EP1753832A2 - Composition d'encre - Google Patents

Composition d'encre

Info

Publication number
EP1753832A2
EP1753832A2 EP05744201A EP05744201A EP1753832A2 EP 1753832 A2 EP1753832 A2 EP 1753832A2 EP 05744201 A EP05744201 A EP 05744201A EP 05744201 A EP05744201 A EP 05744201A EP 1753832 A2 EP1753832 A2 EP 1753832A2
Authority
EP
European Patent Office
Prior art keywords
ink composition
substrate
agent
image
printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05744201A
Other languages
German (de)
English (en)
Other versions
EP1753832A4 (fr
Inventor
Yossi Pearl
Ofer Ben-Zur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kornit Digital Ltd
Original Assignee
Kornit Digital Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IL162231A external-priority patent/IL162231A/en
Priority claimed from PCT/IL2005/000166 external-priority patent/WO2005076730A2/fr
Application filed by Kornit Digital Ltd filed Critical Kornit Digital Ltd
Publication of EP1753832A2 publication Critical patent/EP1753832A2/fr
Publication of EP1753832A4 publication Critical patent/EP1753832A4/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066—Thermic treatments of textile materials
    • D06P5/2083—Thermic treatments of textile materials heating with IR or microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B41J11/002—Curing or drying the ink on the copy materials, e.g. by heating or irradiating
    • B41J11/0021—Curing or drying the ink on the copy materials, e.g. by heating or irradiating using irradiation
    • B41J11/00216—Curing or drying the ink on the copy materials, e.g. by heating or irradiating using irradiation using infrared [IR] radiation or microwaves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J11/00—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form
    • B41J11/0015—Devices or arrangements  of selective printing mechanisms, e.g. ink-jet printers or thermal printers, for supporting or handling copy material in sheet or web form for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing
    • B41J11/002—Curing or drying the ink on the copy materials, e.g. by heating or irradiating
    • B41J11/0022—Curing or drying the ink on the copy materials, e.g. by heating or irradiating using convection means, e.g. by using a fan for blowing or sucking air
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407—Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • B41J3/4078—Printing on textile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
    • B41M5/0017—Application of ink-fixing material, e.g. mordant, precipitating agent, on the substrate prior to printing, e.g. by ink-jet printing, coating or spraying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0058—Digital printing on surfaces other than ordinary paper on metals and oxidised metal surfaces
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001—Special chemical aspects of printing textile materials
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/20—Physical treatments affecting dyeing, e.g. ultrasonic or electric
    • D06P5/2066—Thermic treatments of textile materials
    • D06P5/2077—Thermic treatments of textile materials after dyeing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/30—Ink jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/007—Digital printing on surfaces other than ordinary paper on glass, ceramic, tiles, concrete, stones, etc.
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/0041—Digital printing on surfaces other than ordinary paper
    • B41M5/0076—Digital printing on surfaces other than ordinary paper on wooden surfaces, leather, linoleum, skin, or flowers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat

Definitions

  • the present invention relates to the field of printing and, more particularly, to a new ink composition and use thereof for high-resolution, high-definition multicolor direct printing on surfaces such as textile.
  • One such demand is for an ink composition which will be suitable for printing long lasting, durable, abrasion resistant, water-, detergent- and chemical-fast color images on a variety of materials, which will not wear out rapidly upon use, handling, washing and exposure to the environment.
  • Inkjet printing is a wide-spread technique in which a stream of a specific liquid ink composition is ejected as droplets from minute nozzles to record characters and patterns on the surface of a printing subject without making direct contact between the ink application apparatus and the surface of the subject.
  • a typical inkjet printing system includes methods and apparatii in which electric signals are converted to mechanical signals for a continuous or on-demand spraying of an ink composition which is stored in a nozzle head portion, to thereby record characters, symbols and patterns on the surface of a subject.
  • Inkjet printers have grown in availability, performance and popularity while dropping significantly in price, mostly due to their reliability, relatively quiet operation, versatility, graphics capability, print quality, and low cost. Moreover, inkjet printers have made possible "on demand" color printing without the need for complicated devices Inkjet printers are capable of printing on a variety of surfaces. For example, commercial inkjet printers can spray directly on a non-flat, curved item such as the label on a glass bottle. For consumer use, there are a number of specialty papers, ranging from adhesive-backed labels or stickers to business cards and brochures. When the subject surface is of a garment or another textile fabric surface, digital inkjet technology is probably the most favorable technique for designer art and image creation.
  • the presently available ink compositions include aqueous-based ink compositions and non-aqueous solvent-based ink compositions.
  • Aqueous-based ink compositions are typically composed of water and a colorant, usually a dye or pigment dispersion, and may further contain a number of additives for imparting certain features to the ink (e.g., improved stability and flow, feather resistance, and the like).
  • Non-aqueous solvent- based ink compositions are typically composed of one or more volatile organic solvents, such as low alcohols, low alkanes and the like, a colorant and one or more additives which affect the physical and chemical properties of the composition.
  • the ink composition must ensure rapid drying, no bleeding or smearing, uniform printing on the surface of the subject, no blending of colors in the case of multicolor printing, wash-fastness, no clogging of the nozzles, easy system cleaning and other characteristics.
  • the ink composition should be characterized, for example, by suitable viscosity, solubility, volatility, compatibility with other components of the printing system and, in cases of continuous flow inkjet printing, electrical resistance. .
  • the ink composition should typically have the following properties: room temperature Brookfield viscosity of 1 to 50 centipoises, surface tension of 25 to 55 dynes per centimeter and a submicron contained particle size.
  • the ink composition should typically have the following properties: room temperature Brookfield viscosity of up to 15 centipoises, electrical resistance of 50 to 2000 ohm per centimeter and a sonic velocity of 1200 to 1800 meters per second.
  • the ink composition must allow the colorant, being either pigment or dye, to adhere to the subject surface such that the resulting printed image is robust and has good adhesion to the subject surface, giving the printed image mechanical and chemical durability which ensures the image is wash-fast and abrasion resistant.
  • applying the presently available ink compositions while using any of the present printing techniques, including inkjet printing, on various surfaces, and particularly on more abso ⁇ tive surfaces such as textiles, is associated with various limitations.
  • the printed images are often neither water-fast nor detergent-resistant, resulting in fading of the printed image after washing, abrasion and/or exposure to various elements and further oftentimes fail to meet the demand for pleasant hand feel. Therefore, while the textile industry requires that the image be both water-resistant and detergent-resistant, that the colors and hues would be as vivid as possible, that the colorant of the ink would adhere tenaciously to the substrate, and that the desirable hand properties of the substrate would be maintained, the presently known ink compositions fail to accomplish these requirements.
  • Several techniques are presently known in the art which are aimed at overcoming the limitations associated with digital inkjet printing on textile and other abso ⁇ tive surfaces. These include, for example, pre-treatment of the fabric prior to the printing process. Thus, U.S.
  • Patents Nos. 6,291,023, 6,698,874 and 6,840,992 teach coating compositions which are applied on the fabric prior to printing. Albeit, these pre-treatments are not suitable for all fabric materials, use environmentally unfriendly chemicals, are time-consuming and cost-ineffective. Partial answers to the abovementioned requirements of ink compositions were previously provided in the industry, and mostly involve curing the applied ink compositions by various levels of heat or by activating light-sensitive elements in the ink composition by UV illumination. In cases where such ink compositions are used, the curing results in the formation of cross-linking between the components of the ink composition.
  • U.S. Patent No. 4,978,969 discloses a method of inkjet printing using a UV curable ink composition.
  • the ink contains a UV sensitive agent such as a urethane oligomer.
  • the ink composition is applied onto the subject surface which is then exposed to UV light to effect the curing.
