EP1611261A2 - Annealing frame - Google Patents
Annealing frameInfo
- Publication number
- EP1611261A2 EP1611261A2 EP04724567A EP04724567A EP1611261A2 EP 1611261 A2 EP1611261 A2 EP 1611261A2 EP 04724567 A EP04724567 A EP 04724567A EP 04724567 A EP04724567 A EP 04724567A EP 1611261 A2 EP1611261 A2 EP 1611261A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- basket
- glow
- rack
- annealing
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000137 annealing Methods 0.000 title claims abstract description 54
- 239000000463 material Substances 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 238000005266 casting Methods 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000007669 thermal treatment Methods 0.000 abstract 1
- 238000010791 quenching Methods 0.000 description 7
- 230000000171 quenching effect Effects 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000110 cooling liquid Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0006—Details, accessories not peculiar to any of the following furnaces
- C21D9/0025—Supports; Baskets; Containers; Covers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D5/00—Supports, screens, or the like for the charge within the furnace
- F27D5/0006—Composite supporting structures
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0006—Details, accessories not peculiar to any of the following furnaces
- C21D9/0018—Details, accessories not peculiar to any of the following furnaces for charging, discharging or manipulation of charge
Definitions
- the invention relates to a glow rack, in particular for the transport of cast aluminum parts in the heat treatment process.
- Annealing racks for the transport of annealing material through an annealing furnace and also for quenching the annealing material in quenching liquid are exposed to large temperature fluctuations and local temperature differences, so that they suffer high thermal stresses.
- an annealing rack filled with annealing material enters an oven, the upper edge of the annealing rack first heats up, while the side walls and the bottom are initially kept cold by the annealing material. Due to the different heating, the glow rack is warped and broken.
- a method for annealing and flushing inside of copper tube coils the copper tube coils being arranged in annealing racks stacked one above the other when passing through an annealing furnace.
- the annealing frames can be stacked and unstacked fully automatically.
- Detachable connections between individual parts of the glow racks are not mentioned. With fixed connections, there is a risk of permanent bending, in the worst case even a break. There is no provision for securing the annealing material in the annealing rack. When the annealing rack is bent, the annealing material can thus shift or even tip over.
- a transport basket for annealing material in roller hearth furnaces is known with a multi-part base made of several grids lying side by side, which are articulated with little angular mobility by means of bolts and with end and side walls that are rigidly movable with the floor and with each other are connected by profile brackets.
- This transport basket is placed directly on the hearth rolls and taken away by them.
- the disadvantage of this is that the annealing material in such transport baskets can shift or tip over during transport and be damaged in the process.
- the side panels are firmly connected to the gratings, in particular welded. In this area, permanent bending or breakage may occur. This can also cause the annealing material to shift or tip over.
- Transport baskets bent in this way cannot be stacked. Such a stacking is also not provided.
- the invention is therefore based on the object of designing an annealing rack of the type mentioned, in particular for the transport of cast aluminum parts in the heat treatment process, in such a way that annealing material of the most varied shape is stored in it in a tilt-proof and non-slip manner during transportation.
- a glow rack of the type mentioned at the outset in that it is constructed from at least one glow rack element with at least one glow basket which can be placed therein and can be adapted to the annealing material.
- glow rack element By dividing the glow rack into glow rack element (s) on the one hand and glow basket / glow baskets on the other hand, good to be glowed can be safely inserted into the glow basket and then placed with it in the glow rack element. For heavier goods, the basket is first placed in the glow rack element and then filled. It is also conceivable to use two or more glow baskets per glow rack element.
- the above-mentioned division into two makes it possible to produce the glow rack element from a very stable material in a simple basic shape.
- the incandescent baskets are then to be individually designed for safe transport while avoiding moving or tipping over of the annealing material for the product to be transported.
- a less stable material can be selected for them than for the glow frame elements.
- An annealing article which is composed of several annealing frame elements, can thus accommodate annealing baskets of various designs for the safe transportation of annealing materials of various designs for an annealing process that takes place simultaneously or in succession.
- the glow rack according to the invention can be designed such that the glow rack elements can be stacked one above the other. As a result, the height of the glow rock can be based on the quantity of the material to be glowed.
- each glow rack element has at least one support and corner supports protruding upwards from the corners of the support.
