AU2011221358B2

AU2011221358B2 - Method For Producing A Synthetic Fibre For Use In An Artificial Grass Sports Field And Such A Synthetic Fibre

Info

Publication number: AU2011221358B2
Application number: AU2011221358A
Authority: AU
Inventors: Marinus Hendrikus Olde Weghuis; Geurt Bastiaan Slootweg; Frederik Jan Van Der Gaag
Original assignee: Ten Cate Thiolon BV
Current assignee: Ten Cate Thiolon BV
Priority date: 2004-05-19
Filing date: 2011-09-07
Publication date: 2012-08-30
Anticipated expiration: 2025-04-11
Also published as: AU2011221358A1

Abstract

214991/RV/jn A B S T R A C T The invention relates to a method for producing a synthetic fibre for use in an artificial grass sports field, comprising the steps of; 1) supplying a layer of synthetic material: and ii) obtaining the synthetic fibre from the layer of synthetic material. The invention also relates to such a synthetic fibre and to an artificial lawn suitable for sports fields, consisting of a substrate to which synthetic fibres according to the invention have been attached. The object of the invention is therefore to provide a more universal fibre, which on the one hand can be produced for a specific use and on the other hand saves on production and material costs. According to the invention, the layer of synthetic material is composed of at least two layers of different synthetic materials, using a co extrusion process. The co-extrusion step provides a separation of the different properties of the synthetic materials that are used.

Description

1A Regulation 3.2 AUSTRALIA PATENTS ACT, 1990 COMPLETE SPECIFICATION FOR A STANDARD PATENT ORIGINAL Name of Applicant: TEN CATE THIOLON B.V. Actual Inventors: VAN DER GAAG, Frederik Jan; OLDE WEGHUIS, Marinus Hendrikus; SLOOTWEG, Geurt Bastiaan Address for service in A J PARK, Level 11, 60 Marcus Clarke Street, Canberra ACT Australia: 2601, Australia Invention Title: Method For Producing A Synthetic Fibre For Use In An Artificial Grass Sports Field And Such A Synthetic Fibre The following statement is a full description of this invention, including the best method of performing it known to us. 34M5566 1 METHOD FOR PRODUCING A SYNTHETIC FIBRE FOR USE IN AN ARTIFICIAL GRASS SPORTS FIELD AND SUCH A SYNTHETIC FIBRE. DESCRIPTION 5 The invention relates to a method for producing a synthetic fibre, a synthetic fibre and an artificial lawn for use in an artificial grass sports field. Currently, synthetic materials are being used for various purposes. Especially the use of various sorts of synthetic materials in 10 artificial lawns for sports fields has markedly increased in recent years. Research in this regard has in particular been concentrated on the development of synthetic fibres for use in artificial lawns for sports fields, in which fibres of a particular 15 length are attached to a substrate, for example by tufting. The development of artificial grass fibres and artificial grass sports fields derived therefrom has progressed so far that it is now possible to construct artificial grass sports fields which are very difficult to distinguish from natural grass sports fields, not only as regards the 20 way they look but also, and in particular, as regards the way they function during play. Unlike natural grass sports fields, artificial grass sports fields can be played on longer and more intensively, irrespective of the weather conditions. Currently, the development of new artificial 25 grass fibres is particularly focussed on obtaining a fibre which will further reduce the incidence of injuries such as grazes and burns caused by sliding or twisted joints. Existing fibres specifically developed for artificial grass sports field are obtained from a layer of synthetic material, for 4 example by means of a cutting operation. The layer of synthetic material may consist of a mixture of different synthetic materials, for example, with one synthetic material serving to give the fibre a certain strength (against breaking or splitting), whilst another synthetic material in 5 the mixture provides the fibre with a certain elasticity or flexibility or better sliding properties. A drawback of such existing synthetic fibres is the fact that, due to the homogeneous structure all (sub)properties of the fibre are homogeneously incorporated in the fibre. As a result, certain 10 properties of the fibre may be less prominently present than is desirable, whilst other properties predominate more than is desirable. Therefore, the composition of the current fibres is usually standardized and often their production and material costs are unnecessarily high. It is an object of the present invention to provide a 15 synthetic fibre, artificial lawn and method therefor, which overcomes or at least partially ameliorates some of the abovementioned disadvantages or which at least provides the public with a useful choice. According to the invention, the playing properties of the 20 synthetic fibre can be significantly improved by stretching the fibre after the co-extrusion process. Apart from an increase in length, according to the invention it is precisely the selection of materials after the stretching process that provides a fibre with such strength properties in a transverse direction that it will split less easily, for 25 example. When used in an artificial grass sports field, such a fibre, and consequently the artificial lawn, will have a much longer life, and the artificial lawn will require much less maintenance, thus remaining playable longer. Furthermore, the risk of injury of the players is considerably reduced.

