EP1917073A1 - Composition depilatoire - Google Patents
Composition depilatoireInfo
- Publication number
- EP1917073A1 EP1917073A1 EP06762166A EP06762166A EP1917073A1 EP 1917073 A1 EP1917073 A1 EP 1917073A1 EP 06762166 A EP06762166 A EP 06762166A EP 06762166 A EP06762166 A EP 06762166A EP 1917073 A1 EP1917073 A1 EP 1917073A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cosmetic composition
- composition according
- hair
- fat
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 82
- 230000035617 depilation Effects 0.000 title abstract description 48
- -1 mercapto compounds Chemical class 0.000 claims abstract description 81
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000002537 cosmetic Substances 0.000 claims abstract description 39
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 15
- 150000003751 zinc Chemical class 0.000 claims abstract description 6
- 150000001875 compounds Chemical class 0.000 claims description 40
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 34
- 150000003839 salts Chemical class 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 14
- 150000003141 primary amines Chemical class 0.000 claims description 14
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 14
- PBFKVYVGYHNCGT-UHFFFAOYSA-N 1-sulfanylpropane-1,2,3-triol Chemical compound OCC(O)C(O)S PBFKVYVGYHNCGT-UHFFFAOYSA-N 0.000 claims description 13
- 150000003335 secondary amines Chemical class 0.000 claims description 12
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- NHGXDBSUJJNIRV-UHFFFAOYSA-M tetrabutylammonium chloride Chemical compound [Cl-].CCCC[N+](CCCC)(CCCC)CCCC NHGXDBSUJJNIRV-UHFFFAOYSA-M 0.000 claims description 9
- 239000002562 thickening agent Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 8
- 229920001983 poloxamer Polymers 0.000 claims description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- ROWKJAVDOGWPAT-UHFFFAOYSA-N Acetoin Chemical compound CC(O)C(C)=O ROWKJAVDOGWPAT-UHFFFAOYSA-N 0.000 claims description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 229920002266 Pluriol® Polymers 0.000 claims description 5
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 229960000541 cetyl alcohol Drugs 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- VHJLVAABSRFDPM-QWWZWVQMSA-N dithiothreitol Chemical compound SC[C@@H](O)[C@H](O)CS VHJLVAABSRFDPM-QWWZWVQMSA-N 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 239000011135 tin Substances 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- 229930194542 Keto Natural products 0.000 claims description 3
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 239000007853 buffer solution Substances 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- GFAZHVHNLUBROE-UHFFFAOYSA-N hydroxymethyl propionaldehyde Natural products CCC(=O)CO GFAZHVHNLUBROE-UHFFFAOYSA-N 0.000 claims description 3
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 3
- 239000011736 potassium bicarbonate Substances 0.000 claims description 3
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 235000011181 potassium carbonates Nutrition 0.000 claims description 3
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 235000000346 sugar Nutrition 0.000 claims description 3
- 150000003626 triacylglycerols Chemical class 0.000 claims description 3
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 claims description 2
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- YEYKMVJDLWJFOA-UHFFFAOYSA-N 2-propoxyethanol Chemical compound CCCOCCO YEYKMVJDLWJFOA-UHFFFAOYSA-N 0.000 claims description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 2
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 239000001913 cellulose Substances 0.000 claims description 2
- 229920002678 cellulose Polymers 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical group CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 claims description 2
- 229940043264 dodecyl sulfate Drugs 0.000 claims description 2
- 230000032050 esterification Effects 0.000 claims description 2
- 238000005886 esterification reaction Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 2
- 150000002193 fatty amides Chemical class 0.000 claims description 2
- 235000013773 glyceryl triacetate Nutrition 0.000 claims description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 claims description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003961 organosilicon compounds Chemical class 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000151 polyglycol Polymers 0.000 claims description 2
- 239000010695 polyglycol Substances 0.000 claims description 2
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 235000011067 sorbitan monolaureate Nutrition 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 229960002622 triacetin Drugs 0.000 claims description 2
