EP1644573B1 - Verfahren zur herstellung von markisenstoffe - Google Patents

Verfahren zur herstellung von markisenstoffe Download PDF

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Publication number
EP1644573B1
EP1644573B1 EP04743881A EP04743881A EP1644573B1 EP 1644573 B1 EP1644573 B1 EP 1644573B1 EP 04743881 A EP04743881 A EP 04743881A EP 04743881 A EP04743881 A EP 04743881A EP 1644573 B1 EP1644573 B1 EP 1644573B1
Authority
EP
European Patent Office
Prior art keywords
yarn
weft
warp
fabric
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP04743881A
Other languages
English (en)
French (fr)
Other versions
EP1644573A1 (de
Inventor
Joan c/o Telya Products S.L. Garzon Romero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Telya Products Sl
Original Assignee
Telya Products Sl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Telya Products Sl filed Critical Telya Products Sl
Publication of EP1644573A1 publication Critical patent/EP1644573A1/de
Application granted granted Critical
Publication of EP1644573B1 publication Critical patent/EP1644573B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/047—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with fluoropolymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/10—Particulate form, e.g. powder, granule
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/14—Properties of the materials having chemical properties
    • D06N2209/147—Stainproof, stain repellent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1678—Resistive to light or to UV
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/06—Building materials
    • D06N2211/063—Wall coverings