According to the invention, the fibre may consist of at least one or of several twined monofilaments. The fibre may be formed as a band, and more in particular the band fibre may be formed as a fibrillated band fibre. 5 In a first functional embodiment of the process according to the invention, the layer of synthetic material is composed of a core layer of a first synthetic material, which core layer is surrounded on both sides by one or several outer layers, each consisting of a different synthetic material. 10 Thus a functional separation of the different properties of the different synthetic materials can be achieved, in which each layer of synthetic material has a function-specific property, which is not necessary or not functional elsewhere in the fibre. The layers may have different thicknesses, depending on 15 the desired function-specific properties of the synthetic fibre to be obtained. In a first embodiment, the first synthetic material consists of a mixture of a polymer and a plastomer, in which in particular the ratio of the plastomer in the core layer is 30-80 wt.% 20 and more in particular the ratio of the plastomer in the core layer is 30-50 wt.%. This results in a fibre having a core layer which, from a function-specific viewpoint, exhibits a very favourable non-splitting behaviour. In another embodiment, at least one of the other synthetic 25 materials may comprise a hydrophilic additive. The artificial grass fibre thus obtained has this function-specific characteristic that it can absorb moisture (water). This will keep the artificial grass sports field moist longer, which has a positive effect on playing behaviour (slides etc.). When the field is played on, the absorbed moisture is -T released, the same as with natural grass. An example of a hydrophilic additive that can be used as the top layer or outer layer of the co-extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the 5 copolymer, this polymer is capable of absorbing much water. Another embodiment of a hydrophilic additive is the use of polyhydroxyethyl methylacrylate. In yet another embodiment, at least one of the other synthetic materials may comprise an antistatic additive. As a result, 10 any static electricity generated when the field is played on can discharge. Usually, the strewing material between the fibres, which is used in many artificial grass sports fields, is statically charged during play and as a result migrates upwards in the field. Thus, the granular strewing material can be spread through the air, which is less 15 pleasant during play. The antistatic additive furthermore ensures that no static discharges will take place via the players. More specifically, the antistatic additive may be a polymer, especially a permanent antistatic, such as a polyamide or a 20 polyether block amide. In another embodiment, the additive is a polyester block copolymer. In another aspect, the invention may be said to consist in a method for producing a synthetic fibre for use in an artificial grass sports field using a co-extrusion process, comprising the steps of: 25 supplying a first synthetic material; supplying at least a second synthetic material and at least a third synthetic material; composing by co-extrusion a layer of synthetic material defining said synthetic fibre, consisting of at least a layer of first synthetic material and a layer of said second synthetic material and a layer of said third synthetic material, wherein the layer of synthetic material is composed of a core layer of said first synthetic material, which core layer is surrounded on both sides by at least two outer layers, each of 5 said at least two outer layers consisting of a different synthetic material with respect to each other, and each having a function specific property. Preferably, after step iii) the layer of synthetic material is stretched. 10 Preferably, the fibre consists of at least one monofilament. Preferably, the fibre consists of several twined monofilaments. Preferably, the fibre is in the form of a band. Preferably, the band fibre is a fibrillated band fibre. Preferably, the layers have different thicknesses. 15 Preferably, the first synthetic material consists of a mixture of a polymer and a plastomer. Preferably, the ratio of the plastomer in the core layer is 30-80 wt.%. Preferably, the ratio of the plastomer in the core layer is 35-50 wt.%. Preferably, at least one of the other synthetic materials comprises a 20 hydrophilic additive. Preferably, the hydrophilic additive is an ethylene vinyl alcohol co polymer. Preferably, the hydrophilic additive is a polyhydroxyethyl methacrylate. Preferably, at least one of the other synthetic materials comprises an 25 antistatic additive. Preferably, the antistatic additive is a polymer, in particular a polyamide or a polyether block amide. Preferably, between the core layer and each of said at least two outer layers, a further bonding player is present.

