DE102007019369A1 - Photocatalytic material-containing particles - Google Patents

Abstract

Photocatalytic material-containing particles and granules are described which can serve as detergents or cleaners or at least can be used in them. The use of these particles and granules allows the elimination, deactivation or reduction of impurities and microorganisms, especially bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm. It allows easier removal of colored dirt (colored spots) from Textiles, it allows the reduction of the fiber adhesion of dirt, preferably colored stains, on textiles, it allows to increase the water solubility of dirt, preferably colored stains on textiles, it allows the prevention of the formation of fetid odors on the textiles, it allows the equipment the textiles with a self-cleaning capacity, each with the use of light in the wavelength range of 10-1200 nm.

Description

The The present invention relates to particles and granules, which a) photocatalytic material, b) carrier material and c) contain organic solvent. Further concerns they detergents or cleaners containing such particles and / or Granules contain. Furthermore, it relates to a method for producing these particles and granules. Further it relates to a method for applying fine particulate photocatalytic material on textiles and hard surfaces. Furthermore, it relates to various methods for cleaning, care, Equipment, softening and / or conditioning of textiles by using these articles in a treatment bath the particles according to the invention, granules or washing or cleaning agents, at and / or followed by a Exposure of the article to light in the wavelength range from 10-1200 nm.

Of the Use of photocatalytic materials to combat Dirt and / or unwanted microorganisms is desirable, because the photocatalytic material can become more electromagnetic Operate radiation of a suitable wavelength range, by dirt and / or unwanted microorganisms to reduce photocatalytic or photochemical reaction or to deactivate.

In but usually it is suitable photocatalytic Material around very finely divided substances, for example in the size range of at least <500 nm.

Therefore it is problematic, such finely divided photocatalytic material to incorporate into powder detergents. So can it z. B. not directly into a powdered detergent matrix be incorporated, because then a particle separation occurs, which leads to inhomogeneities in the detergent. D. H. some parts of the detergent would be fractions of the photocatalytic Contain other materials, others would be completely free of it.

The The object of the present invention was therefore the homogeneous incorporation of finely divided photocatalytic material into solid detergent matrices to enable.

These Problem is solved by the subject matter of the present invention namely a particle containing a) photocatalytic Material, b) carrier material and c) organic solvent.

The Particles according to the invention are suitable To be part of a washing or cleaning agent. The invention Particles can also be self-contained Be cleaning agent.

This Subject offers two immediate benefits. First, it allows he improved handling and dosage of the photocatalytic Material, since it is now in "diluted" form.

This explains itself as follows. If a professional z. In 1000 g of a detergent matrix incorporate 0.1% photocatalytic material should, then he would, if he had to photocatalytic Material as such is limited, exactly 1 g of this very Feeding finely divided material and this homogeneously in the Distribute detergent matrix. If he, however, the inventive Particles served, which z. B. 5% photocatalytic material include, then he could already take 20g of these particles and incorporate into the detergent matrix. The amount of work to be done Particles, so it gets bigger and therefore lighter can be handled and dosed and also a more homogeneous distribution of the photocatalytic material throughout the detergent matrix allows. In addition, the invention Particles larger than the photocatalytic starting material, which on the one hand further facilitates the handling and dosage and On the other hand prevents segregation tendencies.

Secondly retains the photocatalytic material used Activity, since it is no longer undesirable Self-agglomeration phenomena of the photocatalytic material, z. B. due to storage and segregation, can come, causing a loss photocatalytic activity would mean.

Furthermore goes with the incorporation of the finely divided photocatalytic material in the solid carrier a very good storage stability which also relates to the entire detergent in which the particles according to the invention can be incorporated. This is an advantage with regard to possible decomposition processes, which at least otherwise from the activity of the photocatalytic Could result in materials in the detergent matrix.

By allowing the use of the photocatalytic material in a "diluted" form possible interactions of the photocatalytic material with sensitive detergent ingredients of a Detergent matrix, such. As perfume, enzymes, bleach, bleach activators, optical brighteners, reduced.

Furthermore is determined by the application of the invention Particles in the textile treatment also a uniform Drawing the photocatalytic material on the treated Textiles possible. In addition, the Dust levels are reduced during detergent production.

The allow particles of the invention Furthermore, a textile-friendly textile treatment, for. B. stain treatment.

The contained photocatalytic material uses electromagnetic Radiation of a suitable wavelength range, by virtue of which z. As contaminants or microbes by photocatalytic or photochemical reaction, e.g. By oxidation or by reduction, degradable, deactivatable or reducible. The photocatalytic Material is in particular a daylight-active material, in particular a daylight active bleach, so uses the electromagnetic Radiation of daylight. For a preferential development The effectiveness of the photocatalytic material is the presence preferably oxygen and / or water required. That's enough z. As the present in water, dissolved oxygen or the water contained in the air (humidity).

The photocatalytic activity of the photocatalytic material advantageously refers to natural or artificial Light in the wavelength range of 10-1200 nm, preferably 300-1200 nm, in particular between 380 and 800 nm. If the photocatalytic material, especially those of the human eye perceptible radiation of the visible region of the spectrum with Wavelengths between 380 and 800 nm for the o. G. Purposes of dismantling, deactivation or reduction of Exploits contaminants, then is a preferred embodiment of the invention. Also UV light (10-380 nm) is very beneficial.

advantageously, even the light passes through glass windows in closed Living spaces come in (diffused daylight), to the desired photocatalytic activity of the photocatalytic material. Even Light from technical light sources (artificial light), such as. B. from commercial Incandescent (incandescent) bulbs, halogen lamps, fluorescent tubes, Kornpaktleuchtstofflampen (energy-saving lamps) and light sources based on light-emitting diodes, is sufficient to the desired Effect. In particular, the natural sunlight leads to very good effects.

The Photocatalytic material can be used in several ways the textile treatment unfold their effect.

First be called the effect in the textile treatment bath. If you z. B. The textiles to be treated are placed in a tub containing a wash liquor contains, in which previously inventive Particles were given, and then this textile treatment bath, for example Light exposes, z. B. in the sun, then unfolds the photocatalytic Material in the textile treatment bath a general cleaning performance. Such is also possible in the textile treatment in an automatic Washing machine which has a window (porthole), as it at least in front loaders is common and / or in washing machine with internal light source.

To the the second is the effect of drying the textile. The im Textile treatment on the textiles to be dried photocatalytic material can interact with light, z. b. by sunlight when drying on a leash outdoors, to develop a general cleaning performance. Such is also possible in the case of textile drying in an automatic Clothes dryer with internal light source.

Thirdly, the effect after drying of the textile should be mentioned. The dried textiles are not really dry in the true sense, but contain a residual moisture, which is in balance with the ambient humidity (room humidity, body moisture). These conditions are sufficient to light exposure, z. As by sunlight, a general cleaning performance caused by the deposited on the textiles photocatalytic material to unfold. This latter effect is particularly advantageous because the treated garments are as it were provided with a long-term protection, so that the clothing is equipped with a self-cleaning ability. This self-cleaning capacity is z. B. advantageous to counteract the emergence of fetid odors, which are on the clothes z. B. sweaty activities (such as sports activities) quickly form. This self-cleaning capacity is z. B. advantageous to prevent the colonization of microbes on textiles or at least complicate. This self-cleaning capacity is z. B. advantageous to ward off or complicate a mounting and solid adhesion of particular colored stains on fibers. The photocatalytically active material is advantageous in order to improve the Wiederschwasbarkeit of colored stains. The photocatalytically active material is able namely under the action of light, the structure of particular colored stains (dyes) z. B by oxidation to destroy. The conjugated double bonds, which are responsible for the absorption of visible light in the dyes and thus for the coloring, are cleaved or hydroxylated. The dye loses its coloring properties and also its strong fiber adhesion. At the same time the water solubility is increased. Thus it can be prevented that a colored spot "eats" into the textile and destroys it permanently.

advantageously, is not only the elimination of conventional pollution, but also the elimination, deactivation, denaturing or Reduction of microbes, in particular harmful microflora or microbial growth, in particular of algae, blue-green algae, Lichens, germs, fungi, molds, mold spores, yeasts, Mites, preferably house dust mites, or more generally of (indoor) Noxen with allergenic potential.

Under Noxa is understood here as a factor affecting the human organism harm, or at least the person in his well-being can affect. These are in particular the factors just mentioned, especially microbiological factors like viruses, bacteria, fungi etc.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften,
• – farbige Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben.

The development of the general cleaning effect, which can be observed in the application of the particles according to the invention, is particularly effective with respect to colored impurities or soiling, which in particular decrease

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B, from green grasses,
• - technical dyes of cosmetics, inks, color pencils,
• - colored metabolites and / or excretory products of mold or other micro flora or microbial growth or microbes.

advantageously, is also the Wiederauswaschbarkeit of colored soiling Textiles containing the particles of the invention were washed, relieved. Usually at the distance from stains on textiles fast action the highest bid, because the fresher a stain, the easier it is he takes off. A drying of stains or other dirt, For example, blood, coffee, tea, ballpoint pen, fruit, red wine or tar stains, especially over several days should usually be avoided so that it does not become a possibly irreversible one Fiber adhesion comes. The present invention brings relief here, because textiles which have been treated with detergents which are the inventive Particles showed that the fiber adhesion of stains or other contaminants has been so attenuated that they could be washed out more easily.

The described advantages also extend to the cleaning hard Surfaces.

The Particles according to the invention contain an organic Solvents. If the organic solvent is at least a nonionic surfactant, preferably from the group of the alkoxylated Fatty alcohols, the alkylphenol polyglycol ether, the alkoxylated Fatty acid alkyl esters, polyhydroxy fatty acid amides, the alkyl glycosides, the alkyl polyglucosides, the amine oxides of the fatty acid glucamides and / or the long-chain alkyl sulfoxides, so is a preferred Embodiment of the invention before. It is beneficial and corresponds to a further preferred embodiment of Invention, when a predominant part of the organic Solvent consists of nonionic surfactant (s), preferably contains the organic solvent is> 50% by weight, advantageously> 60% by weight, more preferably> 70% by weight and in particular> 80% by weight of nonionic surfactant, wherein the indication wt .-% on the total amount of the organic solvent is related. It is even possible that> 90% by weight or even 100% of the total organic solvent of nonionic surfactant (s) consists.

Most suitable organic solvents include alkoxylated fatty alcohol. Thus, if the organic solvent contains alkoxylated fatty alcohol, preferably in amounts of at least 40 wt .-%, advantageously of at least 50 wt .-%, more preferably of at least 60 wt .-%, in excess in some advantageous manner at least 70% by weight, more preferably at least 80% by weight, in particular at least 90% by weight, most preferably in amounts of 100% by weight, in each case by weight to the total amount of the organic solvent, which are advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18, in particular 12 to 18 carbon atoms and preferably on average 1 to 12 moles of alkylene oxide, preferably ethylene oxide, per mole of alcohol, in particular 7 mol Ethylene oxide per mole of alcohol, so is a preferred embodiment of the invention.

Surprisingly could be found that if the organic solvent at least one alkoxylated fatty alcohol comprises, a particularly good storage stability of the invention Particle results. This also applies to detergent matrices, in which the particles can be incorporated. Furthermore was a particularly good, uniform in the washing application Aufziehverhalten the photocatalytic material observed.

If the organic solvent at least one humectant preferably glycerol, dimers and trimers of glycerol, Ethylene glycol, propylene glycol, sugar alcohols, as preferably Glucitol, xylitol, mannitol, alkylpolyglucosides, fatty acid glucamides, Sucrose esters, sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights of 200 to 8000, Propanediols, butanediols, triethylene glycol, hydrogenated glucose syrup and / or mixtures of the abovementioned, preferably in amounts of 0.01 to 50 wt .-%, advantageously 0.1 to 40 wt .-%, in more advantageous Way 1-30 wt .-%, more advantageously 2-20 Wt .-%, in particular 5-15 wt .-%, based on the total amount of the organic solvent, so is also a preferred Embodiment of the invention before.

For example may be preferred organic solvents which 85-95% by weight of nonionic surfactant, preferably alkoxylated fatty alcohol, and 5-15% by weight of humectant, preferably glycerin, contain. In particular, organic solvents are preferred, which consist only of nonionic surfactant and humectants.

It could found that if the organic solvent at least one organic humectant, one further improved deposition of finely divided photoactive material in the Frame of a traditional textile treatment on the textiles resulted. A particularly suitable humectant is glycerol and its dimers and trimers and / or mixtures thereof. We could find that in the presence of the, preferably organic, Humectant means a very good effect of the agent against impurities resulted, especially when using glycerol.

The inventive carrier material comprises preferably inorganic material, in particular zeolite, sulfate, Carbonate, silicate, clay, silicic acid and / or mixtures thereof. This corresponds to a preferred embodiment of the invention.

In a preferred embodiment of the invention included the particles according to the invention alkylpolyglucoside in an amount of 0.1-40 wt .-%, based on the total organic solvents.

Consists the carrier material at least 40 wt .-%, preferably at least 50% by weight, advantageously at least 60% by weight, in a further advantageous manner at least to 70 wt .-%, more advantageously at least 80% by weight, in particular at least 90% by weight inorganic material, advantageously zeolite, in particular Zeolite X, Y, A, P, MAP and / or mixtures thereof, wt .-% based on the entire substrate, so again is one preferred embodiment of the invention.

When very advantageous has the use of spray-dried Powder as inventive carrier material proved. Spray drying is a long established one Process that also in the production of powdered Detergents is applied. The first step of the procedure is the preparation of an aqueous slurry (Slurry) thermally stable (detergent) ingredients that are preferably neither under the conditions of spray-drying volatilize or decompose (eg surfactants, builders, Setting means). Then the slurry is over Pumps transported in a spray tower and over Nozzles sprayed in the head of the tower are located. The sprayed slurry is then rising through Air at a temperature of preferably 200 to 350 ° C. dried and the adhering water is evaporated, so that the used ingredients at the outlet of the tower as fine Powder can be obtained.

• (a) anorganisches Trägermaterial, vorzugsweise umfassend Zeolith, Sulfat, Carbonat, Silikat, Ton, Kieselsäure und/oder deren Gemische, vorzugsweise in Mengen > 30 Gew.-%, vorteilhafterweise > 40 Gew.-%, in weiter vorteilhafter Weise > 50 Gew.-%, noch vorteilhafter > 60 Gew.-%, insbesondere 70–90 Gew.-%,
• (b) Niotensid, insbesondere ethoxylierten Fettalkohol, vorteilhafterweise in Mengen von 0,1–40 Gew.-%. Insbesondere 0,5–5 Gew.-%
• (c) optional Vergrauungsinhibitor, vorzugsweise Carboxymethylcellulose-Natriumsalz, vorzugsweise in Mengen von 0–10 Gew.-%, insbesondere 1–5 Gew.-%,
• (d) optional Wasser, vorzugsweise in Mengen von 0,05–30 Gew.-%, vorteilhafterweise 5–25 Gew.-%, insbesondere 10–20 Gew.-%,
• (e) optional Alkalien, vorzugsweise die Hydroxide der Alkalimetalle, insbesondere Natriumhydroxid und/oder Kaliumhydroxid, Gew.-% jeweils bezogen auf das Trägermaterial, so liegt eine weitere bevorzugte Ausführungsform der Erfindung vor.

If the particles according to the invention as support material thus comprise a spray-dried powder, preferably containing

• (a) inorganic support material, preferably comprising zeolite, sulfate, carbonate, silicate, clay, silicic acid and / or mixtures thereof, preferably in amounts of> 30% by weight, advantageously> 40% by weight, in a further advantageous manner> 50% by weight, more preferably> 60% by weight, in particular 70-90% by weight,
• (B) nonionic surfactant, in particular ethoxylated fatty alcohol, advantageously in amounts of 0.1-40 wt .-%. In particular 0.5-5% by weight
• (c) optionally graying inhibitor, preferably carboxymethylcellulose sodium salt, preferably in amounts of 0-10% by weight, in particular 1-5% by weight,
• (d) optionally water, preferably in amounts of 0.05-30% by weight, advantageously 5-25% by weight, in particular 10-20% by weight,
• (E) optionally alkalis, preferably the hydroxides of the alkali metals, in particular sodium hydroxide and / or potassium hydroxide, wt .-% in each case based on the carrier material, so is a further preferred embodiment of the invention.

When photocatalytic material is according to a preferred embodiment of the invention contain titanium dioxide, in particular a modified one Titanium dioxide, preferably a carbon-modified titanium dioxide.

The photocatalytic material, in particular the (preferably modified) Titanium dioxide, according to a preferred embodiment the invention in the particle according to the invention in amounts of advantageously 0.0001 to 30 wt .-%, preferably 0.001 to 20 wt .-%, advantageously 0.01 to 15 wt .-%, in a further advantageous manner 0.1 to 10 wt .-%, even more advantageous 1 to 5 wt .-%, wt .-% based on the total particles.

To a preferred embodiment is in the (preferably modified) titanium dioxide around with carbon modified titanium dioxide. But it can also be modified differently Titanium dioxides are used, for example, modified with nitrogen Titanium dioxide or z. B. doped with rhodium and / or platinum ions Titanium dioxide. However, it is particularly according to the invention preferably that it is non-metal modified titanium dioxide is.

The carbon content of the advantageously carbon-modified titanium dioxide may in a preferred embodiment in the range of 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5 wt. %, in particular from 0.4 to 0.8% by weight. Advantageously, the TiO ₂ content of the carbon-modified titanium dioxide z. B. over 95 wt .-%, 96 wt .-%, 97 wt .-%, 98 wt .-% or 99 wt .-%, based on the total carbon-modified titanium dioxide.

If the carbon only in a surface layer of the titanium dioxide particles is embedded, so is a preferred embodiment in front. The modified titanium dioxide may advantageously additionally Contain nitrogen.

If the specific surface of the titanium dioxide, preferably of the modified titanium dioxide, after BET (BET advantageously after DIN ISO 9277: 2003-05 determined, preferably also simplified after DIN 66132: 1975-07 ) preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in a further advantageous manner 200 to 350 m ² / g, in particular 250 to 300 m ² / g, so is also a preferred embodiment.

The carbon-modified titanium dioxide may according to a preferred embodiment, for. Example, be obtained by intimately mixing a titanium compound having a specific surface area of preferably at least 50 m ² / g by BET, with an organic carbon compound and the mixture is thermally treated at a temperature of up to 350 ° C.

The thereby usable carbonaceous substance can according to a preferred Embodiment be a carbon compound, which contains at least one functional group, preferably selected from OH, CHO, COOH, NHx, SHx. In particular, can it is in the carbon compound is a compound of the Group ethylene glycol, glycerine, succinic acid, pentaerythritol, Carbohydrates, sugars, starch, alkylpolyglucosides, organoammonium hydroxides or mixtures thereof. It is also possible that used as the carbonaceous substance carbon black or activated carbon becomes.

It may also be preferred that the carbonaceous substance, which is advantageously mixed with the titanium compound, after the thermal treatment to the modified titanium dioxide to reach a decomposition temperature of at most 400 ° C. preferably <350 ° C and particularly preferably <300 ° C having.

The Preferably used for the preparation of the modified titanium dioxide Titanium compound which according to the aforementioned preferred embodiment with an organic carbon compound intimately mixed can be an amorphous, semi-crystalline or crystalline Titanium oxide or hydrous titanium oxide or a titanium hydrate or a titanium oxyhydrate, which in turn is a preferred embodiment equivalent.

The thermal treatment of the mixture of the titanium compound and the Carbon compound can according to a preferred embodiment advantageously in a continuously operated calcining unit, preferably a rotary kiln are performed. The modified titanium dioxide can be, in particular in the context of the previously described, preferably z. B. obtained thereby, that a titanium dioxide (eg with a particle size in the range between 2 to 600 nm or z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. 200 to 400 nm), such as commercially available in powder or mud form, takes and from this a suspension in a liquid, preferably water. To the suspension is then advantageously a carbonaceous Substance added and it is mixed. Mixing can be supported be through the use of ultrasound. The mixing process (eg Stirring) may preferably last several hours, preferably 2, 4, 6, 8, 10 or 12 hours or even longer. Based on the solids of the suspension is the amount of the carbon compound advantageously 1-40 wt .-%, accordingly, the amount the titanium compound is preferably 60-99% by weight.

After that the liquid is removed, for example by filtration, Evaporate in vacuo or decant, and the residue is preferably dried (eg, preferably at temperatures from 70-200 ° C, advantageously over several hours, for example at least 12 hours) and then calcined, for example at a temperature of at least 260 ° C, preferably z. B. at 300 ° C, preferably over a period of several hours, preferably 1-4 hours, in particular 3 hours. The calcination can advantageously take place in a closed vessel.

It may be advantageous that the calcination temperature, z. B. 300 ° C, within an hour is reached (slow Heating to 300 ° C).

there is preferably a color change of the powder from white to dark brown to beige or slightly yellowish-brownish. Too long a heating leads to inactive, colorless powders. The expert can estimate this with a few routine experiments. The calcination can, for. B. advantageously done so long, until after a color change of the powder from white over dark brown another color change to beige or slightly yellowish-brownish takes place.

A maximum temperature of 350 ° C should preferably not be exceeded. In the thermal treatment there is a decomposition of the organic carbon compound on the surface of the titanium compound, so preferably a modified titanium dioxide is formed, preferably 0.005-4 Wt .-% carbon.

After the thermal treatment, the product is advantageously deagglomerated by known methods, for example in a pin mill, jet mill or counter-jet mill. The grain fineness to be achieved depends on the grain size of the starting titanium compound. The particle size or specific surface area of the product is only slightly lower, but of the same order of magnitude as that of the educt. The desired grain fineness of the photocatalyst depends on the field of application of the photocatalyst. It is usually in the range as with TiO ₂ pigments, but may also be below or above.

The in the particles of the invention contained photocatalytic Material, preferably modified titanium dioxide can advantageously a particle size in the range of 2 to 600 nm, ie z. B. 3 to 150 nm or z. B. 4 to 100 nm or z. B. 5 to 75 nm or z. B. 10 to 30 nm or z. B. 200 to 400 nm. The particle size of the photocatalytic material, preferably modified titanium dioxide, although preferably in the range of 100-500 nm, advantageously 200-400 nm lie. It may also be preferred that the particle size is very small, z. In the range 2-150 nm, preferably 3-100 nm, advantageously 4-80 nm or z. B. 5-50 nm or z. B. 8-30 nm or z. B. 10-20 nm is located.

Very small particles, e.g. B. with a particle size in particular 2, 3, 4, 5 or 10 nm, can also with each other Agglomerates form, which then correspondingly larger are, for. B. up to 600 nm or up to 500 nm or up to 400 nm or up to 300 nm in size, etc.

The particle size can be z. Advantageously at values such as 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. In particular, very small particle sizes below 50 nm, below 40 nm, below 30 nm or below 20 nm may be preferred.

It may be advantageous in the preparation of the modified titanium dioxide micronized titanium dioxide, that is, titanium dioxide with very small particle size, e.g. B. between 2 and 150 nm or z. b. between 5 and 100 nm. The particle size can then z. Advantageously at values such as 2 nm, 3 nm, 4 nm, 5 nm, 10 nm, 15 nm, 20 nm, 25 nm, 30 nm, 35 nm, 40 nm, 45 nm, 50 nm or 60 nm. Such values are preferred.

The Bulk density of the preferably modified titanium dioxide is preferably in the range of 100 to 800 g / l, advantageously from 200 to 600 g / l, especially from 300 to 500 g / l. For example the bulk density may be 350 g / l, 400 g / l or 500 g / l.

To In a preferred embodiment, this is (preferably modified) titanium dioxide in the anatase crystal modification.

The The modified titanium dioxide described above is characterized a very good photocatalytic activity, in particular using daylight, off. Especially those of the human Eye perceptible radiation of the visible region of the spectrum with wavelengths between 380 and 800 nm are used for the purposes of mining, deactivating or reducing Impurities from the described modified titanium dioxide very well used. Also UV radiation between 10-380 nm can be used very well.

• a) photokatalytisches Material in Mengen von 0,01–40 Gew.-%, vorzugsweise 0,1–30 Gew.-%, vorteilhafterweise 1–20 Gew.-%, noch vorteilhafter 5–15 Gew.-%, insbesondere 8–12 Gew.-%
• b) Trägermaterial, vorzugsweise umfassend sprühgetrocknetes Pulver, insbesondere umfassend Zeolith, in Mengen von 30–90 Gew.-%, vorzugsweise 40–80 Gew.-%, vorteilhafterweise 50–70 Gew.-%, insbesondere 55–65 Gew-%
• c) organisches Lösemittel, vorzugsweise Niotensid und/oder Feuchthaltemittel, in Mengen von 5–60 Gew.-%, vorzugsweise 10–50 Gew.-%, vorteilhafterweise 20–40 Gew.-%, insbesondere 25–35 Gew.-%.

A particularly preferred particle according to the invention comprises according to a preferred embodiment of the invention

• a) photocatalytic material in amounts of 0.01-40% by weight, preferably 0.1-30% by weight, advantageously 1-20% by weight, more preferably 5-15% by weight, in particular 8% 12% by weight
• b) support material, preferably comprising spray-dried powder, in particular comprising zeolite, in amounts of 30-90 wt .-%, preferably 40-80 wt .-%, advantageously 50-70 wt .-%, in particular 55-65 wt%
• c) organic solvent, preferably nonionic surfactant and / or humectant, in amounts of 5-60 wt .-%, preferably 10-50 wt .-%, advantageously 20-40 wt .-%, in particular 25-35 wt .-%.

Farther it may be advantageous if the inventive Particles include Aviviermittel. Accordingly, inventive Particles comprising a lubricant, preferably oils, Cationic surfactants, in particular esterquats, phyllosilicates, fatty acid derivatives, Silicone oils, polymers, such as preferably polymeric cationic surfactants silicone-based or polyethylene-based polymers, preferably in an amount of 0.05 to 10 wt .-%, preferably 0.1-5 Wt .-% by weight based on the total particles, a preferred Embodiment of the invention.

hand modifiers help the grip, the shine, the color brilliance, the softness and / or to improve the smoothness of the tissues treated with it. Particularly suitable are esterquats. Esterquat is the collective name for cationic surface-active compounds with two hydrophobic groups that have ester bonds with a quaternized di (tri-) ethanolamine or an analogous Connection are linked. Suitable lubricants are described below. The avivage component includes, for example quaternary ammonium compounds such as monoalk (en) yltrimethylammonium compounds, Dialk (en) yldimethylammonium compounds, mono-, di- or triesters of fatty acids with alkanolamines.

wobei in (I) R für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R¹ für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R² und R³ entweder gleich R oder R¹ sind oder für einen aromatischen Rest stehen. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (I) sind Monotalgtrimethylammoniumchlorid, Monostearyltrimethylammoniumchlorid, Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples of employable quaternary ammonium compounds are shown, for example, in the formulas (I) and (II):

wherein in (I) R is an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{1 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ² and R ^{3 are} either R or R ¹ or are an aromatic radical , X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (I) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride chloride or dihexadecylammonium chloride.

Compounds of formula (II), (III) and (IV) are so-called ester quats. Esterquats are characterized by excellent biodegradability. In formula (II) R ^{4 is} an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these anions. Preference is given to compounds in which R ^{5 represents} the group O (CO) R ⁷ . Particular preference is given to compounds in which R ^{5 is} the group O (CO) R ⁷ and R ⁴ and R ^{7 are} alk (en) yl radicals having 16 to 18 carbon atoms. Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (I) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyloxyethyl) ammonium methosulfate, bis (palmitoyloxyethyl) hydroxyethylmethylammonium methosulfate, 1,2-bis- [tallowloxy] -3-trimethylammoniumpropane chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate.

