DE102006031897A1 - Washing-, caring- or cleaning agent, useful for the cosmetic treatment of human body and for treating textiles and hard surfaces, and for refreshing air, comprises light-active bleaching agent containing titanium dioxide - Google Patents

Abstract

Washing-, caring- or cleaning agent (I) comprises a light-active bleaching agent containing titanium dioxide. Independent claims are included for: (1) a process to treat textiles comprising contacting the textile with (I) and exposing the surface of the textiles in light having a wavelength of 300-1200 nm; (2) a process to treat hard surface comprising contacting the hard surface with (I) and exposing the hard surface in light having a wavelength of 300-1200 nm; (3) a process for the cosmetic treatment of human body, comprising contacting the body parts with (I) and exposing the body parts in light having a wavelength of 300-1200 nm; and (4) a process for refreshing (room)-air comprising contacting the air with (I) and irradiating the air with light having a wave length of 300-1200 nm.

Description

The The invention relates to a washing, care or cleaning agent, which contains a light-active bleaching agent, the titanium dioxide, which is preferably modified. Furthermore, the invention relates Process for textile treatment, for the treatment of hard surfaces, for cosmetic treatment of the human body as well as for improvement the (room) air using the light-active bleaching agent.

The Washing, cleaning and care of various objects provides a basic human need and modern industry is constantly trying to meet these needs of man in many ways to cope in which they have an unmanageable variety of products from the field of washing, cleaning and care products provides.

Especially colored stains, on textiles, but also on hard surfaces always a special challenge for the meaningful conception of detergents, care and cleaning agents, because such colored Stains already in very small quantities to distinct spots to lead and as very disturbing be perceived. In addition, many colored stains extremely tight can adhere to the textile fiber or another surface. Out these reasons Many detergents, cleansers or cleaners contain bleach.

To those bleaching agents of the prior art, which in connection with washing, care or Detergents that have been widely used include, in particular the oxygen-based bleaching agents, e.g. Sodium perborate, sodium percarbonate and hydrogen peroxide, and chlorine-based bleaching agents, such as e.g. Sodium hypochlorite.

With however, these bleaches are limited in use associated. Hydrogen peroxide as such has only a short storage stability. sodium and sodium percarbonate are known to decompose into water to form of hydrogen peroxide. But its bleaching effect is strongly temperature and pH dependent. Below 60 ° C the bleaching effect is low. Therefore, one often resorts to bleach activators such as N, N, N ', N'-tetraacetylethylenediamine (TAED) or p-nonanoyloxybenzenesulfonate (NOBS). In neutral or acidic solution hydrogen peroxide does not have sufficient bleaching ability. The Optimum bleaching effect is achieved only at pH 10-11.

in the Case of chlorine-based bleach, for example, has sodium hypochlorite solutions you incompatibility problems with other detergent ingredients, making bleach and detergent often have to be dosed separately. To stabilize the bleach solution is generally a strong alkaline aqueous solution required by sodium hypochlorite. Acidification releases of harmful Chlorine gas.

in addition comes that common Bleaching agents such as hydrogen peroxide or sodium hypochlorite for many applications, especially care applications, are too aggressive.

The The object of the present invention was therefore to provide a washing, Care or cleaning agent with an alternative bleaching system to disposal to deliver.

These Task became surprising solved by the subject invention, namely by providing a washing, care or cleaning agent, which is a light-active Contains bleach, the titanium dioxide, preferably modified titanium dioxide, in particular carbon-modified titanium dioxide.

The Inventive photoactive Bleaching agent comprises (preferably modified) titanium dioxide and may advantageously the radiation perceivable by the human eye of the visible region of the spectrum with wavelengths between 380 and 800 nm for exploit the purposes of photo bleaching and so a general cleaning effect unfold, e.g. by the incidence of daylight.

The light activity of the light-active bleaching agent advantageously relates to natural or artificial Light with one wavelength in the range of 300-1200 nm, preferably between 380 and 800 nm.

Advantageously, even the light which is incident through glass windows in closed living spaces (diffused daylight) is sufficient to achieve the desired cleaning (eg significant reduction of colored soiling). Even light from technical light sources (artificial light), such as from commercially available Light bulbs (incandescent bulbs), halogen lamps, fluorescent tubes, compact fluorescent lamps (energy-saving lamps) as well as light sources based on light-emitting diodes, are sufficient to effect the desired cleaning (eg stain removal).

One greater Advantage of the washing, Care or cleaning agent is that it is also without the Use of technical equipment, such as. a washing machine, get along. For example, a stained textile can be treated locally with the agent according to the invention, for example by spraying or potions, and the treated textile may then be subjected to e.g. being hung on a leash, so that by the action of light a bleaching effect or general Cleaning effect takes place.

One Another advantage of the washing, care or cleaning agent according to the invention is that it is synonymous for the mobile application is suitable. For example, can a coffee stain or Red wine stain with a liquid agent according to the invention sprayed become. The soiled garment does not even have to be taken off become.

The inventive washing, Care or cleaning agent unfolds a general cleaning effect and does a very good job of removing in particular colored soiling with the help of light, especially with help visible to the human eye visible radiation Range of the spectrum with wavelengths between 380 and 800 nm. The treated substrates are protected. advantageously, can the washing, Care or cleaning agents also using UV radiation (wavelength 380-200 nm, preferably 380-320 nm) has a general cleaning effect and preferably also a good job in removing colored stains Afford.

• – rote bis blaue Anthocyanfarbstoffe, wie z.B. Cyanidin, z.B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z.B. Lycopin, beta-Carotin, z.B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z.B. Curcumin, z.B. aus Curry und Senf,
• – braune Gerbstoffe, z.B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z.B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z.B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften

The agent according to the invention is particularly effective in the reduction or removal of stains which are due to:

• - red to blue anthocyanin dyes, such as cyanidin, eg from cherries or blueberries,
• - red betanidin from the red bed,
• Orange-red carotenoids such as lycopene, beta-carotene, eg from tomatoes or carrots,
• Yellow curcuma dyes, such as curcumin, eg curry and mustard,
• - brown tannins, eg from tea, fruit, red wine
• - deep brown humic acid, eg from coffee, tea, cocoa,
• - green chlorophyll, for example, from green grasses,
• - Technical dyes from cosmetics, inks, color pencils

One Another advantage of the agent according to the invention is that even bacteria and other microorganisms are killed. This is an important contribution to a significant reduction the germ count and thus to an effective hygiene, e.g. Laundry hygiene.

It So is a germ reduction on a harmless to health Measure reached.

It It is known that bacteria and fungi grow quickly in a moist environment multiply. Related e.g. on textiles that means that only then when (washed) laundry stored dry, it does not cause an increase of microorganisms comes. Nevertheless, you can these over survive for several weeks on dry laundry. In a humid environment, however, it comes to a strong increase of microorganisms on the wash.

By the usual today Textile washing if possible low temperatures (30 ° C and 40 ° C) It can happen that the germ reduction on the laundry itself after the machine wash only suboptimal. During subsequent drying in air unlike drying in a tumble dryer not to expect a further reduction of the germs. On the contrary It can lead to bacterial growth, especially in the slow Air drying, as is common in today's urban civilization, since there lack of space or access to outdoor areas only in poorly ventilated clear or in enclosed spaces can be dried. In particular for heavily loaded garments (e.g. Socks, Underpants, tea towels) let yourself then no longer guarantee sufficient hygienic purity. Especially Here the agent of the invention helps.

at the treatment of objects, in particular textiles, with the agent according to the invention is advantageously an effective amount of (preferably modified) Titanoxids on the object surface, in particular textile surface applied. This then takes care of adequate germ reduction and reduction of color stains.

Such Eben applies to the treatment of hard surfaces, for example, when cleaning floors. Again, it is advantageous an effective amount of the (preferably modified) titanium oxide on the surface to be treated deposited and can exert its effect by exposure to light unfold in the visible spectral range.

A effective amount of the (preferably modified) titanium oxide already before, if at least a gradual cleaning effect (eg bleaching effect) is achieved. This can easily be clarified in the routine experiment. The Cleaning action may be e.g. depending on the light radiation or the type or intensity of pollution, e.g. also over several Drag on for hours.

One Another advantage of the agent according to the invention is that it is next to the advantageously occurring general cleaning effect and preferably in addition to the advantageously occurring hygiene effect also beneficial in reducing, eliminating or neutralizing fetid odors can be used. The fetid Odor can be advantageously reduced so that an odor no longer available.

Of the For the sake of clarity, it should be noted that it is the washing, Care or cleaning agents not only to wash, care or Cleaning agents for Textiles, but also to washing, care or cleaning agents for hard surfaces (e.g., dishes, floor, Tiles, glass, metal) as well as washing, care or cleaning agents for cosmetic Can act purposes, such. Skin or hair washing and cleaning agent or care products. Likewise, under the term care products to understand also those means, which serve the (room) air care, So-called air fresheners, room fragrancing and air fresheners. Inventive (room) air handlers have to but at least one fragrance, such as an essential oil (such as e.g. Conifer needle oils, Citrus oil, eucalyptus oil, lavender oil etc.).

Essential oils which are particularly suitable according to the invention can also be selected from the following group:
Angelica fine - Angelica archangelica, Anise - Pimpinella anisum, Benzoin siam - Styrax tokinensis, Cabreuva - Myrocarpus fastigiatus, Cajeput - Melaleuca leucadendron, Cistus - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltannennadel - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce Spruce Needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle (Strawflower) Helichrysum ang., Ginger extra - Zingiber off., St. John's Wort - Hypericum perforatum, Jojoba, Camomile German - Matricaria recutita, Chamomile blue fine - Matricaria chamomilla, Chamomile rom. - Anthemis nobilis, Chamomile wild - Ormensis multicaulis, Carrot - Daucus carota, Mountain pine - Pinus mugho, Lavandine - Lavendula hybrida, Litsea cubeba - (May Chang), Manuka - Leptospermum scoparium , Melissa - Melissa officinalis, sea pine - Pinus pinaster, myrrh - C ommiphora molmol, myrtle - Myrtus communis, Neem - Azadirachta, Niaouli - (MQV) Melaleuca quin. viridiflora, Palmarosa - Cymbopogom martini, Patchouli - Pogostemon patchouli, Peru balsam - Myroxylon balsamum var. pereirae, Raventsara aromatica, Rosewood - Aniba pink odora, sage - Salvia officinalis Horsetail - Equisetaceae, yarrow extra - Achilles millefolia, plantain lanceolate - Plantago lanceolata, Styrax - Liquidambar orientalis, Tagetes (Marigold) Tagetes patula, Tea Tree - Melaleuca alternifolia, Tolu Balsam - Myroxylon Balsamum L., Virginia Cedar - Juniperus virginiana, Frankincense (Olibanum) - Boswellia carteri, Silver Fir - Abies alba.

fragrances, as preferably essential oils, can in all agents according to the invention be included.

in the In the broadest sense fall under the term of care products also all Finishing agent, e.g. the color finishing of walls or other surfaces performed by the application of paints, paints and coatings can be. Thus, therefore, a paint or a coating material a care agent in the context of the invention. To the coating materials belong in the present context advantageously also substances such as e.g. Glue, paste, dispersion, solvent, Reaction, contact adhesives.

The Fabrication of the compositions according to the invention is preferably directed according to the needs of the Intended use.

Compositions of the invention may be in solid, semi-solid, liquid, disperse, emulsified, suspended, aerosol or gel form. Solid and liquid agents may, for example, be packaged in sachets or (preferably self-dissolving) sachets (pouches), especially in multi-chamber pouches. Within the meaning of the invention, the term liquid also includes any solid-state dispersions Liquids. Compositions according to the invention may also be present as pastes, ointments, lotions or creams. Solid agents can be present as free-flowing powders, as flakes, as solid blocks, as pieces (eg soap bars), as spheres or sticks or tablets, in particular multilayer tablets.

In a particular embodiment are the erfindungegmäßen means in liquid Form before. The application can preferably with spray devices respectively. These sprayers contained in a container a filling from the inventive (liquid, mushy or powdery) washing, Care or cleaning agent. The filling can be under pressure a propellant (compressed gas cans, aerosols, aerosols) or it can be a mechanically operated pump sprayer (pump sprays) act. The containers have a removal device, preferably in the form of Valves, which remove the contents as fog, smoke, foam, Powder, paste or liquid jet enable. As a container for the sprayers are mainly cylindrical metal vessels (aluminum, tinplate, Volume preferably <1000 mL), protected or non-shattering glass or plastic (volume preferably <220 mL) or splintering Glass or plastic (volume preferably <150 mL) in question.

The Application can e.g. in the case of liquid agents preferably also be done with a roller applicator, as he e.g. out of the area the deodorant scooter is known. Such scooters have a stored in a ball bed Ball on which moves by movement over a surface can be. The ball takes something of the to be distributed Means up and promoted this to the surface to be treated.

The Application can e.g. also with so-called wet wipes, i. for the Users prefabricated, preferably individually packaged, wet wipes, as they are e.g. from the field of glass cleaning (eyeglass cleaning cloths) or from the field of wet toilet paper are well known. Such wet wipes, which may advantageously also contain preservatives are then advantageously impregnated with a composition of the invention or advantageously, they are individually packed. she can then e.g. be used as a mobile stain remover. If a consumer, as a result of an unfortunate skill, e.g. one Makes red wine stain on his shirt, so he can use such a wet wipe and by rubbing the wet tissue on the stained textile advantageously remove the stain or at least the stain reduce.

The agent according to the invention, preferably liquid Means, can also be multiphase, the phases may e.g. arranged horizontally be, one above the other, or vertically, so next to each other, be arranged. It may be also be a disperse system in which e.g. the solid ingredients inhomogeneous in the liquid Matrix are distributed, so that one such disperse system should be shaken before use.

• (a) Schwerpunktverstärker wie z.B. Fettentferner. Diese dienen vorwiegend zur (Vor)-Behandlung lokal auftretender Fett- und/oder Pigmentverschmutzungen, und werden direkt auf die Textilien aufgetragen.
• (b) Einweichmittel. Diese sind zumeist stärker alkalisch eingestellte Hilfsmittel (bis etwa pH 13) mit geringerem Tensidanteil. Sie begünstigen Quellungsvorgänge bei Anschmutzungen und erniedrigen die Schmutzhaftung.
• (c) separate Bleichmittel, wie Fleckensalze, flüssige Bleichen, Waschkraftverstärker. Sie können sowohl als Waschmittel-Additiv wie auch zur Vorbehandlung verwendet werden.
• (d) separate Enthärter, vorzugsweise enthaltend Builder, wie z.B. Citrate und/oder Zeolithe, und Dispergiermittel, wie z.B. Polycarboxylate.
• (e) separate Verfärbungsinhibitoren,
• (f) Spezialfleckentfernungsmittel für einzelne Fleckenarten
• (g) Textilvorbehandlungsmittel, vorzugsweise flüssig oder pastös, vorzugsweise Spray, zur gezielten Fleckenvorbehandlung.

Preferred laundry detergents according to the invention include the so-called laundry detergents for textiles. These include in particular:

• (a) emphasis amplifier such as grease remover. These are used primarily for (pre-) treatment of locally occurring grease and / or pigment soiling, and are applied directly to the textiles.
• (b) soaking. These are mostly more alkaline adjunct adjuvants (up to about pH 13) with a lower surfactant content. They promote swelling processes in soiling and reduce the dirt adhesion.
• (c) separate bleaching agents, such as stain salts, liquid bleaches, detergency boosters. They can be used both as a detergent additive as well as for pretreatment.
• (D) separate softeners, preferably containing builders, such as citrates and / or zeolites, and dispersants, such as polycarboxylates.
• (e) separate discoloration inhibitors,
• (f) Special stain remover for single stain types
• (G) textile pretreatment agent, preferably liquid or pasty, preferably spray, for targeted stain pretreatment.

• (a) Weichspüler, auch Avivagemittel oder Gewebeconditioner genannt, sowie entsprechende Tücher für die Trocknerapplikation
• (b) Wäschesteifen, welche die Wirkung haben, der Wäsche eine steife und füllige Formgebung zu verleihen
• (c) Formspüler, welche die Wirkung haben, dass damit behandelte Textilien im Faserverband gefestigt werden, so dass die Wäsche einen leichten Appretur- bis kräftigen Stärkegriff erhält
• (d) Hygienespüler, welche vorzugsweise dem letzten Spülgang zugesetzt werden und einen antimikrobiellen Wirkstoff sowie vorzugsweise nichtionische Tenside enthalten
• (e) Bügelhilfen, welche beispielsweise aufgesprüht werden und auch ohne Bügeln in gewissem Ausmaß faserglättend wirken, wenn z.B. nach dem Aufsprühen die noch feuchte Wäsche mit der Hand gestrafft wird
• (f) (Gardinen)-Weißspüler, welche den Zweck haben, den Weißgrad (der Gardinen) zu erhöhen und ggf. faserfestigend wirken
• (g) Pflegespüler, welche das Textil bei der Textilbehandlung (z.B. Maschinenwäsche) mit Wirkstoffen ausstatten (z.B. Öle), welche beim Tragen des Textils an die menschliche Haut abgegeben werden können und der Haut zum Vorteil gereichen bzw. sie pflegen
• (h) Bügelwasser, welche vorteilhafterweise mineralarmes oder vollentsalztes Wasser, vorzugsweise Konservierungsmittel und Duftstoffe umfassen, zur Verwendung in Dampfbügeleisen
• (i) Textilerfrischer, d.h. Produkte welche Gerüche aus vielen textilen Materialien entfernen, z.B. via Einkapselung der zu entfernenden Gerüche mit Hilfe geeignet Mittel wie z.B. Cyclodextrinen oder aber via anderer Wirkstoffe, wie z.B. Zink-Ricinoleat.
• (j) flüssiges Nachbehandlungsmittel, vorzugsweise Spray, zur gezielten Flecken(nach)behandlung

Preferred agents within the meaning of the invention are also aftertreatment agents for textiles. These include in particular:

• (A) Fabric softener, also called softening agent or fabric conditioner, and corresponding wipes for the dryer application
• (b) laundry stiffeners which have the effect of giving the laundry a stiff and voluminous shape
• (c) mold conditioners which have the effect of consolidating textiles treated therewith in the fiber structure so that the laundry obtains a light finish to strong strength grip
• (D) hygiene rinse, which are preferably added to the last rinse and contain an antimicrobial agent and preferably nonionic surfactants
• (e) ironing aids, which are sprayed on, for example, and even without ironing to a certain extent fiber-smoothing, if, for example, after spraying the still wet laundry by hand is tightened
• (f) (curtain) white rinse, which have the purpose to increase the whiteness (of the curtains) and possibly act fiber-strengthening
• (g) nurses who furnish the textile in the textile treatment (eg machine wash) with active ingredients (eg oils), which can be given to the human skin when wearing the fabric and the skin to benefit or maintain them
• (h) ironing water, which advantageously comprises low-mineral or demineralized water, preferably preservatives and perfumes, for use in steam irons
• (I) textile fresheners, ie products which remove odors from many textile materials, eg via encapsulation of the odors to be removed by means of suitable agents such as cyclodextrins or via other active ingredients, such as zinc ricinoleate.
• (j) liquid aftertreatment agent, preferably spray, for targeted stain (after) treatment

• (a) Vollwaschmittel, (enthält vorzugsweise. Bleichmittel, optische Aufheller, Enzyme usw.)
• (b) Colorwaschmittel, (vorzugsweise enthaltend Verfärbungsinhibitoren, Cellulasen usw.)
• (c) Feinwaschmittel, (vorzugsweise geringere Alkalität),
• (d) Spezialwaschmittel, wie z.B. insbesondere
• i) Wollwaschmittel, (vorzugsweise pH-neutral)
• ii) Gardinenwaschmittel,
• iii) Waschmittel für die Handwäsche,
• iv) Waschmittel mit Zusatznutzen, wie vorzugsweise
• – Waschmittel mit Geruchsabsorber
• – UV-Schutz-Waschmittel,
• – Hygiene-Waschmittel,
• – Bügelerleichterungswaschmittel,
• – Spezialwaschmittel für schwarze oder weiße Wäsche,
• – Sensitiv-Waschmittel, vorzugsweise enthaltend pflegende Substanzen, wie z.B. Mandelöl, Aloe Vera Extrakt usw.
• – Duftintensiv- bzw. Aroma-Waschmittel)

In general, any textile treatment agents, such as detergents or fabric softeners, in liquid as well as in solid form are particularly preferred. Preferred agents according to the invention are therefore detergents. These include in particular:

• (a) heavy-duty detergent, (preferably contains bleach, optical brightener, enzymes, etc.)
• (b) color detergents, (preferably containing discoloration inhibitors, cellulases, etc.)
• (c) mild detergent, (preferably lower alkalinity),
• (d) special detergents, such as in particular
• i) wool detergent, (preferably pH neutral)
• ii) Curtain Detergents,
• iii) detergent for hand washing,
• iv) added-benefit detergent, as preferably
• - Detergent with odor absorber
• - UV protection detergent,
• - hygiene detergent,
• - ironing laundry detergent,
• - special detergent for black or white laundry,
• - Sensitive detergent, preferably containing nourishing substances, such as almond oil, aloe vera extract, etc.
• - scent-intensive or aroma detergent)

To the most preferred cleaning agents include, in particular, hand dishwashing detergents as well as the machine dishwashing detergents.