- OQILCOQZDHPEAZ-UHFFFAOYSA-N octyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OCCCCCCCC OQILCOQZDHPEAZ-UHFFFAOYSA-N 0.000 claims 2
- MYDHMMOUDFESFR-UHFFFAOYSA-N 2,3,4,6,7,8-hexahydropyrrolo[1,2-a]pyrazine Chemical compound C1CNC=C2CCCN21 MYDHMMOUDFESFR-UHFFFAOYSA-N 0.000 claims 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 claims 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims 1
- 229940074979 cetyl palmitate Drugs 0.000 claims 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 1
- 150000002083 enediols Chemical class 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- 229940100556 laureth-23 Drugs 0.000 claims 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 38
- 238000003797 solvolysis reaction Methods 0.000 abstract description 28
- 238000006075 micellar catalysis Methods 0.000 abstract description 11
- 238000003408 phase transfer catalysis Methods 0.000 abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 abstract description 7
- 239000011593 sulfur Substances 0.000 abstract description 7
- 239000003054 catalyst Substances 0.000 abstract description 6
- 230000009467 reduction Effects 0.000 abstract description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000003925 fat Substances 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- 239000012071 phase Substances 0.000 description 21
- 238000009472 formulation Methods 0.000 description 19
- 239000000693 micelle Substances 0.000 description 18
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 14
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 229960003067 cystine Drugs 0.000 description 12
- 239000010410 layer Substances 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 238000003776 cleavage reaction Methods 0.000 description 10
- 239000006071 cream Substances 0.000 description 10
- 238000005238 degreasing Methods 0.000 description 10
- 230000002951 depilatory effect Effects 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 230000007017 scission Effects 0.000 description 10
- 239000000839 emulsion Substances 0.000 description 9
- 230000006870 function Effects 0.000 description 9
- 235000018102 proteins Nutrition 0.000 description 9
- 108090000623 proteins and genes Proteins 0.000 description 9
- 102000004169 proteins and genes Human genes 0.000 description 9
- 239000008346 aqueous phase Substances 0.000 description 8
- 239000012973 diazabicyclooctane Substances 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 210000003491 skin Anatomy 0.000 description 7
- LEVWYRKDKASIDU-QWWZWVQMSA-N D-cystine Chemical compound OC(=O)[C@H](N)CSSC[C@@H](N)C(O)=O LEVWYRKDKASIDU-QWWZWVQMSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 6
- 206010040880 Skin irritation Diseases 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 239000003444 phase transfer catalyst Substances 0.000 description 6
- 230000002829 reductive effect Effects 0.000 description 6
- 230000036556 skin irritation Effects 0.000 description 6
- 231100000475 skin irritation Toxicity 0.000 description 6
- 239000000499 gel Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000000376 reactant Substances 0.000 description 5
- 239000002594 sorbent Substances 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 4
- 244000166124 Eucalyptus globulus Species 0.000 description 4
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000000872 buffer Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000002270 dispersing agent Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 125000005842 heteroatom Chemical group 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000036961 partial effect Effects 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- WAROVFJVCBYVHY-UHFFFAOYSA-N 1-ethenylpyrrolidin-2-one;trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C=CN1CCCC1=O.CC(=C)C(=O)NCCC[N+](C)(C)C WAROVFJVCBYVHY-UHFFFAOYSA-N 0.000 description 3
- XYYUAOIALFMRGY-UHFFFAOYSA-N 3-[2-carboxyethyl(dodecyl)amino]propanoic acid Chemical compound CCCCCCCCCCCCN(CCC(O)=O)CCC(O)=O XYYUAOIALFMRGY-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- SJRJJKPEHAURKC-UHFFFAOYSA-N N-Methylmorpholine Chemical compound CN1CCOCC1 SJRJJKPEHAURKC-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- 206010044625 Trichorrhexis Diseases 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 235000013877 carbamide Nutrition 0.000 description 3
- 238000006555 catalytic reaction Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000013467 fragmentation Methods 0.000 description 3
- 238000006062 fragmentation reaction Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- HYTYHTSMCRDHIM-UHFFFAOYSA-M potassium;2-sulfanylacetate Chemical compound [K+].[O-]C(=O)CS HYTYHTSMCRDHIM-UHFFFAOYSA-M 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 2
