EP1747306B1 - Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre - Google Patents

Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre Download PDF

Info

Publication number
EP1747306B1
EP1747306B1 EP05737712.9A EP05737712A EP1747306B1 EP 1747306 B1 EP1747306 B1 EP 1747306B1 EP 05737712 A EP05737712 A EP 05737712A EP 1747306 B1 EP1747306 B1 EP 1747306B1
Authority
EP
European Patent Office
Prior art keywords
layer
synthetic
synthetic material
fibre
fibres
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05737712.9A
Other languages
German (de)
French (fr)
Other versions
EP1747306A1 (en
EP1747306B2 (en
Inventor
Frederik Jan Van Der Gaag
Marinus Hendrikus Olde Weghuis
Geurt Bastiaan Slootweg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ten Cate Thiolon BV
Original Assignee
Ten Cate Thiolon BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34965064&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1747306(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Ten Cate Thiolon BV filed Critical Ten Cate Thiolon BV
Publication of EP1747306A1 publication Critical patent/EP1747306A1/en
Publication of EP1747306B1 publication Critical patent/EP1747306B1/en
Application granted granted Critical
Publication of EP1747306B2 publication Critical patent/EP1747306B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/42Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C13/00Pavings or foundations specially adapted for playgrounds or sports grounds; Drainage, irrigation or heating of sports grounds
    • E01C13/08Surfaces simulating grass ; Grass-grown sports grounds
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2929Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]