Are z. B. quaternized compounds of formula (II) are used which have unsaturated alkyl chains, the acyl groups are preferred, the corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45 and having a cis / trans isomer ratio (in wt%) of greater than 30:70, preferably greater than 50:50, and more preferably equal to or greater than 60:40. Commercial examples are sold by Stepan under the tradename Stepantex ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under Dehyquart ^® Cognis products, known under Rewoquat ^® products from Degussa or those known under Tetranyl ^® products of Kao. Further preferred compounds are the diesterquats corresponding to formula (III) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

Instead of the ester group O (CO) R, where R is a long chain Alk (en) ylrest, z. B. plasticizing compounds can be used, which have the following groups: RO (CO), N (CO) R or RN (CO), of which N (CO) R groups are preferred are.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.In addition to the optional quaternary compounds described above, e.g. B. Other compounds are used as softening component, such as, for example, quaternary imidazolinium compounds of the formula (IV),

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt, X^– ein Anion ist und r eine Zahl zwischen 0 und 5 ist. Ein bevorzugtes Beispiel einer kationischen Abscheidungshilfe gemäß Formel (V) ist 2,3-Bis[talgacyloxy]-3-trimethylammoniumpropanchlorid.Further particularly preferably employable softening compounds are described by formula (V),

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group, X ^{- is} an anion and r is a number between 0 and 5. A preferred example of a cationic deposition aid according to formula (V) is 2,3-bis [tallowacyloxy] -3-trimethylammoniumpropane chloride.

Further Softening components which can be used according to the invention provide quaternized protein hydrolysates or protonated amines represents.

Furthermore, cationic polymers are also suitable softening component. Suitable cationic polymers include the polyquaternium polymers as described in U.S. Pat CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997) , in particular the polyquaternium-6, polyquaternium-7, polyquaternium-10 polymers (Polymer JR, LR and KG series from Amerchol), also referred to as merquats, polyquaternium-4 copolymers, such as graft copolymers having a cellulose backbone and quaternary ammonium groups allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyl triammonium chloride, and similar quaternized guar derivatives (e.g., Cosmedia Guar from Cognis or Jaguar series from Rhodia), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. As the commercial product Glucquat ^® 100, according to CTFA nomenclature a "Lauryl Methyl Gluceth-10 hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, aminosilicone polymers and copolymers.

Polyquaternized polymers (for example Luviquat ^® Care from BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Some said cationic polymers additionally have skin and / or textile care properties.

Also usable are compounds of the formula (VI)

R ¹⁷ can be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl and X ^- is an anion.

Further Suitable softening components include protonated or quaternized Polyamines.

Especially preferred plasticizing components are alkylated quaternary Ammonium compounds, of which at least one alkyl chain an ester group and / or amido group is interrupted. Most notably preferred are N-methyl-N- (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate or bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate.

It may also contain nonionic softening components especially polyoxyalkylene glycol alkanoates, polybutylenes, long-chain fatty acids, ethoxylated fatty acid ethanolamides, Alkyl polyglucosides, in particular sorbitan mono, di- and triesters, and fatty acid esters of polycarboxylic acids

Also among the most preferred optionally usable softening agents are cationic cellulose derivatives, cationic starches, copolymers of a diallyl quaternary ammonium salt and an acrylamide, quaternized vinylpyrrolidone vinylimidazole polymer polyglycolamine condensates, quaternized collagen polypeptides, polyethyleneimine, cationized silicon polymer (e.g., amodimethicone), cationic silicon polymers, e.g. , B. provided in a mixture with other components under the trademark Dow Corning 929 (cationized emulsion), copolymers of adipic acid and dimethylaminohydroxypropyldiethylenetriamine, cationic chitin derivatives, cationized guar gum (e.g., Jaguar CBS, Jaguar C-17, Jaguar C-16, etc., manufactured by Celanese Company), quaternary ammonium salt polymers (e.g., Mirapol A-15, Mirapol AD-1, Mirapol AZ-1, etc., manufactured by the Miranol Division of the Rhone Poulenc Company). Particularly preferred is polyquaternium-11 available as Luviquat.RTM ^® PQ 11 sold by the BASF Corporation.

To a preferred embodiment of the invention are also Skin care or skin care active ingredients in the inventive Contain particles, in particular in amounts> 0.01 wt .-%, wt .-% based on the total Particle.

Skin care products (skin-care active ingredients) can in particular those Be agents that give the skin a sensory benefit, z. By delivering lipids and / or moisturizing factors. Skin care products may, for. Proteins, amino acids, Lecithins, lipids, phosphatides, plant extracts, vitamins; also fatty alcohols, fatty acids, fatty acid esters, Waxes, Vaseline, paraffins act as skin care products.

• a) Wachse wie beispielsweise Carnauba, Spermaceti, Bienenwachs, Lanolin und/oder Derivate derselben und andere.
• b) Hydrophobe Pflanzenextrakte
• c) Kohlenwasserstoffe wie beispielsweise Squalene und/oder Squalane
• d) Höhere Fettsäuren, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurinsäure, Stearinsäure, Behensäure, Myristinsäure, Palmitinsäure, Ölsäure, Linolsäure, Linolensäure, Isostearinsäure und/oder mehrfach ungesättigte Fettsäuren und andere.
• e) Höhere Fettalkohole, vorzugsweise solche mit wenigstens 12 Kohlenstoffatomen, beispielsweise Laurylalkohol, Cetylalkohol, Stearylalkohol, Oleylalkohol, Behenylalkohol, Cholesterol und/oder 2-Hexadecanaol und andere.
• f) Ester, vorzugsweise solche wie Cetyloctanoate, Lauryllactate, Myristyllactate, Cetyllactate, Isopropylmyristate, Myristylmyristate, Isopropylpalmitate, Isopropyladipate, Butylstearate, Decyloleate, Cholesterolisostearate, Glycerolmonostearate, Glyceroldistearate, Glyceroltristearate, Alkyllactate, Alkylcitrate und/oder Alkyltartrate und andere.
• g) Lipide wie beispielsweise Cholesterol, Ceramide und/oder Saccharoseester und andere.
• h) Vitamine wie beispielsweise die Vitamine A und E, Vitaminalkylester, einschließlich Vitamin C Alkylester und andere.
• i) Sonnenschutzmittel
• j) Phospholipide
• k) Derivate von alpha-Hydroxysäuren
• m) Germizide für den kosmetischen Gebrauch, sowohl synthetische wie beispielsweise Salicylsäure und/oder andere als auch natürliche wie beispielsweise Neemöl und/oder andere.
• n) Silikone

sowie Mischungen jeglicher vorgenannter Komponenten.Skin-care active substances are all those active substances which give the skin a sensory and / or cosmetic advantage. Skin-care active substances are preferably selected from the following substances:

• a) waxes such as carnauba, spermaceti, beeswax, lanolin and / or derivatives thereof and others.
• b) Hydrophobic plant extracts
• c) hydrocarbons such as squalene and / or squalane
• d) Higher fatty acids, preferably those having at least 12 carbon atoms, for example lauric acid, stearic acid, behenic acid, myristic acid, palmitic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and / or polyunsaturated fatty acids and others.
• e) Higher fatty alcohols, preferably those having at least 12 carbon atoms, for example, lauryl alcohol, cetyl alcohol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cholesterol and / or 2-hexadecanol and others.
• f) esters, preferably such as cetyloctanoates, lauryl lactates, myristyl lactates, cetyl lactates, isopropyl myristates, myristyl myristates, isopropyl palmitates, isopropyl adipates, butyl stearates, decyl oleates, cholesterol stearates, glycerol monostearates, glycerol distearates, glycerol tristearates, alkyl lactates, alkyl citrates and / or alkyl tartrates and others.
• g) lipids such as cholesterol, ceramides and / or sucrose esters and others.
• h) vitamins such as vitamins A and E, vitamin C esters, including vitamin C alkyl esters and others.
• i) sunscreen
• j) phospholipids
• k) derivatives of alpha hydroxy acids
• m) Germicides for cosmetic use, both synthetic and, for example, salicylic acid and / or others as well as natural ones such as neem oil and / or others.
• n) silicones

as well as mixtures of any of the aforementioned components.

preferred skin-care active substances are also essential oils, in particular selected from the group of Angelica fine - Angelica archangelica, anise - Pimpinella anisum, Benzoin siam - Styrax tokinensis, cabreuva - myrocarpus fastigiatus, cajeput - melaleuca leucadendron, Cistrose - Cistrus ladaniferus, Copaiba balm - Copaifera reticulata, Costus root - Saussurea discolor, Edeltannennadel - Abies alba, Elemi - Canarium luzonicum, Fennel - Foeniculum dulce spruce needle - Picea abies, Geranium - Pelargonium graveolens, Ho leaves - Cinnamonum camphora, Immortelle Helichrysum ang., Ginger extra - Zingiber off., St. John's wort - Hypericum perforatum, jojoba, chamomile German - Matricaria recutita, chamomile blue fine - Matricaria chamomilla, chamomile roman - Anthemis nobilis, chamomile wild - Ormensis multicaulis, carrot - Daucus carota, mountain pine - Pinus mugho, Lavandin - Lavendula hybrida, Litsea Cubeba - (May Chang), Manuka - Leptospermum scoparium, melissa - Melissa officinalis, sea pine - Pinus pinaster, myrrh - Commiphora molmol, myrtle - myrtus communis, Neem - Azadirachta, Niaouli - (MQV) Melaleuca quin. viridiflora, Palmarosa - Cymbopogom martini, Patchouli - Pogostemon patchouli, Peru balsam - Myroxylon balsamum var. pereirae, Raventsara aromatica, rosewood - Aniba pink odora, sage - Salvia officinalis Horsetail - Equisetaceae, Yarrow extra - Achillea millefolia, plantain - Plantago lanceolata, Styrax - Liquidambar orientalis, Tagetes (Marigold) Tagetes patula, Tea Tree - Melaleuca alternifolia, Tolu Balsam - Myroxylon balm around L., Virginia cedar - Juniperus virginiana, frankincense (Olibanum) - Boswellia carteri, silver fir - Abies alba.

Preferred skin-care active substances are also skin-protecting oils, in particular selected from the group algae oil Oleum Phaeophyceae, aloe vera oil aloe vera brasiliana, apricot kernel oil Prunus armeniaca, arnica oil Arnica montana, avocado oil Persea americana, borage oil Borago officinalis, calendula oil Ca lendula officinalis, Camellia oil Camellia oleifera, Thistle oil Carthamus tinctorius, Peanut oil Arachis hypogaea, Hemp oil Cannabis sativa, Hazelnut oil Corylus avellana, Hypericum perforatum, Jojoba oil Simondsia chinensis, Caraway oil Daucus carota, Coconut oil Cocos nucifera, Pumpkin seed oil Curcubita pepo, Kukui nut oil Aleurites moluccana, Macadamia nut oil Macadamia ternifolia, almond oil Prunus dulcis, olive oil Olea europaea, pear seed oil Prunus persica, rapeseed oil Brassica oleifera, castor oil Ricinus communis, black seed oil Nigella sativa, sesame seed oil Sesamium indicum, sunflower oil Helianthus annus, grape seed oil Vitis vinifera, walnut oil Juglans regia, wheat germ oil Triticum sativum.

To a further preferred embodiment of the invention contains a particle according to the invention Fragrances (perfume oil), preferably in quantities from 0.01 to 10 wt .-%, wt .-% based on the total particles. The fragrances promote the acceptance of the product Consumers and convey a sense of cleanliness. suitable Fragrances are described below.

Especially In combination with humectants and nonionic surfactant could be a special long lasting odor effect of the fragrances can be observed. This concerns both the particles of the invention as such as the objects treated with it.

According to one Another preferred embodiment of the invention the particles according to the invention are powdered and / or surrounded by a coating, these preferably thermoplastics, such as PEG, PVA, polyacrylates, PVP, carbohydrates, polyesters as preferably PET includes.

Contain the particles of the invention carrier material with a mean particle size between 0.1 and 2.0 mm, preferably 0.15 and 1.5 mm, in particular 0.2 and 1.2 mm, so again is a preferred embodiment of Invention.

One Another object of the invention are granules, which aggregates of several inventive Particles include. Such granules are available by agglomeration of the particles according to the invention, z. B in a mixer using conventional binders. The aggregates can in addition to the invention Particles also contain other particles.

One Another object of the invention is a washing or cleaning agent, containing particles according to the invention and / or Granules.

To a preferred embodiment of the invention Particles, granules, detergents or cleaners contain other optional ingredients, in particular washing, care and / or cleaning active ingredients, advantageously selected from the group comprising anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, acidifiers, Alkalizing agents, antibacterial agents, antioxidants, anti redeposition agents, Antistatic agents, builders, bleaches, bleach activators, Bleach stabilizers, bleach catalysts, cobuilders, dispersants, Electrolytes, enzymes, colorants, dyes, dyes, Fluorescers, fungicides, germicides, odor-complexing substances, Auxiliaries, hydrotropes, rinse aids, complexing agents, preservatives, Corrosion inhibitors, optical brighteners, perfume carriers, Pearlescing agent, pH-adjusting agent, repellent and impregnating agent, Polymers, fragrance (s) (perfume (oil)), swelling and Anti-slip agents, foam inhibitors, phyllosilicates, dirt-repellent Fabrics, silver protectants, silicone oils, viscosity regulators, Thickeners, discoloration inhibitors, grayness inhibitors and / or vitamins.

• (a) Aniontenside, vorzugsweise Alkylbenzolsulfonate, Alkansulfonate, Methylestersulfonate, α-Olefinsulfonate, Alkylsulfate und/oder Alkylethersulfate, vorteilhafterweise in Mengen von 0–40 Gew.-%, vorzugsweise in Mengen von 1–25 Gew.-%, insbesondere in Mengen von 5–15 Gew.-%
• (b) Nichtionische Tenside, vorzugsweise alkoxylierte Fettalkohole, Alkylphenolpolyglykolether, alkoxylierte Fettsäurealkylester, Polyhydroxyfettsäureamide, Alkylglykoside, Alkylpolyglucoside, Saccharoseester, Sorbitanester, Aminoxide, Fettsäureglucamide und/oder der langkettigen Alkylsulfoxide, vorteilhafterweise in Mengen von 0–20 Gew.-%, vorzugsweise 0,1–15 Gew.-%, insbesondere 1–10 Gew.-%,
• (c) Gerüststoffe, vorzugsweise Zeolith, alkalische amorphe Disilicate, kristalline Schichtsilicate Polycarboxylat und/oder Natriumcitrat, vorteilhafterweise in Mengen von 0–70 Gew.-%, vorzugsweise 5–60 Gew.-%, insbesondere 10–50 Gew.-%,
• (d) Alkalien, vorzugsweise NaOH, KOH und/oder Natriumcarbonat, vorteilhafterweise in Mengen von 0–30 Gew.-%, vorzugsweise 1–25 Gew.-%, insbesondere 5–15 Gew.-%
• (e) Bleichmittel, vorzugsweise Natriumperborat und/oder, Natriumpercarbonat, vorzugsweise in Mengen von 0–25 Gew.-%, insbesondere 5–20 Gew.-%,
• (f) Korrosionsinhibitoren, vorzugsweise Natriumsilicat, vorteilhafterweise in Mengen von 0–10 Gew.-%, vorzugsweise 0,5–6 Gew.-%, insbesondere 1–5 Gew.-%,
• (g) Stabilisatoren, vorzugsweise Phosphonate, vorteilhafterweise 0–5 Gew.-%, insbesondere 0.01–1 Gew.-%,
• (h) Schauminhibitor, vorzugsweise Seife, Siliconöle und/oder Paraffine, vorteilhafterweise in Mengen von 0–8 Gew.-%, vorzugsweise 0,1–5 Gew.-%, insbesondere 1–4 Gew.-%,
• (i) Enzyme, vorzugsweise Proteasen, Amylasen, Mannanasen, Tannasen, Cellulasen und/oder Lipasen, vorteilhafterweise in Mengen von 0–5 Gew.-%, vorzugsweise 0,1–5 Gew.-%, insbesondere 0,5–2 Gew.-%,
• (j) Vergrauungsinhibitor, vorzugsweise Carboxymethyl-cellulose, vorteilhafterweise in Mengen von 0–2 Gew.-%, insbesondere 0,01–1 Gew.-%,
• (k) Verfärbungsinhibitor, vorzugsweise Polyvinylpyrrolidon-Derivate, vorteilhafterweise in Mengen von 0–2 Gew.-%, vorzugsweise 0,01–1,2 Gew.-%, insbesondere 0,05–0,5 Gew.-%,
• (l) Stellmittel, vorzugsweise Natriumsulfat, vorteilhafterweise in Mengen von 0–50 Gew.-%, vorzugsweise 5–40 Gew.-%, insbesondere 10–30 Gew.-%,
• (m) Duftstoffe, vorzugsweise in Mengen von 0–10 Gew.-%, insbesondere 0,01–5 Gew.-%,
• (n) Optische Aufheller, vorzugsweise Stilben-Derivate und/oder Biphenyl-Derivate, vorteilhafterweise in Mengen von 0–3 Gew.-%, vorzugsweise 0,01–1 Gew.-%, insbesondere 0,005–0,5 Gew.-%,
• (o) Aviviermittel, vorzugsweise Öle, Kationtenside, wie insbesondere Esterquats, Schichtsilicate, Fettsäure-Derivate, Siliconöle, Polymere, wie vorzugsweise polymere Kationtenside auf Siliconbasus oder Polymere auf Basis von Polyethylen, enthalten ist, vorzugsweise in einer Menge von 0 bis 15 Gew.-%, vorteilhafterweise 0,1–10 Gew.-%, insbesondere 0,5–5 Gew.-%,
• (p) hautpflegende Aktivstoffe, vorzugsweise solche, wie weiter oben beschrieben, vorzugsweise in einer Menge von 0 bis 15 Gew.-%, vorteilhafterweise 0,1–10 Gew.-%, insbesondere 0,5–5 Gew.-%,
• (q) Wasser, vorzugsweise in Mengen von 0–30 Gew.-%, vorzugsweise 0,1 bis 20 Gew.-%, insbesondere 1–15 Gew.-%
• (r) optional Salzersatzpolymere, vorzugsweise solche wie nachfolgend beschrieben, insbesondere in Mengen > 0,01 Gew.-%.

A preferred washing or cleaning agent according to the invention, in addition to the particles and / or granules according to the invention z. B. include the following components (both individual of these components as well as all these components):

• (A) anionic surfactants, preferably alkylbenzenesulfonates, alkanesulfonates, methyl ester sulfonates, α-olefinsulfonates, alkyl sulfates and / or alkyl ether sulfates, advantageously in amounts of 0-40 wt .-%, preferably in amounts of 1-25 wt .-%, in particular in amounts of 5-15% by weight
• (b) Nonionic surfactants, preferably alkoxylated fatty alcohols, alkylphenol polyglycol ethers, alkoxylated fatty acid alkyl esters, polyhydroxy fatty acid amides, alkyl glycosides, alkyl polyglucosides, sucrose esters, sorbitan esters, amine oxides, fatty acid glucamides and / or the long-chain alkyl sulfoxides, advantageously in amounts of 0-20% by weight, preferably 0, 1-15% by weight, in particular 1-10% by weight,
• (c) builders, preferably zeolite, alkaline amorphous disilicates, crystalline layered silicates, polycarboxylate and / or sodium citrate, advantageously in amounts of 0-70% by weight, preferably 5-60% by weight, in particular 10-50% by weight,
• (d) alkalis, preferably NaOH, KOH and / or sodium carbonate, advantageously in amounts of 0-30 Wt .-%, preferably 1-25 wt .-%, in particular 5-15 wt .-%
• (e) Bleaching agent, preferably sodium perborate and / or sodium percarbonate, preferably in amounts of 0-25% by weight, in particular 5-20% by weight,
• (f) corrosion inhibitors, preferably sodium silicate, advantageously in amounts of 0-10% by weight, preferably 0.5-6% by weight, in particular 1-5% by weight,
• (g) stabilizers, preferably phosphonates, advantageously 0-5% by weight, in particular 0.01-1% by weight,
• (h) foam inhibitor, preferably soap, silicone oils and / or paraffins, advantageously in amounts of 0-8% by weight, preferably 0.1-5% by weight, in particular 1-4% by weight,
• (I) enzymes, preferably proteases, amylases, mannanases, tannases, cellulases and / or lipases, advantageously in amounts of 0-5 wt .-%, preferably 0.1-5 wt .-%, in particular 0.5-2 wt .-%,
• (j) grayness inhibitor, preferably carboxymethyl cellulose, advantageously in amounts of 0-2% by weight, in particular 0.01-1% by weight,
• (k) discoloration inhibitor, preferably polyvinylpyrrolidone derivatives, advantageously in amounts of 0-2% by weight, preferably 0.01-1.2% by weight, in particular 0.05-0.5% by weight,
• (I) adjusting agent, preferably sodium sulfate, advantageously in amounts of 0-50 wt .-%, preferably 5-40 wt .-%, in particular 10-30 wt .-%,
• (m) fragrances, preferably in amounts of 0-10% by weight, in particular 0.01-5% by weight,
• (n) optical brighteners, preferably stilbene derivatives and / or biphenyl derivatives, advantageously in amounts of 0-3% by weight, preferably 0.01-1% by weight, in particular 0.005-0.5% by weight .
• (O) Aviviermittel, preferably oils, cationic surfactants, such as in particular esterquats, layered silicates, fatty acid derivatives, silicone oils, polymers, such as preferably polymeric cationic surfactants based on silicone or polyethylene-based polymers, preferably in an amount of 0 to 15 wt. %, advantageously 0.1-10% by weight, in particular 0.5-5% by weight,
• (p) skin-care active substances, preferably those as described above, preferably in an amount of 0 to 15% by weight, advantageously 0.1-10% by weight, in particular 0.5-5% by weight,
• (q) water, preferably in amounts of 0-30% by weight, preferably 0.1 to 20% by weight, in particular 1-15% by weight
• (R) optionally salt replacement polymers, preferably those as described below, in particular in amounts> 0.01 wt .-%.

The aforementioned Components, d. H. some of these, several or all of them this, can also be part of the invention Particles and / or granules.

suitable Salt substitute polymers which are preferably usable are, for example the sulfonic acid-containing polymers, which with particular Preference be used.

Especially preferably used as sulfonic acid-containing polymers are copolymers of unsaturated carboxylic acids, Sulfonic acid-containing monomers and optionally further ionogenic or nonionogenic monomers.

In the context of the present invention are as unsaturated monomer carboxylic acids of the formula R ¹ (R ² ) C = C (R ³ ) COOH in which R ¹ to R ³ independently of one another are -H, -CH ₃ , a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, NH ₂ , -OH or -OOOH substituted alkyl or alkenyl radicals or for -OOOH or -COOR ⁴ , wherein R ^{4 is} a saturated or unsaturated, straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms.

Among the unsaturated carboxylic acids which can be described by the above formula, especially acrylic acid (R ¹ = R ² = R ³ = H), methacrylic acid (R ¹ = R ² = H; R ³ = CH ₃₎ and / or maleic acid (R ¹ = COOH; R ² = R ³ = H) is preferred.

In the sulfonic acid-containing monomers are those of the formula R ⁵ (R ⁶ ) C = C (R ⁷ ) -X-SO ₃ H in which R ⁵ to R ^{7 are} independently of one another sown for -H, -CH ₃ , a straight-chain or branched one alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, alkyl or alkenyl radicals substituted by -NH ₂ , -OH or -COOH, or -COOH or -COOR ⁴ , wherein R ^{4 is} a saturated or unsaturated, straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms, and X is an optionally present spacer group which is selected from - (CH ₂ ) _n - where n = 0 to 4, -COO- ( CH ₂ ) _k - with k = 1 to 6, -C (O) -NH-C (CH ₃ ) ₂ - and -C (O) -NH-CH (CH ₂ CH ₃ ) -.

Preferred among these monomers are those of the formulas H ₂ C = CH-X-SO ₃ H H ₂ C = C (CH ₃ ) -X-SO ₃ H HO ₃ SX- (R ⁶ ) C = C (R ⁷ ) -X-SO ₃ H, in which R ⁶ and R ^{7 are} independently selected from -H, -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ and X is an optional spacer group which is selected from - (CH ₂ ) _n - with n = 0 to 4, -COO- (CH ₂ ) _k - with k = 1 to 6, -C (O) -NH-C (CH ₃ ) ₂ - and - C (O) -NH-CH (CH ₂ CH ₃ ) -.

Especially preferred sulfonic acid-containing monomers are included 1-acrylamido-1-propanesulfonic acid, 2-acrylamido-2-propanesulfonic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3-Methacrylamido-2-hydroxypropanesulfonic acid, allylsulfonic acid, Methallylsulfonic acid, allyloxybenzenesulfonic acid, Methallyloxybenzenesulfonic acid, 2-hydroxy-3- (2-propenyloxy) propanesulfonic acid, 2-methyl-2-propene-1-sulfonic acid, styrenesulfonic acid, Vinyl sulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate, Sulfomethacrylamide, sulfomethylmethacrylamide and water-soluble Salts of the acids mentioned.

Particularly suitable other ionic or nonionic monomers are ethylenically unsaturated compounds. The content of the polymers used in these other ionic or nonionic monomers is preferably less than 20% by weight, based on the polymer. Particularly preferred polymers to be used consist only of monomers of the formula R ¹ (R ² ) C =C (R ³ ) COOH and monomers of the formula R ⁵ (R ⁶ ) C =C (R ⁷ ) -X-SO ₃ H.

• i) ungesättigten Carbonsäuren der Formel R¹(R²)C=C(R³)COOH in der R¹ bis R³ unabhängig voneinander für -H, -CH₃, einen geradkettigen oder verzweigten gesättigten Alkylrest mit 2 bis 12 Kohlenstoffatomen, einen geradkettigen oder verzweigten, ein- oder mehrfach ungesättigten Alkenylrest mit 2 bis 12 Kohlenstoffatomen, mit -NH₂, -OH oder -COOH substituierte Alkyl- oder Alkenylreste wie vorstehend definiert oder für -COOH oder -COOR⁴ steht, wobei R⁴ ein gesättigter oder ungesättigter, geradkettigter oder verzweigter Kohlenwasserstoffrest mit 1 bis 12 Kohlenstoffatomen ist,
• ii) Sulfonsäuregruppen-haltigen Monomeren der Formel R⁵(R⁶)C=C(R⁷)-X-SO₃H in der R⁵ bis R⁷ unabhängig voneinander für -H, -CH₃, einen geradkettigen oder verzweigten gesättigten Alkylrest mit 2 bis 12 Kohlenstoffatomen, einen geradkettigen oder verzweigten, ein- oder mehrfach ungesättigten Alkenylrest mit 2 bis 12 Kohlenstoffatomen, mit -NH₂, -OH oder -COOH substituierte Alkyl- oder Alkenylreste wie vorstehend definiert oder für -OOOH oder -COOR⁴ steht, wobei R⁴ ein gesättigter oder ungesättigter, geradkettigter oder verzweigter Kohlenwasserstoffrest mit 1 bis 12 Kohlenstoffatomen ist, und X für eine optional vorhandene Spacergruppe steht, die ausgewählt ist aus -(CH₂)_n- mit n = 0 bis 4, -COO-(CH₂)_k- mit k = 1 bis 6, -C(O)-NH-C(CH₃)₂- und -C(O)-NH-CH(CH₂CH₃)-
• iii) gegebenenfalls weiteren ionogenen oder nichtionogenen Monomeren besonders bevorzugt.

In summary, copolymers are made of

• i) unsaturated carboxylic acids of the formula R ¹ (R ² ) C = C (R ³ ) COOH in the R ¹ to R ³ independently of one another are -H, -CH ₃ , a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, alkyl or alkenyl radicals substituted by -NH ₂ , -OH or -COOH as defined above, or -COOH or -COOR ⁴ , where R ^{4 is} a saturated or unsaturated, straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms,
• ii) sulfonic acid group-containing monomers of the formula R ⁵ (R ⁶ ) C =C (R ⁷ ) -X-SO ₃ H in the R ⁵ to R ⁷ independently of one another are -H, -CH ₃ , a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, alkyl or alkenyl radicals substituted by -NH ₂ , -OH or -COOH as defined above, or -OOOH or -COOR ⁴ in which R ^{4 is} a saturated or unsaturated, straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms, and X is an optionally present spacer group which is selected from - (CH ₂ ) _n - where n = 0 to 4, -COO- (CH ₂ ) _k - with k = 1 to 6, -C (O) -NH-C (CH ₃ ) ₂ - and -C (O) -NH-CH (CH ₂ CH ₃ ) -
• iii) optionally further ionic or nonionic monomers are particularly preferred.

