EP1687471A1 - Fil composite comprenant un fil continu et une matrice comprenant un polym re mousse - Google Patents
Fil composite comprenant un fil continu et une matrice comprenant un polym re mousseInfo
- Publication number
- EP1687471A1 EP1687471A1 EP04805560A EP04805560A EP1687471A1 EP 1687471 A1 EP1687471 A1 EP 1687471A1 EP 04805560 A EP04805560 A EP 04805560A EP 04805560 A EP04805560 A EP 04805560A EP 1687471 A1 EP1687471 A1 EP 1687471A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- yarn
- composite
- foaming system
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 78
- 239000011159 matrix material Substances 0.000 title claims abstract description 37
- 229920000642 polymer Polymers 0.000 title claims abstract description 37
- 238000005187 foaming Methods 0.000 claims abstract description 44
- 238000000576 coating method Methods 0.000 claims abstract description 37
- 239000011248 coating agent Substances 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 35
- 238000001125 extrusion Methods 0.000 claims abstract description 27
- 239000011368 organic material Substances 0.000 claims abstract description 24
- 239000011147 inorganic material Substances 0.000 claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 claims abstract description 22
- 238000009987 spinning Methods 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 238000002360 preparation method Methods 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 10
- 238000000926 separation method Methods 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims description 74
- 239000002861 polymer material Substances 0.000 claims description 60
- 229910010272 inorganic material Inorganic materials 0.000 claims description 20
- 239000000945 filler Substances 0.000 claims description 19
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 14
- 239000003063 flame retardant Substances 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 11
- 239000011521 glass Substances 0.000 claims description 11
- 239000004800 polyvinyl chloride Substances 0.000 claims description 11
- 229920000098 polyolefin Polymers 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- -1 polytetrafluoroethylene Polymers 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 229920006397 acrylic thermoplastic Polymers 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 229920000742 Cotton Polymers 0.000 claims description 3
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 3
- 206010047289 Ventricular extrasystoles Diseases 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- BHTBHKFULNTCHQ-UHFFFAOYSA-H zinc;tin(4+);hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Sn+4] BHTBHKFULNTCHQ-UHFFFAOYSA-H 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 239000004753 textile Substances 0.000 description 14
- 239000004744 fabric Substances 0.000 description 8
- 239000004014 plasticizer Substances 0.000 description 7
- 229920001944 Plastisol Polymers 0.000 description 6
- 239000004999 plastisol Substances 0.000 description 6
- 238000009941 weaving Methods 0.000 description 6
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000004156 Azodicarbonamide Substances 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 3
- 235000019399 azodicarbonamide Nutrition 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000003017 thermal stabilizer Substances 0.000 description 3
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 102100035474 DNA polymerase kappa Human genes 0.000 description 2
- 101710108091 DNA polymerase kappa Proteins 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 230000004584 weight gain Effects 0.000 description 2
- 235000019786 weight gain Nutrition 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- KLLLJCACIRKBDT-UHFFFAOYSA-N 2-phenyl-1H-indole Chemical compound N1C2=CC=CC=C2C=C1C1=CC=CC=C1 KLLLJCACIRKBDT-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000013475 authorization Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 239000005078 molybdenum compound Chemical class 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
- D02G3/404—Yarns or threads coated with polymeric solutions
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2935—Discontinuous or tubular or cellular core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
Definitions
- the present invention makes it possible to limit or even eliminate the use of opacifying fillers in the polymer materials used for the manufacture of these composite threads.
- This process in addition to requiring operations to treat the textile obtained, does not make it possible to obtain a yarn whose fibers are distributed uniformly in the matrix formed around the fibers.
- the present invention solves the problems of the prior art and relates to a composite wire comprising a continuous wire made of an inorganic or organic material and a matrix of polymeric material, said continuous wire being coated, coated, extruded or incorporated in said matrix of polymer material, characterized in that said matrix comprises at least one foamed polymer.
- coated wire, coated, extruded or incorporated in a matrix of polymer material any wire covered or embedded in a matrix of polymer material capable of being obtained by dipping, extrusion, coating, coextrusion of the fibers and the matrix, mixture of fibers followed by a melting of part of the fibers, co-spinning followed by melting and any other industrializable process capable of obtaining a composite yarn according to the invention.
- chlorinated polymer By way of chlorinated polymer, mention may be made, for example, of polyvinyl chloride but also superchlorinated PVCs, polyvinylidene chlorides and chlorinated polyolefins.
