EP1728586A2 - Superlegierungspulver - Google Patents

Superlegierungspulver Download PDF

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Publication number
EP1728586A2
EP1728586A2 EP06114507A EP06114507A EP1728586A2 EP 1728586 A2 EP1728586 A2 EP 1728586A2 EP 06114507 A EP06114507 A EP 06114507A EP 06114507 A EP06114507 A EP 06114507A EP 1728586 A2 EP1728586 A2 EP 1728586A2
Authority
EP
European Patent Office
Prior art keywords
superalloy
powder
elements
enriched
powder according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP06114507A
Other languages
English (en)
French (fr)
Other versions
EP1728586A3 (de
EP1728586B1 (de
Inventor
Pascal Etuve
Justine Menuey
Didier Ribot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Safran Aircraft Engines SAS
Original Assignee
SNECMA Services SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SNECMA Services SA filed Critical SNECMA Services SA
Priority to EP07117338A priority Critical patent/EP1878533B1/de
Publication of EP1728586A2 publication Critical patent/EP1728586A2/de
Publication of EP1728586A3 publication Critical patent/EP1728586A3/de
Application granted granted Critical
Publication of EP1728586B1 publication Critical patent/EP1728586B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0433Nickel- or cobalt-based alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/22Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip
    • B22F3/225Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces for producing castings from a slip by injection molding
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/057Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being less 10%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/058Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/07Alloys based on nickel or cobalt based on cobalt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps

