EP1706679B1 - Verfahren zur wärmeerzeugung in gebäuden und kontinuierlich arbeitender wärmeerzeuger mit kavitationseffekt - Google Patents
Verfahren zur wärmeerzeugung in gebäuden und kontinuierlich arbeitender wärmeerzeuger mit kavitationseffekt Download PDFInfo
- Publication number
- EP1706679B1 EP1706679B1 EP04724932A EP04724932A EP1706679B1 EP 1706679 B1 EP1706679 B1 EP 1706679B1 EP 04724932 A EP04724932 A EP 04724932A EP 04724932 A EP04724932 A EP 04724932A EP 1706679 B1 EP1706679 B1 EP 1706679B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat generator
- flow
- heat
- water
- cavitation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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- 238000010276 construction Methods 0.000 title abstract description 8
- 238000004519 manufacturing process Methods 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 9
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- HRIZJUDKZZJVBC-UHFFFAOYSA-N ethane-1,1-diol;ethane-1,2-diol Chemical compound CC(O)O.OCCO HRIZJUDKZZJVBC-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
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Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24V—COLLECTION, PRODUCTION OR USE OF HEAT NOT OTHERWISE PROVIDED FOR
- F24V99/00—Subject matter not provided for in other main groups of this subclass
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D3/00—Hot-water central heating systems
- F24D3/02—Hot-water central heating systems with forced circulation, e.g. by pumps
Definitions
- the invention relates to heat engineering, namely heat recovery processes, where the heat is different from fuel combustion, and can be used for independent heating of buildings and structures of various uses and for water heating for industrial and household needs.
- the heat is transferred to the main stream of the liquid either by the action of countercurrent jet streams or by mechanical obstructions placed on the path of the liquid, or by the use of continuous heat generators which act on a limited volume of the heating medium, or by a reduction of the Volume of heating medium while increasing the energy cost due to the liquid heating or by heavy water addition in addition to the main stream won.
- liquid heating means which are heat generators, which in the patents RU 2045715 C1 , F 25 B29 / 00, 10.10.1995, BI. No. 28, and UA 47535 C2 , F 24J3 / 00, 15.07.2002, BI. No. 7, are described.
- the water with a certain degree of purity for example, industrial water
- a pump which builds a delivery pressure up to 6atm, promoted to the heat generator input
- the patent RU 2045715 C1 F 25 B29 / 00 This heat generator heats the water with a total weight of 200 kg within a closed circuit with an initial temperature of 18-20 ° C up to 70 ° C by means of a powerful pump operated with a power of 5.5 kW.
- the patent does not provide information on the thermal performance of the heat generator, and the efficiency is given without any indication of the outside air temperature, thickness and material of the walls in the room which have been heated by this device and this method; moreover, the rate for periodic liquid heating in a closed loop is indicated, which has a deviation of 1.5 ° C per minute.
- the object is to recover the heat by changing and more accurately determining the water temperature intervals used in the heat recovery in the heat generator, and to ensure an efficiency increase in heat generation.
- the object was achieved by means of the examples presented, wherein the water was preheated by means of an electric heater or a heat generator with the same characteristics up to a temperature of 63-70 ° C. Thereafter, the operating cycle of the same heat generator was filled with this preheated water, and after its operation in the closed loop process, a heating temperature of 0.8 ° C per minute to the vapor point was reached.
- the electric motor power was up to 11 kW, i. H. increased by two times, and the operating cycle of the heat generator was filled with water of the same weight of 100 kg and a temperature of about 63 ° C.
- the efficiency of the heat generator operation according to the patent reached a value of 2.
- the heating intensity of a closed-cycle working fluid is mainly due to the increase in the rotational speed of the power in the device within a certain time unit, i. depends on the intensification of the cavitation and impact wave processes.
