EP1861906B1 - Voie de decharge remplie de gaz - Google Patents
Voie de decharge remplie de gaz Download PDFInfo
- Publication number
- EP1861906B1 EP1861906B1 EP06706016A EP06706016A EP1861906B1 EP 1861906 B1 EP1861906 B1 EP 1861906B1 EP 06706016 A EP06706016 A EP 06706016A EP 06706016 A EP06706016 A EP 06706016A EP 1861906 B1 EP1861906 B1 EP 1861906B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- discharge path
- electrode
- gas
- electrodes
- activation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910020494 K2WO4 Inorganic materials 0.000 claims abstract 3
- 150000001875 compounds Chemical class 0.000 claims 4
- 230000004913 activation Effects 0.000 abstract description 17
- 230000003213 activating effect Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 4
- 239000000654 additive Substances 0.000 description 3
- AAQNGTNRWPXMPB-UHFFFAOYSA-N dipotassium;dioxido(dioxo)tungsten Chemical compound [K+].[K+].[O-][W]([O-])(=O)=O AAQNGTNRWPXMPB-UHFFFAOYSA-N 0.000 description 3
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229910052792 caesium Inorganic materials 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910013641 LiNbO 3 Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
- 235000012773 waffles Nutrition 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T1/00—Details of spark gaps
- H01T1/24—Selection of materials for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01T—SPARK GAPS; OVERVOLTAGE ARRESTERS USING SPARK GAPS; SPARKING PLUGS; CORONA DEVICES; GENERATING IONS TO BE INTRODUCED INTO NON-ENCLOSED GASES
- H01T4/00—Overvoltage arresters using spark gaps
- H01T4/10—Overvoltage arresters using spark gaps having a single gap or a plurality of gaps in parallel
- H01T4/12—Overvoltage arresters using spark gaps having a single gap or a plurality of gaps in parallel hermetically sealed
Definitions
- the invention relates to a gas-filled discharge path such as spark gap or surge arrester.
- a gas-filled discharge section is from the document DE 19814631 A1 known.
- a glassy electrode activating composition is used which contains several components, inter alia as a basic component cesium tungstate (Cs 2 WO 4 ).
- Cs 2 WO 4 cesium tungstate
- a discharge gap is shown with an electrode activation mass which contains, inter alia, a small proportion of K 2 WO 4 .
- the invention has for its object to provide a gas-filled discharge gap with good extinguishing properties.
- a gas-filled discharge gap with at least two electrodes is specified, in which an electrode activation mass containing K 2 WO 4 is applied to ensure at least one of the ignition properties, wherein K 2 WO 4 as a base component of the electrode activation mass in an amount of 20 to 90 weight percent is provided.
- Potassium tungstate has the properties of a getter. This material is chemically very stable and can exert a getter effect even after a surge current load. As an additional property, free potassium and / or potassium oxide is formed by reduction of K 2 WO 4 in the gas-filled cavity, resulting in a low work function of the activating composition.
- Potassium tungstate melts at a brazing temperature of about 820 °, in particular loose activation particles are bound, so that the escape of loose activation particles can be prevented from the activation mass.
- the envisaged in the invention use of a potassium tungstate or one of the other potassium compounds containing activation mass ensures very good quenching properties of the discharge path after electrical load.
- An arrester with a K 2 WO 4 containing activation mass extinguished automatically and reliably after a discharge despite the applied DC voltage.
- a discharge path designed as a spark gap, with a, for example, ceramic, preferably cylindrical, hollow body with a jacket surface is specified. Open end faces of the hollow body are closed by end electrodes. Thus, a closed cavity is formed, which is filled with a noble gas.
- the activation mass is arranged on the mutually facing active surfaces of the electrodes.
- the active surfaces may have at least one or more indentations in the form of a waffle for receiving the activating mass. Waffling is understood to mean intersecting depressions.
- a plurality of recesses may be provided, which do not intersect.
- a discharge path designed as a two-way arrester is provided with two end electrodes, preferably arranged on the end side, and a hollow-cylindrical center electrode. Between the center electrode and one of the end electrodes, a hollow-cylindrical ceramic insulator is preferably arranged in each case.
- the activation mass is for application to both the center electrode and the end electrodes of the arrester suitable.
- the center electrode may be provided with a circumferential groove for receiving the activation mass.
- the activation mass can be incorporated in end electrodes in both embodiments on the mutually facing active electrode surfaces in the recesses provided for this purpose.
- the activation mass may consist of a basic component, K 2 WO 4 .
- the activation mass may contain a plurality of components, in particular base components.
- K 2 WO 4 is provided as a base component of the activating composition in an amount of 20 to 90% by weight, preferably in an amount of 30 to 60% by weight.
- the activation composition may in one variant have at least one base component and, in addition, additives.
- One of the basic components is K 2 WO 4 .
- the electrode material may also contain a proportion of glass or silicates, for.
- Further suitable are BaTiO 3 , TiO 2 , LiNbO 3 , Na 2 B 4 O 7 , MgO. Na 2 B 4 O 7 , MgO are particularly suitable as additives.
