Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B60—VEHICLES IN GENERAL
  • B60K—ARRANGEMENT OR MOUNTING OF PROPULSION UNITS OR OF TRANSMISSIONS IN VEHICLES; ARRANGEMENT OR MOUNTING OF PLURAL DIVERSE PRIME-MOVERS IN VEHICLES; AUXILIARY DRIVES FOR VEHICLES; INSTRUMENTATION OR DASHBOARDS FOR VEHICLES; ARRANGEMENTS IN CONNECTION WITH COOLING, AIR INTAKE, GAS EXHAUST OR FUEL SUPPLY OF PROPULSION UNITS IN VEHICLES
  • B60K15/00—Arrangement in connection with fuel supply of combustion engines or other fuel consuming energy converters, e.g. fuel cells; Mounting or construction of fuel tanks
  • B60K15/03—Fuel tanks
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B64—AIRCRAFT; AVIATION; COSMONAUTICS
  • B64D—EQUIPMENT FOR FITTING IN OR TO AIRCRAFT; FLIGHT SUITS; PARACHUTES; ARRANGEMENT OR MOUNTING OF POWER PLANTS OR PROPULSION TRANSMISSIONS IN AIRCRAFT
  • B64D37/00—Arrangements in connection with fuel supply for power plant
  • B64D37/32—Safety measures not otherwise provided for, e.g. preventing explosive conditions
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D90/00—Component parts, details or accessories for large containers
  • B65D90/22—Safety features
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
  • B65D90/00—Component parts, details or accessories for large containers
  • B65D90/22—Safety features
  • B65D90/30—Recovery of escaped vapours
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B67—OPENING, CLOSING OR CLEANING BOTTLES, JARS OR SIMILAR CONTAINERS; LIQUID HANDLING
  • B67D—DISPENSING, DELIVERING OR TRANSFERRING LIQUIDS, NOT OTHERWISE PROVIDED FOR
  • B67D7/00—Apparatus or devices for transferring liquids from bulk storage containers or reservoirs into vehicles or into portable containers, e.g. for retail sale purposes
  • B67D7/06—Details or accessories
  • B67D7/32—Arrangements of safety or warning devices; Means for preventing unauthorised delivery of liquid
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
  • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
  • F17C13/00—Details of vessels or of the filling or discharging of vessels
  • F17C13/12—Arrangements or mounting of devices for preventing or minimising the effect of explosion ; Other safety measures
• • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
  • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
  • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
  • F02M37/00—Apparatus or systems for feeding liquid fuel from storage containers to carburettors or fuel-injection apparatus; Arrangements for purifying liquid fuel specially adapted for, or arranged on, internal-combustion engines
  • F02M37/0076—Details of the fuel feeding system related to the fuel tank
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T137/00—Fluid handling
  • Y10T137/2931—Diverse fluid containing pressure systems
  • Y10T137/3115—Gas pressure storage over or displacement of liquid
  • Y10T137/3127—With gas maintenance or application