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 description 2
- BKMMTJMQCTUHRP-VKHMYHEASA-N (S)-2-aminopropan-1-ol Chemical compound C[C@H](N)CO BKMMTJMQCTUHRP-VKHMYHEASA-N 0.000 description 2
- DEPDDPLQZYCHOH-UHFFFAOYSA-N 1h-imidazol-2-amine Chemical compound NC1=NC=CN1 DEPDDPLQZYCHOH-UHFFFAOYSA-N 0.000 description 2
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
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- 108091005896 globular proteins Proteins 0.000 description 1
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- 125000001072 heteroaryl group Chemical group 0.000 description 1
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- 229930195733 hydrocarbon Natural products 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- MRAPAFWHXSJNRN-UHFFFAOYSA-M icosyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](C)(C)C MRAPAFWHXSJNRN-UHFFFAOYSA-M 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
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- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
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- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
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- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
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- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
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- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
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- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- ZMAVJPVLHCSMEV-UHFFFAOYSA-M trimethyl(tetracosyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C ZMAVJPVLHCSMEV-UHFFFAOYSA-M 0.000 description 1
- CEYYIKYYFSTQRU-UHFFFAOYSA-M trimethyl(tetradecyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCC[N+](C)(C)C CEYYIKYYFSTQRU-UHFFFAOYSA-M 0.000 description 1
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Definitions
- the objectives of such Depil istssysteme are, following the cosmetic fashion trend, in the rapid, gentle and painless hair removal, without causing skin irritation and odor nuisance. It is very important that the hair protein fragments as quickly as possible while the skin protein, especially the stratum corneum, is not attacked. This is possible due to the different structure of the hair and skin protein.
- the hair protein consists of ⁇ -keratin and collagen, whereby the ⁇ -helices are cross-linked via disulfide bridges.
- An object of the invention is to provide a fast acting, gentle and low odor composition for the painless removal of hair without causing skin irritation. Another object of the invention is to provide a composition with which the depilation time can be reduced. Another object is to provide an application system for the above depilation formulation which can simultaneously perform a peeling function that removes the hair. When designing the application system, the risk of undesired contamination, e.g. the hands are minimized by the Dephi ceremoniessmasse and environmentally sound disposal of the used Depil michmaschinessystemes be possible.
- the object is achieved by a hair removal cosmetic composition containing at least one fat dissolving compound having a Godfrey M number of 1 to 18, at least one mercapto compound, and at least one amine compound.
- the second step comprises the preferably catalyzed solvolysis process of the hair, which can be subdivided into hydrogen bonds and disulfide bridges (cystine) splitting and subordinate into peptide-cleaving reactions.
- the corresponding ingredients are summarized in the "solvolysis system" of the depilation formulation.
- the third, optional step involves the removal of the depilation mass with the hair fragments from the skin through a peeling process.
- Typical representatives are alcohols having 1, 2, 3, 4, or 5 carbon atoms, in particular monoalcohols and dialcohols, such as, for example, methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, sec-butanol, tert-butanol, n Pentanol, iso-pentanol, neo-pentanol, tert-pentanol, ethylene glycol, and propylene glycol, as well as low molecular weight, water-soluble ethylene oxide homopolymers (for example Pluriol E with a molecular weight of 102 to 2,000 from BASF) and propylene oxide homo Polymers (for example Pluriol P having a molecular weight of 134 to 600 from BASF) and derivatives thereof, low molecular weight, random and water-soluble ethylene oxide and propylene oxide copolymers and derivatives thereof, low molecular weight, water-soluble
- the molecular weights of the fat solvents are preferably in the range of 80 to 5,000, for example in the range of 100 to 700 or of 100 to 2,000 or of 1,000 to 4,000 or of 2,000 to 4,000.
