EP1749081B1 - Composition savonneuse en pate compatible avec une membrane - Google Patents

Composition savonneuse en pate compatible avec une membrane Download PDF

Info

Publication number
EP1749081B1
EP1749081B1 EP04741675.5A EP04741675A EP1749081B1 EP 1749081 B1 EP1749081 B1 EP 1749081B1 EP 04741675 A EP04741675 A EP 04741675A EP 1749081 B1 EP1749081 B1 EP 1749081B1
Authority
EP
European Patent Office
Prior art keywords
composition
amount
acid
alkyl
composition according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP04741675.5A
Other languages
German (de)
English (en)
Other versions
EP1749081A1 (fr
EP1749081B8 (fr
Inventor
Khalil Shamayeli
Ralf-Erbo Knop
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecolab USA Inc
Original Assignee
Ecolab Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecolab Inc filed Critical Ecolab Inc
Publication of EP1749081A1 publication Critical patent/EP1749081A1/fr
Publication of EP1749081B1 publication Critical patent/EP1749081B1/fr
Application granted granted Critical
Publication of EP1749081B8 publication Critical patent/EP1749081B8/fr
Anticipated expiration legal-status Critical
Active legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2041—Dihydric alcohols
    • C11D3/2044—Dihydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols

Definitions

  • compositions mentioned in WO 98/33881 and WO 01/32819 are intended to provide alkaline paste-like compositions which do without synthetic anionic surfactants of the alkyl benzene sulfonate-type or non-ionic surfactants containing alkoxy groups and synthetic anionic surfactants of the sulfate- and sulfonate-type, respectively, because of their foaming tendency or their poor biodegradability, respectively, while at the same time providing appropriate storage stability and excellent washing performance.
  • the compositions described therein lead to problems with respect to purification of the waste water, since they cause a blocking of the filtration unites used to achieve the purification.
  • WO 02/46351 The problem underlying WO 02/46351 is to provide a paste-like detergent or cleaning agent which is appropriate for use in washing processes in which the accumulated waste water is intended to become purified by a filtration process using at least one reverse osmosis step.
  • the content of surfactants used therein is very low.
  • the cleaning performance is reduced or at least the composition is rather appropriate for soil which is easily dispersed predominantly by the alkaline properties of the liquor.
  • the composition contains the compound of formula (I) in an amount of from 5 to 25 wt.-%, preferably 8 to 20 wt.-%, based on the whole composition.
  • the one or more anorganic builders on a non-silicate basis and organic builders are present in the composition in an amount of from 8 to 45 wt.-%, preferably 12 to 30 wt.-%, based on the whole composition.
  • the most appropriate anorganic builder which is on a non-silicate basis is represented by sodium carbonate which as well functions as alkalinity source.
  • Sodium hydrogencarbonate or borate compounds, especially alkali borates, more preferred borax, may as well be used.
  • terpolymers with a weight ration of (meth)acrylic acid and maleic acid or maleinate of between 1:1 and 4:1, preferably between 2:1 and 3:1 and especially 2:1 and 2,5:1, with the amounts as well as the weight ratios being based on the acid.

Claims (11)