• i) einer oder mehreren ungesättigter Carbonsäuren aus der Gruppe Acrylsäure, Methacrylsäure und/oder Maleinsäure
• ii) einem oder mehreren Sulfonsäuregruppen-haltigen Monomeren der Formeln: H₂C=CH-X-SO₃H H₂C=C(CH₃)-X-SO₃H HO₃S-X-(R⁶)C=C(R⁷)-X-SO₃H, in der R⁶ und R⁷ unabhängig voneinander ausgewählt sind aus -H, -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH(CH₃)₂ und X für eine optional vorhandene Spacergruppe steht, die ausgewählt ist aus -(CH₂)_n- mit n = 0 bis 4, -COO-(CH₂)_k- mit k = 1 bis 6, -C(O)-NH-C(CH₃)₂- und -C(O)-NH-CH(CH₂CH₃)-
• iii) gegebenenfalls weiteren ionogenen oder nichtionogenen Monomeren.

Further particularly preferred copolymers consist of

• i) one or more unsaturated carboxylic acids from the group of acrylic acid, methacrylic acid and / or maleic acid
• ii) one or more sulfonic acid group-containing monomers of the formulas: H ₂ C = CH-X-SO ₃ H H ₂ C = C (CH ₃ ) -X-SO ₃ H HO ₃ SX- (R ⁶ ) C = C (R ⁷ ) -X-SO ₃ H, in which R ⁶ and R ^{7 are} independently selected from -H, -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ and X is an optional spacer group which is selected from - (CH ₂ ) _n - with n = 0 to 4, -COO- (CH ₂ ) _k - with k = 1 to 6, -C (O) -NH-C (CH ₃ ) ₂ - and - C (O) -NH-CH (CH ₂ CH ₃ ) -
• iii) optionally further ionogenic or nonionic monomers.

The Copolymers may be the monomers from groups i) and ii) and optionally iii) in varying amounts, wherein all representatives from the group i) with all Representatives from group ii) and all representatives from group iii) can be combined. Especially Preferred polymers have certain structural units which described below.

For example, copolymers which are structural units of the formula are preferred - [CH ₂ -CHCOOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p - in which m and p are each an integer between 1 and 2,000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein spacer groups in which Y. for -O- (CH ₂ ) _n - with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - are, are preferred.

These polymers are prepared by copolymerization of acrylic acid with a sulfonic acid-containing acrylic acid derivative. When the acrylic acid derivative containing sulfonic acid groups is copolymerized with methacrylic acid, another polymer is obtained whose use is likewise preferred. The corresponding copolymers contain the structural units of the formula - [CH ₂ -C (CH ₃ ) COOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p -, in which m and p are each an integer between 1 and 2000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein O- (CH ₂ ) _n - with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - is, are preferred.

Acrylic acid and / or methacrylic acid can also be copolymerized completely analogously with methacrylic acid derivatives containing sulfonic acid groups, as a result of which the structural units in the molecule are changed. Thus, copolymers which are structural units of the formula - [CH ₂ -CHCOOH] _m - [CH ₂ -C (CH ₃ ) C (O) -Y-SO ₃ H] _p - in which m and p are each an integer between 1 and 2,000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein spacer groups in which Y. for -O- (CH ₂ ) with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - is, are particularly preferred, just as preferred as copolymers, the structural units of the formula - [CH ₂ -C (CH ₃ ) COOH] _m - [CH ₂ -C (CH ₃ ) C (O) -Y-SO ₃ H] _p - in which m and p are each an integer between 1 and 2,000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein spacer groups in which Y. for -O- (CH ₂ ) _n - with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - are, are preferred.

Instead of acrylic acid and / or methacrylic acid or in addition thereto, maleic acid can also be used as a particularly preferred monomer from group i). This gives way to inventively preferred copolymers, the structural units of the formula - [HOOCCH-CHCOOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p - in which m and p are each an integer between 1 and 2000 and Y is a spacer group which is selected from substituted or unsubstituted aliphatic, aromatic or Araliphatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein spacer groups in which Y is -O- (CH ₂ ) where n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) -, are preferred. Also preferred according to the invention are copolymers which contain structural units of the formula - [HOOCCH-CHCOOH] _m - [CH ₂ -C (CH ₃ ) C (O) OY-SO ₃ H] _p - in which m and p are each an integer between 1 and 2,000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having 1 to 24 carbon atoms, wherein spacer groups in which Y. for -O- (CH ₂ ) _n - with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - are, are preferred.

In summary, such copolymers are preferred according to the invention, the structural units of the formulas - [CH ₂ -CHCOOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p - - [CH ₂ -C (CH ₃ ) COOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p - - [CH ₂ -CHCOOH] _m - [CH ₂ -C (CH ₃ ) C (O) -Y-SO ₃ H] _p - - [CH ₂ -C (CH ₃ ) COOH] _m - [CH ₂ -C (CH ₃ ) C (O) -Y-SO ₃ H] _p - - [HOOCCH-CHCOOH] _m - [CH ₂ -CHC (O) -Y-SO ₃ H] _p - - [HOOCCH-CHCOOH] _m - [CH ₂ -C (CH ₃ ) C (O) OY-SO ₃ H] _p - in which m and p are each an integer between 1 and 2,000 and Y is a spacer group selected from substituted or unsubstituted aliphatic, aromatic or substituted aromatic hydrocarbon radicals having from 1 to 24 carbon atoms, wherein spacer groups in which Y for -O- (CH ₂ ) _n - with n = 0 to 4, for -O- (C ₆ H ₄ ) -, for -NH-C (CH ₃ ) ₂ - or -NH-CH (CH ₂ CH ₃ ) - are, are preferred.

In the polymers, the sulfonic acid groups completely or partially in neutralized form, d. H. that this acidic hydrogen atom of the sulfonic acid group in some or all sulfonic acid groups against metal ions, preferably Alkali metal ions and in particular against sodium ions, exchanged can be. The use of partially or fully neutralized sulfonic acid group-containing Copolymer is preferred according to the invention.

The Monomer distribution of the invention preferred copolymers used in copolymers which only Monomers from groups i) and ii), preferably in each case 5 to 95% by weight of i) or ii), particularly preferably 50 to 90% by weight Monomer from group i) and 10 to 50 wt .-% monomer from the group ii), in each case based on the polymer.

at Terpolymers are particularly preferred which contain from 20 to 85% by weight. Monomer from group i), 10 to 60 wt .-% monomer from the group ii) and 5 to 30 wt .-% of monomer from group iii).

The molar mass of the sulfo copolymers which can preferably be used according to the invention can be varied in order to adapt the properties of the polymers to the desired intended use. Preferred washing or cleaning agents are characterized in that the copolymers have molar masses of 2000 to 200,000 gmol ^-1 , preferably from 4000 to 25,000 gmol ^-1 and in particular from 5000 to 15,000 gmol ^-1 .

To a preferred embodiment of the invention is the Washing and / or cleaning agents according to the invention in portioned form, preferably in a pouch or as a tablet.

Another object of the invention is a process for preparing a particle according to the invention in which a suspension of photocatalytic material and an organic solvent is formed in a first step, and the resulting suspension is mixed in a second step with a solid support material. Preferably, in the suspension, the photocatalytic material is microfine dispersed, in particular, the photocatalytic material contained is visually not recognizable as a solid.

The to be used photocatalytic material and the organic solvent are preferably those as already described above were. The organic solvent thus preferably contains nonionic surfactant and / or humectants.

The solid support material to be used is preferably that which has already been described above, therefore preferably comprises inorganic material, in particular zeolite, sulfate, carbonate, Silicate, clay, silica and / or mixtures thereof, in particular spray dried material.

The Weight ratio of the photocatalytic material to organic solvent in the prepared suspension may preferably be in the range of 1: 1 to 1:40, advantageously 2: 3 to 1:30, in a further advantageous manner in the range of 1: 2 to 1:20 lie. In particular, weight ratios of the photocatalytic Material to organic solvent in the range of 1: 2 to 1:15, z. B. 1: 2 to 1:10 or 1: 2 to 1: 5 can be very be beneficial. For example, a weight ratio from photocatalytic material to organic solvent from 1: 3 very beneficial.

Especially it is advantageous if> 50 Wt .-%, preferably> 60 % By weight, in particular> 70% by weight consist of the entire suspension of nonionic surfactant.

at mixing the suspension with the solid support material may advantageously 40 to 90 wt .-%, preferably 50 to 80 wt .-%, in particular 60-70 wt .-% of solid support material with advantageously 10 to 60% by weight, preferably 20-50, in particular 30-40% by weight of suspension are reacted, Wt .-% based on the total weight of suspension and solid support material.

Should the particles to be produced contain other ingredients, so These can be incorporated in different ways. For example, solids and liquids with incorporated into the above suspension before these in a second step with a solid support material is mixed. For example, solids and liquids then added when the suspension with a solid support material is mixed. For example, suitable solids and liquids also in the solid carrier material be incorporated before this mixed with said suspension becomes. Again, it is possible after the mixing step the suspension with a solid support material in which the desired particles result in after-treatment of these particles, for example, to load or spray liquids, z. B. with perfume, and / or with solids abzupudern. In particular, combinations of the aforementioned procedures are possible.

In a preferred embodiment of the invention of the invention Procedure, the resulting particles in a further step by granulation in a mixer using a binder converted into coarser granules. It is also possible, the particles not only with him itself, but also to agglomerate with other particles. advantageously Weis are also other agglomeration applicable, z. B. fluidized bed process.

suitable Granulation liquids can z. B. aqueous Solutions of polymers or tacky substances, eg. B. Glucose, his. Aqueous granulation fluids can z. For example, salts, water glass, alkyl polyglycosides, carbohydrates (Saccharides), natural and / or synthetic polymers, especially cellulose ethers, polyacrylates, starch, PEG, PVAL and / or biopolymers, e.g. B. contain xanthan gum. As granulation liquids also low-water systems can be used, for example based on organic solvents, the swollen polymers contain. It is also possible anhydrous granulation liquids to use, for. B. melts or di- or polyhydric alcohols.

Also it is possible to use multiphase granulation fluids to use, for example, aqueous systems, for. B. on Base of an oil-polymer-water emulsion, based on a Surfactant mixture with air or based on a system of nonionic surfactant and polymer solution. Again, anhydrous systems can be used, namely z. As solids-containing melts, or systems of polymer and solvent.

advantageously, can the granulating agent solubility improver (Hydrotrope) include.

typical Hydrotropes are z. As xylene or cumene sulfonate or other substances such as As urea or N-methylacetamide.

Especially Granulation foams are also suitable. A granulation foam you get z. B., if you have a flowable Component subjected to a gaseous medium and thus foams. A granulation foam is for example a surfactant foam obtained by foaming a flowable, surfactant-containing component with a gaseous medium was obtained and can be used as Granulationshilfsmittel. Of the Granulation foam preferably has mean pore sizes below 10 mm, preferably below 5 mm and especially below 2 mm, on. By using a granulation foam instead of conventional Granulating liquids can be even more homogeneous Liquid distributions achieved during the granulation process become. It is preferred if at least one granulation foam and at least one granulation fluid during granulation be used. The particles to be granulated can even better wetted when granulation foam is used.

The resulting granules can be a bulk density in the range of 200-1500 g / l. The lower limit for the bulk density can also be at a value of preferably 250, 300, 350, 400, 450, 500, 550, 600, 650, 700 or even at 750 g / L. It is also possible that the lower limit is even higher, z. At 800 g / L. The upper limit for the bulk density can at a value of preferably 1450, 1400, 1350, 1300, 1250, 1200, 1150, 1100, 1050, 1000, 950, 900, 850, 800 or 750 g / L. It is also possible that the upper limit is even deeper lies, z. B. at a value of preferably 700, 650, 600, 550 or 500 g / L.

One Another object of the invention is a process for the preparation a powdered detergent or cleaning agent, wherein in a first step, particles according to the invention or granules are provided, and in one further step mixed with a powdered detergent or cleaning agent matrix become.

One Another object of the invention is a method for purification hard surfaces, especially dishes, by treatment these hard surfaces with a cleaning fluid, containing particles according to the invention, granules and / or washing or cleaning agents after, at and / or followed from an exposure of the hard surface to light in the Wavelength range of 10-1200 nm. containing particles according to the invention, granules and / or detergents or cleaning agents, means that the particles according to the invention, granules and / or washing or cleaning agents in a liquid, preferably water are dissolved.

In In a preferred embodiment, the foregoing Method using an automatic dishwasher, preferably an automatic dishwasher with Light source performed.

One Another object of the invention is a method for applying fine particulate photocatalytic material on textiles by treating these textiles in a textile treatment bath, to which particles according to the invention, granules or detergents or cleaning agents.

One Another object of the invention is a method for cleaning, Care, equipment, conditioning and / or conditioning of Textiles by treating these textiles in a textile treatment bath, to which particles according to the invention, granules or washing or cleaning agents, at and / or followed by an exposure of the textile article to light in the wavelength range from 10-1200 nm.

serves this method of elimination, deactivation or reduction of microorganisms, especially bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm, such is a preferred embodiment of the invention in front.

serves the method according to the invention for the prophylaxis treatment of textiles in the form of an anticipatory defense and inhibition of Stains and stains on the textile using light in the wavelength range of 10-1200 nm, so is also a preferred embodiment of the invention in front. In this case one speaks of a dirt-repellent equipment, d. H. Stains should be prevented or made more difficult or the pollutability of textiles is made more difficult.

serves the inventive method for equipment of textiles with photocatalytic material for relief the removability of colored dirt (colored spots) of textiles using light in the wavelength range of 10-1200 nm, so is a preferred embodiment of the invention. In this case, one speaks of a dirt-removal and / or Dirt Eliminability Facilitation Equipment, d. H. the removability of dirt or its leachability of Textiles are made easier.

serves the inventive method for equipment of textiles with photocatalytic material to reduce the Fiber adhesion of dirt, preferably colored Stains on textiles using light in the wavelength range from 10-1200 nm, so is a preferred embodiment of the invention.

serves the inventive method for equipment of textiles with photocatalytic material to increase the water solubility of dirt, preferably colored Stains on textiles, using light in the wavelength range from 10-1200 nm, so is a preferred embodiment of the invention.

serves the inventive method for equipment of textiles with photocatalytic material to prevent the Forming fetid smells on the textiles, using light in the wavelength range of 10-1200 nm, so is a preferred embodiment of the invention.

serves the inventive method for equipment of textiles with photocatalytic material, so that the Textiles have a self-cleaning capacity, using light in the wavelength range of 10-1200 nm, so is a preferred embodiment of the invention.

• – rote bis blaue Anthocyanfarbstoffe, wie z. B. Cyanidin, z. B. aus Kirschen oder Heidelbeeren,
• – rotes Betanidin aus der roten Beete,
• – orangerote Carotinoide wie z. B. Lycopin, beta-Carotin, z. B. aus Tomaten oder Möhren,
• – gelbe Curcumafarbstoffe, wie z. B. Curcumin, z. B. aus Curry und Senf,
• – braune Gerbstoffe, z. B. aus Tee, Obst, Rotwein
• – tiefbraune Huminsäure, z. B. aus Kaffee, Tee, Kakao,
• – grünes Chlorophyll, z. B, aus grünen Gräsern,
• – technische Farbstoffe aus Kosmetika, Tinten, Farbstiften
• – (farbige) Stoffwechselprodukte und/oder Ausscheidungsprodukte von Schimmelpilzen oder anderer Mirkoflora oder mikrobiellem Bewuchs oder Mikroben,

unter Einsatz von Licht im Wellenlängenbereich von 10–1200 nm,
so liegt abermals eine bevorzugte Ausführungsform der Erfindung vor.The method according to the invention is used for the removal, removal or reduction of stains and stains on textiles, which originate from:

• - red to blue anthocyanin dyes, such as. B. cyanidin, z. From cherries or blueberries,
• - red betanidin from the red bed,
• - orange-red carotenoids such. As lycopene, beta-carotene, z. From tomatoes or carrots,
• - Yellow curcuma dyes, such as. B. curcumin, z. From curry and mustard,
• - brown tannins, z. B. from tea, fruit, red wine
• - deep brown humic acid, z. B. from coffee, tea, cocoa,
• - green chlorophyll, z. B, from green grasses,
• - Technical dyes from cosmetics, inks, color pencils
• - (colored) metabolites and / or excretions from molds or other micro flora or microbial fouling or microbes,

using light in the wavelength range of 10-1200 nm,
so again is a preferred embodiment of the invention.

One inventive method executed using an automatic washing machine, preferably an automatic washing machine with light source turns, in turn a preferred embodiment of the invention.

One inventive method in which it is is a manual process which takes place in an open tub or a bowl or similar container is carried out, in particular hand wash, prewash and / or soaking, taking the tub after being treated Textiles are penetrated with the wash liquor, light in the wavelength range from 10-1200 nm, especially sunlight, preferably for a period> 5 Minutes, represents another preferred embodiment of the invention.

All The above-described methods are particularly effective below Utilization of light in the visible range (380-800 nm) and / or in the UV range (10-380 nm). It corresponds, therefore, based on all the aforementioned methods, each one preferred Embodiment, when light in the wavelength range 380-800 nm and / or in the range 10-380 is used.

One Another object of the invention is the use of inventive Particles, granules and detergents in textile treatment, in particular textile laundry, for Facilitating the removability of dirt, preferably colored Dirt (colored stains) of textiles, using light in the wavelength range of 10-1200 nm, by equipment textiles with photocatalytic material.

One Another object of the invention is the use of inventive Particles, granules and detergents in textile treatment, in particular textile laundry, for Toughening the pollutability of textiles, especially the Pollution with colored spots, using light in the Wavelength range of 10-1200 nm, by equipment textiles with photocatalytic material.

One Another object of the invention is the use of inventive Particles, granules and detergents in textile treatment to reduce fiber adhesion of dirt, preferably colored dirt (colored spots) on Textiles, using light in the wavelength range from 10-1200 nm, by finishing the textiles with photocatalytic material.

One Another object of the invention is the use of inventive Particles, granules and detergents in textile treatment to increase the water solubility of Dirt, preferably colored dirt (colored spots) on textiles, using light in the wavelength range of 10-1200 nm, by equipping the textiles with photocatalytic Material.

One Another object of the invention is the use of inventive Particles, granules and detergents in the textile treatment to prevent the emergence of fetid Odors on textiles, using light in the wavelength range from 10-1200 nm, by finishing the textiles with photocatalytic material.

One Another object of the invention is the use of inventive Particles, granules and detergents in the textile treatment to furnish the textiles with a Self-cleaning ability, using light in the wavelength range from 10-1200 nm, by finishing the textiles with photocatalytic material.

at All of the above uses light in the wavelength range of 10-380 nm and / or 380-800 nm is preferred.

in the The following are preferred, possible ingredients of particles according to the invention, granules and / or detergents or cleaning agents which optionally contain can be described in more detail. The invention Particles, granules and / or detergents or cleaning agents are hereinafter referred to by the term "erfindungemäßen Means or means. If so hereinafter referred to as funds, so are the inventive Particles, granules and / or detergents or cleaning agents meant.

Anionic surfactants may preferably be present in the agents according to the invention. As anionic surfactants, for example, those of the sulfonate type and sulfates are used. The surfactants of the sulfonate type are preferably C _9-13 -alkylbenzenesulfonates, olefinsulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates, as are obtained, for example, from C _12-18 -monoolefins having terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acid hydrolysis of the sulfonation products into consideration. Also suitable are alkanesulfonates which are obtained from C _12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization. Likewise, the esters of α-sulfo fatty acids (ester sulfonates), z. As the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids suitable.

Further Suitable anionic surfactants are sulfated fatty acid glycerol esters. Among fatty acid glycerol esters are the mono-, di- and triesters As well as their mixtures to understand, as in the production through Esterification of a monoglycerine with 1 to 3 moles of fatty acid or in the transesterification of triglycerides with 0.3 to 2 moles of glycerol to be obtained. Preferred sulfated fatty acid glycerol esters are the sulfonation of saturated fatty acids with 6 to 22 carbon atoms, for example caproic acid, Caprylic acid, capric acid, myristic acid, Lauric acid, palmitic acid, stearic acid or behenic acid.

Alk (en) ylsulfates are the alkali metal salts and in particular the sodium salts of the sulfuric monoesters of C ₁₂ -C ₁₈ fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C ₁₀ -C ₂₀ oxo alcohols and those half-esters of secondary alcohols of these chain lengths are preferred. Also preferred are alk (en) ylsulfates of said chain length, which contain a synthetic, produced on a petrochemical basis straight-chain alkyl radical, which have an analogous degradation behavior as the adequate compounds based on oleochemical raw materials. Of washing technology interest, the C ₁₂ -C ₁₆ alkyl sulfates and C ₁₂ -C ₁₅ alkyl sulfates and C ₁₄ -C ₁₅ alkyl sulfates are preferred. 2,3-alkyl sulfates can be obtained as commercial products from Shell Oil Company under the name DAN ^®, are suitable anionic surfactants.

Also, the sulfuric acid monoesters of the straight-chain or branched C _7-21 -alcohols ethoxylated with from 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C _9-11 -alcohols having on average 3.5 mol of ethylene oxide (EO) or C _12-18 fatty alcohols with 1 to 4 EO are suitable. Due to their high foaming behavior, they are preferably used only in relatively small amounts, in particular in cleaning agents. The agents according to the invention may preferably be free of sulfuric acid monoester.

Another class of anionic surfactants is the class of ether carboxylic acids obtainable by the reaction of fatty alcohol ethoxylates with sodium chloroacetate in the presence of basic catalysts. They have the general formula: R ¹⁰ O- (CH ₂ -CH ₂ -O) _p -CH ₂ -COOH with R ¹⁰ = C ₁ -C ₁₈ and p = 0.1 to 20. Ethercarboxylic acids are water hardness insensitive and have excellent surfactant properties on.

suitable anionic surfactants are, for example, the partial esters of Di- or polyhydroxyalkanes, mono- and disaccharides, polyethylene glycols with the EO adducts of maleic anhydride at least monounsaturated carboxylic acids having a chain length from 10 to 25 carbon atoms with an acid number of 10 to 140.

preferred anionic surfactants have, in addition to an unbranched or branched, saturated or unsaturated, aliphatic or aromatic, acyclic or cyclic, optionally alkoxylated Alkyl radical having 4 to 28, preferably 6 to 20, in particular 8 to 18, more preferably 10 to 16, most preferred 12 to 14 carbon atoms, two or more anionic, in particular two, acid groups, preferably carboxylate, sulfonate and / or sulfate groups, in particular a carboxylate and a sulfate group. Examples of these compounds are the alpha sulfo fatty acid salts, the acylglutamates, the monoglyceride disulfates and the alkyl ethers Glycerindisulfats and in particular those described below monoesterified sulfosuccinates.

Particularly preferred anionic surfactants are the sulfosuccinates, sulfosuccinamates and sulfosuccinamides, especially sulfosuccinates and sulfosuccinamates, most preferably sulfosuccinates. The sulfosuccinates are the salts of the mono- and di-esters of sulfosuccinic acid HOOCCH (SO ₃ H) CH ₂ COOH, while the sulfosuccinamates are the salts of the monoamides of sulfosuccinic acid and the sulfosuccinamides are the salts of the diamides of sulfosuccinic acid ,

at the salts are preferably alkali metal salts, ammonium salts and mono-, di- or Trialkanolammoniumsalze, for example, mono-, Di- or triethanolammonium salts, in particular to lithium, sodium, Potassium or ammonium salts, particularly preferably sodium or ammonium salts, extremely preferably sodium salts.

In the sulfosuccinates, one or both carboxyl groups of the sulfosuccinic acid is preferably with one or two identical or different unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alcohols having 4 to 22, preferably 6 to 20, in particular 8 to 18 , more preferably 10 to 16, most preferably 12 to 14 carbon atoms esterified. Particularly preferred are the esters of unbranched and / or saturated and / or acyclic and / or alkoxylated alcohols, in particular unbranched, saturated fatty alcohols and / or unbranched, saturated, with ethylene and / or propylene oxide, preferably ethylene oxide, alkoxylated fatty alcohols having a degree of alkoxylation of 1 to 20, preferably 1 to 15, in particular 1 to 10, more preferably 1 to 6, most preferably 1 to 4. The monoesters are preferred in the context of the present invention over the diesters. A particularly preferred sulfosuccinate is Sulfobernsteinsäurelaurylpolyglykolester-di-sodium salt (lauryl EO sulfosuccinate, di-sodium salt; INCI Disodium Laureth Sulfosuccinate), for example, as Tego ^® sulfosuccinate F 30 (Goldschmidt) with a sulfosuccinate of 30 parts by weight % is commercially available.

In form the sulfosuccinamates or sulfosuccinamides or form both carboxyl groups of sulfosuccinic preferably with a primary or secondary am in, the one or two identical or different, unbranched or branched, saturated or unsaturated, acyclic or cyclic, optionally alkoxylated alkyl radicals having 4 to 22, preferably 6 to 20, especially 8 to 18, particularly preferably 10 to 16, extremely preferably 12 to 14 carbon atoms, a carboxylic acid amide. Particular preference is given to unbranched and / or saturated and / or acyclic alkyl radicals, in particular unbranched, saturated fatty alkyl radicals.

Also suitable are, for example, the following sulfosuccinates and sulfosuccinamates designated as INCI: Ammonium Dinonyl Sulfosuccinates, Ammonium Lauryl Sulfosuccinates, Diammonium Dimethicone Copolyol Sulfosuccinates, Diammonium Lauramido MEA Sulfosuccinates, Diammonium Lauryl Sulfosuccinates, Diammo Nium Oleamido PEG-2 Sulfosuccinate, Diamyl Sodium Sulfosuccinate, Dicapryl Sodium Sulfosuccinate, Dicyclohexyl Sodium Sulfosuccinate, Diheptyl Sodium Sulfosuccinate, Dihexyl Sodium Sulfosuccinate, Diisobutyl Sodium Sulfosuccinate, Dioctyl Sodium Sulfosuccinate, Disodium Cetearyl Sulfosuccinate, Disodium Cocamido MEA Sulfosuccinate, Disodium CocamidoGlucoside Sulfosuccinate, Disodium Cocoyl Butyl Gluceth-10 Sulfosuccinate, Disodium C12-15 Pareth Sulfosuccinate, Disodium Deceth-5 Sulfosuccinate, Disodium Deceth-6 Sulfosuccinate, Disodium Dihydroxyethyl Sulfosuccinyl undecylenate, Disodium Dimethicone Copolyol Sulfosuccinate, Disodium Hydrogenated Cottonseed Glyceride Sulfosuccinate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamido MEA Sulfosuccinate , Disodium isostearamido MIPA sulfosuccinates, disodium isostearyl sulfosuccinates, disodium laneth-5 sulfosuccinates, disodium lauramido MEA sulfosuccinates, disodium lauramido PEG-2 sulfosuccinates, disodium lauramido PEG-5 sulfosuccinates, Disodium Laureth-6 Sulfosuccinate, Disodium Laureth-9 Sulfosuccinate, Disodium Laureth-12 Sulfosuccinate, Disodium Lauryl Sulfosuccinate, Disodium Myristamido MEA Sulfosuccinate, Disodium Nonoxynol-10 Sulfosuccinate, Disodium Oleamido MEA Sulfosuccinate, Disodium Oleamido MIPA Sulfosuccinate, Disodium Oleamido PEG- 2 sulfosuccinates, disodium oleth-3 sulfosuccinates, disodium oleyl sulfosuccinates, disodium palmitamido PEG-2 sulfosuccinates, disodium palmitoleeamido PEG-2 sulfosuccinates, disodium PEG-4 cocamido MIPA sulfosuccinates, disodium PEG-5 lauryl citrate sulfosuccinates, disodium PEG-8 palm glycerides sulfosuccinates , Disodium Ricinoleamido MEA Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Stearamido MEA Sulfosuccinate, Disodium Stearyl Sulfosuccinamate, Disodium Stearyl Sulfosuccinate, Disodium Tallamido MEA Sulfosuccinate, Disodium Tallowamido MEA Sulfosuccinate, Disodium Tallow Sulfosuccinamate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamido MEA Sulfosucc i-nate, Disodium Undecylenamido PEG-2 Sulfosuccinate, Disodium Wheat Germamido MEA Sulfosuccinate, Disodium Wheat Germamido PEG-2 Sulfosuccinate, Di-TEA-Ole-amido PEG-2 Sulfosuccinate, Ditridecyl Sodium Sulfosuccinate, Sodium Bisglycol Ricinosulfosuccinate, Sodium / MEA Laureth -2 sulfosuccinates and tetrasodium dicarboxyethyl stearyl sulfosuccinamate. Yet another suitable sulfosuccinamate is disodium C _16-18 alkoxypropylene sulfosuccinamate.