- fat-sorbing - components can - in addition to mineral oils - for example
- organosilicon compounds such as phenyldimethicones, cetyldimethicones or cyclomethicones are also very well suited.
- organosilicon compounds such as phenyldimethicones, cetyldimethicones or cyclomethicones are also very well suited.
- Preferably used products are cetyl and cetearyl alcohol. Both a fat sorbent alone and a combination of two, three or more of them can be used.
- the sodium and potassium salts of thioglycolic acid are primarily water-soluble but not soluble in the preferred solvents of this invention
- the aluminum and zinc complexes of thioglycollic acid preferably used in this invention are characterized by a marked solubility in the solvents, eg in the alcohols, which can also be used as fat solvents (see point 1.1.).
- the thioglycolic acid complexes of aluminum and zinc differ from the sodium, potassium and calcium salts in that the latter are almost completely dissociated, i. exist as ions and therefore in the 1.1. listed grease solvents are poorly or not at all soluble.
- the aluminum or zinc compounds of thioglycolic acid are only partially present as ions, but are partially undissociated complexes which have a solubility in the preferred fat solvents for the purposes of this invention (item 1.1.), For example, ethanol.
- additional alkali salts of thioglycolic acid can be used.
- mercaptoethanol and mercaptoglycerol come into consideration, wherein the concentrations used also in the range of 0.2 M to 0.8 M, preferably from 0.2 M to 0.4 M, particularly preferably about 0.3 M, based on the total cosmetic
- the radical R 1 may be a cyclic group, for example a cyclopentyl, cyclohexyl, cycloheptyl or cyclooctyl group.
- Amino and optionally hydroxyl groups may be substituted on this group. Examples of these are: cyclopentylamine, cyclohexylamine, cycloheptylamine, cyclooctylamine, and also 2-amino-cyclohexan-1-ol, 3-amino-cyclohexan-1-ol, 4-amino-cyclohexan-1-ol, 1,4 -Diaminocyclo- hexane.
- Examples include Hydroxyethyl, 2-hydroxyprop-1-yl, 3-hydroxyprop-1-yl, 2,3-dihydroxyprop-1-yl
- the preferred amine compounds are therefore: diethanolamine (HN- (CH 2 CH 2 -OH) 2 ), diisopropanolamine (HN- (CH 2 CH (CH 3 ) -OH) 2 ), dipropanolamine (HN- (CH 2 CH 2 CH 2 -OH) 2 ), piperazine (HN (CH 2 CH 2 ) 2 NH), piperidine cyclobutane (CH 2 ) 5 NH, as well as tricine ((HIGH 2 ) 3 C-NH-CH 2 COOH).
- cyclic compounds may be both hetero-aliphatic and heteroaromatic in nature. Examples include pyrrolidine, piperidine, morpholine, and pyrazole.
- Such tetra-substituted ammonium compounds may have substituents with both aliphatic and aromatic structures.
- the quaternary nitrogen itself may be part of an aromatic ring system, for example a pyridine or pyridinium ring.
- micellar or phase transfer catalysts preferably using quaternary ammonium compounds.
- quaternary ammonium compounds between low molecular weight compounds, such as tetrabutyl ammonium chloride, and high molecular weight, ie polymeric compounds such as Polyquaternium 28, a polymer of vinylpyrrolidone and methacrylamidopropyl-trimethylammonium chloride to distinguish.
- the term substrate refers to the reactive centers of the hair, ie the SS cystine bridges, the hydrogen bond bonds, and the peptide bonds;
- the reactants include mercapto compounds and the alkali.