To the preferred cleaning agents include u. a. the toilet cleaners or toilet cleaner, ie products for cleaning toilet bowls and Urinals, which are preferably as powder, tablets, moldings or Liquids, preferably gels, are offered. In addition to other usual Ingredients such as surfactants contain mostly organic acids (e.g. citric acid and / or lactic acid) or sodium hydrogen sulfate, amidosulfuric acid or phosphoric acid Removal of limescale deposits or so-called primitive stones.

The preferred cleaning agents include, inter alia, the pipe cleaning agent or drain cleaner. These are preferably strongly alkaline preparations, which are usually the elimination of pipe blockages of organic materials - such as hair, fat, food residues, soap deposits, etc. - serve. Additions of Al or Zn powder may serve to form H ₂ gas with a bubble effect. Possible ingredients are commonly alkalies, alkaline salts, oxidizers and neutral salts. In powdered formulations, sodium nitrate and sodium chloride are also preferably included. Pipe cleaners in liquid form may preferably also contain hypochlorite. In addition, there are also drain cleaner on Enzymbasis. Acid preparations are also possible.

To the preferred cleaning agents include u. a. also the universal or all-purpose cleaner or all-purpose cleaner. These are universally applicable Cleaner for all hard surfaces in household and trade, which are wet or damp wipeable. In general, it is neutral or slightly alkaline or weakly acidic products, in particular liquid products. All Purpose cleaner or all-purpose cleaner usually contain surfactants, builders, solvent and hydrotropes, dyes, preservatives, etc.

It also gives special disinfecting all-purpose cleaner. These contain additionally antimicrobial agents (e.g., aldehydes, alcohols, quaternary ammonium compounds, Amphoteric surfactants, triclosan, chlorhexidine, salicylic acid, benzoic acid).

To the preferred cleaning agents include i.a. also the sanitary cleaner. These are products for cleaning in the bathroom and toilet. The alkaline sanitary cleaner are preferably used to remove greasy soil, while the acidic sanitary cleaner especially used for the removal of calcium deposits. Disinfectant cleaner have advantageously also a significant disinfecting effect, in particular the strongly alkaline, chlorine-containing sanitary cleaners.

To the preferred cleaning agents include i.a. also the oven cleaner Grill cleaner, which advantageously in the form of gels or foam sprays are offered. These are usually used for Removal of burned or charred leftovers. Preferably are oven cleaners e.g. with sodium hydroxide, sodium metasilicate, 2-aminoethanol strongly alkaline. Usually included she as well anionic and / or nonionic surfactants, water-soluble solvents and in part thickeners such as polycarboxylates, carboxymethylcellulose.

To the preferred cleaning agents include i.a. also the metal cleaner. These are cleaners for certain types of metal such as stainless steel or silver. stainless steel cleaner contain preferably in addition to acids (preferably up to 3% by weight, for example, citric acid, lactic acid), surfactants (especially to 5% by weight, preferably nonionic and / or anionic surfactants), Water also solvents (preferably to 15% by weight) to remove greasy soils as well as other substances such. As thickeners and preservatives. Very fine polishing body are also in products for preferably shiny stainless steel surfaces contain. Silver cleaning agents, in turn, are preferably acidified. They contain in particular for the removal of black deposits of silver sulfide preferably chelating agents (e.g., thiourea, sodium thiosulfate). Typical offer forms are cleaning cloths, dipping baths, pastes, Liquids. For removing dark discolorations (Oxide layers) serve copper and non-ferrous metal cleaners (e.g., for brass and bronze). These are usually weakly alkaline (preferably adjusted with ammonia) and usually contain polishing agents and preferably also ammonium soaps and / or complexing agents.

To the preferred cleaning agents include i.a. also the glass cleaner or window cleaner. These are preferably for elimination in particular of greasy dirt from glass surfaces. she preferably include substances such as anionic and / or nonionic Surfactants (in particular up to 5% by weight), Ammonia and / or ethanolamine (especially up to 1 wt .-%), ethanol and / or 2-propanol, glycol ethers (especially 10-30% by weight), water, Preservatives, dyes, anti-fogging agents, etc.

To the preferred cleaning agents include i.a. also all special cleaning agents, z. As those for hobs made of glass ceramic, as well as carpet and upholstery cleaner and stain remover.

According to the invention preferred Products are also car care products. Among the preferred car care products counting et al Paint preservatives, paint polishes, paint cleaners, washing preservatives, Shampoo for car wash, Car washes and wax products, polishes for ornamental metals, protective films for decorative metals, Plastic cleaner, tar remover, window cleaner, engine cleaner Etc.

• (a) kosmetische Mittel zur Hautpflege, insbesondere Badepräparate, Hautwasch- u. -reinigungsmittel, Hautpflegemittel, Augenkosmetika, Lippenpflegemittel, Nagelpflegemittel, Intimpflegemittel, Fußpflegemittel, Hautbleichmittel
• (b) kosmetische Mittel mit spezieller Pflegewirkung, insbesondere Lichtschutzmittel, Hautbräunungsmit tel, Depigmentierungsmittel, Desodorantien, Antihidrotika, Haarentfernungsmittel, Rasiermittel, Duftmittel, Fingernagelbleichmittel
• (c) kosmetische Mittel zur Zahnpflege, insbesondere Zahn- u. Mundpflegemittel, Gebißpflegemittel, Zahnprothesenreinigungsmittel, Zahnprothesenhaftmittel, Zahnbleichmittel, Zahnprothesenbleichmittel
• (d) kosmetische Mittel zur Haarpflege, insbesondere Haarwaschmittel, Haarpflegemittel, Haarverfestigungsmittel, Haarverformungsmittel, Haarfärbemittel, Haarbleichmittel.

Preferred cosmetic agents are preferred

• (a) cosmetic skin care products, in particular bath preparations, skin washing u. cleansers, skin care products, ocular cosmetics, lip care products, nail care products, personal care products, foot care products, skin bleaching agents
• (B) cosmetic compositions having a special care effect, in particular light stabilizers, skin tanning agents, depigmenting agents, deodorants, antihidrotic agents, depilatories, shaving agents, fragrances, fingernail bleaches
• (c) cosmetic agents for dental care, in particular dental u. Oral hygiene products, dentifrices, denture cleaners, denture adhesives, dental bleaches, denture bleaches
• (D) cosmetic compositions for hair care, in particular shampoo, hair care products, hair setting agents, hair shaping agents, hair dyes, hair bleach.

preferred Ingredients of the agents according to the invention, especially the cosmetic products, can be defined by their function become. Naturally can some ingredients may also be multifunctional. Preferred ingredients the agents according to the invention, preferably cosmetic products can be:

a) absorbents

These preferably have the task of water and / or oil-soluble dissolved or to absorb finely divided substances.

b) antimicrobials

These can the products are added to the activities of Microorganisms, e.g. on the skin and in the oral cavity.

c) antioxidants

These should serve oxygen-induced reactions such as oxidation to prevent and thus prolong the shelf life of the products, i. the quality of the products.

d) antiperspirants

These are preferably used in cosmetics and reduce the sweat.

e) antifoam

These can be added, e.g. to remove foam during manufacture or to reduce the tendency of finished products to over-foam.

f) anti-dandruff agents

These are used primarily in hair care products as they are can counteract dandruff.

g) antistatic agents

The are e.g. detangler in hair care products. They generally reduce the electrostatic Charging objects, such as the hair surface. hair can be combed so much easier.

h) binders

she guarantee e.g. the cohesion of powdered and powdered products, e.g. cosmetic preparations.

i) substances of biological origin

The are e.g. certain plant ingredients, e.g. Green tea extract. They are intended to give a product certain desired properties, which is related to the corresponding biological material or improve existing properties or unwanted Suppress properties or as far as possible reduce.

j) bleach

These can e.g. serve to lighten the color of the hair or skin.

k) chelating agent

These are used e.g. added to cosmetic products to form complexes with Metal ions form, for example, the stability and / or to manipulate the appearance of the means

l) deodorants / antiperspirants

These can help prevent the development of unpleasant body odors or decreased. You can cover such odors and possibly the formation of perspiration to reduce

m) emollients

These have e.g. In the cosmetic field the task of making the skin supple to make and smooth.

n) emulsifiers / dispersants

in this connection it is surface-active Substances that are preferably capable of immiscible liquids like oil and water stably distributed into each other or the dispersing a powdery one Solid in a liquid Improve medium.

o) emulsion stabilizers

These can the process of Continue to support emulsification (see emulsifiers) and in this way the stability and durability of the product.

p) Depilatory

These serve the preferably selective removal of body hair.

q) moisturizer

These can a contribution to the maintenance or restoration of skin moisture and counteract the drying out of the skin.

r) film former

These are capable of doing so, for example in cosmetic products protective, stabilizing film on surfaces. Preferably skin, hair or nails to create

s) dyes

These are used e.g. also added to cosmetic products to promote product staining generate or even to an indirect object coloration cause, e.g. hair coloring

t) preservatives

These are used e.g. added to cosmetic products to protect them from the damaged Influence of microorganisms (bacteria, fungi, yeasts) to preserve and thus to avoid their spoiling.

u) corrosion inhibitor

These can e.g. serve to prevent corrosion of the package, e.g. a cosmetic To prevent or even the corrosion of parts that otherwise contact the agent.

v) solvent

she can e.g. the basis for for example liquid be cosmetic preparations or else part of solid products be used.

w) oral care

These can the care of teeth and gums serve.

x) oxidizing agent

she can to serve the chemical nature of other substance To change oxidation.

y) pH regulator / buffer substances

These can e.g. in cosmetics to adjust to a desired pH or to stabilize.

z) reducing agent

These are capable of the chemical constitution of another substance to change through redox processes.

aa) abrasives

These can to serve to materials from different (body) surfaces remove, for example, to assist the mechanical cleaning of teeth or to improve the tooth shine.

bb) surfactants / wash-active substances

This are surface-active Compounds used for cleaning purposes.

cc) propellants

This are gaseous Substances with which products, e.g. cosmetic means under pressure in pressure resistant containers can be set to bring the content then at pressure relief.

dd) clouding agent

These one can preferably transparent or translucent products Add to make them more impenetrable to visible light or near-light To make radiation.

ee) UV absorber / light filter substances

she are able to filter certain UV rays and can this way e.g. the skin from premature, light-related aging as well as protect against sunburn.

ff) denaturant

These For example, cosmetic products containing ethanol, added to make them inedible close.

gg) viscosity regulator

These are capable of the viscosity of a product or even decrease.

The aforementioned Ingredients can according to a preferred embodiments in the agents according to the invention, preferably cosmetic agents.

Especially preferred agents are also air fresheners and room fragrancing agents. These agents are used for cleaning, olfactory refining or Improvement (ie the care) of the (room) air. Such products contain volatile and usually pleasant-smelling substances, which advantageously already in very small quantities evil Cover odors can. Air improver for living rooms contain in particular fragrances, such as preferably natural and synthetic essential oils like coniferous needle oils, Citrus oil, eucalyptus oil, lavender oil etc., for example, in amounts of up to 50 wt .-%. Contained as aerosols they rather lower amounts of such essential oils, for example less as 5 wt .-% or less than 2 wt .-%, but preferably still substances such as acetaldehyde (especially <0.5 % By weight), isopropyl alcohol (in particular <5% by weight), mineral oil (in particular <5% by weight) and propellant gases. Other dosage forms are sticks and blocks. In their production It is preferred to use a gel concentrate of essential oils. Advantageously, in addition Formaldehyde (for preservation) and chlorophyll (preferably <5% by weight) be, as well as other ingredients.

Air fresheners are not limited to living spaces, but can also be used for cars, cabinets Ke, dishwashers, refrigerators, shoes and even the application in the vacuum cleaner is possible. In the household (eg in cabinets), for example, in addition to the odor improvers still disinfectants are used which preferably contain substances such as calcium phosphate, talc, stearin and essential oils, for example in the form of sacks.

The inventive agent can be used to scent an object, a surface or a room, preferably of textile fabrics, household surfaces, shoes, waste containers Recycling containers Air, larger household appliances, cat litter, Pets, Pet Beds, in particular of garments, Carpets, carpets, curtains, Curtains, upholstered furniture, bedding, Tents, sleeping bags, Car seats, car carpets, textile car interior linings, Counter tops, walls floors, Bathroom surfaces, Kitchen surfaces, refrigerators, freezers, Washing machines, dishwashers, dryer, ovens and microwave ovens are used directly or indirectly. The agent can be applied in any form, for example by means of a spray applicator sprayed become.

The (preferably modified) titanium dioxide is in the agent according to the invention in amounts of advantageously 0.000001 to 25 wt .-%, preferably 0.01 to 5 wt .-%, based on the total agent. The Lower limit for the (preferably modified) titanium dioxide may also be present at 0.00001 Wt%, 0.00005 wt%, 0.0001 wt%, 0.0005 wt%, 0.001 wt% or 0.005 wt .-%, based on the total agent. The upper limit for the (preferably modified) titanium dioxide may also be present at 20% by weight, 15% by weight, 10% by weight, 5% by weight, 1% by weight, 0.5% by weight, 0.1% by weight, 0.05% by weight, 0.01% by weight, 0.005% by weight, 0.001% by weight, 0.0005% by weight, 0.0001% by weight, 0.00005% by weight, 0.00001 wt .-% or 0.000005 wt .-%, based on the total Medium.

The in the agent according to the invention contained, preferably modified titanium dioxide can advantageously a particle size in the range between 2 to 600 nm, e.g. 3 to 150 nm or e.g. 4 to 100 nm or e.g. 5 to 75 nm or e.g. 10 to 30 nm or e.g. 200 to 400 nm. The particle size of preferably Although modified titanium dioxide may preferably in the range of of 100-500 nm, advantageously 200-400 nm. It can also it may be preferred that the particle size is very small, e.g. in the Range of 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or e.g. 5-50 nm or e.g. 8-30 nm or e.g. 10-20 nm. The particle size can e.g. advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Especially very small particle sizes below 50 nm, below 40 nm, below 30 nm or below 20 nm may be preferred.

It may be advantageous in the preparation of the modified titanium dioxide micronized titanium dioxide, that is, titanium dioxide with very small particle size, e.g. between 2 and 150 nm or z.b. between 5 and 100 nm. The particle size can then e.g. advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The BET specific surface area for the preferably modified titanium dioxide is advantageously 50-500 m ² / g, preferably 100 to 400 m ² / g, more preferably 200 to 350 m ² / g, in particular 250 to 300 m ² / g ,

The bulk density of the preferably modified titanium dioxide is preferably in Range from 100 to 800 g / l, advantageously from 200 to 600 g / l, in particular from 300-500 g / l. For example, the bulk density 350 g / l, 400 g / l or 500 g / l.

To a preferred embodiment it is the (preferably modified) titanium dioxide a carbon-modified titanium dioxide. But it can also differently modified titanium dioxides are used, for example nitrogen-modified titanium dioxide or e.g. with rhodium and / or Platinum ions doped titanium dioxide. However, it is particularly according to the invention preferably that it is non-metal modified titanium dioxide is.

The carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt. -%, in particular from 0.4 to 0.8 wt .-% are. Advantageously, the TiO ₂ content of the carbon-modified titanium dioxide is, for example, more than 95% by weight, 96% by weight, 97% by weight, 98% by weight or 99% by weight, based on the total with carbon modified titanium dioxide.

If the carbon is incorporated only in a surface layer of the titanium dioxide particles, so is a preferred embodiment. The modified titanium dioxide may advantageously additionally contain nitrogen.

If the specific surface of the titanium dioxide, preferably of the modified titanium dioxide, according to BET (BET advantageously determined according to DIN ISO 9277: 2003-05, preferably also simplified according to DIN 66132: 1975-07) preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in a further advantageous manner 200 to 350 m ² / g, in particular 250 to 300 m ² / g, so is also a preferred embodiment.

The carbon-modified titanium dioxide can be obtained according to a preferred embodiment, for example, by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m ² / g according to BET, with an organic carbon compound and the mixture at a temperature of up to is thermally treated to 350 ° C.