  • a significant drawback of this method is that the aforesaid UV exposure is carried out for a relatively long period of time of about 0.5 to 10 minutes.
  • a heat curable system is disclosed in U.S. Patent No.
  • the ink composition contains an aqueous carrier and a dye or pigment dispersion as the colorant.
  • the support medium contains a plastic support sheet and a coating layer that contains a hydrophilic polymer, for example, polyvinyl alcohol, and a reactive component, for example, a compound that bears acid groups.
  • a hydrophilic polymer for example, polyvinyl alcohol
  • a reactive component for example, a compound that bears acid groups.
  • the hydrophilic polymer undergoes a cross-linking reaction.
  • Another two-part inkjet printing composition is disclosed in U.S. Patent No. 4,694,302 wherein one part of the composition contains carboxymethylcellulose, which is a known reactive polymer, and the second part contains an aluminum salt.
  • the dye can be present in either part.
  • the reaction between the carboxymethylcellulose and the aluminum salt leads to the formation of a polymer lattice which binds the dye therein, thereby forming a water-fast ink.
  • This patent also teaches a one-part ink composition wherein the ink contains a colloidal suspension of carbon black in diglyme solvent and a reactive species such as sebacyl chloride. Upon application on a cellulose-containing subject surface such as paper, the sebacyl chloride reacts with the cellulose to form a cellulosic polymer.
  • 6,140,391 discloses an ink composition containing alcohol(s), a polyol, an aldehyde-based cross-linking agent, an acid catalyst, a colorant and a carrier (solvent).
  • a composition is particularly useful in the printing of identification marks on cellulose-based casings such as sausage casings.
  • cellulose-based substrates are typically characterized as relatively low-abso ⁇ tive substrates, the suitability of this composition for printing on high abso ⁇ tive surfaces such as textile is doubted.
  • the disclosed ink composition affords a highly cross-linked printed layer which in practice forms a film-type coating on the surface of the subject.
  • the most commonly used ink compositions typically afford printed images which suffer from adverse characteristics such as sensitivity to abrasion, low wash-fastness, unpleasant hand-feel (and odor) of pre-treated fabrics and the unpleasant hand-feel and cracking of plasticized printed surfaces.
  • adverse characteristics such as sensitivity to abrasion, low wash-fastness, unpleasant hand-feel (and odor) of pre-treated fabrics and the unpleasant hand-feel and cracking of plasticized printed surfaces.
  • an ink composition suitable for printing an image on a substrate which comprises a carrier, a colorant, an agent capable of chemically interacting with the substrate and a catalyst for promoting this interaction, the composition being substantially devoid of a polyol.
  • an ink composition suitable for printing an image on a substrate which comprises a carrier, a colorant, a polyol, an agent capable of chemically interacting with the substrate and a catalyst for promoting this interaction, with the proviso that the agent capable of chemically interacting with the substrate is not an aldehyde-based cross-linking agent.
  • an ink composition suitable for printing an image on a substrate which comprises a carrier, a colorant, a polyol, an agent capable of chemically interacting with the substrate and a catalyst for promoting this interaction, wherein a concentration of the polyol ranges from about 11 weight percentages to about 20 weight percentages of the total weight of the ink composition.
  • an ink composition suitable for printing an image on a substrate which includes a first part and a second part, wherein the first part includes a carrier, a colorant, a polyol and an agent capable of chemically interacting with the substrate and further wherein the second part includes a wetting composition and a catalyst, the wetting composition being capable of interfering with the engagement of the ink composition with at least one binding site on the surface of the substrate, and the catalyst being for promoting this interaction.
  • an ink composition suitable for printing an image on a substrate which includes a first part and a second part, wherein the first part includes a carrier, a colorant, a polyol and a catalyst and further wherein the second part includes a wetting composition and an agent capable of chemically interacting with the substrate, the wetting composition being capable of interfering with the engagement of the ink composition with at least one binding site on the surface of the substrate, and the catalyst being for promoting this interaction.
  • a process of printing an image on a substrate includes providing one of the single part ink compositions of the present invention and applying the ink composition on the surface, so as to form the image on the substrate.
  • a process of printing an image on a substrate includes providing one of the two parts ink compositions of the present invention, contacting at least a portion of the surface of the substrate with the second part of the ink composition, so as to provide a wet portion of the surface; and applying the first part of the ink composition on the wet portion of the surface, so as to form the image on the substrate.
  • the portion is a pre-determined portion of the surface.
  • the density of the second part of the composition in the wet portion of the surface ranges from about 0.01 gram per 1 cm to about 2 grams per 1 cm of the wet portion of the surface.
  • the printing processes further includes, subsequent to the application of the ink composition, curing the image.
  • the printing processes are effected digitally.
  • the image is characterized by high durability, chemical-fastness and wash-fastness.
  • the image is characterized by high color definition, high durability, chemical-fastness and wash-fastness.
  • the chemical interaction with the substrate includes interacting with at least one functional group present within the substrate.
  • the functional group is selected from the group consisting of an amine, an amide, a carboxyl, a hydroxyl and a thiol.
  • the substrate is selected from the group consisting of a textile fabric, a paper, a wood and a plastic.
  • the textile fabric is selected from the group consisting of wool, silk, cotton, linen, hemp, ramie, jute, acetate fabric, acrylic fabric, lastex, nylon, polyester, rayon, viscose, spandex, metallic composite, carbon or carbonized composite, and any combination thereof.
  • the substrate is a garment made of a textile fabric, and more preferably the textile fabric is made of cotton.
  • the printing is effected by inkjet printing.
  • the ink composition has a Brookfield viscosity at room temperature that ranges from about 1 centipoise to about 150 centipoises. According to still further features in the described preferred embodiments the ink composition has a surface tension that ranges from about 25 dynes per centimeter to about 55 dynes per centimeter. According to further features in preferred embodiments of the invention described below, the ink composition has a maximal particle size lower than 1 micron. According to still further features in the described preferred embodiments the ink composition has an electrical resistance that ranges from about 50 ohms per centimeter to about 2000 ohms per centimeter.
  • the ink composition has a sonic velocity that ranges from about 1200 meters per second to about 1800 meters per second. According to still further features in the described preferred embodiments the ink composition has Brookfield viscosity at room temperature of about 16.5 centipoises, surface tension of about 31 dynes per centimeter and maximal particle size lower than 1 micron.
  • the carrier is selected from the group consisting of an aqueous carrier and a non-aqueous carrier.
  • the non-aqueous carrier is selected from the group consisting of a glycol ether, a glycol ether acetate, a ketone, an alkane, an alkene, a halogenated alkane, an alcohol, an aryl and any combination thereof.
  • the concentration of the colorant ranges from about 0.1 weight percentages to about 40 weight percentages of the total weight of the ink composition.
  • the agent capable of chemically interacting with the surface of the substrate is a cross- linking agent.
  • the cross-linking agents is selected from the group consisting of an aldehyde-based cross-linking agent, a polyisocyanate based cross-linking agent, a silane based cross-linking agent, a peroxide based cross-linking agent, an ester based cross-linking agent, an amide based cross-linking agent and a vinyl based cross- linking agent.
  • the aldehyde-based cross-linking agent is a modified melamine formaldehyde.
  • the concentration of the agent capable of chemically interacting with the surface of the substrate ranges from about 0.1 weight percentages to about 60 weight percentages of the total weight of the ink composition.
  • the catalyst is an acid.
  • the acid is selected from the group consisting of dinonylnaphthalene sulfonic acid, dinonylnaphthalene disulfonic acid, dodecylbenzene sulfonic acid, toluene sulfonic acid, an alkyl phosphate acid and an aryl phosphate acid.
  • the concentration of the catalyst ranges from about 0.01 weight percentages to about 15 weight percentages of the total weight of the ink composition.