Another suitable class of compounds are anionic surfactant-cation complexes, the cation itself initially having surfactant properties. Examples are transesterification products of LAS acid with amines, amine derivatives containing a C chain with> 2 C atoms, preferably C ₁₂ -C ₁₆ . These can be z. B. be oxidized on nitrogen, ie, for example, transesterification of LAS acid with amine oxide C _12-14 .

Of the Content of a washing or cleaning agent according to the invention to anionic surfactants, preferably to said anionic Surfactants, can vary widely. Thus, an inventive Detergents or cleaning agents very large amounts of anionic surfactant contained, preferably up to an order of magnitude of up to 40, 50 or 60 wt .-% or more, wt .-% based on the entire washing or cleaning agent. Likewise, an inventive Detergents or cleaners only very small amounts of anionic surfactant contain, for example, less than 15 or 10 wt .-% or less as 5% by weight or even less. Advantageously, in the inventive Detergents or cleaning agents, however, anionic surfactants in amounts of 0.1 to 40 wt .-% and in particular 5 to 30 wt .-%, wherein Concentrations above 10% by weight and even above 15 Wt .-% special preference. According to a preferred embodiment contains the washing or Detergents anionic surfactants, preferably in amounts of at least 0.01 wt .-%, wt .-% based on the total washing or Cleaning supplies. According to another preferred embodiment can the washing or cleaning agent according to the invention be free of anionic surfactant. Also the invention Particles and granules can be free from Be anionic surfactant.

additionally to the said anionic surfactants, but also independently Of these, in the invention Agents, in particular in the washing or cleaning preparations, soaps be included. Particularly suitable are saturated fatty acid soaps, such as the salts of lauric acid, myristic acid, Palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid and in particular natural Fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures. The content of one of the preferred according to the invention Washing or cleaning agent on soaps is independent of other anionic surfactants, preferably not more than 3% by weight and in particular from 0.5 to 2.5% by weight, based on the total washing or detergent. According to another preferred embodiment is the agent of soap according to the invention.

The anionic surfactants and soaps may be in the form of their sodium, Potassium or ammonium salts and as soluble salts organic Bases, such as mono-, di- or triethanolamine, are present. Preferably they are in the form of their sodium or potassium salts, in particular in the form of the sodium salts.

advantageously, can nonionic surfactants in the inventive Be included means. For example, their content in inventive Washing or cleaning agents up to 2 or 3 or 5 wt .-%, based on the entire detergent or cleaning agent. It can also larger amounts of nonionic surfactant in the Detergents or cleaning agents may be included, for example to to 5% by weight or 10% by weight or 15% by weight or 20% by weight, 30% by weight, 40% by weight, 50% by weight or even more if it is is appropriate. Meaningful lower limits can at values of 0.01, 0.1, 1, 2, 3 or 4 wt .-%, wt .-% each based on the entire detergent or cleaning agent

Preferably however, the nonionic surfactants are larger in size Quantities, ie up to 50 wt .-%, advantageously from 0.1 to 40 Wt .-%, particularly preferably from 0.5 to 30 and in particular of From 2 to 25% by weight, based in each case on the entire washing or cleaning agent, contain. Contains a preferred embodiment the washing or cleaning agent according to the invention nonionic surfactants, preferably in amounts of at least 0.1 Wt .-%, based on the total washing or cleaning agent. To another, but less preferred, embodiment can the washing or cleaning agent according to the invention also be free of nonionic surfactant.

advantageously, may be any nonionic known in the art Surfactants in the inventive compositions be.

The Composition according to the invention, in particular washing or detergents, may also be cationic Containing surfactants. Suitable cationic surfactants are, for example, surface-active quaternary compounds, in particular with an ammonium, Sulfonium, phosphonium, iodonium or arsonium group. By the Use of quaternary surface-active compounds with antimicrobial effect, the agent can be with an antimicrobial Be designed effect or its possibly due to others Ingredients improves existing antimicrobial effect become.

Particularly preferred cationic surfactants are the quaternary, z. T. antimicrobial ammonium compounds (QAV, INCI Quaternary Ammonium Compounds) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- , in which R ^I to R ^IV identical or different C _{1 -22-} alkyl radicals C _7-28 -Aralkyl radicals or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in the pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- are} halide ions, sulfate ions, hydroxide ions or like anions. For optimum antimicrobial activity, preferably at least one of the radicals has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.

QAC are by reaction of tertiary amines with alkylating agents, such as Methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary Amines with a long alkyl radical and two methyl groups succeed especially easy, even the quaternization of tertiary Amines with two long residues and one methyl group can help with of methyl chloride under mild conditions become. Amines containing three long alkyl radicals or hydroxy-substituted alkyl radicals are poorly reactive and are preferred with dimethyl sulfate quaternized.

Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride, CAS No. 8001-54-5), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, CAS No. 58390-78 -6), benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) -ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-timethyl-ammonium bromide, CAS No. 57-09-0), benzetonium chloride (N, N Dimethyl N- [2- [2- [p- (1,1,3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0), dialkyldimethylammonium chlorides such as di-n -decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, 1-cetylpyridiniumchloride (CAS No. 123-03- 5) and thiazoline iodide (CAS No. 15764-48-1) and mixtures thereof. Preferred QACs are the benzalkonium chlorides having C ₈ -C ₁₈ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkyl-benzyl-dimethylammonium chloride. A particularly preferred QAC Kokospentaethoxymethylammoniummethosulfat (INCI PEG-5 Cocomonium Methosulfate; Rewoquat CPEM ^®).

to Avoidance of possible incompatibilities, if applicable antimicrobial cationic surfactants with possibly contained anionic Surfactants can z. B. as possible aniontensidverträgliches and / or possibly as little as possible cationic surfactant used or in a particular embodiment of the invention completely dispensed with cationic surfactants.

The washing or cleaning agents according to the invention may contain one or more cationic surfactants contained, advantageously in amounts, based on the total washing or cleaning agent, from 0 to 30 wt .-%, more preferably greater than 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5% by weight. Suitable minimum values may also be 0.5, 1, 2 or 3 wt .-%. According to a preferred embodiment, the washing or cleaning agent according to the invention comprises cationic surfactants, preferably in amounts of at least 0.1% by weight, based on the total washing or cleaning agent. According to another preferred embodiment, the agent according to the invention, preferably washing or cleaning agent, can be free of cationic surfactant.

As well the agents according to the invention, preferably detergents or cleaners, including amphoteric surfactants contain. These will be even closer below described.

The Detergents or cleaning agents according to the invention may contain one or more amphoteric surfactants, advantageously in quantities, based on the total washing or cleaning agent, from 0 to 30% by weight, more advantageously greater 0 to 20 wt .-%, preferably 0.01 to 10 wt .-%, in particular 0.1 to 5% by weight. According to another preferred embodiment the agent according to the invention can be free from amphoteric Be surfactants.

To a particular embodiment, the inventive Detergents or cleaners contain very little total surfactant, z. For example, the total amount of surfactant may be less than 20% by weight, 15% by weight, 10% Wt .-% or 5 wt .-%, advantageously even less than 3 wt .-% or below 1 wt .-%, in particular even below 0.5 wt .-% or below 0.1 Wt .-%, wt .-% in each case based on the total washing or Cleaning supplies. Preferably, the total surfactant content but at least 0.01 wt .-%, 0.1 wt% or 1 wt .-%, based on the entire detergent or cleaning agent.

Further Ingredients of the compositions according to the invention can be inorganic and organic builders. To the inorganic ones Builders include water-insoluble or non-water-soluble ingredients, such as aluminosilicates and in particular zeolites.

In In a specific embodiment, the inventive Agent, preferably detergent or cleaner, no phosphate and / or contain no zeolite. But it is much more preferable that the agent contains zeolite. It may then preferably be that this zeolite content, based on the total weight of Washing or cleaning agent, less than 5 wt .-%, preferably at most 4 wt .-%, at most 3 wt .-% or at most 2 wt .-% is.

It but can also be advantageously provided that the inventive Detergents or cleaning agents have a zeolite content of at least 10 wt .-%, z. B. at least 15 wt .-% or at least 20 wt .-% or at least 30 wt .-% or even beyond, for example at least 50 wt .-%, wt .-% based on the total washing or detergent Soluble builder may be the inventive Washing or cleaning agents, preferably in amounts of 0.1% by weight to 30% by weight, preferably 5% to 25% by weight, and more preferably 10% by weight to 20% by weight, based on the total weight of the washing or detergent, with sodium carbonate being more soluble Builder is particularly preferred. But it can be advantageous also be provided that the inventive Washing or cleaning agent less than 10 wt .-%, for example contains less than 5% by weight of soluble builder on the entire washing or cleaning agent. Suitable, for example Citrate, SKS-6, citric acid, MGDA (methyl glycine di-acetetic acid), triphosphates, phosphonates, aliphatic dicarboxylic acids (eg adipic, glutaric, succinic acid). After another preferred embodiment, the inventive Detergents or cleaners free of soluble builder be.

Useful finely crystalline, synthetic and bound water-containing zeolite is preferably zeolite A and / or P. As zeolite P, for example, zeolite MAP ^(R) (commercial product of Crosfield) is particularly preferred. Also suitable however are zeolite X and mixtures of A, X and / or P. Of particular interest is a co-crystallized sodium / potassium aluminum silicate of zeolite A and zeolite X, which (as VEGOBOND AX ^® commercial product of Condea August S. p A.) is commercially available. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C ₁₂ -C ₁₈ fatty alcohols having 2 to 5 ethylene oxide groups , C ₁₂ -C ₁₄ fatty alcohols having 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of preferably less than 10 microns (volume distribution, measuring method: Coulter Counter) and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of ge tethered water.

When other particularly suitable zeolites are zeolites of the faujasite type to call. Together with the zeolites X and Y belongs to the Mineral faujasite to the faujasite types within the zeolite structure group 4, which are characterized by the double-six-membered subunit D6R. The zeolite structure group 4 includes in addition to those mentioned Faujasit types still the minerals Chabazit and Gmelinit as well as the synthetic zeolites R (chabazite type), S (gmelinite type), L and ZK-fifth The latter two synthetic zeolites have none mineral analogues.

Faujasite-type zeolites are composed of β-cages linked by tetrahedral D6R subunits, with the β-cages resembling the carbon atoms in the diamond. The three-dimensional network of the faujasite-type zeolites useful in the present invention has pores of 2.2 and 7.4 Å, the unit cell also contains 8 wells of about 13 Å in diameter, and can be represented by the formula Na ₈₆ [(AlO ₂ ). ₈₆ (SiO ₂ ) ₁₀₆ ]. 264H ₂ O. The network of zeolite X contains a void volume of about 50%, based on the dehydrated crystal, which represents the largest void space of all known zeolites (zeolite Y: about 48% void volume, faujasite: about 47% void volume).

in the For the purposes of the present invention, the term "zeolite of the faujasite type "preferably all three zeolites containing the faujasite subgroup of the zeolite structure group 4. In addition to the zeolite X are so according to the invention also zeolite Y and faujasite and mixtures of these compounds suitable, wherein the pure zeolite X is preferred.

Also Mixtures or cocrystallizates of faujasite-type zeolites with other zeolites, not necessarily the zeolite structure group 4 are suitable according to the invention, wherein preferably at least 50 wt .-% of the zeolites of the faujasite type are.

The suitable aluminum silicates are commercially available, and the methods for their presentation are in standard monographs described.

Examples of commercially available X-type zeolites can be described by the following formulas: Na ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, K ₈₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Ca ₄₀ Na ₆ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₆ ] xH ₂ O, Sr ₂₁ Ba ₂₂ [(AlO ₂ ) ₈₆ (SiO ₂ ) ₁₀₅ ] xH ₂ O, where x can take values greater than 0 to 276. These zeolites have pore sizes of 8.0 to 8.4 Å.

Suitable, for example, zeolite A-LSX corresponding to a co-crystallizate of zeolite X and zeolite A, and in its anhydrous form the formula: (M _{2 / n} O + M _{'2 / n} O) · Al ₂ O ₃ · ZSiO ₂ where M and M 'may be alkali or alkaline earth metals and z is a number from 2.1 to 2.6. This product is commercially available under the brand name VEGOBOND AX from CONDEA August S. p. A.

Y-type zeolites are also commercially available and can be obtained, for example, by the formulas Na ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] .xH ₂ O, K ₅₆ [(AlO ₂ ) ₅₆ (SiO ₂ ) ₁₃₆ ] xH ₂ O, where x is numbers greater than 0 to 276. These zeolites have pore sizes of 8.0 Å.

The particle sizes of the suitable zeolites are advantageously in the range from 0.1 μm to 100 μm, preferably from 0.5 μm to 50 μm and in particular from 1 μm to 30 μm, in each case measured by standard particle size determination methods. After another, less preferred Ausfüh The washing or cleaning agent according to the invention can be free of zeolite.

In a preferred embodiment of the invention all inorganic constituents contained preferably water-soluble be. In these embodiments, therefore, others Builders used as the zeolites mentioned.

Further Suitable builders are polyacetals, which by reaction of dialdehydes with polyolcarboxylic acids, which are 5 to 7 C atoms and at least 3 hydroxyl groups can be obtained. Preferred polyacetals are selected from dialdehydes such as glyoxal, glutaraldehyde, Terephthalaldehyde and mixtures thereof and from Polyolcarbonsäuren such as gluconic acid and / or glucoheptonic acid.

Further suitable organic builders are dextrins, for example Oligomers or polymers of carbohydrates by partial Hydrolysis of starches can be obtained. The hydrolysis can be carried out by customary, for example acidic or enzyme-catalyzed processes. Preferably, they are hydrolysis products with middle Molar masses in the range of 400 to 500,000 g / mol. This is a polysaccharide with a dextrose equivalent (DE) in the range of 0.5 to 40, in particular from 2 to 30 preferred, DE being a common Measure of the reducing effect of a polysaccharide compared to dextrose, which has a DE of 100. Useful are both maltodextrins with a DE between 3 and 20 and dry glucose syrups with a DE between 20 and 37 as well as so-called yellow dextrins and white dextrins with higher molecular weights in the range from 2000 to 30,000 g / mol. In the oxidized derivatives of such Dextrins are their reaction products with oxidizing agents, which are capable of at least one alcohol function of the saccharide ring to oxidize the carboxylic acid function.

Also Oxydisuccinates and other derivatives of disuccinates, preferably Ethylenediamine disuccinate are other suitable cobuilders. there ethylenediamine-N, N'-disuccinate (EDDS) is preferably used in the form of its sodium or magnesium salts used. Further preferred are in this Also related glycerol disuccinates and glycerol trisuccinates. Suitable amounts are, for example, 3 to 15 wt .-%, based on the entire washing or cleaning agent.

Further useful organic cobuilders are, for example, acetylated Hydroxycarboxylic acids or their salts, which optionally may also be present in Lactonform and which at least 4 carbon atoms and at least one hydroxy group and maximum contain two acid groups.

A another substance class with cobuilder properties are the phosphonates These are in particular hydroxyalkane or aminoalkanephosphonates. Among the hydroxyalkane phosphonates is 1-hydroxyethane-1,1-diphosphonate (HEDP) of particular importance as a co-builder. It is preferably used as the sodium salt, wherein the disodium salt neutral and the tetrasodium salt is alkaline (pH9). As aminoalkanephosphonates preferably ethylenediamine tetramethylenephosphonate (EDTMP), Diethylenetriaminepentamethylenephosphonate (DTPMP) and their higher Homologous in question. They are preferably in the form of neutral reacting Sodium salts, e.g. B. as hexasodium salt of EDTMP or hepta- and octa-sodium salt of DTPMP. As a builder will be there from the class of phosphonates preferred HEDP used. The aminoalkane phosphonates also have a pronounced Schwermetallbindeabmögen. Accordingly, it may be preferable to use aminoalkane phosphonates, in particular DTPMP, to use or mixtures of the phosphonates mentioned.

In Cases in which a phosphate content is tolerated can Phosphates are also used, in particular pentasodium triphosphate, optionally also pyrophosphates and orthophosphates, the first Line act as a precipitant for calcium salts. Phosphates are predominantly used in automatic dishwashing detergents, partly but also used in detergents.

Alkali metal phosphates is the summary term for the alkali metal (especially sodium and potassium) salts of various phosphoric acids, in which one can distinguish metaphosphoric acids (HPO ₃ ) _n and orthophosphoric H ₃ PO _{4 in} addition to higher molecular weight representatives. The phosphates combine several advantages: they act as alkali carriers, prevent lime deposits on machine parts or lime incrustations in fabrics and also contribute to the cleaning performance.

Sodium dihydrogen phosphate, NaH ₂ PO ₄ , exists as a dihydrate (density 1.91 gcm ^-3 , melting point 60 °) and as a monohydrate (density 2.04 gcm ^-3 ). Both salts are white powders which are very soluble in water and which lose their water of crystallization when heated and at 200 ° C into the weak acid diphosphate (disodium hydrogen diphosphate, Na ₂ H ₂ P ₂ O ₇ ), at higher temperature in sodium trimetaphosphate (Na ₃ P ₃ O ₉ ) and Maddrell's salt (see below), go over. NaH ₂ PO _{4 is} acidic; It arises when phosphoric acid is adjusted to a pH of 4.5 with sodium hydroxide solution and the mash is sprayed. Potassium dihydrogen phosphate (potassium phosphate primary or monobasic potassium phosphate, KDP), KH ₂ PO ₄ , is a white salt of 2.33 gcm ^-3 density, has a melting point of 253 ° [decomposition to form potassium polyphosphate (KPO ₃ ) _x ] and is light soluble in water.

Disodium hydrogen phosphate (secondary sodium phosphate), Na ₂ HPO ₄ , is a colorless, very slightly water-soluble crystalline salt. It exists anhydrous and with 2 mol. (Density 2.066 gcm ^-3 , water loss at 95 °), 7 mol (density 1.68 gcm ^-3 , melting point 48 ° with loss of 5 H ₂ O) and 12 mol. Water (density 1.52 gcm ^-3 , melting point 35 ° with the loss of 5 H ₂ O), becomes anhydrous at 100 ° C. and on more intense heating passes into the diphosphate Na ₄ P ₂ O ₇ . Disodium hydrogen phosphate is prepared by neutralization of phosphoric acid with soda solution using phenolphthalein as an indicator. Di-potassium hydrogen phosphate (secondary or dibasic potassium phosphate), K ₂ HPO ₄ , is an amorphous, white salt that is readily soluble in water.

Trisodium phosphate, tertiary sodium phosphate, Na ₃ PO ₄ , are colorless crystals which have a density of 1.62 gcm ^-3 as dodecahydrate and a melting point of 73-76 ° C (decomposition), as decahydrate (corresponding to 19-20% P ₂ O ₅ ) have a melting point of 100 ° C and in anhydrous form (corresponding to 39-40% P ₂ O ₅ ) have a density of 2.536 gcm ^-3 . Trisodium phosphate is readily soluble in water under alkaline reaction and is prepared by evaporation of a solution of exactly 1 mole of disodium phosphate and 1 mole of NaOH. Tripotassium phosphate (tertiary or tribasic potassium phosphate), K ₃ PO ₄ , is a white, deliquescent, granular powder of density 2.56 gcm ^-3 , has a melting point of 1340 ° and is readily soluble in water with an alkaline reaction. It arises z. Example, when heating Thomasschlacke with coal and potassium sulfate. Despite the higher price, the more soluble, therefore highly effective, potassium phosphates are often preferred over the corresponding sodium compounds in the detergent industry.

Tetrasodium diphosphate (sodium pyrophosphate), Na ₄ P ₂ O ₇ , exists in anhydrous form (density 2.534 gcm ^-3 , melting point 988 °, also indicated 880 °) and as decahydrate (density 1.815-1.836 gcm ^-3 , melting point 94 ° with loss of water) , Both substances are colorless crystals which are soluble in water with an alkaline reaction. Na ₄ P ₂ O ₇ is formed on heating of disodium phosphate to> 200 ° or by reacting phosphoric acid with soda in a stoichiometric ratio and dewatering the solution by spraying. The decahydrate complexes heavy metal salts and hardness agents and therefore reduces the hardness of the water. Potassium diphosphate (potassium pyrophosphate), K ₄ P ₂ O ₇ , exists in the form of the trihydrate and is a colorless, hygroscopic powder with a density of 2.33 gcm ^-3 , which is soluble in water, the pH being 1% Solution at 25 ° 10.4.

Condensation of the NaH ₂ PO ₄ or the KH ₂ PO ₄ results in higher molecular weight sodium and potassium phosphates, in which one can distinguish cyclic representatives, the sodium or potassium metaphosphates and chain types, the sodium or potassium polyphosphates. In particular, for the latter are a variety of names in use: hot or cold phosphates, Graham's salt, Kurrolsches and Maddrell's salt. All higher sodium and potassium phosphates are collectively referred to as condensed phosphates.

The technically important pentasodium triphosphate, Na ₅ P ₃ O ₁₀ (sodium tripolyphosphate), is an anhydrous or with 6 H ₂ O crystallizing, non-hygroscopic, white, water-soluble salt of the general formula NaO- [P (O) (ONa) -O] _n -Na with n = 3. In 100 g of water dissolve at room temperature about 17 g, at 60 ° about 20 g, at 100 ° around 32 g of the salt water-free salt; after two hours of heating the solution to 100 ° caused by hydrolysis about 8% orthophosphate and 15% diphosphate. In the preparation of pentasodium triphosphate, phosphoric acid is reacted with soda solution or sodium hydroxide solution in a stoichiometric ratio and the solution is dehydrated by spraying. Similar to Graham's salt and sodium diphosphate, pentasodium triphosphate dissolves many insoluble metal compounds (including lime soaps, etc.). Pentakaliumtriphosphat, K ₅ P ₃ O ₁₀ (potassium tripolyphosphate), for example, in the form of a 50 wt .-% solution (> 23% P ₂ O ₅ , 25% K ₂ O) in the trade. The potassium polyphosphates are widely used in the washing and cleaning industry. There are also sodium potassium tripolyphosphates which can also be used in the context of the present invention. These arise, for example, when hydrolyzed sodium trimetaphosphate with KOH: (NaPO ₃ ) ₃ + 2 KOH → Na ₃ K ₂ P ₃ O ₁₀ + H ₂ O

These are according to the invention just like sodium tripolyphosphate, potassium tripolyphosphate or Mi can be used from these two; Mixtures of sodium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of potassium tripolyphosphate and sodium potassium tripolyphosphate or mixtures of sodium tripolyphosphate and potassium tripolyphosphate and sodium potassium tripolyphosphate can also be used according to the invention.

In a preferred embodiment of the invention as inorganic builder substances, in particular carbonates and silicates used.

Particularly noteworthy here are crystalline, layered sodium silicates of the general formula NaMSi _x O _{2x + 1} .yH ₂ O, where M is sodium or hydrogen, x is a number from 1.6 to 4, preferably 1.9 to 4.0 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. However, since such crystalline silicates at least partially lose their crystalline structure in a spray-drying process, crystalline silicates are preferably subsequently added. Preferred crystalline layered silicates of the formula given are those in which M is sodium and x assumes the values 2 or 3. In particular, both β- and δ-sodium disilicates Na ₂ Si ₂ O ₅ .yH ₂ O are preferred. Such compounds are commercially available, for example, under the name ^SKS® (from Clariant). Thus, it is mainly SKS-6 ^® is a δ-sodium having the formula Na ₂ Si ₂ O ₅ · yH ₂ O, SKS-7 ^® primarily the β-sodium disilicate. Reaction with acids (eg citric acid or carbonic acid) gives kanemite NaHSi ₂ O ₅ .yH ₂ O, commercially available under the names SKS- ^9® or SKS- ^10® (from Clariant) from the δ-sodium disilicate. It may also be advantageous to use chemical modifications of these phyllosilicates. For example, the alkalinity of the layered silicates can be suitably influenced. Phyllosilicates doped with phosphate or with carbonate have altered crystal morphologies in comparison with the δ-sodium disilicate, dissolve more rapidly and show increased calcium binding capacity in comparison with δ-sodium disilicate. Thus, phyllosilicates of the general empirical formula xNa ₂ O.ySiO ₂ .zP ₂ O ₅ in which the ratio x to y is a number 0.35 to 0.6, the ratio x to z is a number from 1.75 to 1200 and the ratio y to z is equivalent to a number from 4 to 2800 known. The solubility of the layered silicates can also be increased by using particularly finely divided layered silicates. Also compounds from the crystalline layer silicates with other ingredients can be used. In particular compounds with cellulose derivatives, which have advantages in the disintegrating effect, as well as compounds with polycarboxylates, eg. As citric acid, or polymeric polycarboxylates, eg. As copolymers of acrylic acid, to name.

The preferred builder substances also include amorphous sodium silicates having a modulus Na ₂ O: SiO _{2 of} from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which have secondary washing properties. In the context of this invention, the term "amorphous" is also understood to mean "X-ray amorphous". This means that the silicates do not yield sharp X-ray reflections typical of crystalline substances in X-ray diffraction experiments, but at most one or more maxima of the scattered X-rays which have a width of several degrees of diffraction angle. However, it may well even lead to particularly good builder properties if the silicate particles provide blurred or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline regions of size 10 to a few hundred nm, with values of up to max. 50 nm and in particular up to max. 20 nm are preferred. Such so-called X-ray amorphous silicates, which likewise have a dissolution delay compared with the conventional water glasses, are known. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.

Especially preferred inorganic water-soluble builders are alkali metal carbonates and alkali metal bicarbonates, wherein sodium and potassium carbonate and especially sodium carbonate to the preferred embodiments counting.

useful Organic builders are, for example, those in Form of their alkali metal and in particular sodium salts usable polycarboxylic acids, such as citric acid, adipic acid, succinic acid, Glutaric, tartaric, sugar acids, Aminocarboxylic acids, nitrilotriacetic acid (NTA), provided such use for environmental reasons not to complain about, as well as mixtures of these. preferred Salts are the salts of polycarboxylic acids such as citric acid, Adipic acid, succinic acid, glutaric acid, Tartaric acid, sugar acids and mixtures of these. The acids themselves can also be used. The acids typically have besides their builder effect also the property of an acidifying component and serve thus, such as in the invention Granules, also for setting a lower and milder pH value of detergents or cleaning agents. In particular, here are Citric acid, succinic acid, glutaric acid, Adipic acid, gluconic acid and any mixtures to name from these.

Further suitable organic builders are polymeric polycarboxylates, for example the alkali metal salts of polyacrylic acid or of polymethacrylic acid, for example those having a relative molecular mass of 500 to 70,000 g / mol. For the purposes of this document, the molecular weights stated for polymeric polycarboxylates are weight-average molar masses M _{w of} the particular acid form, which were determined in principle by means of gel permeation chromatography (GPC), a UV detector being used. The measurement was carried out against an external polyacrylic acid standard, which provides realistic molecular weight values due to its structural relationship with the polymers investigated. These data differ significantly from the molecular weight data, in which polystyrene sulfonic acids are used as standard. The molar masses measured against polystyrenesulfonic acids are generally significantly higher than the molecular weights specified in this document.

The agents according to the invention can also Contain polymers. Suitable polymers, also known as carriers may be used in conjunction with perfume include in particular Polyacrylates, which preferably have a molecular weight of 2000 to 20,000 g / mol. Because of their superior solubility In turn, from this group, the short-chain polyacrylates, the molecular weights of 2000 to 10,000 g / mol, and particularly preferred from 3000 to 5000 g / mol.

Suitable are furthermore copolymeric polycarboxylates, especially those of Acrylic acid with methacrylic acid and acrylic acid or methacrylic acid with maleic acid. As special suitable copolymers of acrylic acid with maleic acid proven, the 50 to 90 wt .-% acrylic acid and 50 to 10 Wt .-% maleic acid. Your molecular weight, based on free acids, is generally 2000 to 70000 g / mol, preferably 20,000 to 50,000 g / mol and in particular 30,000 to 40,000 g / mol.

Of the Content of washing or cleaning agents on organic builders can vary within a wide range. Preference is given to contents of 2 to 20 wt .-%, in particular contents of not more than 10 wt .-% find particular approval, based on the entire detergent or cleaning agent. According to another preferred embodiment, the Inventive agent free of organic builders be.