Definitions

  • the invention relates to a method for producing a synthetic fibre for use in an artificial grass sports field according to claim 1.
  • the invention also relates to such a synthetic fibre and to an artificial lawn suitable for a sports field, consisting of a substrate to which synthetic fibres according to the invention are attached.
  • the layer of synthetic material may consist of a mixture of different synthetic materials, for example, with one synthetic material serving to give the fibre a certain strength (against breaking or splitting), whilst another synthetic material in the mixture provides the fibre with a certain elasticity or flexibility or better sliding properties.
  • a drawback of such existing synthetic fibres is the fact that, due to the homogeneous structure all (sub)properties of the fibre are homogeneously incorporated in the fibre. As a result, certain properties of the fibre may be less prominently present than is desirable, whilst other properties predominate more than is desirable. Therefore, the composition of the current fibres is usually standardized and often their production and material costs are unnecessarily high.
  • the object of the invention is therefore to provide a more universal fibre, which on the one hand can be produced for a specific use and which on the other hand saves production and material costs.
  • the layer of synthetic material is composed of at least two layers of different synthetic materials, using a co-extrusion process.
  • the co-extrusion step accomplishes a separation of the various properties of the synthetic materials that are used.
  • the synthetic fibre With a layered structure, it becomes possible to provide each layer with a function-specific property, which property does not need to be present elsewhere in the fibre, or needs to be present only to a markedly reduced degree. This makes it possible to select the formulation for the fibre specifically for a certain use, which, in addition to a more efficient material consumption, also results in a synthetic fibre with markedly improved playing and fibre properties than in the homogeneously composed known fibres.
  • the playing properties of the synthetic fibre are significantly improved by stretching the fibre after the co-extrusion process.
  • it is precisely the selection of materials after the stretching process that provides a fibre with such strength properties in a transverse direction that it will split less easily, for example.
  • a fibre When used in an artificial grass sports field, such a fibre, and consequently the artificial lawn, will have a much longer life, and the artificial lawn will require much less maintenance, thus remaining playable longer. Furthermore, the risk of injury of the players is considerably reduced.
  • the fibre may consist of at least one or of several twined monofilaments.
  • the fibre may be formed as a band, and more in particular the band fibre may be formed as a fibrillated band fibre.
  • the layer of synthetic material is composed of a core layer of a first synthetic material, which core layer is surrounded on both sides by one or several outer layers, each consisting of a different synthetic material.
  • each layer of synthetic material has a function-specific property, which is not necessary or not functional elsewhere in the fibre.
  • the layers may have different thicknesses, depending on the desired function-specific properties of the synthetic fibre to be obtained.
  • the first synthetic material consists of a mixture of a polymer and a plastomer, in which in particular the ratio of the plastomer in the core layer is 30-80 wt.% and more in particular the ratio of the plastomer in the core layer is 30-50 wt.%.
  • At least one of the other synthetic materials may comprise a hydrophilic additive.
  • the artificial grass fibre thus obtained has this function-specific characteristic that it can absorb moisture (water). This will keep the artificial grass sports field moist longer, which has a positive effect on playing behaviour (slides etc.). When the field is played on, the absorbed moisture is released, the same as with natural grass.
  • hydrophilic additive that can be used as the top layer or outer layer of the co-extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the copolymer, this polymer is capable of absorbing much water.
  • hydrophilic additive is the use of polyhydroxyethyl methylacrylate.
  • At least one of the other synthetic materials may comprise an antistatic additive.
  • any static electricity generated when the field is played on can discharge.
  • the strewing material between the fibres which is used in many artificial grass sports fields, is statically charged during play and as a result migrates upwards in the field.
  • the granular strewing material can be spread through the air, which is less pleasant during play.
  • the antistatic additive furthermore ensures that no static discharges will take place via the players.
  • the antistatic additive may be a polymer, especially a permanent antistatic, such as a polyamide or a polyether block amide.
  • the additive is a polyester block copolymer.
  • the fibres (10, 20, 30, 40) have been obtained from a foil of a synthetic material, which foil, obtained by co-extrusion, is composed of at least two layers of different synthetic materials (11, 12) as shown in Fig. 1A .
  • the layered structure of the synthetic fibre (10, 20, 30, 40) according to the invention makes it possible to provide each layer (sub-layers 11 and 12 in this embodiment) with a function-specific property.
  • the use of a synthetic material having a specific property in a particular part of the synthetic fibre obviates or strongly reduces the need for the presence of this synthetic material and the related function-specific property elsewhere in the fibre.
  • the sub-layer 11 which in principle provides the synthetic fibre with the required mechanical strength (and rigidity) and which in particular non-splitting properties such that the synthetic fibre used for the artificial grass sports field will not split as a result of being played on.