  • the concentration ranges from about 0.1 weight percentages to about 10 weight percentages of the total weight of the ink composition.
  • the polyol is selected from the group consisting of a polyester polyol, a polyether polyol, a urethane polyol, a polyether, a polyester acrylate, an acrylic polyol, a urethane acrylic polyol, a polyester urethane triol resin, a polyvinyl butyral, a polyvinyl chloride acrylate and an oxidized castor oil.
  • the concentration of the polyol ranges from about 0.5 weight percentages to about 30 weight percentages of the total weight of the ink composition.
  • the ink composition further includes at least one additional ingredient selected from the group consisting of an amine stabilizer, an alcohol stabilizer, a non-reactive agent, a softener/plasticizer, a dispersing agent, a surface active agent and an ionizable material.
  • the second part of the ink composition is characterized by a surface tension lower than a surface tension of the first part of the ink composition.
  • the surface tension of the second part of the ink composition is lower than the surface tension of the first part of the ink composition by at least 2 dynes per centimeter.
  • the second part of the ink composition is characterized by a surface tension lower than 50 dynes per centimeter. More preferably the surface tension of the second part of the ink composition ranges from about 35 dynes per centimeter to about 15 dynes per centimeter. Most preferably the surface tension of the second part of the ink composition ranges from about 25 dynes per centimeter to about 10 dynes per centimeter.
  • the second part of the ink composition includes water.
  • the second part of the ink composition includes at least one organic solvent.
  • the organic solvent is selected from the group consisting of an alcohol, a ketone, an ether, an alkyl polysiloxane, an alkane, an alkene, a cycloalkane, a cycloalkene, an aryl, a heteroalicyclic, a heteroaryl and any combination thereof.
  • the alcohol is selected from the group consisting of methanol, ethanol, propanol, 2-propanol, 1- butanol, 2-butanol and pentanol.
  • the alkane is selected from the group consisting of hexane, heptane, octane, petroleum ether, tert-butylchloride, isobutylchloride, perfluorohexane, perfluoroheptane and perfluorooctane.
  • the organic solvent has a boiling point lower than 100 °C.
  • the second part of the ink composition further includes at least one agent selected from the group consisting of an amine stabilizer, an alcohol stabilizer, a non-reactive agent, a softener/plasticizer, a surface active agent, a surface tension modifying agent, a viscosity modifying agent, a thickener agent and any combination thereof.
  • the concentration of any one of these agents ranges from about 0.01 weight percentages to about 75 weight percentages of the total weight of the wetting composition.
  • process refers to manners, means, techniques and procedures for accomplishing a given task including, but not limited to, those manners, means, techniques and procedures either known to, or readily developed from known manners, means, techniques and procedures by practitioners of the chemical, pharmacological, biological, biochemical and medical arts.
  • singular form “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise.
  • the term “a compound” or “at least one compound” may include a plurality of compounds, including mixtures thereof.
  • range format is merely for convenience and brevity and should not be construed as an inflexible limitation on the scope of the invention. Accordingly, the description of a range should be considered to have specifically disclosed all the possible subranges as well as individual numerical values within that range. For example, description of a range such as from 1 to 6 should be considered to have specifically disclosed subranges such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6 etc., as well as individual numbers within that range, for example, 1, 2, 3, 4, 5, and 6. This applies regardless of the breadth of the range. Whenever a numerical range is indicated herein, it is meant to include any cited numeral (fractional or integral) within the indicated range.
  • the present invention is of an ink composition suitable for printing images on a variety of substrates, particularly abso ⁇ tive substrates such as textile, of printing processes utilizing same and of printed images formed thereby which are durable, wash-fast, chemically robust and resistant to physical wear.
  • the principles and operation of the ink composition, the process and the images according to the present invention may be better understood with reference to the accompanying descriptions and examples.
  • an ink composition that includes a multifunctional component, which is capable of forming chemical bonds with functional groups that are naturally present in the substrate material, and available for binding on its surface, along with other components that can promote such a binding, the colorants in such a composition could be meshed into the printed substrate, and thus a highly durable image would be achieved. It was further envisioned that such an ink composition would be highly efficient for printing images on abso ⁇ tive surfaces such as textile fabrics.
  • each of the ink compositions of the present invention comprises, in addition to a colorant and a carrier (which functions as a solvent), an agent that is capable of chemically interacting with functional groups found within the printed substrate, preferably on its surface, as is detailed hereinbelow and a catalyst, which promotes such chemical interactions, as is further detailed hereinbelow.
  • an ink composition suitable for printing an image on a surface of a substrate which includes a carrier, a colorant, an agent capable of chemically interacting with functional groups that are present within the printed substrate and a catalyst for promoting the chemical interaction.
  • the composition is substantially devoid of a polyol.
  • an ink composition suitable for printing an image on a surface of a substrate which includes a carrier, a colorant, a polyol, a non aldehyde-based cross-linking agent as the agent being capable of chemically interacting with functional groups present within the printed substrate and a catalyst for promoting the chemical interaction.
  • an ink composition suitable for printing an image on a surface of a substrate which includes a carrier, a colorant, a polyol, an agent capable of chemically interacting with functional groups present within the printed substrate and a catalyst for promoting the chemical interaction.
  • the concentration of the polyol ranges from about 11 weight percentages to about 20 weight percentages of the total weight of the ink composition.
  • the ink compositions, according to the present invention are formulated so as to adhere to the substrate, preferably upon curing by heat.
  • the curing is part of the printing process and can be effected by heat and/or dry air emanating from a heat source such as, for example, an infrared conveyor or a filament coil, or a dry air source such as, for example, a hot air blower.
  • a heat source such as, for example, an infrared conveyor or a filament coil
  • a dry air source such as, for example, a hot air blower.
  • the substrate can be any material onto which printing an image is desired, as long as the material contains functional groups that are available for interacting with the ink composition presented herein.
  • Exemplary substrates include, without limitation, a textile fabric, a paper, a wood and a plastic. While the ink composition according to the present embodiments is designed to form durable images on abso ⁇ tive substrates, preferably, the substrate is an abso ⁇ tive material such as a textile fabric.
  • the textile fabrics may include wool, silk, cotton, linen, hemp, ramie, jute, acetate fabric, acrylic fabric, lastex, nylon, polyester, rayon, viscose, spandex, metallic composite, carbon or carbonized composite, and any combination thereof.
  • the substrate onto which the image in printed on is a garment made of a textile fabric, and more preferably it is substantially comprised of cotton.
  • the ink composition, according to the present invention is formulated such that is it suitable also for the main inkjet printing techniques, the "drop-on-demand" technique and the continuous flow techniques, as these techniques are familiar to any artisan skilled in the art. Therefore, preferably the ink composition of the present invention is for use in an inkjet printing machine.
  • Inkjet printing requires the ink composition to be characterized by several chemical and physical criteria, such as, Brookfield viscosity at room temperature, surface tension, maximal particle size, electrical resistance and sonic velocity, as these terms are known to any artisan skilled in the art.
  • Each of the ink compositions presented herein therefore exhibits, among other properties, the following physical properties which render them suitable for inkjet printing: Brookfield viscosity at room temperature that ranges from about 1 centipoise to about 150 centipoises; Surface tension that ranges from about 25 dynes per centimeter to about 55 dynes per centimeter; Maximal particle size lower than 1 micron; Electrical resistance that ranges from about 50 ohms per centimeter to about 2000 ohms per centimeter; and Sonic velocity that ranges from about 1200 meters per second to about 1800 meters per second.
  • the ink composition exhibits a Brookfield viscosity at room temperature of about 16.5 centipoises, a surface tension of about 31 dynes per centimeter and a maximal particle size lower than 1 micron.