The thereby usable carbonaceous substance can according to a preferred Embodiment one Be carbon compound, which is at least one functional group contains preferably selected from OH, CHO, COOH, NHx, SHx. In particular, it may be in the carbon compound a compound from the group of ethylene glycol, glycerol, succinic acid, pentaerythritol, Carbohydrates, sugar, starch, Alkyl polyglucosides, organoammonium hydroxides or mixtures thereof act. It is also possible, used as the carbonaceous substance soot or activated carbon becomes.

It may also be preferred that the carbonaceous substance, which is advantageously mixed with the titanium compound, after the thermal treatment to the modified titanium dioxide to reach a decomposition temperature of at most 400 ° C, preferably <350 ° C. and particularly preferably <300 ° C.

The Preferably used for the preparation of the modified titanium dioxide Titanium compound, which according to above said preferred embodiment is intimately mixed with an organic carbon compound, may be an amorphous, semi-crystalline or crystalline titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate which in turn corresponds to a preferred embodiment.

The thermal treatment of the mixture of the titanium compound and the Carbon compound can according to a preferred embodiment advantageously in a continuously operated calcining unit, preferably a rotary kiln are performed.

The modified titanium dioxide can be, especially in the context of what has been described above, preferably e.g. obtained by using a titanium dioxide (for example having a particle size in the range between 2 to 600 nm or e.g. 3 to 150 nm or or e.g. 4 to 100 nm or e.g. 5 to 75 nm or e.g. 10 to 30 nm or e.g. 200 to 400 nm), such as commercially available available in powder or mud form, takes and from this a suspension in a liquid, as preferably water, produces. To the suspension is then advantageously added a carbonaceous substance and it is mixed. The mixing can be supported by the use from ultrasound. The mixing process (e.g., stirring) may preferably be several Hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer.

Based on the solids of the suspension is the amount of the carbon compound advantageously 1-40 wt .-%, accordingly, the amount of the titanium compound preferably 60-99% by weight.

After that becomes the liquid removed, for example by filtration, evaporation in vacuo or Decant, and the residue is preferably dried (e.g., preferably at temperatures of 70-200 ° C, advantageously over several Hours, for example at least 12 hours)) and then calcined, for example at a temperature of at least 260 ° C, preferably e.g. at 300 ° C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours. The calcination can advantageously be in a closed Vessel take place.

It may be advantageous that the Calcining temperature, e.g. 300 ° C, within one hour (slow heating to 300 ° C).

In this case, a color change of the powder from white to dark brown to beige or slightly yellowish-brownish is preferably observed. Too long a heating leads to inactive, colorless powders. The expert can estimate this with a few routine experiments. The calcination can, for example, advantageously for so long take place until after a color change of the powder from white over dark brown another color change on beige or slightly yellow-brownish statfindet.

A maximum temperature of 350 ° C should preferably not be exceeded become. Thermal treatment causes decomposition the organic carbon compound on the surface of the Titanium compound, so that preferably a modified titanium dioxide arises, which preferably contains 0.005-4 wt .-% carbon.

After the thermal treatment, the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill. The grain fineness to be achieved depends on the grain size of the starting titanium compound. The particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt. The desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as with TiO ₂ pigments, but may also be below or above.

The Particle size of the modified Titanium dioxide may preferably be in the range of 2-600 nm, preferably in the range of 100-500 nm, advantageously 200-400 nm. It can It may also be preferred that the particle size is very small, e.g. in the Range of 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or e.g. 5-50 nm or e.g. 8-30 nm or e.g. 10-20 nm.

It may be advantageous in the preparation of the modified titanium dioxide micronized titanium dioxide, that is, titanium dioxide with very small particle size, e.g. between 2 and 150 nm or z.b. between 5 and 100 nm. The particle size can then e.g. advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The BET specific surface area for the preferably modified titanium dioxide is advantageously 50-500 m ² / g, preferably 100 to 400 m ² / g, more preferably 200 to 350 m ² / g, in particular 250 to 300 m ² / g ,

The bulk density of the preferably modified titanium dioxide is preferably in Range from 100 to 800 g / l, advantageously from 200 to 600 g / l, in particular from 300-500 g / l. For example, the bulk density 350 g / l, 400 g / l or 500 g / l.

To a preferred embodiment is the (preferably modified) titanium dioxide in the crystal modification Anatas in front.

a Another object of the invention is a method of treatment a textile, comprising contacting the textile with a inventive washing, Care or cleaning agent, at and / or followed by exposure the surface of the treated substance to light having a wavelength in the range from 300-1200 nm, preferably 400-800 nm. For a preferred unfolding the effectiveness of the photobleach is the presence of preferably Oxygen and / or water (for example, from air, ie air humidity) required. That's enough e.g. the dissolved oxygen present in water or the in the moisture dissolved Oxygen or atmospheric oxygen. The exposure can also be in one Treatment bath done.

This Method offers the benefits of photodiode, a good one Color and textile protection, a general substrate protection. In addition, will the removal of stains from the treated tissue considerably improved. For clarification, it should be noted that in the process according to the invention usable liquid Washing, care or cleaning agents only from the components (preferably modified) titanium dioxide and solvent, preferably comprising Water, can exist. Advantageously, in such liquid washing, care or Detergents but also surfactants and optionally further, optional Contain ingredients. Possible Ingredients that can be used in the process will continue described below.

a Another object of the invention is a method of treatment hard surfaces, comprising the contacting of the hard surface with a washing, Care or cleaning agent, at and / or followed by exposure the surface at light with one wavelength in the range of 300-1200 nm, preferably 400-800 nm. For a preferred Deployment of the effectiveness of the photobleach is the presence preferably oxygen and / or water (for example from air, ie Humidity) required. For this purpose it suffices e.g. the present in water, dissolved Oxygen or oxygen or atmospheric oxygen dissolved in the moisture. The exposure can also be done in a treatment bath.

Also this procedure offers the benefits of photodisinfection and a general substrate protection, as well as a good color and material protection the treated surface. The removal of stains from the treated surface will significantly improved.

a Another object of the invention is a method for cosmetic Treatment of the human body, comprising the contacting of body parts (for example skin, hair, Teeth) with a washing, Care or cleaning agent, at and / or followed by exposure the surface at light with one wavelength in the range of 300-1200 nm, preferably 400-800 nm. For a preferred Deployment of the effectiveness of the photobleach is the presence preferably oxygen and / or water (for example from air, ie Humidity) required. For this purpose it suffices e.g. the dissolved oxygen present in water or dissolved in moisture Oxygen or atmospheric oxygen. The exposure can also be in one Treatment bath done. This procedure is also very gentle.

a Another object of the invention is a method for improvement the (room) air comprising contacting air (e.g. spraying) with a washing, Care or cleaning agents, containing at least one fragrance, such as, preferably, essential oil, at and / or followed by irradiation with light having a wavelength in the range from 300-1200 nm, preferably 400-800 nm. For the development of efficacy the photobleach is the presence of preferably oxygen and / or Water (for example from air, ie air humidity) required. For this purpose it suffices e.g. the dissolved water present in water Oxygen or oxygen or atmospheric oxygen dissolved in the moisture.

to Clarification should also be noted here that in the inventive method usable liquid Washing, care or cleaning agents only from the components (preferably modified) titanium dioxide and solvent may exist. Only in the method for improving the (room) air is as additional Component mandatory fragrance, preferably essential oil present. Advantageously way are in liquid Detergents, care or cleaning agents but also surfactants and if necessary other, optional ingredients included. Possible ingredients in The method can be used, are described below.

The inventive washing, Care or cleaning agents can in addition to the (preferably modified) titanium dioxide further ingredients contain. It should be noted that under the concept of care products also the conditioners fall.

To a preferred embodiment has the washing according to the invention, Care or cleaning agent next to the (preferably modified) Titanium dioxide at least one other, preferably several ingredients on, in particular washing, care and / or cleaning active ingredients, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, Alkalizing agents, anti-crease compounds, antibacterial agents, Antioxidants, anti redeposition agents, antistatic agents, builders, Bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, Ironing aids, Co-builders, dispersants, anti-shrinkage agents, electrolytes, enzymes, Colorants, colorants, Dyes, color transfer inhibitors, Fluorescers, fungicides, germicides, odor-complexing substances, Aids, Hydrotropes, Rinse Aids, Complexing agents, preservatives, corrosion inhibitors, optical Brightener, perfume carrier, pearlescing agent, pH adjuster, Phobic and impregnating agents, Polymers, fragrance (s) (perfume (oil)), source and Slip Resists, Foam Inhibitors, Phyllosilicates, Dirt Repellent Fabrics, silver protectants, silicone oils, UV protectants, viscosity regulators, Thickeners, discoloration inhibitors, Grayness inhibitors, vitamins and / or fabric softeners.

In the following preferred ingredients of the inventive compositions are described in detail. Anionic surfactants are preferably contained in the agents according to the invention. As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids are suitable.

Further suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters and mixtures thereof, as obtained in the preparation by esterification of a monoglycerol with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol. Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₈ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants.

The sulfuric acid monoesters of straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11- alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 . Fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are preferably used only in relatively small amounts, for example in amounts of from 1 to 5% by weight, in detergents in particular. The agents according to the invention may preferably be free of sulfuric acid monoester.

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by the reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: R ¹⁰ O- (CH ₂ -CH ₂ -O) _p -CH ₂ -COOH with R ¹⁰ = C ₁ -C ₁₈ and p = 0.1 to 20. Ethercarbonsauren are water hardness insensitive and have excellent surfactant properties on.

suitable anionic surfactants are, for example, the partial esters of Di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the EO adducts of maleic anhydride at least monounsaturated carboxylic acids with a chain length from 10 to 25 carbon atoms with an acid number of 10 to 140.

preferred anionic surfactants have, in addition to an unbranched or branched, saturated or unsaturated, aliphatic or aromatic, acyclic or cyclic, optional alkoxylated alkyl radical having 4 to 28, preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferably 12 to 14 carbon atoms, two or more anionic, in particular two, acid groups, preferably carboxylate, Sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group. Examples of these compounds are the alpha-sulfofatty acid salts, the acylglutamates, the monoglyceride disulfates and the alkyl ethers Glycerindisulfats and in particular those described below monoesterified sulfosuccinates.

Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,

at the salts are preferably alkali metal salts, ammonium salts and mono-, di- or Trialkanolammoniumsalze, for example, mono-, Di- or triethanolammonium salts, in particular to lithium, sodium, Potassium or ammonium salts, more preferably sodium or ammonium salts, most preferably Sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having an alkoxyly degree of from 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurylpolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic acid preferably with a primary or secondary Amin, one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals with 4 to 22, preferably 6 to 20, especially 8 to 18, especially preferably 10 to 16, most preferably Bears 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or Acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated according to INCI: ammonium dinonyl sulfosuccinates, ammonium lauryl sulfosuccinates, diammonium dimethicone copolyol sulfosuccinates, diammonium lauramido-MEA sulfosuccinates, diammonium lauryl sulfosuccinates, diammonium oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium Cocamido Glucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 sulfosuccinates, disodium C12-15 pareth sulfosuccinates, disodium deceth-5 sulfosuccinates, disodium deceth-6 sulfosuccinates, disodium dihydroxyethyl sulfosuccinyl undecylenates, disodium dimethi Disodium Isostearamido MEA Sulfosuccinate, Disodium Isostearamido MIPA Sulfosuccinate, Disodium Isostearyl Sulfosuccinate, Disodium Laneth-5 Sulfosuccinate, Disodium Lauramido MEA Sulfosuccinate, Disodium Lauramido PEG-2 Sulfosuccinate, Disodium Lauramido PEG-5 Sulfosuccinate, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA Sulfosuccinate, Disodium Oleamido MIPA- Sulfosuccinates, disodium oleamido PEG-2 sulfosuccinates, disodium oleth-3 sulfosuccinates, disodium oleyl sulfosuccinates, disodium palmitamido PEG-2 sulfosuccinates, disodium palmitoleeamido PEG-2 sulfosuccinates, disodium PEG-4 cocamido MIPA sulfosuccinates, disodium PEG-5 lauryl citrate sulfosuccinates, disodium PEG-8 Palm Gl Disodium Stearyl Sulfosuccinate, Disodium Stearyl Sulfosuccinate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccinate, Disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido, Disodium Stearamido MEA Sulfosuccinate, Disodium Stearamido MEA Sulfosuccinate, Disodium Undecylenamdo PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA-Ole-amido PEG-2 Sulfosuccinate, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth-2 Sulfosuccinate and Tetrasodium Dicarboxyethyl Stearyl Sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Another suitable class of compounds are anionic surfactant-cation complexes, the cation itself initially having surfactant properties. Examples are transesterification products of LAS acid with amines, amine derivatives containing a C chain with> 2 C atoms, preferably C ₁₂ -C ₁₆ . These can be oxidized, for example, on the nitrogen, ie for example transesterification of LAS acid with amine oxide C _12-14 .

The content of anionic surfactants in the composition according to the invention, preferably of the anionic surfactants mentioned, can vary within wide ranges, depending on the purpose of the agent in question. Sc, an agent according to the invention may contain very large amounts of anionic surfactant, preferably up to an order of magnitude of up to 40, 50 or 60% by weight or more. Likewise, an agent according to the invention may contain only very small amounts of anionic surfactant, for example less than 15 or 10% by weight or less than 5% by weight or even less. However, anionic surfactants are advantageously present in the compositions according to the invention in amounts of from 0.1 to 40% by weight and in particular from 5 to 30% by weight, with concentrations above 10% by weight and even above 15% by weight being particular Find favor. According to a preferred embodiment, the agent according to the invention contains anionic surfactants, preferably in amounts of at least 0.01% by weight, based on the total agent. According to another preferred Ausfüh The agent according to the invention may be free from anionic surfactant.

In addition to the said anionic surfactants, but also independent of these, can in the inventive compositions Soaps should be included. Particularly suitable are saturated fatty acid soaps, like the salts of lauric acid, myristic, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid as well in particular of natural fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures. The content of the agent in soaps is, independently of other anionic surfactants, preferably not more than 3% by weight and in particular from 0.5 to 2.5 Wt .-%, based on the total agent. After another preferred embodiment is the agent of the invention of soap.

The anionic surfactants and soaps in the form of their sodium, potassium or ammonium salts and as soluble salts organic bases, such as mono-, di- or triethanolamine. Preferably, they are in the form of their sodium or potassium salts, especially in the form of the sodium salts. Anionic surfactants and Soaps can also be prepared in situ by being spray dried Composition of the anionic surfactant acids and optionally fatty acids are introduced, which then by the alkali carriers in the spray-drying Composition be neutralized.

advantageously, can nonionic surfactants may also be present in the compositions according to the invention, both solid and liquid Means. For example, their content may be up to 2 or 3 or 5 wt .-%. It can also larger quantities be contained in nonionic surfactant, for example up to 5 wt .-% or 10% by weight or 15% by weight or 20% by weight, 30% by weight, 40% by weight, 50% by weight or even above out, if appropriate. Meaningful lower limits can at values of 0.01, 0.1, 1, 2, 3 or 4 wt .-% are.

Preferably However, the nonionic surfactants are in larger quantities, ie up to 50 Wt .-%, advantageously from 0.1 to 40 wt .-%, more preferably from 0.5 to 30 and in particular from 2 to 25 wt .-%, each based on the entire remedy, included. According to a preferred embodiment contains that inventive agent nonionic surfactants, preferably in amounts of at least 0.1 Wt .-%, based on the total agent. After another preferred embodiment can the agent of the invention be free of nonionic surfactant.

advantageously, can all known from the prior art nonionic surfactants in the inventive compositions be included. Preferred nonionic surfactants are presented below.

The inventive cleaning, Care and detergent, can preferably also contain cationic surfactants. Suitable cationic surfactants are, for example, surface-active quaternary Compounds, in particular with an ammonium, sulfonium, phosphonium, Iodonium or arsonium group. Through the use of quaternary surface active Compounds with antimicrobial activity may be the agent with a antimicrobial effect be designed or its optionally due to other ingredients already existing antimicrobial Effect can be improved.

Particularly preferred cationic surfactants are the quaternary, partially antimicrobial ammonium compounds (QAV, INCI quaternary ammonium compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _1-22 alkyl radicals C _7-28 aralkyl radicals or heterocyclic radicals, where two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, for example a pyridinium or Imidazoliniumverbindung , form, represent and X ^{- are} halide ions, sulfate ions, hydroxide ions or similar anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are tertiary by implementation Amines with alkylating agents, e.g. Methyl chloride, benzyl chloride, Dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, also the quaternization of tertiary amines with two long residues and one methyl group can help with Methyl chloride be carried out under mild conditions. Amines, over three long alkyl radicals or hydroxy-substituted Have alkyl radicals, are less reactive and are preferably quaternized with dimethyl sulfate.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390 -78-6), benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N-dimethyl-N- [2- [2- [p- (1,1,3, 3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n-decyl-dimethylammonium chloride (CAS No. 7173-51-5-5) , Didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyl-dimethyl-ammonium chloride, 1-cetylpyridinium chloride (CAS No. 123-03-5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities the antimicrobial cationic surfactants with in the agent according to the invention anionic surfactants contained as possible anionic surfactant and / or possibly as possible little cationic surfactant used or in a particular embodiment the invention entirely dispensed with cationic surfactants.

Further below will be particularly related to conditioning agents and plasticizers further cationic surfactants, including quaternary ammonium compounds described. These too can preferably in the inventive compositions be included.

The inventive cleaning, Care or detergent, can contain one or more cationic surfactants, advantageously in amounts, based on the total composition, from 0 to 30% by weight, even more advantageously greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5 Wt .-%. Suitable minimum values can also at 0.5, 1, 2 or 3 wt .-% are. According to a preferred embodiment contains the agent of the invention cationic surfactants, preferably in amounts of at least 0.1% by weight, based on the total mean. According to another preferred embodiment the agent of the invention be free from cationic surfactant.

As well can the cleaning invention, Care or detergent, also containing amphoteric surfactants. These will be discussed below in particular in connection with conditioning agents and plasticizers even closer described.

The inventive cleaning, Care or detergent can contain one or more amphoteric surfactants, advantageously in amounts, based on the total composition, from 0 to 30% by weight, even more advantageously greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5 Wt .-%. According to another preferred embodiment, the agent according to the invention free from amphoteric surfactants.

To a particular embodiment can the agents according to the invention contain only very little total surfactant, e.g. can the total amount of surfactant below 20% by weight, 15% by weight, 10% by weight or 5% by weight, advantageously even below 3 wt .-% or below 1 wt .-%, in particular even below 0.5 wt .-% or less than 0.1 wt .-%, wt .-% in each case on the entire remedy. Preferably, however, the total surfactant content is at least 0.01 wt .-%, 0.1 wt .-% or 1 wt .-%, based on the entire means.

Further Ingredients of the agents according to the invention can be inorganic and organic builders. To the inorganic ones Builders include water or non-water soluble ingredients, such as aluminosilicates and especially zeolites.