- Other known devices include a heat generator with inlet and outlet for the operating fluid, a pump which is coupled to the heat generator inlet, a fluid circulation amplifier, a tubular member with a brake mechanism on the heat generator outlet, said tubular member is connected to a return line ( UA 7205 A , F 25 B29 / 00, 30.06.1995, BI. No. 2; RU 2045715 C1, F25 B29 / 00, 10.10.1995, BI. No. 28).
- a closest solution in its technical nature is a liquid heating device consisting of a heat generator with an inlet and outlet for the working fluid, a pump connected to the heat generator inlet, a liquid accelerator, a delivery line and a return line, a tubular component including a brake mechanism on the Heat generator outlet to which the return line is coupled, injection pipe socket, one-sided, conical series pipe socket, bushings with cylindrical channels and a conical liquid distributor consists.
- a heat generator with an inlet and outlet for the working fluid
- a pump connected to the heat generator inlet
- a liquid accelerator a liquid accelerator
- a delivery line and a return line
- a tubular component including a brake mechanism on the Heat generator outlet to which the return line is coupled
- injection pipe socket one-sided, conical series pipe socket
- bushings with cylindrical channels and a conical liquid distributor consists.
- the invention has for its object to provide a heat generator which is used in a heat recovery process, which provides an increase in efficiency in the heat recovery on the assumption of Schuffenmengenzuddling without the energy consumption is increased, and to provide a method that simultaneously the Schuffenzuzen the consumers and the heating of this heating means by a heat generator allows.
- the total volume of the heating medium in the container (36) is composed of a volume required for the filling of the entire heating system and the heat exchanger (44) and an additional volume of water, which is 0.7 times heating system volume and on Fig. 9 Dotted is: 1. Water level.
- the ethylene glycol content in the water not only allows the boiling water increase of the working liquid, but also the continuity of the air-water phase under the condition that the flow velocity for this medium in the gap region of the Beschizunistsmodators and the heat generator is increased to supersonic speed, and secures the Tin -Freezing the heating system in emergencies and switching off the heat generator safely.
- the goal is achieved by using an additional device consisting of a stainless steel tube whose upper end is in the cowl region of the heating medium container and the lower end in the discharge tube of the pump is immersed.
- an additional device consisting of a stainless steel tube whose upper end is in the cowl region of the heating medium container and the lower end in the discharge tube of the pump is immersed.
- the lower part of which are located along the circumference along length vertical openings, but their height does not exceed the limits of the AbGermanrohrstutzens the pump.
- This device makes it possible to intensify the heat exchange process by pumping in a respective amount of air together with the operating liquid flow into the heat generator system by saturating the liquid flow with the air of the cavitation bubble flow and by decreasing the water partial pressure, which in turn affects the heat transfer intensity among them
- Conditions in the heat generator is increased by 20%.
- it becomes possible to increase the working fluid boiling point by 5% to a temperature of 120 ° C.
- the operating fluid container has the following construction: two chambers of the container are divided by a partition wall 37 made of a material having a low specific thermal conductivity and connected in the lower part by means of a flow channel 38 for the operating fluid; These chambers are also connected in the region of an air cap of the container 36 by means of a steel pipe by a partition wall 37. This makes it possible to establish a pressure equilibrium in the container chambers and to maintain the same operating fluid level in the container.
- the working fluid can be heated much more actively with the heat generator located therein. As a result, a continuous thermal diffusion process with a large heating medium circumference is avoided.
- a colder operating fluid which is discharged from a discharge pipe socket 34 of the pump 35 together with the air, in the ratio of 0.002 of the weight of the derived operating fluid, within a certain time unit on the discharge pipe to the heat generator from the flow channel 38 water pump pumping flows.
- the heat generator and the container 36 are connected to the heating system (or hot water supply system) by means of a pressure port 21 and a return line 45, which leads via a flange in the air duct area of the container filled with operating fluid, but does not touch the surface of the operating fluid.
- the container is also equipped with a thermocouple 40 to read the operating fluid temperature and to monitor and control the opening electrohydraulic valve 41 by means of an assembly of monitoring and control units 49.