Definitions

• the invention relates to a system for securing hazardous substances, such as fuels, in tank containers.
• the disadvantage here is that the inert gases suppress the risk of ignition in an undamaged container, but do not prevent the fuel from flowing out in the case of a damaged container.
• DE 43 39 772 AI describes a safety device in which the inside of the container is filled with a cellular, open-pored material, the cells of which contain the liquid Record partial quantities.
• the division of the liquid and the use of an appropriate material prevent the liquid from flowing out in the event of an accident or the like in which the container opens.
• An open-pore foamed plastic or rubber is mentioned as the open-pore-cellular material.
• the disadvantage here is that a large part of the volume of the tank is lost, so that less transport capacity is available.
• binders with a large specific surface area for binding petroleum or petroleum products if they leak due to an accident or due to carelessness.
• Such binders are known for example from DE 43 20 908 AI or from DE 26 35 087 AI.
• DE 94 00 792 T2 like DE 27 44 767 AI, discloses devices or methods for inerting containers, a chemical / physical reaction between the inert gas and the substances stored in the containers not being possible.
• the inert or protective gas is selected so that there is no reaction with the storage materials, for example food. A retention of the stored substance in the substances to prevent leakage is not obvious.
• DE 80 35 111 U1 relates to a device for foaming substances stored in bunkers, for example highly flammable substances such as lignite.
• the risk of fire or explosion is reduced by adding a foam to the bunker from above to cover the surface of the bed in the bunker and to interrupt any fires that may be present.
• the substance stored in the bunker for example the bulk material, reacts with the foam or with a substance that is part of the foam. Holding the stored substance in the substances in order to prevent leakage is not disclosed.
• CH 259 609 is concerned with a foam which is favorable for fire-fighting purposes, in which the number of foams increases due to a higher alkyl sulfate leaves.
• the alkyl sulfate can be added to the water immediately before use or can be stored in a form ready for processing. No reaction between the substance to be extinguished and the foam or parts of the foam is disclosed, which leads to a change in the material to be extinguished. A retention of the substance to be extinguished in the foam to prevent leakage is not disclosed.
• JP-57-074215 and US-5,531,290 are concerned with bringing the hazardous substance, here fuel, into a solid state which prevents leakage by gelling.
• the fuel becomes unusable and recycling is not possible after an accidental activation, for example.
• the gelled fuel also remains at risk of fire since there is no reduction in the flash point.
• the object of the invention is to prevent leakage and to suppress the risk of fire in the case of a tank or container filled with hazardous substances without substantially reducing the tank volume.
• a system for securing bulk substances, such as fuels, in tank containers in which the tank container is connected to an insert unit, in which one or more substances are located, which can be introduced into the tank container and by means of a physical reaction put the hazardous substance in a changed state that prevents escape.
• insert assembly is understood to mean a device which comprises the storage and release for the substances for the reaction mentioned and which enables introduction into the tank container.
• a chemical reaction can certainly take place in or by means of the insert unit, but this does not essentially aim at the hazardous substance and substances reacting chemically with one another, ie by converting the hazardous substance for the purpose of binding the hazardous substance.
• the polyurethane foam used for binding, ie absorbing the fuel is formed chemically in the unit or at least thus initiates the reaction necessary to form the foam.
• the unit can also take up the individual substances separately first and bring them together only at the place of use, ie in the tank, where the actual reaction to form the foam takes place.
• the binding of the hazardous substance only takes place through purely physical absorption, similar to a sponge. Because the chemical composition of the hazardous substance is not changed, the sucked 'fabric is even recyclable, as opposed to the method known from the prior art gelling.
• a physical reaction in the sense of the invention means that the hazardous substance is bound without using a chemical change in the hazardous substance, e.g. B. for purely physical absorption, sponge, classic oil binder.
• the term “binder” is also to be understood exclusively as a “physical binder”. It is part of the invention if chemical binding processes also occur.
• the binding that takes place in the tank has the advantage that binding takes place before it runs out, so that at least part of the tank structure remains usable and helps hold the hazardous substance together.
• the weight requirement of 1:10 to 1:60 of the binder per bound weight of the hazardous substance is significantly lower than in chemical binding processes, e.g. B. Gelling. This makes the method particularly attractive for weight-sensitive areas, for example aviation, in which a fuel weight that is high in relation to the total mass must be carried.