  1. Composition de nettoyage ou détergente sous forme de pâte, comprenant
    a) un composant tensioactif comprenant un composé de formule générale R1-COOM (I) en une quantité comprise entre 5 et 25 % en poids, de préférence entre 8 et 20 % en poids par rapport à l'ensemble de la composition, R1 représentant un résidu alkyle ou alcényle linéaire ou ramifié ayant 8 à 22 atomes de carbone et M représentant un ion de métal alcalin ;
    1,5 à 8 % en poids, sur la base de l'ensemble de la composition d'un alcoxylate d'alcool gras et/ou d'un alcoxylate d'alcool oxo ayant 8 à 22 atomes de carbone et un degré moyen d'alcoxylation d'au moins 5 ; et
    un tensioactif anionique choisi parmi les composés comprenant des sulfates d'alkyle en C8-C18, des sulfates d'éther d'alkyle en C8-C18, des alkylsulfonates en C8-C18, des α-oléfinesulfonates en C8-C18, des acides gras sulfonés en C8-C18, des alkylbenzènesulfonates en C8-C18, des esters d'alkyle sulfosucciniques mono et di-C1-C12, des carboxylates d'éther d'alkylpolyglycol en C8-C18, des N-acyltaurides en C8-C18, des N-sarcosinate en C8-C18, des iséthionates d'alkyle en C8-C18 et leurs mélanges ;
    b) un composé de formule générale R2-O-R3 (II) en une quantité comprise entre 1 et 20 % en poids par rapport à l'ensemble de la composition, R2 représentant un résidu alkyle ou alcényle linéaire ou ramifié ayant 8 à 22 atomes de carbone et R3 représentant un atome d'hydrogène ou un résidu alkyle linéaire ou ramifié ayant 1 à 8 atomes de carbone ;
    c) de l'eau et/ou un composé de formule générale X-CH2-(CHY)n-CH2-Z (III), n étant un nombre entier compris entre 0 et 2, et X, Y et Z symbolisant indépendamment un atome d'hydrogène ou un groupe hydroxyle à condition qu'au moins 2 groupes hydroxyle soient présents ;
    d) une ou plusieurs sources d'alcalinité, et
    e) un ou plusieurs adjuvants organiques et anorganiques sur une base non silicatée en une quantité comprise entre 8 et 45 % en poids ;
    la composition étant essentiellement exempte d'inhibiteurs de grisaillement sur base de cellulose, de silicates et de phosphates, c'est-à-dire que la teneur par rapport à l'ensemble de la composition est inférieure à 1 % en poids, et qu'elle présente à 25 °C une viscosité de 100 000 à 500 000 mPas à 5 tours par minute et une viscosité de 15 000 à 80 000 mPas à 50 tours par minute, mesurées chacune à l'aide d'un viscosimètre rotatif Brookfield (fuseau n° 7) dans des conditions par ailleurs identiques.
  2. Composition selon la revendication 1, caractérisée en ce qu'elle contient le tensioactif anionique en une quantité allant jusqu'à 15 % en poids, de préférence comprise entre 1,5 à 8 % en poids par rapport à l'ensemble de la composition.
  3. Composition selon la revendication 1 ou 2, caractérisée en ce qu'elle contient le composé de formule (II) en une quantité comprise entre 3 et 15 % en poids par rapport à l'ensemble de la composition.
  4. Composition selon les revendications 1 à 3, caractérisée en ce qu'elle contient de l'eau et/ou un composé de formule (III) en une quantité comprise entre 5 et 70 % en poids, la teneur en eau étant de préférence comprise entre 15 et 50 % en poids et la teneur du composé de formule (III) étant de préférence comprise entre 3 et 20 % en poids, plus préférablement entre 5 et 15 % en poids, toutes par rapport à l'ensemble de la composition.
  5. Composition selon les revendications 1 à 4, caractérisée en ce qu'elle contient la source d'alcalinité en une quantité comprise entre 10 et 30 % en poids, de préférence entre 15 et 25 % en poids par rapport à l'ensemble de la composition.
  6. Composition selon les revendications 1 à 5, caractérisée en ce qu'elle contient des adjuvants organiques et anorganiques en une quantité comprise entre 12 et 30 % en poids par rapport à l'ensemble de la composition.
  7. Composition selon les revendications 1 à 6, caractérisée en ce que l'alcoxylate dans l'alcoxylate d'alcool gras et/ou un alcoxylate d'alcool oxo est représenté par un éthoxylate et/ou un propoxylate.
  8. Procédé de lavage de textiles à l'aide de la composition selon les revendications 1 à 7.
  9. Procédé selon la revendication 8, caractérisé en ce que les eaux usées accumulées pendant tout le processus de lavage ou des parties de celui-ci sont purifiées à l'aide d'au moins une unité de filtration sur membrane.
  10. Procédé selon les revendications 8 ou 9, caractérisé en ce que le processus de filtration comprend au moins une étape d'osmose inverse.
  11. Utilisation de la composition selon les revendications 1 à 7 comme détergent dans une blanchisserie commerciale et/ou dans des machines à laver privées, comme agent de nettoyage et/ou comme agent de lavage de vaisselle.
EP04741675.5A 2004-05-28 2004-05-28 Composition savonneuse en pate compatible avec une membrane Active EP1749081B8 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2004/050959 WO2005118760A1 (fr) 2004-05-28 2004-05-28 Composition savonneuse en pate compatible avec une membrane

Publications (3)

Publication Number Publication Date
EP1749081A1 EP1749081A1 (fr) 2007-02-07
EP1749081B1 true EP1749081B1 (fr) 2019-09-04
EP1749081B8 EP1749081B8 (fr) 2019-10-16

Family

ID=34957716

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04741675.5A Active EP1749081B8 (fr) 2004-05-28 2004-05-28 Composition savonneuse en pate compatible avec une membrane

Country Status (2)

Country Link
EP (1) EP1749081B8 (fr)
WO (1) WO2005118760A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2118253B1 (fr) * 2007-03-12 2012-04-18 Ecolab Inc. Composition de savon en pâte à compatibilité membranaire avec des propriétés de démoussage améliorées
WO2011018337A1 (fr) 2009-08-12 2011-02-17 Unilever Plc Formulations de savon liquide concentrées ayant une viscosité facile à pomper
EP2519623B2 (fr) 2009-12-30 2019-03-20 Ecolab Inc. Produits de remplacement de phosphate pour des compositions de détergent et/ou de nettoyage compatibles avec des membranes
WO2013053383A1 (fr) 2011-10-11 2013-04-18 Ecolab Usa Inc. Récipient de pâte avec dispositif de dosage amélioré
WO2013071963A1 (fr) 2011-11-16 2013-05-23 Ecolab Usa Inc. Procédé de dosage déclenché par la température et dispositif de dosage d'une pâte de détergent
WO2013164492A1 (fr) 2012-07-13 2013-11-07 Basf Se Utilisation de tensioactifs alcoxylés non ioniques comme additifs dans des compositions de nettoyage aqueuses pour membrane
DE102014204389A1 (de) * 2014-03-11 2015-09-17 Henkel Ag & Co. Kgaa Verbesserte Tensidmischung mit optimiertem Ethoxylierungsgrad

