EP1706584A2 - Messeinrichtung und bohrvorrichtung für tiefbohrungen - Google Patents

Messeinrichtung und bohrvorrichtung für tiefbohrungen

Info

Publication number
EP1706584A2
EP1706584A2 EP04804461A EP04804461A EP1706584A2 EP 1706584 A2 EP1706584 A2 EP 1706584A2 EP 04804461 A EP04804461 A EP 04804461A EP 04804461 A EP04804461 A EP 04804461A EP 1706584 A2 EP1706584 A2 EP 1706584A2
Authority
EP
European Patent Office
Prior art keywords
measuring device
measuring
packer
drill pipe
unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP04804461A
Other languages
German (de)
English (en)
French (fr)
Inventor
Magdalena Rotthäuser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DTB Patente GmbH
Original Assignee
DTB Patente GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DTB Patente GmbH filed Critical DTB Patente GmbH
Publication of EP1706584A2 publication Critical patent/EP1706584A2/de
Withdrawn legal-status Critical Current

Links

Classifications

    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B47/00Survey of boreholes or wells
    • E21B47/01Devices for supporting measuring instruments on drill bits, pipes, rods or wirelines; Protecting measuring instruments in boreholes against heat, shock, pressure or the like
    • E21B47/013Devices specially adapted for supporting measuring instruments on drill bits
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/003Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings with electrically conducting or insulating means
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B17/00Drilling rods or pipes; Flexible drill strings; Kellies; Drill collars; Sucker rods; Cables; Casings; Tubings
    • E21B17/02Couplings; joints
    • E21B17/028Electrical or electro-magnetic connections
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/12Packers; Plugs
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B47/00Survey of boreholes or wells
    • E21B47/12Means for transmitting measuring-signals or control signals from the well to the surface, or from the surface to the well, e.g. for logging while drilling
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B49/00Testing the nature of borehole walls; Formation testing; Methods or apparatus for obtaining samples of soil or well fluids, specially adapted to earth drilling or wells
    • E21B49/08Obtaining fluid samples or testing fluids, in boreholes or wells
    • E21B49/084Obtaining fluid samples or testing fluids, in boreholes or wells with means for conveying samples through pipe to surface