- the chlorinated polymer material according to the present invention has a halogen content by weight of between 40 and 70%.
- silicone polymer material organopolysiloxanes and more particularly resins and elastomers of polysiloxane with or without diluent can be used according to the invention.
- polyurethane polymer material one can use according to the invention any material consisting of a hydrocarbon chain comprising the urethane or -NHCOO- unit.
- said coating can be carried out with a liquid preparation of monomer or of polymer, for example a liquid preparation of polymer obtained by melting of a polymer or by dispersion, for example in the form of plastisol, and for example a liquid monomer preparation consisting of a liquid monomer which will polymerize under the effect of heat or by irradiation, for example UV irradiation.
- a liquid preparation of monomer or of polymer for example a liquid preparation of polymer obtained by melting of a polymer or by dispersion, for example in the form of plastisol
- a liquid monomer preparation consisting of a liquid monomer which will polymerize under the effect of heat or by irradiation, for example UV irradiation.
- traditional plasticizers for example comprising at least one phthalate, and therefore not to compromise the processing properties of the wire, with respect to its subsequent weaving.
- the composite yarn can then be assembled on itself, in any suitable knitted textile structure, but it can be assembled with other yarns, according to the present invention or not, to constitute different two-dimensional or three-dimensional structures; in the latter case, it may be grids in which the threads according to the present invention are crisscrossed and fixed with other threads, according to the present invention or not, and fabrics, in which the composite threads according to the invention are woven with other warp and / or weft threads, also according to the invention or not.
- a very particular application of the present invention relates to obtaining technical fabrics, intended for the realization or manufacture of blinds or curtains both inside and outside.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Multicomponent Fibers (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0313813A FR2862664B1 (fr) | 2003-11-25 | 2003-11-25 | Fil composite comprenant un fil continu et une matrice comprenant un polymere mousse |
PCT/FR2004/003032 WO2005052232A1 (fr) | 2003-11-25 | 2004-11-25 | Fil composite comprenant un fil continu et une matrice comprenant un polymère mousse |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1687471A1 true EP1687471A1 (fr) | 2006-08-09 |
EP1687471B1 EP1687471B1 (fr) | 2008-05-21 |
Family
ID=34531256
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04805560A Active EP1687471B1 (fr) | 2003-11-25 | 2004-11-25 | Fil composite comprenant un fil continu et une matrice comprenant un polym re mousse |
Country Status (14)
Country | Link |
---|---|
US (1) | US7718259B2 (fr) |
EP (1) | EP1687471B1 (fr) |
JP (1) | JP2007512447A (fr) |
KR (1) | KR20060124659A (fr) |
CN (1) | CN1882730A (fr) |
AT (1) | ATE396292T1 (fr) |
AU (1) | AU2004293611A1 (fr) |
BR (1) | BRPI0416890A (fr) |
CA (1) | CA2547054A1 (fr) |
DE (1) | DE602004014017D1 (fr) |
DK (1) | DK1687471T3 (fr) |
ES (1) | ES2304637T3 (fr) |
FR (1) | FR2862664B1 (fr) |
WO (1) | WO2005052232A1 (fr) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9045845B2 (en) * | 2001-12-28 | 2015-06-02 | Chavanoz Industrie | Composite yarn, method for obtaining same and resulting textile structure |
US20040260034A1 (en) | 2003-06-19 | 2004-12-23 | Haile William Alston | Water-dispersible fibers and fibrous articles |
US7892993B2 (en) | 2003-06-19 | 2011-02-22 | Eastman Chemical Company | Water-dispersible and multicomponent fibers from sulfopolyesters |
US8513147B2 (en) | 2003-06-19 | 2013-08-20 | Eastman Chemical Company | Nonwovens produced from multicomponent fibers |
FR2862664B1 (fr) * | 2003-11-25 | 2006-03-17 | Chavanoz Ind | Fil composite comprenant un fil continu et une matrice comprenant un polymere mousse |
US7785509B2 (en) | 2005-12-21 | 2010-08-31 | Pascale Industries, Inc. | Expansible yarns and threads, and products made using them |
US7635745B2 (en) * | 2006-01-31 | 2009-12-22 | Eastman Chemical Company | Sulfopolyester recovery |
