EP1809128B1 - Enveloppe pour articles a fumer presentant des proprietes ameliorees de reduction du monoxyde de carbone - Google Patents

Enveloppe pour articles a fumer presentant des proprietes ameliorees de reduction du monoxyde de carbone Download PDF

Info

Publication number
EP1809128B1
EP1809128B1 EP05799390A EP05799390A EP1809128B1 EP 1809128 B1 EP1809128 B1 EP 1809128B1 EP 05799390 A EP05799390 A EP 05799390A EP 05799390 A EP05799390 A EP 05799390A EP 1809128 B1 EP1809128 B1 EP 1809128B1
Authority
EP
European Patent Office
Prior art keywords
wrapping material
calcium carbonate
particle size
tobacco products
total content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05799390A
Other languages
German (de)
English (en)
Other versions
EP1809128A2 (fr
Inventor
Thomas Glatz Feinpapiere FRITZSCHING
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Glatz Feinpapiere Julius Glatz GmbH
Original Assignee
Glatz Feinpapiere Julius Glatz GmbH
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Publication date
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Publication of EP1809128A2 publication Critical patent/EP1809128A2/fr
Application granted granted Critical
Publication of EP1809128B1 publication Critical patent/EP1809128B1/fr
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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00—Cigars; Cigarettes
    • A24D1/02—Cigars; Cigarettes with special covers

Definitions

  • the present invention relates to an improved smoking article wrapping material useful in smoking articles, e.g. Cigarettes that reduce carbon monoxide as a constituent of smoke ingredients without altering the air permeability of the tobacco wrapper paper in the unburned state.
  • the known inventions and applications are aimed directly or indirectly at a change in the air permeability of the tobacco product wrapping material, which reduces all smoke ingredients and changed the number of smoking products in only slightly changed proportions.
  • CO reduction catalysts used in the prior art change the appearance of the tobacco wrapper papers or do not conform to legal regulations.
  • the aim of the present invention is thus to overcome the above-mentioned problems and to provide a tobacco product wrapping material, which allows a reduction of the carbon monoxide content of the smoke ingredients with unchanged air permeability.
  • the inventors of the present invention have found that the above object is achieved by a smoking article wrapping material containing as filler two calcium carbonate different in particle size and amount.
  • the present invention therefore provides a tobacco product wrapping material containing as a filler calcium carbonates of different particle size, one of the calcium carbonates having a particle size of from 0.1 to 2 ⁇ m and an amount of from 51 to 99%, based on the total content of calcium carbonate fillers. and another calcium carbonate has a particle size of 3.5-10 microns and is contained in an amount of 1-49% based on the total content of calcium carbonate fillers.
  • the tobacco product wrapping material according to the invention is a cigarette paper.
  • the total filler content of the tobacco product wrapping material according to the invention is 10 -50%, preferably 25 to 40%, based on the total weight of the tobacco product wrapping material.
  • the calcium carbonates used according to the invention are calcium carbonate having a particle size of from 0.1 to 2.0 ⁇ m, preferably from 0.3 to 1 ⁇ m, in an amount of from 51 to 99%, preferably from 70 to 95%, based on the Total amount of the fillers, as well as a second calcium carbonate having a particle size of 3.5-10 microns, preferably 4 to 6 microns, in an amount of 1-49%, preferably 5 -30%, based on the total amount of fillers , is included.
  • fillers such as calcium carbonate of a different particle size, titanium dioxide, magnesium oxide, talc or kaolin may optionally be added to the tobacco product wrapping material according to the invention.
  • the differentiation of the particle size of the calcium carbonate causes in the combustion process of the tobacco product wrapping material in combination with a manufactured therefrom smoking product, preferably cigarette, the formation of an outer ash tube, which shows a particularly porous structure.
  • the porous structure of the smoldering tobacco wrapper paper is essentially determined by the inventive combination of two different in particle size and amount of calcium carbonate and the total amount of calcium carbonate and only slightly by the level of air permeability of the tobacco product wrapping material.
  • the tobacco product wrapping material of the present invention may optionally include a burning rate retarding substance and / or a burning rate accelerating substance.
  • disodium hydrogenphosphate can be mentioned as the burning rate retarding substance.
  • alkali metal or alkaline earth metal salts such as sodium, potassium and magnesium salts, or carboxylic acid salts, such as acetic, citric, malic, lactic and tartaric salts, in particular citric acid salts, can be used as the burning rate accelerating substance.
  • the proportions of the respective constituents in the tobacco product wrapping material according to the invention based in each case on the total weight of the tobacco product wrapping material, usually - if present - 0 - 6%, preferably 0 - 3%, the burning rate retarding and / or accelerating substance.
  • the base wrapping material for the tobacco product wrapping material to be used according to the invention usually consists of cellulose fibers obtained, for example, from flax, softwood or hardwood. To alter the properties of the base wrapper material, if desired, various blends of cellulosic fibers can also be used as the base wrapper material.
  • the basis weight of the tobacco product wrapping material used according to the invention is usually 15 to 60 g / m 2 , preferably 18 to 40 g / m 2 .
  • a further aspect of the present invention is a method for reducing the carbon monoxide content in the flue gas, incorporating calcium carbonate fillers of different particle size in a suitable mixing ratio into a smoking article wrapping material while maintaining the air permeability of the tobacco wrap material, one of the calcium carbonates having a particle size of 0.1 to 2 ⁇ m and incorporated in a proportion of 51 to 99%, based on the total content of calcium carbonate fillers, and another calcium carbonate has a particle size of 3.5 to 10 microns and in a proportion of 1 to 49%, based on the total content Calcium carbonate fillers, is incorporated.
  • the air permeability of the tobacco product wrapping material can be maintained.
  • the inventive incorporation of said Calciumcarbonatyogllstoffe the proportion of carbon monoxide in the flue gas and the ratio of carbon monoxide to dry condensate can be reduced in a favorable and desired manner.
  • a further aspect of the present invention is a tobacco article comprising a tobacco rod, a tobacco product wrapping material, the filler thereof, two calcium carbonate particles of different particle size and quantity, each having a particle size of 0.1-2 ⁇ m and 51-99%, and 3.5-10% ⁇ m particle size and 1 -49% proportion, and optionally comprises a filter.
  • the particle size of the calcium carbonate used according to the invention was determined by means of a sedigraph.
  • a further aspect of the present invention is a method for reducing the carbon monoxide content of smoking ingredients in a smoking article comprising a tobacco rod, a smoking article wrapping material and optionally a filter, the method being characterized by incorporating into the smoking article wrapping material as filler a calcium carbonate of different particle size , wherein one of the calcium carbonates has a particle size of 0.1 to 2 microns and is incorporated in an amount of 51-99%, based on the total content of calcium carbonate fillers and another calcium carbonate has a particle size of 3.5 to 10 microns and in one Amount of 1 - 49%, based on the total content of calcium carbonate fillers, is incorporated.
  • Cigla 60 air permeability 60 CU, glow salt sodium acetate, 33% filler content, 25 g / m 2 , Julius Glatz GmbH, Neidenfels
  • the filler is composed of 80% Precarb 720 (average particle size 0.5 ⁇ m according to Sedigraph measurement, Schaefer Kalk, Dietz) and 20% Precarb 160 G (average particle size 4.2 ⁇ m according to Sedigraph measurement, Schaefer Kalk, Dietz) ,
  • Cigla 60 air permeability 60 CU, glow salt potassium citrate, 29% filler content, 25 g / m 2 , Julius Glatz GmbH, Neidenfels
  • the filler is composed of 80% Precarb 720 (average particle size 0.5 ⁇ m according to Sedigraph measurement, Schaefer Kalk, Dietz) and 20% Precarb 160 G (average particle size 4.2 ⁇ m according to Sedigraph measurement, Schaefer Kalk, Dietz) ,
  • Cigla 60 air permeability 60 CU, glow salt sodium acetate, 33% filler content, 25 g / m 2 , Julius Glatz GmbH, Neidenfels
  • the filler is composed of 100% Precarb 122VP (average particle size 1.6 ⁇ m according to Sedigraph measurement, Schaefer Kalk, Dietz).