- the reactants which cause the solvolysis of the hair for example the negatively charged hydroxide ion, thioglycolate anion, mercaptoglycerol or mercaptoethanol, associate in a rapid equilibrium step with a micelle (Mizf) consisting of the preferably surfactant-like and / or or high molecular weight positively charged quaternary ammonium salt, to the micelle complex (MizS).
- Dithiothreitol can be used in a concentration of from 0.2 M to 0.8 M, preferably from 0.2 M to 0.4 M, based on the total cosmetic composition.
- the reaction constants of the first and second reaction steps ( Figure 1) and the hair breakage time are determined and normalized as target variables for describing the modes of action of the depilatory ingredients.
- the best values correspond to one in the normalized scale of Figure 2 and the worst values to zero.
- a function describing the modes of action of the depilation ingredients is obtained.
- Figure 2 shows the isolines of the standardized target variable (depilation rate) as a function of the pH value and the methanol concentration at a constant thioglycolic acid and DABCO concentration (FIG. 2).
- Constant values 0.3 M potassium thioglycolate and tertiary amine concentration 0.025 M DABCO.
- the depilatory composition according to the invention can be used in the case of a conventional per se formulation, e.g. be used as a cream, spray, gel, gel cream or foam etc.
- a "glove" whose one side is coated with the depilation mass and whose back surface is used as an exfoliating glove for removing the depilation mass and the hair, preferably serves according to the invention for application of the depilation mass.
- the production of such a glove is extremely cost-effective, since the gloves can be made up of a multi-layered package.
- the uppermost layer of the three-ply package comprises, for example, a non-woven fabric coated with the depilation mass or a
- the following formulation corresponds to a Depil michscreme that is transferred in the foam process on the skin. After three minutes of exposure, the cream can be washed off with a wet peeling tissue.
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
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- Biomedical Technology (AREA)
- Cosmetics (AREA)
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Abstract
Composition cosmétique dépilatoire qui contient des complexes d'aluminium ou de zinc de l'acide thioglycolique solubles dans des solvants pour la fission des ponts cystine-soufre, ainsi que des amines tertiaires en tant que catalyseurs de solvolyse. L'utilisation d'un tel système permet une élimination des poils rapide et sans danger pour la peau, même pour une valeur pH relativement basse de 10,5. L'utilisation de catalyseurs pour la catalyse micellaire et par transfert de phase en liaison avec des composés mercapto permet d'obtenir une réduction supplémentaire de la durée d'épilation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP06762166A EP1917073A1 (fr) | 2005-06-23 | 2006-06-23 | Composition depilatoire |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05013593A EP1736207A1 (fr) | 2005-06-23 | 2005-06-23 | Composition dépilatoire |
EP05026090A EP1779899A1 (fr) | 2005-06-23 | 2005-11-30 | Composition dépilatoire |
PCT/EP2006/006080 WO2006136441A1 (fr) | 2005-06-23 | 2006-06-23 | Composition depilatoire |