  • the synthetic fibre 20 is built up of three layers of three different synthetic materials indicated by reference numerals 21, 22, 23.
  • the middle layer 21 is made of an inexpensive synthetic material that is to give the fibre 20 its mechanical strength, whilst the outer layers 22 and 23 may be made of different synthetic materials, each of which may exhibit a different function-specific property, which property comes out best on the outer side of the synthetic fibre rather than in the centre.
  • the outer layers 21 and 22 may have an elastic property, for example, contrary to the inner layer 21, which provides the fibre with a certain rigidity (against breaking or splitting), which elastic property of the outer layer 21 or 22 has a positive effect on the playing properties of the artificial grass sports field.
  • FIG. 1C shows an embodiment in which the outer layers 32A and 32B are made of the same synthetic material.
  • Fig. 1D shows a further, more complex layered structure of a synthetic fibre according to the invention.
  • a layered synthetic fibre made up of a central core 41 and surrounded by different types of outer layers 42A-42B or 43A-43B, respectively, is obtained.
  • the synthetic fibre contrary to the known synthetic fibres, does not have a homogeneous structure in which all different synthetic materials and the related properties are homogeneously incorporated in the fibre.
  • certain properties of the fibre may be present less prominently than is desirable, whereas other properties are now predominantly present than desired.
  • the inner layers 11, 21, 31 and 41 may be made of a more inexpensive synthetic material that in principle provides the fibre with a certain strength against breaking or splitting.
  • the outer layers 12, 22, 32, 32A-32B, 42A-42B and 43A-43B may be made of a synthetic material that does not necessarily need to be present in the fibre core.
  • a specific embodiment may be made up of an outer layer built up of an antistatic additive.
  • the antistatic additive prevents the fibre from being charged by means of static electricity generated as a result of the artificial grass sports field being played on. Contrarily, the antistatic additive precisely ensures that the generated static electricity can discharge from the artificial grass sports field and, for example, will not discharge via the players, which can lead to unpleasant experiences.
  • a granular strewing material (usually made of a rubber-like material) is used, which, due to the static electricity that is generated, migrates upward in the artificial grass sports field and which is spread through the air as a result of the field being played on.
  • the airborne granular strewing material has a disturbing effect on the players.
  • the antistatic additive in particular is a permanent antistatic, possibly a polymer, such as a polyamide or polyether block amide.
  • the additive is a polyester block copolymer.
  • one of the outer layers (or both outer layers) (12, 22-23, 32a-32b, 43a-43b) may comprise a hydrophilic additive.
  • the artificial grass fibre thus obtained has the function-specific characteristic that it can absorb moisture (water) from the atmosphere, such as rain. This makes the artificial grass sports field remain moist longer, just like a natural-lawn sports field, which has a positive effect on the playing behaviour in particular when sliding etc. While the field is being played on, the absorbed moisture is released, the same as with natural grass.
  • hydrophilic additive that can be used as the top layer or outer layer (12, 22-23, 32a-32b, 43a-43b) of the co-extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the copolymer, this copolymer can absorb much water.
  • This water can be absorbed from the air (in the form of rain, fog, etc.) or can be supplied by an active sprinkler installation. (Often, artificial grass sports fields are sprinkled just before they are played on.)
  • the absorbed water is released again, which reduces the risk of injury, for example when sliding. Furthermore, the absorbed water keeps the temperature of the field lower, since an artificial grass sports field can be heated by the sun, under adverse conditions to temperatures as high as 70 °C.
  • a hydrophilic additive as the outer layer uses polyhydroxyethyl methacrylate.
  • a five-layer co-extrusion configuration is required, as shown in Fig. 1D .
  • the layers 32a-42b are bonding layers for the hydrophilic layer 43a-43b to the central layer 41 in that case.
  • the various layers of the artificial grass fibre are shown to have different thicknesses.
  • the bonding layer 42a-42b is considerably thinner than shown, usually it is 1-5% of the total fibre thickness, whilst the other layers 41-43a-43b are considerably thicker. If polyethylene is used as the middle layer 11-21-31-41, ethylene vinyl alcohol copolymer functioning as the hydrophilic additive will bond to the middle layer without any filling bonding layers being used.
  • Figs. 2A and 2B show a few embodiments of an artificial grass sports field in which a synthetic fibre according to the invention can be applied.
  • the artificial grass sports field comprises a substrate 1, to which several synthetic fibres 2 as obtained by using the method according to the invention are attached at the locations indicated by reference numeral 3, for example by tufting.
  • the synthetic fibre 2 has been obtained from a layer of synthetic material, which material has been produced from at least two different synthetic materials by means of a co-extrusion process.
  • the synthetic fibre may be individually attached to the substrate or as a bundle of, for example intertwined fibres 2a-2c. More in particular, the fibre that is obtained by co-extrusion can be a fibrillated band fibre.
  • the synthetic fibre according to the invention may be a monofilament. Also in this case, several monofilaments may be twined to form a bundle, after which each bundle is attached to the substrate 1.
  • the substrate has an open structure and is composed of a grid of supporting yarns 1a-1b, to which the synthetic fibres 2 are attached.