Definitions

  • the subject of the invention is a superalloy powder.
  • the presence of melting elements in the second powder makes it possible to lower the melting point thereof and to work at a temperature at which the second powder is liquid, while the first powder remains in the solid state.
  • the aim of the invention is to propose an alternative to existing solutions, offering good results in terms of homogeneous distribution of the melting element or elements within the powder, which results, in particular, in the absence of deformation of the parts made by sintering.
  • the subject of the invention is a superalloy powder according to claim 1 or claim 5.
  • the powder of the invention It is not necessary to mix the powder of the invention with another powder as in FR 2 822 741 because the powder of the invention already has the final composition which is needed, both in terms of constituent elements of the superalloy and in terms of element (s) melting (s).
  • the proportion of B and, optionally, Si is adapted for use of the powder without prior mixing step with another powder (as explained above, the proportion of melting elements has a determining influence on the behavior of the powder during the heat treatment thereof).
  • said melting element is an integral part of the superalloy: it is not chemically deposited or mechanically inlaid on the surface of the superalloy grains, as in the known techniques mentioned above.
  • the constituent elements of the superalloy including the melting element, are present in each grain of powder and, consequently, are distributed within the powder in a perfectly homogeneous manner. This avoids the problems of localized porosity and supercooling related to a too low proportion, or too important, element melting in some regions of the powder.
  • a technique for atomizing a precursor liquid mixture comprising the elements of said superalloy and said at least one melting element.
  • each powder is a base Ni or Co superalloy powder, which comprises at least the three elements Ni, Co and Cr (Chrome).
  • These powders were made using an atomization technique from a precursor liquid mixture comprising the elements of the superalloy (Ni, Co, Cr ...) and at least one melting element (B and optionally Si).
  • This liquid mixture was obtained by melting alloys by induction, under vacuum, in a crucible equipped with a burette allowing the liquid mixture to flow at a low flow rate. Jets of inert gases under high pressure, flowing at a speed close to that of the sound, are used to spray the mixture leaving the burette. The mixture then disintegrates into fine droplets which then take a spheroidal shape under the effect of the surface tension and cool very rapidly in an atomization chamber.
  • the inert gases used are, for example, argon or nitrogen.
  • base Ni the superalloy enriched in melting elements, essentially comprises:
  • carbon (C), zirconium (Zr), and phosphorus (P) may be found in minute proportions, for example, on the order of 0.06% or less.
  • the superalloy enriched in melting elements essentially comprises: 16.4 to 19.6% of Co; 8.2 to 12.8% Cr; 2.6 to 4.4% Mo; 2.25 to 3.3% AI; 1.95 to 2.9% Ti; 0.8 to 2% Si; 0.5 to 1.3% B; and a balance in Ni.
  • the enriched superalloy essentially comprises: 14 to 16% of Co; 12 to 15.3% Cr; 3.35 to 4.7% Mo; 2.9 to 3.5% AI; 2.5 to 3.1% Ti; 0.4 to 1% of B; and a balance in Ni.
  • B is the only melting element.
  • the enriched superalloy essentially comprises: 17.2 to 22.2% of Cr; 26.75 to 30% Ni; 0 to 1.5% Si; 0.8 to 1% of B; 0.1 to 0.5% C; 0 to 0.37% Zr; 0 to 3% of Ta; and a balance in Co.
  • the cobalt base powders of the second type may comprise impurities, such as phosphorus P, in minute proportions, for example of the order of 0.04% or less.
  • Table 1 shows the compositions of the examples of powders (a) and (b), mentioned above, and of an example of powder (c) corresponding to the second type of superalloy powder according to the invention.
  • Table 1 Ex Composition in% by weight Or Co Cr MB al Ti Yes B VS Zr P Your (at) based 16.4 8.2 2.6 2.25 1.95 0.8 0.5 0 0 0 0 19.6 12.8 4.4 3.3 2.9 two 1.3 0.06 0.05 0.01 0 (B) based 14 12 3.35 2.9 2.5 0 0.4 0 0 0 0 16 15.3 4.7 3.5 3.1 0 1 0.06 0.06 0.02 0 (vs) 26.75 based 17.2 0 0 0 0 0.8 0.1 0 0 - 30 22.2 0 0 0 1.5 1 0.5 0.37 0.04 -
  • superalloy powder can be used in the implementation of any solder-diffusion process applied during the manufacture or repair of nickel-based alloy parts, cobalt, especially in the aeronautical field. It can be an assembly of parts, a filling of cracks, or cracks, on part or a reload of part surface to correct a superficial defect or to restore certain properties or geometrical dimensions of that -this.
  • the introduction of the filler powder can be carried out in different ways.
  • the raw powder can be used mixed with a cementum, for example of the Nicrobraz 320 type. It will be noted that the mixture obtained can be used in the form of cords.
  • a supply can be made in the form of a compact filler.
  • Said compact filler is obtained from the powder either by a manufacturing technique ensuring a sintering compaction thereof, or by means of injection molding techniques of metal powders.
  • FIG. 1 shows an example of a compact filler piece made by sintering from a superalloy powder according to the invention. This is a plate intended to be used to reload the surface of a room.
  • This plate was made from a powder of the aforementioned first type, according to the following steps: oven drying of the raw powder; distribution thereof in a mold adapted to the desired size and sintered thickness; placing the mold in an oven to heat treat it.
  • heat treatment one can perform (for an oven pressure of 0.13 Pa) a gradual increase in temperature up to 1160 ° C, then a hold at this temperature for about 10 min, followed by a gradual cooling.
  • the invention makes it possible to avoid the management and storage of several references of powders, and to avoid any step of mixing powders, critical from a hygiene and safety point of view.
  • the sintering temperature is significantly reduced. relative to the temperature required for a two-component mixture. Thanks to the homogeneity of the powder and the reduction of the sintering temperature, a noticeable improvement in the homogeneity of the properties of the sintered plate and a good preservation of the dimensions and the shape thereof, in particular a respect of the wished dimensions and a good flatness.
  • Figure 2 illustrates, conversely, the deformation problems that can be encountered during sintering of a two-component mixture.
  • the homogeneity of the superalloy powder of the invention also results in an improvement of the mechanical properties of the zone reloaded with said plate.
  • the powder is mixed with a binder in a kneader.
  • the binder includes, for example, polypropylene, ethylene, vinyl acetate and paraffin.
  • the mixing time must be such as to obtain a plasticization of the mixture.
  • the mixture is then cooled before being ground.
  • the granulates thus obtained can be introduced into the hopper of a press and the injection can be carried out in molds of dimensions specific to the compact part to be produced.
  • the mold blank is then chemically untied and the blank is sintered.
  • Table 2 Example Use a Use b Use c (at) Yes Yes Yes (B) Yes Yes (vs) Yes Yes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Powder Metallurgy (AREA)
EP06114507A 2005-05-26 2006-05-24 Superlegierungspulver Active EP1728586B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07117338A EP1878533B1 (de) 2005-05-26 2006-05-24 Superlegierungspulver