- a centering aid in particular a cone-cone connection, is conceivable for the stacking of the glow rack elements, the end of the corner supports which is remote from the mounting surface being provided as a cone and the end located on the support being provided with a receiving cone. This enables safe stacking and unstacking.
- the stacked glow frame elements are prevented from slipping and falling under dynamic loads during transport.
- the floor can of course also be made in several parts. It can then be assembled depending on the space required.
- the floor can have a closed surface, but rust-shaped or frame-shaped floors are preferred. Perforated hollow profiles are preferably used for the frame.
- the corner supports can be connected to the support and / or to one another by means of frame struts in at least one of the glow rack elements.
- the frame struts stabilize the corner supports and can prevent the glow basket from slipping.
- the frame struts can e.g. B. be flat iron.
- the support, the corner supports and optionally the frame struts of the incandescent frame element are detachable, in particular connected to one another by plug connections. Due to the detachable connections, all dynamic and thermal loads arising during transport through the annealing furnace can be absorbed without causing permanent deformation. For this purpose, the connections are preferably with a small spike! perform. After quenching in a water bath, it does not happen a permanent distortion of the glow frame elements.
- the glow fabric element according to the invention is therefore suitable for frequent running through the heat treatment process. The individual components can be easily replaced. Storage costs are reduced because the dismantled glow frame elements and individual spare parts can be stored flat together.
- the glow rack according to the invention is designed such that at least one of the glow article elements is provided with means for releasably fixing the glow basket. This prevents or reduces slippage of the glow basket on the support of the glow rack element, particularly in the case of strong dynamic loads. In particular, depressions are conceivable in the support of the respective glow rack element, into which legs of the basket base or the glow basket with its entire base surface can then be placed.
- the glow rack according to the invention can have a glow basket in which the basket base is formed with basket supports protruding upwards.
- the components to be glowed are placed on the basket floor.
- the basket supports support the components somewhat. Depending on the shape and number of components, they can be arranged anywhere on the basket base.
- the basket supports are preferably hollow profiles, in particular perforated hollow profiles.
- the basket base can be made of perforated hollow profiles and z. B. be frame or rust-shaped.
- the glow rack according to the invention can also have basket struts, with the basket supports in at least one of the glow baskets being connected to the basket base and / or to one another by means of the basket struts.
- the basket base and the basket supports and optionally the basket struts can be detachably connected, in particular by plug connections.
- the connections of the basket floor, basket supports and possibly basket struts should preferably be carried out with little play. This prevents permanent distortion in the heat treatment process.
- the basket struts not only stabilize the basket supports, they can also support the components to be glowed. They can also be used in different ways depending on their needs Places are attached.
- the basket struts are preferably made of flat iron or perforated hollow profiles.
- wire brackets are releasably attached to the basket base and / or the basket supports and / or the basket struts.
- This wire bracket can in particular be inserted and / or screwed.
- These wire brackets are ideal for particularly complex aluminum components, such as those used in the automotive industry.
- Annealing material can be easily removed during the automatic loading and unloading process because it is centered by the wire bracket.
- the wire bracket can be pre-made
- FIG. 1 a front view of an embodiment of a glow frame element according to the invention.
- FIG. 6 a top view of the glow rack element according to FIG. 3 with the glow basket inserted.
- Fig. 7 a detailed view w of the plug-in connections basket strut / basket support of the glow basket
- Fig. 8 a detailed view x of the plug-in connection of the support profiles / corner support of the glow element.
- Fig. 9 a detailed view y of the pluggable and screwable connection of the wire bracket with the glow basket
- Figures 1-3 show a glow rack element 1 in front and side view and top view.
- FIG. 1 shows a short, horizontal, hollow support profile 2 as part of the support 3, which has a multiplicity of bores 4 and is connected to corner supports 6 via frame struts 5.
- All the hollow profiles used in the annealing rack, ie annealing rack elements and baskets, are preferably those with high moments of inertia.
- all hollow profiles with the same wall thickness are preferably selected in order to avoid different temperature profiles during the quenching process. Only some of the holes 4 are provided with reference numerals. Due to the inclined frame struts 5, accelerations and inertial forces can be better absorbed.
- the corner supports 6 are connected at their lower end to the support 3 and have a centering tip 7 at their upper end.