• the hazardous substance is held in the large pores in relation to the foam mass.
• the known exchange substances can also be used.
• a special feature here is that the absorbent binder is only formed by a chemical reaction immediately before use. As a result, compact, space-saving substances can initially be carried along, which foam up only when used and thus form the required large contact area.
• the binder as soon as it is in contact with the hazardous substance - here fuel - is at the same time able to by means of a chemical reaction, that is, as in the known extinguishing foams, by simply covering them, to reduce the flammability.
• the reaction increases the flash point of the hazardous substance or even makes it non-flammable. This can be done, for example, by adding dibromo-neopentyl alcohol. It is particularly effective if the diisocyanate is replaced by dibromo-neopentyl alcohol during foam formation.
• the foam not only keeps the fuel in its numerous pores, but also exchanges with the fuel via a particularly large, finely divided contact surface, through which the bromine compounds of the foam can attach to the hydrocarbon molecules of the fuel in order to ensure the ignitability of the chemical to reduce modified fuel. It is therefore physically bound and the flash point is increased chemically.
• dibromo-neopentyl alcohol, diisocyanate and the like substances with a similar effect, such as, for example, B. Powder can be added by means of which even higher flash point increases are possible.
• the tank container is preferably connected to the insert unit via a line, the tank container being a closed fuel tank, but possibly also an open fuel tank.
• a one-piece or multi-piece container is suitable as an insert unit, which can be emptied suddenly into the hazardous substance tank with a highly effective pump system or by means of stored, expanding compressed gases or via pipes.
• gases for example, carbon dioxide or nitrogen are suitable as pressurized gases.
• the propellant gas With the help of the propellant gas used, the PUR foam foams even better and is fed into the tanks to reduce or prevent fire.
• tank containers are provided at various points in the wings and in the fuselage. Here, particular care should be taken to ensure that the substances which can be introduced can optionally be supplied to the various tank containers present in the aircraft.
• Particles of a polyolefin can also be used as a binder, for example polypropylene or polyethylene fibers, as are described, for example, in DE 43 20 908 A1.
• Particles of a rigid polyurethane foam can also be used as a binder, this being used as a rigid polyurethane foam powder which has been treated on its surface with organosilanes.
• Ceramic inert dusts for example from finely ground calcium carbonate or silicon dioxide, can also be used as binders.
• the binders can also be colored, in particular fluorescent colored. Catalysts which accelerate the reaction can also be added to the dangerous goods and / or the binder.
• Figures 1 and 2 in a schematic representation of a device for eliminating fire and leakage hazards in a tank system.
• FIG 3 shows an embodiment with an open tank container
• Fig. 4 shows an embodiment installed in an aircraft.
• the danger posed by highly flammable fuels is known.
• the aim is to prevent the leakage of such fuels and similar hydrocarbons. This reduces the risk of fire and the risk of environmental contamination
• a stationary, cylindrical tank container 10 for storing gasoline is described with reference to FIGS. 1 and 2.
• the tank container 10 is partly filled with gasoline 15 to gasoline 16 at. Practice.
• a tank drain 13 is provided to relieve pressure
• the safety device comprises a pressure vessel 18, to which a vessel 20, which is filled with CO 2 gas with 5 bar pressure, can be reached via an intermediate valve 12, which can be opened suddenly, the non-combustible CO 7 gas empty the container 18
• the system for securing further comprises a release switch 14, which can be coupled, for example, to an emergency button or a heat sensor (not shown).
• the release switch 14 is connected via two synchronously switched signals 21 a and 21 b with a release valve 12 at the lower area of the tank 10 and the further release valve 22 in the lateral area of the container 20
• the release switch 14 When an emergency situation occurs, the release switch 14 is either operated manually or triggered by a sensor. By opening the valves 22 and 12, the compressed gas initially flows from the container 20 into the container 18 and brings it to the emptying via the line 28 and the valve 12 Into tank 10 In the tank 18 there is a substance highly dispersed in water, which reacts physically with the fuel in the tank and solidifies the liquid. Suitable for this purpose are conventional oil binders, for example based on polyolefin or polyurethane-based, or oil binders with inert inorganic substances, such as calcium carbonate or silicon dioxide flours. Such substances suddenly thicken the liquid in the container so that leakage is avoided.
• a pump (not shown) can also be installed in line 28, which pumps the substance required for the reaction.
• a finely ground powder which is rapidly distributed in the dangerous goods and whose viscosity changes and / or increases the ignition temperature.
• the system shown in Figures 1 and 2 is not limited to a stationary storage tank, but can in principle also be used for tank transport vehicles for road and sea transport.
