EP1644573B1 - Method for the manufacture of awning fabrics - Google Patents

Method for the manufacture of awning fabrics Download PDF

Info

Publication number
EP1644573B1
EP1644573B1 EP04743881A EP04743881A EP1644573B1 EP 1644573 B1 EP1644573 B1 EP 1644573B1 EP 04743881 A EP04743881 A EP 04743881A EP 04743881 A EP04743881 A EP 04743881A EP 1644573 B1 EP1644573 B1 EP 1644573B1
Authority
EP
European Patent Office
Prior art keywords
yarn
weft
warp
fabric
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP04743881A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1644573A1 (en
Inventor
Joan c/o Telya Products S.L. Garzon Romero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Telya Products Sl
Original Assignee
Telya Products Sl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Telya Products Sl filed Critical Telya Products Sl
Publication of EP1644573A1 publication Critical patent/EP1644573A1/en
Application granted granted Critical
Publication of EP1644573B1 publication Critical patent/EP1644573B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00Condition, form or state of the materials
    • D06N2205/10Particulate form, e.g. powder, granule
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/12Permeability or impermeability properties
    • D06N2209/126Permeability to liquids, absorption
    • D06N2209/128Non-permeable
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/14Properties of the materials having chemical properties
    • D06N2209/147Stainproof, stain repellent
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1678Resistive to light or to UV
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/06Building materials
    • D06N2211/063Wall coverings