The agents according to the invention can components from the classes of the grayness inhibitors (dirt carrier), the neutral salts and / or the fabric softening aids (for example Cationic surfactants), which is preferred.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, the water-soluble Salts of polymeric carboxylic acids, glue, gelatin, salts of Ethercarboxylic acids or ether sulfonic acids of Starch or cellulose or salts of acidic sulfuric acid esters cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the starch products mentioned above, z. B. degraded starch, aldehyde starches, etc. Also Polyvinylpyrrolidone is useful. However, preference is given to cellulose ethers, such as carboxymethyl cellulose (Na salt), methyl cellulose, hydroxyalkyl cellulose and mixed ethers, such as methyl hydroxyethyl cellulose, methyl hydroxypropyl cellulose, Methylcarboxy-methylcellulose and mixtures thereof, and polyvinylpyrrolidone for example, in amounts of preferably 0.1 to 5 wt .-%, based on the entire detergent or cleaning agent used.

When typical example of a suitable representative of the neutral salts is called sodium sulfate. It can be in quantities of for example 0 to 60 wt .-%, preferably 2 to 45 wt .-% are used, based on the entire washing or cleaning agent.

The agents according to the invention can avivifying agents contain z. As plasticizer. Suitable softening agents are z. T. been described in more detail. suitable Surfactants (plasticizers) are, for example, swellable Phyllosilicates of the type of montmorillonites, for example Bentonite, as well as cationic surfactants.

In the following, the nonionic surfactants are described in more detail. The nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or linear and methyl-branched radicals in the mixture may contain, as they are usually present in Oxoalkoholresten. In particular are However, alcohol ethoxylates with linear radicals of alcohols of natural origin having 12 to 18 carbon atoms, eg. From coconut, palm, palm kernel, tallow fat or oleyl alcohol, and on average from 2 to 8 EO per mole of alcohol. The preferred ethoxylated alcohols include, for example, C ₁₂ -C ₁₄ -alcohols with 3 EO to 6 EO, C ₉ -C ₁₇ -alcohols with 7 EO, C ₁₃ -C ₁₅ -alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C ₁₄ -C ₁₅ -alcohols with 4 EO, 5 EO, 7 EO or 9 EO, C ₁₂ -C ₁₈ -alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ₁₂ -C ₁₄ -alcohol with 3 EO and C ₁₂ -C ₁₈ -alcohol with 7 EO. The degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number.

preferred Alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic Surfactants can also be used fatty alcohols with more than 12 EO become. Examples include (tallow) fatty alcohols with 14 EO, 16 EO, 20 EO, 25 EO, 30 EO or 40 EO.

Preferred nonionic surfactants are one or more ethylene oxide (EO) and / or propylene oxide (PO) alkoxylated, unbranched or branched, saturated or unsaturated C _10-22 alcohols having a degree of alkoxylation of up to 30, preferably ethoxylated C _10-18 fatty alcohols having a degree of ethoxylation of less than 30, preferably 1 to 20, in particular 1 to 12, more preferably 1 to 8, most preferably 2 to 5, for example C _12-14 fatty alcohol ethoxylates with 2, 3 or 4 EO or a mixture of the C _12-14 fatty alcohol ethoxylates with 3 and 4 EO in a weight ratio of 1 to 1 or isotridecyl alcohol ethoxylate with 5, 8 or 12 EO.

In addition, as further nonionic surfactants and alkyl glycosides of the general formula RO (G) _x can be used in which R is a primary straight-chain or methyl-branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G is the symbol which represents a glycose unit having 5 or 6 C atoms, preferably glucose. The degree of oligomerization x, which indicates the distribution of monoglycosides and oligoglycosides, is any number from 1 to 10; preferably x is 1.1 to 1.4. also suitable are N-methylglucamides with C ₁₂ / C ₁₄ .

Another class of preferred nonionic surfactants used either as the sole nonionic surfactant or in combination with other nonionic surfactants, in particular together with alkoxylated fatty alcohols and / or alkyl glycosides, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably from 1 to 4 carbon atoms in the alkyl chain, especially fatty acid methyl esters, particularly preferred are C ₁₂ -C ₁₈ fatty acid methyl esters having an average of 3 to 15 EO, in particular with an average of 5 to 12 EO, z. B. also used.

Also Nonionic surfactants of the amine oxide type, for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamide may be suitable. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated Fatty alcohols, especially not more than half of them.

Farther suitable are alkoxylated amines, advantageously ethoxylated and / or propoxylated, especially primary and secondary Amines having preferably 1 to 18 carbon atoms per alkyl chain and average 1 to 12 moles of ethylene oxide (EO) and / or 1 to 10 moles of propylene oxide (PO) per mole of amine.

In the case of compositions according to the invention which are particularly suitable for automatic dishwashing, in particular dishwashing compositions in the form of tablet tablets, such as tabs, all surfactants are suitable in principle as surfactants. However, the nonionic surfactants described above and especially the low-foaming nonionic surfactants are particularly preferred for this purpose. Particularly preferred are the alkoxylated alcohols, especially the ethoxylated and / or propoxylated alcohols. The person skilled in the art generally means, under alkoxylated alcohols, the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferably in the context of the present invention, the longer-chain alcohols C ₁₀ to C ₁₈ , preferably C ₁₂ to C ₁₆ , such as C ₁₁ -, C ₁₂ - , C ₁₃ , C ₁₄ , C ₁₅ , C ₁₆ , C ₁₇ and C ₁₈ alcohols. As a rule, n moles of ethylene oxide and one mole of alcohol, depending on the reaction conditions, form a complex mixture of addition products of different degrees of ethoxylation. A further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide. Also, if desired, by a final etherification with short-chain alkyl groups, such as preferably the butyl group, the substance class of "closed" alcohol ethoxylates reach, which can also be used in the context of the invention. Very particularly preferred for the purposes of the present invention are highly ethoxylated fatty alcohols or mixtures thereof with end-capped fatty alcohol ethoxylates.

Advantageously, the compositions according to the invention may also contain foam inhibitors, for example foam-inhibiting paraffin oil or foam-inhibiting silicone oil, for example dimethylpolysiloxane. The use of mixtures of these agents is possible. As additives which are solid at room temperature, paraffin waxes, silicic acids, which may also be hydrophobized in a known manner, and in particular bismuth derivatives which are derived from C _2-7 diamines and C _12-22 carboxylic acids, are suitable.

For the use of preferably suitable foam-inhibiting paraffin oils, which may also be present in admixture with paraffin waxes, are generally complex mixtures without a sharp melting point. For characterization, the melting range is usually determined by differential thermal analysis (DTA) and / or the solidification point. This is the temperature at which the paraffin passes through Slow cooling from the liquid to the solid State passes. Paraffins with less than 17 carbon atoms are not useful according to the invention, their share in the paraffin oil mixture should therefore be as low as possible be and is preferably below the usual analytical methods, for example gas chromatography, significantly measurable limit. Preferably, paraffins are used which solidify in the range of 20 ° C to 70 ° C. there It should be noted that even at room temperature appearing Paraffin wax mixtures different proportions of liquid Paraffin oils may contain. In the invention useful Paraffin waxes, the liquid content is 40 ° C. as high as possible, without 100% at this temperature be.

Preferred paraffin wax mixtures have at 40 ° C a liquid content of at least 50 wt .-%, in particular from 55 wt .-% to 80 wt .-%, and at 60 ° C, a liquid content of at least 90 wt .-% to. This has the consequence that the paraffins are flowable and pumpable at temperatures down to at least 70 ° C, preferably down to at least 60 ° C. It is also important to ensure that the paraffins contain as far as possible no volatile components. Preferred paraffin waxes contain less than 1 wt .-%, in particular less than 0.5 wt .-% at 110 ° C and atmospheric pressure vaporizable fractions. According to Paraffins which can be obtained for example under the trade names Luna Flex ^® from Fuller and Deawax ^® DEA Mineralöl AG.

The Paraffin oils may be solid bisamides at room temperature, which vary from saturated fatty acids with 12 to 22, preferably 14 to 18 carbon atoms and of alkylenediamines with 2 to 7 carbon atoms derived. Suitable fatty acids are lauric, myristic, stearic, arachinic and behenic acid as well as their mixtures, as they are from natural fats respectively hardened oils, such as tallow or hydrogenated palm oil, are available. Suitable diamines are, for example Ethylene diamine in 1,3-propylenediamine, tetamethylenediamine, pentamethylenediamine, Hexamethylenediamine, p-phenylenediamine and toluenediamine. preferred Diamines are ethylenediamine and hexamethylenediamine. Especially preferred Bisamides are bis-myristoyl-ethylenediamine, bispalmitoyl-ethylenediamine, Bis-stearoyl-ethylenediamine and mixtures thereof and the corresponding derivatives of hexamethylenediamine. Also suitable are hexamethylenediamine ethoxylates.

The aforementioned Ingredients may optionally be part of the invention Particles, granules and / or detergents or cleaning agents be.

The agents according to the invention may preferably with other ingredients, especially washing, care, and / or Detergents or cosmetic ingredients. From the broad state of the art is well known which Ingredients of detergents, care or cleaning agents and which Raw materials can usually still be added.

Preferably, the agent may comprise UV absorbers, which are advantageously applied to the treated fabrics and improve the lightfastness of the fibers and / or the lightfastness of other formulation ingredients. Under UV absorber are organic substances (sunscreen) to understand, which are able to absorb ultraviolet rays and the absorbed energy in the form of longer-wave radiation, eg. B. to give off heat again. Compounds having these desired properties include, for example, the non-radiative deactivating compounds and derivatives of benzophenone having substituents in the 2- and / or 4-position. Also suitable are substituted benzotriazoles, phenyl-substituted acrylates (cinnamic acid derivatives) in the 3-position, optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural substances such as umbelliferone and the endogenous urocanic acid. The biphenyl and especially stilbene derivatives, commercially available as Tinosorb ^® FD or Tinosorb ^® FR available ex Ciba. As UV-B absorber are to call 3-Benzylidencampher or 3-Benzylidennorcampher and its derivatives, eg. B. 3- (4-methylbenzylidene) camphor; 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 2-octyl 4- (dimethylamino) benzoate and 4- (dimethylamino) benzoic acid amyl ester; Esters of cinnamic acid, preferably 2-ethylhexyl 4-methoxycinnamate, 4-methoxycinnamic acid propyl ester, 4-methoxycinnamic acid iso-amyl ester, 2-cyano-3,3-phenylcinnamic acid 2-ethylhexyl ester (octocrylene); Esters of salicylic acid, preferably 2-ethylhexyl salicylate, 4-isopropylbenzyl salicylate, homomenthyl salicylate; Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4'-methylbenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone; Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzmalonate; Triazine derivatives, such as. For example, 2,4,6-trianilino- (p-carbo-2'-ethyl-1'-hexyloxy) -1,3,5-triazine and Octyl Triazone or Dioctyl Butamido Triazone (Uvasorb HEB ^®); Propane-1,3-diones, such as. B. 1- (4-tert-butylphenyl) -3- (4'-methoxyphenyl) propane-1,3-dione; Ketotricyclo (5.2.1.0) decane derivatives. Also suitable are 2-phenylbenzimidazole-5-sulfonic acid and its alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium and glucammonium salts; Sulfonic acid derivatives of benzophenones, preferably 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its salts; Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid and 2-methyl-5- (2-oxo-3-bomylidene) sulfonic acid and salts thereof.

As a typical UV-A filter in particular derivatives of benzoylmethane in question, such as 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) propane-1,3-dione, 4-tert-butyl-4 'Methoxydibenzoylmethan (Parsol 1789), 1-phenyl-3- (4'-isopropylphenyl) propane-1,3-dione and enamine compounds. Of course, the UV-A and UV-B filters can also be used in mixtures. In addition to the soluble substances mentioned, insoluble photoprotective pigments, namely finely dispersed, preferably nano-metal oxides or salts, are also suitable for this purpose. Examples of suitable metal oxides are in particular zinc oxide and titanium dioxide and, in addition, oxides of iron, zirconium, silicon, manganese, aluminum and cerium and mixtures thereof. As salts silicates (talc), barium sulfate or zinc stearate can be used. The oxides and salts are already used in the form of the pigments for skin-care and skin-protecting emulsions and decorative cosmetics. The particles should have an average diameter of less than 100 nm, preferably from 5 to 50 nm and in particular from 15 to 30 nm. They may have a spherical shape, but it is also possible to use those particles which have an ellipsoidal or otherwise deviating shape from the spherical shape. The pigments can also be surface-treated, ie hydrophilized or hydrophobized. Typical examples are coated titanium dioxides, such as. T805 as titanium dioxide (Degussa) or Eusolex ^® T2000 (Merck). Suitable hydrophobic coating agents are in particular silicones and in particular trialkoxyoctylsilanes or simethicones. Micronized zinc oxide is preferably used. Further suitable UV light protection filters can be found in the relevant prior art.

The UV absorbers may advantageously be used in amounts of 0.01 Wt .-% to 5 wt .-%, preferably from 0.03 wt .-% to 1 wt .-%, to be included in the agent. You can also help the agent subsequently, for example together with other substances, be mixed. In a preferred embodiment are the particles according to the invention, granules and / or detergents or cleaners, however, free of UV absorber or UV-A filter.

Preferably can the washing or Detergent also be present as a tablet or shaped body. As "tablet" or "shaped body" are used in the present Regardless of the method of preparation, dimensionally stable, called solid body. Let such bodies For example, crystallization, molding, injection molding, reactive or thermal sintering, (co) extrusion, impounding, Pastillation, or compaction processes such as calendering or tableting. The preparation of the "tablets" or "Shaped body" by tableting is within the scope of the present Application particularly preferred. The tablet is therefore preferably made of pressed, particulate material.

invention Washing or cleaning agent, preferably as a tablet or shaped body present, may preferably disintegration aids contain. Come as swellable disintegration aids For example, bentonites or other swellable silicates into consideration. Also synthetic polymers, in particular those used in the hygiene sector Superabsorbent or cross-linked polyvinylpyrrolidone, can be deploy.

With particular advantage, polymers based on starch and / or cellulose are used as swellable disintegration aids. These base substances can be processed alone or in mixture with other natural and / or synthetic polymers to swellable disintegrating agents. In the simplest case, a cellulosic material or pure cellulose can be converted by pressure transfer into secondary particles by granulation, compaction or other application, which swell on contact with water and thus serve as a disintegrant. As a cellulosic material, wood pulp has proven to be by thermi or chemical-thermal process from wood or wood shavings (sawdust, sawmill waste) is accessible. This cellulosic material from the TMP (thermo-mechanical pulp) or the CTMP (chemo-thermo-mechanical pulp) process can then be compacted by application of pressure, preferably roller compacted and converted into particle form. Of course, pure cellulose can also be used in a completely analogous manner, although it is more expensive from the raw material base. Here, both microcrystalline and amorphous finely divided cellulose and mixtures thereof can be used.

One Another way is to add the cellulose-containing material with addition to granulate granulating aids. As a granulation aid have, for example, solutions of synthetic polymers or nonionic surfactants proven. To residues washed with the agents according to the invention To avoid textiles, the primary fiber length should be the cellulose or cellulose used in the cellulose-containing Material below 200 microns, with primary fiber lengths below 100 microns, especially below 50 microns are preferred.

The Secondary particles ideally have a particle size distribution, preferably greater than 90% by weight of the particle sizes above 200 microns have. A certain amount of dust can to an improved storage stability of the thus produced Contribute to tablets. Proportions of a fine dust content of less 0.1 mm up to 10 wt .-%, preferably up to 8 wt .-% can in the agents used according to the invention Disintegrant granules may be present.

When other surfactants for all inventive Agents may consider so-called gemini surfactants. this includes In general, such compounds are understood as meaning the two hydrophilic ones Possess groups and two hydrophobic groups per molecule. These groups are usually by a so-called "spacer" separated from each other. This spacer is usually a carbon chain, which should be long enough that the hydrophilic groups have a sufficient Have space to act independently of each other can. Such surfactants are generally characterized by an unusually low critical micelle concentration and the ability to control the surface tension of the To greatly reduce water out. In exceptional cases however, under the term gemini surfactants not only dimeric but also understood trimeric surfactants.

suitable Gemini surfactants are, for example, sulfated hydroxy mixed ethers or dimer alcohol bis and trimer alcohol tris sulfates and ether sulfates. End-capped dimeric and trimeric mixed ethers are outstanding especially through their bi- and multi-functionality. Thus, the end-capped surfactants mentioned have good properties Net properties and are low in foam, making them especially for the use in automatic washing, care or cleaning procedures suitable.

used but can also be gemini polyhydroxy fatty acid amides or poly-polyhydroxy fatty acid amides, as described in the relevant State of the art will be described.

in der RCO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen, R²³ für Wasserstoff, einen Alkyl- oder Hydroxyalkylrest mit 1 bis 4 Kohlenstoffatomen und [Z] für einen linearen oder verzweigten Polyhydroxyalkylrest mit 3 bis 10 Kohlenstoffatomen und 3 bis 10 Hydroxylgruppen steht. Bei den Polyhydroxyfettsäureamiden handelt es sich um bekannte Stoffe, die üblicherweise durch reduktive Aminierung eines reduzierenden Zuckers mit Ammoniak, einem Alkylamin oder einem Alkanolamin und nachfolgende Acylierung mit einer Fettsäure, einem Fettsäurealkylester oder einem Fettsäurechlorid erhalten werden können.Further suitable surfactants are polyhydroxy fatty acid amides of the following formula

wherein RCO is an aliphatic acyl group having 6 to 22 carbon atoms, R ^{23 is} hydrogen, an alkyl or hydroxyalkyl group having 1 to 4 carbon atoms and [Z] is a linear or branched polyhydroxyalkyl group having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups. The polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.

in der R für einen linearen oder verzweigten Alkyl- oder Alkenylrest mit 7 bis 12 Kohlenstoffatomen, R²⁴ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest mit 2 bis 8 Kohlenstoffatomen und R²⁵ für einen linearen, verzweigten oder cyclischen Alkylrest oder einen Arylrest oder einen Oxy-Alkylrest mit 1 bis 8 Kohlenstoffatomen steht, wobei C_1-4-Alkyl- oder Phenylreste bevorzugt sind und [Z] für einen linearen Polyhydroxyalkylrest steht, dessen Alkylkette mit mindestens zwei Hydroxylgruppen substituiert ist, oder alkoxylierte, vorzugsweise ethoxylierte oder propoxylierte Derivate dieses Restes.The group of polyhydroxy fatty acid amides also includes compounds of the following formula

in the R is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R ^{24 is} ei a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R ^{25 is} a linear, branched or cyclic alkyl radical or an aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms, wherein C _1-4 alkyl or Phenyl radicals are preferred and [Z] is a linear polyhydroxyalkyl radical whose alkyl chain is substituted with at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated derivatives of this radical.

[Z] is preferably by reductive amination of a reduced sugar obtained, for example, glucose, fructose, maltose, lactose, galactose, Mannose or xylose. The N-alkoxy or N-aryloxy-substituted Compounds can then be converted, for example, by reaction with fatty acid methyl esters in the presence of an alkoxide as Catalyst converted into the desired polyhydroxy fatty acid amides become.

Suitable are also N-methylglucamides.

in der R²⁶ für Alkyl- und/oder Alkenylreste mit 6 bis 22 Kohlenstoffatomen, R²⁷ für Wasserstoff oder Alkylreste mit 1 bis 4 Kohlenstoffatomen, R²⁸ für Alkylreste mit 1 bis 4 Kohlenstoffatomen, n für Zahlen von 1 bis 6 und X¹ für ein Alkali- und/oder Erdalkalimetall oder Ammonium steht. Typische Beispiele sind die Carboxymethylierungsprodukte von Hexylmethylamin, Hexyldimethylamin, Octyldimethylamin, Decyldimethylamin, Dodecylmethylamin, Dodecyldimethylamin, Dodecylethylmethylamin, C_12/14-Kokosalkyldimethylamin, Myristyldimethylamin, Cetyldimethylamin, Stearyldimethylamin, Stearylethylmethylamin, Oleyldimethylamin, C_16/18-Talgalkyldimethylamin sowie deren technische Gemische.The agents according to the invention preferably also contain amphoteric surfactants. In addition to numerous mono- to tri-alkylated amine oxides, the betaines represent an important class. Betaines are known surfactants which are predominantly produced by carboxyalkylation, preferably carboxymethylation of aminic compounds. Preferably, the starting materials are condensed with halocarboxylic acids or their salts, in particular with sodium chloroacetate, wherein one mole of salt is formed per mole of betaine. Furthermore, the addition of unsaturated carboxylic acids, such as acrylic acid is possible. As regards the nomenclature and, in particular, the distinction between betaines and 'true' amphoteric surfactants, reference should be made to the relevant literature. Examples of suitable betaines are the carboxyalkylation products of secondary and in particular tertiary amines which follow the formula (IX)

in the R ^{26 is} alkyl and / or alkenyl radicals having 6 to 22 carbon atoms, R ^{27 is} hydrogen or alkyl radicals having 1 to 4 carbon atoms, R ^{28 is} alkyl radicals having 1 to 4 carbon atoms, n is from 1 to 6 and X ^{1 is from} an alkali and / or alkaline earth metal or ammonium. Typical examples are the carboxymethylation products of hexylmethylamine, hexyldimethylamine, octyldimethylamine, decyldimethylamine, dodecylmethylamine, dodecyldimethylamine, dodecylethylmethylamine, C _12/14 cocoalkyldimethylamine, myristyldimethylamine, cetyldimethylamine, stearyldimethylamine, stearylethylmethylamine, oleyldimethylamine, C _16/18 tallowalkyldimethylamine, and technical mixtures thereof.

in der R³¹CO für einen aliphatischen Acylrest mit 6 bis 22 Kohlenstoffatomen und 0 oder 1 bis 3 Doppelbindungen, m für Zahlen von 1 bis 3 steht und R²⁹, R³⁰, n und X² die oben angegebenen Bedeutungen haben. Typische Beispiele sind Umsetzungsprodukte von Fettsäuren mit 6 bis 22 Kohlenstoffatomen, namentlich Capronsäure, Caprylsäure, Caprinsäure, Laurinsäure, Myristinsäure, Palmitinsäure, Palmoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Gemische, mit N,N-Dimethylaminoethylamin, N,N-Dimethylaminopropylamin, N,N-Diethylaminoethylamin und N,N-Diethylaminopropylamin, die mit Natriumchloracetat kondensiert werden. Bevorzugt ist der Einsatz eines Kondensationsproduktes von C_8/18-Kokosfettsäure-N,N-dimethylaminopropylamid mit Natriumchloracetat.Also suitable are carboxyalkylation products of amidoamines which follow the formula (X),

in which R ^{31 is} CO for an aliphatic acyl radical having 6 to 22 carbon atoms and 0 or 1 to 3 double bonds, m is a number from 1 to 3 and R ²⁹ , R ³⁰ , n and X ² are as defined above. Typical examples are reaction products of fatty acids having 6 to 22 carbon atoms, namely caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures, with N, N-dimethylaminoethylamine, N, N-dimethylaminopropylamine, N, N-diethylaminoethylamine and N, N-diethylaminopropylamine, which are condensed with sodium chloroacetate. The use of a condensation product of C _8/18 coconut fatty acid N, N-dimethylaminopropylamide with sodium chloroacetate is preferred.

in der R³² für einen Alkylrest mit 5 bis 21 Kohlenstoffatomen, R³³ für eine Hydroxylgruppe, einen OCOR³²- oder NHCOR³²-Rest und m für 2 oder 3 steht. Auch bei diesen Substanzen handelt es sich um bekannte Stoffe, die beispielsweise durch cyclisierende Kondensation von 1 oder 2 Mol Fettsäure mit mehrwertigen Aminen, wie beispielsweise Aminoethyl-ethanolamin (AEEA) oder Diethylentriamin erhalten werden können. Die entsprechenden Carboxyalkylierungsprodukte stellen Gemische unterschiedlicher offenkettiger Betaine dar. Typische Beispiele sind Kondensationsprodukte der oben genannten Fettsäuren mit AEEA, vorzugsweise Imidazoline auf Basis von Laurinsäure oder wiederum C_12/14-Kokosfettsäure, die anschließend mit Natriumchloracetat betainisiert werden.Furthermore come as suitable starting materials for the purposes of the invention optionally usable Betaine also considers imidazolines that follow the formula (XI),

in which R ^{32 is} an alkyl radical having 5 to 21 carbon atoms, R ^{33 is} a hydroxyl group, an OCOR ³² or NHCOR ³² radical and m is 2 or 3. These substances are also known substances which can be obtained, for example, by cyclizing condensation of 1 or 2 moles of fatty acid with polyhydric amines, such as, for example, aminoethyl-ethanolamine (AEEA) or diethylenetriamine. The corresponding carboxyalkylation products are mixtures of different open-chain betaines. Typical examples are condensation products of the abovementioned fatty acids with AEEA, preferably imidazolines based on lauric acid or again C _12/14 coconut fatty acid, which are subsequently betainized with sodium chloroacetate.

Solvents contained in the inventive compositions for example, come from the group of or polyhydric alcohols, alkanolamines or glycol ethers. Preferably if the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or butanediol, glycerol, Diglycol, propyl or butyl diglycol, hexylene glycol, ethylene glycol methyl ether, Ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, Diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, butoxy-propoxy-propanol (BPP), dipropylene glycol monomethyl, or ethyl ether, di-isopropylene glycol monomethyl, or ethyl ether, Methoxy, ethoxy or butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures this solvent.

Some glycol ethers are available under the trade name Arcosolv ^® (Arco Chemical Co.) or Cellosolve ^®, carbitol ^® or Propasol ^® (Union Carbide Corp.); this includes z. B. ButylCarbitol® ^{®, ®} hexyl carbitol, methyl ^®, and Carbitol ^® itself, (2- (2-ethoxy) ethoxy) ethanol. The choice of glycol ether can be readily made by one skilled in the art on the basis of its volatility, water solubility, weight percent of total dispersion, and the like. Pyrrolidone solvents, such as N-alkyl-pyrrolidones, for example N-methyl-2-pyrrolidone or NC ₈ -C ₁₂ -alkyl-pyrrolidone, or 2-pyrrolidone, may also be used. Further preferred as the sole solvent or as a constituent of a solvent mixture are glycerol derivatives, in particular glycerol carbonate.

Among the alcohols which may be included in the compositions of the invention are low molecular weight liquid polyethylene glycols, for example polyethylene glycols having a molecular weight of 200, 300, 400 or 600. Further suitable cosolvents are other alcohols, for example (a) lower alcohols such as Ethanol, propanol, isopropanol and n-butanol, (b) ketones such as acetone and methyl ethyl ketone, (c) C ₂ -C ₄ polyols such as a diol or a triol, for example ethylene glycol, propylene glycol, glycerol or mixtures thereof. Especially preferred is 1,2-octanediol from the class of diols.

In a preferred embodiment, the agent according to the invention contains one or more solvents from the group comprising C ₁ to C ₄ monoalcohols, C ₂ to C ₆ glycols, C ₃ to C ₁₂ glycol ethers and glycerol, in particular ethanol. The C ₃ - to C ₁₂ glycol ethers according to the invention contain alkyl or alkenyl groups having less than 10 carbon atoms, preferably up to 8, in particular up to 6, more preferably 1 to 4 and most preferably 2 to 3 carbon atoms.

Preferred C ₁ to C ₄ monohydric alcohols are ethanol, n-propanol, isopropanol and tert-butanol. Preferred C ₂ to C ₆ glycols are ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, 1,5-pentanediol, neopentyl glycol and 1,6-hexanediol, in particular ethylene glycol and 1,2-propylene glycol. Preferred C ₃ - to C ₁₂ glycol ethers are di-, tri-, tetra- and pentaethylene glycol, di-, tri- and tetrapropylene glycol, propylene glycol monotertiary butyl ether and propylene glycol monoethyl ether and the solvents designated according to INCI butoxydiglycol, butoxyethanol, butoxyisopropanol, butoxypropanol, butyloctanol, ethoxydiglycol, Ethoxyethanol, ethyl hexanediol, isobutoxypropanol, isopentyldiol, 3-methoxybutanol, methoxyethanol, methoxyisopropanol and methoxymethylbutanol.

The Means according to the invention may be one or more Solvents contained only in such amounts, so that it still a solid.

In a preferred embodiment, the inventive Agents, preferably detergents or cleaners, if appropriate contain one or more complexing agents.

complexing (INCI chelating agents), also called sequestering agents, are ingredients, to complex and inactivate the metal ions.

