with other ingredients can be used. In particular compounds with cellulose derivatives, which have advantages in the disintegrating effect, as well as compounds with polycarboxylates, eg. As citric acid, or polymeric polycarboxylates, eg. As copolymers of acrylic acid, to name.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which likewise have a dissolution delay compared with the conventional water glasses, are known.

Especially preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous Silicates. The content of (X-ray) amorphous silicates can preferably 1 to 10 wt .-%, which is a preferred embodiment corresponds to the invention.

Especially preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, wherein sodium and potassium carbonate and especially sodium carbonate to the preferred embodiments counting. The content of the alkali metal carbonates may be in one vary very broadly and can preferably 1 to 10 wt .-% be. According to another preferred embodiment the agent according to the invention free of alkali metal carbonates be. According to another preferred embodiment can the agent according to the invention is free from all builder substances, in particular of all the abovementioned builder substances and all be in the following builders.

Useful organic builders are, for example, usable in the form of their alkali and especially sodium polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for environmental reasons, as well as Mixtures of these. Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used. The acids be In addition to their builder effect typically also the property of an acidifying component and thus also serve to set a lower and milder pH of inventive compositions, eg. B. those with washing, care and / or cleaning effect. In particular, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

The agents according to the invention can also Contain polymers. Suitable polymers include in particular polyacrylates, which preferably has a molecular weight of 2,000 to 20,000 g / mol exhibit. Because of their superior solubility In turn, from this group, the short-chain polyacrylates, the molecular weights of 2000 to 10,000 g / mol, and particularly preferred from 3000 to 5000 g / mol.

Suitable are furthermore copolymeric polycarboxylates, especially those of Acrylic acid with methacrylic acid and acrylic acid or methacrylic acid with maleic acid. As special suitable copolymers of acrylic acid with maleic acid proven, the 50 to 90 wt .-% acrylic acid and 50 to 10 Wt .-% maleic acid. Your molecular weight, based on free acids, is generally 2000 to 70000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

Of the Content of the organic builder substances can be in one vary wide frame. Levels of from 0.1 to 20 are preferred Wt .-%, in particular contents of not more than 10 wt .-% special Find favor. According to another preferred embodiment the agent according to the invention can be free of organic Be builders.

It It should be noted at this point that the statement wt .-%, Unless otherwise indicated, each to the entire mean refers.

The agents according to the invention can components from the classes of the grayness inhibitors (dirt carrier) and / or the fabric softening aids (for example cationic surfactants) which is preferred.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, the water-soluble Salts of polymeric carboxylic acids, glue, gelatin, salts of Ethercarboxylic acids or ether sulfonic acids of Starch or cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the starch products mentioned above, z. B. degraded starch, aldehyde starches, etc. Also Polyvinylpyrrolidone is useful. However, preference is given to cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, Methylcarboxy-methylcellulose and mixtures thereof, and polyvinylpyrrolidone for example, in amounts of preferably 0.1 to 5 wt .-%, based on the means used.

suitable Plasticizers, which are described in more detail below are, for example, swellable phyllosilicates of the type of montmorillonite, for example bentonite, as well as cationic surfactants.

Of the Content of water on average is preferably 0 to less as 100% by weight and in particular 0.5 to 95% by weight, values of at most 5% by weight, in particular in the case of non-aqueous find special preference for liquid funds.

According to a preferred embodiment, water z. In an amount of more than 20% by weight, advantageously more than 30% by weight, more preferably more than 40% by weight, even more preferably more than 50% by weight, in particular from 60 to 99% by weight, particularly preferably from 70 to 98% by weight and most preferably 80 to 95 wt .-%, based on the total agent.

The The upper limit of water may also be 80% by weight, 70% by weight, 60% by weight, 50 wt%, 40 wt%, 30 wt%, 20 wt%, or 10 wt% wt% relative to the entire remedy.

The Lower limit of water can z. B. also at 80 wt .-%, 70 wt .-%, 60% by weight, 50% by weight, 40% by weight, 30% by weight, 20% by weight or 10% by weight relative to the entire remedy.

The mentioned upper and lower limits can of course be meaningfully combined, for. B. to water contents of 60-80 Wt .-% or 10-30 wt .-% etc.

in the following non-ionic surfactants are described in more detail, which may preferably be included.

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture may contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of native origin having 12 to 18 carbon atoms, for. From coconut, palm, palm kernel, tallow fat or oleyl alcohol, and on average from 2 to 8 EO per mole of alcohol. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alcohols with 3 EO to 6 EO, C ₉ -C ₁₁ -alcohols with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alcohols with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₅ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.

preferred Alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic Surfactants can also be used fatty alcohols with more than 12 EO become. Examples include (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

Preferred nonionic surfactants are one or more ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation of up to 30, preferably ethoxylated C _10-18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12-14 fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10; preferably x is 1.1 to 1.4. also suitable are N-methylglucamides with C ₁₂ / C ₁₄ .

Another class of preferred nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters, particularly preferred are C ₁₂ -C ₁₈ fatty acid methyl esters having an average of 3 to 15 EO, in particular with an average of 5 to 12 EO, z. B. also used.

Also Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide may be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated Fatty alcohols, especially not more than half of them.

Also suitable are alkoxylated amines, advantageously ethoxylated and / or propoxylated, ins particular primary and secondary amines having preferably 1 to 18 C atoms per alkyl chain and on average 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of amine.

The low-foaming nonionic surfactants may be preferred. Particularly preferred are the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols. The person skilled in the art generally means, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably in the context of the present invention, the longer-chain alcohols C ₁₀ to C ₁₈ , preferably C ₁₂ to C ₁₆ , such as C ₁₁ -, C ₁₂ - , C ₁₃ , C ₁₄ , C ₁₅ , C ₁₆ , C ₁₇ and C ₁₈ alcohols. As a rule, n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, form a complex mixture of addition products of different degrees of ethoxylation. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Also, if desired, by a final etherification with short-chain alkyl groups, such as preferably the butyl group, the substance class of "closed" alcohol ethoxylates reach, which can also be used in the context of the invention. Very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates.

Advantageously, the compositions according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. As additives which are solid at room temperature, paraffin waxes, silicic acids, which may also be hydrophobized in a known manner, and in particular bismuth derivatives which are derived from C _2-7 diamines and C _12-22 carboxylic acids, are suitable.

For use, preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) and / or the solidification point. This is the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful in the invention, their proportion in the paraffin oil mixture should therefore be as low as possible and is preferably below the limit significantly measurable by conventional analytical methods, for example gas chromatography. Preferably paraffins are used which solidify in the range of 20 ° C to 70 ° C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin oils. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ° C. is as high as possible, without already being 100% at this temperature. Preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It is also important to ensure that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. According to Paraffins which can be obtained for example under the trade names Luna Flex ^® from Fuller and Deawax ^® DEA Mineralöl AG.

The Paraffin oils may be solid bisamides at room temperature, which vary from saturated fatty acids with 12 to 22, preferably 14 to 18 carbon atoms and of alkylenediamines with 2 to 7 carbon atoms derived. Suitable fatty acids are lauric, myristic, stearic, arachinic and behenic acid as well as their mixtures, as they are from natural fats respectively hardened oils, such as tallow or hydrogenated palm oil, are available. Suitable diamines are, for example Ethylenediamine 1,3-propylenediamine, tetamethylenediamine, pentamethylenediamine, Hexamethylenediamine, p-phenylenediamine and toluenediamine. preferred Diamines are ethylenediamine and hexamethylenediamine. Especially preferred Bisamides are bis-myristoyl-ethylenediamine, bispalmitoyl-ethylenediamine, Bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine. Also suitable are hexamethylenediamine ethoxylates.

The agents according to the invention may preferably with other ingredients, especially washing, care, and / or Detergents or cosmetic ingredients. From the broad state of the art is well known which Ingredients of detergents, care or cleaning agents and which Raw materials can usually still be added. These are, for example, substances such as bleach, Bleach activators and / or bleach catalysts, enzymes, temperature-sensitive Dyes, etc., which of course also directly on average may be included.

Farther can the agents of the invention in Form of a conditioning agent and the demgemäßen Components included. Under the term conditioning is in the According to this invention preferably the avivating treatment of Textiles, fabrics and fabrics. By conditioning the textiles are given positive qualities, such as an improved softness, an increased gloss and color brilliance, an improved scent impression, reduction of felting, ironing relief by reducing the sliding properties, reducing the creasing behavior and static charge, and color transfer inhibition in dyed textiles.