  • the main components of the ink composition may vary according to the type of substrate and the specific requirements of the final printed product, yet each serve the same principle as follows.
  • the carrier is selected to provide a medium for mixing, suspending and/or dissolving the other components of the ink composition, and be volatile and benign.
  • the colorant is selected to achieve the desirable color and other physical and chemical properties, and be suitable for a given printing machine and printing technology.
  • the agent which is capable of forming chemical interactions with the printed substrate is selected to be chemically compatible with the functional groups present within the substrate and preferably within its surface, such that it can form chemical bonds with these functional groups.
  • this agent is a cross-linking agent, as is detailed hereinbelow.
  • the catalyst is selected to be chemically compatible with the agent above and the chemical interaction that occur with the substrate.
  • colorant as used herein describes a substance which imparts the desired color to the printed image.
  • the colorant may be a pigment, a lake or a dye.
  • Pigments are solid colorants with are typically suspended in the carrier of the ink composition, whereby dyes are liquid colorants which are dissolved in the carrier of the ink composition.
  • the colorant is selected suitable in terms of its chemical and physical properties.
  • the colorant is a heat curable colorant.
  • Such colorants are preferred since, as is detailed hereinbelow, the chemical interaction between the agent that interacts with the substrate and the substrate is oftentimes heat-dependent and thus, an added value is obtained.
  • Exemplary dye colorants that are suitable for use in the context of the present invention include, without limitation, azo chrome complexes such as the commercially available Orasol black RLI, Orasol Red G and CU phthalocyanine and similar azo-cobalt complexes.
  • Exemplary pigment colorants that are suitable for use in the context of the present invention include, without limitation, quinacridone, benzimidazolone, carbon black, phthalocyanine, diarylide, azo, titanium oxide and calcium carbonate.
  • Exemplary commercially available pigments are such as Permajet, Renol and Microlith.
  • the colorant content in the ink composition of the present invention ranges from about 0.2 weight percentage to about 40 weight percentage of the total weight of the ink composition.
  • the colorant content ranges from 1 to 10 weight percentages of the total weight of the ink composition.
  • One of the main components of the ink composition is the carrier.
  • the carrier according to the present invention, is required to be safe in terms of environmental hazards and volatile so as to allow fast drying and curing of the resulting image, and further be capable of dissolving and/or suspending all the other components of the ink composition so as to allow the ink composition to be applied easily and uniformly onto the substrate.
  • the carrier affects the main physical properties of the ink composition, and thus is selected according to the required application and the other components.
  • the carrier can be an aqueous carrier, having water as its main ingredient, or a non-aqueous carrier, having one or more organic solvents as its main ingredients.
  • Preferred carriers according to the present invention are non-aqueous carriers.
  • the carrier content in the ink compositions presented herein typically ranges from about 20 weight percentages to about 90 weight percentages of the total weight of the ink composition.
  • the term “about” refers to ⁇ 10 %.
  • the term "volatile” refers to a substance or a composition that is characterized by a relatively low boiling point and/or high evaporation rate.
  • organic solvents which can compose the carrier include glycol ethers, glycol ether acetates, ketones, alkanes, alkenes, halogenated alkanes, alcohols, aryls and any combination thereof.
  • Preferred organic solvents which can compose the carrier of the ink compositions presented herein include, without limitation, propylene glycol monomethyl ether acetate, l-(l-methoxypropan- 2-yloxy)propan-2-ol (dipropylene glycol monomethyl ether), l-(l-(l-methoxypropan- 2-yloxy)propan-2-yloxy)propan-2-ol (tripropylene glycol monomethyl ether), ethylene glycol butyl ether acetate, 4-methylpentan-2-one (methyl isobutyl ketone) and cyclohexanone.
  • the component of the ink compositions presented herein which provides for enhanced durability of the images formed thereby is an agent that is capable of chemically interacting with the substrate.
  • agent that is capable of chemically interacting with the substrate.
  • such agent interacts with functional groups that are present within the substrate material and more preferably, which are present on its surface.
  • chemical interaction describes a chemical reaction which takes place between two or more substances, and typically leads to a formation of a bond.
  • the bond in the case of the present invention, can be a covalent bond, an ionic bond, a hydrogen bond and the like and thus, the chemical interaction can involve, for example, nucleophilic and electrophilic substitutions, nucleophilic and electrophilic addition reactions, elimination reactions, cycloaddition reactions, rearrangement reactions, chelate formation, ionic complex formation, affinity-pair formation and any other known organic and inorganic reactions.
  • the phrase "functional group" describes a chemical moiety that is capable of undergoing a chemical reaction that typically leads to a bond formation.
  • the bond in the case of the present invention, can be a covalent bond, a ionic bond, a hydrogen bond and the like.
  • suitable functional groups according to the present invention include, without limitation, amine, amide, halide, hydroxyl, thiol, cyano, sulfonamide, carboxyl, thiocarbamate, urea and thiourea, as these terms are defined hereinafter.
  • the functional groups according to the present invention are those which are abundant and available for chemical interactions in the substances which compose the substrate onto which the image in printed.
  • Such functional groups that are present within prevalent substrates typically include, without limitation, amine, amide, carboxyl, hydroxyl and thiol.
  • this agent By chemically interacting with the substrate, this agent provides for improves adherence of the ink composition and thus ensures that the image formed by the ink composition would sustain washes, abrasion and other physical and chemical stress.
  • the chemical interaction involves cross-linking and the agent capable of interacting with the substrate is a cross-linking agent.
  • cross-linking describes a chemical reaction that involves the formation of interconnecting links between various components and thus leads to the cross-wise formation of interconnecting links.
  • cross-linking agent refers to a chemical substance which has two or more reactive groups available for chemical interaction typically leading to bond formation, whereby these functional groups participate in such a bond formation that leads to cross-linking between other chemical substances.
  • the cross-linking agent has more than two reactive groups, enabling the cross-linking agent to form a branched mesh of interconnecting links.
  • the reactive groups on the cross-linking agent according to the present invention must be chemically compatible with the functional groups available on the surface of the substrate, and be reactive under mild condition at which printing and/or curing are performed. For example, in the case of a substrate with amine groups on its surface, a cross-linking agent with a carboxyl groups may form amide bonds with the substrate.
  • hydroxyl and/or thiol groups on the surface of the substrate will form bonds with cross-linking agents having amine groups, carboxyl groups, acyl-halide groups, aldehyde groups, isocyanate groups, as these terms are defined hereinbelow, and many other such reactive groups which interact readily in mild conditions and/or mild heating.
  • the cross-linking agent can be, for example, an aldehyde-based cross- linking agent, an amine-based cross-linking agent, an isocyanate-based cross-linking agent, a carboxyl-based cross-linking agent, a silane based cross-linking agent, an acyl-halide cross-linking agent, a peroxide based cross-linking agent, an ester based cross-linking agent, an amide based cross-linking agent and a vinyl based cross- linking agent.
  • Each of these cross-linking agents include one or more of the indicated reactive groups.
  • Aldehyde-based cross-linking agents are the most commonly used cross- linking agents in many industries due to their highly reactive profile under mild conditions and the relatively safe use thereof in industrial scale. When the ink composition is designed for printing onto textile fabrics, aldehyde-based cross linking agents are particularly advantageous due to the abundant presence of hydroxyl groups on surfaces of textile fabrics. Therefore, unless otherwise indicated, in each of the aspects of the present invention, a preferred cross-linking agent is an aldehyde-based cross-linking agent Still, aldehyde-based cross-linking agents may be found inadequate for certain applications.
  • aldehyde-based cross-linking agents can be chemically incompatible with other components in the ink composition, chemically incompatible with components in the substrate (such as a composite fiber fabric), and their use can be further limited by safety considerations, regulations and the likes.