Suitable For example, the following are named according to INCI Complexing agents, for example, in the International Cosmetic Ingredient Dictionary and Handbook are described in more detail: Aminotrimethylene Phosphonic Acid, Beta-Alanine Diacetic Acid, Calcium Disodium EDTA, Citric Acid, Cyclodextrin, Cyclohexanediamine Tetraacetic Acid, Diammonium Citrate, Diammonium EDTA, Diethylenetriamine Pentamethylene Phosphonic acid, dipotassium EDTA, disodium azacycloheptane diphosphonates, Disodium EDTA, Disodium Pyrophosphate, EDTA, Etidronic Acid, Galactaric Acid, Gluconic Acid, Glucuronic Acid, HEDTA, Hydroxypropyl Cyclodextrin, Methyl cyclodextrin, pentapotassium triphosphates, pentasodium aminotrimethylene phosphonates, Pentasodium Ethylenediamine Tetramethylene Phosphonate, Pentasodium Pentetates, pentasodium triphosphates, pentetic acid, phytic acid, Potassium Citrate, Potassium EDTMP, Potassium Gluconate, Potassium Polyphosphates, Potassium Trisphosphonomethylamine Oxides, Ribonic Acid, Sodium Chitosan Methylene Phosphonates, Sodium Citrate, Sodium Diethylenetriamine Pentamethylene phosphonates, Sodium dihydroxyethyl glycinates, Sodium EDTMP, Sodium Gluceptate, Sodium Gluconate, Sodium Glycereth-1 Polyphosphates, Sodium Hexametaphosphate, Sodium Metaphosphate, Sodium Metasilicate, Sodium Phytate, Sodium Polydimethylglycinophenolsulfonate, Sodium trimetaphosphates, TEA-EDTA, TEA polyphosphates, tetrahydroxyethyl Ethylenediamine, Tetrahydroxypropyl Ethylenediamine, Tetrapotassium Etidronates, tetrapotassium pyrophosphates, tetrasodium EDTA, tetrasodium Etidronates, Tetrasodium pyrophosphates, Tripotassium EDTA, Trisodium Dicarboxymethyl Alaninate, Trisodium EDTA, Trisodium HEDTA, Trisodium NTA and trisodium phosphates.

preferred Chelating agents are tertiary amines, especially tertiary Alkanolamines (amino alcohols). The alkanolamines have both amino as well as hydroxy and / or ether groups as functional groups. Especially preferred tertiary alkanolamines are triethanolamine and Tetra-2-hydroxypropylethylenediamine (N, N, N ', N'-tetrakis (2-hydroxy-propyl) ethylenediamine).

One Particularly preferred complexing agent is etidronic acid (1-hydroxyethylidene-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid, HEDP, acetophosphonic acid, INCI Etidronic Acid) including their salts. In a preferred embodiment contains the agent according to the invention accordingly as a complexing agent Etidronic acid and / or one or more of its salts.

In a particular embodiment contains the inventive Means a complexing agent combination of one or more tertiary Amines and one or more other complexing agents, preferably one or more complexing acids or their salts, in particular of triethanolamine and / or tetra-2-hydroxypropylethylenediamine and etidronic acid and / or one or more of its salts.

The Detergents or cleaning agents according to the invention advantageously contains complexing agents in an amount from usually 0 to 20% by weight, preferably 0.1 to 15 wt .-%, in particular 0.5 to 10 wt .-%, particularly preferably 1 up to 8% by weight, more preferably from 1.5 to 6% by weight, based on the entire detergent or cleaning agent.

In a further preferred embodiment optionally, the agent according to the invention or more enzymes.

When Enzymes are especially those from the classes of hydrolases as the proteases, esterases, lipases or lipolytic acting Enzymes, amylases, cellulases or other glycosyl hydrolases and mixtures the enzymes mentioned in question. All of these hydrolases carry in the Laundry to remove stains such as protein, grease and or starchy stains and grayness. Cellulases and other glycosyl hydrolases may be over it By removing pilling and microfibrils for color retention and to increase the softness of the textile. to Bleaching or to inhibit color transfer can also Oxireduktasen be used.

Particularly suitable are bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens derived enzymatic agents. Preferably, subtilisin-type proteases and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and Li pase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or Lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest. Examples of such lipolytic enzymes are the known cutinases. Peroxidases or oxidases have also proved suitable in some cases. Suitable amylases include in particular α-amylases, iso-amylases, pullulanases and pectinases. As cellulases are preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures thereof used. Since different cellulase types differ by their CMCase and avicelase activities, the desired activities can be set by targeted mixtures of the cellulases. It is particularly advantageous if the agents according to the invention contain mannanase. This corresponds to a preferred embodiment of the invention. It was found that the mannanase in combination with the photocatalytic material gave a particularly good effect in the soil removal of galactomannanhaltigen residues. The use of tannase is also preferred.

The Enzymes can act as shaped bodies on carriers be embedded or coated to protect against premature To protect decomposition. The proportion of enzymes, enzyme mixtures or enzyme granules may, for example, about 0.1 to 5 wt .-%, preferably 0.12 to about 2 wt .-%, based on the total washing or detergent.

The agents according to the invention, preferably detergents or cleaners, may contain bleaching agents. Among the compounds serving as bleaches in water H ₂ O ₂ , sodium percarbonate, sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance. Other useful bleaching agents are, for example, peroxopyrophosphates, citrate perhydrates and H ₂ O ₂ -producing peracidic salts or peracids, such as persulfates or persulfuric acid. Also useful is the urea peroxohydrate percarbamide, which can be described by the formula H ₂ N-CO-NH ₂ .H ₂ O ₂ . In particular, when using the means for cleaning hard surfaces, for example in automatic dishwashing, they may, if desired, also contain bleaching agents from the group of organic bleaches, although their use is also possible in principle for laundry detergents. Typical organic bleaches are the diacyl peroxides, such as dibenzoyl peroxide. Other typical organic bleaches are the peroxyacids, examples of which include the alkyl peroxyacids and the aryl peroxyacids. Preferred representatives are the peroxybenzoic acid and its ring-substituted derivatives, such as alkylperoxybenzoic acids, but also peroxy-α-naphthoic acid and magnesium monoperphthalate, the aliphatic or substituted aliphatic peroxyacids, such as peroxylauric acid, peroxystearic acid, ε-phthalimidoperoxycaproic acid (phthalimidoperoxyhexanoic acid, PAP), o-carboxybenzamidoperoxycaproic acid, N-nonenylamidoperadipic acid and N-nonenylamidopersuccinates, and aliphatic and araliphatic peroxydicarboxylic acids such as 1,12-diperoxycarboxylic acid, 1,9-diperoxyazelaic acid, diperoxysebacic acid, diperoxybrassic acid, the diperoxyphthalic acids, 2-decyldiperoxybutane-1,4-diacid, N, N-terephthaloyl di (6-aminopercaproic acid) can be used.

The Bleaching agents may preferably be coated to contain them to protect against premature decomposition.

The Detergents or cleaning agents according to the invention may preferably contain one or more antimicrobial agents or preservatives in an amount of usually 0.0001 to 3 wt .-%, preferably 0.0001 to 2 wt .-%, in particular 0.0002 to 1 wt%, more preferably 0.0002 to 0.2 wt%, extremely preferably 0.0003 to 0.1 wt .-%, contained.

antimicrobial Active substances or preservatives are differentiated according to the antimicrobial spectrum and mechanism of action between bacteriostats and bactericides, Fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol-urea acetate. The terms antimicrobial effect and antimicrobial active ingredient in the context of the invention Teach the usual meaning. Suitable antimicrobial Active ingredients are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic esters, acid amides, Phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface active agents Compounds, guanidines, antimicrobial amphoteric compounds, Quinolines, 1,2-dibromo-2,4-di-cyanobutane, iodo-2-propyl-butyl-carbamate, Iodine, iodophors, peroxo compounds, halogen compounds and any Mixtures of the preceding.

The antimicrobial agent may be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1,2-propylene glycol, glycerol, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-propanol. Methylmorpholine-acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylenebis (6-bromo-4-chlorophenol), 4,4'-di-chloro-2'-hydroxydiphenyl ether ( Dichlosan), 2,4,4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) -urea, N, N '- (1, 10-decanediyldi-1-pyridinyl-4-ylidene) bis (1-octanamine) dihydrochloride, N, N'-bis (4-chlorophenyl) -3,12-diimino-2,4,11, 13-tetraaza-tetradecandiimidamide, glucoprotamines, antimicrobial quaternary surface active compounds, guanidines including the bi- and polyguanidines such as 1,6-bis (2-ethylhexyl-biguanido-hexane) -dihydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-phenyl-N ₁ , N ₁ -methyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -o-chlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ', 2,6-dichlorophenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1,6-di- [N ₁ , N ₁ '-beta (p-methoxyphenyl) diguanido-N ₅ , N, ₅ '] -hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ ' -alpha-methyl-beta-phenyldiguanido-N ₅ , N ₅ ') -hexane dihydrochloride, 1.6- Di- (N ₁ , N ₁ '- p -nitrophenyldiguanido-N ₅ , N ₅ ') hexane dihydrochloride, omega: omega-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') -di n-propyl ether dihydrochloride, omega: omega'-di- (N ₁ , N ₁ '-p-chlorophenyldiguanido-N ₅ , N ₅ ') di-n-propyl ether tetrahydrochloride, 1,6-di (N ₁ , N ₁ '-2,4-dichlorophenyldiguanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- (N ₁ , N ₁ '-p-methylphenyl-diguanido-N ₅ , N ₅ ') hexane dihydrochloride, 1,6-di- (N ₁ , N ₁ '-2,4,5-trichlorophenyldi guanido-N ₅ , N ₅ ') hexane-tetrahydrochloride, 1,6-di- [N ₁ , N ₁ ' -alpha (p-chlorophenyl) ethyldiguanido-N ₅ , N ₅ '] hexane dihydrochloride, omega: omega-di (N ₁ , N ₁ ' -p-chlorophenyl) nyldiguanido-N ₅ , N ₅ ') m-xylenedihydrochloride, 1,12-di- (N ₁ , N ₁ ' -p-chlorophenyldiguanido-N ₅ , N ₅ ) dodecane dihydrochloride, 1,10-di - (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') decane tetrahydrochloride, 1,12-di- (N ₁ , N ₁ '-phenyldiguanido-N ₅ , N ₅ ') dodecane-tetrahydrochloride, 1, 6-di- (N ₁ , N ₁ '-o-chlorophenyl-guanido-N ₅ , N ₅ ') hexane-dihydrochloride, 1,6-di- (N ₁ , N ₁ '-o-chloro-phenyldiguanido-N ₅ , N ₅ ') hexane tetrahydrochloride, ethylene bis (1-tolyl biguanide), ethylene bis (p-tolyl biguanide), ethylene bis (3,5-dimethylphenyl biguanide), ethylene bis (p-tert-butyl) amylphenyl biguanide), ethylene bis (nonylphenyl biguanide), ethylene bis (phenyl biguanide), ethylene bis (N-butylphenyl biguanide), ethylene bis (2,5-diethoxyphenyl biguanide), ethylene bis (2,4-dimethyl phenyl biguanide ), Ethylene bis (o-diphenylbiguanide), ethylene bis (mixed amyl naphthyl biguanide), N-butyl ethylene bis (phenylbiguanide), trimethylene bis (o-tolyl biguanide), N-butyl trimethyl bis (phenyl biguanide) and the corresponding salts such as acetates, glucone ate, hydrochlorides, hydrobromides, citrates, bisulfites, fluorides, polymaleates, N-cocoalkyl sarcosinates, phosphites, hypophosphites, perfluorooctanoates, silicates, sorbates, salicylates, maleates, tartrates, fumarates, ethylenediaminetetraacetates, iminodiacetates, cinnamates, thiocyanates, arginates, pyromellitates, tetracarboxybutyrates, Benzoates, glutarates, monofluorophosphates, perfluoropropionates and any mixtures thereof. Furthermore, halogenated xylene and cresol derivatives, such as p-chloromethacresol or p-chlorometaxylene, as well as natural antimicrobial agents of plant origin (eg from spices or herbs), of animal and microbial origin are suitable. Preferably, antimicrobial surface-active quaternary compounds, a natural antimicrobial agent of plant origin and / or a natural antimicrobial agent of animal origin, most preferably at least one natural antimicrobial agent of plant origin from the group comprising caffeine, theobromine and theophylline and essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial agent of animal origin from the group, comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobial surface-active quaternary compound with an ammonium, sulfonium, phosphonium, iodonium - or Arsoniumgruppe, peroxo compounds and chlorine compounds are used. Also substances of microbial origin, so-called bacteriocins, can be used. Glycine, glycine derivatives, formaldehyde, compounds which readily split off formaldehyde, formic acid and peroxides are preferably used.

The suitable as antimicrobial agents quaternary ammonium compounds (QAV) have been described above. Is particularly suitable, for example, benzalkonium chloride, etc. Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ^® ex Lonza, Marquat® ^® ex Mason, Variquat ^® ex Witco / Sherex and Hyamine ^® ex Lonza and as Bardac ^® ex Lonza. Other commercially obtainable antimicrobial agents are N- (3-chloroallyl) hexaminium chloride such as Dowicide and Dowicil ^{® ®} ex Dow, benzethonium chloride such as Hyamine ^® 1622 ex Rohm & Haas, methylbenzethonium as Hyamine ^® 10X ex Rohm & Haas, cetylpyridinium chloride such as Cepacol ex Merrell Labs ,

Furthermore, the agents according to the invention, preferably washing or cleaning agents, may optionally contain ironing aids for improving the water absorbency, the rewettability of the treated textiles and for facilitating the ironing of the treated textiles. For example, silicone derivatives can be used in the formulations. These additionally improve the rinsing out of the wash-active formulations by their foam-inhibiting properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated. Preferred silicones are polydimethylsiloxanes which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds.

The agents according to the invention may preferably perfumed with perfume oil (fragrances, fragrances) be.

With The term perfume oil are preferably in themselves meant perfume compositions which commonly be used for product scenting and in particular for human Discretion are fragrant. This will be explained with an example. Will a professional z. B. make a shower gel fragrant, so adds He usually does not just give him a (well) smelling Substance, but a collective (well) smelling substances. Such a collective usually consists of a multitude individual fragrances, z. B. more than 10 or 15, preferably to to 100 or more. These riches cooperatively form a desired one fragrant, harmonious smell.

One Perfume oil according to the invention can individual fragrance compounds, eg. B. the synthetic products of the type of esters, ethers, aldehydes, ketones, alcohols and hydrocarbons contain. Fragrance compounds of the ester type are e.g. B. benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, Dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, Ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, Benzyl salicylate, cyclohexyl salicylate, Floramat, Melusat and Jasmecyclat. The ethers include, for example, benzyl ethyl ether and Ambroxan, to the aldehydes z. B. the linear alkanals with 8-18 C atoms, citral, citronellal, citronellyloxy-acetaldehyde, cyclamen aldehyde, lilial and Bourgeonal, to the ketones z. As the Jonone, α-Isomethylionon and methyl cedryl ketone, to the alcohols anethole, citronellol, eugenol, Geraniol, linalool, phenylethyl alcohol and terpineol, to the hydrocarbons are mainly the terpenes like limonene and pinas. However, mixtures of different fragrances are preferred used, which together form an appealing scent of the formed Create perfume oil.

The But perfume oils can also be natural Fragrance mixtures contain as accessible from plant sources are, for. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are muscatel sage oil, chamomile oil, Clove oil, lemon balm oil, mint oil, cinnamon leaf oil, Lime blossom oil, juniper berry oil, vetiver oil, Olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroliol, orange peel oil and sandalwood oil. To be perceptible, one must Fragrance be volatile, being in addition to the nature of the functional Groups and the structure of the chemical compound also the molecular weight plays an important role. So have the most fragrances Molar masses up to about 200 daltons, while molar masses of 300 Dalton and more of an exception. by virtue of the different volatility of fragrances changed the smell of a compound of several fragrances Perfumes during evaporation, taking the Olfactory impressions in "top note", "heart note" or middle note "(middle note or body) and" base note " (end note or dry out) divided.

Tenacious Fragrances, in the context of the present invention advantageously can be used in the perfume oils, for example the essential oils like angelica root oil, Aniseed oil, arnica blossom oil, basil oil, Bay oil, champacabell oil, silver fir oil, Pine oil, Elemiöl, Eucalyptusöl, Fennel oil, spruce alder oil, galbanum oil, Geranium oil, ginger grass oil, guaiac wood oil, Gurjun Balm Oil, Helichrysum Oil, Ho Oil, Ginger Oil, Iris oil, cajeput oil, calamus oil, chamomile oil, Camphor oil, kanaga oil, cardamom oil, cassia oil, Pine Needle Oil, Kopaïva Balsam Oil, Coriander Oil, Spearmint oil, caraway oil, cumin oil, Lemongrass oil, musk kernel oil, myrrh oil, Clove oil, neroli oil, niaouli oil, olibanum oil, Origanum oil, palmarosa oil, patchouli oil, Peru balsam oil, petitgrain oil, pepper oil, Peppermint oil, allspice oil, pine oil, rose oil, Rosemary oil, sandalwood oil, celery oil, Star anise, thuja oil, thyme oil, verbena oil, Vetiver oil, juniper berry oil, wormwood oil, Wintergreen Oil, Ylang Ylang Oil, Hyssop Oil, Cinnamon oil, cinnamon leaf oil and cypress oil.

But the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention advantageously as adherent fragrances or fragrance mixtures in the perfume oils. These compounds include the following compounds and mixtures thereof: ambrettolide, α-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, borneol, bornyl acetate, α-bromostyrene, n -Decylaldehyde, n-dodecylaldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron, isoeugenol, isoeugenol methyl ether, isosafrole, jasmon , Camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl-n-amyl ketone, Methylanthranilsäuremethyles ter, p-methylacetophenone, methylchavikol, p-methylquinoline, methyl-β-naphthyl ketone, methyl-n-nonylacetaldehyde, methyl n-nonyl ketone, muscone, β-naphthol ethyl ether, β-naphthol methyl ether, nerol, nitrobenzene, n-nonylaldehyde, Nonyl alcohol, n-octylaldehyde, p-oxyacetophenone, pentadecanolide, β-phenylethyl alcohol, phenylacetaldehyde dimethyl acetal, phenylacetic acid, pulegone, safrole, isoamyl salicylate, methyl salicylate, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, skatole, terpineol, thymene, thymol, γ-undelactone, Vaniline, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester. Among the more volatile fragrances, which are advantageously used in the perfume oil in the present invention include, in particular, the lower-boiling fragrances natural or synthetic origin, which can be used alone or in mixtures. Examples of more readily volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linayl acetate and propionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

All The aforementioned fragrances are alone or in a mixture in the perfume oils according to the present invention with the already can be used.

Especially can also scents from the group of allyl alcohol esters, Esters of secondary alcohols, esters of tertiary alcohols, allylic ketones, acetals, ketals, condensation products of amines and aldehydes and / or mixtures thereof in perfume oil be included.

allyl alcohol are the esters of allyl alcohol, which has the following structural feature has, C (OH) -C = C. Examples of allylalkohlester are in particular allylamyl glycolate, allylanthranilate, allyl benzoate, allyl butyrate, Allyl caprate, allyl caproate, allyl cinnamate, allyl cyclohexane acetate, allyl cyclohexane butyrate, Allylcyclohexane propionate, allylheptoate, allylnonanoate, allylsalicylate, Amyl cinnamyl acetate, amyl cinnamyl formate, cinnamyl formates, cinnamyl acetates, Cyclogalbanate, geranyl acetate, geranylacetoacetate, geranyl benzoate, Geranyl cinnamate, methallyl butyrate, methallyl caproate, neryl acetate, Neryl butyrate, amyl cinnamyl formate, alpha methyl cinnamyl acetate, methyl geranyl tiglate, mertenyl acetate, farnesyl acetate, fenchyl acetate, geranyl anthranilate, Geranyl butyrate, Gerany isobutyrate, geranyl caproate, geranyl caprylate, Geranyl ethyl carbonate, geranyl formate, geranyl furoate, geranyl heptoate, Geranylmethoxyacetate, geranyl pelargonate, geranylphenylacetate, geranylphthalate, geranylpropionate, Geranyl iso-propoxyacetate, garanyl valerate, geranyl iso-valerate, trans-2-hexenyl acetate, trans-2-hexenyl butyrate, trans-2-hexenyl caproate, trans-2-hexenylphenylacetate, trans-2-hexenylpropionate, trans-2-hexenyltiglate, trans-2-hexenyl valerate, beta-pentenyl acetate, alpha-phenylallyl acetate, Prenyl acetate, Trichloromethylphenylcarbinylacetat and / or their Mixtures. Allyl alcohol esters may preferably be used in the invention Perfume oil may be included.

Examples of Esters of Secondary Alcohols (Secondary alcohols are present when two H atoms are substituted by organic radicals (R ¹ and R ² ) on the carbon atom bearing the OH group [general formulas: R ¹ -CH ( OH) -R ² ]) are in particular ortho-tert-amylcyclohexyl acetate, isoamylbenzylacetate, secondary n-amylbutyrate, amylvinylcarbinylacetate, amylvinylcarbinylpropionate, cyclohexylsalicylate, dihydro-nor-cyclopentadienylacetate, dihydro-nor-cyclopentadienylpropionate, isobornylacetate, isobornylsalicylate, isobornylvalerate, Frutene, 2 Methylbutene-2-ol-4-acetate, methylphenylcarbinylacetate, 2-methyl-3-phenylpropan-2-yl acetate, prenylacetate, 4-tert-butylcyclohexylacetate, verdox (2-tert-butylcyclohexylacetate), I vertenex (4- tert-butylcyclohexyl acetate), Violiff (carboxylic acid 4-cycloocten-1-yl methyl ester), ethenyl-iso-amyl carbinyl acetate, fenchyl acetate, fenchyl benzoate, fenchyl n-butyrate, fenchyl isobutyrate, laevomenthyl acetate, dl-menthyl acetate, menthyl anthranilate, menthyl benzoate, menthyl -i soy butyrate, menthyl formate, levo-menthyl phenylacetate, menthyl propionate, menthyl salicylate, menthyl iso-valerate, cyclohexyl acetates, cyclohexyl anthranilate, cyclohexyl benzoate, cyclohexyl butyrate, cyclohexyl isobutyrate, cyclohexyl caproate, cyclohexyl cinnamate, cyclohexyl formates, cyclohexylheptoate, cyclohexyl oxalate, cyclohexyl pelargonate, cyclohexyl phenylacetate, cyclohexyl propionate, Cyclohexyl thioglycolate, cyclohexyl valerate, cyclohexyl iso-valerate, methyl amyl acetate, methyl benzyl carbinyl acetate, methyl butyl cyclohexanyl acetate, 5-methyl-3-butyltetrahydropyran-4-yl acetate, methyl citrate, methyl isophosphate, 2-methylcyclohexyl acetate, 4-methylcyclohexyl acetate, 4-methylcyclohexylmethylcarbinylacetate, methylethylbenzylcarbinylacetate , 2-methylheptanol-6-acetate, methylheptenylacetate, alpha-methyl-n-hexylcarbinylformate, methyl-2-methylbutyrate, methylnonylcarbinylacetate, methylphenylcarbinylacetate, methylphenylcarbinylanthranilate, methylphenylcarbinylbenzoate, methylphenylcarbinyl-n-butyrate, methylphenyl carbinyl isobutyrate, methylphenylcarbinyl; Caproate, methylphenylcarbinylcaprylate, methylphenylcarbinyl cinnamate, methylphenylcarbinylformate, methylphenylcarbinylphenylacetate, methylphenylcarbinylpropionate, methylphenylcarbinylsalicylate, methylphenylcarbinyliso-valerate, 3-nonanylacetate, 3-nonenylacetate, nonanediol-2,3-acetate, nonynolacetate, 2-octanylacetate, 3-octanylacetate, n-octyl acetate, sec-octylisobutyrate, beta-pentenylacetate, alpha-phenylallylacetate, phenylethylmethylcarbinyliso-valerate, phenylethylene glycol diphenylacetate, phenylethyethylcarbinylacetate, phenylglycoldiacetate, sec-phenylglycol monoacetate, phenylglycolmonobenzoate, isopropylcaprate, Isopropyl caproate, isophorppyl caprylate, isopropyl cinnamate, para-isopropylcyclohexanyl acetate, propyl glycol diacetate, propylene glycol di-isobutyrate, propylene glycol dipropionate, isopropyl n-heptoate, isopropyl n-hept-1-yne carbonate, isopropyl pelargonate, isopropyl propionate, isopropyl undecylenate, isopropyl n-valerate, isopropyl n-valerate, isopropyl iso-valerate, isopropyl sebacinate, isopulegyl acetate, isopuleglyacetoacetate, isopuleglyisobutyrate, isopulegylformate, thymylpropionate, alpha-2,4-trimethylcyclohexanemethylacetate, trimethylcyclohexylacetate, vanillin triacetate, vanillylidene diacetate, vanillylvanilate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Preferred examples of esters of tertiary alcohols (tertiary alcohols are those in which three H atoms are substituted by organic radicals R ¹ , R ² , R ³ at the α-C atom which carries the OH group (general formula: R ¹ R ² R ³ C-OH)) are tertiary amyl acetate, Caryophylleneacetat, Cedrenylacetat, Cedrylacetat, Dihydromyrcenylacetat, Dihydroterpinylacetat, Dimethylbenzylcarbinylacetat, Dimethylbenzylcarbinylisobutyrat, Dimethylheptenylacetat, Dimethylheptenylformiat, Dimethylheptenylpropionat, Dimethylheptenyl-iso-butyrate, Dimethylphenylethylcarbinylacetat, Dimethylphenylethylcarbinyl iso-butyrate, Dimethylphenylethylcarbinyl -iso-valerate, dihydro-nor-dicyclopentadienylacetate, dimethylbenzylcarbinylbutyrate, dimethylbenzylcarbinylformate, dimethylbenzylcarbinylpropionate, dimethylphenylethylcarbinyl-n-butyrate, dimethylphenyletylcarbinylformate, dimethylphenylethylcarbinylpropionate, elemylacetate, ethynylcyclohexylacetate, eudesylacetate, eugenylcinnamate, eugenylformate, iso-euge nylformiat, Eugenylphenylacetat, Isoeudehylphenylacetat, Guaiylacetat, Hydroxycitronellylethylcarbonat, Linallylacetat, Linallylanthranilat, Linallylbenzoat, Linallylbutyrat, Linallyliosbutyrat, Linallylcarproat, Linallylcaprylat, Linallylcinnamat, Linallylcitronellat, Linallylformiat, Linallylheptoat, Linallyl-N-methyl anthranilate, Linallylmethyltiglat, Linallylpelargonat, Linallylphenylacetat, Linallylpropionat, Linallylpyruvat, Linallylsalicylat, Linallyl n-valerate, linallyl iso-valerate, methylcyclopentenolone butyrate, methylcyclopentenolone propionate, methylethylphenylcarbinylacetate, methylheptincarbonate, methylnicotinate, myrcenylacetates, myrcenylformate, myrcenylpropionate, cis-ocimenylacetate, phenylsalicylate, terpinylacetate, terpinylanthranilate, terpinylbenzoate, terpinyl-n-butyrate, terpinyliso- butyrate, terpinyl cinnamate, terpinyl formate, terpinyl phenylacetate, terpinyl propionate, terpinyl n-valerate, terpinyl iso-valerate, tributyl acetyl citrate, and / or mixtures thereof. These esters may preferably be contained in the perfume oil according to the invention.