FR2939152B1 (fr) | 2008-12-01 | 2011-05-06 | Porcher Ind | Fil composite photoluminescent, procede d'obtention et structure textile obtenue |
US8512519B2 (en) | 2009-04-24 | 2013-08-20 | Eastman Chemical Company | Sulfopolyesters for paper strength and process |
FR2949125B1 (fr) * | 2009-08-11 | 2012-07-13 | David Ambs | Renfort composite a base de fibres naturelles |
US20120183861A1 (en) | 2010-10-21 | 2012-07-19 | Eastman Chemical Company | Sulfopolyester binders |
US8882963B2 (en) | 2012-01-31 | 2014-11-11 | Eastman Chemical Company | Processes to produce short cut microfibers |
US20130260104A1 (en) * | 2012-04-03 | 2013-10-03 | Nike, Inc. | Yarns, Threads, And Textiles Incorporating A Thermoplastic Polymer Material |
US20130255103A1 (en) | 2012-04-03 | 2013-10-03 | Nike, Inc. | Apparel And Other Products Incorporating A Thermoplastic Polymer Material |
US9303357B2 (en) | 2013-04-19 | 2016-04-05 | Eastman Chemical Company | Paper and nonwoven articles comprising synthetic microfiber binders |
US9598802B2 (en) | 2013-12-17 | 2017-03-21 | Eastman Chemical Company | Ultrafiltration process for producing a sulfopolyester concentrate |
US9605126B2 (en) | 2013-12-17 | 2017-03-28 | Eastman Chemical Company | Ultrafiltration process for the recovery of concentrated sulfopolyester dispersion |
US10053801B2 (en) | 2014-01-28 | 2018-08-21 | Inman Mills | Sheath and core yarn for thermoplastic composite |
US20160030789A1 (en) * | 2014-06-06 | 2016-02-04 | GeITech Solutions, Inc. | Colorized fire extinguishing compositions |
KR101561890B1 (ko) * | 2014-08-22 | 2015-10-26 | 주식회사 덕성 | 원사 코팅용 수성 열경화성 우레탄 컴파운드 및 이를 코팅한 코팅 원사의 제조방법 |
WO2016050603A1 (fr) | 2014-10-01 | 2016-04-07 | Sika Technology Ag | Procédé de fabrication et composition pour protections de blindage de canalisation en pvc-p expansé |
CN104562352A (zh) * | 2014-12-16 | 2015-04-29 | 周劲松 | 一种线束保护用涂层纱线 |
CN106192064B (zh) * | 2016-06-21 | 2018-07-06 | 胡剑锋 | 医用材料 |
FR3080387B1 (fr) * | 2018-04-20 | 2020-11-13 | Mermet | Fil composite renforce, procede de preparation et textile comprenant un tel fil |
CN108699732A (zh) * | 2018-05-17 | 2018-10-23 | 福建华彩新材料有限公司 | 一种共混聚合物纤维的制备工艺 |
WO2020055680A1 (fr) * | 2018-09-12 | 2020-03-19 | Inman Mills | Tissu tissé à canal creux destiné à empêcher les dommages structurels causés à un fil fonctionnel, fil monofilament ou fil contenu dans celui-ci |
DE112018008059T5 (de) * | 2018-10-08 | 2021-08-26 | Fujian Huafeng New Material Co., Ltd. | Verfahren zur Herstellung eines Garns mit Batikeffekt |
EP3939463A1 (fr) | 2019-08-02 | 2022-01-19 | NIKE Innovate C.V. | Semelle extérieure pour chaussure |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2224274A (en) * | 1938-08-26 | 1940-12-10 | Milton A Powers | Fabric material |
US3508990A (en) * | 1965-10-24 | 1970-04-28 | Owens Corning Fiberglass Corp | Method of producing a multi-element glass cord construction |
US3551281A (en) * | 1966-07-29 | 1970-12-29 | Sekisui Chemical Co Ltd | Laminated safety glass with polyvinylacetal interlayer containing organotin compound |
US3615970A (en) * | 1969-01-10 | 1971-10-26 | Burlington Industries Inc | Glass fiber fabric for drapery |
US3551280A (en) * | 1969-04-01 | 1970-12-29 | Delta Rope & Twine Ltd | Synthetic twines and method of production thereof |
US3761346A (en) * | 1969-12-29 | 1973-09-25 | Owens Corning Fiberglass Corp | Composite linear material and process of making such material |
US3785919A (en) * | 1971-11-09 | 1974-01-15 | Du Pont | Composite filament with elastomeric core and microapertured polypropylene foam sheath and process therefor |
GB2032483B (en) * | 1978-10-17 | 1982-11-03 | Engineered Yarns Inc | Bonded fabrik of multifilament core yarn |
US4265972A (en) * | 1979-03-09 | 1981-05-05 | Bernard Rudner | Coated fibers and related process |
JPS6228443A (ja) * | 1985-07-25 | 1987-02-06 | 増田 照雄 | 緯入れ用ノズルへの圧力水供給装置 |
JPH03174051A (ja) * | 1989-11-30 | 1991-07-29 | Toray Ind Inc | 発泡性布帛および発泡構造体 |
US5278218A (en) * | 1990-12-10 | 1994-01-11 | Rhone-Poulenc Chimie | Zinc stannate/zinc hydroxystannate heat-stabilized chloropolymers |
DE69832822T2 (de) * | 1998-06-19 | 2006-08-31 | Ticona Celstran, Inc., Winona | Beschichtete langfaserige verstärkungsverbundstruktur und verfahren zu deren herstellung |