Definitions

  • the present invention relates to a measuring device according to the preamble of claim 1 and a drilling device according to claim 16.
  • EP 0 102 672 B1 discloses a measuring device for connection to a pipe string for deep drilling, with an electrically operated measuring unit for measuring relevant data, the measuring device being designed to supply electrical energy via the pipe string.
  • the measuring device converts soil properties into electrical signals and is driven into the soil for soil investigations. Due to the arrangement of the measuring device provided at the end of the drill pipe, only known measurement data can be recorded with the known measuring device which relate to the bottom area surrounding the measuring head at the end of the drill pipe. With the known measuring device it is not possible to record measurement data above the bottom of the borehole.
  • the object of the present invention is to further develop a measuring device according to the preamble of claim 1.
  • the measuring device can in principle be provided at any point in the drill string.
  • the measuring device can be arranged immediately after the chisel unit, so that measured values can be taken from the bottom of the borehole.
  • the arrangement of several measuring devices in a drill string is also readily possible.
  • the measuring device is supplied with electrical energy via the drill pipe. In the same way, the data or signal transfer from the measuring device to the surface takes place.
  • An evaluation device is then provided above ground, the measuring device being electrically coupled to the evaluation device. The electrical coupling serves on the one hand for data or signal transfer from the measuring device to Above ground and can also be used to transfer control commands.
  • the measuring device has a stable outer housing for receiving and thus for protecting the individual functional units.
  • the housing In order to be integrated into the drill string or the drill string or to be connected to parts of the drill string, the housing has screw connections at both ends.
  • the screw connections should preferably have an internal thread, so that the housing corresponds to a sleeve from the connection.
  • the functional units of the measuring device can include a converter, in particular a voltage converter, which converts the measuring signals received by the measuring unit, so that the converted signals, which may have a different frequency than the electrical energy supplied, are correctly recognized by the evaluation device.
  • the evaluation device can also be designed such that the measurement signals are derived from the energy consumption of the measurement unit.
  • the measuring unit can have a plurality of measuring devices for recording different data.
  • all known methods for measurement and / or analysis can be used here, it being understood that a correspondingly robust design is provided with regard to the conditions in the borehole.
  • the structure of the individual measuring devices can be modular, so that, if necessary, one type of measuring device can be exchanged for another type of measuring device if the measuring device is used for another application.
  • the sensor system of the measuring unit it is possible to provide the sensor system of the measuring unit on the outside of the housing, so that the measured values are taken from the medium flowing past the outside of the housing.
  • the sensor system it is advisable to provide the sensor system in a flow path within the housing.
  • at least one electrically operated, in flow connection with the measuring unit standing pump provided.
  • an electrically operated two-way valve in connection with the measuring unit, in order to discharge the examined medium either into the annular space or into the drill pipe if necessary.
  • An upstream filter can largely prevent damage to the pump and / or the sensor system.
  • the flow path to the pump can be closed by upstream valves, which is important if, for certain reasons, no measurement is to be carried out and no medium is to get into the measuring device.
  • the measuring device has an electrically, in particular electrohydraulically operated, packer.
  • the packer is intended for dividing the annular space into a section above the packer and a section below the packer. The two sections are effectively sealed.
  • the packer When the packer is retracted, it does not protrude beyond the housing, or only slightly. In the extended state, the packer lies against the borehole wall.
  • the packer In order to achieve a quasi-sealing function, the packer has a plurality of packer segments which at least partially overlap at least in the retracted state.
  • a particularly electrically operated lubricant supply device is provided above the packer, through which a layer of lubricant is applied to the top of the packer segments in the extended state or when the packer segments are extended.
  • the lubricant layer serves on the one hand as a protective layer and on the other hand as a sliding layer, which promotes the re-entry of the packer into the housing.
  • the pump is designed to lower the annular space level below the packer when the packer is in the extended state.
  • the inflow opening of the housing into the measuring device is provided below the packer, while the outflow opening in the housing is above the packer.
  • control unit for controlling the functional units as required. If necessary, the control unit is controlled from above ground via the evaluation device in which the measured values are displayed, evaluated and processed.
  • a generator provided above ground is usually used to supply energy to the measuring device.
  • the measuring device In order to ensure the functioning of the measuring device even in the event of malfunctions of the generator, the measuring device has an energy store for an emergency power supply. Ultimately, this is an accumulator provided in the housing.
  • 1 is a schematic view of a drill pipe placed in a borehole
  • FIG. 2 is a schematic view of the pipe end of a drill pipe
  • FIG. 3 is a schematic view of part of a sleeve
  • FIG. 6 is a detailed view of a sleeve
  • Fig. 7 is a schematic partial view of a drill pipe screwed into a sleeve
  • Fig. 8 is a schematic view of a measuring device according to the invention.
  • a drilling device 1 is shown schematically.