U In a further aspect, the invention may be said to consist in a synthetic fibre obtained by using the method described above. In a further aspect, the invention may be said to consist in a synthetic 5 fibre obtained by using the method described above, said synthetic fibre being composed of a layer of synthetic material, wherein said layer is composed of core layer of a first synthetic material, which core layer is surrounded on both sides by at least two outer layers, each of said at least two outer layers consisting of a different synthetic material 10 each having a function specific property. In a further aspect, the invention may be said to consist in an artificial lawn suitable for sports fields, provided with synthetic fibres described above. In a further aspect, the invention may be said to consist in an 15 artificial lawn suitable for sports fields, provided with synthetic fibres described above, said synthetic fibre being composed of a layer of synthetic material, wherein said layer is composed of a core layer of a first synthetic material, which core layer is surrounded on both sides by at least two outer layers, each of said at least two outer layers 20 consisting of a different synthetic material, each having a function specific property. Preferably, the lawn comprises a substrate to which the synthetic fibres have been attached. Preferably, a granular material has been strewn between the synthetic 25 fibres. A synthetic fibre suitable for use in an artificial lawn, said synthetic fibre comprising a core layer of synthetic material; a first outer layer of synthetic material; a second outer layer of synthetic material on an opposed side of the core layer from the first outer layer, wherein said core layer first outer layer and second outer layer are co-extruded: 5 wherein each of said core layer, first outer layer and second outer layer are composed of a different synthetic material, and wherein each of said core layer, first outer layer and second outer layer have a different function specific property. In a further aspect, the invention may be said to consist in a method 10 for producing a synthetic fibre as described in the accompanying specification with or without reference to the accompanying figures. In a further aspect, the invention may be said to consist in a synthetic fibre as described in the accompanying specification with or without reference to the accompanying figures. 15 In a further aspect, the invention may be said to consist in an artificial lawn as described in the accompanying specification with or without reference to the accompanying figures. Other aspects of the invention may become apparent from the following description which is given by way of example only and with 20 reference to the accompanying drawings. As used herein the term "and/or" means "and" or "or", or both. As used herein "(s)" following a noun means the plural and/or singular forms of the noun. 25 The term "comprising" as used in this specification and claims means "consisting at least in part of". When interpreting statements in this specification and claims which include that term, the features, prefaced by that term in each statement, all need to be present but other features can also be present. Related terms such as 0 "comprise" and "comprised" are to be interpreted in the same manner. To those skilled in the art to which the invention relates, many changes in construction and widely differing embodiments and applications of the invention will suggest themselves without 5 departing from the scope of the invention as defined in the appended claims. The disclosures and the descriptions herein are purely illustrative and are not intended to be in any sense limiting. The invention will now be described by way of example only and with reference to the drawings in which: 10 Figs. 1A-1D show different embodiments of a synthetic fibre according to the invention; Figs. 2A and 2B schematically show a few embodiments of an artificial grass sports field provided with a synthetic fibre obtained by using the method according to the invention. 