Description

  • The invention relates to a method for producing a synthetic fibre for use in an artificial grass sports field according to claim 1.
  • The invention also relates to such a synthetic fibre and to an artificial lawn suitable for a sports field, consisting of a substrate to which synthetic fibres according to the invention are attached.
  • Currently, synthetic materials are being used for various purposes. Especially the use of various sorts of synthetic materials in artificial lawns for sports fields has markedly increased in recent years. One fibre is known from EP259940 , which describes a strip-like thread that may be produced by co-extrusion of a number of films.
  • Research in this regard has in particular been concentrated on the development of synthetic fibres for use in artificial lawns for sports fields, in which fibres of a particular length are attached to a substrate, for example by tufting. The development of artificial grass fibres and artificial grass sports fields derived therefrom has progressed so far that it is now possible to construct artificial grass sports fields which are very difficult to distinguish from natural grass sports fields, not only as regards the way they look but also, and in particular, as regards the way they function during play.
  • Unlike natural grass sports fields, artificial grass sports fields can be played on longer and more intensively, irrespective of the weather conditions. Currently, the development of new artificial grass fibres is particularly focussed on obtaining a fibre which will further reduce the incidence of injuries such as grazes and burns caused by
    sliding or twisted joints.
  • Existing fibres specifically developed for artificial grass sports field are obtained from a layer of synthetic material, for example by means of a cutting operation. The layer of synthetic material may consist of a mixture of different synthetic materials, for example, with one synthetic material serving to give the fibre a certain strength (against breaking or splitting), whilst another synthetic material in the mixture provides the fibre with a certain elasticity or flexibility or better sliding properties.
  • A drawback of such existing synthetic fibres is the fact that, due to the homogeneous structure all (sub)properties of the fibre are homogeneously incorporated in the fibre. As a result, certain properties of the fibre may be less prominently present than is desirable, whilst other properties predominate more than is desirable. Therefore, the composition of the current fibres is usually standardized and often their production and material costs are unnecessarily high.
  • The object of the invention is therefore to provide a more universal fibre, which on the one hand can be produced for a specific use and which on the other hand saves production and material costs. According to the invention, the layer of synthetic material is composed of at least two layers of different synthetic materials, using a co-extrusion process.
  • The co-extrusion step accomplishes a separation of the various properties of the synthetic materials that are used. By providing the synthetic fibre with a layered structure, it becomes possible to provide each layer with a function-specific property, which property does not need to be present elsewhere in the fibre, or needs to be present only to a markedly reduced degree. This makes it possible to select the formulation for the fibre specifically for a certain use, which, in addition to a more efficient material consumption, also results in a synthetic fibre with markedly improved playing and fibre properties than in the homogeneously composed known fibres.
  • According to the invention, the playing properties of the synthetic fibre are significantly improved by stretching the fibre after the co-extrusion process. Apart from an increase in length, according to the invention it is precisely the selection of materials after the stretching process that provides a fibre with such strength properties in a transverse direction that it will split less easily, for example. When used in an artificial grass sports field, such a fibre, and consequently the artificial lawn, will have a much longer life, and the artificial lawn will require much less maintenance, thus remaining playable longer. Furthermore, the risk of injury of the players is considerably reduced.
  • According to the invention, the fibre may consist of at least one or of several twined monofilaments. The fibre may be formed as a band, and more in particular the band fibre may be formed as a fibrillated band fibre.
  • In a first functional embodiment of the process according to the invention, the layer of synthetic material is composed of a core layer of a first synthetic material, which core layer is surrounded on both sides by one or several outer layers, each consisting of a different synthetic material.
  • Thus a functional separation of the different properties of the different synthetic materials can be achieved, in which each layer of synthetic material has a function-specific property, which is not necessary or not functional elsewhere in the fibre.
  • The layers may have different thicknesses, depending on the desired function-specific properties of the synthetic fibre to be obtained.
  • In a first embodiment, the first synthetic material consists of a mixture of a polymer and a plastomer, in which in particular the ratio of the plastomer in the core layer is 30-80 wt.% and more in particular the ratio of the plastomer in the core layer is 30-50 wt.%. This results in a fibre having a core layer which, from a function-specific viewpoint, exhibits a very favourable non-splitting behaviour.
  • In another embodiment, at least one of the other synthetic materials may comprise a hydrophilic additive. The artificial grass fibre thus obtained has this function-specific characteristic that it can absorb moisture (water). This will keep the artificial grass sports field moist longer, which has a positive effect on playing behaviour (slides etc.). When the field is played on, the absorbed moisture is released, the same as with natural grass.
  • An example of a hydrophilic additive that can be used as the top layer or outer layer of the co-extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the copolymer, this polymer is capable of absorbing much water.
  • Another embodiment of a hydrophilic additive is the use of polyhydroxyethyl methylacrylate.
  • In yet another embodiment, at least one of the other synthetic materials may comprise an antistatic additive. As a result, any static electricity generated when the field is played on can discharge. Usually, the strewing material between the fibres, which is used in many artificial grass sports fields, is statically charged during play and as a result migrates upwards in the field. Thus, the granular strewing material can be spread through the air, which is less pleasant during play.
  • The antistatic additive furthermore ensures that no static discharges will take place via the players.
  • More specifically, the antistatic additive may be a polymer, especially a permanent antistatic, such as a polyamide or a polyether block amide. In another embodiment, the additive is a polyester block copolymer.
  • The invention will now be explained in more detail with reference to a drawing, in which:
    • Figs. 1A-1D show different embodiments of a synthetic fibre according to the invention;
    • Figs. 2A and 2B schematically show a few embodiments of an artificial grass sports field provided with a synthetic fibre obtained by using the method according to the invention.
  • The fibres (10, 20, 30, 40) have been obtained from a foil of a synthetic material, which foil, obtained by co-extrusion, is composed of at least two layers of different synthetic materials (11, 12) as shown in Fig. 1A. Contrary to the currently known synthetic fibres, which are composed of a homogeneous mixture of synthetic materials, the layered structure of the synthetic fibre (10, 20, 30, 40) according to the invention makes it possible to provide each layer ( sub-layers 11 and 12 in this embodiment) with a function-specific property. As a result, the use of a synthetic material having a specific property in a particular part of the synthetic fibre obviates or strongly reduces the need for the presence of this synthetic material and the related function-specific property elsewhere in the fibre.