In a preferred embodiment contains the agent of the invention no phosphate and / or no zeolite. But it is also possible that the agent contains zeolite. It may then be preferred that this zeolite content, based on the total weight of the agent, less than 5% by weight, preferably at most 4 wt .-%, at most 3 wt .-% or at most 2 wt .-% is.

It but can also be advantageously provided that the inventive agent a zeolite content of at least 10% by weight, e.g. at least 15 Wt .-% or at least 20 wt .-% or at least 30 wt .-% or also about it In addition, for example, at least 50 wt .-% has.

Soluble builders may preferably contain the agent according to the invention in amounts of 0.1% by weight to 30% by weight, preferably 5% by weight to 25% by weight and particularly preferably 10% by weight to 20% by weight. , based on the total weight of the agent, with sodium carbonate as the soluble builder being particularly preferred. However, it can also be advantageously provided that the agent according to the invention contains less than 10% by weight, for example less than 5% by weight, of soluble builder. Citrates, for example, are suitable, SKS-6, citric acid, MGDA (methyl glycine di-acetic acid), triphosphates, phosphonates, aliphatic dicarboxylic acids (eg adipic, glutaric, succinic). In another preferred embodiment, the agent of the invention may be free of soluble builder.

Useful finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P zeolite MAP ^® (commercial product from Crosfield) is particularly preferred. Also suitable however are zeolite X and mixtures of A, X and / or P. Of special interest is also a co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, which as VEGOBOND AX ^® (a product of Condea August SpA) Trade is available. This product is described below. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols with 2 bis 5 ethylene oxide groups, C ₁₂ -C ₁₄ fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of preferably less than 10 microns (volume distribution, measuring method: Counter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.

When other particularly suitable zeolites are zeolites of the faujasite type to call. Together with the zeolites X and Y belongs the mineral Faujasite to the faujasite types within the zeolite structure group 4, which are characterized by the double-six-membered subunit D6R. To zeolite structure group 4 count beside the minerals chabazite and gmelinite mentioned in the faujasite types as well as the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-5. The latter two synthetic zeolites have none mineral analogues.

Faujasite-type zeolites are composed of β-cages linked by tetrahedral D6R subunits, with the β-cages resembling the carbon atoms in the diamond. The three-dimensional network of the faujasite-type zeolites useful in the present invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 wells of about 13 Å in diameter, and can be represented by the formula Na ₈₆ [(AlO ₂ ). ₈₆ (SiO ₂ ) ₁₀₆ ] · 264 H ₂ O describe. The network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y: about 48% void volume, faujasite: about 47% void volume).

in the In the context of the present invention, the term "faujasite-type zeolite" denotes all three zeolites, which form the faujasite subgroup of the zeolite structure group 4. In addition to zeolite X, the invention also includes zeolite Y and faujasite as well as mixtures of these compounds, the pure zeolite X is preferred.

Also Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, not necessarily the zeolite structure group 4 belong have to, are suitable according to the invention wherein preferably at least 50 wt .-% of the zeolites of the faujasite type are.

The suitable aluminum silicates are commercially available, and the methods for their presentation are in standard monographs described.

Examples of commercially available X-type zeolites can be described by the following formulas: Na ₈₆ [(AlO ₂ ) 86 (SiO ₂ ) ₁₀₆ ] xH ₂ O, K ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Ca ₄₀ Na ₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Sr ₂₁ Ba ₂₂ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, where x can take values greater than 0 to 276. These zeolites have pore sizes of 8.0 to 8.4 Å.

Suitable, for example, zeolite A-LSX corresponding to a co-crystallizate of zeolite X and zeolite A, and in its anhydrous form the formula: (M _{2 / n} O + M _{'2 / n} O) · Al ₂ O ₃ · ZSiO ₂ where M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. Commercially available this product is under the brand name VEGOBOND AX by the company CONDEA Augusts SpA

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas Na ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] .xH ₂ O, K ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] xH ₂ O, where x is numbers greater than 0 to 276. These zeolites have pore sizes of 8.0 Å.

The particle sizes of the suitable zeolites are advantageously in the range of 0.1 μm to at 100 μm, preferably from 0.5 μm to 50 μm and in particular from 1 μm to 30 μm, each measured by standard particle size determination methods. In another preferred embodiment, the agent of the invention may be free of zeolite.

In a preferred embodiment The invention is intended to contain all inorganic constituents preferably water-soluble be. In these embodiments Therefore, other builders than the mentioned zeolites used.

Further Suitable builders are polyacetals, which by reaction of dialdehydes with polyol carboxylic acids containing 5 to 7 carbon atoms and at least 3 hydroxyl groups can be obtained. preferred Polyacetals are made from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic receive.

Further suitable organic builder substances are dextrins, for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches. The hydrolysis can be carried out by customary, for example acid or enzyme catalyzed processes. Preferably, it is hydrolysis products having average molecular weights in the range of 400 to 500,000 g / mol. In this case, a polysaccharide with a dextrose equivalent (DE) in the range from 0.5 to 40, in particular from 2 to 30 is preferred, DE being a common measure of the reducing effect of a polysaccharide compared to dextrose, which has a DE of 100 , is. Usable are both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 and so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30,000 g / mol. A preferred dextrin is in the British Patent Application 94 19 091 described. The oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.

Also Oxydisuccinates and other derivatives of disuccinates, preferably Ethylenediamine disuccinate are other suitable cobuilders. there becomes ethylenediamine-N, N'-di-succinate (EDDS) preferably used in the form of its sodium or magnesium salts. Also preferred in this context are glycerol disuccinates and glycerol trisuccinates. Suitable amounts are, for example at 3 to 15 wt .-%, based on the total agent.

Further useful organic cobuilders are, for example, acetylated hydroxy or their salts, which may also be present in lactone form can and which at least 4 carbon atoms and at least one hydroxy group and a maximum of two acid groups contain.

A another substance class with cobuilder properties are the phosphonates These are in particular hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkane phosphonates is 1-hydroxyethane-1,1-diphosphonate (HEDP) of particular importance as a co-builder. It is preferably used as the sodium salt, wherein the disodium salt neutral and the tetrasodium salt is alkaline (pH 9). As aminoalkanephosphonates preferably ethylenediamine tetramethylenephosphonate (EDTMP), Diethylentriaminpentamethylenphosphonat (DTPMP) and their higher homologues in question. They are preferably in the form of neutral reacting Sodium salts, e.g. as the hexasodium salt of EDTMP or hepta- and octa-sodium salt of DTPMP. As a builder will be there from the class of phosphonates preferred HEDP used. The aminoalkane phosphonates also have a pronounced Heavy metal binding capacity. Accordingly, it may, especially if the means also bleach be preferred, Aminoalkanphosphonate, in particular DTPMP, to use or mixtures of the phosphonates mentioned.

In cases In which a phosphate content is tolerated, phosphates can also be used especially pentasodium triphosphate, if appropriate Pyrophosphates and orthophosphates, primarily as precipitants for lime salts Act. Phosphates become predominant in automatic dishwashing detergents, partly but also used in detergents.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as a dihydrate (density 1.91 gcm ^-3 , melting point 60 °) and as a monohydrate (density 2.04 gcm ^-3 ). Both salts are white powders which are very soluble in water and which lose their water of crystallization when heated and at 200 ° C into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below). NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (potassium phosphate or potassium phosphate monobasic potassium phosphate, KDP), KH ₂ PO ₄ , is a white salt of 2.33 gcm ^-3 , has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _x ] and is light soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 mol. (Density 2.066 gcm ^-3 , water loss at 95 °), 7 mol (density 1.68 gcm ^-3 , melting point 48 ° with loss of 5 H ₂ O) and 12 mol. Water (density 1.52 gcm ^-3 , melting point 35 ° with the loss of 5 H ₂ O), becomes anhydrous at 100 ° C. and on more intense heating passes into the diphosphate Na ₄ P ₂ O ₇ . Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Di-potassium hydrogen phosphate (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals which have a density of 1.62 gcm ^-3 as dodecahydrate and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 gcm ^-3 . Trisodium phosphate is readily soluble in water under alkaline reaction and is prepared by evaporation of a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH. Tripotassium phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 gcm ^-3 , has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It arises, for example, when heating Thomasschlacke with coal and potassium sulfate. Despite the higher price, the more soluble, therefore highly effective, potassium phosphates are often preferred over the corresponding sodium compounds in the detergent industry.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 gcm ^-3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1.815-1.836 gcm ^-3 , melting point 94 ° with loss of water) , Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed on heating of disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dewatering the solution by spraying. The decahydrate complexes heavy metal salts and hardness agents and therefore reduces the hardness of the water. Potassium diphosphate (potassium pyrophosphate), K ₄ P ₂ O ₇ , exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 gcm ^-3 , which is soluble in water, the pH being 1% Solution at 25 ° 10.4.

Condensation of the NaH ₂ PO ₄ or the KH ₂ PO ₄ results in higher molecular weight sodium and potassium phosphates, in which one can distinguish cyclic representatives, the sodium or potassium metaphosphates and chain types, the sodium or potassium polyphosphates. In particular, for the latter are a variety of names in use: hot or cold phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ O ₁₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphosphat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example, in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH: (NaPO ₃ ) ₃ + 2 KOH → Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are exact according to the invention such as sodium tripolyphosphate, potassium tripolyphosphate or mixtures can be used from these two; also mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate used according to the invention.

In a preferred embodiment of the invention are in particular as inorganic builder substances Carbonates and silicates used.

Particularly noteworthy here are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2x + 1} .yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added to the direct or post-treated spray-drying product. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Such compounds are commercially available, for example, under the name ^SKS® (from Clariant). Thus, it is SKS-6® is primarily a δ-sodium having the formula Na ₂ Si ₂ O ₅ · yH ₂ O, SKS-7 ^® primarily the 11-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) gives kanemite NaHSi ₂ O ₅ .yH ₂ O, commercially available under the names SKS- ^9® and SKS- ^10® (from Clariant) from the δ-sodium disilicate. It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have altered crystal morphologies in comparison with the δ-sodium disilicate, dissolve more rapidly and show increased calcium binding capacity in comparison with δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula x Na ₂ O.y SiO ₂ .z P ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z a number of 1.75 to 1200 and the ratio y to z of a number of 4 to 2800 is known. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. Also compounds from the crystalline layer silicates with other ingredients can be used. In particular, compounds with cellulose derivatives which have advantages in the disintegrating action, and compounds with polycarboxylates, for example citric acid, or polymeric polycarboxylates, for example copolymers of acrylic acid, may be mentioned.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which likewise have a dissolution delay compared with the conventional water glasses, are known. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates. The content of the (X-ray) amorphous silicates in particular zeolite-free compositions is preferably 1 to 10 wt .-%, which corresponds to a preferred embodiment of the invention.

Especially preferred inorganic water-soluble Builders are alkali metal carbonates and alkali metal bicarbonates, wherein sodium and potassium carbonate and especially sodium carbonate to the preferred embodiments counting. The content of the alkali metal carbonates in particular zeolite-free Means can vary within a very wide range and is preferably 1 to 50 wt .-%, advantageously 5 to 40 wt .-%, in particular 8 to 30 wt .-%, where usually the content of alkali metal carbonates is higher than on (X-ray) amorphous Silicates. According to another preferred embodiment, the agent according to the invention be free of alkali metal carbonates.

Useful organic builders are, for example, usable in the form of their alkali and especially sodium saize polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, Am inocarbonsäuren, nitrilotriacetic acid (NTA), if such a rate is not objectionable for environmental reasons, as well as mixtures of these. Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures thereof. The acids themselves can also be used. In addition to their builder action, the acids also typically have the property of an acidifying component and thus also serve, for example in the granules according to the invention, for setting a lower and milder pH of detergents, cleaners and cleaners. In particular, citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any desired mixtures of these can be mentioned here.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

The agents according to the invention can also contain polymers, in particular as a carrier for the perfume oils. Suitable polymers which also as carriers may be used in conjunction with perfume include in particular Polyacrylates, which preferably has a molecular weight of 2,000 to 20,000 g / mol exhibit. Because of their superior solubility can from this group again the short-chain polyacrylates, the molecular weights from 2,000 to 10,000 g / mol, and more preferably from 3,000 to 5,000 g / mol, be preferred.

Suitable are furthermore copolymeric polycarboxylates, especially those of acrylic acid with methacrylic acid and the acrylic acid or methacrylic acid with maleic acid. Particularly suitable are copolymers of acrylic acid with maleic which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid. Your molecular weight, based on free acids, is in general from 2000 to 70000 g / mol, preferably from 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

Of the Content of the organic builder substances can be in one vary wide frame. Preference is given to contents of from 2 to 20% by weight, in particular, contents of not more than 10% by weight are particularly popular Find. According to another preferred embodiment, the agent according to the invention be free of organic builders.

It It should be noted at this point that the statement wt .-%, Unless otherwise indicated, each to the entire mean refers.

The agents according to the invention can Components from the classes of the grayness inhibitors (dirt carrier), the Neutral salts and / or the fabric softening aids (for example Cationic surfactants), which is preferred.

graying have the task of removing the dirt from the fiber in the fleet to keep it suspended, thus allowing the dirt to be recovered prevent. These are water-soluble Colloids mostly organic nature suitable, for example, the water-soluble Salts of polymeric carboxylic acids, glue, Gelatin, salts of ether carboxylic acids or ether sulfonic acids of Strength or the cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are suitable for this purpose. Farther can be soluble Starch preparations and other than the starch products mentioned above use, e.g. degraded starch, aldehyde etc .. Also, polyvinylpyrrolidone is useful. However, preference is given Cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxy-methylcellulose and their mixtures, and polyvinylpyrrolidone, for example, in amounts of preferably 0.1 to 5 wt .-%, based on the agents used.

When typical example of a suitable representative of neutral salts is sodium sulfate to call. It can be used in amounts of, for example, 0 to 60% by weight, preferably 2 to 45 wt .-% are used.

Suitable plasticizers, which are described in more detail below, are, for example swellable phyllosilicates of the type of montmorillonites, for example bentonite, as well as cationic surfactants.

Of the Content of water on average depends i.a. after that, whether the means in liquid or solid form is Therefore, preferably 0 to less than 100 wt .-% and in particular 0.5 to 95 wt .-%, with values of at most 5 wt .-% in particular for solid or non-aqueous liquids find special preference. Not included was this in the case of solid agents, the optionally present aluminosilicates like zeolite adhering water.

in the Trap liquid Contains funds the agent of the invention according to a preferred embodiment, water in an amount of more than 20% by weight, advantageously more than 30 wt .-%, more preferably more than 40 wt .-%, still more preferably more than 50% by weight, in particular 60 to 99% by weight, more preferably 70 to 98% by weight and most preferably 80 to 95% by weight, based on the total mean.

The The upper limit of water may also be 80% by weight, 70% by weight, 60% by weight, 50 wt%, 40 wt%, 30 wt%, 20 wt%, or 10 wt% wt% relative to the entire remedy.

The Lower limit of water may e.g. even at 80 wt%, 70 wt%, 60 Wt%, 50 wt%, 40 wt%, 30 wt%, 20 wt% or 10 wt% relative to the entire remedy.

The mentioned upper and lower limits can of course be meaningfully combined, e.g. to water contents of 60-80 wt.% or 10-30 wt.%, etc.

The inventive agent can, if it is a solid, an excellent trickling exhibit. According to a preferred embodiment, the agent according to the invention essentially solid preferably in powdered, pressed or granular form in front.

Lies the agent in particulate Form before, so can the particles are post-treated, for example by the Particles of the agent rounded. The rounding can be done in a usual way Run rounder. Preferably, the rounding time is included no longer than 4 minutes, especially not more than 3.5 minutes. rounding of not more than 1.5 minutes or less are particularly preferred. The rounding becomes a further standardization of the grain spectrum achieved because any resulting agglomerates crushed become.

One Composition according to the invention in particulate form can be especially with nonionic surfactants. Perfume oil and / or Foam inhibitors or preparation forms containing these ingredients contain, preferably with amounts up to 20 wt .-% of active substance, in particular with amounts of 2 to 18 wt .-% of active substance, respectively based on the post-treated product, in per se conventional Way, preferably in a mixer or possibly a fluidized bed, post-treated.

Especially may be an inventive agent also with solids, preferably in amounts of up to 15% by weight, especially in amounts of 2 to 15 wt .-%, each based on the total weight of the post-treated agent, aftertreated or be powdered.

When Solids for post-treatment can be preferably bicarbonate, Carbonate, zeolite, silicic acid, Citrate, urea or mixtures thereof, in particular in quantities from 2 to 15 wt .-%, based on the total weight of the aftertreated Products, use. The aftertreatment can be advantageously in a mixer and / or by means of mills.

In a preferred embodiment The invention is a means of the invention aftertreated with nonionic surfactants, for example, optical brighteners and / or hydrotropes, Perfume, and / or a solution of optical brighteners and / or foam inhibitors or preparation forms, which may contain these ingredients. Preferably, these are Ingredients or formulations containing these ingredients contained, in liquid, melted or pasty Form on the particulate Agent, which is to be treated, applied.

there it is preferred that the aftertreatment with the here mentioned Substances in a common Mixer, for example only in a 2-wave mixer inside of a maximum of 1 minute, preferably within 30 seconds and for example, within 20 seconds, with the times at the same time for Addition and mixing time is done.

in the The following describes the nonionic surfactants in more detail. This nonionic Surfactants can applied to the particulate agents in an aftertreatment step. Of course, everyone can nonionic surfactants but advantageously directly in the composition according to the invention, the e.g. liquid or firm, foamy or gel-like can be included.

The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture may contain, as they are usually present in Oxoalkoholresten. In particular, however, alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, for example of coconut, palm, palm kernel, tallow or oleyl alcohol, and on average 2 to 8 EO per mole of alcohol are preferred. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₇₄ -alcohols with 3 EO to 6 EO, C ₉ -C ₁₁ -alcohols with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alcohols with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.

preferred Alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic Surfactants can fatty alcohols with more than 12 EO can also be used. Examples therefor are (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

Preferred nonionic surfactants are one or more ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation of up to 30, preferably ethoxylated C _10-18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12- fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10; preferably x is 1.1 to 1.4. also suitable are N-methyl glucamides with C ₁₂ / C ₁₄ .

Another class of preferred nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably from 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters, particularly preferred are C ₁₂ -C ₁₈ fatty acid methyl esters having an average of 3 to 15 EO, in particular having an average of 5 to 12 EO, are also used, for example.

Also Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide can be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, in particular not more than half from that.

Farther suitable are alkoxylated amines, advantageously ethoxylated and / or propoxylated, especially primary and secondary amines with preferably 1 to 18 C atoms per alkyl chain and on average 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of amine.