Compositions according to the invention, in particular conditioning agents, may contain, for example, polymerizable betaine esters of the general formula (I): [R ^a -X- (CH ₂ ) _k -NR ^b R ^c - (CR ^d R ^e ) _l - (C = O) -O- (R ^f -O) _m -R ^g ] ⁽⁺⁾ (I) in which
R ^{a is} an ethylenically unsaturated radical containing at least one carbonyl function, such as acryloyl, methacryloyl, maleoyl or itaconoyl;
X is an oxygen atom, -N (CH ₃ ) - or -NH-;
R ^b , R ^{c are} independently optionally branched alkyl radicals having 1 to 4 carbon atoms, which may contain heteroatom substituents, in particular O, S, N, P;
the rest
R ^d , R ^{e are} independently selected from hydrogen (H), optionally branched alkyl radicals having 1 to 4 C atoms, optionally substituted aryl or benzyl radicals and -CH ₂ COOH, -CH ₂ COOR, -CH ₂ CH ₂ COOH, -CH ₂ CH ₂ COOR; wherein R optionally multiple bonds containing, linear or branched and / or cyclic and / or substituted and / or halogen atoms and / or containing heteroatoms and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms or one exclusively from ethylene or propylene or Butylene or styrene oxide-based polyether;
R ^{f is} an optionally multiple bonds containing branched and / or substituted and / or cyclic hydrocarbon radical having 1 to 10, preferably 2 or 3 carbon atoms, or a styrene radical or is composed solely of ethylene or propylene or butylene or styrene radicals, or a said moiety containing block copolymer or random copolymer is;
R ^{g is} an optionally branched, optionally double bonds, optionally cyclic hydrocarbon radical having 1 to 22 carbon atoms, wherein R ^{9 is} an optionally branched, optionally double bonds contained hydrocarbon radical when m = 0 and R ⁹ can be H, if m> 0 is;
k, l are independently 1 to 4, where k is preferably 2 or 3 and 1 is preferably 1; and
m has a value between 0 to 100, preferably 0 to 40;
A ^{(-) is} an anion; and or
Homopolymers prepared from polymerizable betaine esters of general formula (I) and copolymers prepared from polymerizable betaine esters of general formula (I) and suitable comonomers of general formula (II). R ^W R ^Z C = CR ^x R ^y (II) in which
R ^X and R ^{y are} H,
R ^{W is} H or CH ₃ and
R ^{Z is} a radical containing at least one carbonyl group, such as -C (O) OR, -C (O) NR'R ", where R, R 'and R" are H or optionally multiple bonds, linear or branched and / or cyclic and / or substituted and / or halogen atoms containing and / or heteroatoms containing and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms; or in those
R ^W and R ^x H are,
R ^Y and R ^{Z are} carbonyl group-containing radicals such as -C (O) OR, -C (O) NR'R ", where R 'and R" are H or optionally multiple, linear or branched and / or cyclic aliphatic or aromatic and / or substituted and / or halogen atoms and / or heteroatoms containing hydrocarbon radicals having 1 to 18 carbon atoms;
or in those
R ^W , R ^X and R ^{Y are} H and
R ^{Z is} an aromatic or heteroaromatic radical optionally containing halogen atom and / or heteroatom-substituted, linear and / or branched alkyl substituents;
or in those
R ^W , R ^X and R ^{Y are} H and
R ^{Z is} - (CH ₂ ) _a -OR ^III , wherein R ^{III is} H or an optionally carbonyl-containing alkyl radical having 1 to 22 C atoms or a polyether exclusively composed of ethylene or propylene or butylene or styrene oxide, which is a represents the said radicals containing blockwise or random copolymer and a is 0 or 1.

To a preferred embodiment, the inventive Mean no polymerizable betaine esters.

invention Means such. As conditioning, can advantageously a pH of less than or equal to 8, preferably less than 7, more preferably between 1 and 6 and especially between 2 and 5. This corresponds to a preferred embodiment. Also, pH values ≤ 10 or ≤ 9 are possible.

It are also alkaline agents possible, for. With a pH ≥ 9 or ≥ 10, or even ≥ 11 or ≥ 12. These but are less preferred.

The Conditioning agents according to the invention can in a preferred embodiment additionally surfactants contain. The additional use of surfactants causes an enhancement of the conditioning properties and also contributes to improved storage stability and dispersibility or emulsifiability of the individual Conditioner components at.

to Improvement of the softness and the reviving properties the agents according to the invention can be plasticizer components exhibit. Examples of such compounds are quaternary Ammonium compounds, cationic polymers and emulsifiers, as they are used in hair care products and also in agents for Textilavivage become. These softening compounds, which are also hereafter can be described in more detail, in all inventive Means, but especially in the conditioning or in funds with the intended softening effect.

wobei in (III) R und R¹ für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R² für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R³ entweder gleich R, R¹ oder R² ist oder für einen aromatischen Rest steht. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (III) sind Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),

wherein in (III) R and R ^{1 is} an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{2 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ^{3 is} either R, R ¹ or R ² or is a aromatic residue stands. X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (III) are didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. Here, R ^{4 is} an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion, as well as mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁷ for R ⁵ and to alkyl radicals having 16 to 18 carbon atoms for R ⁴ and R ⁷ . Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium metho sulfate or methyl N, N-bis (acyl-oxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated alkyl chains are used, the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio are preferred (in wt .-%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30 have. Commercial examples are sold by Stepan under the tradename Stepantex ^® Methylhydroxyalkyldi-alkoyloxyalkylammoniummethosulfate or those known under Dehyquart ^® Cognis products known under or Rewoquat ^® manufactured by Goldschmidt-Witco. Further preferred compounds are the diesterquats corresponding to formula (V), under the name Rewoquat ^® W 222 LM or CR 3099 are available and provide in addition to the softness for stability and color protection.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. In addition to the quaternary compounds described above, it is also possible to use other known compounds, for example quaternary imidazolinium compounds of the formula (VI)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt und r eine Zahl zwischen 0 und 5 ist.Further suitable quaternary compounds are described by formula (VII)

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group and r is a number between 0 and 5 is.

Next The compounds of formulas (III) and (IV) may also short-chain, water-soluble, quaternary ammonium compounds be used, such as Trihydroxyethylmethylammoniummethosulfat or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, Stearyltrimethylammonium chloride, distearyldi-methylammonium chloride, Lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and tricetylmethylammonium chloride.

Also protonated alkylamine compounds which have a softening effect, and the non-quaternized, protonated precursors of cationic Emulsifiers are suitable.

Further Cationic compounds which can be used according to the invention represent the quaternized protein hydrolysates.

Suitable cationic polymers include the polyquaternium polymers as referred to in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, also referred to as Merquats, Polyquaternium-10 polymers (Ucare Polymer IR 400, Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride , and similar quaternized guar derivatives (eg Cosmedia Guar, manufacturer: Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. As the commercial product Glucquat ^® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers and copolymers.

Polyquaternized polymers (for example, Luviquat Care by BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Also useful in the present invention are cationic silicone oils, such as the commercially available Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimeth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicone). , SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ^® -Quat 3270 and 3272 (manufacturer: Goldschmidt-Rewo; diquaternary polydimethylsiloxanes, quaternium-80), and Silicone quat Rewoquat ^® SQ 1 (Tegopren ^® 6922, manufacturer: Goldschmidt-Rewo).

die Alkylamidoamine in ihrer nicht quaternierten oder, wie dargestellt, ihrer quaternierten Form, sein können. R¹⁷ kann ein aliphatischer Alk(en)ylrest mit 12 bis 22 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen sein. s kann Werte zwischen 0 und 5 annehmen. R¹⁸ und R¹⁹ stehen unabhängig voneinander jeweils für H, C_1-4-Alkyl oder Hydroxyalkyl. Bevorzugte Verbindungen sind Fettsäureamidoamine wie das unter der Bezeichnung Tego Amid^®S 18 erhältliche Stearylamidopropyldimethylamin oder das unter der Bezeichnung Stepantex^® X 9124 erhältliche 3- Talgamidopropyl-trimethylammo-nium-methosulfat, die sich neben einer guten konditionierenden Wirkung auch durch farbübertragungsinhibierende Wirkung sowie speziell durch ihre gute biologische Abbaubarkeit auszeichnen.It is likewise possible to use compounds of the formula (VIII)

the alkylamidoamines may be in their quaternized or, as shown, their quaternized form. R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl. Preferred compounds are fatty acid amidoamines, such as under the name Tego Amid ^® S 18 stearylamidopropyldimethylamine available or obtainable under the name Stepantex ^® X 9124 3- tallowamidopropyl trimethylammo-nium methosulfate, which by a good conditioning effect by dye transfer-inhibiting effect and by to distinguish their good biodegradability.