Some Fragrance esters can be both ester allylic and secondary or allylic and tertiary alcohols, in particular Amylvinylcarbinylacetate, amylvinylcarbinylpropionate, hexylvinylcarbinylacetate, 3-nonenylacetate, 4-hydroxy-2-hexenylacetate, linallylanthranilate, linallylbenzoate, Linallyl butyrate, linallyl butadate, linallyl carproate, linallyl caprylate, Linallyl cinnamate, linallyl citronellate, linallyl formate, linallylheptoate, Linallyl-N-methylanthranilate, linallylmethyltiglate, linallyl pelargonate, Linalinallyl phenylacetate, linallyl propionate, linallyl pyruvate, linallylsalicylate, Linallyl n-valerate, linallyl iso-valerate, myrtenyl acetate, nerolidyl acetates, Nerolidyl butyrate, beta-pentenyl acetate, alpha-phenylallyl acetate, and / or mixtures thereof. These esters may also be preferred in the perfume oil according to the invention be included.

allylic Ketones are characterized by the following structural feature C-C (= O) -C = C. Preferred examples are acetylfuran, allethrolone, Allylionone, allylpulegone, amylcyclopentenone, benzylideneacetone, benzylideneacetophenone, Alphaisomethylionone, 4- (2,6,6-trimethyl-1-cyclohexen-1-yl) 3-buten-2-one, Beta damascone (1- (2,6,6-trimethylcyclohexen-1-yl) -2-buten-1-one), Damascenone (1- (2,6,6-trimethyl-1,3-cyclohexadien-1-yl) -2-buten-1-one), Delta Damascone (1- (2,6,6-trimethyl-3-cyclohexen-1-yl) -2-buten-1-one), Alpha ionone (4- (2,6,6-trimethyl-1-cyclohexenyl-1-yl) -3-butene-2-one), Beta ionone (4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -3-buten-2-one), Gamma methyl ionone, (4- (2,6,6-trimethyl-2-cyclohexyl-1-yl) -3-methyl-3-buten-2-one), Pulegone and / or mixtures thereof. Allylic ketones can preferably in the perfume oil according to the invention be included.

Acetals are geminal diethers of the general formula R ¹ CH (OR ² ) (OR ³ ). Preferred examples are acetaldehyde benzyl-beta-methoxyethyl acetal, acetaldehyde diisoamyl acetal, acetaldehyde di-pentanediol acetal, acetaldehyde di-n-propyl acetal, acetaldehyde-ethyl-trans-3-hexenyl acetal, acetaldehyde phenylethylene glycol acetal, acetaldehyde phenylethyl n-propyl acetal, cinnamic aldehyde dimethyl acetal, acetaldehyde benzyl beta-methoxyethyl acetal, acetaldehyde diisoamyl acetal, acetaldehyde diethyl acetal, acetaldehyde di-cis-3-hexenyl acetal, acetaldehyde dipentanediol acetal, acetaldehyde di-n-propyl acetal, acetaldehyde ethyl trans- 3-hexenyl acetal, acetaldehyde-phenylethylene glycol acetal, acetaldehyde, phenylethyl-n-propyl acetal, acetylvinyl dimethyl acetal, alpha-amyl cinnamic aldehyde di-isopropyl acetal, p-tert-amylphenoxy acetaldehyde diethyl acetal, anisaldehyde diethyl acetal, anisaldehyde dimethyl acetal, isoapiols, benzaldehyde diethyl acetal, benzaldehyde di ( ethylene glycol monobutyl ether) acetal, benzaldehyde dimethyl acetal, benzaldehyde ethylene glycol acetal, benzaldehyde glyceryl acetal, Ben aldehyde-propylene glycol acetal, cinnamic aldehyde diethyl acetal, citraldiethyl acetal, citral dimethyl acetal, citralpropylene glycol acetal, alpha-methyl cinnamic aldehyde diethyl acetal, alpha-cinnamic aldehyde dimethyl acetal, phenyl acetaldehyde-2,3-butylene glycol acetal, phenyl acetal dehydcitronellylmethylacetal, Phenylacetaldehyddiallylacetal, Phenylacetaldehyddiamylacetal, Phenylacetaldehyddibenzylacetal, Phenylacetaldehyddibutylacetal, phenylacetaldehyde, Phenylacetaldehyddigeranylacetal, phenylacetaldehyde dimethylacetal, Phenylacetaldehydethyleneglycolacetal, Phenylacetaldglycerylacetal, Citronellalcyclomonoglycolacetal, Citronellaldiethylacetal, Citronellaldimethylacetal, Citronellaldiphenylethylacetal, Geranoxyacetaldehyddiethylacetal and / or mixtures thereof. Acetals may preferably be contained in the perfume oil according to the invention.

Ketals are geminal diethers of the general formula R ¹ R ² C (OR ³ ) (OR ⁴ ). Preferred examples are acetone diethyl ketal, acetone dimethyl ketal, acetophenone diethyl ketal, methyl amyl catechol ketal, methyl butyl catechol ketal and / or mixtures thereof. Ketals may preferably be present in the perfume oil according to the invention.

preferred Examples of condensation products of amines and aldehydes are anisaldehydemethylanthranilate, aurantiol (hydroxycitronellalmethylanthranilate), Verdantiol (4-tert-butyl-alphamethyldihydrocinnamaldehydmethylanthranilat) Vertosin (2,4-dimethyl-3-cyclohexene carbaldehyde), hydroxycitronellalane anthranilate, Hydroxycitronellallinallylanthranilate, methyl N- (4- (4-hydroxy-4-methylpentyl) -3-cyclohexenyl-methylidene) anthranilate, Methyl naphthyl ketone methyl anthranilate, methyl nonyl acetaldehyde methyl anthranilate, Methyl N- (3,5,5-trimethylhexylidene) anthranilate, vanillin methyl anthranilate and / or mixtures thereof. Condensation products of amines and Aldehydes may preferably be used in the invention Perfume oil may be included.

Especially it is advantageous if fragrances such. Adoxal (2,6,10-trimethyl-9-undecene-1-al), amyl acetate, Anisaldehyde (4-methoxybenzaldehydes), bacdanol (2-ethyl-4- (2,2,3-trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol), Benzaldehyde, benzophenone, benzyl acetate, benzyl salicylate, 3-hexen-1-ol, Cetalox (dodecahydro-3A, 6,6,9A-tetramethyl-naphtho [2,1B] -furan), cis-3-hexenylacetate, cis-3-hexenyl salicylate, citronellol, coumarin, cyclohexyl salicylate, Cymal (2-methyl-3- (para-isopropylphenyl) propionaldehyde), decyl aldehyde, ethyl vanillin, Ethyl 2-methyl butyrate, ethylene braseate, eucalyptol, eugenol, exaltolide (Cyclopentadecanolide), Florhydral (3- (3-isopropylphenyl) butanal), Galaxolide (1,3,4,6,7,8-hexahydro-4,6,6,7,8,8-hexamethyl-cyclopenta-gamma-2-benzopyran), gamma decalactone, gamma dodecalactone, geraniol, geranylnitrile, helional (alpha-methyl-3,4, (methylenedioxy) hydrocinnamaldehyde), Heliotropin, hexyl acetate, hexyl cinnamaldehyde, hexyl salicylate, hydroxyambrane (2-cyclododecylpropanol), Hydroxycitronellal, iso E super (7-acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7, tetramethyl naphthalene), isoeugenol, isojasmon, koavon (acetyl di-isoamylene), Lauryl aldehyde, Irg 201 (2,4-dihydroxy-3,6-dimethyl benzoic acid methyl ester), Lyral (4- (4-hydroxy-4-methyl-pentyl) -3-cyclohexene-1-carboxaldehyde), Majantol (2,2-dimethyl-3- (3-methylphenyl) -propanol), mayor (4- (1-methylethyl) cyclohexanemethanol), Methyl anthranilate, methyl beta naphthyl ketone, methyl cedrone (methyl cedryl ketone), Methylchavicol (1-methyloxy-4,2-propen-1-yl-benzene), methyldihydrojasmonate, Methyl nonylacetaldehyde, musk indanone (4-acetyl-6-tert-butyl-1,1-dimethyl indan), nerol, nonalactone (4-hydroxynonanoic acid, lactone), norlimbanol (1- (2,2,6-trimethylcyclohexyl) -3-hexanol), P.T. Bucinal (2-methyl-3 (para tert butylphenyl) propionaldehyde), para Hydroxyphenylbutanone, patchouli, phenylacetaldehyde, phenylethyl acetate, Phenylethylalcohol, phenylethylphenylacetate, phenylhexanol / phenoxanol (3-methyl-5-phenylpentanol), Polysantol (3,3-dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol), Rosaphen (2-methyl-5-phenylpentanol), sandalwood, alpha-terpinene, Tonalid / musk plus (7-acetyl-1,1,3,4,4,6-hexamethyltetralin), Undecalactone, undecavertol (4-methyl-3-decen-5-ol), undecylaldehyde or undecened aldehydes, vanillin and / or mixtures in the inventive Perfume oil are included.

• (a) mandelartigem Geruch, wie vorzugsweise Benzaldehyd, Pentanal, Heptenal, 5-Methylfurfural, Methylbutanal, Furfural und/oder Acetophenon oder
• (b) apfelartigem Geruch, wie vorzugsweise (S)-(+)-Ethyl-2-methylbutanoat, Diethylmalonat, Ethylbutyrat, Geranylbutyrat, Geranylisopentanoat, Isobutylacetat, Linalylisopentanoat, (E)-β-Damascone, Heptyl-2-methylbutyrat, Methyl-3-methylbutanoat, 2-Hexenal-pentyl-methylbutyrat, Ethylmethylbutyrate und/oder Methyl-2-Methylbutanoat oder
• (c) apfelschalenartigem Geruch, wie vorzugsweise Ethylhexanoat, Hexylbutanoat und/oder Hexylhexanoat oder
• (d) aprikosenartigem Geruch wie vorzugsweise γ-Undecalacton oder
• (e) bananenartigem Geruch, wie vorzugsweise Isobutylacetat, Isoamylacetat, Hexenylacetat und/oder Pentylbutanoat oder
• (f) bittermandelartigem Geruch wie vorzugsweise 4-Acetyltoluol oder
• (g) schwarze Johannisbeere-artigem Geruch wie vorzugsweise Mercaptomethylpentanon und/oder Methoxymethylbutanethiol oder
• (h) zitrusartigem Geruch wie vorzugsweise Linalylpentanoat, Heptanal, Linalylisopentanoat dodecanal, Linalylformiat, α-p-Dimethylstyrol, p-Cymenol, Nonanal, β-Cubebene, (Z)-Limonenoxid, cis-6-Ethenyltetrahydro-2,2,6-trimethylpyran-3-ol, cis-pyranoidlinalooloxid, Dihydrolinalool, 6(10)-Dihydromyrcenol, Dihydromyrcenol, β-Farnesen, (Z)-β-Farnesen, (Z)-Ocimen, (E)-Limonenoxid, Dihydroterpinylacetat, (+)-Limonen, (Epoxymethylbutyl)-methylfuran und/oder p-Cymen oder
• (i) kakaoartigem Geruch wie vorzugsweise Dimethylpyrazin, Butylmethylbutyrat und/oder Methylbutanal oder
• (j) kokusnußartigem Geruch, wie vorzugsweise γ-Octalacton, γ-Nonalacton, Methyllaurat, Tetradecanol, Methylnonanoat, (3S,3aS,7aR)-3a,4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2(3H)-on, 5-Butyldihydro-4-methyl-2(3H)-Furanon, Ethylundecanoat und/oder δ-Decalacton oder
• (k) sahneartigem Geruch wie vorzugsweise Diethylacetal, 3-Hydroxy-2-butanon, 2,3-Pentadion und/oder 4-Heptenal oder
• (l) blumenartigem Geruch wie vorzugsweise Benzylalcohol, Phenylessigsäure, Tridecanal, p-Anisylalcohol, Hexanol, (E,E)-Farnesylaceton, Methylgeranat, trans-Crotonaldehyd, Tetradecylaldehyd, Methylanthranilat, Linalooloxid, Epoxylinalool, Phytol, 10-epi-γ-Eudesmol, Neroloxid, Ethyldihydrocinnamat, γ-Dodecalacton, Hexadecanol, 4-Mercapto-4-methyl-2-pentanol, (Z)-Ocimene, Cetylalcohol, Nerolidol, Ethyl-(E)-cinnamat, Elemicin, Pinocarveol, α-Bisabolol, (2R,4R)-Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2H-pyran, (E)-Isoelemicin, Methyl-2-methylpropanoat, Trimethylphenylbutenon, 2-Methylanisol, β-Farnesol, (E)-Isoeugenol, Nitro-phenylethan, Ethylvanillat, 6-Methoxyeugenol, Linalool, β-Ionon, Trimethylphenylbutenon, Ethylbenzoat, Phenylethylbenzoat, Isoeugenol und/oder Acetophenone oder
• (m) Frische-Geruch wie vorzugsweise Methylhexanoat, Undecanon, (Z)-limonenoxid, Benzylacetat, Ethylhydroxyhexanoat, Isopropylhexanoat, Pentadecanal, β-Elemene, α-Zingiberene, (E)-Limonenoxid, (E)-p-Mentha-2,8-dien-1-ol, Menthon, Piperiton, (E)-3-Hexenol und/oder Carveol oder
• (n) Frucht-Geruch wie verzugsweise Ethylphenylacetat, Geranylvalerat, γ-Heptalacton, Ethylpropionat, Diethylacetal, Geranylbutyrat, Ethylheptylat, Ethyloctanoat, Methylhexanoat, Dimethylheptenal, Pentanon, Ethyl-3-methylbutanoat, Geranylisovalerat, Iobutylacetat, Ehoxypropanol, Mthyl-2-butenal, Methylnonanedion, Linalylacetat, Mthylgeranat, Lmonenoxid, Hdrocinnamicalcohol, Dethylsuccinat, Ehylhexanoat, Ehylmethylpyrazin, Nryletat, Ctronellylbutyrat, Heylacetat, Nonylacetat, Butylmethylbutyrat, Pentenal, Isopentyldimethylpyrazin, p-menth-1-en-9-ol, Hexadecanon, Octylacetat, γ-Dodecalacton, Epoxy-β-ionon, Ethyloctenoat, Ethylisohexanoat, Isobornylpropionat, Cedrenol, p-menth-1-en-9-yl acetat, Cadinadien, (Z)-3-Hexenylhexanoat, Ethylcyclohexanoat, 4-Methylthio-2-butanon, 3,5-Octadienon, Methylcyclohexancarboxylat, 2-pentylthiophen, α-Ocimene, Butandiol, Ethylvalerat, Pentanol, Isopiperiton, Butyloctanoat, Ethylvanillat, Methylbutanoat, 2-Mmethylbutylacetat, Propylhexanoat, Butylhexanoat, Isopropylbutanoat, Spathulenol, Butanol, δ-Dodecalacton, Methylquinoxalin, Sesquiphellandren, 2-Hexenol, Ethylbenzoate, Isopropylbenzoat, Ethyllactat und/oder Citronellylisobutyrat oder
• (o) Geranium-artigen Geruch, wie vorzugsweise Geraniol, (E,Z)-2,4-Nonadienal, Octadienon und/oder o-Xylen oder
• (p) weintraubenartigem Geruch wie vorzugsweise Ethyldecanoat und/oder Hexanon oder
• (q) grapefruitartigem Geruch wie vorzugsweise (+)-5,6-Dimethyl-8-isopropenylbicyclo[4.4.0]dec-1-en-3-on und/oder p-Menthenethiol oder
• (r) grasartigem Geruch wie vorzugsweise 2-Ethylpyridin, 2,6-Dimethylnaphthalen, Hexanal und/oder (Z)-3-Hexenol oder
• (s) grüner Note, vorzugsweise 2-Ethylhexanol, 6-Decenal, Dimethylheptenal, Hexanol, Heptanol, Methyl-2-butenal, Hexyloctanoate, Nonansäure, Undecanon, Methylgeranat, Isobornylformiate, Butanal, Octanal, Nonanal, Epoxy-2-decenal, cis-Linalool, Pyranoxid, Nonanol, alpha,γ-dimethylallylalcohol, (Z)-2-penten-1-ol, (Z)-3-hexenylbutanoat, Isobutylthiazol, (E)-2-nonenal, 2-dodecenal, (Z)-4-decenal, 2-octenal, 2-hepten-1-al, Bicyclogermacrene, 2-Octenal, α-Thujene, (Z)-β-Farnesene, (–)-γ-Elemene, 2,4-Octadienal, Fucoserraten, Hexenylacetat, Geranylaceton, Valencene, β-Eudesmol, 1-Hexenol, (E)-2-Undecenal, Artemisia keton, Viridiflorol, 2,6-Nonadienal, Trimethylphenylbutenon, 2,4-Nonadienal, Butylisothiocyanat, 2-Pentanol, Elemol, 2-Hexenal, 3-Hexenal, (+)-(E)-Limonenoxid, cis-Isocitral, Dimethyloctadienal, Bornylformiat, Bornylisovalerat, Isobutyraldehyd, 2,4-Hexadienal, Trimethylphenylbutenon, Nonanon, (E)-2-Hexenal, (+)-cis-Rosenoxide, Menthone, Coumarin, (Epoxymethylbutyl)-methylfuran, 2-Hexenol, (E)-2-hexenol und/oder Carvylacetat oder
• (t) Grüner Tee-artigem Geruch, vorzugsweise (–)-Cubenol oder
• (u) kräuterartigem Geruch, vorzugsweise Octanon, Hexyloctanoat, Caryophyllenoxide, Methylbutenol, Safranal, Benzylbenzoat, Bornylbutyrat, Hexylacetat, β-Bisabolol, Piperitol, β-Selinene, α-Cubebene, p-Menth-1-en-9-ol, 1,5,9,9-Tetramethyl-12-oxabicyclododeca-4,7-dien, T-muurolol, (–)-Cubenol, Levomenol, Ocimene, α-Thujene, p-Menth-1-en-9-yl acetat, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, Hydroxypentanon, (Z)-Ocimene, β-Elemene, δ-Cadinol, (E)-β-Ocimene, (Z)-Dihydrocarvone, α-Cadinol, Calamenen, (Z)-Piperitol. Lavandulol, β-Bourbonene, (Z)-3-Hexenyl-2-methylbutanoat, 4-(1-Methylethyl)-benzenemethanol, Artemisia keton, Methyl-2-butenol, Heptanol, (E)-Dihydrocarvon, p-2-Menthen-1-ol, α-Curcumene, Spathulenol, Sesquiphellandren, Citronellylvalerat, Bornylisovalerat, 1,5-Octadien-3-ol, Methylbenzoat, 2,3,4,5-Tetrahydroanisol und/oder Hydroxycalamenen oder
• (v) honigartigem Geruch, vorzugsweise Ethylcinnamate, β-Phenethylacetat, Phenylessigsäure, Phenylethanal, Methylanthranilat, Zimtsäure, β-Damascenone, Ethyl-(E)-cinnamat, 2-Phenylethylalcohol, Citronellylvalerate, Phenylethylbenzoate und/oder Eugenol oder
• (w) Hyazinthen-artigem Geruch, vorzugsweise Hotrienol oder
• (x) jasminartigem Geruch, vorzugsweise Methyljasmonate, Methyldihydroepijasmonat und/oder Methylepijasmonat oder
• (y) lavendelartigem Geruch, vorzugsweise Linalylvalerate und/oder Linalool oder
• (z) zitronenartigem Geruch, vorzugsweise Neral, Octanal, δ-3-Carene, Limonen, Geranial, 4-mercapto-4-methyl-2-pentanol, Citral, 2,3-Dehydro-1,8-cineol und/oder α-Terpinen oder
• (aa) lilienartigem Geruch, vorzugsweise Dodecanal oder
• (bb) magnolienartigem Geruch, vorzugsweise Geranylaceton oder
• (cc) mandarinenartigem Geruch, vorzugsweise Undecanol oder
• (dd) melonenartigem Geruch, vorzugsweise Dimethylheptenal oder
• (ee) Minze-artigem Geruch, vorzugsweise Menthone, Ethylsalicylat, p-Anisaldehyd, 2,4,5,7atetrahydro-3,6-dimethyl-benzofuran, Epoxy-p-menthene, Geranial, (Methylbutenyl)-methylfuran, Dihydrocarvylacetat, β-Cyclocitral, 1,8-Cineol, β-Phellandrene, Methylpentanon, (+)-Limonen, Dihydrocarveol(–)-Carvon, (E)-p-Mentha-2,8-dien-1-ol, Isopulegylacetat, Piperiton, 2,3-Dehydro-1,8-cineol, α-Terpineol, DL-carvon und/oder α-Phellandrene oder
• (ff) nußartigem Geruch, vorzugsweise 5-methyl-(E)-2-hepten-4-on, γ-Heptalacton, 2-Acetylpyrrol, 3-Octen-2-on, Dihydromethylcyclopentapyrazin, Acetylthiazol, 2-Octenal, 2,4-Heptadienal, 3-Octenon, Hydroxypentanon, Octanol, Dimethylpyrazin, Methylquinoxalin und/oder Acetylpyrrolin oder
• (gg) orangenartigem Geruch, vorzugsweise Methyloctanoat, Undecanon, Decylalcohol, Limonen und/oder 2-Decenal oder
• (hh) Orangenschalen-artigem Geruch, vorzugsweise Decanal und/oder β-Carene oder
• (ii) pfirsichartigem Geruch, vorzugsweise γ-Nonalacton, (Z)-6-Dodecene-γ-lacton, δ-Decalacton, R-δ-Decenolacton, Hexylhexanoat, 5-Octanolid, γ-Decalacton und/oder δ-Undecalacton oder
• (jj) Pfefferminze-artigem Geruch, vorzugsweise Methylsalicylat und/oder I-Menthol oder
• (kk) Kiefer-artigem Geruch, vorzugsweise α-p-Dimethylstyrol, β-Pinene, Bornylbenzoat, δ-Terpinen, Dihydroterpinylacetat und/oder α-Pinen oder
• (ll) ananasartigem Geruch, vorzugsweise Propylbutyrat, Propylpropanoat und/oder Ethylacetat oder
• (mm) pflaumenartigem Geruch, vorzugsweise Benzylbutanoat, oder
• (nn) himbeerartigem Geruch, vorzugsweise β-Ionone oder
• (oo) Rose-artigem Geruch, vorzugsweise β-Phenethylacetat, 2-Ethylhexanol, Geranylvalerat, Geranylacetat, Citronellol, Geraniol, Geranylbutyrat, Geranylisovalerat, Citronellylbutyrat, Citronellylacetat, Isogeraniol, Tetrahydro-4-methyl-2-(2-methyl-1-propenyl)-2,5-cis-2H-pyran, Isogeraniol, 2-Phenylethylalcohol, Citronellylvalerat und/oder Citronellylisobutyrat, oder
• (pp) Grüne Minze-artigem Geruch, vorzugsweise Carvylacetate und/oder Carveol, oder
• (qq) erdbeerenartigem Geruch, vorzugsweise Hexylmethylbutyrat, Methylcinnamat, Pentenal, Methylcinnamate oder
• (rr) süßlichem Geruch, vorzugsweise Benzylalcohol, Ethylphenylacetat, Tridecanal, Nerol, Methylhexanoat, Linalylisovalerat, Undecanaldehyd, Caryophyllenoxid, Linalylacetat, Safranal, Uncineol, Phenylethanal, p-Anisaldehyd, Eudesmol, Ethylmethylpyrazin, Citronellylbutyrat, 4-Methyl-3-penten-2-on, Nonylacetat, 10-Epi-γ-eudesmol, β-Bisabolol, (Z)-6-Dodecen-γ-lacton, β-Farnesene, 2-Dodecenal, γ-Dodecalacton, Epoxy-β-ionon, 2-Undecenal, Styrenglycol, Methylfuraneol, (–)-cis-Rosenoxid, (E)-β-Ocimene, Dimethylmethoxyfuranon, 1,8-Cineole, Ethylbenzaldehyd, 2-Pentylthiophen, α-Farnesene, Methionol, 7-Methoxycoumarin, (Z)-3-Hexenyl-2-methylbutanoat, o-Aminoacetophenon, Viridiflorol, Isopiperitone, β-Sinensal, Ethylvanillat, Methylbutanoat, p-Methoxystyrol, 6-Methoxyeugenol, 4-Hexanolid, δ-Dodecalacton, Sesquiphellandren, Diethylmalat, Linalylbutyrat, Guaiacol, Coumarin, Methylbenzoat, Isopropylbenzoat, Safrole, Durene, γ-Butyrolacton, Ethylisobutyrat und/oder Furfural oder
• (ss) Vanille-artigem Geruch, vorzugsweise Vanillin, Methylvanillat, Acetovanillon und/oder Ethylvanillat oder
• (tt) wassermelonenartigem Geruch, vorzugsweise 2,4-Nonadienal oder
• (uu) holzartigem Geruch, vorzugsweise α-Muurolene, Cadina-1,4-dien-3-ol, Isocaryophyllene, Eudesmol, α-Ionon, Bornylbutyrat, (E)-α-Bergamoten, Linalooloxid, Ethylpyrazin, 10-epi-γ-Eudesmol, Germacrene B, trans-Sabinenhydrat, Dihydrolinalool, Isodihydrocarveol, β-Farnesene, β-Sesquiphellandren, δ-Elemene, α-Calacorene, Epoxy-β-ionon, Germacrene D, Bicyclogermacrene, Alloaromadendrene, α-Thujene, oxo-β-Ionon, (–)-γ-Elemene. γ-Muurolene, Sabinene, α-Guaiene, α-Copaene, γ-Cadinene, Nerolidol, β-Eudesmol, α-Cadinol, δ-Cadinene, 4,5-Dimethoxy-6-(2-propenyl)-1,3-benzodioxol, [1ar(1aalpha,4aalpha,7alpha,7abeta,7balpha)]-decahydro-1,1,7-trimethyl-4-methylene-1H-cycloprop[e]azulen, α-Gurjunen, Guaiol, α-Farnesene, γ-Selinene, 4-(1-Methylethyl)-benzenemethanol, Perillen, Elemol, α-Humulene, β-Caryophyllene und/oder β-Guaiene oder
• (vv) Mischungen aus vorgenannten.

enthalten.The agent according to the invention can according to a preferred embodiment, in particular fragrances