In the case of compositions according to the invention which are particularly suitable for automatic dishwashing, in particular dishwashing compositions in the form of tablet tablets, such as tabs, all surfactants are suitable in principle as surfactants. However, the nonionic surfactants described above and especially the low-foaming nonionic surfactants are particularly preferred for this purpose. Particularly preferred are the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols. The person skilled in the art generally understands, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably the longer-chain alkoxy in the context of the present invention hole C ₁₀ to C ₁₈ , preferably from C ₁₂ to C ₁₆ , such as C ₁₁ , C ₁₂ , C ₁₃ , C ₁₄ , C ₁₅ , C ₁₆ , C ₁₇ and C ₁₈ alcohols. As a rule, n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, form a complex mixture of addition products of different degrees of ethoxylation. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Also, if desired, by a final etherification with short-chain alkyl groups, such as preferably the butyl group, the substance class of "closed" alcohol ethoxylates reach, which can also be used in the context of the invention. Very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates.

Advantageously, the compositions according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. As additives which are solid at room temperature, paraffin waxes, silicic acids, which may also be hydrophobized in a known manner, and in particular bismuth derivatives which are derived from C _2-7 diamines and C _12-22 carboxylic acids, are suitable.

For use, preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) and / or the solidification point. This is the temperature at which the paraffin passes from the liquid to the solid state by slow cooling. Paraffins with less than 17 carbon atoms are not useful in the invention, their proportion in the paraffin oil mixture should therefore be as low as possible and is preferably below the limit significantly measurable by conventional analytical methods, for example gas chromatography. Preferably paraffins are used which solidify in the range of 20 ° C to 70 ° C. It should be noted that even at room temperature appearing paraffin wax mixtures may contain different proportions of liquid paraffin oils. In the case of the paraffin waxes which can be used according to the invention, the liquid fraction at 40 ° C. is as high as possible, without already being 100% at this temperature. Preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It is also important to ensure that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. According to Paraffins which can be obtained for example under the trade names Luna Flex ^® from Fuller and Deawax ^® DEA Mineralöl AG.

The paraffin oils can bisamides solid at room temperature, which differ from saturated ones fatty acids with 12 to 22, preferably 14 to 18 carbon atoms and of alkylenediamines with 2 to 7 carbon atoms derived. Suitable fatty acids are Laurin, myristic, stearic, arachinic and behenic acid as well their mixtures, as they are made of natural Greases or hardened oils, such as Tallow or hydrogenated palm oil, available are. Suitable diamines are, for example, ethylenediamine 1,3-propylenediamine, Tetramethylenediamine, pentamethylenediamine, hexamethylenediamine, p-phenylenediamine and toluenediamine. Preferred diamines are ethylenediamine and hexamethylenediamine. Particularly preferred bisamides are bis-myristoyl-ethylenediamine, Bispalmitoyl-ethylenediamine, bis-stearoyl-ethylenediamine and their Mixtures and the corresponding derivatives of hexamethylenediamine. Also suitable are hexamethylenediamine ethoxylates.

The agents according to the invention can preferably with further constituents, in particular washing, Care and / or cleaning agents or cosmetic ingredients, be mixed. From the broad state of the art is general known which ingredients of detergents, care or cleaning products and which commodities usually can still be mixed. These are, for example, substances such as bleach, Bleach activators and / or bleach catalysts, enzymes, temperature-sensitive Dyes, etc., which are natural can also be included directly in the middle.

Preferably, the agent may comprise UV absorbers, which are advantageously applied to the treated fabrics and improve the lightfastness of the fibers and / or the lightfastness of other formulation ingredients. Under UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg heat to give back. Compounds exhibiting these desired properties include, for example, the non-radiation deactivating compounds and derivatives of Ben zophenones with substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the body's own urocanic acid. The biphenyl and especially stilbene derivatives, commercially available as Tinosorb ^® FD or Tinosorb ^® FR available ex Ciba. 3-benzylidene camphor or 3-benzylidene norcamphor and derivatives thereof, for example 3- (4-methylbenzylidene) camphor, may be mentioned as UV-B absorbers; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid ester; Esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxycinnamate, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid iso-amyl ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene); Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate; Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate; Triazine derivatives, such as 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and Octyl Triazone or Dioctyl Butamido Triazone (Uvasorb HEB ^®); Propane-1,3-diones such as 1- (4-tert-butylphenyl) -3- (4'-methoxyphenynl) propane-1,3-dione; Ketotricyclo (5.2.1.0) decane derivatives. Also suitable are 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts; Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-boryl-nylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter in particular derivatives of benzoylmethane are suitable, such as 1- (4'-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione, 4-tert-butyl 4'-methoxydibenzoylmethane (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) -propane-1,3-dione and enamine compounds. Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed, preferably nano-metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments can also be surface-treated, ie hydrophilized or hydrophobized. Typical examples are coated titanium dioxides, for example Titandioxid T 805 (Degussa) or Eusolex ^® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Micronized zinc oxide is preferably used. Further suitable UV light protection filters can be found in the relevant prior art.

The UV absorbers can advantageously in amounts of from 0.01% by weight to 5% by weight, preferably from 0.03 wt .-% to 1 wt .-%, to be contained in the agent. You can do that Means also subsequently, for example, together with other substances.

Preferably can the agents according to the invention, if they are solid, they are also available as tablets or shaped bodies. As "tablet" or "shaped body" are in the frame independent of the present application Form-stable, solid body called by the nature of their preparation. Such bodies can be, for example, by crystallization, molding, injection molding, reactive or thermal sintering, (co) extrusion, compounding, pastillation, or compaction processes such as calendering or tableting produce. The preparation of the "tablets" or "shaped bodies" by tableting is particularly preferred in the context of the present application. The Tablet is therefore preferably made of compressed, particulate material.

Composition according to the invention in solid form, preferably present as a tablet or shaped body, can preferably contain disintegration aids. As swellable disintegration aids For example, bentonites or other swellable silicates come in Consideration. Also synthetic polymers, especially those in the hygiene sector used superabsorber or cross-linked polyvinylpyrrolidone, can be used.

With particular advantage are as swellable disintegration aids polymers based on Starch and / or cellulose used. These base substances can be processed alone or in mixture with other natural and / or synthetic polymers to swellable disintegrating agents. In the simplest case, a cellulosic material or pure cellulose can be converted by pressure transfer into secondary particles by granulation, compaction or other application, which swell on contact with water and thus serve as a disintegrant. Wood pulp which has been obtained by thermal or chemical-thermal processes from wood or wood chips (sawdust, sawmill waste) has proven to be suitable as a cellulosic material. This cellulosic material from the TMP (thermo-mechanical pulp) or the CTMP (chemo-thermo-mechanical pulp) process can then be compacted by application of pressure, preferably roller compacted and converted into particle form. Of course, pure cellulose can also be used in a completely analogous manner, although it is more expensive from the raw material base. Here, both microcrystalline and amorphous finely divided cellulose and mixtures thereof can be used.

One Another way is to add the cellulose-containing material with addition to granulate granulating aids. As a granulation aid have solutions, for example proven synthetic polymers or nonionic surfactants. Around Residues on with the agents according to the invention To avoid washed textiles, the primary fiber length should be the used cellulose or cellulose in the cellulosic material below 200 μm lie, with primary fiber lengths below 100 μm, especially below 50 microns are preferred.

The secondary particle ideally have a particle size distribution, preferably more than 90 wt .-% of the particles have sizes above 200 microns. A certain amount of dust can lead to an improved storage stability of it contributing tablets. Proportions of a fine dust content from less than 0.1 mm up to 10% by weight, preferably up to 8% by weight can in the agents used according to the invention be present with disintegrant granules.

Farther can the agents according to the invention in the form of a conditioner and / or conditioning substrate present and the proper components contain. The term conditioning is in the sense of this Invention preferably the avivating treatment of textiles, To understand fabrics and fabrics. By conditioning will be gave the textiles positive characteristics, such as a improved softness, increased gloss and color brilliance, an improved scent impression, reduction of felting, ironing relief by reducing the sliding properties, reducing the creasing behavior and static charging as well as color transfer inhibition colored Textiles.

Compositions according to the invention, in particular conditioning agents, may contain, for example, polymerizable betaine esters of the general formula (I): [R ^a -X- (CH ₂ ) _k -NR ^b R ^c - (CR ^d R ^e ) _l - (C = O) -O- (R ^f -O) _m R ^g ] ⁽⁺⁾ A ^(-) (I) in which
R ^{a is} an ethylenically unsaturated radical containing at least one carbonyl function, such as acryloyl, methacryloyl, maleoyl or itaconoyl;
X is an oxygen atom, -N (CH ₃ ) - or -NH-;
R ^b , R ^{c are} independently optionally branched alkyl radicals having 1 to 4 carbon atoms, wherein
these heteroatom substituents, in particular 0, S, N, P may contain;
the rest
R ^d , R ^{e are} independently selected from hydrogen (H), optionally branched alkyl radicals having 1 to 4 C atoms, optionally substituted aryl or benzyl radicals and -CH ₂ COOH, -CH ₂ COOR, -CH ₂ CH ₂ COOH, -CH ₂ CH ₂ COOR; wherein R optionally Mehrbin compounds containing, linear or branched and / or cyclic and / or substituted and / or halogen atoms containing and / or heteroatoms containing and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms or a solely from ethylene or propylene or butylene or styrene oxide-built polyether;
R ^{f is} an optionally multiple bonds containing branched and / or substituted and / or cyclic hydrocarbon radical having 1 to 10, preferably 2 or 3 carbon atoms, or a styrene radical or is composed solely of ethylene or propylene or butylene or styrene radicals, or a said moiety containing block copolymer or random copolymer is;
R ^{g is} an optionally branched, optionally double bonds, optionally cyclic hydrocarbon radical having 1 to 22 carbon atoms, wherein R ^{g is} an optionally branched, optionally double bonds contained hydrocarbon radical when m = 0 and R ^g may be H, if m> 0 is;
k, l are independently 1 to 4, where k is preferably 2 or 3 and 1 is preferably 1;
and
m has a value between 0 to 100, preferably 0 to 40;
A ^{(-) is} an anion; and or
Homopolymers prepared from polymerizable betaine esters of general formula (I) and copolymers prepared from polymerizable betaine esters of general formula (I) and suitable comonomers of general formula (II). R ^w R ^z C = CR ^x R ^y (II) in which
R ^x and R ^{Y are} H,
R ^{w is} H or CH ₃ and
R ^{z is} a radical containing at least one carbonyl group, such as, for example, -C (O) OR, -C (O) NR'R ", where R, R and R" are H or optionally polysubstituted, linear or branched and / or or are cyclic and / or substituted and / or halogen atoms containing and / or containing heteroatoms and / or carbonyl-containing hydrocarbon radicals having 1 to 18 carbon atoms; or in those
R ^w and R ^x H are,
R ^Y and R ^{Z are} carbonyl group-containing radicals such as -C (O) OR, -C (O) NR'R ", where R. R 'and R" are H or optionally multiple, linear or branched and / or cyclic aliphatic or aromatic and / or substituted and / or halogen atoms and / or heteroatoms containing hydrocarbon radicals having 1 to 18 carbon atoms;
or in those
R ^W , R ^x and R ^{Y are} H and
R ^{Z is} an aromatic or heteroaromatic radical optionally containing halogen atom and / or heteroatom-substituted, linear and / or branched alkyl substituents;
or in those
R ^W , R ^x and R ^{Y are} H and
R ^{Z is} - (CH ₂ ) _a -OR ^III , wherein R ^{III is} H or an optionally carbonyl-containing alkyl radical having 1 to 22 C atoms or a polyether exclusively composed of ethylene or propylene or butylene or styrene oxide, which is a represents the said radicals containing blockwise or random copolymer and a is 0 or 1.

To a preferred embodiment contain the agents of the invention no polymerizable betaine esters.

Conditioners according to the invention can advantageously a pH of less than or equal to 8, preferably less than 7, more preferably between 1 and 6 and in particular between 2 and 5.

The Conditioning agents according to the invention can in a preferred embodiment additionally surfactants contain. The additional Use of surfactants causes a strengthening of the conditioning Properties and contributes in addition to improved storage stability and dispersibility or emulsifiability of the individual conditioning agent components.

to Improvement of the softness and the reviving properties can the agents according to the invention Have plasticizer components. Examples of such compounds are quaternary Ammonium compounds, cationic polymers and emulsifiers, such as they are used in hair care products and also in means for Textilavivage become. These softening compounds, which are also hereafter describe in more detail can, can in all agents according to the invention, but especially in the conditioners or in funds with desired plasticizing effect, be included.

wobei in (III) R und R¹ für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R² für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R³ entweder gleich R, R¹ oder R² ist oder für einen aromatischen Rest steht. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (III) sind Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchiorid oder Dihexadecylammoniumchlorid.Suitable examples are quaternary ammonium compounds of the formulas (III) and (IV),

wherein in (III) R and R ^{1 is} an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{2 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ^{3 is} either R, R ¹ or R ² or is a aromatic residue stands. X ^- represents either halide, methosulfate, methophosphate or phosphate ion as well as mixtures from these. Examples of cationic compounds of the formula (III) are didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. Here, R ^{4 is} an aliphatic alkyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion, as well as mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁷ for R ⁵ and to alkyl radicals having 16 to 18 carbon atoms for R ⁴ and R ⁷ . Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (IV) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium metho sulfate or methyl N, N-bis (acyl-oxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (IV) which have unsaturated alkyl chains are used, the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio are preferred (in wt .-%) of greater than 30: 70, preferably greater than 50: 50 and in particular greater than 70: 30 have. Commercial examples are sold by Stepan under the tradename Stepantex ^® Methylhydroxyalkyldi-alkoyloxyalkylammoniummethosulfate or those known under Dehyquart ^® Cognis products known under or Rewoquat ^® manufactured by Goldschmidt-Witco. Further preferred compounds are the diesterquats corresponding to formula (V) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR and provide in addition to the softness also for stability and color protection.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.In addition to the quaternary compounds described above, it is also possible to use other known compounds, for example quaternary imidazolinium compounds of the formula (VI)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt und r eine Zahl zwischen 0 und 5 ist.Further suitable quaternary compounds are described by formula (VII)

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group and r is a number between 0 and 5 is.

In addition to the compounds of the formulas (III) and (IV) it is also possible to use short-chain, water-soluble, quaternary ammonium compounds, such as trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldi-methylammonium chloride, Lau ryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.

Also protonated alkylamine compounds which have a softening effect, and the non-quaternized, protonated precursors of cationic Emulsifiers are suitable.

Further usable according to the invention cationic compounds constitute the quaternized protein hydrolysates represents.

Suitable cationic polymers include the polyquaternium polymers as referred to in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, also referred to as Merquats, Polyquaternium-10 polymers (Ucare Polymer IR 400, Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride , and similar quaternized guar derivatives (eg Cosmedia Guar, manufacturer: Cognis GmbH), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. , The commercial product Glucquat ^® 100, according to CTFA nomenclature a "lauryl methyl Gluceth 10 Hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers and copolymers.

Polyquaternized polymers (for example, Luviquat Care by BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Also useful in the present invention are cationic silicone oils, such as the commercially available Q2-7224 (manufactured by Dow Corning, a stabilized trimethylsilylamodimeth-icon), Dow Corning 929 emulsion (containing a hydroxylamino-modified silicone, also referred to as amodimethicone). , SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ^® quat 3270 and 3272 (manufacturer: Goldschmidt-Rewo; diquaternary polydimethylsiloxanes, quaternium-80), and Silicone quat Rewoquat ^® SQ1 (Tegopren® ^® 6922 , Manufacturer: Goldschmidt-Rewo).

die Alkylamidoamine in ihrer nicht quaternierten oder, wie dargestellt, ihrer quaternierten Form, sein können. R¹⁷ kann ein aliphatischer Alk(en)ylrest mit 12 bis 22 Kohlenstoffatomen mit 0, 1, 2 oder 3 Doppelbindungen sein. s kann Werte zwischen 0 und 5 annehmen. R¹⁸ und R¹⁹ stehen unabhängig voneinander jeweils für H, C_1-4-Alkyl oder Hydroxyalkyl. Bevorzugte Verbindungen sind Fettsäureamidoamine wie das unter der Bezeichnung Tego Amid^®S 18 erhältliche Stearylamidopropyldimethylamin oder das unter der Bezeichnung Stepantex^® X 9124 erhältliche 3-Talgamidopropyl-trimethylammo-niummethosulfat, die sich neben einer guten konditionierenden Wirkung auch durch farbübertragungsinhibierende Wirkung sowie speziell durch ihre gute biologische Abbaubarkeit auszeichnen.It is likewise possible to use compounds of the formula (VIII)

the alkylamidoamines may be in their quaternized or, as shown, their quaternized form. R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl. Preferred compounds are fatty acid amidoamines, such as sold under the name Tego Amid ^® S 18 stearylamidopropyldimethylamine available or the 3-tallowamidopropyl trimethylammo-niummethosulfat obtainable under the name Stepantex ^® X 9124, which is a good conditioning effect good by dye transfer-inhibiting effect and in particular by their distinguish biodegradability.

Especially preferred are alkylated quaternary ammonium compounds of which at least one alkyl chain by an ester group and / or Amido group is interrupted, in particular N-methyl-N (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate.

When nonionic plasticizers are mainly polyoxyalkylene glycol alkanoates, Polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, Alkylpolyglycosides, especially sorbitan mono, di- and triesters and fatty acid esters of polycarboxylic acids into consideration.

In an agent according to the invention, preferably conditioning agents may be plasticizers in amounts from 0.1 to 80% by weight, usually 0.1 to 70 wt .-%, preferably 0.2 to 60 wt .-% and in particular 0.5 to 40 wt .-%, each based on the total agent included be.

Conditioners according to the invention can preferably one or more anionic surfactants, in particular those already described above.

Conditioners according to the invention can preferably one or more nonionic surfactants, in particular those already described above.

When other surfactants for all the agents according to the invention, especially for the conditioning agents, come so-called gemini surfactants into consideration. These are generally understood to mean such compounds, which have two hydrophilic groups and two hydrophobic groups per molecule. These groups are usually separated by a so-called "spacer". This spacer is usually a carbon chain that is long enough should be that the hydrophilic groups have a sufficient distance have to be independent can act from each other. Such surfactants are generally characterized by an unusually low critical micelle concentration and surface tension ability to greatly reduce the water out. In exceptional cases however, under the term gemini surfactants not only dimeric but also understood trimeric surfactants.

suitable Gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis and trimer alcohol tris sulfates and ether sulfates. End-capped dimeric and trimeric mixed ethers are outstanding especially through their bi- and multi-functionality. So the end-capped surfactants mentioned have good wetting properties and are low-foaming, making them especially suitable for use in machine washing, care or cleaning processes are suitable.

used can be but also gemini polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as they are in the relevant State of the art will be described.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²³ für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

wherein RCO is an aliphatic acyl group having 6 to 22 carbon atoms, R ^{23 is} hydrogen, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl group having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R²⁴ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R²⁵ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the following formula

R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, with C _1-4 alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this residue.