Especially preferred are alkylated quaternary ammonium compounds, of which at least one alkyl chain by an ester group and / or Amido group is interrupted, in particular N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate.

When nonionic plasticizers are mainly polyoxyalkylene glycol alkanoates, Polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, Alkylpolyglycosides, especially sorbitan mono, di- and triesters and fatty acid esters of polycarboxylic acids into consideration.

In an agent according to the invention, preferably conditioning agent Plasticizers may be used in amounts of from 0.1 to 80% by weight, usually 0.1 to 70 wt .-%, preferably 0.2 to 60 wt .-% and in particular 0.5 to 40 wt .-%, each based on the total agent included be.

invention Conditioning agents may preferably be one or more Anionic surfactants, especially those already above have been described.

invention Conditioning agents may preferably be one or more contain nonionic surfactants, especially those which continue already described above.

When other surfactants for all inventive Means, especially for the conditioning come so-called gemini surfactants into consideration. These are generally such compounds having two hydrophilic groups and have two hydrophobic groups per molecule. These groups are usually separated by a so-called "spacer". This spacer is usually a carbon chain that is long enough should be that the hydrophilic groups have a sufficient distance have to act independently of each other. Such surfactants are generally characterized by an unusual low critical micelle concentration and the ability to to greatly reduce the surface tension of the water, out. In exceptional cases, however, under the term Gemini surfactants understood not only dimeric but also trimeric surfactants.

suitable Gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis and trimer alcohol tris sulfates and ether sulfates. End-capped dimeric and trimeric mixed ethers are outstanding especially through their bi- and multi-functionality. Thus, the end-capped surfactants mentioned have good properties Net properties and are low in foam, making them especially for the use in automatic washing, care or cleaning procedures suitable.

used but can also be gemini polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as described in the relevant State of the art will be described.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²³ für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

wherein RCO is an aliphatic acyl group having 6 to 22 carbon atoms, R ^{23 is} hydrogen, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl group having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R²⁴ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R²⁵ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the following formula

R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.

[Z] is preferably by reductive amination of a reduced sugar obtained, for example, glucose, fructose, maltose, lactose, galactose, Mannose or xylose. The N-alkoxy or N-aryloxy-substituted Compounds can then be converted, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide as Catalyst converted into the desired polyhydroxy fatty acid amides become.

Suitable as an ingredient for the inventive Agents are also N-methylglucamides.

The agents according to the invention preferably contain also amphoteric surfactants. In addition to numerous one to three times alkylated amine oxides make the betaines a significant class represents.

in der R²⁶ für Alkyl- und/oder Alkenylreste mit 6 bis 22 Kohlenstoffatomen, R²⁷ für Wasserstoff oder Alkylreste mit 1 bis 4 Kohlenstoffatomen, R²⁸ für Alkylreste mit 1 bis 4 Kohlen-stoffatomen, n für Zahlen von 1 bis 6 und X¹ für ein Alkali- und/oder Erdalkalimetall oder Ammonium steht. Typische Beispiele sind die Carboxymethylierungsprodukte von Hexylmethylamin, Hexyldimethylamin, Octyldimethylamin, Decyldimethylamin, Dodecylmethylamin, Dodecyldimethylamin, Dodecylethylmethylamin, C_12/14-Kokosalkyldimethylamin, Myristyldimethylamin, Cetyldimethylamin, Stearyldimethylamin, Stearylethyl-methylamin, Oleyldimethylamin, C_16/18-Talgalkyldimethylamin sowie deren technische Gemische.Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. Preferably, the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein one mole of salt is formed per mole of betaine. Furthermore, the addition of unsaturated carboxylic acids, such as acrylic acid is possible. As regards the nomenclature and, in particular, the distinction between betaines and 'true' amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (IX)

R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{28 is} alkyl radicals having 1 to 4 carbon atoms, n is a number from 1 to 6 and X is ^{1 represents} an alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C _12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C _16/18 tallowalkyldimethylamine, and technical mixtures thereof.

in der R³¹ CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen und 0 oder 1 bis 3 Doppelbindungen, m für Zahlen von 1 bis 3 steht und R²⁹, R³⁰, n und X² die oben angegebenen Bedeutungen haben. Typische Beispiele sind Umsetzungsprodukte von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, namentlich Capronsäure, Caprylsäure, Caprin-säure, Laurinsäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearin-säure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Gemische, mit N,N-Dimethylaminoethylamin, N,N-Dimethylaminopropylamin, N,N-Diethylaminoethylamin und N,N-Diethylaminopropylamin, die mit Natriumchloracetat kondensiert werden. Bevorzugt ist der Einsatz eines Kondensationsproduktes von C_8/18-Kokosfettsäure-N,N-dimethylaminopropylamid mit Natriumchloracetat.Also suitable are carboxyalkylation products of amidoamines which follow the formula (X),

in which R ^{31 is} CO for an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R ²⁹ , R ³⁰ , n and X ² are as defined above. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic, caprylic, capric, lauric, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic, elaeostearic, arachidic, gadoleic, acids , Behenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. The use of a condensation product of C _8/18 coconut fatty acid N, N-dimethylaminopropylamide with sodium chloroacetate is preferred.

in der R³² für einen Alkylrest mit 5 bis 21 Kohlenstoffatomen, R³³ für eine Hydroxylgruppe, einen OCOR³²- oder NHCOR³²-Rest und m für 2 oder 3 steht. Auch bei diesen Substanzen handelt es sich um bekannte Stoffe, die beispielsweise durch cyclisierende Kondensation von 1 oder 2 Mol Fettsäure mit mehrwertigen Aminen, wie beispielsweise Aminoethyl-ethanolamin (AEEA) oder Diethylentriamin erhalten werden können. Die entsprechenden Carboxyalkylierungsprodukte stellen Gemische unterschiedlicher offenkettiger Betaine dar. Typische Beispiele sind Kondensationsprodukte der oben genannten Fettsäuren mit AEEA, vorzugsweise Imidazoline auf Basis von Laurinsäure oder wiederum C_12/14-Kokosfettsäure, die anschließend mit Natriumchloracetat betainisiert werden.Further suitable suitable starting materials for the betaines usable in the context of the invention are imidazolines which follow the formula (XI),

in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethyl-ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C _12/14 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.

Solvent, used in the compositions of the invention are, for example, from the group or polyhydric alcohols, alkanolamines or glycol ethers, if so they are miscible with water in the specified concentration range. Preferably, the solvents are selected from Ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, Glycerol, diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether, Ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n- butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, Propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylene glycol monomethyl, or ethyl ether, di-isopropylene glycol monomethyl, or -ethyl ether, methoxy, ethoxy or butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures this solvent.

Some glycol ethers are available under the trade name Arcosolv ^® (Arco Chemical Co.) or Cellosolve ^®, carbitol ^® or Propasol ^® (Union Carbide Corp.); this includes z. B. ButylCarbitol® ^{®, ®} hexyl carbitol, methyl ^®, and Carbitol ^® itself, (2- (2-ethoxy) ethoxy) ethanol. The choice of glycol ether can be readily made by one skilled in the art on the basis of its volatility, water solubility, weight percent of total dispersion, and the like. Pyrrolidone solvents, such as N-alkyl-pyrrolidones, for example N-methyl-2-pyrrolidone or NC ₈ -C ₁₂ -alkyl-pyrrolidone, or 2-pyrrolidone, may also be used. Also preferred as the sole solvent or as part of a solvent mixture are glycerol derivatives, in particular glycerol carbonate.

Among the alcohols which may preferably be used as cosolvents in the present invention are low molecular weight liquid polyethylene glycols, for example, polyethylene glycols having a molecular weight of 200, 300, 400 or 600. Other suitable cosolvents are other Al alcohols, for example (a) lower alcohols such as ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and methyl ethyl ketone, (c) C ₂ -C ₄ polyols such as a diol or a triol, for example ethylene glycol, propylene glycol , Glycerol or mixtures thereof. Especially preferred is 1,2-octanediol from the class of diols.

In a preferred embodiment, the agent according to the invention contains one or more solvents from the group comprising C ₁ to C ₄ monoalcohols, C ₂ to C ₆ glycols, C ₃ to C ₁₂ glycol ethers and glycerol, in particular ethanol , The C ₃ - to C ₁₂ glycol ethers according to the invention contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms.

Preferred C ₁ to C ₄ monohydric alcohols are ethanol, n-propanol, isopropanol and tert-butanol. Preferred C ₂ to C ₆ glycols are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,5-pentanediol, neopentyl glycol and 1,6-hexanediol, in particular ethylene glycol and 1,2-propylene glycol. Preferred C ₃ - to C ₁₂ glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, tri- and tetrapropylene glycol, propylene glycol monotertiary butyl ether and propylene glycol monoethyl ether and the solvents designated according to INCI butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyloctanol, ethoxydiglycol, Ethoxyethanol, ethyl hexanediol, isobutoxypropanol, isopentyldiol, 3-methoxybutanol, methoxyethanol, methoxyisopropanol and methoxymethylbutanol.