  • For example, it is possible to use a synthetic material for the sub-layer 11 which in principle provides the synthetic fibre with the required mechanical strength (and rigidity) and which in particular non-splitting properties such that the synthetic fibre used for the artificial grass sports field will not split as a result of being played on.
  • In another embodiment as shown in Fig. 1B, the synthetic fibre 20 is built up of three layers of three different synthetic materials indicated by reference numerals 21, 22, 23. The middle layer 21 is made of an inexpensive synthetic material that is to give the fibre 20 its mechanical strength, whilst the outer layers 22 and 23 may be made of different synthetic materials, each of which may exhibit a different function-specific property, which property comes out best on the outer side of the synthetic fibre rather than in the centre.
  • Thus, the outer layers 21 and 22 may have an elastic property, for example, contrary to the inner layer 21, which provides the fibre with a certain rigidity (against breaking or splitting), which elastic property of the outer layer 21 or 22 has a positive effect on the playing properties of the artificial grass sports field.
  • Whereas in the embodiment in Fig. 1B the outer layers 22 and 23 may be made of different synthetic materials, Fig. 1C shows an embodiment in which the outer layers 32A and 32B are made of the same synthetic material.
  • Fig. 1D shows a further, more complex layered structure of a synthetic fibre according to the invention. By means of co-extrusion of different synthetic materials, a layered synthetic fibre made up of a central core 41 and surrounded by different types of outer layers 42A-42B or 43A-43B, respectively, is obtained.
  • The essence of the method according to the invention and the synthetic fibres according to the invention obtained thereby lie in the fact that the synthetic fibre, contrary to the known synthetic fibres, does not have a homogeneous structure in which all different synthetic materials and the related properties are homogeneously incorporated in the fibre. As a result of the homogeneous structure or composition of the existing artificial grass sports fields, certain properties of the fibre may be present less prominently than is desirable, whereas other properties are now predominantly present than desired.
  • Using the method according to the invention, it is possible to obtain synthetic fibres according to a specific formulation that, contrary to the standardized fibres, exhibit a function-specific property in certain parts of the fibre that is not considered necessary or desirable elsewhere in the fibre.
  • This enables a more efficient use of the various (synthetic) materials, which not only serves to reduce costs but also provides a more universal synthetic fibre according to the invention having markedly improved playing and fibre properties than in the homogeneously constructed known fibres. In this specific embodiment, the inner layers 11, 21, 31 and 41 may be made of a more inexpensive synthetic material that in principle provides the fibre with a certain strength against breaking or splitting. The outer layers 12, 22, 32, 32A-32B, 42A-42B and 43A-43B may be made of a synthetic material that does not necessarily need to be present in the fibre core.
  • In this context, a specific embodiment may be made up of an outer layer built up of an antistatic additive. The antistatic additive prevents the fibre from being charged by means of static electricity generated as a result of the artificial grass sports field being played on. Contrarily, the antistatic additive precisely ensures that the generated static electricity can discharge from the artificial grass sports field and, for example, will not discharge via the players, which can lead to unpleasant experiences.
  • In addition, in most artificial grass sports fields a granular strewing material (usually made of a rubber-like material) is used, which, due to the static electricity that is generated, migrates upward in the artificial grass sports field and which is spread through the air as a result of the field being played on. The airborne granular strewing material has a disturbing effect on the players.
  • The antistatic additive in particular is a permanent antistatic, possibly a polymer, such as a polyamide or polyether block amide. In another embodiment, the additive is a polyester block copolymer.
  • In another embodiment, one of the outer layers (or both outer layers) (12, 22-23, 32a-32b, 43a-43b) may comprise a hydrophilic additive. The artificial grass fibre thus obtained has the function-specific characteristic that it can absorb moisture (water) from the atmosphere, such as rain. This makes the artificial grass sports field remain moist longer, just like a natural-lawn sports field, which has a positive effect on the playing behaviour in particular when sliding etc. While the field is being played on, the absorbed moisture is released, the same as with natural grass.
  • An example of a hydrophilic additive that can be used as the top layer or outer layer (12, 22-23, 32a-32b, 43a-43b) of the co-extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the copolymer, this copolymer can absorb much water.
  • The middle layer (11, 21, 31, 41) in this case gives the fibre its strength, whilst the relatively thin top layer (12, 22-23, 32a-32b, 43a-43b) absorbs water. This water can be absorbed from the air (in the form of rain, fog, etc.) or can be supplied by an active sprinkler installation. (Often, artificial grass sports fields are sprinkled just before they are played on.)
  • During play, the absorbed water is released again, which reduces the risk of injury, for example when sliding. Furthermore, the absorbed water keeps the temperature of the field lower, since an artificial grass sports field can be heated by the sun, under adverse conditions to temperatures as high as 70 °C.
  • Another embodiment of a hydrophilic additive as the outer layer (12, 22-23, 32a-32b, 43a-43b) uses polyhydroxyethyl methacrylate. In order to prevent bonding problems to the middle layer (11, 21, 31, 41), a five-layer co-extrusion configuration is required, as shown in Fig. 1D. The layers 32a-42b are bonding layers for the hydrophilic layer 43a-43b to the central layer 41 in that case.
  • For illustration purposes, the various layers of the artificial grass fibre (as shown in Figs. 1A-1D) are shown to have different thicknesses. The thicknesses as shown, however, do not correspond to the actual thicknesses of the produced artificial grass fibres in any way.
  • In the embodiment in Fig. 1D, the bonding layer 42a-42b is considerably thinner than shown, usually it is 1-5% of the total fibre thickness, whilst the other layers 41-43a-43b are considerably thicker. If polyethylene is used as the middle layer 11-21-31-41, ethylene vinyl alcohol copolymer functioning as the hydrophilic additive will bond to the middle layer without any filling bonding layers being used.
  • Figs. 2A and 2B show a few embodiments of an artificial grass sports field in which a synthetic fibre according to the invention can be applied. In both figures, the artificial grass sports field comprises a substrate 1, to which several synthetic fibres 2 as obtained by using the method according to the invention are attached at the locations indicated by reference numeral 3, for example by tufting. The synthetic fibre 2 has been obtained from a layer of synthetic material, which material has been produced from at least two different synthetic materials by means of a co-extrusion process. The synthetic fibre may be individually attached to the substrate or as a bundle of, for example intertwined fibres 2a-2c. More in particular, the fibre that is obtained by co-extrusion can be a fibrillated band fibre.
  • In another embodiment, as shown in Fig. 2B, the synthetic fibre according to the invention may be a monofilament. Also in this case, several monofilaments may be twined to form a bundle, after which each bundle is attached to the substrate 1. In Fig. 2B, the substrate has an open structure and is composed of a grid of supporting yarns 1a-1b, to which the synthetic fibres 2 are attached.