- the container 36 is additionally equipped with a valve 51 to feed the system in an emergency with operating fluid; it can also be used to connect to the water supply system to ensure a continuous supply of water to the tank.
- the discharge of the working fluid from the container via a valve 52 which is housed in the lower part of the container.
- a diesel generator 54 is provided with the required power, which is connected to the pump and the assembly with monitoring and control units 49.
- the system is equipped with hand-controlled valves to bring the system into the operating state with the manual control valve 42 and to ensure the manual operating fluid discharge from the heating system and from the heat exchanger 44.
- the system is equipped with a container 43 for water hammer provided, which is connected downstream of the valves 41, 42.
- the return line is provided with a thermocouple 46 which is connected to the monitoring and control device 49 and makes it possible to read the temperature in the return line and to control the function of the valve 47 (opening Elektrohydroventils) via the monitoring and control device.
- the monitoring and control device 49 controls the function of all system units in automatic mode.
- the invention is also based on the object to improve the hot water system.
- the generation of a large amount of energy, an intensification of the thermal diffusion process and an operational continuity of the Kavitationsippogenerators to heat large volumes of the operating fluid and their simultaneous promotion ensured in the supply line.
- the continuous Kavitations lockergenerator with an inlet and an outlet for the operating fluid, a pump, a supply line and a return line, in accordance with the invention additionally with an acceleration activator of the operating fluid ( Fig. 2 ) is provided, which is connected to a pump 35 and intermediate pipe socket 33 for conveying fluid.
- the acceleration activator consists of at least three series pipe sockets with different flow channel diameters which are connected to each other by means of frusto-conical flanges lying in the main flow direction of the working fluid, and from a jet acceleration channel 29 which is tangential to the flow channel of the pipe socket 26.
- the operating fluid accelerator activator is additionally equipped with static cavities 24, 31 with radially arranged openings which produce a stream of calibrated cavitation bubbles which enter the gap region of the stream to crush the cavitation bubbles and generate a secondary stream.
- the acceleration activator of the operating fluid is additionally provided with a gap splitting channel 23 (Betriebswashkeitausfelder) and a high-pressure chamber 1 for the operating current, which has a jet acceleration gap channel which is tangential to the passage channel of the central pipe socket 2 of the heat generator ( Fig. 1 ) runs.
- the central pipe stub 2 of the heat generator is connected to a central part 7, which contains a static cavitator 3 with radial openings 4, which generate a stream of calibrated cavitation bubbles, and has radial channels 5 in the gap region of the stream.
- the static cavitator 3 also has a cavitating Laval nozzle 6, which ensures the immediate main flow constriction and expansion of the liquid and allows the secondary flow of crushed cavitation bubbles.
- the continuous Kavitations lockergenerator additionally contains Hauptstrom-separating flanges 10, 11 with a conical Stromzerteiler that distributes the operating fluid under pressure through the tangentially directed gap channels 12, 23 in the channels of the outlet nozzle 14 of the heat generator evenly; the at least five outlet ports are concentric with the central port 2 of the heat generator and from a discharge port 21 of the heating system or the hot water system, which supplies the consumers with hot water.
- the outlet ports 14 are equipped with static cavities 15 with radially disposed openings 16 which produce a stream of calibrated cavitation bubbles. Circular grooves 17 in the outlet port 19 and cavitating Laval nozzles 18 crush the Kavitationsblasen.
- the outlet ports 19 are additionally equipped with nozzle outputs 20 of the heat generator, which are inclined at an angle of 45 ° to the nozzle centerline and laterally aligned away from the central port 2 of the heat generator.
- a system which enables the simultaneous heating of the heating medium to the consumers and the heating of this heating means by a heat generator operates as follows.