Definitions

  • the present invention refers to a method to manufacture awning fabrics.
  • US 2001/0031590 A1 discloses awning fabrics which are made from polyester filament yarn (continuous filament yarn) and/or polyester monofilament yarn.
  • the invention of said document has as its object to create awning fabric that has the lowest possible weight per unit area while providing good UV stability and weather resistance.
  • the European patent application num. 1355001 discloses an awning fabric which is formed by weaving, at a high density, high-bulky and texturised polyester filament yarns and then by treating uniformly the inner and outer surfaces of the resulting fabric with a coating solution of polytetrafluoroethylene.
  • the awning fabrics disclosed in these patents have in common that all of them are manufactured with polyolefine yarns obtained from cut fibres, joined by the conventional spinning or ring process, and that the composition of the polyolefinic plastic material used comprises always at least two polymeric components with different melting point; as for example, polypropylene and polyethylene.
  • the aim of the present invention is to solve the mentioned disadvantages by developing a manufacturing method of awning fabrics from continuous filament yarn with a single polymeric component of the polyolefin group, offering the advantages that will be described below.
  • the method of the present invention refers to awning fabrics with warp yarns and weft yarns involving the steps of weaving said warp yarns and said weft yarns with a density over 16 warp yarns per centimetre and 10 weft yarns per centimetre, and treating the fabric by immersion with a water-repellent product, and is characterised in that prior to the weaving step, warp yarns and weft yarns are prepared following the steps of:
  • UV stabiliser it means a product which, when admixed with a thermoplastic resin, selectively absorbs UV rays.
  • the fabrics of the present invention manufactured from continuous filament yarns of a single polymeric component of the polyolefin group, have presented a texture, rigidity and inscription effects optimal to be used in awnings. Furthermore, said fabrics present the advantages which are described below, respect to the fabrics for awnings with polyolefin yarns, described in the state the art.
  • Fabrics of polyolefin obtained by the method of the present invention are very suitable for manufacturing awnings since they have, respect of other polyolefin fabrics of continuous filament known in the state of the art, at the same time, an optimum resistance to wetting, water penetration and bleaching caused by the sunlight.
  • said only polymeric component is polypropylene.
  • the step which involves texturing the warp or weft yarn allow to achieve a natural fibre look of the fabric.
  • step b) a step which involves twisting the weft or warp yarn to make the weaving easier is carried on.
  • the step of texturing is carried on a step which involves twisting the weft or warp yarn.
  • the warp yarn is textured to achieve a natural fibre look, and, at the same time, the weft yarn is twisted to make the yarn weaving easier.
  • the extruded yarn has between 30 and 340 filaments, so that a good texturing of the yarn is carried on.
  • the fabric has 30 warp yarns per centimetre and 15 weft yarns per centimetre, to create a woven structure dense enough to achieve a good resistance to water penetration.
  • the water-repellent product is a fluoro-acrylic copolymer, so that a water penetration resistance between 10 and 80 cm of water column is achieved.
  • the UV stabiliser comprises a Hindered Amine Light Stabiliser (HALS).
  • HALS is a chemically reactive substance that scavenge free radicals, created by the UV light induced degradation of the polymer matrix, which prevents the physical degradation of said polymer.
  • said plastic material comprise between 0.1% and 10% of pigments, to obtain the desired colour.
  • said UV stabilizer product comprises, furthermore, an UV absorber of high molecular weight, which protects from the sun the pigments with comprises the plastic material, and prevents the decolouration of the fabric.
  • the method of manufacturing awning fabrics starts with the preparation of material of polypropylene granulate, adding 0.8% of stabilizer product and 3% of a combination of pigments based on polyolefin.
  • the stabilizer product comprises a mix of a Hindered Amine Light Stabilizer (HALS) and an UV absorber of high molecular weight, preferably of the benzotriazole group.
  • HALS Hindered Amine Light Stabilizer
  • the method of manufacturing continuous filament warp yarn and continuous filament weft yarn starts, with the extrusion method. Following that, it continues with the texturing process for the warp yarn and the twisting process for the weft yarn.
  • the extrusion process of the warp yarn and the weft yarn starts with the insertion of the polyolefinic plastic material, comprising the UV stabiliser and the pigments, into an extruder and it continues with the application of an extrusion temperature of 230°C.
  • the melted plastic is driven through an isolated conduct up to the spinning head of the extruder, where it is forced by the pressure pumps through the spinplates.
  • the spinplates have 0.3 mm-diameter holes. The number of holes determines the yarn filaments, due to be 120.
  • the yarn is air-cooled at 15°C. Afterwards, 1% of spinning oil is applied.
  • the yarn is then stretched to orientate and align the molecular chains, thus achieving an acceptable tenacity. It is stretched by means of hot cylinders (120°C) and/or by means of ovens (140°C).
  • the stretch ratio is from 1 to 4.
  • the yarn suffers a process of shrinking of 5% by means of hot cylinders and/or by means of ovens.
  • the amount of melted material going through the spinplates along with the stretch and shrinkage ratio determines the yarn coarseness or count, of preferably 440 dtex.
  • the cone winding of the yarn is carried on by means of a winding machine.
  • the wound warp yarn is textured to achieve a natural fibre look by air pressure.
  • the method involves putting the yarn into water to moisten it, and immediately inserting it into a hole under air pressure, in a determined direction, which curls the filaments and achieves the texturing effect.
  • the air pressure rating in this hole is 11 bar. Once textured, the yarn is wound again.
  • the extruded yarn is inserted into a double-twist twisting machine applying an 80 turns per metre torsion.
  • the warp yarns are warped in a beam and then placed on the back of the loom, in the right shape to achieve the necessary design.
  • the weft yarns are placed on a bobbin holder and they are then inserted into the loom perpendicularly to the warp yarns.
  • the final fabric obtained with a specific weaving machine for this case has a woven structure of 15 weft yarns per centimetre and 30 warp yarns per centimetre. This weaving density is enough to achieve a good water penetration resistance with the subsequent finishing treatment.
  • the finishing process involves treating the fabric with a water-repellent product. This process starts with the fabric washing with an anionic product at 90°C for 6 hours to remove the remains of spinning oil. After that, a water wash is carried on and finally a moister-proofing of the fabric with a fluoro-acrylic copolymer in emulsion.
  • the application dose of this copolymer is 4% for a initial 50% fabric humidity.
  • the treated fabric is dried in an oven at 130°C for 2.5 minutes.
  • the finishing guarantees a fabric enduring a 20 cm water column, according to UNE EN 20811 Regulation, and having a high resistance (ISO5) to wetting, according to UNE EN 24920 Regulation.
  • the described process results in obtaining a fabric of continuous filament yarn of polypropylene which, unlike the other polyolefinic fabrics with continuous filament yarns known in the state of the technique, meets all quality standards established for awning fabrics, especially regarding its water penetration and wetting resistance.
  • the annexed table shows the results of a comparative test made with two pieces of polyolefin fabric of continuous filament yarn.
  • Fabric A is a sample of the fabric obtained by the method of the present invention, whereas fabric B is a current state of the art polyolefin fabric suitable to be applied to upholstery and outdoor furniture covering.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)

Claims (11)