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Paper (AREA)
  • Manufacture Of Tobacco Products (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)

Claims (8)

  1. Matériau d'enveloppe pour articles à fumer, contenant comme matière de charge des carbonates de calcium ayant différentes tailles de particules, dans lequel l'un des carbonates de calcium a une taille de particules de 0,1 à 2 µm et est présent en une quantité de 51 à 99%, ramenée à la teneur totale en matières de charge de carbonate de calcium, et un autre carbonate de calcium a une taille de particules de 3,5 à 10 µm et est présent en une quantité de 1 à 49%, ramenée à la teneur totale en matières de charge de carbonate de calcium.
  2. Matériau d'enveloppe pour articles à fumer selon la revendication 1, qui est un papier à cigarettes.
  3. Matériau d'enveloppe pour articles à fumer selon la revendication 1 ou la revendication 2, dans lequel l'un des carbonates de calcium a une taille de particules de 0,3 à 1 µm et est présent en une quantité de 70 à 95%, ramenée à la teneur totale en matières de charge de carbonate de calcium, et l'autre carbonate de calcium a une taille de particules de 4 à 6 µm et est présent en une quantité de 5 à 30%, ramenée à la teneur totale en matières de charge de carbonate de calcium.
  4. Matériau d'enveloppe pour articles à fumer selon l'une des revendications 1 à 3, dans lequel la teneur totale en matières de charge est de 10 à 50%, ramenée au poids total du matériau d'enveloppe pour articles à fumer.
  5. Matériau d'enveloppe pour articles à fumer selon la revendication 4, dans lequel la teneur totale en matières de charge se situe entre 25% à 40%.
  6. Matériau d'enveloppe pour articles à fumer selon l'une des revendications 1 à 5, contenant en plus une ou plusieurs autres matières de charge choisies dans le groupe constitué par le carbonate de calcium d'une autre taille de particules, le dioxyde de titane, l'oxyde de magnésium, le kaolin et/ou le talc.
  7. Procédé de réduction de la teneur en monoxyde de carbone de la fumée du tabac, dans lequel des matières de charge de carbonates de calcium de différentes tailles de particules sont incorporées selon un rapport de mélange approprié dans un matériau d'enveloppe pour articles à fumer en maintenant la perméabilité à l'air du matériau d'enveloppe pour articles à fumer, l'un des carbonates de calcium ayant une taille de particules de 0,1 à 2 µm et étant incorporé en une quantité de 51 à 99%, ramenée à la teneur totale en matières de charge à base de carbonate de calcium, et un autre carbonate de calcium ayant une taille de particules de 3,5 à 10 µm et étant incorporé en une quantité de 1 à 49%, ramenée à la teneur totale en matières de charge à base de carbonate de calcium.
  8. Article à fumer comprenant un boudin de tabac, un matériau d'enveloppe pour articles à fumer selon l'une des revendications 1 à 6 et le cas échéant un filtre.
EP05799390A 2004-10-19 2005-10-12 Enveloppe pour articles a fumer presentant des proprietes ameliorees de reduction du monoxyde de carbone Active EP1809128B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004050960A DE102004050960B4 (de) 2004-10-19 2004-10-19 Rauchwarenumhüllungsmaterial mit verbesserten Kohlenmonoxidreduzierungseigenschaften
PCT/EP2005/055195 WO2006042817A2 (fr) 2004-10-19 2005-10-12 Materiau d'emballage pour produits du tabac presentant de meilleures proprietes de reduction du monoxyde de carbone