15 The fibres (10, 20, 30, 40) have been obtained from a foil of a synthetic material, which foil, obtained by co-extrusion, is composed of at least two layers of different synthetic materials (11, 12) as shown in Fig. 1A. Contrary to the currently known synthetic fibres, which are composed of a homogeneous mixture of synthetic 20 materials, the layered structure of the synthetic fibre (10, 20, 30, 40) according to the invention makes it possible to provide each layer (sub layers 11 and 12 in this embodiment) with a function-specific property. As a result, the use of a synthetic material having a specific property in a particular part of the synthetic fibre obviates or strongly reduces 25 the need for the presence of this synthetic material and the related function-specific property elsewhere in the fibre. For example, it is possible to use a synthetic material for the sub-layer 11 which in principle provides the synthetic fibre with the required mechanical strength (and rigidity) and which in particular non-splitting properties such that the synthetic fibre used for the artificial grass sports field will not split as a result of being played on. In another embodiment as shown in Fig. 1B, the synthetic 5 fibre 20 is built up of three layers of three different synthetic materials indicated by reference numerals 21, 22, 23. The middle layer 21 is made of an inexpensive synthetic material that is to give the fibre 20 its mechanical strength, whilst the outer layers 22 and 23 may be made of different synthetic materials, each of which may exhibit a 10 different function-specific property, which property comes out best on the outer side of the synthetic fibre rather than in the centre. Thus, the outer layers 21 and 22 may have an elastic property, for example, contrary to the inner layer 21, which provides the fibre with a certain rigidity (against breaking or splitting), which 15 elastic property of the outer layer 21 or 22 has a positive effect on the playing properties of the artificial grass sports field. Whereas in the embodiment in Fig. 1B the outer layers 22 and 23 may be made of different synthetic materials, Fig. IC shows an embodiment in which the outer layers 32A and 32B are made of the same 20 synthetic material. Fig. 1D shows a further, more complex layered structure of a synthetic fibre according to the invention. By means of co-extrusion of different synthetic materials, a layered synthetic fibre made up of a central core 41 and surrounded by different types of outer layers 42A 25 42B or 43A-43B, respectively, is obtained. The essence of the method according to the invention and the synthetic fibres according to the invention obtained thereby lie in the fact that the synthetic fibre, contrary to the known synthetic fibres, does not have a homogeneous structure in which all different IU synthetic materials and the related properties are homogeneously incorporated in the fibre. As a result of the homogeneous structure or composition of the existing artificial grass sports fields, certain properties of the fibre may be present less prominently than is 5 desirable, whereas other properties are now predominantly present than desired. Using the method according to the invention, it is possible to obtain synthetic fibres according to a specific formulation that, contrary to the standardized fibres, exhibit a function-specific 10 property in certain parts of the fibre that is not considered necessary or desirable elsewhere in the fibre. This enables a more efficient use of the various (synthetic) materials, which not only serves to reduce costs but also provides a more universal synthetic fibre according to the invention 15 having markedly improved playing and fibre properties than in the homogeneously constructed known fibres. In this specific embodiment, the inner layers 11, 21, 31 and 41 may be made of a more inexpensive synthetic material that in principle provides the fibre with a certain strength against breaking or splitting. The outer layers 12, 22, 32, 20 32A-32B, 42A-42B and 43A-43B may be made of a synthetic material that does not necessarily need to be present in the fibre core. In this context, a specific embodiment may be made up of an outer layer built up of an antistatic additive. The antistatic additive prevents the fibre from being charged by means of static 25 electricity generated as a result of the artificial grass sports field being played on. Contrarily, the antistatic additive precisely ensures that the generated static electricity can discharge from the artificial grass sports field and, for example, will not discharge via the players, which can lead to unpleasant experiences.