  • the drilling device 1 has a drilling head 2 arranged above ground and a drill pipe 3, which is located in a borehole 4 in the drilling state.
  • a chisel unit 5 At the lower end of the drill pipe 3 there is a chisel unit 5.
  • a measuring device 6 directly above the chisel unit 5, which is connected via a conductor 7 to an evaluation device 8 located above ground.
  • the measuring device 6 makes it possible to record measured values during drilling, which can then be evaluated directly via the evaluation device 8.
  • the drill pipe 3 itself is composed of a large number of alternately arranged drill pipes 10 and sleeves 11.
  • Drill pipes 10 of the type in question can have a length of up to 10 m and longer, while drill pipes 3 for deep drilling can have a length of several thousand meters.
  • FIG. 2 A part of a drill pipe 10 is shown in FIG. 2 and in a detailed representation according to FIG. 4.
  • the drill pipe 10 has a drill pipe body 12 made of electrically conductive material. It is now provided that at least one electrical pipe conductor 7a is passed through the drill pipe body 12 and is connected at the end, at both ends, to a pipe contact connection 13 provided on the drill pipe body 12, the pipe conductor 7a and the pipe contact connection 13 opposite the pipe pipe body 12 are electrically isolated.
  • the pipe conductor 7a is fixed on the inside 14 of the pipe.
  • a longitudinal groove 15 for the pipe conductor 7a is provided on the inside of the pipe 14. In the present case, the groove 15 is dovetailed tail-shaped.
  • the groove 15 runs parallel to the central axis of the drill pipe 10. In the present case, the depth of the groove 15 is greater than the outer diameter of the pipe 7a.
  • the pipe conductor 7a is held in the groove 15 via an insulation 16.
  • the insulation 16 also has an electrically insulating function.
  • the pipe conductor 7a has a conductor insulation 17 which extends over the entire length of the pipe conductor 7a.
  • an electrical insulation layer 18 is vapor-deposited on the entire inside of the pipe 14, which also covers the groove 15 and thus the pipe conductor 7a. The insulation layer 18 is applied to the entire inside of the pipe 14.
  • the pipe contact connection 13 is provided on the end face 19 of the pipe end of the drill pipe 10. It goes without saying that a corresponding pipe contact connection 13 is provided at both ends of the drill pipe body 12, even if this is not dealt with in more detail below.
  • the pipe contact connection 13 is circumferential and has the shape of a contact ring. Otherwise, the pipe contact connection 13 is arranged on an insulation ring 20 resting on the end face 19.
  • the insulation ring 20, which consists of an elastic material, has an annular groove 21 for receiving the pipe contact connection 13.
  • the annular groove 21 is deeper than the height of the pipe contact connection 13.
  • the pipe contact connection 13 is spring-loaded in the direction away from the end face 19, namely in the direction of the sleeve 11 to be connected to the drill pipe 10.
  • a pin 22 on which an external thread 23 is provided.
  • a step 24 which at its end merges into the tube outside 25.
  • a circumferential seal 26 which in the present case is an O-ring.
  • an annular seal can be arranged on the step 24.
  • a part of a sleeve 11 is shown in FIG. 4 and in the detailed representation according to FIG. 6.
  • the sleeve 11 has a sleeve body 27 made of electrically conductive material.
  • An electrical sleeve conductor 7b is passed through the sleeve body 27 and is connected at the end, at both ends of the sleeve body 27, to sleeve contact connections 28, even if this is not shown in detail.
  • the socket conductor 7b and the socket contact connections 28 are electrically insulated from the socket body 27.
  • the socket conductor 7b is fixed on the inside of the socket 29.
  • a longitudinal groove 30 is provided on the inside of the sleeve 29 of the sleeve body 27.
  • the groove 30 is formed in the same way as the groove 15. Otherwise, the groove 30 runs parallel to the central axis of the sleeve 11. It is not shown that the sleeve conductor 7b is cast into the groove 30 via insulation and is otherwise covered by a conductor insulation , Furthermore, an electrical insulation layer 31, which also covers the socket conductor 7b, is vapor-deposited on the inside of the socket 29 as well as on the inside of the pipe 14.
  • the socket contact connection 28 is provided on an end shoulder 32.
  • the shoulder 32 is located between the internal thread 33 and the inside of the socket 29.
  • the socket contact connection 28 is formed all the way round and is arranged on an insulation ring 20 resting on the shoulder 32.
  • the type and structure of the insulation ring 20 corresponds to the insulation ring 20 provided on the drill pipe 10, that is to say it has an annular groove 21 for receiving the socket contact connection 28, the annular groove 21 being deeper than the height of the socket contact connection 28. Otherwise, the socket contact connection 28 is in the direction of the shoulder 32 spring loaded away.
  • the spring loading can be designed with respect to the contact connections 13, 28 such that one or a plurality of springs, for example small helical compression springs, act on the respective underside of the contact connection.
  • spring tongues can be provided on the respective contact connection.
  • the spring tongues can in principle be directed inwards and / or outwards, spring tongues pointing outwards then projecting beyond the actual contact connection and being able to effect the electrical contact.
  • the outer end face 34 is located between the internal thread 33 and the sleeve outside 36.
  • the drill pipes 10 and sleeves 11 described in the previously formed manner in connection with the pipe conductors 7a and sleeve conductors 7b result in a two-pole energy and data transmission system via the drill pipe 3.
  • the one pole is formed by the drill pipe body, which consists of the drill pipe bodies 12 and the sleeve bodies 27, while the other pole is formed by the conductor 7, which is composed of the pipe conductors 7a and the sleeve conductors 7b and the contact connections 13 and 28.
  • the system according to the invention also has the advantage that the drill pipe 3 and thus the two poles can be extended as desired, since the electrical connection via the contact connections 13, 28 on the one hand and the material of the drill pipe body can be achieved by screwing a drill pipe 10 with a sleeve 11 12 and the sleeve body 27 on the other hand results.