Claims (20)

  1. A method for producing a synthetic fibre (10, 20, 30, 40) for use in an artificial grass sports field using a co-extrusion process, comprising the steps of:
    i. supplying a first synthetic material;
    ii. supplying at least a second synthetic material;
    iii. composing by co-extrusion a layer of synthetic material consisting of at least a layer of first synthetic material (11, 21, 31, 41) and a layer of said second synthetic material (12, 22, 32, 42), wherein the layer of synthetic material is composed of an inner layer of said first synthetic material and one or more outer layers, each layer consisting of a different synthetic material
    iv. obtaining the synthetic fibre from the layer of synthetic material,
    characterized in that after step iii) the layer of synthetic material is stretched.
  2. A method according to claims 1, characterized in that after step iii) fibres in the form of at least one monofilament are obtained from the layer of synthetic material.
  3. A method according to claim 2, characterized by the further step of twining the fibre from several monofilaments.
  4. A method according to claim 1, characterized in that after step iii) the fibre is obtained from the layer of synthetic material in the form of a band.
  5. A method according to claim 4, characterized by the further step of fibrillating the band fibre.
  6. A method according to claim 1, characterized in that during step iii) the layers are composed having different thicknesses.
  7. A method according to any one or more of the preceding claims, characterized in that step i) comprises the step of supplying the first synthetic material as a mixture of a polymer and a plastomer.
  8. A method according to claim 7, characterized in that the plastomer is being supplied with the ratio of the plastomer in the first synthetic material being 30-80 wt.%.
  9. A method according to claim 8, characterized in that the plastomer is being supplied with the ratio of the plastomer in the core layer being 35-50 wt.%.
  10. A method according to any one or more of the preceding claims, characterized in that step ii) consists of supplying a hydrophilic additive as at least one of the other synthetic materials.
  11. A method according to claim 10, characterized in that the hydrophilic additive being supplied is an ethylene vinyl alcohol co-polymer.
  12. A method according to claim 11, characterized in that the hydrophilic additive being supplied is a polyhydroxyethyl methacrylate.
  13. A method according to any one or more of the preceding claims, characterized in that step ii) comprises the step of supplying an antistatic additive as at least one of the other synthetic materials.
  14. A method according to claim 13, characterized in that the antistatic additive being supplied is a polymer, in particular a polyamide or a polyether block amide.
  15. A method according to any one or more of the claims 1-14, characterized in that step ii) comprises the step of supplying a further bonding layer between the inner layer and each of said outer layers.
  16. A method according to any one or more of the preceding claims, characterized in that the layer of synthetic material is composed of an inner layer of said first synthetic material, which inner layer is surrounded on both sides by one or more outer layers, each layer consisting of a different synthetic material.
  17. A synthetic fibre obtained by using the method according to any one or more of the preceding claims, said synthetic fibre being composed of a layer of synthetic material, wherein said layer is composed of an inner layer of a first synthetic material and one or more outer layers, each layer consisting of a different synthetic material.
  18. An artificial lawn suitable for sports fields, provided with synthetic fibres according to claim 17.
  19. An artificial lawn according to claim 18, characterized in that the lawn comprises a substrate to which the synthetic fibres have been attached.
  20. An artificial lawn according to claim 18 or 19, characterized in that a granular material has been strewn between the synthetic fibres.
EP05737712.9A 2004-05-19 2005-04-11 Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre Active EP1747306B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL1026239A NL1026239C2 (en) 2004-05-19 2004-05-19 Method for manufacturing a plastic fiber for use in an artificial grass sports field as well as such a plastic fiber.
PCT/NL2005/000275 WO2005111281A1 (en) 2004-05-19 2005-04-11 Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre

Publications (3)

Publication Number Publication Date
EP1747306A1 EP1747306A1 (en) 2007-01-31
EP1747306B1 true EP1747306B1 (en) 2016-09-28
EP1747306B2 EP1747306B2 (en) 2023-11-29

Family

ID=34965064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05737712.9A Active EP1747306B2 (en) 2004-05-19 2005-04-11 Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre

Country Status (12)