Definitions

  • the present invention refers to a method to manufacture awning fabrics.
  • US 2001/0031590 A1 discloses awning fabrics which are made from polyester filament yarn (continuous filament yarn) and/or polyester monofilament yarn.
  • the invention of said document has as its object to create awning fabric that has the lowest possible weight per unit area while providing good UV stability and weather resistance.
  • the European patent application num. 1355001 discloses an awning fabric which is formed by weaving, at a high density, high-bulky and texturised polyester filament yarns and then by treating uniformly the inner and outer surfaces of the resulting fabric with a coating solution of polytetrafluoroethylene.
  • the awning fabrics disclosed in these patents have in common that all of them are manufactured with polyolefine yarns obtained from cut fibres, joined by the conventional spinning or ring process, and that the composition of the polyolefinic plastic material used comprises always at least two polymeric components with different melting point; as for example, polypropylene and polyethylene.
  • the aim of the present invention is to solve the mentioned disadvantages by developing a manufacturing method of awning fabrics from continuous filament yarn with a single polymeric component of the polyolefin group, offering the advantages that will be described below.
  • the method of the present invention refers to awning fabrics with warp yarns and weft yarns involving the steps of weaving said warp yarns and said weft yarns with a density over 16 warp yarns per centimetre and 10 weft yarns per centimetre, and treating the fabric by immersion with a water-repellent product, and is characterised in that prior to the weaving step, warp yarns and weft yarns are prepared following the steps of:
  • UV stabiliser it means a product which, when admixed with a thermoplastic resin, selectively absorbs UV rays.
  • the fabrics of the present invention manufactured from continuous filament yarns of a single polymeric component of the polyolefin group, have presented a texture, rigidity and inscription effects optimal to be used in awnings. Furthermore, said fabrics present the advantages which are described below, respect to the fabrics for awnings with polyolefin yarns, described in the state the art.
  • Fabrics of polyolefin obtained by the method of the present invention are very suitable for manufacturing awnings since they have, respect of other polyolefin fabrics of continuous filament known in the state of the art, at the same time, an optimum resistance to wetting, water penetration and bleaching caused by the sunlight.
  • said only polymeric component is polypropylene.
  • the step which involves texturing the warp or weft yarn allow to achieve a natural fibre look of the fabric.
  • step b) a step which involves twisting the weft or warp yarn to make the weaving easier is carried on.
  • the step of texturing is carried on a step which involves twisting the weft or warp yarn.
  • the warp yarn is textured to achieve a natural fibre look, and, at the same time, the weft yarn is twisted to make the yarn weaving easier.
  • the extruded yarn has between 30 and 340 filaments, so that a good texturing of the yarn is carried on.
  • the fabric has 30 warp yarns per centimetre and 15 weft yarns per centimetre, to create a woven structure dense enough to achieve a good resistance to water penetration.
  • the water-repellent product is a fluoro-acrylic copolymer, so that a water penetration resistance between 10 and 80 cm of water column is achieved.
  • the UV stabiliser comprises a Hindered Amine Light Stabiliser (HALS).
  • HALS is a chemically reactive substance that scavenge free radicals, created by the UV light induced degradation of the polymer matrix, which prevents the physical degradation of said polymer.
  • said plastic material comprise between 0.1% and 10% of pigments, to obtain the desired colour.
  • said UV stabilizer product comprises, furthermore, an UV absorber of high molecular weight, which protects from the sun the pigments with comprises the plastic material, and prevents the decolouration of the fabric.
  • the method of manufacturing awning fabrics starts with the preparation of material of polypropylene granulate, adding 0.8% of stabilizer product and 3% of a combination of pigments based on polyolefin.
  • the stabilizer product comprises a mix of a Hindered Amine Light Stabilizer (HALS) and an UV absorber of high molecular weight, preferably of the benzotriazole group.
  • HALS Hindered Amine Light Stabilizer
  • the method of manufacturing continuous filament warp yarn and continuous filament weft yarn starts, with the extrusion method. Following that, it continues with the texturing process for the warp yarn and the twisting process for the weft yarn.
  • the extrusion process of the warp yarn and the weft yarn starts with the insertion of the polyolefinic plastic material, comprising the UV stabiliser and the pigments, into an extruder and it continues with the application of an extrusion temperature of 230°C.
  • the melted plastic is driven through an isolated conduct up to the spinning head of the extruder, where it is forced by the pressure pumps through the spinplates.
  • the spinplates have 0.3 mm-diameter holes. The number of holes determines the yarn filaments, due to be 120.
  • the yarn is air-cooled at 15°C. Afterwards, 1% of spinning oil is applied.
  • the yarn is then stretched to orientate and align the molecular chains, thus achieving an acceptable tenacity. It is stretched by means of hot cylinders (120°C) and/or by means of ovens (140°C).
  • the stretch ratio is from 1 to 4.
  • the yarn suffers a process of shrinking of 5% by means of hot cylinders and/or by means of ovens.
  • the amount of melted material going through the spinplates along with the stretch and shrinkage ratio determines the yarn coarseness or count, of preferably 440 dtex.
  • the cone winding of the yarn is carried on by means of a winding machine.
  • the wound warp yarn is textured to achieve a natural fibre look by air pressure.
  • the method involves putting the yarn into water to moisten it, and immediately inserting it into a hole under air pressure, in a determined direction, which curls the filaments and achieves the texturing effect.
  • the air pressure rating in this hole is 11 bar. Once textured, the yarn is wound again.
  • the extruded yarn is inserted into a double-twist twisting machine applying an 80 turns per metre torsion.
  • the warp yarns are warped in a beam and then placed on the back of the loom, in the right shape to achieve the necessary design.
  • the weft yarns are placed on a bobbin holder and they are then inserted into the loom perpendicularly to the warp yarns.
  • the final fabric obtained with a specific weaving machine for this case has a woven structure of 15 weft yarns per centimetre and 30 warp yarns per centimetre. This weaving density is enough to achieve a good water penetration resistance with the subsequent finishing treatment.
  • the finishing process involves treating the fabric with a water-repellent product. This process starts with the fabric washing with an anionic product at 90°C for 6 hours to remove the remains of spinning oil. After that, a water wash is carried on and finally a moister-proofing of the fabric with a fluoro-acrylic copolymer in emulsion.
  • the application dose of this copolymer is 4% for a initial 50% fabric humidity.
  • the treated fabric is dried in an oven at 130°C for 2.5 minutes.
  • the finishing guarantees a fabric enduring a 20 cm water column, according to UNE EN 20811 Regulation, and having a high resistance (ISO5) to wetting, according to UNE EN 24920 Regulation.
  • the described process results in obtaining a fabric of continuous filament yarn of polypropylene which, unlike the other polyolefinic fabrics with continuous filament yarns known in the state of the technique, meets all quality standards established for awning fabrics, especially regarding its water penetration and wetting resistance.
  • the annexed table shows the results of a comparative test made with two pieces of polyolefin fabric of continuous filament yarn.
  • Fabric A is a sample of the fabric obtained by the method of the present invention, whereas fabric B is a current state of the art polyolefin fabric suitable to be applied to upholstery and outdoor furniture covering.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
EP04743881A 2003-07-10 2004-07-07 Method for the manufacture of awning fabrics Expired - Lifetime EP1644573B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES200301606A ES2234407B1 (es) 2003-07-10 2003-07-10 Procedimiento de fabricacion de telas de toldos y similares.
PCT/IB2004/002218 WO2005005714A1 (en) 2003-07-10 2004-07-07 Method for the manufacture of awning fabrics and similar materials