JP3733317B2 (ja) * | 2001-10-31 | 2006-01-11 | 日本ポリプロ株式会社 | 難燃性ポリプロピレン系繊維 |
FR2834302B1 (fr) * | 2001-12-28 | 2005-05-06 | Chavanoz Ind | Fil composite, procede d'obtention et structure textile obtenue |
US7144925B2 (en) * | 2002-05-09 | 2006-12-05 | Dow Global Technologies Inc. | Fire resistance acoustic foam |
DE10331888B4 (de) * | 2003-07-14 | 2005-11-10 | Clariant Gmbh | Elastisches Belagmaterial mit verbesserten Flammschutzeigenschaften sowie ein Verfahren zu dessen Herstellung |
FR2862664B1 (fr) * | 2003-11-25 | 2006-03-17 | Chavanoz Ind | Fil composite comprenant un fil continu et une matrice comprenant un polymere mousse |
JP4244052B2 (ja) * | 2006-06-06 | 2009-03-25 | 信越化学工業株式会社 | 塩化ビニル系樹脂組成物およびその成形体 |
US20080248278A1 (en) * | 2007-04-02 | 2008-10-09 | General Electric Company | Fiber reinforced thermoplastic sheets with surface coverings and methods of making |
-
2003
- 2003-11-25 FR FR0313813A patent/FR2862664B1/fr not_active Expired - Fee Related
-
2004
- 2004-11-25 DE DE602004014017T patent/DE602004014017D1/de active Active
- 2004-11-25 CN CNA2004800344422A patent/CN1882730A/zh active Pending
- 2004-11-25 US US10/579,232 patent/US7718259B2/en not_active Expired - Fee Related
- 2004-11-25 DK DK04805560T patent/DK1687471T3/da active
- 2004-11-25 BR BRPI0416890-9A patent/BRPI0416890A/pt not_active IP Right Cessation
- 2004-11-25 CA CA002547054A patent/CA2547054A1/fr not_active Abandoned
- 2004-11-25 JP JP2006540540A patent/JP2007512447A/ja active Pending
- 2004-11-25 ES ES04805560T patent/ES2304637T3/es active Active
- 2004-11-25 WO PCT/FR2004/003032 patent/WO2005052232A1/fr active IP Right Grant
- 2004-11-25 AT AT04805560T patent/ATE396292T1/de active
- 2004-11-25 AU AU2004293611A patent/AU2004293611A1/en not_active Abandoned
- 2004-11-25 EP EP04805560A patent/EP1687471B1/fr active Active
- 2004-11-25 KR KR1020067012785A patent/KR20060124659A/ko not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO2005052232A1 * |
Also Published As
Publication number | Publication date |
---|---|
KR20060124659A (ko) | 2006-12-05 |
CN1882730A (zh) | 2006-12-20 |
JP2007512447A (ja) | 2007-05-17 |
US7718259B2 (en) | 2010-05-18 |
BRPI0416890A (pt) | 2007-02-27 |
DK1687471T3 (da) | 2008-09-29 |
ATE396292T1 (de) | 2008-06-15 |
FR2862664A1 (fr) | 2005-05-27 |
FR2862664B1 (fr) | 2006-03-17 |
DE602004014017D1 (de) | 2008-07-03 |
EP1687471B1 (fr) | 2008-05-21 |
WO2005052232A1 (fr) | 2005-06-09 |
CA2547054A1 (fr) | 2005-06-09 |
ES2304637T3 (es) | 2008-10-16 |
AU2004293611A1 (en) | 2005-06-09 |
US20070048523A1 (en) | 2007-03-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1687471B1 (fr) | Fil composite comprenant un fil continu et une matrice comprenant un polym re mousse | |
EP0900294B1 (fr) | Fil composite | |
EP2480708B1 (fr) | Procédé de fabrication d'un fil composite | |
FR2888255A1 (fr) | Fils de renforcement et composites ayant une tenue au feu amelioree | |
EP1458910B1 (fr) | Fil composite, procede d obtention et structure textil e obtenue | |
CA2365117C (fr) | Composition plastique ignifugeante, fil et textile enduits avec cette derniere | |
FR2933418A1 (fr) | Composition ignifugee a base de pvc. | |
EP3904571A1 (fr) | Fibres synthétiques polymères additionnées de lignine, leur procédé d'obtention et leur utilisation pour la confection de produits textiles | |
EP1550641A2 (fr) | Réseau destiné à la constitution d'écran attenuateur de lumiere et son procédé de fabrication | |
FR3080386A1 (fr) | Fil composite, procede de fabrication et surface textile comprenant un tel fil | |
EP0296988A1 (fr) | Etoffe enduite ignifuge ajourée | |
KR102410883B1 (ko) | 열반사 기능을 갖는 복합사, 이의 제조방법 및 이를 이용한 원단 | |
KR102542019B1 (ko) | 전기방사법을 이용한 고강도 가발 원사용 나노섬유 복합사 및 그 제조 방법 | |
AU2010297202B2 (en) | Composite yarn, method for obtaining same and resulting textile structure | |
IE44756B1 (en) | Monofilament fibre of polymeric material, a method of making said fibre, and pile fabric made from said fibre | |
JP2004029339A (ja) | 難燃性光ファイバケーブルおよびその製造方法 | |
FR2791352A1 (fr) | Composition plastique ignifugeante, fil et structure textile enduits avec cette derniere |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20060509 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR |
|
17Q | First examination report despatched |