  • the high reactivity of aldehyde-based cross-linking agents may oftentimes lead to unstable ink composition, being difficult to prepare, store, transfer and utilize or having short shelf-life. More important is the fact that aldehyde-based cross-linking agents typically form a highly cross-linked mesh which may be found too brittle for certain applications such as printing of fabrics and garments. Such an enhanced brittleness may lead to poor cracking-resistance of the formed image.
  • the agent capable of interacting with the substrate is a cross-linking agent, whereby the cross-linking agent is preferably an aldehyde-based cross-linking agent
  • the agent capable of interacting with the substrate is not an aldehyde-based cross-linking agent.
  • Ink compositions that include agents other than aldehyde-based cross-linking agents can be efficiently used in applications where reduced brittleness is desired. Such compositions may thus include other cross-linking agents, as described above.
  • amine refers to an -NR'R" group where R' and R" are each hydrogen, alkyl, alkenyl, cycloalkyl, aryl, heteroaryl (bonded through a ring carbon) or heteroalicyclic (bonded through a ring carbon) as defined hereinbelow.
  • alkyl and alkane as used herein, describes a saturated aliphatic hydrocarbon including straight chain and branched chain groups.
  • the alkyl group has 1 to 20 carbon atoms.
  • alkyl group may contain 1 carbon atom, 2 carbon atoms, 3 carbon atoms, etc., up to and including 20 carbon atoms. More preferably, the alkyl is a medium size alkyl having 1 to 10 carbon atoms. Most preferably, unless otherwise indicated, the alkyl is a lower alkyl having 1 to 5 carbon atoms.
  • alkenyl and alkene refers to an alkyl group which consists of at least two carbon atoms and at least one carbon-carbon double bond.
  • cycloalkyl describes an all-carbon monocyclic or fused ring (i.e., rings which share an adjacent pair of carbon atoms) group where one or more of the rings does not have a completely conjugated pi-electron system.
  • heteroalicyclic describes a monocyclic or fused ring group having in the ring(s) one or more atoms such as nitrogen, oxygen and sulfur. The rings may also have one or more double bonds. However, the rings do not have a completely conjugated pi- electron system.
  • aryl describes an all-carbon monocyclic or fused-ring polycyclic (i.e., rings which share adjacent pairs of carbon atoms) groups having a completely conjugated pi-electron system.
  • heteroaryl describes a monocyclic or fused ring (i.e., rings which share an adjacent pair of atoms) group having in the ring(s) one or more atoms, such as, for example, nitrogen, oxygen and sulfur and, in addition, having a completely conjugated pi-electron system.
  • heteroaryl groups include pyrrole, furane, thiophene, imidazole, oxazole, thiazole, pyrazole, pyridine, pyrimidine, quinoline, isoquinoline and purine.
  • halide describes fluorine, chlorine, bromine or iodine.
  • cyano describes a -C ⁇ N group.
  • hydroxyl refers to a -OH group.
  • peroxide refers to a -O-O-R' group, where R' is as defined herein.
  • silane describes a -O-Si-(OR')(OR")(OR'") group, where R', R" and R'" are as defined herein.
  • thiol refers to a -SH group.
  • an aldehyde-based cross-linking agent is a preferred cross-linking agent in some aspects of the present invention.
  • aldehyde-based cross-linking agents include, without limitation, modified melamine formaldehyde based cross-linking agents, urea formaldehyde based cross- linking agents, glycoluril formaldehyde based cross-linking agents and benzoguanamine formaldehyde based cross-linking agents.
  • modified melamine formaldehyde-based agents include, without limitation, methylated melamine formaldehyde, N-butylated melamine formaldehyde and isobutylated melamine formaldehyde.
  • a preferred modified melamine formaldehyde-based agent is a methylated melamine formaldehyde.
  • Exemplary urea formaldehyde -based agent include, without limitation, methylated urea formaldehyde, N-butylated urea formaldehyde and isobutylated urea formaldehyde.
  • Exemplary glycoluril formaldehyde based agents include, without limitation, N-butylated glycoluril formaldehyde and methylated/ethylated glycoluril formaldehyde.
  • Exemplary benzoguanamine formaldehyde based agents include, without limitation, N-butylated benzoguanamine formaldehyde and methylated/ethylated benzoguanamine formaldehyde.
  • the cross-linking agent content in the ink composition of the present invention ranges from about 0.4 weight percentage to about 55 weight percentage of the total weight of the ink composition. More preferably, the cross- linking agent content ranges from about 5 weight percentage to about 25 weight percentage of the total weight of the ink composition.
  • the ink compositions presented herein are typically designed such that the chemical interaction between the agent described above and the substrate would be effected in the presence of a catalyst.
  • the term "catalyst" as used herein describes a chemical substance which is capable of promoting, initiating and/or catalyzing the chemical reaction between the agent capable of chemically interacting with the substrate and the functional groups in the substrate.
  • the catalyst is selected so to promote, initiate and/or catalyze the reaction upon contact of the ink composition with the substrate, optionally in combination with an external heat that is applied during the curing of the image.
  • the catalyst component of the ink composition of the present invention accelerates the chemical interaction between the substrate and the cross-linking agent such that a substantial portion of the functional groups and reactive groups in both the substrate and the agent will react therebetween during the time period that begins once the ink composition is applied onto the substrate and ends when the printed image is cured and the carrier has evaporated.
  • Preferred catalysts according to the present invention are acid catalysts and more preferred are strong acid catalysts.
  • Acid catalysts are suitable since they may catalyze most of the reactions described above between various functional groups on the substrate and reactive groups within, e.g., the various cross-linking agents described above. Since, when utilizing a highly reactive agent for interacting with the substrate, the presence of the catalyst may promote undesired reactions between the different components of the ink composition before its application onto the substrate, the acid catalyst is preferably attenuated.
  • the acid catalyst is present in the ink composition either as a blocked catalyst, namely as a salt form thereof with a volatile basic counter-ion or as a complex with about 3 weight percentage of a low amine or about 15 weight percentage of a low alcohol present in the ink composition, whereby the amine or the alcohol serves as a volatile acid attenuating additive.
  • the salt or the complex described above decompose upon application of the composition onto the substrate and thus the reactive form of the catalyst is generated.
  • the catalyst is a blocked (salt) acid catalyst or an unblocked (free) acid catalyst.
  • Exemplary blocked acid catalyst include, without limitation, blocked dinonylnaphthalene sulfonic acid, blocked dinonylnaphthalene disulfonic acid, blocked dodecylbenzene sulfonic acid, blocked toluene sulfonic acid, a blocked alkyl phosphate acid and a blocked aryl phosphate acid.
  • the catalyst content in the ink composition of the present invention ranges from about 0.01 weight percentage to about 15 weight percentage of the total weight of the ink composition. More preferably, the catalyst content ranges from about 0.1 to about 10 weight percentages of the total weight of the ink composition.
  • some of the ink compositions presented herein further include a polyol.
  • polyol describes a chemical substance that has two or more free hydroxyl groups, as this term is defined hereinbelow, and includes, for example, diols, a triols, tetraols, etc.
  • Typical polyols are substances that include from about 50 to about 400 hydroxyl groups.
  • Representative examples of a polyol include, without limitation, a polyester polyol, a polyether polyol, a urethane polyol, a polyester acrylate, an acrylic polyol, a urethane acrylic polyol, a polyester urethane triol resin, a polyvinyl butyral, a polyvinyl chloride acrylate and an oxidized castor oil.
  • the inco ⁇ oration of polyols in the ink compositions of the present invention provides the formed image with chemical and physical qualities such as flexibility, softness and pleasant hand-feel.
  • the polyol extends and branches the links which are formed between the functional groups on the surface of the substrate and the agent which is selected so as to interact therewith, and therefore affects the mesh affixing the colorant to the substrate.