The Composition according to the invention, preferably conditioning agent or liquid detergent, may be one or more solvents in an amount of usually up to 90% by weight, preferably 0.1 to 30 wt .-%, in particular 2 to 20 wt .-%, particularly preferably From 3 to 15% by weight, most preferably from 5 to 12% by weight, for example 5.3 or 10.6 wt .-%, each based on the total agent included.

In a preferred embodiment, the inventive If appropriate, means, in particular the conditioning agent or more complexing agents.

complexing (INCI chelating agents), also called sequestering agents, are ingredients, to complex and inactivate the metal ions, for example, their adverse effects on stability or the appearance of the agents, such as cloudiness, to prevent. On the one hand, it is important to deal with many Ingredients incompatible calcium and magnesium ions of water hardness to complex. The complexation of the ions of heavy metals such as iron or copper retards oxidative decomposition the finished product.

Suitable For example, the following are named according to INCI Complexing agents, for example, in the International Cosmetic Ingredient Dictionary and Handbook are described in more detail: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic acid, dipotassium EDTA, disodium azacycloheptane diphosphonates, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactaric Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl cyclodextrin, pentapotassium triphosphates, pentasodium aminotrimethylene phosphonates, Pentasodium Ethylenediamine Tetramethylene Phosphonate, Pentasodium Pentetates, pentasodium triphosphates, pentetic acid, phytic acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetriamine Pentamethylene phosphonates, Sodium dihydroxyethyl glycinates, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphates, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonate, Sodium trimetaphosphate, TEA-EDTA, TEA-polyphosphate, tetrahydroxyethyl Ethylenediamine, Tetrahydroxypropyl Ethylenediamine, Tetrapotassium Etidronates, tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium Etidronates, Tetrasodium pyrophosphates, Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and trisodium phosphates.

preferred Chelating agents are tertiary amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both amino as well as hydroxy and / or ether groups as functional groups. Particularly preferred tertiary alkanolamines are tri-ethanolamine and tetra-2-hydroxypropyl-ethylenediamine (N, N, N ', N'-tetrakis- (2-hydroxy-propyl) -ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and possibly solvents are described in the prior art.

One Particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts. In a preferred embodiment contains the agent according to the invention accordingly as Complexing agent etidronic acid and / or one or more their salts.

In a particular embodiment contains the inventive Means a complexing agent combination of one or more tertiary Amines and one or more other complexing agents, preferably one or more complexing acids or their salts, in particular of triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of its salts.

The Inventive agents, in particular conditioning agents, advantageously contains complexing agents in an amount from usually 0 to 20% by weight, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, particularly preferably 1 up to 8% by weight, more preferably from 1.5 to 6% by weight, based on the total mean.

In Another embodiment contains the inventive Agents, in particular conditioning agents, if necessary or more viscosity regulators, preferably as Thickeners act.

The Viscosity of the agent can be determined by standard methods (For example, Brookfield RVD-VII at 20 rpm and 20 ° C, spindle 3) are measured and is preferably in the range of 10 to 5000 mPas. Preferred liquid up Gel-like agents have viscosities from 20 to 4000 mPas, with values between 40 and 2000 mPas being particularly preferred are.

suitable Thickeners are inorganic or polymeric organic compounds. It can also be used mixtures of several thickeners become.

To the inorganic thickeners include, for example, polysilicic acids, Clay minerals such as montmorillonites, zeolites, silicas, Aluminum silicates, phyllosilicates and bentonites.

The Organic thickeners come from the groups of natural Polymers, the modified natural polymers and the fully synthetic polymers.

Out naturally derived polymers used as thickeners, are, for example, xanthan gum, agar, carrageenan, gum tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, gellan gum, locust bean gum, Starch, dextrins, gelatin and casein.

modified Natural products come mainly from the group of modified starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and propylcellulose, highly etherified Methylhydroxyethylcellulose and Kernmehlether called.

A large group of thickeners, widely used in the find the most diverse application areas are the fully synthetic Polymers such as polyacrylic and polymethacrylic compounds which crosslink or uncrosslinked and possibly cationically modified, Vinyl polymers, polycarboxylic acids, polyethers, activated Polyamide derivatives, castor oil derivatives, polyimines, polyamides and polyurethanes. Examples of such polymers are Acrylic resins, ethylacrylate-acrylamide copolymers, acrylic ester-methacrylic acid-ester copolymers, Ethyl acrylate-acrylic acid-methacrylic acid copolymers, N-methylolmethacrylamide, maleic anhydride-methyl vinyl ether copolymers, Polyether-polyol copolymers and butadiene-styrene copolymers.

Further suitable thickeners are derivatives of organic acids and their alkoxide adducts, for example aryl polyglycol ethers, carboxylated nonylphenol ethoxylate derivatives, sodium alginate, diglycerol monoisostearate, nonionic ethylene oxide adducts, coconut fatty acid diethanolamide, isododecenylsuccinic anhydride and galactomannan. Thickener from the mentioned classes of substances are commercially available and, for example, under the trade names Acusol ^® -820 (methacrylic acid (stearyl alcohol 20 EO) ester-acrylic acid copolymer, 30% in water, Rohm & Haas), Da-Pral ^® -GT -282-S (alkyl polyglycol ethers, Akzo), DEUTEROL ^® polymer-11 (dicarboxylic acid co-polymer, Schoner GmbH) deuteron ^® -xg (anionic heteropolysaccharide based on β-D-glucose, D-mannose, D-glucuronic acid , Schoner GmbH), -XN deuteron ^® (non-ionic polysaccharide, Schoner GmbH), DICRYLAN ^® -Verdicker-O (ethylene oxide adduct, 50% solution in water / isopropanol, Pfersse Chemie), EMA ^® -81 and EMA ^® - 91 (ethylene-maleic anhydride copolymer, Monsanto), thickener QR-1001 (polyurethane emulsion, 19-21% in water / diglyme, Rohm & Haas), Mirox ^® -AM (anio African acrylic acid-acrylate copolymer dispersion, 25% in water, Stockhausen), SER-AD FX 1100 (hydrophobic urethane polymer, Servo Delden), Shellflo ^® -S (high-molecular weight polysaccharide, stabilized with formaldehyde, Shell), Shellflo XA ^® (xanthan biopolymer, stabilized with formaldehyde, Shell), Kelzan, Keltrol T (Kelco) is.

In a further preferred embodiment the agent according to the invention, in particular Conditioner, optionally one or more enzymes.

When Enzymes are especially those from the classes of hydrolases as the proteases, esterases, lipases or lipolytic acting Enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures the enzymes mentioned in question. All of these hydrolases carry in the Laundry to remove stains such as protein, grease and or starchy stains and grayness. Cellulases and other glycosyl hydrolases may be over it By removing pilling and microfibrils for color retention and to increase the softness of the textile. to Bleaching or to inhibit color transfer can also Oxireduktasen be used.

Especially are well suited from bacterial strains or fungi like Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents. Preferably Proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or Protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular Interest. Examples of such lipolytic acting Enzymes are the known cutinases. Also peroxidases or oxidases have proven to be suitable in some cases. To the appropriate Amylases include in particular α-amylases, iso-amylases, Pullulanases and pectinases. As cellulases are preferably cellobiohydrolases, Endoglucanases and β-glucosidases, which include cellobiases be called, or mixtures thereof used. Because different Cellulase types through their CMCase and avicelase activities can distinguish by targeted mixtures of cellulases the desired activities are set.

The Enzymes can act as shaped bodies on carriers be embedded or coated to protect against premature To protect decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules may, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%, based on the total agent.

The agents according to the invention (eg conditioning agents) may optionally contain bleaching agents. Among the compounds which serve as bleaches and deliver H ₂ O ₂ in water, sodium percarbonate, sodium perborate tetrahydrate and sodium perborate monohydrate are particularly important. Other useful bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H ₂ O ₂ -forming peracidic salts or peracids, such as persulfates or persulfuric acid. Also useful is the urea peroxohydrate percarbamide, which can be described by the formula H ₂ N-CO-NH ₂ .H ₂ O ₂ . In particular, when using the means for cleaning hard surfaces, for example in automatic dishwashing, they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents. Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, examples of which include the alkyl peroxyacids and the aryl peroxyacids. Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxycaproic acid (Phthalimidoperoxyhexansäure, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonylamidopersuccinates, and aliphatic and araliphatic peroxydicarboxylic acids such as 1,12-diperoxy carboxylic acid, 1,9-diperoxyazelaic acid, diperoxysebacic acid, diperoxybrassic acid, the diperoxyphthalic acids, 2-decyl-diperoxybutane-1,4-diacid, N, N- Terephthaloyl-di (6-aminopercaproic acid) can be used.