  • the energy is fed in or data is taken from the conductor 7 via a slip ring collector (not shown), which is provided on the first drill pipe 10.
  • the slip ring collector is connected to the pipe conductor 7a and insulated from the drill pipe body 12.
  • the slip ring collector is in turn connected to the evaluation device 8, while the drill rod body forms the ground connection.
  • the measuring device 6 shows a schematic illustration of the measuring device 6.
  • the measuring device 6 is connected to the last drill pipe 10 of the drill pipe 3.
  • the measuring device 6 has an electrically operated measuring unit 40 with which it is possible to measure relevant data about the state of the rock, the drilling fluid or the raw material to be extracted.
  • the measuring device 6 is supplied with electrical energy via the conductor 7 described above. It goes without saying that the measuring device 6 has a contact connection corresponding to the contact connections 13, 28 and a continuation of the conductor 7, even if this is not shown in detail.
  • the measuring device 6 has an outer housing 41 in which the measuring unit 40 and further functional units, which will be discussed in more detail below, are accommodated.
  • the housing 41 has screw connections 42, 43 at both ends thereof.
  • the screw connections 42, 43 correspond to those of the sleeve 11.
  • the measuring device 6 can be integrated into the drill pipe 3.
  • the measuring device 6 has a converter 44 for converting measurement signals received via the measuring unit 40 for subsequent transfer to the evaluation device 8. It is not shown that the measuring unit 40 can have a plurality of different measuring devices for recording the most varied data of the medium in question.
  • the individual measuring devices should have a modular structure, so that it is possible to replace measuring devices if necessary.
  • the sensors or the measurement sensors are provided in the flow path 45 within the housing 41. In principle, however, it is also possible for the measured value recorders to be directed outward into the annular space via external openings in the housing 41.
  • an electrically operated pump 46 which supplies the medium to be examined via the flow path 45 to the measuring unit 40.
  • An electrically operated valve unit 47 with at least one two-way valve is provided above the measuring unit 40 in order to discharge the examined medium into the annular space or via the drill pipe 3, if necessary.
  • corresponding outflow openings 48 are provided in the housing 41.
  • at least one filter 49 and one valve unit 50 are connected upstream of the pump 46.
  • the valve unit 50 serves to close the inflow openings 51 provided in the housing 41.
  • An electrohydraulic packer 52 is also provided.
  • the packer 52 has a plurality of packer segments, not shown in detail. In the retracted state of the packer 52, which is shown in FIG. 8, the packer segments overlap at least partially.
  • the packer 52 as a whole is constructed in such a way that it separates the annular space in an upper and lower part in the extended state and at least essentially seals these sections.
  • a lubricant supply device 53 which serves to apply a layer of lubricant to the top of the packer segments in the extended state.
  • the lubricant supply device 53 can be operated electrically or else mechanically.
  • the mechanically operated lubricant supply is preferably mechanically coupled to the packer 52 in that the lubricant supply is actuated when the packer segments are extended.
  • the measuring device 6 in the present case has a control unit 54 for controlling the individual functional units as required and an energy store 55.
  • the aforementioned functional units do not necessarily have to be arranged in the order shown. If the function of the measuring device 6 is not called into question, other arrangements can also be selected. It should be noted, however, that the packer 52 is located between the lower inlet openings 51 and the upper outflow openings 48, so that it is possible to lower the annular space level below the extended packer 52 by means of the pump 46.
  • Measuring device 6 are electrically connected to the two poles described above, so that an electrical power supply and, insofar as Measuring unit 40 or the control unit 54 are affected, data exchange with the evaluation device 8 is possible.
  • the measuring device 6 in which the drill string in the housing 41 of the measuring device 6 is open, it is in principle also possible for the measuring device 6 to have a through-tube section which is either on both sides or at one end with the drill pipe and at the other end with the Chisel unit 5 is connected.
  • the medium is then led through corresponding flow paths through the housing and also past the measuring unit 40.
  • the medium that has already been measured is either released into a drill string or into the annular space.
  • a corresponding valve unit opening into the drill string is required in this case.
  • the invention makes it possible to continuously measure the state of the medium in the borehole before, during and after drilling.
  • the data can be evaluated in the evaluation device 8 immediately. For example, hydrological changes during drilling are recognized immediately and testing is also possible immediately.
  • the non-return flap 56 closes off the drill pipe while the packer 52 is being extended.
  • the pump 46 requests the medium after the outflow openings 48 have been closed by means of the valve unit 47 through the drill string to the surface.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Fluid Mechanics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Remote Sensing (AREA)
  • Geophysics (AREA)
  • Mechanical Engineering (AREA)
  • Earth Drilling (AREA)
  • Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
  • Geophysics And Detection Of Objects (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
EP04804461A 2004-01-22 2004-12-31 Messeinrichtung und bohrvorrichtung für tiefbohrungen Withdrawn EP1706584A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004003481A DE102004003481B4 (de) 2004-01-22 2004-01-22 Meßeinrichtung und Bohrvorrichtung für Tiefbohrungen sowie Verfahren zur Messung relevanter Daten bei Tiefbohrungen
PCT/EP2004/014877 WO2005071224A2 (de) 2004-01-22 2004-12-31 MEßEINRICHTUNG UND BOHRVORRICHTUNG FÜR TIEFBOHRUNGEN