- the pump 35 After filling the container 36 with the required amount of liquid, as mentioned above, at an initial temperature of about 5 ° C, the pump 35 turns on without the participation of the monitoring and control device 49 a. Thereafter, the heating of the operating fluid by means of the heat generator up to a temperature of 90 ° C. The heating process is monitored by a thermocouple 40. After a temperature of 90 ° C has been reached, the operating fluid opens the manual control valve 42 and enters the heating circuit with heat exchangers 44 with the heat generator on. The valves 48, 51 must be open. The thermocouple 46 reads the heating medium data in the return line 45. After filling the heating system with operating fluid, the valves 42, 48 and 51 are closed.
- the pump will start, and the heater operating temperature will be set on the monitoring and control device both in the supply line and in the return line of the heating system.
- the upper temperature limit for closing the opening Elektrohydroventils 41 is set lower than the operating fluid temperature of 90 ° C in the container 36, for example, at 80 ° C.
- the pump 35 is turned on simultaneously.
- the temperature for opening the valve 47 (electrohydraulic valve), for example, at 60 ° C, and for automatically turning on the pump 35 is set to start the heat generator operation.
- a temperature of 90 ° C for opening the opening solenoid valve 41 is also set. After that, the pump and the heat generator automatically start. When the operating fluid temperature in the container reaches 90 ° C, valves 41 and 47 open.
- the heat generator delivers the water into the system while continuing to heat the working fluid in the container.
- the valves 41, 47 are automatically closed and the pump shuts off until the system has cooled to a temperature of 60 ° C.
- the valve 47 is opened, and the pump and the heat generator automatically turn on, which promotes the properly warmed water through the open valve 41 into the system.
- the time required for water heating is low. This is related to the fact that the total mass of water entering from the return line 45 at a temperature of 60 °, in comparison with that Water mass is insignificant, which is in the container and at least 80 ° C is warm. As a result, the water quickly reaches the temperature of over 63 ° C.
- the diameter of the flow passage of the pipe socket 32 is 2.4 times as large as the diameter of the inner channel, and the liquid flow rate increases up to 14 m / s.
- the internal channel of the static cavitator is not a flow channel. Therefore, the main stream, when it comes to its conical end, additionally twisted; he receives a retrograde movement.
- the liquid flow passes into the conical pipe socket channel 28, in which its speed again increases up to 5m / s, and into the cylindrical pipe socket channel 28 with a diameter which is half the diameter of the pipe socket 32, in which its speed up to 9m / s increases and the direction of current flow is abruptly changed by the taper of the conical guide flange 27 in the jet acceleration channel 29, which runs tangentially to the pipe socket flow passage 26.
- the liquid flow rate is increased up to 14 m / s.
- the main liquid flow later enters the conical channel 25, in which he again receives a speed of 9m / s, and device in the inner channel of the static Kavitators 24, in which proceed the same physical phenomena as when flowing through the static Kavitators 31 with the thermal energy development.
- the flow passes through the pipe stub channel 28, the flow direction changing flange and the channel 25, the pipe stub 26 and the static cavitator 24 of the pipe stub 22, the temperature of the main liquid stream is then gradually increased.
- a gap channel 23 was installed with openings. When passing through these openings, the main liquid flow is accelerated, and cavitation bubbles are formed in the high-pressure chamber 1, and thus a thermal energy is developed. About the tangential to the flow channel of the pipe socket 2 arranged gap jet acceleration channel of the main liquid flow comes at a speed of 9m / s into the flow channel of the central pipe socket of the heat generator; it is twisted, and thereby the thermal energy is developed. When the main flow passes through the static cavitator 3 and the bubble generating openings, the radial passages 5 and the Laval nozzles 6, thermal energy is also developed.
- the current comes into the conical pipe socket channel 8 in which it is twisted, and it is again developed heat energy.
- the main flow separation flange 10 With a conical flow divider, the main flow is divided into individual flows into the tangentially directed gap channels 12, 13 and into the at least five flow channels of the outlet ports 14 and into the flow channel of the pressure port 21 of the heating system or the hot water supply system.
- the current reaches a speed of 8m / s.