[Z] is preferably by reductive amination of a reduced sugar obtained, for example, glucose, fructose, maltose, lactose, galactose, Mannose or xylose. The N-alkoxy or N-aryloxy substituted Connections can then, for example, by reaction with fatty acid methyl esters in the presence of a Alkoxides are converted as a catalyst into the desired polyhydroxy fatty acid amides.

Suitable are also N-methylglucamides.

The agents according to the invention preferably also contain amphoteric surfactants. In addition to numerous up to triply alkylated amine oxides, the betaines represent a significant Class dar.

in der R²⁶ für Alkyl- und/oder Alkenylreste mit 6 bis 22 Kohlenstoffatomen, R²⁷ für Wasserstoff oder Alkylreste mit 1 bis 4 Kohlenstoffatomen, R²⁸ für Alkylreste mit 1 bis 4 Kohlen-stoffatomen, n für Zahlen von 1 bis 6 und X¹ für ein Alkali- und/oder Erdalkalimetall oder Ammonium steht. Typische Beispiele sind die Carboxymethylierungsprodukte von Hexylmethylamin, Hexyldimethylamin, Octyldimethylamin, Decyldimethylamin, Dodecylmethylamin, Dodecyldimethylamin, Dodecylethylmethylamin, C_12/14-Kokosalkyldimethylamin, Myristyldimethylamin, Cetyldimethylamin, Stearyldimethylamin, Stearylethyl-methylamin, Oleyldimethylamin, C_16/18-Talgalkyldimethylamin sowie deren technische Gemische.Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. Preferably, the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein per Moles of betaine a mole of salt is formed. Furthermore, the addition of unsaturated carboxylic acids, such as acrylic acid is possible. As regards the nomenclature and, in particular, the distinction between betaines and 'true' amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (IX)

R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{28 is} alkyl radicals having 1 to 4 carbon atoms, n is a number from 1 to 6 and X is ^{1 represents} an alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C _12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C _16/18 tallowalkyldimethylamine, and technical mixtures thereof.

in der R³¹CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen und 0 oder 1 bis 3 Doppelbindungen, m für Zahlen von 1 bis 3 steht und R²⁹, R³⁰, n und X² die oben angegebenen Bedeutungen haben. Typische Beispiele sind Umsetzungsprodukte von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, namentlich Capronsäure, Caprylsäure, Caprin-saure, Laurinsäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearin-säure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Gemische, mit N,N-Dimethylaminoethylamin, N,N-Dimethylaminopropylamin, N,N-Diethylaminoethylamin und N,N-Diethylaminopropylamin, die mit Natriumchloracetat kondensiert werden. Bevorzugt ist der Einsatz eines Kondensationsproduktes von C_8/18-Kokosfettsäure-N,N-dimethylaminopropylamid mit Natriumchloracetat.Also suitable are carboxyalkylation products of amidoamines which follow the formula (X),

in which R ^{31 is} CO for an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R ²⁹ , R ³⁰ , n and X ² are as defined above. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic, caprylic, capric, lauric, myristic, palmitic, palmitic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic, elaeostearic, arachidic, gadoleic, acids , Behenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. The use of a condensation product of C _8/18 coconut fatty acid N, N-dimethylaminopropylamide with sodium chloroacetate is preferred.

in der R³² für einen Alkylrest mit 5 bis 21 Kohlenstoffatomen, R³³ für eine Hydroxylgruppe, einen OCOR³²- oder NHCOR³²-Rest und m für 2 oder 3 steht. Auch bei diesen Substanzen handelt es sich um bekannte Stoffe, die beispielsweise durch cyclisierende Kondensation von 1 oder 2 Mol Fettsäure mit mehrwertigen Aminen, wie beispielsweise Aminoethyl-ethanolamin (AEEA) oder Diethylentriamin erhalten werden können. Die entsprechenden Carboxyalkylierungsprodukte stellen Gemische unterschiedlicher offenkettiger Betaine dar. Typische Beispiele sind Kondensationsprodukte der oben genannten Fettsäuren mit AEEA, vorzugsweise Imidazoline auf Basis von Laurinsäure oder wiederum C_12/14-Kokosfettsäure, die anschließend mit Natriumchloracetat betainisiert werden.Further suitable suitable starting materials for the betaines usable in the context of the invention are imidazolines which follow the formula (XI),

in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethyl-ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C _12/14 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.

In a preferred embodiment are the agents of the invention in liquid Form before, for example in the form of conditioning or liquid detergent etc. To achieve a liquid Consistency can be the use of both liquid organic solvents, as well as being indicated by water. The agents according to the invention therefore contain solvents if necessary.

Solvents that can be used in the compositions according to the invention originate, for example example of monohydric or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible in the specified concentration range with water. Preferably, the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether , Diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylene glycol monomethyl, or ethyl ether, di-isopropylene glycol monomethyl, or ethyl ether, methoxy, ethoxy or butoxy triglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures of these solvents.

Some glycol ethers are available under the trade name Arcosolv ^® (Arco Chemical Co.) or Cellosolve ^®, carbitol ^® or Propasol ^® (Union Carbide Corp.); this includes for example ButylCarbitol® ^®, hexyl carbitol ^®, MethylCarbitol® ^®, and carbitol ^® itself, (2- (2-ethoxy) ethoxy) ethanol. The choice of glycol ether can be readily made by one skilled in the art on the basis of its volatility, water solubility, weight percent of total dispersion, and the like. Pyrrolidone solvents, such as N-alkyl-pyrrolidones, for example N-methyl-2-pyrrolidone or NC ₈ -C ₁₂ -alkyl-pyrrolidone, or 2-pyrrolidone, may also be used. Also preferred as the sole solvent or as part of a solvent mixture are glycerol derivatives, in particular glycerol carbonate.

Alcohols which may be preferably used as cosolvents in the present invention include low molecular weight liquid polyethylene glycols, for example, polyethylene glycols having a molecular weight of 200, 300, 400 or 600. Further suitable cosolvents are other alcohols, for example (a) lower alcohols such as ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and methyl ethyl ketone, (c) C ₂ -C ₄ polyols such as a diol or a triol, for example ethylene glycol, propylene glycol, glycerol or mixtures thereof. Especially preferred is 1,2-octanediol from the class of diols.

In a preferred embodiment, the agent according to the invention contains one or more solvents from the group comprising C ₁ to C ₄ monoalcohols, C ₂ to C ₆ glycols, C ₃ to C ₁₂ glycol ethers and glycerol, in particular ethanol , The C ₃ - to C ₁₂ glycol ethers according to the invention contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms.

Preferred C ₁ -C ₄ -monoalcohols are ethanol, n-propanol, isopropanol and tert-butanol. Preferred C ₂ to C ₆ glycols are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,5-pentanediol, neopentyl glycol and 1,6-hexanediol, in particular ethylene glycol and 1,2-propylene glycol. Preferred C ₃ - to C ₁₂ glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, tri- and tetrapropylene glycol, propylene glycol monotertiary butyl ether and propylene glycol monoethyl ether and the solvents designated according to INCI butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyloctanol, ethoxydiglycol, Ethoxyethanol, ethyl hexanediol, isobutoxypropanol, isopentyldiol, 3-methoxybutanol, methoxyethanol, methoxyisopropanol and methoxymethylbutanol.

The inventive agent, preferably conditioning agent or liquid detergent, may be one or more solvent in an amount of usually up to 90% by weight, preferably 0.1 to 30% by weight, in particular 2 to 20% by weight, more preferably 3 to 15% by weight, most preferably 5 to 12 wt .-%, for example, 5.3 or 10.6 wt .-%, each based on the entire remedy, included.

In a preferred embodiment can the cleaning, Care or detergent, in particular the conditioner optionally contain one or more complexing agents.

complexing (INCI chelating agents), also called sequestering agents, are ingredients, to complex and inactivate the metal ions, for example their adverse effects on the stability or appearance of the products, for example, cloudiness, to prevent. On the one hand, it is important to deal with many Ingredients incompatible calcium and magnesium ions of the water hardness to complex. The complexation of the ions of heavy metals such as iron or copper delayed the oxidative decomposition of the finished agents.

For example, the following according to INCI complexing agents are suitable, for example, in the International Cosmetic Ingredient Dictionary and Handbook are described in more detail: Aminotrimethylene phosphonic acid, beta-alanines diacetic acid, calcium disodium EDTA, citric acid, cyclodextrin, cyclo Hexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic Acid, Dipotassium EDTA, Disodium Azacycloheptane Diphosphonate, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactic Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl Cyclodextrin, Pentapotassium Triphosphates, Pentasodium Aminotrimethylene Phosphonates, Pentasodium Ethylenediamines Tetramethylene Phosphonates, Pentasodium Pentetates, Pentasodium Triphosphates, Pentetic Acid, Phytic Acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconates, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan, Methylene Phosphonates, Sodium Citrate , Sodium Diethylenetriamine Pentamethylene Phosphonate, Sodium Dihydroxyethylglycinate, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphate, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, So polydimethylglycinophenolsulfonates, sodium trimetaphosphates, TEA-EDTA, TEA polyphosphates, tetrahydroxyethyl ethylene diamines, tetrahydroxypropyl ethylene di diamines, tetrapotassium etidronates, tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium etidronates, tetrasodium pyrophosphates, tripotassium EDTA, trisodium dicarboxymethyl alaninates, trisodium EDTA, trisodium HEDTA, Trisodium NTA and Trisodium Phosphate.

preferred Complexing agents are tertiary Amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both Amino as well as hydroxy and / or ether groups as functional groups. Particularly preferred tertiary Alkanolamines are tri-ethanolamine and tetra-2-hydroxyprop-pylethylenediam in (N, N, N ', N'-tetrakis- (2-hydroxypropyl) ethylenediamine). Particularly preferred combinations of tertiary amines with Zinkricinoleat and one or more ethoxylated fatty alcohols as nonionic solubilizers and optionally solvents are described in the prior art.

One particularly preferred complexing agent is the etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxy-ethane-1,1-diphosphonic acid, HEDP, acetophosphonic, INCI Etidronic Acid) including their salts. In a preferred embodiment, the agent according to the invention contains accordingly as a complexing agent etidronic and / or one or more of their salts.

In a particular embodiment contains the agent of the invention a complexing agent combination of one or more tertiary amines and one or more other complexing agents, preferably one or more complexing acids or salts thereof, in particular of triethanolam in and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of their salts.

The inventive cleaning, Care or washing agents, in particular conditioning, contains advantageously Complexing agent in an amount of usually 0 to 20% by weight, preferably 0.1 to 15% by weight, in particular 0.5 to 10% by weight, particularly preferably 1 to 8% by weight, very preferably 1.5 to 6% by weight, based on the total mean.

In a further embodiment contains the cleaning invention, Care or washing agents, in particular conditioners, if necessary one or more viscosity regulators, which preferably act as a thickener.

The viscosity the remedy can with usual Standard methods (for example Brookfield viscometer RVD-VII at 20 rpm and 20 ° C, Spindle 3) are measured and is preferably in the range of 10 to 5000 mPas. Preferred liquid to gelatinous Means have viscosities from 20 to 4000 mPas, with values between 40 and 2000 mPas especially are preferred.

suitable Thickeners are inorganic or polymeric organic compounds. It can also mixtures of several thickeners are used.

To counting the inorganic thickeners for example polysilicic acids, Clay minerals such as montmorillonites, zeolites, silicas, aluminum silicates, Phyllosilicates and bentonites.

The Organic thickeners come from the groups of natural Polymers, modified natural Polymers and fully synthetic polymers.

Out naturally derived polymers used as thickeners, are, for example, xanthan gum, agar agar, carrageenan, gum tragacanth, gum arabic, alginates, pectins, polyoses, guar flour, gellan gum, locust bean gum, Strength, Dextrins, gelatin and casein.

modified Natural products come mainly from the group of modified starches and Celluloses, examples being carboxymethylcellulose and others Cellulose ethers, hydroxyethyl and propylcellulose, highly etherified Methylhydroxyethylcellulose and Kernmehlether called.

A size Group of thickeners, the most widely used in the most diverse Fields of application are the fully synthetic polymers such as Polyacrylic and polymethacrylic compounds which are crosslinked or uncrosslinked and optionally cationically modified, vinyl polymers, polycarboxylic acids, polyethers, activated Polyamide derivatives, castor oil derivatives, Polyimines, polyamides and polyurethanes. Examples of such polymer are acrylic resins, ethyl acrylate-acrylamide copolymers, acrylic ester-methacrylic acid-ester copolymers, Ethyl acrylate-acrylic acid-methacrylic acid copolymers, N-methylolmethacrylamide, maleic anhydride-methyl vinyl ether copolymers, Polyether-polyol copolymers and butadiene-styrene copolymers.

Further suitable thickeners are derivatives of organic acids and their alkoxide adducts, for example aryl polyglycol ethers, carboxylated nonylphenol ethoxylate derivatives, sodium alginate, diglycerol monoisostearate, nonionic ethylene oxide adducts, coconut fatty acid diethanolamide, isododecenylsuccinic anhydride and galactomannan. Thickener from the mentioned classes of substances are commercially available and, for example, under the trade names Acusol ^® -820 (methacrylic acid (stearyl alcohol 20 EO) ester-acrylic acid copolymer, 30% in water, Rohm & Haas), Da-Pral ^® -GT -282-S (alkyl polyglycol ethers, Akzo), DEUTEROL ^® polymer-11 (dicarboxylic acid co-polymer, Schoner GmbH) deuteron ^® -xg (anionic heteropolysaccharide based on β-D-glucose, D-mannose, D-glucuronic acid , Schoner GmbH), -XN deuteron ^® (non-ionic polysaccharide, Schoner GmbH), DICRYLAN ^® -Verdicker-O (ethylene oxide adduct, 50% solution in water / isopropanol, Pfersse Chemie), EMA ^® -81 and EMA ^® - 91 (ethylene-Ma-leinsäureanhydrid copolymer, Monsanto), thickener QR-1001 (polyurethane emulsion, 19-21% in water / diglyme, Rohm & Haas), Mirox ^® -AM (anionic acrylic acid-acrylate copolymer dispersion, 25% in water, Stockhausen), SER-AD FX 1100 (hydrophobic urethane polymer, servo Delden), Shellflo ^® -S (high-molecular Po charide stabilized with formaldehyde, Shell), Shellflo XA ^® (xanthan biopolymer, stabilized with formaldehyde, Shell), Kelzan, Keltrol T (Kelco) is.

In a further preferred embodiment contains the cleaning invention, Care or washing agents, in particular conditioners, if necessary one or more enzymes.

When Enzymes are especially those from the classes of hydrolases as the proteases, esterases, lipases or lipolytic acting Enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures the enzymes mentioned in question. All of these hydrolases carry in the Laundry to remove stains such as protein, fat or starch Stains and graying at. Cellulases and other glycosyl hydrolases can about that By removing pilling and microfibrils for color retention and to increase contribute to the softness of the textile. For bleaching or inhibition the color transfer can also Oxireduktasen be used.

Especially are well suited from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens obtained enzymatic agents. Preferably Proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and Lipasebzw. lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or Protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular Interest. examples for Such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have in some cases as proved suitable. Suitable amylases include in particular α-amylases, Iso-amylases, pullulanases and pectinases. Being cellulases preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures of these used. Because different types of cellulase are affected by their CMCase and avicelase activities can distinguish adjusted by targeted mixtures of cellulases the desired activities become.

The Enzymes can as a shaped body on carriers be embedded or coated to protect against premature To protect decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules can for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%, based on the total agent.

The detergents or cleaners or conditioners according to the invention (eg conditioning agents) may optionally contain bleaches. Among the compounds serving as bleaches in water H ₂ O ₂ , sodium percarbonate, sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as persulfates or persulfuric acid. Also useful is the urea peroxohydrate percarbamide, which can be described by the formula H ₂ N-CO-NH ₂ .H ₂ O ₂ . In particular, when using the means for cleaning hard surfaces, for example in automatic dishwashing, they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents. Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, examples of which include the alkyl peroxyacids and the aryl peroxyacids. Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxycaproic acid (Phthalimidoperoxyhexansäure, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonylamidopersuccinates, and aliphatic and araliphatic peroxydicarboxylic acids such as 1,12-diperoxy carboxylic acid, 1,9-diperoxyazelaic acid, diperoxysebacic acid, diperoxybrassic acid, the diperoxyphthalic acids, 2-decyl-diperoxybutane-1,4-diacid, N, N- Terephthaloyl-di (6-aminopercaproic acid) can be used.

The Bleach can preferably be coated to prevent them from premature decomposition protect.

dyes can in the agent according to the invention be used, the amount of one or more dyes so low to choose is that after application of the agent no visible residues remain. Preferably, the agent according to the invention is free of dyes.

The inventive agent may preferably contain one or more antimicrobial agents or preservatives in an amount of usually 0.0001 to 3 wt .-%, preferably from 0.0001 to 2% by weight, in particular from 0.0002 to 1% by weight, more preferably 0.0002 to 0.2 wt%, more preferably 0.0003 to 0.1 wt .-%, contained.

antimicrobial Agents or preservatives are differentiated according to the antimicrobial spectrum and mechanism of action between bacteriostats and bactericides, Fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol-urea acetate. The terms antimicrobial effect and antimicrobial agent have within the scope of the teaching of the invention the usual Importance. Suitable antimicrobial agents are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, Phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents Compounds, guanidines, antimicrobial amphoteric compounds, Quinolines, 1,2-dibromo-2,4-di-cyanobutane, iodo-2-propyl-butyl-carbamate, iodine, iodophors, peroxo compounds, Halogen compounds and any mixtures of the above.