• (a) almond-like odor, such as preferably benzaldehyde, pentanal, heptenal, 5-methylfurfural, methylbutanal, furfural and / or acetophenone or
• (b) apple-like odor, preferably (S) - (+) - ethyl-2-methylbutanoate, diethyl malonate, ethyl butyrate, geranyl butyrate, geranyl isopentanoate, isobutyl acetate, linalyl isopentanoate, (E) -β-damascone, heptyl-2-methyl butyrate, methyl 3-methylbutanoate, 2-hexenalpentyl-methyl butyrate, ethylmethyl butyrate and / or methyl 2-methylbutanoate or
• (c) apple peel-like odor, such as preferably ethylhexanoate, hexylbutanoate and / or hexylhexanoate or
• (d) apricot-like odor, preferably γ-undecalactone, or
• (e) banana-like odor, such as preferably isobutyl acetate, isoamyl acetate, hexenyl acetate and / or pentyl butanoate or
• (f) bitter almond-like odor such as preferably 4-acetyltoluene or
• (g) blackcurrant-like odor, preferably mercaptomethylpentanone and / or metho xymethylbutanethiol or
• (c) citrus-like odor such as preferably linalyl pentanoate, heptanal, linalyl isopentanoate dodecanal, linalyl formate, α-p-dimethylstyrene, p-cymenol, nonanal, β-cubebene, (Z) -liminene oxide, cis-6-ethenyl-tetrahydro-2,2,6- trimethylpyran-3-ol, cis-pyranoidlinalooloxide, dihydrolinalool, 6 (10) -dihydromyrcenol, dihydromyrcenol, β-farnesene, (Z) -β-farnesene, (Z) -cime, (E) -liminene oxide, dihydrotypinyl acetate, (+) -Limonen, (Epoxymethylbutyl) -methylfuran and / or p-cymene or
• (i) cocoa like odor, preferably dimethylpyrazine, butylmethyl butyrate and / or methylbutanal or
• (j) coconut-like odor, such as preferably γ-octalactone, γ-nonalactone, methyl laurate, tetradecanol, methyl nonanoate, (3S, 3aS, 7aR) -3a, 4,5,7a-tetrahydro-3,6-dimethylbenzofuran-2 (3H) -on, 5-butyldihydro-4-methyl-2 (3H) -furanone, ethyl undecanoate and / or δ-decalactone or
• (k) creamy odor such as preferably diethyl acetal, 3-hydroxy-2-butanone, 2,3-pentadione and / or 4-heptenal, or
• (l) flower-like odor such as preferably benzyl alcohol, phenylacetic acid, tridecanal, p-anisyl alcohol, hexanol, (E, E) -farnesylacetone, methyl geranate, trans-crotonaldehyde, tetradecylaldehyde, methyl anthranilate, linalooloxide, epoxylinalool, phytol, 10-epi-γ-eudesmol , Nerol oxide, ethyldihydrocinnamate, γ-dodecalactone, hexadecanol, 4-mercapto-4-methyl-2-pentanol, (Z) -oximes, cetyl alcohol, nerolidol, ethyl (E) -cinnamate, elemicin, pinocarveol, α-bisabolol, ( 2R, 4R) -Tetrahydro-4-methyl-2- (2-methyl-1-propenyl) -2H-pyran, (E) -Isoelemicin, methyl 2-methylpropanoate, trimethylphenylbutenone, 2-methylanisole, β-farnesol, ( E) isoeugenol, nitro-phenylethane, ethyl vanillate, 6-methoxyeugenol, linalool, β-ionone, trimethylphenylbutenone, ethyl benzoate, phenylethyl benzoate, isoeugenol and / or acetophenones or
• (m) freshness odor, preferably methylhexanoate, undecanone, (Z) -limonoxide, benzylacetate, ethylhydroxyhexanoate, isopropylhexanoate, pentadecanal, β-elemene, α-zingiberene, (E) -liminic oxide, (E) -p-mentha-2, 8-dien-1-ol, menthone, piperone, (E) -3-hexenol and / or carveol or
• (n) fruit odor such as, preferably, ethyl phenylacetate, geranyl valerate, γ-heptalactone, ethyl propionate, diethyl acetal, geranyl butyrate, ethylheptylate, ethyloctanoate, methylhexanoate, dimethylheptenal, pentanone, ethyl-3-methylbutanoate, geranylisovalerate, iobutylacetate, ethoxypropanol, methyl-2-butenal, Methylnonanedione, linalyl acetate, methyl geranate, lmone oxide, hdrocinnamiccohol, ethylsuccinate, ethylhexanoate, ethylmethylpyrazine, nylate, ctronellylbutyrate, heylacetate, nonylacetate, butylmethylbutyrate, pentenal, isopentyldimethylpyrazine, p-menth-1-en-9-ol, hexadecanone, octylacetate, γ-dodecalactone, Epoxy β-ionone, ethyloctenoate, ethylisohexanoate, isobornyl propionate, cedrenol, p-menth-1-en-9-yl acetate, cadinadiene, (Z) -3-hexenylhexanoate, ethylcyclohexanoate, 4-methylthio-2-butanone, 3.5 Octadienone, methylcyclohexanecarboxylate, 2-pentylthiophene, α-ocimene, butanediol, ethyl valerate, pentanol, isopiperone, butyl octanoate, ethyl vanillate, methyl butanoate, 2-methylbutyl acetate, propyl hexanoate, butyl hexano at, isopropylbutanoate, spathulenol, butanol, δ-dodecalactone, methylquinoxaline, sesquiphenilene, 2-hexenol, ethyl benzoate, isopropyl benzoate, ethyl lactate and / or citronellyl isobutyrate or
• (o) Geranium-like odor, such as preferably geraniol, (E, Z) -2,4-nonadienal, octadienone and / or o-xylene or
• (p) grape-like odor such as preferably ethyl decanoate and / or hexanone or
• (q) grapefruit-like odor such as preferably (+) - 5,6-dimethyl-8-isopropenylbicyclo [4.4.0] dec-1-en-3-one and / or p-menthenethiol or
• (R) grassy odor such as preferably 2-ethylpyridine, 2,6-dimethylnaphthalene, hexanal and / or (Z) -3-hexenol or
• (s) green note, preferably 2-ethylhexanol, 6-decenal, dimethylheptenal, hexanol, heptanol, methyl-2-butenal, hexyloctanoates, nonanoic acid, undecanone, methyl geranate, isobornylformiate, butanal, octanal, nonanal, epoxy-2-decenal, cis -Linalool, pyranoxide, nonanol, alpha, γ-dimethylallylalcohol, (Z) -2-penten-1-ol, (Z) -3-hexenylbutanoate, isobutylthiazole, (E) -2-nonenal, 2-dodecenal, (Z) 4-decenal, 2-octenal, 2-hepten-1-al, bicyclo mermose, 2-octenal, α-thujene, (Z) -β-farnesene, (-) - γ-elemene, 2,4-octadienal, fucoserrate , Hexenylacetate, geranylacetone, valencene, β-eudesmol, 1-hexenol, (E) -2-undecenal, artemisia ketone, viridiflorol, 2,6-nonadienal, trimethylphenylbutenone, 2,4-nonadienal, butylisothiocyanate, 2-pentanol, elemole, 2-hexenal, 3-hexenal, (+) - (E) -liminene oxide, cis -isocitral, dimethyloctadienal, bornylformate, bornylisovalerate, isobutyraldehyde, 2,4-hexadienal, trimethylphenylbutenone, nonanone, (E) -2-hexenal, (+ ) -cis-Rose Oxides, Menthone, Coumarin, (Epoxymethylbutyl) -methylfu ran, 2-hexenol, (E) -2-hexenol and / or carvyl acetate or
• (t) Green Tea-like odor, preferably (-) - Cubenol or
• (u) herbaceous odor, preferably octanone, hexyloctanoate, caryophyllene oxides, methylbutenol, safranal, benzyl benzoate, bornyl butyrate, hexyl acetate, β-bisabolol, piperitol, β-selenene, α-cubebene, p-menth-1-en-9-ol, 1 , 5,9,9-tetramethyl-12-oxabicyclododeca-4,7-diene, T-muurolol, (-) - cubenol, levomenol, ocimene, α-thujene, p-menth-1-en-9-yl acetate, Dehydrocarveol, Artemisia alcohol, γ-Muurolene, hydroxypentanone, (Z) -oximes, β-elemene, δ-cadinol, (E) -β-Ocimene, (Z) -dihydrocarvone, α-cadinol, Cala (Z) -piperitol. Lavandulol, β-bourbonene, (Z) -3-hexenyl-2-methylbutanoate, 4- (1-methylethyl) benzene-ethanol, artemisia ketone, methyl-2-butenol, heptanol, (E) -dihydrocarvone, p-2-menthene 1-ol, α-curcumene, spathulenol, sesquipellandrene, citronellyl valerate, bornyl isovalerate, 1,5-octadien-3-ol, methyl benzoate, 2,3,4,5-tetrahydroanisole and / or hydroxycalmenes or
• (v) honey-like odor, preferably ethyl cinnamate, β-phenethyl acetate, phenylacetic acid, phenylethanal, methyl anthranilate, cinnamic acid, β-damascenone, ethyl (E) -cinnamate, 2-phenylethylalcohol, citronellyl valerate, phenylethyl benzoate and / or eugenol or
• (w) Hyacinth-like odor, preferably Hotrienol or
• (x) jasmine-like odor, preferably methyl jasmonate, methyldihydroepijasmonate and / or methylepijasmonate or
• (y) lavender-like odor, preferably linalyl valerate and / or linalool or
• (z) lemon-like odor, preferably, neral, octanal, δ-3-carene, limonene, geranial, 4-mercapto-4-methyl-2-pentanol, citral, 2,3-dehydro-1,8-cineol and / or α -Terpines or
• (aa) lily-like odor, preferably dodecanal or
• (bb) magnolia-like odor, preferably geranylacetone or
• (cc) mandarin-like odor, preferably undecanol or
• (dd) melon-like odor, preferably dimethylheptenal or
• (ee) Minty odor, preferably menthone, ethyl salicylate, p-anisaldehyde, 2,4,5,7-tetrahydro-3,6-dimethylbenzofuran, epoxy-p-menthene, geranial, (methylbutenyl) -methylfuran, dihydrocarvylacetate, β -Cyclocitral, 1,8-cineole, β-phellandrene, methylpentanone, (+) - limonene, dihydrocarveol (-) - carvone, (E) -p-mentha-2,8-dien-1-ol, isopulegyl acetate, piperitone, 2,3-dehydro-1,8-cineole, α-terpineol, DL-carvone and / or α-phellandrene or
• (ff) Nutty odor, preferably 5-methyl- (E) -2-hepten-4-one, γ-heptalactone, 2-acetylpyrrole, 3-octen-2-one, dihydromethylcyclopentapyrazine, acetylthiazole, 2-octenal, 2,4 Heptadienal, 3-octenone, hydroxypentanone, octanol, dimethylpyrazine, methylquinoxaline and / or acetylpyrroline or
• (gg) orange-like odor, preferably methyloctanoate, undecanone, decyl alcohol, limonene and / or 2-decenal or
• (hh) orange peel-like odor, preferably decanal and / or beta-carene or
• (ii) peach-like odor, preferably γ-nonalactone, (Z) -6-dodecene-γ-lactone, δ-decalactone, R-δ-decenolactone, hexylhexanoate, 5-octanolide, γ-decalactone and / or δ-undecalactone or
• (jj) peppermint-like odor, preferably methyl salicylate and / or I-menthol or
• (kk) pine-like odor, preferably α-p-dimethylstyrene, β-pinene, bornyl benzoate, δ-terpinene, dihydroterpinyl acetate and / or α-pinene or
• (II) pineapple-like odor, preferably propyl butyrate, propyl propanoate and / or ethyl acetate or
• (mm) plum-like odor, preferably benzyl butanoate, or
• (nn) raspberry-like odor, preferably β-ionone or
• (oo) Rose-like odor, preferably β-phenethyl acetate, 2-ethylhexanol, geranyl valerate, geranyl acetate, citronellol, geraniol, geranyl butyrate, geranyl isovalerate, citronellyl butyrate, citronellyl acetate, isogeraniol, tetrahydro-4-methyl-2- (2-methyl-1) propenyl) -2,5-cis-2H-pyran, isogeraniol, 2-phenylethyl alcohol, citronellyl valerate and / or citronellyl isobutyrate, or
• (pp) spearmint-like odor, preferably carvylacetate and / or carveol, or
• (qq) strawberry-like odor, preferably hexylmethyl butyrate, methyl cinnamate, pentenal, methyl cinnamate or
• (rr) sweet odor, preferably benzyl alcohol, ethyl phenylacetate, tridecanal, nerol, methylhexanoate, linalyl isovalerate, undecanedehyde, caryophyllene oxide, linalyl acetate, safranal, uncinol, phenylethanal, p-anisaldehyde, eudesmol, ethylmethylpyrazine, citronellylbutyrate, 4-methyl-3-pentene-2 -on, nonyl acetate, 10-epi-γ-eudesmol, β-bisabolol, (Z) -6-dodecene-γ-lactone, β-farnesene, 2-dodecenal, γ-dodecalactone, epoxy-β-ionone, 2-undecenal , Styrene glycol, methyl furanol, (-) - cis-rose oxide, (E) -β-octenes, dimethylmethoxyfuranone, 1,8-cineols, ethylbenzaldehyde, 2-pentylthiophene, α-farnesene, methionol, 7-methoxycoumarin, (Z) -3 -Hexenyl 2-methylbutanoate, o-aminoacetophenone, viridiflorol, isopiperitones, β-sinensal, ethyl vanillate, methyl butanoate, p-methoxystyrene, 6-methoxyeugenol, 4-hexanolide, δ-dodecalactone, sesquiphenoids, diethyl malate, linalyl butyrate, guaiacol, coumarin, methyl benzoate , Isopropyl benzoate, safroles, durene, γ-butyrolactone, ethyl isobutyrate and / or furfural or
• (ss) vanilla-like odor, preferably vanillin, methyl vanillate, acetovanillon and / or ethyl vanillate or
• (tt) watermelon-like odor, preferably 2,4-nonadienal or
• (uu) woody odor, preferably α-muurolene, cadina-1,4-dien-3-ol, isocaryophyllene, eudesmol, α-ionone, bornyl butyrate, (E) -α-bergamotene, linalooloxide, ethylpyrazine, 10-epi-γ Eudesmol, germacrene B, trans-sabin hydrate, dihydrolinalool, isodihydrocarveol, β-farnesenes, β-sesquiphellandrene, δ-elemene, α-calacorene, epoxy-β-ionone, germacrene D, bicyclo mermose, alloaromadendrene, α-thujene, oxo-β Ionone, (-) - γ-elemene. γ-muurolens, Sabinene, α-guaienes, α-copenes, γ-cadinene, nerolidol, β-Eu desmol, α-cadinol, δ-cadenines, 4,5-dimethoxy-6- (2-propenyl) -1,3-benzodioxole, [1ar (1aalpha, 4aalpha, 7alpha, 7abeta, 7balpha)] - decahydro-1,1 , 7-trimethyl-4-methylene-1H-cycloprop [e] azulen, α-gurjunen, guaiol, α-farnesene, γ-selenene, 4- (1-methylethyl) -benzenemethanol, Perillen, Elemol, α-Humulenes, β -Caryophyllene and / or β-guaiene or
• (vv) mixtures of the above.

contain.

In a preferred embodiment contains the inventive means to certain minimum values Perfume oil, namely at least 0.00001% by weight, advantageously at least 0.0001 wt .-%, in considerably more advantageous Way at least 0.001 wt .-%, more preferably at least 0.01% by weight, more preferably at least 0.1% by weight, in still further advantageous manner, at least 0.2% by weight, in very advantageously at least 0.3 wt .-%, in particularly advantageous Way at least 0.4 wt .-%, in a particularly advantageous manner at least 0.45 wt .-%, in a significantly advantageous manner at least 0.5 wt .-%, in a very advantageous manner, at least 0.55 Gew .-%, in an extremely advantageous manner at least 0.6 wt .-%, most advantageously at least 0.65 Wt .-%, most advantageously at least 0.7 wt .-%, in exceptionally advantageous manner at least 0.75 wt .-%, in exceptional advantageously at least 0.8 wt .-%, in extraordinary advantageously at least 0.85 wt .-%, in particular at least 0.9 wt .-% of perfume oil, based on the total Washing or cleaning agents.

In In a preferred embodiment, the perfume oils contain less than 8, advantageously less than 7, in more advantageous Way less than 6, in turn, less than 5, more advantageously less than 4, even more advantageous less than 3, preferably less than 2, in particular no perfumes from the list amylcinnamal, amylcinnamyl alcohol, benzyl alcohol, Benzyl salicylate, cinnamyl alcohol, cinnamal, citral, coumarin, eugenol, Geraniol, hydroxycitronellal, hydroxymethylpentylcyclohexenecarboxaldehyde, Isoeugenol, anisyl alcohol, benzyl benzoate, benzyl cinnamate, citronellol, Farnesol, hexylcinnamaldehyde, lilial, d-limonene, linalool, methylheptin carbonate, 3-methyl-4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -3-buten-2-one, oak moss extract, Tree moss extract.

To In another preferred embodiment, the inventive Be free of perfume oil.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited non-patent literature

• - DIN ISO 9277: 2003-05 [0043]
• - DIN 66132: 1975-07 [0043]
• CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997) [0072]

Claims (38)

Particles containing a) photocatalytic Material, b) carrier material, c) organic solvent Particle according to Claim 1, characterized that the organic solvent is at least one nonionic surfactant comprises, preferably from the group of alkoxylated fatty alcohols, the alkylphenol polyglycol ether, the alkoxylated fatty acid alkyl ester, the polyhydroxy fatty acid amides, the alkyl glycosides, the Alkyl polyglucosides, the amine oxides of fatty acid glucamides and / or the long-chain alkyl sulfoxides. Particles according to one of the preceding claims 1 or 2, characterized in that the organic solvent contains alkoxylated fatty alcohol, preferably in amounts of at least 40% by weight, advantageously of at least 50% by weight, in a further advantageous manner of at least 60 wt .-%, in excess advantageously at least 70 wt .-%, in even more advantageous Way of at least 80 wt .-%, in particular of at least 90 wt .-%, in the most advantageous manner in amounts of 100 wt .-%, wt .-% each based on the total amount of the organic solvent, which are advantageously ethoxylated, especially primary Alcohols are preferably 8 to 18, especially 12 to 18 carbon atoms and preferably on average 1 to 12 moles of alkylene oxide, preferably ethylene oxide, per mole of alcohol, in particular 7 moles of ethylene oxide per mole of alcohol. Particles according to one of the preceding claims 1-3, characterized in that the organic Solvent comprises at least one humectant, preferably glycerol, dimers and trimers of glycerine, ethylene glycol, Propylene glycol, sugar alcohols, preferably glucitol, xylitol, Mannitol, alkylpolyglucosides, fatty acid glucamides, sucrose esters, Sorbitans, polysorbates, polydextrose, polyethylene glycol, preferably with average molecular weights from 200 to 8000, propanediols, Butanediols, triethylene glycol, hydrogenated glucose syrup and / or mixtures from the abovementioned, preferably in quantities of from 0.01 to 50% by weight, advantageously 0.1 to 40 wt .-%, in a further advantageous manner 1-30 wt .-%, more preferably 2-20 wt .-%, in particular 5-15 wt .-%, wt .-% each based on the total organic Solvents. Particles according to one of the preceding claims 1-4, characterized in that alkylpolyglucoside in an amount of 0.1-40 wt .-%, based on the entire organic solvent. Particles according to one of the preceding claims 1-5, characterized in that as a carrier material inorganic material, preferably zeolite, sulfate, carbonate, Silicate, clay, silica and / or mixtures thereof is. Particles according to one of the preceding claims 1-6, characterized in that the carrier material at least 40% by weight, preferably at least 50% by weight, advantageously at least 60 wt .-%, in a further advantageous manner at least to 70 wt .-%, more preferably at least 80 wt .-%, in still more preferably at least 90 wt .-%, in particular completely is zeolite, preferably zeolite X, Y, A, P, MAP and / or Mixtures of these, wt .-% based on the carrier material. Particles according to one of the preceding claims 1-7, characterized in that the carrier material spray-dried Comprising powder, preferably containing (a) inorganic Support material, preferably comprising zeolite, sulfate, Carbonate, silicate, clay, silicic acid and / or mixtures thereof, preferably in amounts> 30 Wt .-%, advantageously> 40 Wt .-%, more preferably> 50 wt .-%, more preferably> 60 wt .-%, in particular 70-90% by weight, (b) nonionic surfactant, especially ethoxylated Fatty alcohol, advantageously in amounts of 0.1-40% by weight, in particular 0.5-5% by weight (c) optionally graying inhibitor, preferably carboxymethylcellulose sodium salt, preferably in Amounts of 0-10% by weight, in particular 1-5% by weight, (D) optionally water, preferably in amounts of 0.05-30% by weight, advantageously 5-25% by weight, in particular 10-20 Wt .-%, (e) optionally alkalis, preferably the hydroxides of Alkali metals, in particular sodium hydroxide and / or potassium hydroxide, Wt .-% in each case based on the carrier material, Particles according to one of the preceding claims 1-8, characterized in that as photocatalytic Material titanium dioxide is used, in particular a modified titanium dioxide, preferably a carbon-modified titanium dioxide. Particles according to the preceding claim 9, characterized that the preferably modified titanium dioxide in amounts of 0.0001 to 30 wt .-%, preferably 0.01 to 15 wt .-%, based on the entire particle. Particles according to one of the preceding claims 9 or 10, characterized in that the carbon content of the carbon modified titanium dioxide ranging from 0.01 to 10 wt .-%, preferably from 0.05 to 5.0 wt .-%, advantageously from 0.3 to 1.5% by weight, in particular from 0.4 to 0.8% by weight. Particles according to one of the preceding claims 9-11, characterized in that the specific surface area of the modified titanium dioxide by BET is preferably 50 to 500 m ² / g, advantageously 100 to 400 m ² / g, in particular 200 to 350 m ² / g. Particles according to one of the preceding claims 9-12, characterized in that the particle size of the modified titanium dioxide in the range of 2-500 nm, preferably in the range of 200-400 nm Particles according to one of the preceding claims 1-13, comprising a) photocatalytic material in Amounts of 0.01-40 wt .-%, preferably 0.1-30 Wt .-%, advantageously 1-20 wt .-%, even more advantageous 5-15% by weight, especially 8-12% by weight b) Support material, preferably comprising spray-dried Powder, in particular comprising zeolite, in quantities of 30-90 Wt .-%, preferably 40-80 wt .-%, advantageously 50-70 % By weight, in particular 55-65% by weight c) organic solvent, preferably nonionic surfactant and / or humectant, in quantities of 5-60% by weight, preferably 10-50% by weight, advantageously 20-40 wt .-%, in particular 25-35 wt .-%. Particles according to one of the preceding claims 1-14, characterized in that a lubricant, preferably oils, cationic surfactants, in particular esterquats, Phyllosilicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone based cationic surfactants or polymers based on polyethylene, is contained, preferably in one Amount of 0.05 to 10% by weight, preferably 0.1 to 5% by weight Wt .-% based on the total particle. Particles according to one of the preceding claims 1-15, characterized in that the particles powdered and / or surrounded by a coating, these being preferably thermoplastics, such as PEG, PVA, polyacrylates, PVP, carbohydrates, Polyester such as preferably comprises PET. Particles according to one of the preceding claims 1-16, characterized in that the used carrier material an average particle size between 0.1 and 2.0 mm, preferably 0.15 and 1.5 mm, in particular 0.2 and 1.2 mm. Granules, characterized that they aggregates of several particles according to any one of claims 1-17 include. Detergents or cleaners containing particles according to any one of claims 1-16 and / or granules according to claim 18. Detergents or cleaners according to Claim 19, characterized in that they comprise, in addition to the particles according to any one of Claims 1-17 and / or granules according to Claim 18, the following components (both individual ones of these components and all these components): (a) anionic surfactants , preferably alkylbenzenesulfonates, alkanesulfonates, methyl ester sulfonates, α-olefinsulfonates, alkyl sulfates and / or alkyl ether sulfates, advantageously in amounts of 0-40 wt .-%, preferably in amounts of 1-25 wt .-%, in particular in amounts of 5-15 wt % (b) Nonionic surfactants, preferably alkoxylated fatty alcohols, alkylphenol polyglycol ethers, alkoxylated fatty acid alkyl esters, polyhydroxy fatty acid amides, alkyl glycosides, alkyl polyglucosides, sucrose esters, sorbitan esters, amine oxides, fatty acid glucamides and / or the long-chain alkyl sulfoxides, advantageously in amounts of 0-20% by weight, preferably 0.1-15 wt .-%, in particular 1-10 wt .-%, (c) builders, preferably preferably zeolite, alkaline amorphous disilicates, crystalline layered silicates, polycarboxylate and / or sodium citrate, advantageously in amounts of 0-70% by weight, preferably 5-60% by weight, in particular 10-50% by weight, (D) alkalis, preferably NaOH, KOH and / or sodium carbonate, advantageously in amounts of 0-30 wt .-%, preferably 1-25 wt .-%, in particular 5-15 wt .-% (e) bleaching agent, preferably sodium perborate and / or sodium percarbonate, preferably in amounts of 0-25% by weight, in particular 5-20% by weight, (f) corrosion inhibitors, preferably sodium silicate, advantageously in amounts of 0-10% by weight, preferably 0, 5-6 wt .-%, in particular 1-5 wt .-%, (g) stabilizers, preferably phosphonates, advantageously 0-5 wt .-%, in particular 0.01-1 wt .-%, (h) foam inhibitor, preferably soap , Silicone oils and / or paraffins, advantageously in amounts of 0-8 wt .-%, preferably 0.1-5 wt .-%, in particular 1-4 wt .-%, (i) enzymes, preferably proteases, amylases, mannanases , Tannases, cellulases and / or lipases, advantageously in amounts of 0-5 wt .-%, preferably 0.1-5 wt .-%, in particular 0.5-2 wt .-%, (j) grayness inhibitor, preferably C Arboxymethyl-cellulose, advantageously in amounts of 0-2 wt .-%, in particular 0.01-1 wt .-%, (k) discoloration inhibitor, preferably polyvinylpyrrolidone derivatives, advantageously in amounts of 0-2 wt .-%, preferably 0.01-1.2 wt .-%, in particular 0.05-0.5 wt .-%, (l) adjusting agent, preferably sodium sulfate, advantageously in amounts of 0-50 wt .-%, preferably 5-40 wt %, in particular 10-30% by weight, (m) fragrances, preferably in amounts of 0-10% by weight, in particular 0.01-5% by weight, (n) optical brighteners, preferably stilbene Derivatives and / or biphenyl derivatives, advantageously in amounts of 0-3 wt .-%, preferably 0.01-1 wt .-%, in particular 0.005-0.5 wt .-%, (o) Aviviermittel, preferably oils, Cationic surfactants, such as in particular esterquats, layered silicates, fatty acid derivatives, silicone oils, polymers, such as preferably silicone-based cationic surfactants or polyethylene-based polymers, preferably in an amount of 0 to 15 wt .-%, advantageously 0.1-10 wt .-%, in particular 0.5-5 wt .-%, (p) skin care active ingredients, preferably those as described above, preferably in an amount of 0 to 15 wt .-%, advantageously 0.1-10 wt .-%, in particular 0.5-5 wt .-%, (q) water, preferably in amounts of 0-30 wt .-%, preferably 0.1 to 20 wt .-%, in particular 1-15 wt .-% (r) optionally Salzersatzpolmere wt .-% in each case based on the total washing or cleaning agent. Washing or cleaning agent according to claim 19 or 20, characterized in that it in portioned form is present, preferably in a pouch or as a tablet. Process for producing a particle after a of claims 1-17, wherein in a first step a suspension of photocatalytic material and an organic Solvent is formed, and the resulting suspension in a second step mixed with a solid carrier becomes. A method according to claim 22, wherein the obtained Particles in a further step by granulation in a mixer converted into granules using a binder become. Process for the preparation of a powdered Washing or cleaning agent according to one of the claims 19 or 20, characterized in that in a first Step particles according to a method according to claim 22 or 23, and these in a further step with a powdered detergent or cleaning agent matrix be mixed. Method of applying fine particulate photocatalytic material on textiles by treating this Textiles in a textile treatment bath, to which particles are added according to any one of claims 1-17, granules according to claim 18 and / or a washing or cleaning agent according to Claim 19-21 are. Process for cleaning, care, equipment, Conditioning and / or conditioning of textiles by treatment of these textiles in a textile treatment bath, to which one uses particles according to any one of claims 1-17, granules according to claim 18 and / or a washing or cleaning agent according to Claim 19-21, at and / or followed by exposure Textiles to light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 or 26 for elimination, deactivation or reduction of Microorganisms, in particular bacteria and germs, in textiles using light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 to 27 for the prophylaxis of textiles in the form of an anticipatory Defense and inhibition of stains and stains under use of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 to 28 for finishing textiles with photocatalytic Material to facilitate the removal of colored dirt (colored spots) of textiles using light in the wavelength range from 10-1200 nm. Method according to one of the preceding claims 25 to 29 for finishing textiles with photocatalytic Material for reducing the fiber adhesion of Dirt, preferably colored spots, on textiles under use of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 to 30 for the equipment of textiles with photocatalytic Material for increasing the water solubility of Dirt, preferably colored spots, on textiles, using of light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 to 31 for the equipment of textiles with photocatalytic Material for preventing the development of fetid odors on textiles, using light in the wavelength range from 10-1200 nm. Method according to one of the preceding claims 25 to 32 for the equipment of textiles with photocatalytic Material for furnishing the textiles with a self-cleaning capacity, using light in the wavelength range of 10-1200 nm. Method according to one of the preceding claims 25 to 33 to remove or reduce soiling and stains on textiles that go back to: - Red to blue anthocyanin dyes, such as. B. cyanidin, z. B. from cherries or blueberries, - red betanidine from the red beds, - orange-red carotenoids such. Lycopene, beta-carotene, e.g. From tomatoes or carrots, - yellow Curcuma dyes, such as. B. curcumin, z. From curry and mustard, - brown Tannins, e.g. B. from tea, fruit, red wine - deep brown Humic acid, e.g. B. from coffee, tea, cocoa, - green Chlorophyll, z. B, from green grasses, - technical Dyes made from cosmetics, inks, colored pencils - colored Metabolites and / or excretions of mold fungi or other micro flora or microbial growth or microbes, under Use of light in the wavelength range of 10-1200 nm. Method according to one of the claims 25 to 34 using an automatic washing machine, preferably an automatic washing machine with light source. Method according to one of the claims 25 to 33, characterized in that it is a manual Process is carried out in an open tub is, in particular hand wash, pre-wash and / or Soaking, taking the tub after the textiles to be treated are penetrated with the wash liquor, light in wavelength ranges from 10-1200 nm, especially sunlight, preferably for a period> 5 Minutes. Method for cleaning hard surfaces, especially dishes, by treating these hard surfaces with a cleaning liquid containing particles after one of claims 1-21, at and / or followed from an exposure of the hard surface to light in the Wavelength range of 10-1200 nm. The method of claim 37 using a automatic dishwashing machine, preferably one automatic dishwashing machine with light source.