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0505299A FR2886182B1 (fr) 2005-05-26 2005-05-26 Poudre de superalliage

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP07117338A Division EP1878533B1 (de) 2005-05-26 2006-05-24 Superlegierungspulver

Publications (3)

Publication Number Publication Date
EP1728586A2 true EP1728586A2 (de) 2006-12-06
EP1728586A3 EP1728586A3 (de) 2007-04-04
EP1728586B1 EP1728586B1 (de) 2008-07-23

Family

ID=35530780

Family Applications (2)

Application Number Title Priority Date Filing Date
EP07117338A Active EP1878533B1 (de) 2005-05-26 2006-05-24 Superlegierungspulver
EP06114507A Active EP1728586B1 (de) 2005-05-26 2006-05-24 Superlegierungspulver

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP07117338A Active EP1878533B1 (de) 2005-05-26 2006-05-24 Superlegierungspulver

Country Status (7)

Country Link
US (1) US20070051199A1 (de)
EP (2) EP1878533B1 (de)
JP (1) JP2006328535A (de)
BR (1) BRPI0601917A (de)
CA (1) CA2548610A1 (de)
DE (2) DE602006001897D1 (de)
FR (1) FR2886182B1 (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2182084A1 (de) * 2008-11-04 2010-05-05 Siemens Aktiengesellschaft Schweisszusatzwerkstoff, Verwendung des Schweisszusatzwserkstoffes und Bauteil
RU2679503C2 (ru) * 2013-12-24 2019-02-11 Либурди Инжиниринг Лимитед Дисперсно-упрочненный сварочный материал на основе никеля для сварки плавлением жаропрочных сплавов

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009285664A (ja) * 2008-05-27 2009-12-10 Toshiba Corp ロウ付け補修材料およびその材料を使用したロウ付け補修方法
MX2011009089A (es) * 2009-03-24 2011-09-27 Alstom Technology Ltd Revestimiento libre de cromo para sustrato.
US20120128526A1 (en) * 2010-11-24 2012-05-24 Kulkarni Anand A Metallic Bondcoat or Alloy with a High y/y' Transition Temperature and a Component
JP6372512B2 (ja) * 2016-04-06 2018-08-15 セイコーエプソン株式会社 粉末冶金用金属粉末、コンパウンド、造粒粉末、焼結体および耐熱部品
GB2565063B (en) 2017-07-28 2020-05-27 Oxmet Tech Limited A nickel-based alloy
CN107779674A (zh) * 2017-11-29 2018-03-09 西华大学 一种镍基合金粉末及其制备方法
US20210308809A1 (en) * 2018-05-01 2021-10-07 Siemens Energy, Inc. Nickel based superalloy braze filler
FR3097876B1 (fr) * 2019-06-28 2022-02-04 Safran Poudre de superalliage, piece et procede de fabrication de la piece a partir de la poudre
CN110512119B (zh) * 2019-09-29 2021-06-01 湖南英捷高科技有限责任公司 一种注射成形镍基合金粉、注射成形方法及镍基合金制品
CN113234963B (zh) * 2021-05-19 2021-12-17 沈阳航空航天大学 室温以及低温环境用镍铬基超合金及其制备方法