In addition, in most artificial grass sports fields a strewing material (usually made of a rubber-like material) is used, which, due to the static electricity that is generated, migrates upward in the artificial grass sports field and which is spread through the air 5 as a result of the field being played on. The airborne strewing material has a disturbing effect on the players. The antistatic additive in particular is a permanent antistatic, possibly a polymer, such as a polyamide or polyether block amide. In another embodiment, the additive is a polyester block 10 copolymer. In another embodiment, one of the outer layers (or both outer layers) (12, 22-23, 32a-32b, 43a-43b) may comprise a hydrophilic additive. The artificial grass fibre thus obtained has the function specific characteristic that it can absorb moisture (water) from the 15 atmosphere, such as rain. This makes the artificial grass sports field remain moist longer, just like a natural-lawn sports field, which has a positive effect on the playing behaviour in particular when sliding etc. While the field is being played on, the absorbed moisture is released, the same as with natural grass. 20 An example of a hydrophilic additive that can be used as the top layer or outer layer (12, 22-23, 32a-32b, 43a-43b) of the co extrusion fibre is ethylene vinyl alcohol copolymer. Depending on the quantity of vinyl alcohol in the copolymer, this copolymer can absorb much water. 25 The middle layer (11, 21, 31, 41) in this case gives the fibre its strength, whilst the relatively thin top layer (12, 22-23, 32a-32b, 43a-43b) absorbs water. This water can be absorbed from the air (in the form of rain, fog, etc.) or can be supplied by an active sprinkler installation. (Often, artificial grass sports fields are I4 sprinkled just before they are played on.) During play, the absorbed water is released again, which reduces the risk of injury, for example when sliding. Furthermore, the absorbed water keeps the temperature of the field lower, since an 5 artificial grass sports field can be heated by the sun, under adverse conditions to temperatures as high as 70 'C. Another embodiment of a hydrophilic additive as the outer layer (12, 22-23, 32a-32b, 43a-43b) uses polyhydroxyethyl methacrylate. In order to prevent bonding problems to the middle layer (11, 21, 31, 10 41), a five-layer co-extrusion configuration is required, as shown in Fig. 1D. The layers 32a-42b are bonding layers for the hydrophilic layer 43a-43b to the central layer 41 in that case. For illustration purposes, the various layers of the artificial grass fibre (as shown in Figs. 1A-iD) are shown to have 15 different thicknesses. The thicknesses as shown, however, do not correspond to the actual thicknesses of the produced artificial grass fibres in any way. In the embodiment in Fig. 1D, the bonding layer 42a-42b is considerably thinner than shown, usually it is 1-5% of the total fibre 20 thickness, whilst the other layers 41-43a-43b are considerably thicker. If polyethylene is used as the middle layer 11-21-31-41, ethylene vinyl alcohol copolymer functioning as the hydrophilic additive will bond to the middle layer without any filling bonding layers being used. Figs. 2A and 2B show a few embodiments of an artificial 25 grass sports field in which a synthetic fibre according to the invention can be applied. In both figures, the artificial grass sports field comprises a substrate 1, to which several synthetic fibres 2 as obtained by using the method according to the invention are attached at the locations indicated by reference numeral 3, for example by tufting. The synthetic fibre 2 has been obtained from a layer of synthetic material, which material has been produced from at least two different synthetic materials by means of a co-extrusion process. The synthetic fibre may be individually attached to the substrate or as a bundle of, for example 5 intertwined fibres 2a-2c. More in particular, the fibre that is obtained by co-extrusion can be a fibrillated band fibre. In another embodiment, as shown in Fig. 2B, the synthetic fibre according to the invention may be a monofilament. Also in this case, several monofilaments may be twined to form a bundle, after which 10 each bundle is attached to the substrate 1. In Fig. 2B, the substrate has an open structure and is composed of a grid of supporting yarns la lb, to which the synthetic fibres 2 are attached. In this way, the invention provides a more universal fibre, which on the one hand can be produced for a specific use and 15 which on the other hand saves production and material costs. According to the invention, the layer of synthetic material is composed of at least two layers of different synthetic materials, using a co-extrusion process. The co-extrusion step accomplishes a separation of the 20 various properties of the synthetic materials that are used. By providing the synthetic fibre with a layered structure, it becomes possible to provide each layer with a function-specific property, which property does not need to be present elsewhere in the fibre, or needs to be present only to a markedly reduced degree. This makes it possible to 25 select the formulation for the fibre specifically for a certain use, which, in addition to a more efficient material consumption, also results in a synthetic fibre with markedly improved playing and fibre properties than in the homogeneously composed known fibres. Where in the foregoing description reference has been made I I-t to elements or integers having known equivalents, then such equivalents are included as if they were individually set forth. Although the invention has been described by way of example and with reference to particular embodiments, it is to be 5 understood that modifications and/or improvements may be made without departing from the scope or spirit of the invention. In addition, where features or aspects of the invention are described in terms of Markush groups, those skilled in the art will recognise that the invention is also thereby described in terms of any 10 individual member or subgroup of members of the Markush group.