  • the enhanced flexibility of the resulting image, which results from the presence of polyol may be advantageous is some applications, it may reduce the resistance of the formed image to chemical and physical stress and thus is disadvantageous in applications that require high resistance.
  • the ink composition comprises a polyol
  • the ink composition is substantially devoid of polyol.
  • the phrase "substantially devoid of a certain substance refers to a composition that is totally devoid of this substance or includes no more than 0.1 weight percent of the substance.
  • Non-limiting examples of polyols that are suitable for use in the context of certain aspects of the present invention include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butylene glycol, hexanediol, pentanediol, glycerin (glycerol), hexanetriol, and thioglycol.
  • the polyol content in the ink composition of the present invention ranges from about 0.1 weight percentage to about 50 weight percentages of the total weight of the ink composition.
  • the polyol content in the ink composition ranges from 0.5 weight percentage to 30 weight percentages of the total weight of the ink composition and more preferably, the polyol content in the ink composition ranges from about 11 weight percentages to about 20 weight percentages of the total weight of the ink composition.
  • a polyol content that ranges from about 11 weight percentages to about 20 weight percentages of the total weight of the ink composition is believed to be highly advantageous in terms of the formed image since it enables the provision of a flexible yet resistant image.
  • each of the ink compositions presented herein comprises a colorant, as is detailed hereinabove, a carrier, as is detailed hereinabove, an agent that is capable of chemically interacting with the substrate, as is detailed hereinabove, and a catalyst, as is detailed hereinabove.
  • the composition is devoid of a polyol. As discussed hereinabove, such compositions are highly suitable for printing applications in which highly stress-resistant images are desired.
  • compositions when including an aldehyde-based cross-linking agent, are further advantageous, since reactions that may occur in the ink composition before the application thereof, due to the high reactivity of both the aldehyde-based cross- linking agent and the polyol, are avoided and thus the stability of the ink composition prior to its application is enhanced.
  • the ink composition further includes a polyol and the agent capable of interacting with the substrate is other than an aldehyde-based cross- linking agent.
  • Such compositions are suitable for use in applications where reduced brittleness and enhanced flexibility of the formed image are desired.
  • Such compositions are further characterized by improved stability prior to application, as is discussed hereinabove.
  • the ink composition includes a polyol in an amount that ranges from about 11 weight percentages and about 20 weight percentages. As is discussed hereinabove, such an amount provides for flexible yet stress-resistant image.
  • Each of the ink compositions described herein can further include one or more additional ingredient which may further modify the chemical and physical properties of the ink composition, and provide for improved performance of the formed image. Examples of such ingredients include, without limitation, non-reactive agents, softeners/plasticizers, dispersing agents, surface active agents and conductivity agents (ionizable materials).
  • non-reactive agents include, without limitation, vinylchloride polymers, vinyl chloride- vinyl acetate copolymers and vinyl acetate polymers such as offered by Wacker Company, solid acrylics such as Paraloid DM55, Paraloid B-72 and B-82 such as offered by Rohm Haas Company and the like.
  • the content of the non-reactive agent in the ink composition ranges from about 0.01 weight percentage to about 50 weight percentages of the total weight of the ink composition.
  • Exemplary softeners/plasticizers include, without limitation, an adipate ester, a phthalate ester, an aryl phosphate, a trimellitate ester and a plastisol, and many other commercially available softeners/plasticizers which are offered by such companies as
  • the content of the softener/plasticizer ranges from about 0.01 weight percentage to 2.5 weight percentages of the total weight of the ink composition.
  • Exemplary dispersing agent include, without limitation, an acrylate polymer, an alkyl ammonium acidic polymer salt and other commercially available dispersing agents such as Byk 108 and Byk 180 offered by Byk-Chemie Company.
  • the content of the dispersing agent ranges from about 0.01 weight percentage to about 10 weight percentages of the total weight of the ink composition.
  • Exemplary surface active agents include, without limitation, a soap, a detergent, a syndet, an emulsifier, a foaming agent, a polyalkylsiloxane, an anionic surface active agent, a cationic surface active agent and a non-ionic surface active agent.
  • the content of the surface active agent ranges from about 0.01 weight percentage to about 5 weight percentages of the total weight of the ink composition.
  • Exemplary ionizable materials include, without limitation, sodium chloride, potassium chloride, potassium bromide, calcium chloride, an alkali halide salt and an alkaline earth salt.
  • the content of the ionizable material ranges from about 0.01 weight percentage to about 5 weight percentages of the total weight of the ink composition.
  • the process described in these patent applications results in high-resolution, high-definition and vivid images, with no bleeding and diffusion of the ink.
  • the present inventors have thus envisioned that one or more of the components of the ink compositions presented herein may be added to the wetting composition which is applied onto the substrate prior to the application of the ink composition.
  • the ink composition can be made up of two parts, one that is applied onto the substrate prior to printing the image and one containing the colorant which is applied when printing the image. The two parts combine in situ on the surface of the substrate.
  • an ink composition suitable for printing an image on a surface of a substrate which includes a first part and a second part, wherein the first part includes a carrier, a colorant, a polyol and an agent capable of chemically interacting with the surface of the substrate, such as a cross-linking agent, as these components are described hereinabove, and further wherein the second part includes a wetting composition and a catalyst, whereby the wetting composition is capable of interfering with the engagement of the ink composition with at least one binding site of the surface of the substrate and the catalyst is as described hereinabove.
  • the catalyst is a component of the first part (the part containing the colorant), and the agent capable of chemically interacting with the surface of the substrate, such as a cross-linking agent, is a component of the second part of the ink composition, being the wetting composition.
  • the two parts ink compositions offer two fundamental advantages over that of presently known ink compositions: a highly durable image which is wash-fast, chemical-fast, flexible and pleasant to the touch is obtained due to the unique capacity to chemically adhere to the substrate as a cross-linked mesh and an extraordinary high level of color definition of photorealistic qualities and no bleeding of the colors when applied on abso ⁇ tive substrates such as textile fabrics, which is obtained due to the unique effect of the wetting composition which is applied onto the surface prior to the colorant.
  • this two-part ink composition provides for improved stability of the ink composition prior to its use since the reactive components which may adversely react prior to its application, as is discussed hereinabove, are separated.
  • the wetting composition is selected capable of interfering with the engagement of the liquid ink composition with at least one binding site of the surface.
  • Such an interference includes, for example, temporarily modifying a mechanical property of the surface by, for example, reducing the contact area between the part of the ink composition containing the colorant and the surface by, e.g., filling the pores in the surface or flattening perturbing objects such as stray fibers; temporarily modifying a physical property of the surface by, for example, reducing the surface tension formed between the surface and that part of the ink composition; and temporarily modifying a chemical property of the surface by, for example, engaging the binding sites of the surface by, e.g., interacting with functional groups on the surface, masking, neutralizing or inverting the charge of functional groups on the surface.
  • binding site describes any site of the surface that may interact, either mechanically or physically, with the ink composition.
  • these include, for example, functional groups on the surface that may physically interact with compatible reactive groups present in the ink composition; functional groups on the surface that may form hydrophobic or hydrophilic interactions with compatible functional groups present in the ink composition; flattening perturbing objects such as stray fibers that can interfere with the uniform application of the ink composition on the surface; any dry area of the surface which may thermodynamically promote abso ⁇ tion of the liquid ink composition; and any area of the surface which due to too high or too low surface tension promotes minimization or maximization of surface area of the ink droplets on the surface.
  • the second part of the ink composition which includes a wetting composition is characterized by a relatively low surface tension.
  • the surface tension of the second part of the ink composition consisting of a wetting composition is lower than 50 dynes per centimeter.