EP06762166A EP1917073A1 (fr) | 2005-06-23 | 2006-06-23 | Composition depilatoire |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1917073A1 true EP1917073A1 (fr) | 2008-05-07 |
Family
ID=35385744
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05013593A Withdrawn EP1736207A1 (fr) | 2005-06-23 | 2005-06-23 | Composition dépilatoire |
EP05026090A Withdrawn EP1779899A1 (fr) | 2005-06-23 | 2005-11-30 | Composition dépilatoire |
EP06762166A Withdrawn EP1917073A1 (fr) | 2005-06-23 | 2006-06-23 | Composition depilatoire |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05013593A Withdrawn EP1736207A1 (fr) | 2005-06-23 | 2005-06-23 | Composition dépilatoire |
EP05026090A Withdrawn EP1779899A1 (fr) | 2005-06-23 | 2005-11-30 | Composition dépilatoire |
Country Status (2)
Country | Link |
---|---|
EP (3) | EP1736207A1 (fr) |
WO (2) | WO2006136440A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2921816B1 (fr) * | 2007-10-09 | 2012-03-23 | Bs Ind | Gant et procede de fabrication d'un tel gant |
DE102009055333A1 (de) * | 2009-12-28 | 2011-06-30 | Henkel AG & Co. KGaA, 40589 | Haarbehandlungsmittel umfassend spezielles Trialkoxysilan und zusätzlichen Hilfsstoff |
EP2356964B1 (fr) * | 2010-02-17 | 2012-06-20 | The Procter & Gamble Company | Spannbarer Enthaarungsartikel |
EP2356968B1 (fr) * | 2010-02-17 | 2012-06-20 | The Procter & Gamble Company | Enthaarungsartikel auf Substratbasis |
EP2356962B1 (fr) * | 2010-02-17 | 2012-07-04 | The Procter & Gamble Company | Effizienter Enthaarungsartikel |
Family Cites Families (37)
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GB191101769A (en) * | 1911-01-24 | 1911-10-26 | John Henry Pexton | Improved Glove or the like for use in Polishing Metal Articles. |
IT951409B (it) * | 1972-04-15 | 1973-06-30 | Eurand Spa | Metodo per l applicazione di microcapsule su stoffe e prodot ti cosi ottenuti |
AT358147B (de) * | 1976-12-03 | 1980-08-25 | Gergely Gerhard | Reinigungsmaterial |
US4437271A (en) * | 1979-03-14 | 1984-03-20 | Minnesota Mining And Manufacturing Company | Surface treating pad having a renewable surface |
DE3166379D1 (en) * | 1980-01-16 | 1984-11-08 | Procter & Gamble | Cleansing article |
EP0047797B1 (fr) * | 1980-09-15 | 1984-08-22 | Firma Carl Freudenberg | Tissu de nettoyage |
CA1211603A (fr) * | 1981-06-01 | 1986-09-23 | Zia Haq | Article a charge de produit actif |
US4593427A (en) * | 1982-12-22 | 1986-06-10 | Ortolivo Thomas V | Waterproof scouring glove |
GB2143720A (en) * | 1983-07-25 | 1985-02-20 | Andrew Thomas Moore | Gloves for cleaning, smoothing and/or polishing objects |
DE3415155A1 (de) * | 1984-04-21 | 1985-10-31 | geb. Ehrmuth Heide 8100 Garmisch-Partenkirchen Brehm | Traegerkoerper mit mikroverkapselten fluessigkeiten verbunden |
US4621388A (en) * | 1984-08-20 | 1986-11-11 | Ortolivo Thomas V | Waterproof scouring glove with flange |
DE3447833A1 (de) * | 1984-12-29 | 1986-07-10 | Allan Gerhard 8047 Karlsfeld Frühauf | Tuch o.dgl. mit einen wirkstoff enthaltenden mikrokapseln |
US4935158A (en) * | 1986-10-30 | 1990-06-19 | Aszman Harry W | Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture |
US4788733A (en) * | 1988-03-14 | 1988-12-06 | Lerner Ross E | Combined cleaning glove and disposal bag |
US5202045A (en) * | 1989-01-05 | 1993-04-13 | Lever Brothers Company, Division Of Conopco, Inc. | S-shaped detergent laminate |