  1. Verfahren zum Herstellen von Markisenstoffen mit Kettfäden und Schussfäden, umfassend die Schritte des Webens der Kettfäden und der Schussfäden mit einer Dichte über 16 Kettfäden pro Zentimeter und 10 Schussfäden pro Zentimeter, und Behandeln des Stoffs durch Eintauchen in ein wasserabweisendes Produkt,
    dadurch gekennzeichnet, dass vor dem Webschritt, die Kettfäden und die Schussfäden gemäß den folgenden Schritten vorbereitet werden:
    a) Vorbereiten von Kunststoffmaterial, das Granulat einer einzigen Polymerkomponente der Polyolefingruppe und wenigstens 0,2 % eines UV-Stabilisators aufweist,
    b) Extrudieren des kontinuierlichen Faserkettfadens und des kontinuierlichen Faserschussfadens,
    c) Texturieren des kontinuierlichen Faserkettfadens oder des kontinuierlichen Faserschussfadens.
  2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass die einzige Polymerkomponente Polypropylen ist.
  3. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass nach Schritt b) ein Schritt ausgeführt wird, der das Zwirnen des Kettfadens oder des Schussfadens umfasst.
  4. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass nach dem ersten Schritt des Texturierens des Kettfadens oder des Schussfadens, ein Schritt ausgeführt wird, der das Zwirnen des Kettfadens oder des Schussfadens umfasst.
  5. Verfahren nach Anspruch 1 oder 4, dadurch gekennzeichnet, dass der extrudierte Faden zwischen 30 und 340 Fasern aufweist.
  6. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der Stoff 30 Kettfäden pro Zentimeter und 15 Schussfäden pro Zentimeter aufweist.
  7. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass das wasserabweisende Produkt ein Fluor-Acryl-Copolymer ist.
  8. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass der UV-Stabilisator ein Hindered Amine Light Stabilisator ist.
  9. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass das Kunststoffmaterial zwischen 0,1 % und 10 % Pigmente aufweist.
  10. Verfahren nach Anspruch 8 und 9, dadurch gekennzeichnet, dass das UV-Stabilisatorprodukt auch einen UV-Absorbierer von hohem Molekulargewicht aufweist.
  11. Verwendung von texturiertem kontinuierlichem Fasergarn einer einzigen Polymerkomponente der Polyolefingruppe als Kettfaden oder Schussfaden in Stoffen, die als Markisen verwendet werden.
EP04743881A 2003-07-10 2004-07-07 Verfahren zur herstellung von markisenstoffe Expired - Lifetime EP1644573B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES200301606A ES2234407B1 (es) 2003-07-10 2003-07-10 Procedimiento de fabricacion de telas de toldos y similares.
PCT/IB2004/002218 WO2005005714A1 (en) 2003-07-10 2004-07-07 Method for the manufacture of awning fabrics and similar materials

Publications (2)

Publication Number Publication Date
EP1644573A1 EP1644573A1 (de) 2006-04-12
EP1644573B1 true EP1644573B1 (de) 2012-06-13

Family

ID=34043269

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04743881A Expired - Lifetime EP1644573B1 (de) 2003-07-10 2004-07-07 Verfahren zur herstellung von markisenstoffe

Country Status (4)

Country Link
EP (1) EP1644573B1 (de)
DK (1) DK1644573T3 (de)
ES (2) ES2234407B1 (de)
WO (1) WO2005005714A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10214836B1 (en) 2017-08-18 2019-02-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11767616B2 (en) 2017-08-18 2023-09-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI81051C (fi) * 1988-08-04 1990-09-10 Schauman Wilh Oy Lastpresenning.
FR2683535B1 (fr) * 1991-11-12 1994-10-28 Atochem Nouveaux copolymeres fluores et leur utilisation pour le revetement et l'impregnation de substrats divers.
DE4301166C2 (de) 1993-01-19 1997-12-18 Mehler Tech Textilien Gmbh Textiles Gewebe für Markisen, Schirme, Zelte, Persennings und dergleichen sowie Verfahren zu dessen Herstellung
AT402743B (de) * 1993-06-18 1997-08-25 Asota Gmbh Recyclierbares gewebe aus polyolefingarn
US5431979A (en) * 1994-04-12 1995-07-11 Hoechst Celanese Corporation Cut-resistant tarpaulin
AT404365B (de) 1996-06-28 1998-11-25 Asota Gmbh Recyclierbare gewebe aus polyolefingarnen
FR2756290B1 (fr) * 1996-11-27 1998-12-31 Atochem Elf Sa Copolymeres fluores pour le traitement oleophobe et hydrophobe de substrats divers
EP0878567B1 (de) * 1997-05-14 2004-09-29 Borealis GmbH Polyolefinfasern und Polyolefingarne und daraus hergestellte textile Flächengebilde
FI3882U1 (fi) * 1998-10-22 1999-04-12 Upm Kymmene Corp Peite
JP2000127312A (ja) * 1998-10-30 2000-05-09 Hagihara Industries Inc クロスシート
DE10018484A1 (de) 2000-04-14 2001-10-18 Schmitz Werke Markisenstoff und Verfahren zu seiner Herstellung
KR20020091288A (ko) * 2001-05-30 2002-12-06 한국타포린 주식회사 압출코팅용 수지조성물을 이용한 타포린 및 이의제조방법
KR100389049B1 (en) 2002-04-15 2003-06-25 Gu Ui Mun Awning fabric and method for producing thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10214836B1 (en) 2017-08-18 2019-02-26 Glen Raven, Inc. Acrylic compositions including a hindered amine light stabilizer and methods of making and using the same

Also Published As

Publication number Publication date
WO2005005714A1 (en) 2005-01-20
ES2234407A1 (es) 2005-06-16
ES2388062T3 (es) 2012-10-08
EP1644573A1 (de) 2006-04-12
ES2234407B1 (es) 2006-11-01
DK1644573T3 (da) 2012-09-03

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