The Bleaching agents may preferably be coated to contain them to protect against premature decomposition.

dyes can be used in the composition according to the invention be, wherein the amount of one or more dyes so low it is to be chosen that after application of means no visible residues remain. Preferably the agent according to the invention is free of dyes.

The Means according to the invention may preferably be a or several antimicrobial agents or preservatives in an amount of usually 0.0001 to 3 wt .-%, preferably 0.0001 to 2% by weight, especially 0.0002 to 1% by weight, especially preferably 0.0002 to 0.2 wt%, most preferably 0.0003 to 0.1 wt .-%, contained.

antimicrobial Agents or preservatives are differentiated according to the antimicrobial spectrum and mechanism of action between bacteriostats and bactericides, Fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol-urea acetate. The terms antimicrobial effect and antimicrobial active ingredient in the context of the invention Teach the usual meaning. Suitable antimicrobial Active ingredients are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, Phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents Compounds, guanidines, antimicrobial amphoteric compounds, Quinolines, 1,2-dibromo-2,4-di-cyanobutane, iodo-2-propyl-butyl-carbamate, Iodine, iodophors, peroxo compounds, halogen compounds and any Mixtures of the preceding.

The antimicrobial agent may be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-propanol. Methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxydiphenyl ether ( Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,11, 13-tetraaza-tetradecandiimidamide, glucoprotamines, antimicrobial surface-active quaternary compounds, guanidines including the bi- and polyguanidine-type such as 1,6-bis- (2-ethylhexyl-biguanido-hexane) -dihydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyl-N ₁ , N ₁ -methyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -o-chlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ', 2,6-dichlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- [N ₁ , N ₁ '-beta (p-methoxyphenyl) diguanido-N ₅ , N ₅ '] -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -α-alpha-beta-phenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1.6 -Di- (N ₁ , N ₁ '- p -nitrophenyldiguanido-N ₅ , N ₅ ') hexane dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') - di-n-propyl ether dihydrochloride, omega: omega'-di- (N ₁ , N ₁ '-p-chlorophenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether tetrahydrochloride, 1,6-di- ( N ₁ , N ₁ ', 2,4-dichlorophenyldiguanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-p-methylphenyl-niguano-N ₅ , N ₅ ' ) hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ '-2,4,5-trichlorophenyldi guanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- [N ₁ , N ₁ '-alpha (p-chlorophenyl) ethyldiguanido-N ₅ , N ₅ '] hexane dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-p-chloro phe-nyldiguanido-N ₅ , N ₅ ') m-xylenedihydrochloride, 1,12-di- (N ₁ , N ₁ ' -p-chlorophenyldiguanido-N ₅ , N ₅ ') dodecane dihydrochloride, 1, 10-di- (N ₁ , N ₁ '-phenyl-diguanido-N ₅ , N ₅ ') -decane-tetrahydrochloride, 1,12-di- (N ₁ , N ₁ '-phenyl-diguanido-N ₅ , N ₅ ') -dodecane tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-o-chlorophenyldi-guanido-N ₅ , N ₅ ') hexane-dihydrochloride, 1,6-di- (N ₁ , N ₁ '-o- chlorophenyldiguanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, ethylene-bis (1-tolyl biguanide), ethylene-bis- (p-tolyl biguanide), ethylene-bis- (3,5-dimethylphenylbiguanide), ethylene-bis - (p-tert-amylphenylbiguanide), ethylene-bis- (nonylphenylbiguanide), ethylene-bis (phenylbifluoride), ethylene-bis- (N-butylphenylbioguanide), ethylene bis (2,5-diethoxyphenylbiguanide), Ethylene bis (2,4-dimethylphenyl biguanide), ethylene bis (o-diphenylbiguanide), ethylene bis (mixed amyl naphthyl biguanide), N-butyl ethylene bis (phenylbiguanide), trimethylene bis (o-tolyl biguanide) , N-butyl-trimethyl-bis (phenyl biguanide) and the corresponding salts such as acetates , Gluconates, hydrochlorides, hydrobromides, citrates, bisulfites, fluorides, polymaleates, N-cocoalkyl sarcosinates, phosphites, hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylenediaminetetraacetates, iminodiacetates, cinnamates, thiocyanates, arginates, pyromellitates, tetracarboxybutyrates , Benzoates, glutarates, monofluorophosphates, perfluoropropionates and any mixtures thereof. Furthermore, halogenated xylene and cresol derivatives, such as p-chloromethacresol or p-chlorometaxylene, as well as natural antimicrobial agents of plant origin (eg from spices or herbs), of animal and microbial origin are suitable. Preferably, antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial agent of animal origin from the group comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobially acting quaternary surface active compound having an ammonium, sulfonium, phosphonium, iodonium or arsonium group, peroxo compounds and chlorine compounds. Also substances of microbial origin, so-called bacteriocins, can be used. Glycine, glycine derivatives, formaldehyde, compounds which readily split off formaldehyde, formic acid and peroxides are preferably used.

The suitable as antimicrobial agents quaternary ammonium compounds (QAV) have been described above. Is particularly suitable, for example, benzalkonium chloride, etc. Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Variquat ^® ex Witco / Sherex and Hyamine ^® ex Lonza and as Bardac ^® ex Lonza. Other commercially obtainable antimicrobial agents are N- (3-chloroallyl) hexaminium chloride such as Dowicide and Dowicil ^{® ®} ex Dow, benzethonium chloride such as Hyamine ^® 1622 ex Rohm & Haas, methylbenzethonium as Hyamine ^® 10X ex Rohm & Haas, cetylpyridinium chloride such as Cepacol ex Merrell Labs ,

Farther the agents according to the invention may optionally Ironing aids to improve water absorbency, the rewettability of the treated textiles and the facilitation of Ironing of treated textiles included. It can For example, silicone derivatives are used in the formulations become. These additionally improve the rinsing behavior the detergent-active formulations by their foam-inhibiting properties. Preferred silicone derivatives are, for example polydialkyl or Alkylarylsiloxanes in which the alkyl groups one to five Have C atoms and are completely or partially fluorinated. preferred Silicones are polydimethylsiloxanes which are optionally derivatized can be and then amino-functional or quaternized or Si-OH, Si-H and / or Si-Cl bonds. The Viscosities of the preferred silicones are 25 ° C ranging between 100 and 100,000 mPas, with the silicones in Amounts between 0.2 and 5 wt .-%, based on the total agent can be used.

preferred agents according to the invention are liquid detergents, preferably containing surfactant (s) and other customary Ingredients of washing, care or cleaning agents. For example may according to the invention suitable liquid detergents as thickening system, in each case based on the total agent a) 0.1 to 5% by weight of a polymeric thickener, b) 0.5 to 7% by weight a boron compound and c) 1 to 8% by weight of a complexing agent, contain.

in the The scope of the present invention are aqueous, more viscous Preferred agents, preferably liquid detergents, whose Content of surfactant (s) over 25 wt .-% is.

suitable Thickener, also called swelling (ungs) agent, such as. B. Alginates or agar-agar have been described above. preferred aqueous liquid detergents contain as thickening system 0.2 to 4 wt .-%, preferably 0.3 to 3 wt .-% and in particular 0.4 to 1.5% by weight of a polysaccharide.

One preferably used polymeric thickener is xanthan, a microbial anionic heteropolysaccharide derived from Xanthomonas campestris and some other species under aerobic conditions is produced and a molecular weight of 2 to 15 million daltons having. Xanthan is made from a chain bound with β-1,4 Glucose (cellulose) with side chains formed. The structure of Subgroups consists of glucose, mannose, glucuronic acid, Acetate and pyruvate, where the number of pyruvate units is the viscosity of xanthan gum.

invention Agents such as preferably liquid detergents can preferably contain a boron compound in amounts of 0.5 to 7 wt .-% is used, included. examples for Boron compounds which can be used in the context of the present invention are boric acid, boron oxide, alkali borates such as ammonium, Sodium and potassium ortho-, meta- and -pyroborate, borax in its different hydration levels and polyborates such as Alkali metal pentaborate.

Also, organic boron compounds such as esters of boric acid are used, as well. B. reaction products of H ₃ BO ₃ with nonionic surfactants and / or fragrances.

preferred Liquid detergents contain 0.5 to 4 wt .-%, preferably 0.75 to 3 wt .-% and in particular 1 to 2 wt .-% boric acid and / or sodium tetraborate.