- the flow of fluid rotating into the outlet port 14 is affected by the Coriolis force, which deflects the outer layers of the fluid in a direction perpendicular to their relative velocity direction and will exert a pressure on the walls of the flow passage of the outlet ports 14 causing the thermal energy development.
- the cross-sectional area of the gap channel 13 depends on the circumference of the heating means, which must be conveyed into the discharge nozzle 21, and represents a variable size, which thereby also regulates the Schuffen-conveying speed.
- the liquid flow enters the internal flow channels of static cavitators 15; it passes over the openings 16, the Spaltstrom Suite with circular grooves 17 in the outlet port 19 and the Laval nozzles 18.
- the same physical processes and the same thermal energy development come about, as it flows through the liquid flow through the static cavitators of the acceleration activator ( Fig. 2 ) and the central pipe socket 2 of the heat generator is the case.
- the liquid flow passes through the nozzle ports 20 of the outlet ports 19, which has an edge inclination angle of 45 degrees to the exhaust port axis, additional thermal energy is developed.
- the total area of the thermal diffusion process becomes at least five times larger compared with the construction of the heat generators having a nozzle outlet for the working liquid.
- the above-stated objective of improving the apparatus by means of the design change and the addition of new equipment ensures the generation of a large amount of heat energy by the cavitation heat generator to heat significant volumes of liquid and the continuity of the thermal energy effect while conveying liquid into the feed line to accomplish.
- the continuous cavitation heat generator and the heat recovery process applied here can be used in accordance with this invention for the independent heating of buildings and buildings of various purposes as well as in agriculture in the technical work processes or for energy production.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Steam Or Hot-Water Central Heating Systems (AREA)
- Physical Water Treatments (AREA)
- Jet Pumps And Other Pumps (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
- Sorption Type Refrigeration Machines (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL04724932T PL1706679T3 (pl) | 2003-12-31 | 2004-03-31 | Sposób wytwarzania ciepła w budynkach i w wytwornicach ciepła z efektem kawitacji pracujących w systemie pracy ciągłej |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
UA20031213218A UA66334C2 (ru) | 2003-12-31 | 2003-12-31 | Способ получения тепла для отопления зданий и сооружений и кавитационный теплогенератор непрерывного действия |
PCT/UA2004/000019 WO2005064244A1 (fr) | 2003-12-31 | 2004-03-31 | Procede pour produire de la chaleur et chauffer des immeubles et constructions ainsi que generateur de chaleur par cavitation a action ininterrompue |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1706679A1 EP1706679A1 (en) | 2006-10-04 |
EP1706679B1 true EP1706679B1 (de) | 2008-12-03 |
Family
ID=34513818
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04724932A Expired - Lifetime EP1706679B1 (de) | 2003-12-31 | 2004-03-31 | Verfahren zur wärmeerzeugung in gebäuden und kontinuierlich arbeitender wärmeerzeuger mit kavitationseffekt |
Country Status (10)
Country | Link |
---|---|
US (1) | US20070152077A1 (ru) |
EP (1) | EP1706679B1 (ru) |
CN (1) | CN1918440B (ru) |
AT (1) | ATE416350T1 (ru) |
CA (1) | CA2554673A1 (ru) |