- the centering tips 7 of the respectively lower glow element elements 1 engage in corresponding bulges of the support 3 of the respective upper one Glow rack element 1 a. These bulges are not shown.
- the centering aids 7 enable safe stacking and unstacking. In the event of dynamic loads during transport, the stacked glow frame elements 1 are prevented from slipping and falling.
- a transport switching flag 8 in the form of an elongated plate is arranged between two corner supports 6.
- This transport switching flag 8 is also detachably fastened with bolts and split pins. It is detected by light barriers, not shown, and on the basis of this, the position of the glow rack for the process control is detected.
- an identification switch flag 17 is attached to one of the corner supports 6, from which details of each of the individual annealing frames or the annealing material transported therein can be read.
- the function of the positioning profile 9 shown is explained below in FIG. 3.
- FIG. 2 shows a long horizontal support profile 10 with holes 11 as part of the support 3 as well as frame struts 5 and corner supports 6 with centering aids 7.
- the long support profile 10 has a greater height than the short support profile 2. Only a few of the bores 11 are provided with reference numerals.
- the structure of the support 3 with two short support profiles 2 and two long support profiles 10 can be seen in the plan view according to FIG. 3. Only some of the holes 4 and 11 are marked with reference numerals, in the four corners of the support 3 are the four corner supports 6 with centering aids 7.
- the long support profiles 10 are about the positioning professional! 9 connected to each other.
- the positioning profile 9 has three square holes 12. As can be seen from FIGS. 5 and 10, the basket supports 18 are inserted into these square bores 12. Further explanations follow in the corresponding figure descriptions.
- FIGs 4 to 6 correspond to Figures 1 to 3. They also have a glow basket 13 which is inserted into a glow rack element 1.
- the basket floor 14 consists of two short floor profiles 15, which are arranged in parallel at a distance from one another and between which four long floor profiles 16 are arranged.
- the long "floor sections 16 are situated on the shorter Aufiageprofiien 2 and the positioning profile 9.
- DA- The positioning profile 9 not only serves to support the glow basket 13.
- the three square bores 12 also allow three basket supports 18 to be passed through the glow basket 13.
- These basket supports 18 and the positioning profile 9 are designed as hollow profiles.
- the basket supports 18 are in by gravity alone
- Basket supports 18 projecting upwards are arranged on the basket base 14.
- the basket supports 18 are connected to one another via basket struts 19, the long basket struts 19 covering the long base profiles 16 in the plan view according to FIG. 6.
- the basket supports 18 and the basket struts 19 of the glow basket 13 are either made from frequently perforated hollow profiles of the same wall thickness or from flat iron, the annealed material can be produced at quenching
- each part can be replaced individually if necessary.
- No complete glow rack elements 1 need to be stored. A small supply is completely sufficient, but when it is disassembled » 5 it only takes up a small amount of space.
- the plug connection of three parts of the glow basket 13 can be seen here.
- This plug connection detachably connects a short floor profile 15 with a long basket strut 19 ( 0) running perpendicularly thereto and also with a basket support 18 projecting vertically upwards from the basket bottom 14.
- the short floor profiles 15 have a rectangular bore 20 into which the basket support 18 which projects upwards is inserted with its lower end with play.
- This basket support 18 is drilled through above its insertion area and the long basket strut 19 is inserted through this hole with play.
- This long basket strut 19 thus lies on the short floor profile 15.
- the long basket strut 19 is secured at its inserted end with a split pin 21 with play.
- the three parts of the glow basket are therefore equipped with a certain mobility when plugged together, so that the stability of the basket is not adversely affected and the basket can handle stresses during heat treatment and dynamic loads.
- FIG. 8 The detail x from FIG. 1 is shown enlarged in FIG. 8. The plug connection of three parts of the glow frame element can be seen here.
- the long support profile 10 also has a securing bore 25 and 25 'on both sides.
- the securing bores 24, 24 'and 25, 25' in the long gene support profile 10 and in the corner support 6 are arranged in alignment.
- a securing bolt 26 is inserted parallel to the longitudinal axis of the inserted short support profile 2.
- the securing bolt 26 is secured with a split pin 27.
- the detail y from FIG. 6 is shown enlarged in FIG. 9.
- the plug-in and screw connection of wire brackets 30 on a long bottom profile 16 of the basket bottom 14 can be seen here.
- the wire brackets 30 shown are inserted or pushed through in bores of the long bottom profile 16.