Publications (2)

Publication Number Publication Date
EP1809128A2 EP1809128A2 (fr) 2007-07-25
EP1809128B1 true EP1809128B1 (fr) 2008-05-07

Family

ID=36095779

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05799390A Active EP1809128B1 (fr) 2004-10-19 2005-10-12 Enveloppe pour articles a fumer presentant des proprietes ameliorees de reduction du monoxyde de carbone

Country Status (6)

Country Link
US (1) US20090044819A1 (fr)
EP (1) EP1809128B1 (fr)
AT (1) ATE394039T1 (fr)
DE (2) DE102004050960B4 (fr)
ES (1) ES2303691T3 (fr)
WO (1) WO2006042817A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012104773A1 (de) * 2012-06-01 2013-12-05 Delfortgroup Ag Zigarettenpapier mit plättchenförmigem Füllstoff

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2718829T3 (es) * 2007-02-23 2019-07-04 Schweitzer Mauduit Int Inc Envolturas para artículos para fumar que tienen una difusión reducida que conduce a características reducidas de predisposición a la ignición
US8654659B2 (en) 2009-12-23 2014-02-18 Citrix Systems, Inc. Systems and methods for listening policies for virtual servers of appliance
SI2402167T1 (sl) 2010-07-02 2014-01-31 Omya International Ag Papir za kapljično tiskanje
DE102012109642B8 (de) * 2012-10-10 2014-06-26 Delfortgroup Ag Zigarettenpapier mit Füllstoff mit spezieller Partikelgrößenverteilung und Zigarette
DE102013109386B3 (de) * 2013-08-29 2015-01-15 Delfortgroup Ag Effizient herstellbares Zigarettenpapier für selbstverlöschende Zigaretten, Verfahren zu seiner Herstellung sowie eine Zigarette

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2538802A (en) * 1947-05-03 1951-01-23 Ecusta Paper Corp Method of manufacturing calcium carbonate
US5109876A (en) * 1990-04-19 1992-05-05 R. J. Reynolds Tobacco Company Cigarette paper and cigarette incorporating same
US5168884A (en) * 1991-04-12 1992-12-08 Philip Morris Incorporated Smoking articles using novel paper wrapper
US5263500A (en) * 1991-04-12 1993-11-23 Philip Morris Incorporated Cigarette and wrapper with controlled puff count
US5888348A (en) * 1996-11-14 1999-03-30 Schweitzer-Mauduit International, Inc. Method for controlling the permeability of a paper
US6823872B2 (en) * 1997-04-07 2004-11-30 Schweitzer-Mauduit International, Inc. Smoking article with reduced carbon monoxide delivery
US5893372A (en) * 1997-04-07 1999-04-13 Schweitzer Maudit International, Inc. High opacity wrapping paper
US5921249A (en) * 1997-07-14 1999-07-13 Schweitzer-Mauduit International, Inc. High and low porosity wrapping papers for smoking articles
JP2000157245A (ja) * 1998-11-24 2000-06-13 Mishima Paper Co Ltd 高燃焼性たばこ用巻紙

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012104773A1 (de) * 2012-06-01 2013-12-05 Delfortgroup Ag Zigarettenpapier mit plättchenförmigem Füllstoff

Also Published As

Publication number Publication date
ES2303691T3 (es) 2008-08-16
DE102004050960A1 (de) 2006-05-18
EP1809128A2 (fr) 2007-07-25
WO2006042817A2 (fr) 2006-04-27
WO2006042817A3 (fr) 2006-06-15
DE102004050960B4 (de) 2008-07-24
ATE394039T1 (de) 2008-05-15
US20090044819A1 (en) 2009-02-19
DE502005004048D1 (de) 2008-06-19

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