DE (1) | DE502004008603D1 (ru) |
EA (1) | EA008132B1 (ru) |
PL (1) | PL1706679T3 (ru) |
UA (1) | UA66334C2 (ru) |
WO (1) | WO2005064244A1 (ru) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102006006161A1 (de) * | 2006-02-10 | 2007-08-16 | Juri Steinhauer | Kavitationserzeuger |
KR100802475B1 (ko) * | 2007-03-08 | 2008-02-12 | (주) 볼텍스웨어 | 캐비테이션을 이용한 고온발생 방법 및 그 장치 |
RU2490556C2 (ru) * | 2011-04-05 | 2013-08-20 | Александр Семенович Фролов | Теплогенератор устройства для отопления помещений |
WO2013102247A1 (pt) * | 2012-01-02 | 2013-07-11 | Ioel Dotte Echart Rubem | Gerador de cavitação hidrodinâmica e hidrossônica |
US11573034B2 (en) | 2016-08-09 | 2023-02-07 | Sabanci Üniversitesi | Energy harvesting device |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3721521A (en) * | 1971-04-30 | 1973-03-20 | Us Army | Apparatus for converting pressure energy to thermal energy |
US3961485A (en) * | 1973-11-06 | 1976-06-08 | Michael Eskeli | Turbine with heat intensifier |
FR2485169B1 (fr) * | 1980-06-20 | 1986-01-03 | Electricite De France | Perfectionnements aux installations de fourniture d'eau chaude comprenant un circuit thermodynamique |
US4344567A (en) * | 1980-12-31 | 1982-08-17 | Horne C James | Hydraulic heating system |
US4372254A (en) * | 1981-01-23 | 1983-02-08 | Edmund Hildebrandt | Hydraulic heat generator |
RU2045715C1 (ru) | 1993-04-26 | 1995-10-10 | Юрий Семенович Потапов | Теплогенератор и устройство для нагрева жидкостей |
UA7205A (ru) | 1994-09-15 | 1995-06-30 | Юрій Семенович Потапов | Устройство для нагревания жидкости и теплогенератор, который используется в нем |
US6493507B2 (en) * | 1997-01-30 | 2002-12-10 | Ival O. Salyer | Water heating unit with integral thermal energy storage |
RU2142604C1 (ru) * | 1998-01-26 | 1999-12-10 | Петраков Александр Дмитриевич | Способ получения энергии и резонансный насос-теплогенератор |
RU2160417C2 (ru) * | 1998-05-29 | 2000-12-10 | Петраков Александр Дмитриевич | Насос-теплогенератор |
UA47535C2 (ru) | 2000-05-18 | 2002-07-15 | Леонід Павлович Фоминський | Способ получения тепла |
RU2165054C1 (ru) * | 2000-06-16 | 2001-04-10 | Юрий Семенович Потапов | Способ получения тепла |
AT410591B (de) * | 2001-10-04 | 2003-06-25 | Newtech Innovations & Technolo | Wärmegenerator |
-
2003
- 2003-12-31 UA UA20031213218A patent/UA66334C2/ru unknown
-
2004
- 2004-03-31 CA CA002554673A patent/CA2554673A1/en not_active Abandoned
- 2004-03-31 DE DE502004008603T patent/DE502004008603D1/de not_active Expired - Lifetime
- 2004-03-31 US US10/584,796 patent/US20070152077A1/en not_active Abandoned
- 2004-03-31 AT AT04724932T patent/ATE416350T1/de active
- 2004-03-31 PL PL04724932T patent/PL1706679T3/pl unknown
- 2004-03-31 EP EP04724932A patent/EP1706679B1/de not_active Expired - Lifetime
- 2004-03-31 EA EA200601256A patent/EA008132B1/ru not_active IP Right Cessation
- 2004-03-31 CN CN2004800420074A patent/CN1918440B/zh not_active Expired - Fee Related
- 2004-03-31 WO PCT/UA2004/000019 patent/WO2005064244A1/ru active Application Filing
Also Published As
Publication number | Publication date |
---|---|
US20070152077A1 (en) | 2007-07-05 |
UA66334A (ru) | 2004-04-15 |
UA66334C2 (ru) | 2008-12-10 |
CN1918440B (zh) | 2010-06-16 |
EA008132B1 (ru) | 2007-04-27 |
EA200601256A1 (ru) | 2006-10-27 |
DE502004008603D1 (de) | 2009-01-15 |
CA2554673A1 (en) | 2005-07-14 |
CN1918440A (zh) | 2007-02-21 |
WO2005064244A1 (fr) | 2005-07-14 |
ATE416350T1 (de) | 2008-12-15 |
PL1706679T3 (pl) | 2009-07-31 |
EP1706679A1 (en) | 2006-10-04 |
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