The antimicrobial agent may be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-propanol. Methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxydiphenyl ether ( Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,11, 13-tetraaza-tetradecandiimidamide, glucoprotamines, antimicrobial surface-active quaternary compounds, guanidines including the bi- and polyguanidine-type such as 1,6-bis- (2-ethylhexyl-biguanido-hexane) -dihydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyl-N ₁ , N ₁ -methyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -o-chlorophenyldiguanido- N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ', 2,6-dichlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- [N ₁ , N ₁ '-beta (p-methoxyphenyl) diguanido-N ₅ , N, ₅ '] -hexane-dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -alpha-methyl-beta-phenyldiguanido-N ₅ , N ₅ ') -hexane-dihydrochloride, 1 , 6-di- (N ₁ , N ₁ '-p-nitro-phenyldiguanido-N ₅ , N ₅ ') hexane-dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-phenyl-diguanido-N ₅ , N ₅ ') di-n-propyl ether dihydrochloride, omega: omega-di- (N ₁ , N ₁ ' -p-chlorophenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether tetrahydrochloride, 1 , 6-di- (N ₁ , N ₁ '-2,4-dichlorophenyldiguanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-p-methylphenyl) -diyl guanido-N ₅ , N ₅ ') hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -2,4,5-trichlorophenyl-guanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1, 6-di- [N ₁ , N ₁ '-alpha (p-chlorophenyl) ethyldiguanido-N ₅ , N ₅ '] hexane dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-p-chlorophenyl) nyldiguanido-N ₅ , N ₅ ') m-xylenedihydrochloride, 1,12-di (N ₁ , N ₁ ' -p-chlorophenyldiguanido-N ₅ , N ₅ ') dodecane dihydrochloride, 1,10- Di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -decane tetrahydrochloride, 1,12-di (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') dodecane-tetrahydrochloride , 1,6-di- (N ₁ , N ₁ '-o-chlorophenyl-guanido-N ₅ , N ₅ ') hexane-dihydrochloride, 1,6-di- (N ₁ , N ₁ '-o-chlorophenyldiguanido- N ₅ , N ₅ ') hexane tetrahydrochloride, ethylene bis (1-tolyl biguanide), ethylene bis (p-tolyl biguanide), ethylene bis (3,5-dimethylphenyl biguanide), ethylene bis ( p-tert-amylphenylbiguanide), ethylene-bis- (nonylphenylbiguanide), ethylene-bis (phenylbifluoride), ethylene-bis (N-butylphenylbioguanide), ethylene bis (2,5-diethoxyphenylbiguanide), ethylene bis (2,4-d ethylphenyl biguanide), ethylene bis (o-diphenylbiguanide), ethylene bis (mixed amyl naphthyl biguanide), N-butyl ethylene bis (phenylbiguanide), trimethylene bis (o-tolyl biguanide), N-butyl trimethyl bis (phenyl biguanide) and the corresponding salts such as acetates, gluconates, hydrochlorides, hydrobromides, citrates, bisulfites, fluorides, polymaleates, N-Cocosalkylsarcosinate, phosphites, hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylenediaminetetraacetates , Iminodiacetates, cinnamates, thiocyanates, arginates, pyromellitate, tetracarboxybutyrates, benzoates, glutgrates, monofluorophosphates, perfluoropropionates and any mixtures thereof. Also suitable are halogenated xylene and cresol derivatives, such as p-chloromethacresol or p-chlorometaxylene, as well as natural antimicrobial agents of plant origin (eg from spices or herbs), of animal and microbial origin. Preferably, antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial agent of animal origin from the group, comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobial surface-active quaternary compound with an ammonium, sulfonium, phosphonium, iodonium - or Arsoniumgruppe, peroxo compounds and chlorine compounds are used. Also substances of microbial origin, so-called bacteriocins, can be used. Glycine, glycine derivatives, formaldehyde, compounds which readily split off formaldehyde, formic acid and peroxides are preferably used.

The suitable as antimicrobial agents quaternary ammonium compounds (QAV) have been described above. Is particularly suitable, for example, benzalkonium chloride, etc. Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Variquat ^® ex Witco / Sherex and Hyamine ^® ex Lonza and as Bardac ^® ex Lonza. Other commercially obtainable antimicrobial agents are N- (3-chloroallyl) hexaminium chloride such as Dowicide and Dowicil ^{® ®} ex Dow, benzethonium chloride such as Hyamine ^® 1622 ex Rohm & Haas, methylbenzethonium as Hyamine ^® 10X ex Rohm & Haas, cetylpyridinium chloride such as Cepacol ex Merrell Labs ,

Farther can the washing or cleaning agents, care products, optionally ironing aids to improve water absorbency, rewettability treated textiles and to facilitate ironing treated textiles. It can in the formulations For example, silicone derivatives are used. Improve this additionally the rinsing behavior the detergent-active formulations by their foam-inhibiting properties. Preferred silicone derivatives are, for example polydialkyl or Alkylarylsiloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated. Preferred silicones are polydimethylsiloxanes which may optionally be derivatized can and then amino-functional or quaternized or Si-OH, Si-H and / or Have Si-Cl bonds. The viscosities of the preferred silicones are at 25 ° C ranging between 100 and 100,000 mPas, with the silicones in Amounts between 0.2 and 5 wt .-%, based on the total agent can be used.

The agent according to the invention, especially conditioning agents, according to all known, familiar to the expert Techniques are obtained. The agents can, for example, by mixing immediately from their raw materials, possibly using high shear Mixtures are obtained. For liquid formulations, in particular Conditioning agent, is recommended e.g. a melting, if necessary existing plasticizer components and subsequent dispersing the melt in a solvent, preferably water.

Preferably the conditioning agents are present as fabric softeners. They usually do in the rinse cycle an automatic washing machine introduced.

Another object of the invention is a substrate, in particular conditioning substrate, which with an agent according to the invention, in particular conditioning agent, which therefore contains, in addition to other constituents, the perfume composition according to the invention, is impregnated and / or coated.

Inventive conditioning substrates find their use especially in textile treatment and in particular in textile drying processes. The substrate material is preferably made of porous flat towels. she can from a fibrous or cellular flexible material that has sufficient thermal stability for use in the dryer and the sufficient amounts of impregnation or Retain coating agent can be used to effectively condition fabrics without having to worry during the Storage a significant leakage or bleeding of the agent he follows. To these towels belong Towels off woven and unwoven synthetic and natural fibers, felt, paper or foam, such as hydrophilic polyurethane foam.

Preferably, conventional cloths of nonwoven material (nonwovens) are used here. Nonwovens are generally defined as adhesively bonded fibrous products having a mat or layered fibrous structure, or those comprising fibrous mats in which the fibers are randomly or randomly distributed. The fibers may be natural such as wool, silk, jute, hemp, cotton, flax, sisal or ramie; or synthetically, such as rayon, cellulose esters, polyvinyl derivatives, polyolefins, polyamides or polyesters. In general, any fiber diameter or titer is suitable for the present invention. The nonwoven fabrics employed herein tend not to rupture or disintegrate due to the random or random arrangement of fibers in the nonwoven material which impart excellent strength in all directions when used, for example, in a household tumble dryer. Examples of nonwoven fabrics suitable as substrates in the present invention include, for example WO 93/23603 known. Preferred porous and flat cleaning cloths consist of one or different fiber materials, in particular of cotton, refined cotton, polyamide, polyester or mixtures of these. The cleaning substrates in fabric form preferably have an area of from 10 to 5000 cm ² , preferably from 50 to 2000 cm ² , in particular from 100 to 1500 cm ² and particularly preferably from 200 to 1000 cm ² . The gram pitch of the material is usually between 20 and 1000 g / m ² , preferably from 30 to 500 g / m ² and in particular from 50 to 150 g / m ² . Conditioning substrates can be obtained by impregnation or impregnation or else by melting the agents or conditioners according to the invention onto a substrate.

One Another object of the invention is the use of a conditioning agent according to the invention or a conditioning substrate according to the invention in a textile conditioning process, such as a rinse cycle, a Textile drying process and a textile dry cleaning or Fabric refreshment process. Likewise, a conditioned substrate, e.g. made of wood, paper, leather or similar can be used as a room fragrance.

preferred inventive agent are liquid detergents, preferably containing surfactant (s) and other conventional ingredients of washing, Care or cleaning agents. For example, according to the invention suitable liquid detergent as thickening system, in each case based on the total agent a) 0.1 to 5% by weight of a polymeric thickener, b) 0.5 to 7% by weight a boron compound and c) 1 to 8% by weight of a complexing agent, contain.

in the The present invention relates to aqueous, higher-viscosity liquid detergents preferably, whose content of surfactant (s) over 25 wt .-% is.

suitable Thickener, also called swelling (ungs) agent, such as. B. Alginates or agar-agar have been described above. preferred aqueous liquid detergent contained as a thickening 0.2 to 4 wt .-%, preferably 0.3 to 3 wt .-% and in particular 0.4 to 1.5 wt .-%, of a polysaccharide.

One preferably used polymeric thickener is xanthan, a microbial anionic heteropolysaccharide derived from Xanthomonas campestris and some other species under aerobic conditions is produced and a molecular weight of 2 to 15 million daltons having. Xanthan gum is made from a chain of β-1,4-bound glucose (cellulose) formed with side chains. The structure of the subgroups consists of Glucose, mannose, glucuronic acid, Acetate and pyruvate, where the number of pyruvate units is the viscosity of xanthan certainly.

Liquid detergents of the invention may preferably contain a boron compound which is used in amounts of from 0.5 to 7% by weight. Examples of boron compounds used in the context of Boronic acid, boron oxide, alkali metal borates such as ammonium, sodium and potassium ortho-, meta- and pyroborates, borax in its various stages of hydration and polyborsten such as alkali metal pentaborates.

Also, organic boron compounds such as esters of boric acid are used, as well as reaction products of H ₃ BO ₃ with nonionic surfactants and / or fragrances.

preferred liquid detergent contain from 0.5 to 4 wt .-%, preferably 0.75 to 3 wt .-% and in particular 1 to 2 wt .-% boric acid and / or sodium tetraborate.

Farther can Inventive liquid detergent 1 to 8 wt .-% of a complexing agent. Especially preferred liquid detergent contain citric acid or sodium citrate, wherein liquid detergent preferred are 2.0 to 12% by weight, preferably 3.0 to 6.0 Wt .-% and in particular 4.0 to 5.0. Wt .-% sodium citrate.

Next the components of the thickening system contain the liquid detergents according to the invention preferably surfactant (s), wherein anionic, nonionic, cationic and / or amphoteric surfactants are used. Preference is given to From an application point of view mixtures of anionic and nonionic Surfactants, wherein the proportion of nonionic surfactants preferably to be taller can be considered as the proportion of anionic surfactants. The use of sugars and / or sugar derivatives such as alkyl polyglucosides or Cyclodextrins can also be made.

• – Aniontenside, wie z.B. Alkylbenzolsulfonat, Alkylsulfat, in Mengen von vorteilhafterweise 5-30 Gew.-%, vorzugsweise 8-15 Gew.-%, insbesondere 15-20 Gew.-%,
• – Nichtionische Tenside, wie z.B. Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid, vorteilhafterweise 0,1-20 Gew.-%, vorzugsweise 2-15 Gew.-%, insbesondere 6-11 Gew.-%,
• – Gerüststoffe, wie z.B. Zeolith, Polycarboxylat, Natriumcitrat, 5-60 Gew.-%, vorzugsweise 10-55 Gew.-%, insbesondere 15-40 Gew.-%,
• – Alkalien, wie z.B. Natriumcarbonat, vorteilhafterweise 1-30 Gew.-%, vorzugsweise 2-25 Gew.-%, insbesondere 5-20 Gew.-%,
• – zusätzliche Bleichmittel, wie z.B. Natriumperborat, Natriumpercarbonat, vorteilhafterweise 5-25 Gew.-%, vorzugsweise 10-20 Gew.-%,
• – Korrosionsinhibitoren, z.B. Natriumsilicat, vorteilhafterweise 1-6 Gew.-%, vorzugsweise 2-5 Gew.-%, insbesondere 3-4 Gew.-%,
• – Stabilisatoren, z.B. Phosphonate vorteilhafterweise 0-1 Gew.-%,
• – Schauminhibitor, z.B. Seife, Siliconöle, Paraffine vorteilhafterweise 0,1-4 Gew.-%, vorzugsweise 0,2-2 Gew.-%, insbesondere 1-3 Gew.-%,
• – Enzyme, z.B. Proteasen, Amylasen, Cellulasen, Lipasen, vorteilhafterweise 0,1-2 Gew.-%, vorzugsweise 0,2-1 Gew.-%, insbesondere 0,3-0,8 Gew.-%,
• – Vergrauungsinhibitor, z.B. Carboxymethylcellulose, vorteilhafterweise 0-1 Gew.-%,
• – Verfärbungsinhibitor, z.B. Polyvinylpyrrolidon-Derivate, vorteilhafterweise 0-2 Gew.-%,
• – Stellmittel, z.B. Natriumsulfat, vorteilhafterweise 0-20 Gew.-%,
• – Optische Aufheller, z.B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise 0,1-0,3 Gew.-%, insbesondere 0,1-0,4 Gew.-%,
• – Duftstoffe
• – Wasser
• – Seife
• – Bleichaktivatoren
• – Cellulosderivate
• – Schmutzabweiser.

A powdery heavy-duty detergent according to the invention may preferably contain, for example, components which are selected from the following:

• Anionic surfactants, such as, for example, alkylbenzenesulfonate, alkylsulfate, in amounts of advantageously 5-30% by weight, preferably 8-15% by weight, in particular 15-20% by weight,
• Nonionic surfactants, such as, for example, fatty alcohol polyglycol ethers, alkyl polyglucoside, fatty acid glucamide, advantageously 0.1-20% by weight, preferably 2-15% by weight, in particular 6-11% by weight,
• Builders, such as zeolite, polycarboxylate, sodium citrate, 5-60% by weight, preferably 10-55% by weight, in particular 15-40% by weight,
• Alkalis, for example sodium carbonate, advantageously 1-30% by weight, preferably 2-25% by weight, in particular 5-20% by weight,
• Additional bleaching agents, for example sodium perborate, sodium percarbonate, advantageously 5-25% by weight, preferably 10-20% by weight,
• Corrosion inhibitors, for example sodium silicate, advantageously 1-6% by weight, preferably 2-5% by weight, in particular 3-4% by weight,
• Stabilizers, eg phosphonates, advantageously 0-1% by weight,
• Foam inhibitor, for example soap, silicone oils, paraffins, advantageously 0.1-4% by weight, preferably 0.2-2% by weight, in particular 1-3% by weight,
• Enzymes, eg proteases, amylases, cellulases, lipases, advantageously 0.1-2% by weight, preferably 0.2-1% by weight, in particular 0.3-0.8% by weight,
• Graying inhibitor, eg carboxymethylcellulose, advantageously 0-1% by weight,
• Discoloration inhibitor, for example polyvinylpyrrolidone derivatives, advantageously 0-2% by weight,
• Adjusting agent, eg sodium sulphate, advantageously 0-20% by weight,
• Optical brighteners, eg stilbene derivative, biphenyl derivative, advantageously 0.1-0.3% by weight, in particular 0.1-0.4% by weight,
• - perfumes
• - Water
• - Soap
• - bleach activators
• - Cellulosic derivatives
• - Dirt deflector.

• – Aniontenside, wie z.B. Alkylbenzolsulfonat, Alkylsulfat, in Mengen von vorteilhafterweise 5-40 Gew.-%, vorzugsweise 8-30 Gew.-%, insbesondere 15-25 Gew.-%,
• – Nichtionische Tenside, wie z.B. Fettalkoholpolyglycolether, Alkylpolyglucosid, Fettsäureglucamid, vorteilhafterweise 0,1-25 Gew.-%, vorzugsweise 5-20 Gew.-%, insbesondere 10-15 Gew.-%,
• – Gerüststoffe, wie z.B. Zeolith, Polycarboxylat, Natriumcitrat, vorteilhafterweise 0-15 Gew.-%, vorzugsweise 0,01-10 Gew.-%, insbesondere 0,1-5 Gew.-%,
• – Schauminhibitor, z.B. Seife, Siliconöle, Paraffine, vorteilhafterweise 0,1-4 Gew.-%, vorzugsweise 0,2-2 Gew.-%, insbesondere 1-3 Gew.-%,
• – Enzyme, z.B. Proteasen, Amylasen, Cellulasen, Lipasen, vorteilhafterweise 0,1-2 Gew.-%, vorzugsweise 0,2-1 Gew.-%, insbesondere 0,3-0,8 Gew.-%,
• – Optische Aufheller, z.B. Stilben-Derivat, Biphenyl-Derivat, vorteilhafterweise 0,1-0,3 Gew.-%, insbesondere 0,1-0,4 Gew.-%,
• – Duftstoffe
• – -Stabilisatoren,
• – Wasser
• – Seife, vorteilhafterweise 1-20 Gew.-%, vorzugsweise 2-15 Gew.-%, insbesondere 5-10 Gew.-%,
• – Alkohole/Lösungsmittel, vorteilhafterweise 0-25 Gew.-%, vorzugsweise 1-20 Gew.-%, insbesondere 2-15 Gew.-%,

A liquid heavy-duty detergent according to the invention may preferably contain, for example, the following components which are selected from the following:

• Anionic surfactants, such as, for example, alkylbenzenesulfonate, alkylsulfate, in amounts of advantageously 5-40% by weight, preferably 8-30% by weight, in particular 15-25% by weight,
• Nonionic surfactants, such as, for example, fatty alcohol polyglycol ethers, alkyl polyglucoside, fatty acid glucamide, advantageously 0.1-25% by weight, preferably 5-20% by weight, in particular 10-15% by weight,
• - Builders, such as zeolite, polycarboxylate, sodium citrate, advantageously 0-15 wt .-%, vorzugswei 0.01-10% by weight, in particular 0.1-5% by weight,
• Foam inhibitor, for example soap, silicone oils, paraffins, advantageously 0.1-4% by weight, preferably 0.2-2% by weight, in particular 1-3% by weight,
• Enzymes, eg proteases, amylases, cellulases, lipases, advantageously 0.1-2% by weight, preferably 0.2-1% by weight, in particular 0.3-0.8% by weight,
• Optical brighteners, eg stilbene derivative, biphenyl derivative, advantageously 0.1-0.3% by weight, in particular 0.1-0.4% by weight,
• - perfumes
• - stabilizers,
• - Water
• Soap, advantageously 1-20% by weight, preferably 2-15% by weight, in particular 5-10% by weight,
• Alcohols / solvents, advantageously 0-25% by weight, preferably 1-20% by weight, in particular 2-15% by weight,

The agents according to the invention can preferably also with perfume oil (fragrances, Fragrances) perfumed be.

With the term perfume oil are preferred meant self-contained perfume compositions commonly known be used for product scenting and in particular for human Discretion are fragrant. This will be explained with an example. Want a professional, e.g. fragrant with a shower gel, he adds usually not only a (well) smelling substance, but a collective (well) smelling Substances. Such a collective usually consists of a plurality of individual fragrances, e.g. more than 10 or 15, preferably up to 100 or more. These riches form cooperatively desired fragrant, harmonious smell.

One Perfume oil according to the invention can be individual Fragrance compounds, e.g. the synthetic products of the type the esters, ethers, aldehydes, ketones, alcohols and hydrocarbons contain. Fragrance compounds of the ester type are known e.g. benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, Dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, Ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, Benzyl salicylate, cyclohexyl salicylate, Floramat, Melusat and Jasmecyclat. Count to the Ethern for example, benzyl ethyl ether and ambroxane, to the aldehydes e.g. the linear alkanals with 8-18 carbon atoms, citral, citronellal, citronellyloxy-acetaldehyde, Cyclamenaldehyde, lilial and bourgeonal, to the ketones e.g. the Jonone, α-isomethylionone and methyl cedryl ketone, to the alcohols anethole, citronellol, eugenol, Geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons belong mainly the terpenes like limonene and pinene. However, mixtures are preferred different fragrances used, which together create an appealing Generate fragrance of the perfume oil formed.