Claims

1. A method for producing a synthetic fibre for use in an artificial grass sports field using a co-extrusion process, 5 comprising the steps of: i) supplying a first synthetic material; ii) supplying at least a second synthetic material and at least a third synthetic material; iii) composing by co-extrusion a layer of synthetic material 10 defining said synthetic fibre, consisting of at least a layer of first synthetic material and a layer of said second synthetic material and a layer of said third synthetic material, wherein the layer of synthetic material is composed of a core layer of said first synthetic material, 15 which core layer is surrounded on both sides by at least two outer layers, each of said at least two outer layers consisting of a different synthetic material with respect to each other, and each having a function specific property.

2. A method according to claim 1, wherein after step iii) the 20 layer of synthetic material is stretched.

3. A method according to any one or more of the claims 1-2, wherein the fibre consists of at least one monofilament.

4. A method according to claim 3, wherein the fibre consists of several twined monofilaments. 25

5. A method according to any one or more of the claims 1-2, wherein the fibre is in the form of a band.

6. A method according to claim 5, wherein the band fibre is a fibrillated band fibre.

7. A method according to any one of claims 1-6, wherein the IU layers have different thicknesses.

8. A method according to any one or more of the preceding claims, wherein the first synthetic material consists of a mixture of a polymer and a plastomer. 5

9. A method according to claim 8, wherein the ratio of the plastomer in the core layer is 30-80 wt.%.

10. A method according to claim 9, wherein the ratio of the plastomer in the core layer is 35-50 wt.%.

11. A method according to any one or more of the preceding 10 claims, wherein at least one of the other synthetic materials comprises a hydrophilic additive.

12. A method according to claim 11, wherein the hydrophilic additive is an ethylene vinyl alcohol co-polymer.

13. A method according to claim 12, wherein the hydrophilic 15 additive is a polyhydroxyethyl methacrylate.

14. A method according to any one or more of the preceding claims, wherein at least one of the other synthetic materials comprises an antistatic additive.

15. A method according to claim 14, wherein the antistatic 20 additive is a polymer, in particular a polyamide or a polyether block amide.

16. A method according to any one or more of claims 1-15, wherein between the core layer and each of said at least two outer layers, a further bonding player is present. 25

17. A synthetic fibre obtained by using the method according to any one or more of the preceding claims.

18. A synthetic fibre obtained by using the method according to any one or more of the preceding claims, said synthetic fibre being composed of a layer of synthetic material, wherein said layer is composed of core layer of a first synthetic material, which core layer is surrounded on both sides by at least two outer layers, each of said at least two outer layers consisting of a different synthetic material each having a function specific 5 property.

19. An artificial lawn suitable for sports fields, provided with synthetic fibres according to any one or more of the preceding claims.

20. An artificial lawn suitable for sports fields, provided 10 with synthetic fibres according to any one or more of the preceding claims, said synthetic fibre being composed of a layer of synthetic material, wherein said layer is composed of a core layer of a first synthetic material, which core layer is surrounded on both sides by at least two outer layers, each of 15 said at least two outer layers consisting of a different synthetic material each having a function specific property.

21. An artificial lawn according to claim 20, wherein the lawn comprises a substrate to which the synthetic fibres have been attached. 20

22. An artificial lawn according to claim 20 or 21, wherein a granular material has been strewn between the synthetic fibres.

23. A synthetic fibre suitable for use in an artificial lawn, said synthetic fibre comprising i. a core layer of synthetic material: 25 ii. a first outer layer of synthetic material; iii. a second outer layer of synthetic material on an opposed side of the core layer from the first outer layer, iv. wherein said core layer, first outer layer and second to outer layer are co-extruded; v. wherein each of said core layer, first outer layer and second outer layer are composed of a different synthetic material, and 5 vi. wherein each of said core layer, first outer layer and second outer layer have a different function specific property.

24. A method for producing a synthetic fibre as described in the accompanying specification with or without reference to the 10 accompanying figures.

25. A synthetic fibre as described in the accompanying specification with or without reference to the accompanying figures.

26. An artificial lawn as described in the accompanying 15 specification with or without reference to the accompanying figures.