Publications (2)

Publication Number Publication Date
EP1644573A1 EP1644573A1 (en) 2006-04-12
EP1644573B1 true EP1644573B1 (en) 2012-06-13

Family

ID=34043269

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04743881A Expired - Lifetime EP1644573B1 (en) 2003-07-10 2004-07-07 Method for the manufacture of awning fabrics

Country Status (4)

Country Link
EP (1) EP1644573B1 (es)
DK (1) DK1644573T3 (es)
ES (2) ES2234407B1 (es)
WO (1) WO2005005714A1 (es)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10214836B1 (en) 2017-08-18 2019-02-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11767616B2 (en) 2017-08-18 2023-09-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI81051C (fi) * 1988-08-04 1990-09-10 Schauman Wilh Oy Lastpresenning.
FR2683535B1 (fr) * 1991-11-12 1994-10-28 Atochem Nouveaux copolymeres fluores et leur utilisation pour le revetement et l'impregnation de substrats divers.
DE4301166C2 (de) * 1993-01-19 1997-12-18 Mehler Tech Textilien Gmbh Textiles Gewebe für Markisen, Schirme, Zelte, Persennings und dergleichen sowie Verfahren zu dessen Herstellung
AT402743B (de) 1993-06-18 1997-08-25 Asota Gmbh Recyclierbares gewebe aus polyolefingarn
US5431979A (en) * 1994-04-12 1995-07-11 Hoechst Celanese Corporation Cut-resistant tarpaulin
AT404365B (de) 1996-06-28 1998-11-25 Asota Gmbh Recyclierbare gewebe aus polyolefingarnen
FR2756290B1 (fr) * 1996-11-27 1998-12-31 Atochem Elf Sa Copolymeres fluores pour le traitement oleophobe et hydrophobe de substrats divers
DE59812014D1 (de) * 1997-05-14 2004-11-04 Borealis Gmbh Schwechat Mannsw Polyolefinfasern und Polyolefingarne und daraus hergestellte textile Flächengebilde
FI3882U1 (fi) * 1998-10-22 1999-04-12 Upm Kymmene Corp Peite
JP2000127312A (ja) * 1998-10-30 2000-05-09 Hagihara Industries Inc クロスシート
DE10018484A1 (de) 2000-04-14 2001-10-18 Schmitz Werke Markisenstoff und Verfahren zu seiner Herstellung
KR20020091288A (ko) * 2001-05-30 2002-12-06 한국타포린 주식회사 압출코팅용 수지조성물을 이용한 타포린 및 이의제조방법
KR100389049B1 (en) 2002-04-15 2003-06-25 Gu Ui Mun Awning fabric and method for producing thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10214836B1 (en) 2017-08-18 2019-02-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Also Published As