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4428958A1 (de) * 1994-08-16 1996-02-22 Henkel Kgaa Flüssigwaschmittel mit Bleiche
DE19535082A1 (de) * 1995-09-21 1997-03-27 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Wasch- und Reinigungsmittel
DE19726287A1 (de) * 1997-06-20 1998-12-24 Henkel Ecolab Gmbh & Co Ohg Verfahren zum Waschen von Wäsche, insbesondere von Berufsbekleidung
DE19857687A1 (de) * 1998-12-15 2000-06-21 Henkel Ecolab Gmbh & Co Ohg Pastenförmiges Waschmittel
DE10061416A1 (de) * 2000-12-09 2002-06-20 Henkel Ecolab Gmbh & Co Ohg Alkalische, wasserhaltige Paste
WO2004041990A1 (fr) * 2002-11-06 2004-05-21 Unilever N.V. Composition de détergent à lessive en gel

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
A SZYMANSKI ET AL: "Biodegradation of Fatty Alcohol Ethoxylates under the Conditions of the Die-Away Test", POLISH JOURNAL OF ENVIRONMENTAL STUDIES, 1 January 2002 (2002-01-01), pages 429 - 433, XP055225630, Retrieved from the Internet <URL:http://www.pjoes.com/pdf/11.4/429-433.pdf> [retrieved on 20151104] *
INEOS: "Technical Data Sheet INEOS Oxide Technical Data Sheet @BULLET Lauryl Alcohol Ethoxylates Lauryl Alcohol Ethoxylates Industrial Applications", 1 January 2004 (2004-01-01), XP055225631, Retrieved from the Internet <URL:http://www.ineos.com/Show-Document?Grade=Alkyl Ether AE2&BU=INEOS Oxide&DocumentType=Technical Data Sheet> [retrieved on 20151104] *

Also Published As

Publication number Publication date
EP1749081A1 (fr) 2007-02-07
EP1749081B8 (fr) 2019-10-16
WO2005118760A1 (fr) 2005-12-15

Similar Documents

Publication Publication Date Title
CA2686008C (fr) Formulation de detergent liquide compatible avec les membranes, comprenant des alcools gras alcoxyles ramifies comme agents tensio-actifs non-ioniques
US3741911A (en) Phosphate-free detergent composition
EP2519623B2 (fr) Produits de remplacement de phosphate pour des compositions de détergent et/ou de nettoyage compatibles avec des membranes
EP1606383B1 (fr) Produit de lavage ou de nettoyage
WO2006003434A1 (fr) Particule
JPS6225196A (ja) 三成分界面活性剤系を含有する均一濃厚液体洗剤組成物
US11555164B2 (en) Alkaline hard surface cleaners comprising alkylpyrrolidones
EP1409623B1 (fr) Detergents pour lave-vaisselle comportant des tensioactifs faiblement visqueux
EP1749081B1 (fr) Composition savonneuse en pate compatible avec une membrane
WO2013155383A1 (fr) Composition de nettoyage pour laver la vaisselle
JP4870555B2 (ja) 濡れ性の組成物及びその使用法
JPS60152600A (ja) 石灰石けん分散組成物及びその使用方法
EP1409625B1 (fr) Detergents pour lave-vaisselle comportant des tensioactifs a coefficients de diffusion determines
EP2118253B1 (fr) Composition de savon en pâte à compatibilité membranaire avec des propriétés de démoussage améliorées
JP2010265333A (ja) 液体洗浄剤組成物
US7056876B2 (en) Alkaline, hydrous paste
EP1409624B1 (fr) Detergents pour lave-vaisselle comportant des tensioactifs a tension superficielle dynamique basse
EP1904613B1 (fr) Produits de nettoyage et d&#39;entretien presentant une emulsibilite amelioree
JP2001524589A (ja) 特殊な粘度挙動を示す食器洗浄用洗剤
DE4316746A1 (de) Phosphatfreie Maschinengeschirreinigungsmittel
EP1226226B1 (fr) Detergent pateux
CA2294204A1 (fr) Composition de nettoyage abrasive
DE4316743A1 (de) Klarspülmittel mit biologisch abbaubaren Polymeren
JP2011026430A (ja) 液体洗浄剤組成物
MXPA97006067A (en) Liquid compositions containing tenseactivos polyglucosid rent for industrial cleaning institute

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20061017

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20081201

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20190322

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1175354

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190915

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602004054218

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PK

Free format text: BERICHTIGUNG B8

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: ECOLAB USA INC.

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20190904

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191204

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20191205

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 1175354

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190904

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20200106

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602004054218

Country of ref document: DE

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

26N No opposition filed

Effective date: 20200605

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602004054218

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200531

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200531

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20200531

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20200528

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200528

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200528

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200531

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200528

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20201201

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190904