- the base components may be contained in an amount of about 20 to 90% by weight, respectively, and the additives may be contained in an amount of about less than 10% by weight, respectively.
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Emergency Protection Circuit Devices (AREA)
- Spark Plugs (AREA)
- Catalysts (AREA)
- Glass Compositions (AREA)
Abstract
Claims (4)
- Parcours de décharge rempli de gaz et présentant au moins deux électrodes et une masse d'activation d'électrode disposée sur au moins l'une des électrodes, la masse d'activation d'électrodes contenant du K2WO4, caractérisé en ce que
le K2WO4 est prévu comme composant de base de la pâte d'activation d'électrodes à raison de 20 à 90 % en poids. - Parcours de décharge selon la revendication 1, configuré comme parcours d'étincelles doté de deux électrodes terminales disposées frontalement.
- Parcours de décharge selon la revendication 1, configuré comme évacuateur de surtension doté de deux électrodes terminales disposées frontalement.
- Parcours de décharge selon l'une des revendications 1 à 3, dans lequel la pâte d'activation d'électrodes est disposée dans un creux de chaque électrode.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102005013499A DE102005013499A1 (de) | 2005-03-23 | 2005-03-23 | Gasgefüllte Entladungsstrecke |
PCT/DE2006/000347 WO2006099833A1 (fr) | 2005-03-23 | 2006-02-24 | Voie de decharge remplie de gaz |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1861906A1 EP1861906A1 (fr) | 2007-12-05 |
EP1861906B1 true EP1861906B1 (fr) | 2011-07-13 |
Family
ID=36219680
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP06706016A Active EP1861906B1 (fr) | 2005-03-23 | 2006-02-24 | Voie de decharge remplie de gaz |
Country Status (6)
Country | Link |
---|---|
US (1) | US7795810B2 (fr) |
EP (1) | EP1861906B1 (fr) |
JP (1) | JP4801139B2 (fr) |
CN (1) | CN101147304B (fr) |
DE (1) | DE102005013499A1 (fr) |
WO (1) | WO2006099833A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005016848A1 (de) * | 2005-04-12 | 2006-10-19 | Epcos Ag | Überspannungsableiter |
JP5167967B2 (ja) * | 2008-06-12 | 2013-03-21 | パナソニック株式会社 | 静電気対策部品の製造方法 |
SI23691A (sl) | 2011-03-21 | 2012-09-28 | ISKRA ZAŠČITE d.o.o. | Plinski odvodnik s kovinskim ohišjem za visokotokovne udare |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3430485A1 (de) | 1984-08-18 | 1986-02-27 | Basf Ag, 6700 Ludwigshafen | Brennstoffzelle |
DE4318994C2 (de) * | 1993-05-26 | 1995-04-20 | Siemens Ag | Gasgefüllter Überspannungsableiter |
CH691245A5 (de) | 1996-01-12 | 2001-05-31 | Epcos Ag | Gasgefüllte Entladungsstrecke. |
DE19632417C1 (de) | 1996-08-05 | 1998-05-07 | Siemens Ag | Gasgefüllter Überspannungsableiter mit Elektroden-Aktivierungsmasse |
DE19741658A1 (de) | 1997-09-16 | 1999-03-18 | Siemens Ag | Gasgefüllte Entladungsstrecke |
DE19814631A1 (de) | 1998-03-26 | 1999-09-30 | Siemens Ag | Gasgefüllte Entladungsstrecke |
JP3718142B2 (ja) * | 2001-06-22 | 2005-11-16 | 岡谷電機産業株式会社 | 放電管 |
WO2004091060A1 (fr) | 2003-04-10 | 2004-10-21 | Okaya Electric Industries Co., Ltd. | Tube a decharge et dispositif absorbant les surtensions |
JP4247556B2 (ja) * | 2003-08-08 | 2009-04-02 | 岡谷電機産業株式会社 | 放電型サージ吸収素子 |
-
2005
- 2005-03-23 DE DE102005013499A patent/DE102005013499A1/de not_active Ceased
-
2006
- 2006-02-24 EP EP06706016A patent/EP1861906B1/fr active Active
- 2006-02-24 JP JP2008502237A patent/JP4801139B2/ja not_active Expired - Fee Related
- 2006-02-24 WO PCT/DE2006/000347 patent/WO2006099833A1/fr not_active Application Discontinuation
- 2006-02-24 CN CN2006800092492A patent/CN101147304B/zh active Active
-
2007
- 2007-09-21 US US11/859,586 patent/US7795810B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
DE102005013499A1 (de) | 2006-10-05 |
US7795810B2 (en) | 2010-09-14 |
CN101147304B (zh) | 2011-12-21 |
US20080048545A1 (en) | 2008-02-28 |
CN101147304A (zh) | 2008-03-19 |
JP4801139B2 (ja) | 2011-10-26 |
WO2006099833A1 (fr) | 2006-09-28 |
EP1861906A1 (fr) | 2007-12-05 |
JP2008535150A (ja) | 2008-08-28 |
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