Effective date: 20061109 |
|
DAX | Request for extension of the european patent (deleted) | ||
REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1093759 Country of ref document: HK |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LU MC NL PL PT RO SE SI SK TR |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D Free format text: NOT ENGLISH |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REF | Corresponds to: |
Ref document number: 602004014017 Country of ref document: DE Date of ref document: 20080703 Kind code of ref document: P |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D Free format text: LANGUAGE OF EP DOCUMENT: FRENCH |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2304637 Country of ref document: ES Kind code of ref document: T3 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IS Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080921 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081021 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20090224 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 Ref country code: BG Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080821 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: HU Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20081122 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080521 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20080822 |
|
REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1093759 Country of ref document: HK |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DK Payment date: 20131016 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: MC Payment date: 20131018 Year of fee payment: 10 Ref country code: LU Payment date: 20131018 Year of fee payment: 10 Ref country code: DE Payment date: 20131106 Year of fee payment: 10 Ref country code: GB Payment date: 20131112 Year of fee payment: 10 Ref country code: SK Payment date: 20131017 Year of fee payment: 10 Ref country code: AT Payment date: 20131016 Year of fee payment: 10 Ref country code: CH Payment date: 20131127 Year of fee payment: 10 Ref country code: CZ Payment date: 20131018 Year of fee payment: 10 Ref country code: SE Payment date: 20131108 Year of fee payment: 10 Ref country code: IE Payment date: 20131023 Year of fee payment: 10 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20131017 Year of fee payment: 10 Ref country code: TR Payment date: 20131119 Year of fee payment: 10 Ref country code: BE Payment date: 20131128 Year of fee payment: 10 Ref country code: IT Payment date: 20131118 Year of fee payment: 10 Ref country code: ES Payment date: 20131121 Year of fee payment: 10 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 602004014017 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: V1 Effective date: 20150601 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP Effective date: 20141130 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141201 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141130 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 396292 Country of ref document: AT Kind code of ref document: T Effective date: 20141125 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20141125 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141130 Ref country code: SK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141126 Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 Ref country code: CH Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141130 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: MM4A Ref document number: E 3710 Country of ref document: SK Effective date: 20141125 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150601 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141130 Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20150602 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 12 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20160129 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141126 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 13 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20141125 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 14 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230622 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20231012 Year of fee payment: 20 |