Publications (1)

Publication Number Publication Date
EP1706584A2 true EP1706584A2 (de) 2006-10-04

Family

ID=34800946

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04804461A Withdrawn EP1706584A2 (de) 2004-01-22 2004-12-31 Messeinrichtung und bohrvorrichtung für tiefbohrungen

Country Status (18)

Country Link
US (1) US20070175663A1 (ja)
EP (1) EP1706584A2 (ja)
JP (1) JP2007518905A (ja)
CN (1) CN1906379A (ja)
AP (1) AP2006003680A0 (ja)
AU (1) AU2004314380A1 (ja)
BR (1) BRPI0418436A (ja)
CA (1) CA2544711A1 (ja)
DE (1) DE102004003481B4 (ja)
EA (1) EA200601342A1 (ja)
EC (1) ECSP066719A (ja)
MA (1) MA28297A1 (ja)
MX (1) MXPA06007946A (ja)
NO (1) NO20061988L (ja)
RS (1) RS20060313A (ja)
TN (1) TNSN06230A1 (ja)
WO (1) WO2005071224A2 (ja)
ZA (1) ZA200605652B (ja)

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US7913774B2 (en) 2005-06-15 2011-03-29 Schlumberger Technology Corporation Modular connector and method
GB2454699B (en) * 2007-11-15 2012-08-15 Schlumberger Holdings Measurements while drilling or coring using a wireline drilling machine
US9558894B2 (en) 2011-07-08 2017-01-31 Fastcap Systems Corporation Advanced electrolyte systems and their use in energy storage devices
KR102413496B1 (ko) 2011-07-08 2022-06-24 패스트캡 시스템즈 코포레이션 고온 에너지 저장 장치
EP3798410A1 (en) * 2011-07-27 2021-03-31 FastCAP SYSTEMS Corporation Power supply for downhole instruments
CA3115288A1 (en) 2011-11-03 2013-05-10 Fastcap Systems Corporation Production logging instrument
US9366094B2 (en) * 2012-11-30 2016-06-14 Intelliserv, Llc Pipe joint having coupled adapter
US10872737B2 (en) 2013-10-09 2020-12-22 Fastcap Systems Corporation Advanced electrolytes for high temperature energy storage device
WO2015095858A2 (en) 2013-12-20 2015-06-25 Fastcap Systems Corporation Electromagnetic telemetry device
CN116092839A (zh) 2015-01-27 2023-05-09 快帽系统公司 宽温度范围超级电容器
CN105482996B (zh) * 2016-01-06 2018-01-30 西北工业大学 三维细胞培养支架力学刺激加载装置
WO2018224703A1 (es) * 2017-06-09 2018-12-13 Consejo Superior De Investigaciones Cientificas (Csic) Sonda multiparamétrica para la monitorización de medios subterráneos

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US4570481A (en) * 1984-09-10 1986-02-18 V.E. Kuster Company Instrument locking and port bundle carrier
GB8714754D0 (en) * 1987-06-24 1987-07-29 Framo Dev Ltd Electrical conductor arrangements
US5404946A (en) * 1993-08-02 1995-04-11 The United States Of America As Represented By The Secretary Of The Interior Wireline-powered inflatable-packer system for deep wells
US6581455B1 (en) * 1995-03-31 2003-06-24 Baker Hughes Incorporated Modified formation testing apparatus with borehole grippers and method of formation testing
US5803186A (en) * 1995-03-31 1998-09-08 Baker Hughes Incorporated Formation isolation and testing apparatus and method
US6820702B2 (en) * 2002-08-27 2004-11-23 Noble Drilling Services Inc. Automated method and system for recognizing well control events

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Also Published As

Publication number Publication date
AP2006003680A0 (en) 2006-08-31
MA28297A1 (fr) 2006-11-01
NO20061988L (no) 2006-08-21
RS20060313A (en) 2007-12-31
DE102004003481A1 (de) 2005-08-25
US20070175663A1 (en) 2007-08-02
CN1906379A (zh) 2007-01-31
WO2005071224A2 (de) 2005-08-04
ZA200605652B (en) 2007-11-28
ECSP066719A (es) 2006-10-31
CA2544711A1 (en) 2005-08-04
JP2007518905A (ja) 2007-07-12
BRPI0418436A (pt) 2007-05-22
MXPA06007946A (es) 2007-01-31
TNSN06230A1 (en) 2007-12-03
DE102004003481B4 (de) 2007-01-25
EA200601342A1 (ru) 2007-06-29
AU2004314380A1 (en) 2005-08-04
WO2005071224A3 (de) 2005-11-03

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