Country Link
US (1) US20100040808A1 (en)
EP (1) EP1747306B2 (en)
JP (1) JP2007538183A (en)
KR (1) KR20070035003A (en)
CN (1) CN1961101B (en)
AU (1) AU2005243347A1 (en)
EA (1) EA008915B1 (en)
ES (1) ES2608853T3 (en)
FI (1) FI1747306T4 (en)
NL (1) NL1026239C2 (en)
PT (1) PT1747306T (en)
WO (1) WO2005111281A1 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE459758T1 (en) * 2003-05-28 2010-03-15 Lankhorst Pure Composites Bv YARN FOR ARTIFICIAL GRASS, GROUND COVER AND PLAYING FIELD CONTAINING THE SAME, AND METHOD
NL1026444C2 (en) * 2004-06-17 2005-12-20 Ten Cate Thiolon Bv Artificial grass sports field provided with an infill material as well as such an infill material.
ES2315830T3 (en) * 2005-12-30 2009-04-01 Mondo S.P.A. PROCEDURE TO PRODUCE A THREAD FOR SYNTHETIC LAWN AND SYNTHETIC LAWN STRUCTURE PRODUCED USING THESE THREAD.
NL1032719C2 (en) * 2006-10-23 2008-04-25 Ten Cate Thiolon Bv Artificial grass fiber and an artificial grass field provided with at least one such artificial grass fiber.
EP1983103B1 (en) * 2007-04-19 2014-02-19 Reifenhäuser GmbH & Co. KG Maschinenfabrik Synthetic turf
NL1033949C2 (en) * 2007-06-07 2008-12-09 Desseaux H Tapijtfab Artificial grass constructed from fibers consisting of a core and a mantle, as well as an artificial grass field built from it.
NL1035682C2 (en) 2008-07-10 2010-01-12 Desseaux H Tapijtfab Synthetic turf field.
NL1036418C2 (en) 2009-01-14 2010-07-15 Ten Cate Thiolon Bv PLASTIC FIBER AND AN ARTIFICIAL GRASS FIELD WITH SUCH FIBER.
CN101476174B (en) * 2009-01-20 2011-11-30 江苏共创人造草坪有限公司 Enhanced artificial lawn fibre and preparation thereof
DE102009052848A1 (en) 2009-11-11 2011-05-12 Oerlikon Textile Gmbh & Co. Kg Method for melt spinning monofilament optical fibers made from two different polymer melts, involves generating two different polymer melts by two separate extruders, and extruding polymer melts by spinning nozzle
EP2374917B1 (en) 2010-04-07 2013-02-13 Dow Global Technologies LLC Artificial turf yarn
US10323361B1 (en) * 2011-06-12 2019-06-18 Dale Karmie Synthetic turf system made with antistatic yarns and method of making
CN103764915B (en) * 2011-07-01 2017-03-08 腾凯特塞奥隆公司 Synthetic fibers and the chinampa comprising this fiber
WO2013046494A1 (en) * 2011-09-30 2013-04-04 住友ゴム工業株式会社 Artificial turf and artificial turf facility
EP2682157A1 (en) 2012-07-06 2014-01-08 Peter Osypka Stiftung Mapping electrode for the left atrium of the heart
CN103014898B (en) * 2013-01-07 2014-11-12 江苏共创人造草坪有限公司 Artificial grass fiber with hydrophilic surface and artificial turf
CN103061233B (en) * 2013-01-28 2015-05-06 广州爱奇实业有限公司 Production technology of artificial turf
NL1040263C2 (en) 2013-06-19 2014-12-22 Micronext B V Cool artificial turf.
EP3480361A1 (en) * 2017-11-03 2019-05-08 Polytex Sportbeläge Produktions-GmbH Artificial turf fiber with a non-circular cladding
CN107988655B (en) * 2017-12-29 2020-08-18 广州爱奇实业有限公司 Grass silk fiber, preparation method thereof and simulated lawn prepared by adopting grass silk fiber
AU2020347835A1 (en) 2019-09-16 2022-05-12 Mattex Dubai LLC Water-retaining artificial turf
KR102357998B1 (en) * 2021-07-09 2022-02-08 주식회사 지에스티지 Artificial grass composed to have characteristic of natural grass and method for making the same
KR102419294B1 (en) * 2021-09-13 2022-07-12 주식회사 지에스티지 Artificial grass with improved durability and length accuracy composed to have characteristic of natural grass and method for making the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259940A2 (en) 1986-09-12 1988-03-16 Koninklijke Nijverdal-Ten Cate N.V. Method of manufacturing an artificial grass and an artificial grass obtained therewith
EP0301843A1 (en) 1987-07-27 1989-02-01 Bonar Textiles Limited Mat and method of manufacture
EP0417832A1 (en) 1989-09-05 1991-03-20 Tapijtfabriek H. Desseaux N.V. Method for producing yarn for fields of artificial grass and field of artificial grass produced with this yarn
WO1999004074A1 (en) 1997-07-17 1999-01-28 Tapijtfabriek H. Desseaux N.V. A yarn for articifial grass, a method of manufacturing said yarn and a field of artificial grass in which said yarn is incorporated
WO2004106601A1 (en) 2003-05-28 2004-12-09 Lankhorst Indutech B.V. Yarn for an artificial turf ground cover, artificial turf ground cover and playing field including such a yarn and method for producing such a yarn

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1180403A (en) * 1966-02-11 1970-02-04 Toyo Rayon Co Ltd Polyamide Resin Composition
US3565742A (en) * 1967-07-17 1971-02-23 Monsanto Co Flocked golf green
US4044179A (en) * 1975-11-18 1977-08-23 Mod-Sod Sport Surfaces Playing surface for athletic games
JPS56161019A (en) * 1980-05-16 1981-12-11 Toray Industries Antistatic artificial turf
US4337283A (en) * 1980-09-11 1982-06-29 Haas Jr Frederick T Synthetic turf playing surface with resilient top-dressing
JPS63302027A (en) * 1987-06-03 1988-12-08 Daiyatetsukusu Kk Net-shaped sheet
KR900007643B1 (en) * 1988-08-09 1990-10-17 영진약품공업 주식회사 Novel microorganism streptomyces sp.y-125
JP2837764B2 (en) * 1991-04-17 1998-12-16 三菱レイヨン株式会社 Artificial grass
EP0679487A1 (en) * 1994-04-28 1995-11-02 W.R. Grace & Co.-Conn. Multi-layer polyolefin film containing recycle polymer from cross-linked films
ATE195460T1 (en) * 1995-12-01 2000-09-15 Lankhorst Indutech Bv COEXTRUDED THREAD OR TAPE
EP1378592A1 (en) * 2002-07-01 2004-01-07 Ten Cate Thiolon B.V. Artificial fibre as well as an artificial lawn for sports fields provided with such fibre
US7713636B2 (en) * 2006-12-15 2010-05-11 Exxonmobil Chemical Patents Inc. Multi-layer films comprising propylene-based polymers