Publication number Publication date
DK1644573T3 (da) 2012-09-03
ES2388062T3 (es) 2012-10-08
ES2234407B1 (es) 2006-11-01
EP1644573A1 (en) 2006-04-12
ES2234407A1 (es) 2005-06-16
WO2005005714A1 (en) 2005-01-20

Similar Documents

Publication Publication Date Title
EP1731641A1 (en) Woven fabric and articles made by using the same
KR101606846B1 (ko) 리사이클 폴리에스테르원사를 이용한 복합가공사 및 이를 이용한 블라인드용 직물의 제조방법
EP0885988B1 (en) Cloth having configurational stability and/or water resistance, and core/sheath type composite thread used therefor
EP2199441B1 (en) Fabric for screen including dope dyed fiber
DE3888709T2 (de) Copolyester-Faser.
CA3098119A1 (en) Textile materials containing aramid fibers and dyed polyphenylene sulfide fibers
US5955385A (en) Recyclable wovens composed of polyolefin yarns
KR101827867B1 (ko) 고탄력 및 고강도 모노필라멘트를 이용한 원단 제조공법
JP5465929B2 (ja) ポリアミド繊維、ポリアミド仮撚加工糸及び織編物
EP1644573B1 (en) Method for the manufacture of awning fabrics
DE2038705A1 (de) Fasergebilde
KR101761196B1 (ko) 내구성이 향상된 친환경 코팅사와 코팅사를 제조하는 방법 및 이를 직조한 원단
JP2973846B2 (ja) 耐候性の改善されたポリエステル系繊維およびその製造方法ならびにその繊維を用いてなる繊維製品
AT402743B (de) Recyclierbares gewebe aus polyolefingarn
JPH0441730A (ja) ポリエステル強撚糸
KR20100035256A (ko) 난연성 라이오셀 섬유 및 이를 이용한 직물의 제조방법
EP3660207A1 (en) Non-woven artificial leather using dope-dyed polyester sea-island type composite yarn and method for producing same
RU2278187C2 (ru) Улучшенные синтетические волокна на основе полиолефинов и способ их получения
DE4321560A1 (de) Polyolefingarn und Gewebe
KR100464169B1 (ko) 이수축 혼섬사
JPH08325941A (ja) メッシュシート
KR101272615B1 (ko) 고신축성 혼섬사의 제조방법
CN117210992A (zh) 一种聚丙烯复合纤维防水面料的制造方法
JP2003064533A (ja) 形態安定性を有する布帛及びそれに使用する芯鞘型複合繊維
JP2001262477A (ja) ポリエステル繊維とポリアミド繊維を用いてなる染色物およびその製造方法

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

17P Request for examination filed

Effective date: 20060111

DAX Request for extension of the european patent (deleted)
RTI1 Title (correction)

Free format text: METHOD FOR THE MANUFACTURE OF AWNING FABRICS

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 562078

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120615

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602004038205

Country of ref document: DE

Effective date: 20120809

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: BOHEST AG

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2388062

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20121008

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

REG Reference to a national code

Ref country code: AT

Ref legal event code: MK05

Ref document number: 562078

Country of ref document: AT

Kind code of ref document: T

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120914

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120613

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120731

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20121015

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

26N No opposition filed

Effective date: 20130314

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602004038205

Country of ref document: DE

Effective date: 20130314

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20120913

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120707

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20130731

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20040707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130731

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20140710

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140702

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20140716

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20140714

Year of fee payment: 11

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20150707

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20150801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150707

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150801

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20160713

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150731

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20170613

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20170705

Year of fee payment: 14

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20181107

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602004038205

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20170708

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20190201

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180731

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: TR

Payment date: 20230706

Year of fee payment: 20