Furthermore, liquid detergents according to the invention may contain 1 to 8% by weight of a complexing agent. Particularly preferred liquid detergents contain citric acid or sodium citrate, wherein Liquid detergents are preferred which contain 2.0 to 12 wt .-%, preferably 3.0 to 6.0 wt .-% and in particular 4.0 to 5.0 wt .-% sodium citrate.

Next the components of the thickening system contain the inventive Liquid detergent, preferably surfactant (s), wherein anionic, nonionic, cationic and / or amphoteric surfactants used become. From an application point of view, mixtures are preferred from anionic and nonionic surfactants, the proportion of nonionic surfactants preferably be greater can be considered as the proportion of anionic surfactants. The use of sugars and / or sugar derivatives such as alkyl polyglucosides or Cyclodextrins can also be made.

• – Aniontenside, wie z. B. Alkylbenzolsulfonat, Alkylsulfat, in Mengen von vorteilhafterweise 5–40 Gew.-%, vorzugsweise 8–30 Gew.-%, insbesondere 15–25 Gew.-%,
• – Nichtionische Tenside, wie z. B. Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid, vorteilhafterweise 0,1–25 Gew.-%, vorzugsweise 5–20 Gew.-%, insbesondere 10–15 Gew.-%,
• – Gerüststoffe, wie z. B. Zeolith, Polycarboxylat, Natriumcitrat, vorteilhafterweise 0–15 Gew.-%, vorzugsweise 0,01–10 Gew.-%, insbesondere 0,1–5 Gew.-%,
• – Schauminhibitor, z. B. Seife, Siliconöle, Paraffine, vorteilhafterweise 0,1–4 Gew.-%, vorzugsweise 0,2–2 Gew.-%, insbesondere 1–3 Gew.-%,
• – Enzyme, z. B. Proteasen, Amylasen, Cellulasen, Lipasen, vorteilhafterweise 0,1–2 Gew.-%, vorzugsweise 0,2–1 Gew.-%, insbesondere 0,3–0,8 Gew.-%,
• – Optische Aufheller, z. B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise 0,1–0,3 Gew.-%, insbesondere 0,1–0,4 Gew.-%,
• – Duftstoffe
• – -Stabilisatoren,
• – Wasser
• – Seife, vorteilhafterweise 1–20 Gew.-%, vorzugsweise 2–15 Gew.-%, insbesondere 5–10 Gew.-%,
• – Alkohole/Lösungsmittel, vorteilhafterweise 0–25 Gew.-%, vorzugsweise 1–20 Gew.-%, insbesondere 2–15 Gew.-%,
• – Feuchthaltemittel
• – photokatalytisches Material

An inventive liquid heavy duty detergent may preferably z. B. contain the following components, which are selected from the following:

• - anionic surfactants, such as. B. alkylbenzenesulfonate, alkyl sulfate, in amounts of advantageously 5-40 wt .-%, preferably 8-30 wt .-%, in particular 15-25 wt .-%,
• - Nonionic surfactants, such as. Fatty alcohol polyglycol ethers, alkylpolyglucoside, fatty acid glucamide, advantageously 0.1-25% by weight, preferably 5-20% by weight, in particular 10-15% by weight,
• - builders, such. B. zeolite, polycarboxylate, sodium citrate, advantageously 0-15 wt .-%, preferably 0.01-10 wt .-%, in particular 0.1-5 wt .-%,
• Foam inhibitor, e.g. As soap, silicone oils, paraffins, advantageously 0.1-4 wt .-%, preferably 0.2-2 wt .-%, in particular 1-3 wt .-%,
• - enzymes, eg. B. proteases, amylases, cellulases, lipases, advantageously 0.1-2 wt .-%, preferably 0.2-1 wt .-%, in particular 0.3-0.8 wt .-%,
• - Optical brightener, z. B. stilbene derivative, biphenyl derivative, advantageously 0.1-0.3 wt .-%, in particular 0.1-0.4 wt .-%,
• - perfumes
• - stabilizers,
• - Water
• Soap, advantageously 1-20% by weight, preferably 2-15% by weight, in particular 5-10% by weight,
• Alcohols / solvents, advantageously 0-25% by weight, preferably 1-20% by weight, in particular 2-15% by weight,
• - Humectants
• - Photocatalytic material

The agents according to the invention may preferably perfumed with perfume oil (fragrances, fragrances) be.

With The term perfume oil are preferably in themselves meant perfume compositions which commonly be used for product scenting and in particular for human Discretion are fragrant. This will be explained with an example. Will a professional z. B. make a shower gel fragrant, so adds He usually does not just give him a (well) smelling Substance, but a collective (well) smelling substances. Such a collective usually consists of a multitude individual fragrances, z. B. more than 10 or 15, preferably to to 100 or more. These fragrances cooperatively form a desired one fragrant, harmonious smell.

One usable perfume oil can be individual fragrance compounds, z. As the synthetic products of the ester, ether, aldehyde, Ketones, alcohols and hydrocarbons. fragrance compounds the type of ester are z. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethyl acetate, benzyl acetate, ethylmethylphenylglycinate, allylcyclohexyl-propionate, Styrallyl propionate, benzyl salicylate, cyclohexyl salicylate, floramate, Melusat and Jasmecyclat. For example, the ethers include Benzyl ethyl ether and Ambroxan, to the aldehydes z. B. the linear Alkanals with 8-18 carbon atoms, citral, citronellal, citronellyloxy-acetaldehyde, Cyclamenaldehyde, Lilial and Bourgeonal, to the ketones z. B. the Jonone, ∞ isomethylionone and methyl cedryl ketone, to the Alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the terpenes like limonene and pinene. However, mixtures are preferred different fragrances used, which together create an appealing Generate fragrance of the perfume oil formed.

The perfume oils can also contain natural fragrance mixtures, as they are available from plant sources, eg. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, Wa cholderberry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as orange blossom oil, neroliol, orange peel oil and sandalwood oil. In order to be perceptible, a fragrance must be volatile, with molecular weight also playing an important role in addition to the nature of the functional groups and the structure of the chemical compound. For example, most odorants have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and above are more of an exception. Due to the different volatility of fragrances, the smell of a fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note", "middle note or body" and "base note "(end note or dry out) divided.

Tenacious Fragrances, in the context of the present invention advantageously can be used, for example, the essential oils like angelica root oil, aniseed oil, arnica blossom oil, Basil oil, bay oil, Champacablütenöl, Edling fir oil, Edel fir cone oil, Elemiöl, Eucalyptus oil, fennel oil, spruce alder oil, galbanum oil, Geranium oil, ginger grass oil, guaiac wood oil, Gurjun Balm Oil, Helichrysum Oil, Ho Oil, Ginger oil, iris oil, cajeput oil, calamus oil, Chamomile oil, camphor oil, kanga oil, cardamom oil, Cassia oil, pine needle oil, Kopaïva balsam oil, Coriander oil, spearmint oil, caraway oil, Cumin oil, lemongrass oil, musk kernel oil, Myrrh oil, clove oil, neroli oil, niaouli oil, Olibanum oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, peppermint oil, allspice oil, pine oil, Rose oil, rosemary oil, sandalwood oil, celery oil, Star anise, thuja oil, thyme oil, verbena oil, Vetiver oil, juniper berry oil, wormwood oil, Wintergreen Oil, Ylang Ylang Oil, Hyssop Oil, Cinnamon oil, cinnamon leaf oil and cypress oil.

But also the higher-boiling or solid fragrances natural or of synthetic origin may be within the scope of the present invention Invention advantageously as adherent fragrances or fragrance mixtures be used. These connections include the following mentioned compounds and mixtures thereof: ambrettolide, α-amyl cinnamic aldehyde, Anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, Acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, Benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, Farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, Heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, Hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, Iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmone, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, Methyl n-amyl ketone, methyl anthranilate, p-methyl acetophenone, Methylchavikol, p-methylquinoline, methyl-β-naphthylketone, Methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, Nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethylacetal, phenylacetic acid, pulegone, Safrol, salicylic acid isoamyl ester, salicylic acid methyl ester, salicylic acid hexyl ester, Salicylic acid cyclohexyl ester, santalol, skatole, terpineol, Thymen, thymol, γ-undelactone, vanilin, veratrum aldehyde, Cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, Zimtsäurebenzylester.

To the more volatile odoriferous substances, which are part of the present invention can be used advantageously include especially the lower-boiling fragrances natural or synthetic origin, used alone or in mixtures can be. Examples of more volatile Fragrances are alkyl isothiocyanates (alkyl mustard), butanedione, Limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The above-mentioned fragrances are alone or in a mixture according to present invention can be used with the advantages already mentioned.