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GB933406A (en) * 1960-11-17 1963-08-08 Deloro Stellite Ltd A cobalt-chromium base alloy
US4008844A (en) * 1975-01-06 1977-02-22 United Technologies Corporation Method of repairing surface defects using metallic filler material
US4129444A (en) * 1973-01-15 1978-12-12 Cabot Corporation Power metallurgy compacts and products of high performance alloys
US4140528A (en) * 1977-04-04 1979-02-20 Crucible Inc. Nickel-base superalloy compacted articles
US20020157737A1 (en) * 2000-12-15 2002-10-31 Chesnes Richard Patrick Nickel diffusion braze alloy and method for repair of superalloys

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US3700427A (en) * 1969-07-11 1972-10-24 Gen Electric Powder for diffusion bonding of superalloy members
US4343650A (en) * 1980-04-25 1982-08-10 Cabot Corporation Metal binder in compaction of metal powders
US4478638A (en) * 1982-05-28 1984-10-23 General Electric Company Homogenous alloy powder
AU561663B2 (en) * 1982-05-28 1987-05-14 General Electric Company Homogeneous superalloy powder mixture for the repair of nickel and cobalt superalloy articles
US4705203A (en) * 1986-08-04 1987-11-10 United Technologies Corporation Repair of surface defects in superalloy articles
JPH01165741A (ja) * 1987-12-21 1989-06-29 Kobe Steel Ltd 結晶粒度の異なる同種合金からなるタービンディスク
US5080734A (en) * 1989-10-04 1992-01-14 General Electric Company High strength fatigue crack-resistant alloy article
US5561827A (en) * 1994-12-28 1996-10-01 General Electric Company Coated nickel-base superalloy article and powder and method useful in its preparation
US7279229B2 (en) * 2005-03-24 2007-10-09 General Electric Company Nickel-base braze material and method of filling holes therewith

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB933406A (en) * 1960-11-17 1963-08-08 Deloro Stellite Ltd A cobalt-chromium base alloy
US4129444A (en) * 1973-01-15 1978-12-12 Cabot Corporation Power metallurgy compacts and products of high performance alloys
US4008844A (en) * 1975-01-06 1977-02-22 United Technologies Corporation Method of repairing surface defects using metallic filler material
US4140528A (en) * 1977-04-04 1979-02-20 Crucible Inc. Nickel-base superalloy compacted articles
US20020157737A1 (en) * 2000-12-15 2002-10-31 Chesnes Richard Patrick Nickel diffusion braze alloy and method for repair of superalloys

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2182084A1 (de) * 2008-11-04 2010-05-05 Siemens Aktiengesellschaft Schweisszusatzwerkstoff, Verwendung des Schweisszusatzwserkstoffes und Bauteil
WO2010052049A1 (de) * 2008-11-04 2010-05-14 Siemens Aktiengesellschaft Schweisszusatzwerkstoff, verwendung des schweisszusatzwerkstoffes und bauteil
US20110274579A1 (en) * 2008-11-04 2011-11-10 Nikolai Arjakine Welding Additive, Use of the Welding Additive and Component
RU2505616C2 (ru) * 2008-11-04 2014-01-27 Сименс Акциенгезелльшафт Сварочный присадочный материал, применение сварочного присадочного материала и конструктивный элемент
RU2679503C2 (ru) * 2013-12-24 2019-02-11 Либурди Инжиниринг Лимитед Дисперсно-упрочненный сварочный материал на основе никеля для сварки плавлением жаропрочных сплавов

Also Published As

Publication number Publication date
FR2886182B1 (fr) 2009-01-30
EP1728586A3 (de) 2007-04-04
EP1728586B1 (de) 2008-07-23
DE602006001897D1 (de) 2008-09-04
EP1878533B1 (de) 2010-07-07
CA2548610A1 (fr) 2006-11-26
FR2886182A1 (fr) 2006-12-01
BRPI0601917A (pt) 2007-02-13
EP1878533A2 (de) 2008-01-16
EP1878533A3 (de) 2008-04-16
DE602006015298D1 (de) 2010-08-19
US20070051199A1 (en) 2007-03-08
JP2006328535A (ja) 2006-12-07

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