  • the surface tension of the second part of the ink composition ranges from about 35 dynes per centimeter to about 15 dynes per centimeter. More preferably, the surface tension of the second part of the ink composition ranges from about 25 dynes per centimeter to about 10 dynes per centimeter.
  • the second part of the ink composition consisting of a wetting composition and the first part of the ink composition containing the colorant are formulated such that the surface tension of the second part is lower that the surface tension of the first part of the ink composition.
  • the surface tension of the second part is lower than the surface tension of the first part by at least 2 dynes per centimeter, more preferably by at least 3 dynes per centimeter, more preferably by at least 5 dynes per centimeter and even more preferably by at least 10 dynes per centimeter.
  • the wetting composition includes one or more organic solvents. Since, as is discussed hereinabove, the wetting composition is aimed at temporarily modify the mechanical, physical properties of the surface during the application of the colorant thereon, while not affecting other properties of the surface, it is highly desirable that at least a majority the wetting composition could be removed from the surface once the printing process is completed.
  • preferred organic solvents are characterized as volatile. As is well accepted in the art, boiling points below 100 °C are considered as relatively low boiling points. Hence, according to a preferred embodiment of the present invention, the organic solvent has a boiling point lower than 100 °C.
  • Such organic solvents can be easily removed once the printing process is completed, during, for example, the curing process, as described above, which involves application of heat or air blow onto the surface. As is discussed hereinabove, since it is assumed that characteristics such as volatility and low surface tension improve the beneficial effect of the wetting composition, preferred organic solvents are those that exhibit such characteristics.
  • organic solvents include, without limitation, alkanes, alkenes, cycloalkanes, cycloalkanes and aryls, which are collectively referred to herein as hydrocarbons, alcohols, ketones, ethers, alkyl polysiloxanes, heteroalicyclics, heteroaryls and any combination thereof.
  • alcohol describes a chemical substance that bears one or more hydroxyl groups.
  • An alcohol can be represented by R-OH, wherein R is alkyl, a cycloalkyl, alkenyl, alkynyl, aryl, heteroaryl and the likes, as these terms are defined herein.
  • alcohols that are suitable for use in the context of the present invention include methanol, ethanol, propanol, 2-propanol, 1-butanol, 2- butanol and pentanol.
  • the presently most preferred alcohols are ethanol, 2-propanol (isopropyl alcohol, IP A) and 1-butanol.
  • ketone in the context of this aspect of the present invention describes a chemical substance that has one or more carbonyl groups.
  • ketones that are suitable for use in the context of the present invention include acetone, cyclopentanone, cyclohexanone, methyl ethyl ketone and pentan-3-one.
  • the presently most preferred ketone is cyclohexanone.
  • ether describes a chemical substance having one or more alkoxy groups.
  • alkoxy refers to an -OR group, wherein R is as described hereinabove, and thus an ether can be represented by R-O-R', wherein R and R' are each independently as define herein.
  • Non-limiting examples of ethers that are suitable for use in the context of the present invention include ethylene glycol butyl ether acetate, propyl methyl ether, methoxy propanol, diethyl ether, 1-methoxyhexane, 1-ethoxyhexane and 1- propoxypentane.
  • the presently most preferred ethers are ethylene glycol butyl ether acetate and propyl methyl ether.
  • alkyl polysiloxanes describes a polymeric chemical substance having the general formula L R ' Jn , wherein n is an integer denoting the number of repeating polymeric units, and R and R' are each independently as defined hereinabove.
  • n is an integer from 1 to 3.
  • Non-limiting examples of alkyl polysiloxanes that are suitable for use in the context of the present invention include dimethyl polysiloxane, ethyl methyl polysiloxane, phenyl methyl polysiloxane and nitrilobutyl phenyl polysiloxane.
  • the most preferred alkyl polysiloxane is dimethyl polysiloxane.
  • the presently most preferred wetting compositions according to the present invention include one or more of the alcohols and hydrocarbons described hereinabove.
  • the most preferred alcohols are methanol, ethanol, propanol, 2- propanol, 1-butanol, 2-butanol and pentanol
  • the most preferred hydrocarbons are hexane, heptane, octane, petroleum ether, tert-butylchloride, isobutylchloride, perfluorohexane, perfluoroheptane and perfluorooctane.
  • the wetting composition may include, in addition to, or instead of, the organic solvent, water.
  • the second part of the ink composition consisting of a wetting composition according to the present invention may optionally further include one or more agents which may additionally alter the interaction of the first part of the ink composition with the surface and affect the chemical interaction between the components of the combined ink composition and the substrate.
  • agents include, without limitation, an amine stabilizer for the catalyst, an alcohol stabilizer for the cross-linking agent and the catalyst, a non-reactive agent, a softener/plasticizer, a surface active agent, a surface tension modifying agent, a viscosity modifying agent, a thickener agent and any combination thereof.
  • the addition of such agents to the second part of the ink composition may improve the effect of the wetting composition and may further provide a selected wetting composition with desirable characteristics.
  • the addition of surface tension modifying agents enables to use a wetting composition that comprises an organic solvent with moderate surface tension characteristics, which are improved by the added agent.
  • the addition of viscosity modifying agents enables to use a wetting composition that comprises an organic solvent with high viscosity, which is reduced by the added agent, and so on.
  • the content of each of the abovementioned additives in the second part of the ink composition may range from about 0.01 weight percentage to about 75 weight percentage of the total weight of the wetting composition.
  • ink compositions of the present invention in a printing process thus affords superior printing results, especially when printing on abso ⁇ tive surfaces, which are characterized, in the cases of a single part ink composition, by durability and resistance to abrasions and other stresses, and in the case of the two parts ink composition, further characterized by high-quality, high-color definition and high- resolution photorealistic qualities, as well as improved stability and hence prolonged shelf-life.
  • a process of printing an image on a surface of a substrate which using one of the single part ink compositions according to the present invention, and includes applying the ink composition on the surface, so as to form the image on the surface.
  • a process of printing an image on a surface of a substrate using one of the two parts ink compositions of the present invention includes contacting at least a portion of the surface with the second part of the ink composition, so as to provide a wet portion of the surface; and subsequently applying the first part of the ink composition, containing the colorants on the wet portion of the surface, so as to form the image on the surface.
  • Contacting the surface with the second part of the ink composition can be further controlled by pre-determining the area of the surface that is to be wetted by the wetting composition, so as to contact with the wetting composition only that specific, pre-determined area of the surface onto which the image is printed in the subsequent stage of the process.
  • the pre-determination of the area to be wetted allows for optimization of the entire printing process which depends on accurate material quantification, i.e., of the two parts of the ink composition, and accurate timing of each printing steps, i.e., the wetting, the ink application and the curing steps.
  • the predetermination of the area of the surface can by readily established by a computerized algorithm.
  • the part of the surface that is contacted with the wetting composition is pre-determined digitally.
  • contacting the surface with the second part of the ink composition is performed so as to obtain a wet portion of the surface in which the density of the • • 9 wetting composition ranges from about 0.01 gram per 1 cm of the surface to about 2 9 9 grams per 1 cm of the surface, more preferably from about 0.05 gram per 1 cm to about 1 gram per 1 cm 2 , more preferably from about 0.1 gram per 1 cm 2 to about 1 9 9 gram per 1 cm and, more preferably, from about 0.2 grams per 1 cm to about 0.6 grams per 1 cm 2 .
  • Both processes either the process using the single part ink composition and the process using the two parts ink composition, further include a curing step which may also affect the chemical interaction between the components of the ink composition and the removal of solvents from the carrier and the wetting composition as well as other volatile substances in the ink composition.
  • the curing is effected by heat as described hereinabove.
  • the resulting image is unique in the sense that it combines qualities which are absent or lacking in images which are printed by using presently known ink compositions and printing processes. Therefore, according to another aspect of the present invention there is provided a substrate having an image printed on a surface thereon which is prepared by the printing process described hereinabove using a single part ink composition.