The But perfume oils can also natural Contain fragrance mixtures, as they are accessible from plant sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muscat sage oil, Chamomile oil, Clove oil, Melissa oil mint oil, Cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil, as well as Orange blossom oil, neroliol, Orange peel oil and sandalwood oil.

Around To be perceptible, one must Perfume volatile being, besides the nature of the functional groups and the structure the molecular weight of the chemical compound also plays an important role plays. So most perfumes have molecular weights up to about 200 Dalton, while Molar masses of 300 daltons and above constitute an exception. Due to the different volatility changed by fragrances the smell of a compound of several fragrances perfumes while vaporizing, whereby the odor impressions in "top note", "middle note" body) and "base note" (end note or dry divided out).

Adhesive-resistant fragrances which are advantageously usable in the perfume oils in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, Bay oil, Champacablütenöl, Edeltannenöl, Edeltannenzapfen oil, Elemiöl, eucalyptus oil, fennel oil, spruce algae oil, galbanum oil, geranium oil, Gingergrass oil, guaiac wood oil, gurdy balm oil, helichrysum oil, HO oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine oil, copaia balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lemongrass oil, musk kernel oil, myrrh oil, clove oil, Neroli oil, Niaouli oil, Olibanum oil, Origanum oil, Palmarosa oil, Patchouli oil, Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sandalwood oil, Celery oil, Sterna oil, thuja oil, thyme oil, verbena oil, vetiver oil, juniper berry oil, wormwood oil, wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil and cypress oil.

But also the higher-boiling ones or solid odoriferous natural or of synthetic origin in the context of the present invention advantageously as adherent Fragrances or fragrance mixtures are used in the perfume oils. To this Counting connections the following compounds as well as mixtures of these: Ambrettolide, α-amylcinnamaldehyde, Anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, Acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, Benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, Fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, Heptincarbonsäuremethylester, Heptaldehyde, hydroquinone di-methyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, Indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, Methylanthranilsäuremethylester, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthylketone, Methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muskon, β-naphthol ethyl ether, β-naphthol methyl ether, Nerol, nitrobenzene, n-nonylaldehyde, nonyl alcohol, n-octylaldehyde, p-oxy-acetophenone, Pentadecanolide, β-phenylethyl alcohol, Phenylacetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamyl ester, methyl salicylate, Salicylsäurehexylester, Salicylsäurecyclohexylester, Santalol, skatole, terpineol, thymen, thymol, γ-undelactone, vaniline, veratrum aldehyde, Cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamate, Zimtsäurebenzylester.

To the more volatile Fragrances which are advantageous in the perfume oil in the context of the present invention can be used count especially the lower-boiling fragrances natural or synthetic origin, used alone or in mixtures can be. examples for more volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, Linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, Phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The above-mentioned fragrances are used alone or as a mixture in the perfume oils according to the present invention Invention can be used with the advantages already mentioned.

Especially can also fragrances from the group of allyl alcohol esters, esters of secondary alcohols, Ester tertiary Alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof in the perfume oil be.

allyl alcohol are the esters of allyl alcohol, which has the following structural feature has, C (OH) -C = C. examples for Allylalkohlester are in particular Allylamylglycolat, allylanthranilate, Allyl benzoate, allyl butyrate, allyl caprate, allyl caproate, allyl cinnamate, Allylcyclohexane acetate, allylcyclohexanebutyrate, allylcyclohexanepropionate, Allylheptoate, allylnonanoate, allylsalicylate, amylcinnamylacetate, Amyl cinnamyl formate, cinnamyl formates, cinnamyl acetates, cyclogalbanate, Geranyl acetate, geranyl acetoacetate, geranyl benzoate, geranyl cinnamate, Methallyl butyrate, methallyl caproate, neryl acetate, neryl butyrate, Amyl cinnamyl formate, alpha methyl cinnamyl acetate, methyl geranyl tiglate, Mertenyl acetate, farnesyl acetate, fenchyl acetate, geranyl anthranilate, Geranyl butyrate, Gerany isobutyrate, geranyl caproate, geranyl caprylate, Geranyl ethyl carbonate, geranyl formate, geranyl furoate, geranyl heptoate, Geranylmethoxyacetate, geranyl pelargonate, geraniphenyl acetate, geranyl phthalate, Geranyl propionate, geranyl iso-propoxyacetate, geranyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenyl valerate, beta-pentenyl acetate, alpha-phenylallyl acetate, Prenyl acetate, Trichloromethylphenylcarbinylacetat and / or their Mixtures. Allyl alcohol esters can preferably contained in the perfume oil according to the invention be.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are, in particular, ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate. Dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2-methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, 2-tert-butylcyclohexylacetate, Vertenex (4-tert-butylcyclohexylacetate), Violiff (4-cycloocten-1-yl methylcarboxylate), ethenyl iso-amylcarbinylacetate, fenchyl acetate, fenchyl benzoate, Fenchyl-n-butyrate, fenchyl isobutyrate, laevomenthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate, menthyl isobutyrate, menthyl formate, levo-menthyl phenylacetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, Cy clohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formate, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexylphenylacetate, cyclohexylpropionate, cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methyl amylacetate, methylbenzylcarbinylacetate, methylbutylcyclohexanylacetate, 5-methyl-3-butyltetrahydropyran -4-yl acetate, methyl citrate, methyl isophosphate, 2-methylcyclohexyl acetate, 4-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate, 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformate, methyl-2-methylbutyrate Methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methylphenylcarbinylisobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octyl-isobutyrate, beta-pentenylacetate, alpha-phenylallylacetate, phenylethylmethylcarbinyliso-valerate, phenylethylene glycol diphenylacetate, phenylethyethylcarbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, isopropylcaprate, isopropylcaproate, isoporppylcaprylate, isopropylcinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate, isop ulegyl acetate, isopulegyl acetoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate, vanillin triacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ O-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, dimethylbenzyl carbinyl acetate, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenyl formate, Dimethylheptenylpropionat, Dimethylheptenyl iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate Dimethylphenylethylcarbinyl iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-e ugenyl formate, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellyl ethyl carbonate, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyl iosbutyrat, cinnamate Linallylcarproat, Linallylcaprylat, Linallyl, Linallylcitronellat, Linallyl formate, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallyl pelargonate, Linallylphenylacetat, Linallylpropionat, Linallylpyruvat, Linallylsalicylat, Linallyl-n-valerate, Linallyl-iso-valerate, Methylcyclopentenolonebutyrat, methyl cyclopentenolonpropionat, Methylethylphenylcarbinylacetat, Methylheptincarbonat, methyl nicotinate, Myrcenylacetate, Myrcenylformiat, Myrcenyipropionat, cis-ocimenylacetat, phenyl salicylate, terpinyl acetate, Terpinylanthranilat, Terpinylbenzoat, terpinyl-n butyrate, terpinyl isobutyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Some Fragrance esters can both esters of allylic and secondary or allylic and tertiary alcohols in particular amylvinylcarbinyl acetate, amyl vinylcarbinylpropionate, Hexyl vinyl carbinyl acetate, 3-nonyl acetate, 4-hydroxy-2-hexenyl acetate, linallylanthranilate, linallyl benzoate, Linallyl butyrate, linallyl butadate, linallyl carproate, linallyl caprylate, Linallyl cinnamate, linallyl citronellate, linallyl formate, linallylheptoate, Linallyl-N-methylanthranilate, linallylmethyltiglate, linallyl pelargonate, Linalinallyl phenylacetate, linallyl propionate, linallyl pyruvate, linallylsalicylate, Linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, Nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters may also preferably be present in the perfume oil according to the invention be.

allylic Ketones are over following structural feature, C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, allylionone, allylpulegone, amylcyclopentenone, Benzylideneacetone, benzylideneacetophenone, alpha-isomethyl-ionone, 4- (2,6,6-trimethyl-1-cyclohexene-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), Alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2-one), Beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one), Gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones may preferably contained in the perfume oil according to the invention be.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde-benzyl-beta-methoxyethyl acetal, acetaldehyde-di-iso-amyl acetal, acetaldehyde-di-pentanediol acetal, acetaldehyde-di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal , Acetaldehyde phenylethyl-n-propyl acetal, cinnamic aldehyde dimethyl acetal, acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde diiso amyl acetal, acetaldehyde diethyl acetal, acetaldehyde-di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde di-n- propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvanillin dimethylacetal, alpha-amylcinnamic aldehyde-di-iso-propyl acetal, p-tert-amyl phenoxy acetaldehyde diethyl acetal, Anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiole., Benzaldehyde diethyl acetal, benzaldehyde di (ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene glycol acetal, benzaldehyde glyceryl acetal, Benzaldehydpropylenglycolacetal, Cinnamicaldehyddiethylacetal, Citraldiethyl acetal, citral dimethyl acetal, Citralpropyleneglycolacetal, alpha-Methylcinnamicaldehyd diethylacetal, alpha-Cinnamicaldehyddimethylacetal, phenyl acetaldehyde-2,3-butyleneglycol acetal, Phenylacetaldehydcitronellylmethylacetal, Phenylacetaldehyddiallylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal , Phenylacetaldglycerylacetal, Citronellalcyclomonoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof.

acetals can preferably contained in the perfume oil according to the invention be.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume oil according to the invention.

preferred examples for Condensation products of amines and aldehydes are anisaldehyde methyl anthranilate, Aurantiol (hydroxycitronellalmethyl anthranilate), verdantiol (4-tert-butyl-alpha-methyldihydrocinnamaldehyde-methyl anthranilate), Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), Hydroxycitronellalethylanthranilate, Hydroxycitronellal linallylanthranilat, Methyl-N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and aldehydes may preferably be included in the perfume oil of the invention be.

Especially it is advantageous if fragrances such. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, Anisaldehyde (4-methoxybenzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), benzaldehyde, Benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, cetalox (Dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B] -furan), cis-3-hexenylacetate, cis-3-hexenyl salicylate, citronellol, coumarin, cyclohexyl salicylate, Cymal (2-methyl-3- (para-isopropylphenylpropionaldehyde), decylaldehyde, ethylvanillin, Ethyl 2-methyl butyrate, ethylene braseate, eucalyptol, eugenol, exaltolide (Cyclopentadecanolide), Florhydral (3- (3-isopropylphenyl) butanal), Galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethylcyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), heliotropin, Hexyl acetate, hexyl cinnamic aldehyde, hexyl salicylate, hydroxyambrane (2-cyclododecylpropanol), Hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1, 6,7, tetramethylnaphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl benzoic acid methyl ester), Lyral (4- (4-hydroxy-4-methyl-pentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), methyl anthranilate, methyl beta naphthylketoe, methylcedrylon (methylcedrenyl ketone), methylchavicol (1-Methyloxy-4,2-propen-1-yl-benzene), methyldihydrojasmonate, methylnonylacetaldehyde, Musk indanone (4-acetyl-6-tert-butyl-1,1-dimethylindane), nerol, nonalactone (4-hydroxynonanoic acid, lactone), Norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), P.T. Bucinal (2-methyl-3 (para tert butylphenyl) propionaldehyde), para hydroxyphenylbutanone, Patchouli, phenylacetaldehyde, phenylethylacetate, phenylethylalcohol, Phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), Polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), Rosaphen (2-methyl-5-phenyl pentanol), sandalwood, alpha-terpinene, tonalid / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyltetralin), undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecened aldehydes, vanillin and / or mixtures are contained in the perfume oil according to the invention.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentyl-methylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, lobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate,Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
• (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha,γ-dimethylallylaicohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide, Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7a-tetrahydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (-I-)-Limonen, Dihydrocarveol (–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nullartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
• (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
• (ll) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellyibutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar-(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten.

enthalten.The agent according to the invention can according to a preferred embodiment, in particular fragrance fe with

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenalpentyl-methyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, such as preferably mercaptomethylpentanone and / or methoxymethylbutanethiol or
• (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) Fruit odor, such as ethylphenylacetate, geranylvalerate, γ-heptalactone, ethylpropionate, diethylacetal, geranylbutyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, lobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, lmone oxide, hdrocinnamiccohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, nylate, ctronellylbutyrate, heylacetate, nonylacetate, butylmethylbutyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, Epoxy β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3.5 Octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethyl valerate, pentanol, isopiperone, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, butyl hexano at, isopropylbutanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxaline, sesquiphenilene, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or citronellyl isobutyrate or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
• (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylicohol, (Z) -2-pen ten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) -4-decenal, 2-octenal, 2-hepten-1-al, bicyclogermacrene, 2-Octenal, α-Thujene, (Z) -β-Farnesene, (-) - γ-Elemene, 2,4-Octadienal, Fucoserrate, Hexenylacetate, Geranylacetone, Valencene, β-Eudesmol, 1-Hexenol, (E) - 2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butyl isothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -liminene oxide, cis Isocitral, dimethyloctadienal, bornyl formate, bornyl isovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+) - cis-rose oxides, menthone, coumarin, (epoxymethylbutyl) -methylfuran, 2-hexenol , (E) -2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1 , 5,9,9-tetramethyl-12-oxabicyclododeca-4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, hydroxypentanone, (Z) -Ocimene, β-elemene, δ-cadinol, (E) -β-Ocimene, (Z) -dihydrocarvone, α-cadinol, calamenene, (Z) -piperitol , Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquipellandrene, citronellyl valerate, bornyl isovalerate, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7a-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran, dihydrocarvylacetate , β-cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (-I-) limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, Isopulegyl acetate, piperitone, 2,3-dehydro-1,8-cineol, α-terpineol, DL-carvone and / or α-phellandrene or
• (ff) Odorless odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
• (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethylacetate, 2-ethylhexanol, geranylvalerate, geranylacetate, citronellol, geraniol, geranylbutyrate, geranylisovalerate, citronellyibutyrate, citronellylacetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1-) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalylisovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecen-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal, styrene glycol, methyl furanol, (-) - cis-Rose Oxide, (E) -β-Ocimene, Dimethylmethoxyfuranone, 1,8-Cineole, Ethylbenzaldehyde, 2-Pentylthiophene, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z) -3-Hexenyl-2 methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquipellandrene, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate, isopropyl benzoate, safrole, Durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6- (2-propenyl) -1,3- benzodioxole, [1ar- (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-seleneins, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β-Caryophyllene and / or β-Guaiene or
• (vv) mixtures of the above.

contain.

In a preferred embodiment contains the agent of the invention certain minimum values of perfume oil, namely at least 0.00001 wt .-%, advantageously at least 0.0001 wt .-%, in considerably more advantageous Way at least 0.001 wt .-%, more preferably at least 0.01% by weight, more preferably at least 0.1% by weight, in a further advantageous manner at least 0.2 wt .-%, in very advantageous Way at least 0.3 wt .-%, in a particularly advantageous manner at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 Wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in whole considerably advantageously at least 0.55 wt .-%, in extremely advantageous Way at least 0.6 wt .-%, in the highest advantageously at least 0.65% by weight, most advantageously at least 0.7% by weight, in an exceptionally advantageous manner at least 0.75% by weight, in exceptionally advantageous Way at least 0.8 wt .-%, in extremely advantageous Way at least 0.85 wt .-%, in particular at least 0.9 wt .-% of Perfume oil, based on the entire remedy.

In a preferred embodiment the perfume oils contain less as 8, advantageously less than 7, in a more advantageous manner less than 6, more preferably less than 5, more advantageously less than 4, more advantageously less as 3, preferably less than 2, in particular no perfumes from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, Benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, Geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexenecarboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, Farnesol, hexylcinnamaldehyde, lilial, d-limonene, linalool, methylheptin carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, Oakmoss extract, tree moss extract.

To a further preferred embodiment can the agent of the invention be free of perfume oil.

Claims (11)

Washing, care or cleaning agents, which contains a photoactive bleaching agent comprising titanium dioxide. Means according to claim 1, characterized in that the titanium dioxide is a modified titanium dioxide, preferably carbon-modified titanium dioxide. Agent according to one of claims 1 or 2, characterized that the preferably modified titanium dioxide in amounts of 0.000001 to 25 wt .-%, preferably 0.01 to 5 wt .-%, based on the entire remedy. Agent according to one of claims 1-3, characterized in that the carbon content of the carbon-modified titanium dioxide in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt .-%, in particular from 0.4 to 0.8 wt .-% is. Agent according to one of claims 1-4, characterized in that the BET specific surface area of the modified titanium dioxide is preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in particular 200 to 350 m ² / g. Agent according to one of claims 1-5, characterized that the particle size of the modified Titanium dioxide in the range of 2-600 nm, preferably in the range of 200-400 nm Agent according to one of claims 1-6, characterized that besides the modified titanium dioxide at least one further, preferably has a plurality of ingredients, in particular washing, care and / or cleaning active ingredients, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, Alkalizing agents, anti-wrinkle compounds, antibacterial Substances, antioxidants, anti-redeposition agents, antistatic agents, builders, Bleaching agents, bleach activators, bleach stabilizers, bleach catalysts, Ironing Aid, Cobuilder, Dispersants, inlet preventer, electrolytes, enzymes, colorants, dye, Dyes, color transfer inhibitors, Fluorescers, fungicides, germicides, odor-complexing substances, auxiliaries, Hydrotrope, rinse aid, Complexing agents, preservatives, corrosion inhibitors, optical Brightener, perfume carrier, pearlescer, pH adjusting agents, repellents and impregnating agents, polymers, fragrances, swelling agents and Slip Resists, Foam Inhibitors, Phyllosilicates, Dirt Repellent Fabrics, silver protectants, silicone oils, UV protectants, viscosity regulators, Thickeners, discoloration inhibitors, Grayness inhibitors, vitamins and / or fabric softeners. Process for textile treatment, comprising the contacting of the textile comprising an agent according to any one of claims 1-7, at and / or followed by an exposure of the surface of the Textile to light with a wavelength in the range of 300-1200 nm. A method of treating hard surfaces, comprising the contacting of the hard surface with an agent after one the claims 1-7, at and / or followed by exposure of the surface to light with one wavelength in the range of 300-1200 nm. Process for the cosmetic treatment of the human body, comprising contacting body parts with a means according to one of the claims 1-7, at and / or followed by exposure of the treated body part at light with one wavelength in the range of 300-1200 nm. Process for improving (room) air, comprising the contacting of air with an agent according to any one of claims 1-7, containing at least one fragrance, at and / or followed by Irradiation with light having a wavelength in the range of 300-1200 nm.