Especially can also scents from the group of allyl alcohol esters, Esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof.

Allyl alcohol esters are the esters of allyl alcohol, which has the following structural feature, C (OH) -C = C. Examples of Allylalkohlester are in particular allyl amyl glycolate, Allylanthranilat, allyl benzoate, allyl butyrate, Allylcaprat, allyl caproate, allyl cinnamate, Allylcyclohexanacetat, Allylcyclohexanbutyrat, Allylcyclohexanpropionat, allyl heptoate, Allylnonanoat, Allylsalicylat, Amylcinnamylacetat, Amylcinnamylformiat, Cinnamylformiate, Cinnamylacetate, cyclogalbanate, geranyl acetate, Geranylacetoacetat, geranyl benzoate, Geranylcinnamat, Methallylbutyrat , Methallylcaproat, neryl acetate, Nerylbutyrat, Amylcinnamylformiat, Alphamethylcinnamylacetat, Methylgeranyl tiglat, Mertenylacetat, farnesyl acetate, fenchyl acetate, Geranylanthranilat, geranyl butyrate, Gerany iso-butyrate, Geranylcaproat, Geranylcaprylat, Geranylethylcarbonat, geranyl formate, Geranylfuroat, Geranylheptoat, Geranylmethoxyacetat, Geranylpelargonat, geranyl phenylacetate, Geranylphthalat, Geranyl propionate, geranyl iso-propoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans 2-hexenyl valerate, beta-pentenyl acetate, alpha-phenylallyl acetate, prenyl acetate, trichloromethylphenylcarbinyl acetate and / or mixtures thereof. Allyl alcohol esters may preferably be included in the composition of the invention.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are in particular ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2 Methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, verdox (2-tert-butylcyclohexylacetate), I vertenex (4- tert-butylcyclohexylacetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, levo-menthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate Menthy iso-butyrate, menthyl formate, levo-menthyl phenylacetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formates, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, Cyclohexylphenylacetate, cyclohexylpropionate, cyclohexylthioglycolate, cyclohexylvalerate, cyclohexyl iso-valerate, methyl amylacetate, methylbenzylcarbinylacetate, methylbutylcyclohexanylacetate, 5-methyl-3-butyl-tetrahydropyran-4-yl acetate, methylcitrate, methyliso-campholate, 2-methylcyclohexylacetate, 4-methylcyclohexylacetate , 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methyl phenylcarbinyl-isobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octyl-isobutyrate, beta-pentenylacetate, alpha-phenylallylacetate, phenylethylmethylcarbinyliso-valerate, phenylethylene glycol diphenylacetate, phenylethyethylcarbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, isopropylcaprate, isopropylcaproate, isoporppylcaprylate, isopropylcinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate, isopu legyl acetate, isopulegyl acetoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate, vanillin triacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures thereof. These esters may preferably be contained in the composition according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate Dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-eu genyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallyl formate, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat , Linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, methylcyclopentenolone butyrate, methylcyclopentenolone propionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis-ocimenylacetate, phenylsalicylate, terpinylacetate, terpinylanthranilate, terpinylbenzoate, terpinyl-n- butyrate, terpinyl isobutyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the composition according to the invention.

Some fragrance esters may be both ester allylic and secondary or allylic and tertiary alcohol in particular amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, linallylbutyrate, linallyliosbutyrate, linallyl carproate, linallylcaprylate, linallylcinnamate, linallyl citronellate, linallyl formate, linallylheptoate, linallyl-N- methylanthranilate, linallylmethyltiglate, linallyl pelargonate, linaline phenylacetate, linallyl propionate, linallyl pyruvate, linallyl salicylate, linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters may also be contained in the composition according to the invention.

allylic Ketones are characterized by the following structural feature C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, Allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, Alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), Alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2-one), Beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one), Gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones can preferably contained in the composition according to the invention be.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propylacetal, Cinnamicaldehyde dimethylacetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde diiso amylacetal, acetaldehyde diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde di-n propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde phenylethyl-n-propyl acetal, acetylvinyl dimethyl acetal, alpha-amyl cinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, Anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiole. Benzaldehyde diethyl acetal, benzaldehyde-di- (ethyleneglycol monobutyl ether) acetal, benzaldehyde dimethylacetal, Benzaldehydethyleneglycolacetal, Benzaldehydglyceryl acetal, Benzaldehydpropylenglycolacetal, Cinnamicaldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha-Methylcinnamicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, phenylacetaldehyde 2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, Citronellalcyclomonoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof. Acetals may preferably be included in the composition of the invention.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be included in the composition according to the invention.

preferred Examples of condensation products of amines and aldehydes are anisaldehydemethylanthranilate, aurantiol (hydroxycitronellalmethylanthranilate), Verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalane anthranilate, Hydroxycitronellallinallylanthranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenylmethylidenes) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and aldehydes may preferably be included in the composition of the invention.

In particular, it is advantageous if fragrances such. B. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, anisaldehyde (4-methoxy-benzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3 -cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B ] -furan), cis-3-hexenylacetate, cis-3-hexenylsalicylate, citronellol, coumarin, cyclohexyl salicylate, cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decyl aldehyde, ethyl vanillin, ethyl 2-methyl butyrate, ethylene brasylate , Eucalyptol, eugenol, exaltolide (cyclopentadecanolide), florhydral (3- (3-isopropylphenyl) butanal), galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8- hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, Helional (al pha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, hexylacetate, hexylcinnamaldehyde, hexylsalicylate, hydroxyambrane (2-cyclododecyl-propanol), hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5 , 6,7,8-octahydro-1,1,6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethylbenzoic acid methyl ester), lyral (4- (4-hydroxy-4-methyl-pentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4 - (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, methyl cedryl (methyl cedryl ketone), methyl chavicol (1-methyloxy-4,2-propen-1-yl benzene), methyl dihydrojasmonate, methyl nonyl acetaldehyde, musk indanone (4-acetyl) 6-tert-butyl-1,1-dimethylindane), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), PT Bucinal (2 -Methyl-3 (para tert-butylphenyl) propionaldehyde), para-hydroxyphenylbutanone, Pat chloroyl, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) 4-penten-2-ol), rosaphene (2-methyl-5-phenylpentanol), sandalwood, alpha-terpinene, tartalide / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyltetralin ), Undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecenealdehydes, vanillin and / or mixtures are contained in the composition according to the invention.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentylmethylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder 6-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-Iimonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, lobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
• (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha, γ-dimethylallylalcohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide,
• Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetrahydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol (–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nullartigem Geruch, vorzugsweise 5-methyl-(E)-2-hegten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3- Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
• s(kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-einen oder
• (ll) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β- Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar-(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten.

enthalten.The agent according to the invention can according to a preferred embodiment, in particular fragrances

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenalpentylmethyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
• (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or 6-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness smell such as preferably methylhexanoate, undecanone, (Z) -imimonial oxide, benzyl acetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) Fruit odor, such as ethylphenylacetate, geranylvalerate, γ-heptalactone, ethylpropionate, diethylacetal, geranylbutyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, ammonium oxide, hdrocinnamic alcohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, ethyl acetate, cetronellyl butyrate, heyl acetate, nonyl acetate, butylmethyl butyrate, pentenal, isopentyl dimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, epoxy-β-ionone, ethyloctenoate, ethylisohexanoate, isobornylpropionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene , (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3,5-octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethylvalerate, pentanol, isopiperiton, butyloctanoate, ethyl vanillate, methylbutanoate, 2 -Methylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, butanol, δ-dodecalactone, methylquinoxaline, Sesquiphellandren, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or Citronellylisobutyrat or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
• (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -liminene oxide, cis -isocitral, dimethyloctadienal, bornylformate, bornylisovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+ ) -cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl) -methylf uranium, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides,
• Methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1,5,9,9-tetramethyl-12-oxabicyclododeca- 4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, dehydrocarveol, Artemisia alcohol, γ-muurolene, hydroxypentanone, (Z ) -Oximes, β-elemens, δ-cadinol, (E) -β-ocimene, (Z) -dihydrocarvone, α-cadinol, calamine, (Z) -piperitol. Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquipellandrene, citronellyl valerate, bornyl isovalerate, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran, dihydrocarvylacetate , β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, Piperitone, 2,3-dehydro-1,8-cineol, α-terpineol, DL-carvone and / or α-phellandrene or
• (ff) Odorless odor, preferably 5-methyl- (E) -2-hegten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
• s (kk) Pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydrotinyl vinyl acetate and / or α-one or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphenoids, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate , Isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-seleneins, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
• (vv) mixtures of the above.

contain.