US5232769A (en) * | 1989-08-01 | 1993-08-03 | Kanebo, Ltd. | Microcapsule, treating liquids containing the same, and textile structure having microcapsules adhering thereto |
GB2367749B (en) * | 1997-07-09 | 2002-06-05 | Reckitt Benckiser France | Depilatory compositions and their use |
FR2769836B1 (fr) * | 1997-10-21 | 2000-03-10 | Rhodia Chimie Sa | Utilisation de nanofibrilles de cellulose essentiellement amorphes associees a au moins un compose organique polyhydroxyle dans des formulations cosmetiques |
TWI225793B (en) * | 1997-12-25 | 2005-01-01 | Ajinomoto Kk | Cosmetic composition |
GB9906914D0 (en) * | 1999-03-26 | 1999-05-19 | Quest Int | Compositions containing boswellia extracts |
EP1062903A1 (fr) * | 1999-06-07 | 2000-12-27 | The Procter & Gamble Company | Méthode de nettoyage de tapis utilisant un gant |
JP4488125B2 (ja) * | 1999-06-30 | 2010-06-23 | ライオン株式会社 | 毛髪用組成物 |
TWI278622B (en) * | 1999-10-29 | 2007-04-11 | Shiseido Co Ltd | Quantitative hair folliculi absorption method and skin absorption measurement method |
KR100485622B1 (ko) * | 2000-01-21 | 2005-04-27 | 가오가부시끼가이샤 | 바닥 청소 시트 |
EP1175999A1 (fr) * | 2000-07-25 | 2002-01-30 | SCA Hygiene Products GmbH | Etoffe ayant d'excellentes propriétés d'essuyage prolongées |
FR2813777B1 (fr) * | 2000-09-13 | 2002-12-06 | Catherine Simone Marthe Piquet | Gant reversible jetable |
JP3926598B2 (ja) * | 2001-01-26 | 2007-06-06 | 花王株式会社 | 除毛剤組成物 |
EP1446043A1 (fr) * | 2001-11-16 | 2004-08-18 | The Procter & Gamble Company | Tampon jetable servant a nettoyer la vaisselle et les surfaces dures |
DE10163578A1 (de) * | 2001-12-21 | 2003-07-03 | Henkel Kgaa | Wäschevorbehandlungsmittel |
DE10208199A1 (de) * | 2002-02-26 | 2003-09-11 | Terra Nostra Gmbh | Textiler Träger und Verfahren zu dessen Herstellung |
US20030175333A1 (en) * | 2002-03-06 | 2003-09-18 | Adi Shefer | Invisible patch for the controlled delivery of cosmetic, dermatological, and pharmaceutical active ingredients onto the skin |
US7115551B2 (en) * | 2002-06-07 | 2006-10-03 | The Procter & Gamble Company | Cleansing articles for skin or hair |
GB2391475B (en) * | 2002-08-10 | 2005-02-02 | Reckitt Benckiser | A packaged hair-removing layer, its manufacture and its use |
US7008620B2 (en) * | 2002-09-30 | 2006-03-07 | Johnson & Johnson Consumer Companies, Inc. | Depilatory compositions and articles and the use thereof |
US20040219118A1 (en) * | 2003-05-02 | 2004-11-04 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Method and kit for reducing irritation of skin depilatory compositions |
ITVR20030022U1 (it) * | 2003-05-21 | 2004-11-22 | Togni Giorgio De | Guanto usa e getta per la pulizia del corpo |
US20040237235A1 (en) * | 2003-06-02 | 2004-12-02 | Visioli Donna Lynn | Multipurpose disposable applicator |
-
2005
- 2005-06-23 EP EP05013593A patent/EP1736207A1/fr not_active Withdrawn
- 2005-11-30 EP EP05026090A patent/EP1779899A1/fr not_active Withdrawn
-
2006
- 2006-06-23 EP EP06762166A patent/EP1917073A1/fr not_active Withdrawn
- 2006-06-23 WO PCT/EP2006/006079 patent/WO2006136440A1/fr active Application Filing
- 2006-06-23 WO PCT/EP2006/006080 patent/WO2006136441A1/fr active Application Filing
Non-Patent Citations (1)
Title |
---|
See references of WO2006136441A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO2006136441A1 (fr) | 2006-12-28 |
WO2006136440A1 (fr) | 2006-12-28 |
EP1779899A1 (fr) | 2007-05-02 |
EP1736207A1 (fr) | 2006-12-27 |
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