• the containers 10 can consist of different materials. When used on tankers, it is advantageous that a leak in the tank does not lead to the fuel spilling if it is mixed with the binders. The leak can also be stopped if the size is sufficient.
• Figure 3 shows the system applied to an open tank 30 for edible oils in tropical areas.
• the volatile fraction of the oil can escape via the upper opening 31, the upper space 32 of the tank container 30 being kept free of atmospheric oxygen.
• a pressure vessel 33 is filled with the binders according to the invention.
• a valve 34 can be radio-controlled are triggered so that the binder enters through distributor nozzles 35 and is distributed in the container contents.
• the liquid oil solidifies.
• the composition of the oil changes only slightly because relatively small amounts of binders are required.
• the mixture remains accessible to human nutrition, e.g. B. by squeezing.
• Fig. 4 shows a schematic representation of a system configuration in an aircraft. It is important to ensure that a binding agent is added to the remaining fuel in the aircraft tanks, especially in the event of a dangerous landing or on the airfield, so that these tanks can no longer leak.
• Conventional jet kerosene which is inhibited in its flammability by chemical reaction upon contact with the binder according to the invention, is suitable as the fuel.
• a substance to be introduced here a two-component system, is present as substance A or substance B in a container 40.
• This can be a diisocyanate and a diol, which are brought together and closed shortly before being introduced into the tank polymerize with a polyurethane foam.
• the reaction mixture located in the double container 40 here polyurethane foam, can be pressed into the tank by means of a propellant, which is located in a separate pressure container 41, after a partition wall has been burst.
• a polyurethane foam then forms, which is added to the fuel in selected tanks 43, 44.
• diisocyanate with dibromo-neopentyl alcohol or similar substances that increase the flash point the fuel reacts with these to reduce inflammability.
• the fuel becomes physical through this binder modified with dibromo-neopentyl alcohol and the like bound and flame retardant. Clumping can also occur.
• the flash point is changed.
• a foamed aggregate is formed, in which the fuel is held in the pores, the aggregate itself being so solid or viscous that leakage is prevented. Catalysts and components that accelerate the process of solidification can also be added to the dangerous goods from the outset.
• control via a control unit 42 of the substance to the individual tanks (identified here with 43, 44) only. the individual tanks that are still filled with fuel or for which the fuel could not be drained in flight.
• the substances can also be arranged in the immediate vicinity of the tanks, so that the pipeline and control unit for switching the route of the pipeline are unnecessary.
• the pilot can use the system check to test the readiness of the security system.
• the decision regarding the use of the security system can be made by the on-board personnel or personnel outside the aircraft if a corresponding remote control is installed, e.g. B. during kidnappings on the ground.
• the chemical substances can be fed into the aircraft tanks using pressure. Leakage of fuel is prevented, so that a fan-shaped fire cannot occur below the aircraft. In the case of a parked aircraft that is exposed to attacks from the air, for example, the tank contents can be neutralized by a supply that is triggered as a precaution. It is also advantageous that a binder sets the flash point of the fuel higher, so that there is a further criterion for improving safety.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Aviation & Aerospace Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Sustainable Energy (AREA)
• Sustainable Development (AREA)
• Combustion & Propulsion (AREA)
• Transportation (AREA)
• Life Sciences & Earth Sciences (AREA)
• Organic Chemistry (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Engineering & Computer Science (AREA)
• Cooling, Air Intake And Gas Exhaust, And Fuel Tank Arrangements In Propulsion Units (AREA)
• Filling Or Discharging Of Gas Storage Vessels (AREA)
• Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
• Physical Or Chemical Processes And Apparatus (AREA)
• Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Applications Claiming Priority (2)

Publications (1)

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ID=33426729

Family Applications (1)

Country Status (9)

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• 2003
  • 2003-05-09 DE DE2003121002 patent/DE10321002B3/de not_active Expired - Fee Related
• 2004
  • 2004-05-10 WO PCT/EP2004/050741 patent/WO2004099662A2/de active Application Filing
  • 2004-05-10 JP JP2006505595A patent/JP2008532853A/ja active Pending
  • 2004-05-10 RU RU2005138298A patent/RU2394640C2/ru not_active IP Right Cessation
  • 2004-05-10 CA CA 2525213 patent/CA2525213A1/en not_active Abandoned
  • 2004-05-10 EP EP04731941A patent/EP1644112A2/de not_active Withdrawn
  • 2004-05-10 KR KR1020057021245A patent/KR20060003080A/ko not_active Application Discontinuation
  • 2004-05-10 US US10/556,059 patent/US20070108348A1/en not_active Abandoned
• 2005
  • 2005-11-09 NO NO20055281A patent/NO20055281L/no not_active Application Discontinuation

Non-Patent Citations (1)

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