In a preferred embodiment contains the inventive means to certain minimum values Perfume oil (fragrances), namely at least 0.00001 wt .-%, advantageously at least 0.0001 wt .-%, in considerable advantageously at least 0.001 wt .-%, in a more advantageous manner at least 0.01% by weight, more preferably at least 0.1 Wt .-%, more preferably at least 0.2 wt .-%, in a very advantageous manner at least 0.3 wt .-%, in particularly advantageous Way at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in a very advantageous manner, at least 0.55 Gew .-%, in an extremely advantageous manner at least 0.6 wt .-%, most advantageously at least 0.65 Wt .-%, most advantageously at least 0.7 wt .-%, in exceptionally advantageous manner, at least 0.75% by weight, in exceptionally advantageous Way at least 0.8 wt .-%, in extremely advantageous Way at least 0.85 wt .-%, in particular at least 0.9 wt .-% of Perfume oil, based on the total agent.

In In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, in more advantageous Way less than 6, in turn, less than 5, more advantageously less than 4, even more advantageous less than 3, preferably less than 2, in particular no perfumes from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, Benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, Geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexenecarboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, Farnesol, hexylcinnamaldehyde, lilial, d-limonene, linalool, methylheptin carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, oak moss extract, Tree moss extract.

To In another preferred embodiment, the inventive Be agent free of perfume oil (fragrances).

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• - GB 9419091 [0109]

Claims (25)

Liquid means of disposal or Reduction of (indoor) noxa with allergenic potential containing: a) photocatalytic material, b) humectants. Agent according to claim 1, characterized in that as photocatalytic material titanium dioxide is contained, in particular a modified titanium dioxide, preferably one with carbon modified titanium dioxide. Agent according to one of claims 1 or 2, characterized in that the, preferably modified, titanium dioxide in amounts of 0.0001 to 30 wt .-%, preferably 0.01 to 15 wt .-% contained, wt .-% based on the total mean. Means according to one of the preceding claims, characterized in that the carbon content of the carbon modified titanium dioxide in the range of 0.01 to 10 wt .-% preferably from 0.05 to 5.0% by weight, advantageously from 0.3 to 1.5% by weight, in particular from 0.4 to 0.8 wt .-%, wt .-% based on the Carbon-modified titanium dioxide. Agent according to one of the preceding claims, characterized in that the specific surface area of the, preferably modified, titanium dioxide by BET is preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in particular 200 to 350 m ² / g. Means according to one of the preceding claims, characterized in that the particle size of, preferably modified, titanium dioxide in the range of 2-500 nm, preferably in the range of 200-400 nm. Means according to one of the preceding claims, characterized in that as humectants glycerol, dimers and trimers of glycerol, ethylene glycol, propylene glycol, sugar alcohols, preferably glucitol, xylitol, mannitol, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, orthophosphoric acid, Citric acid, urea, alums, hydrates of aluminum salts, hydrogenated glucose syrup and / or mixtures of the foregoing is, preferably in amounts of 0.01 to 50 wt .-%, advantageously 0.1 to 40% by weight, more preferably 0.5-30 Wt .-%, more preferably 1-20 wt .-%, in even more advantageous Way 1.5-10 wt .-%, in particular 2-5 wt .-%, Wt .-% based on the total agent. Means according to one of the preceding claims, characterized in that a nonionic surfactant is contained, preferably from the group of the alkoxylated alcohols, the alkylphenol polyglycol ethers, the alkoxylated fatty acid alkyl esters, the polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides, the fatty acid glucamides, and / or the long-chain alkyl sulfoxides, preferably in amounts from 0.01 to 30 wt .-%, advantageously 0.1 to 20 wt .-%, in more advantageously 0.5-15 wt .-%, in a more advantageous manner 1-10% by weight, more preferably 1.5-5 Wt .-%, in particular 2-4 wt .-%, wt .-% based on the entire means. Means according to one of the preceding claims, characterized in that it additionally (A) chemical Noxenminderer, such as. Benzylbenzot, 2-propanol, 6-isopropyl-m-cresol, Diazolidinyl urea, anionic sodium dioctyl sulfosuccinate, Pyrethroid pemethrin, d-allethrin, piperonyl butoxide, fungicides, preferably in amounts> 0.01% by weight and or (B) biological Noxenminderer, such as. B. neem oil, Tea tree oil, farnesol, tannin (acid), essential oils, Terpenes, in particular citral, limonene, beta-ionone, linalool, Geraniol, eugenol, myrcene or carvone, e.g. B. in amounts> 0.01 wt .-%, % By weight, based in each case on the total agent. Agent according to one of the preceding claims, characterized in that it contains a) photocatalytic material, b) humectant c) nonionic surfactant d) optionally cationic surfactant, preferably benzalkonium chloride, preferably 0 to 5% by weight e) optionally chemical and / or biological noxa reducers, preferably those of the abovementioned type, preferably in the abovementioned amounts, f) optionally fragrance (s), preferably in an amount of from 0% to 5%, more preferably from 0.1% to 2% by weight; g) optionally further surfactant, preferably in an amount of 0 wt .-% to 20 wt .-%, in particular 0.1 wt .-% to 10 wt .-%; h) optionally an antimicrobial agent, e.g. B. Alkyldimethylbenzylammoniumsaccharinat, preferably in an amount of 0 wt .-% to 3 wt .-%, in particular from 0.01 wt .-% to 1 wt .-%; i) optionally a corrosion inhibitor, for. As sodium nitrite, sodium benzoate, triethanolamine or ammonium hydroxide, preferably in an amount of 0 wt .-% to 20 wt .-%, in particular 0.01 wt .-% to 10 wt .-% j) optionally solvent k) optionally contains water , Wt .-% in each case based on the total mean. Means according to one of the preceding claims, characterized in that it is a dispersion, emulsion, microemulsion, PIT emulsion, suspension, aerosol, foam or paste is present. Method of disposal, deactivation, inhibition or reduction of (indoor) noxa with allergenic potential, full: Applying a treatment agent according to one of Claims 1 to 11, on a substrate which requires this, at and / or followed by exposure of the substrate to light with a wavelength in the range of 300-1200 nm. Method according to claim 12, characterized in that that it is in the (indoor) Noxen with allergenic potential germs, mites, preferably house dust mites, mites, mite larvae, Mite feces, fungi, molds, spores, pet dander, pollen, algae, Parasites such as preferably lice, lice, their eggs, moths, their larvae, ticks or disease-transmitting Microorganisms. The method of claim 12 or 13, wherein the with a treatment agent according to any one of claims 1 to 11 treated substrate after completion of light exposure subjected to a mechanical treatment, as preferably Knocking, vacuuming or brushing. Method according to one of the preceding claims 12-14, characterized in that it is at the substrates to textile substrates, preferably textile clothing items or textile utensils such as bedding, pillows, Duvets, covers, upholstery, rugs, curtains, Sleeping bags, car interior textiles or cuddly toys. Method according to one of the preceding claims 12-15, characterized in that the application the treatment agent by soaking, dipping, soaking, Brushing or in particular by spraying takes place. Method according to one of the preceding claims 12-16, characterized in that the application in the context of textile washing, preferably in one automatic washing machine, in particular at T ≤ 60 ° C, advantageously in an automatic washing machine with light source. Method according to the preceding claim 17, characterized that the treatment agent as a rinsing agent in a automatic washing machine is applied. Method according to one of the preceding claims, characterized in that the application in the context of Textile drying takes place, preferably in an automatic tumble dryer, advantageously in an automatic clothes dryer with light source. Method according to the preceding claim 19, characterized first that the damp, to be dried laundry in put the automatic tumble dryer, then the Agent is sprayed into the dryer chamber and finally the drying process is started. Method according to claim 19, characterized that the wet, to be dried laundry to first The rope is hung up and then sprayed with the agent becomes. Use of a treatment agent according to one of Claims 1-11 for disposal, deactivation, Inhibition or reduction of (indoor) noxa with allergenic potential using light with a wavelength in the range from 300-1200 nm. Use of a treatment agent according to one of Claims 1-11 for the prophylaxis of surfaces and substrates in the form of an anticipatory settlement defense and Inhibition of (indoor) noxa with allergenic potential under use of light having a wavelength in the range of 300-1200 nm. Use of a treatment agent according to one of Claims 1-11 for preventing reproduction of mites and allergens in house dust using light with a wavelength in the range of 300-1200 nm. Use of the combination of photocatalytic Material and humectants for enhancing the effectiveness of chemical and / or biological Noxenminderer using light with a wavelength in the range of 300-1200 nm.