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0259940A2 (en) 1986-09-12 1988-03-16 Koninklijke Nijverdal-Ten Cate N.V. Method of manufacturing an artificial grass and an artificial grass obtained therewith
EP0301843A1 (en) 1987-07-27 1989-02-01 Bonar Textiles Limited Mat and method of manufacture
EP0417832A1 (en) 1989-09-05 1991-03-20 Tapijtfabriek H. Desseaux N.V. Method for producing yarn for fields of artificial grass and field of artificial grass produced with this yarn
WO1999004074A1 (en) 1997-07-17 1999-01-28 Tapijtfabriek H. Desseaux N.V. A yarn for articifial grass, a method of manufacturing said yarn and a field of artificial grass in which said yarn is incorporated
WO2004106601A1 (en) 2003-05-28 2004-12-09 Lankhorst Indutech B.V. Yarn for an artificial turf ground cover, artificial turf ground cover and playing field including such a yarn and method for producing such a yarn

Also Published As

Publication number Publication date
AU2005243347A1 (en) 2005-11-24
ES2608853T3 (en) 2017-04-17
CN1961101A (en) 2007-05-09
CN1961101B (en) 2012-08-22
EA008915B1 (en) 2007-08-31
EP1747306A1 (en) 2007-01-31
EA200602146A1 (en) 2007-04-27
KR20070035003A (en) 2007-03-29
WO2005111281A1 (en) 2005-11-24
PT1747306T (en) 2017-01-03
JP2007538183A (en) 2007-12-27
US20100040808A1 (en) 2010-02-18
EP1747306B2 (en) 2023-11-29
NL1026239C2 (en) 2005-11-22
FI1747306T4 (en) 2024-02-01

Similar Documents

Publication Publication Date Title
EP1747306B1 (en) Method for producing a synthetic fibre for use in an artificial grass sports field and such a synthetic fibre
US8568852B2 (en) Artificial grass turf and infill for sports fields
JP6483846B2 (en) Artificial lawn and manufacturing method
CN101166869A (en) Synthetic turf system having an infill trapping structure
KR101481144B1 (en) An artificial grass fibre as well as an artificial lawn at laest comprising such an artificial grass fibre
US6815059B2 (en) Artificial fibre as well as an artificial lawn for sports fields provided with such fibre
KR101566534B1 (en) An artificial lawn in particular for an artificial grass sports field
SU660601A3 (en) Nonwoven net
US8273424B2 (en) Artificial grass field
TW200909635A (en) Insecticidal thread
CN1820095A (en) Yarn for artificial turf ground cover, artificial turf ground cover and playing field including such a yarn and method for producing it
WO2006085751A1 (en) Artificial fibre for use in an artificial grass sport field
AU2011221358B2 (en) Method For Producing A Synthetic Fibre For Use In An Artificial Grass Sports Field And Such A Synthetic Fibre
EP2520696A1 (en) Synthetic fiber for artificial turf system
US20220341091A1 (en) Water-retaining artificial turf
AU2014201150B2 (en) An artificial lawn, in particular for an artificial grass sports field

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20061113

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20070822

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

INTG Intention to grant announced

Effective date: 20160422

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 832842

Country of ref document: AT

Kind code of ref document: T

Effective date: 20161015

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602005050313

Country of ref document: DE

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Ref document number: 1747306

Country of ref document: PT

Date of ref document: 20170103

Kind code of ref document: T

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20161222

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 832842

Country of ref document: AT

Kind code of ref document: T

Effective date: 20160928

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161229

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2608853

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20170417

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602005050313

Country of ref document: DE

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20161228

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20170128

26 Opposition filed

Opponent name: OERLIKON TEXTILE GMBH & CO. KG

Effective date: 20170519

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20170417

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20160928

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170411

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170430

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170430

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170411

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20181011

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT; INVALID AB INITIO

Effective date: 20050411

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CY

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160928

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230519

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20230417

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20230426

Year of fee payment: 19

Ref country code: FR

Payment date: 20230420

Year of fee payment: 19

Ref country code: ES

Payment date: 20230627

Year of fee payment: 19

Ref country code: DE

Payment date: 20230420

Year of fee payment: 19

Ref country code: CZ

Payment date: 20230403

Year of fee payment: 19

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20230412

Year of fee payment: 19

Ref country code: FI

Payment date: 20230419

Year of fee payment: 19

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20230419

Year of fee payment: 19

PUAH Patent maintained in amended form

Free format text: ORIGINAL CODE: 0009272

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT MAINTAINED AS AMENDED

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20230419

Year of fee payment: 19

27A Patent maintained in amended form

Effective date: 20231129

AK Designated contracting states

Kind code of ref document: B2

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: DE

Ref legal event code: R102

Ref document number: 602005050313

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: FP

P04 Withdrawal of opt-out of the competence of the unified patent court (upc) registered

Effective date: 20240112