  • the image, according to this aspect of the present invention is characterized by an unusual and unique durability, resistance to mechanical, physical and chemical stresses, which is expressed by high wash-fastness, flexibility yet also with a pleasant hand-feel.
  • a substrate having an image printed on a surface thereon which is prepared by the printing process described hereinabove which includes a wetting step, and using a two parts ink composition of the present invention.
  • the image, according to this aspect of the present invention is also characterized by an unusual and unique durability, resistance to mechanical, physical and chemical stresses, high wash-fastness, flexibility and a pleasant hand-feel, and further characterized by high color definition, high resolution photorealistic qualities, even when applied to abso ⁇ tive surfaces such as textile fabrics.
  • a heat curable non-aqueous solvent-based blue dye ink composition suitable for a drop-on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed, a catalyst for catalyzing this chemical interaction and other additives was prepared as follows:
  • a 100 % cotton fabric was mounted onto the machine, and an image was printed using the above described ink composition.
  • the printed fabric was then subjected to curing, by heating to 150-180 °C for 240 seconds using an infrared curing unit.
  • the resulting image exhibited a soft, flexible and non-cracking image having the desirable water-fast and chemical-fast properties.
  • EXAMPLE 2 A heat curable non-aqueous solvent-based black pigment ink composition suitable for a drop-on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed, a catalyst for catalyzing this chemical interaction and other additives was prepared as follows:
  • the other chemicals, except the acid catalyst and the Renol pigment were added and the resulting mixture was shaken for 10 minutes.
  • the Renol pigment was added slowly while shaking at 2500 rounds per minute. After adding the pigment, the mixture was shaken at 6000 rounds per minute at room temperature for 90 minutes.
  • the acid catalyst was then added and the resulting mixture was allowed to shake for another 10 minutes at 2000 rounds per minute and was thereafter filtered via a 1.6 micron glass fiber filter.
  • a 100 % cotton fabric was mounted onto the machine, and an image was printed using the above described ink composition.
  • the printed fabric was then subjected to curing, by heating to 150-180 °C for 240 seconds using an infrared curing unit.
  • the resulting image exhibited a soft, flexible and non-cracking image having the desirable water-fast and chemical-fast properties.
  • EXAMPLE 3 A heat curable non-aqueous solvent-based black dye ink composition suitable for a drop-on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed, a catalyst for catalyzing this chemical interaction and other additives was prepared as follows:
  • a 100 % cotton fabric was mounted onto the machine, and an image was printed using the above described ink composition.
  • the printed fabric was then subjected to curing, by heating to 150-180 °C for 240 seconds using an infrared curing unit.
  • the resulting image exhibited a soft, flexible and non-cracking image having the desirable water-fast and chemical-fast properties.
  • a heat curable non-aqueous solvent-based magenta pigment ink composition suitable for a drop-on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed, a catalyst for catalyzing this chemical interaction and other additives was prepared as follows: Materials: Dipropylene glycol methyl ether (DOW Chemicals) 68.0 grams Tripropylene glycol monomethyl ether (DOW Chemicals) 2.0 grams Cyclohexanone (Sigma-Aldrich) 2.9 grams BYK 315 (Byk-Chemie) 0.05 grams BYK 051 (Byk-Chemie) 0.05 grams Renol Blue B2G-HW 30 (Ciba) 4.0 grams Modified melamine-formaldehyde resin (Cymel 1133, Cytec Ind.) 21.0 grams Blocked P-toluenesulfonic acid (N
  • the other chemicals, except the acid catalyst and the Renol pigment were added and shaken for 10 minutes.
  • the Renol pigment was added slowly while shaking at 2500 rounds per minute. After adding the pigment, the mixture was shaken at 6000 rounds per minute at room temperature for 90 minutes.
  • the acid catalyst was then added and the resulting mixture was allowed to shake for another 10 minutes at 2000 rounds per minute and was thereafter filtered via a 1.6 micron glass fiber filter.
  • a 100 % cotton fabric was mounted onto the machine, and an image was printed using the above described ink composition. The printed fabric was then subjected to curing, by heating to 150-180 °C for
  • a heat curable non-aqueous solvent-based red dye ink composition suitable for a drop-on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed, a catalyst for catalyzing this chemical interaction and other additives was prepared as follows:
  • a heat curable non-aqueous solvent-based ink composition suitable for a drop- on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, a polyol, an aldehyde-based agent capable of chemically interacting with the target substrate to be printed and a catalyst for catalyzing this chemical interaction is prepared as follows: Materials: (Amounts are given as weight percentage of total weight of the resulting ink composition) Ethylene glycol butyl ether acetate (EGBEA) as a carrier, 55 % Microlith Black preparation as a colorant, 6 % Urethane Diol in propylene glycol mono-methylether acetate, 15 % N-butylated melamine formaldehyde for interacting with the subject chemically, 15 % Blocked p-
  • a heat curable non-aqueous solvent-based ink composition suitable for a drop- on-demand inkjet printing machine according to the present invention, containing a carrier, a colorant, a polyol, a non-aldehyde-based agent capable of chemically interacting with the target substrate to be printed and a catalyst for catalyzing this chemical interaction is prepared as follows:
  • the listed chemicals of the first part are added to a glass vessel in the order of appearance, shaken at 2100 rounds per minutes for 60 minutes at room temperature and the resulting mixture is filtered via a 1.6 micron glass fiber filter.
  • the listed chemicals of the second part are mixed and placed in the wetting composition container.
  • the spraying nozzle attached to the printing machine is used to uniformly apply the second part of the ink composition containing the wetting composition and the catalyst onto the subject surface.
  • the first part of the ink composition is used to print an image on the wetted 100 % cotton fabric, and the printed fabric is subjected to curing, by heating to 150-180 °C for 240 seconds using an infrared curing unit.

Abstract

Nouvelles compositions d'encre pour l'impression d'images durables, résistant au lavage et au lessivage sur des surfaces, dont des surfaces fibreuses, poreuses et absorbantes autres. Des procédés d'impression dans lesquels lesdites compositions sont utilisées ainsi que des images ainsi formées sont également décrits.
EP05744201A 2004-05-30 2005-05-30 Composition d'encre Withdrawn EP1753832A4 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
IL162231A IL162231A (en) 2004-05-30 2004-05-30 Direct digital printing process of jet propulsion inkjet on a wet fabric section
IL16345904 2004-08-11
US65123005P 2005-02-10 2005-02-10
PCT/IL2005/000166 WO2005076730A2 (fr) 2004-02-12 2005-02-10 Appareil d'impression numerique
PCT/IL2005/000559 WO2005115761A2 (fr) 2004-05-30 2005-05-30 Composition d'encre

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EP1753832A2 true EP1753832A2 (fr) 2007-02-21
EP1753832A4 EP1753832A4 (fr) 2009-07-29

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EP05744201A Withdrawn EP1753832A4 (fr) 2004-05-30 2005-05-30 Composition d'encre

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Also Published As

Publication number Publication date
EP1753832A4 (fr) 2009-07-29
IL179765A (en) 2012-01-31
WO2005115089A2 (fr) 2005-12-08
WO2005115089A3 (fr) 2006-12-07
JP2008505774A (ja) 2008-02-28
JP2008509231A (ja) 2008-03-27
EP1750945A2 (fr) 2007-02-14
EP1750945B1 (fr) 2022-01-12
WO2005115761A3 (fr) 2006-03-02
EP1750945A4 (fr) 2015-05-06
IL179765A0 (en) 2007-05-15
IL179764A0 (en) 2007-05-15
WO2005115761A2 (fr) 2005-12-08

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