- the inserted wire clips 30 are at the free ends of the wire clips! 30 screwed with self-locking nuts 31.
- the wire clips 30 are specially shaped. They serve to center aluminum parts during the automatic loading and unloading process.
- the wire clips 30 are adapted to the respective aluminum component to be held. The aluminum component is not shown.
- FIG. 10 The detail z from FIG. 4 is shown enlarged in FIG. 10. A plug connection for fixing a glow basket 13 to the glow rack element 1 can be seen here.
- the positioning profile 9 of the glow rack element is provided with two mutually opposite square bores 12 on its top and bottom sides in such a way that a basket support 1 of a glow basket 13 can be pushed through.
- the basket support 18 of the glow basket 13 is designed as a vertical hollow profile, the diameter of which is slightly smaller than the diameter of the two bores 2. In the inserted state, areas of the basket base 14 rest directly on the upper side of the positioning profile 9.
- the glow baskets are filled with the material to be treated, in particular aluminum castings for the automotive sector.
- the assembly is usually automatic.
- the baskets are already in the glow rack element or are lifted into them after assembly.
- Baskets are generally used that are self-supporting only when empty, but not with the annealing material inserted.
- the wire bracket can also be used to fix annealing material with very complicated geometries.
- the advantage of this division into two parts is that these baskets can be easily adapted to the components and the simply designed, stable glow frame elements take on the supporting function. After such an automatic stacking of several glow rack elements, the glow rack is moved into the furnace by means of transport rollers or transport chains.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Heat Treatments In General, Especially Conveying And Cooling (AREA)
- Furnace Charging Or Discharging (AREA)
- Heat Treatment Of Articles (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10315354A DE10315354A1 (en) | 2003-04-03 | 2003-04-03 | Glühgestell |
PCT/EP2004/003396 WO2004087969A2 (en) | 2003-04-03 | 2004-03-31 | Annealing frame |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1611261A2 true EP1611261A2 (en) | 2006-01-04 |
Family
ID=33038873
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04724567A Withdrawn EP1611261A2 (en) | 2003-04-03 | 2004-03-31 | Annealing frame |
Country Status (8)
Country | Link |
---|---|
US (1) | US7790100B2 (en) |
EP (1) | EP1611261A2 (en) |
JP (1) | JP4884208B2 (en) |
CN (1) | CN100392119C (en) |
BR (1) | BRPI0409145A (en) |
DE (1) | DE10315354A1 (en) |
MX (1) | MXPA03004193A (en) |
WO (1) | WO2004087969A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104878185B (en) * | 2015-05-06 | 2018-01-16 | 张家港市骏马钢帘线有限公司 | A kind of intensity of steel wire stabilising arrangement |
CN115261588B (en) * | 2022-08-18 | 2023-06-27 | 无锡博雷液压科技有限公司 | Online annealing heat treatment equipment for steel pipe |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE7217903U (en) * | 1972-08-31 | Klefisch R | Conveyor box for annealing furnace | |
US1854179A (en) * | 1930-05-26 | 1932-04-19 | Chicago Steel Foundry Company | Metallurgical device |
US2430521A (en) * | 1945-09-15 | 1947-11-11 | Mccormick George Clifton | Malleable annealing basket |
US2807454A (en) * | 1955-03-04 | 1957-09-24 | Rolock Inc | Stackable free sledding processing carrier |
US2962273A (en) * | 1958-04-22 | 1960-11-29 | Cambridge Wire Cloth | Material handling basket |
US3499634A (en) * | 1968-02-14 | 1970-03-10 | Champion Spark Plug Co | Combustible support |
US3642263A (en) * | 1969-02-03 | 1972-02-15 | Hayes Inc C I | Workbasket for use in heat-treating furnace |
DE2856041A1 (en) * | 1978-12-23 | 1980-07-10 | Bbc Brown Boveri & Cie | DEVICE IN THE SHAPE OF A BASKET FOR TRANSPORTING Bulk goods through heat treatment furnaces |
DE2904722C2 (en) * | 1979-02-08 | 1982-08-05 | Rudolf 5000 Köln Klefisch | Annealing basket |
DE3011114C2 (en) * | 1980-03-22 | 1983-01-27 | Rudolf 5000 Köln Klefisch | Annealing basket made of heat-resistant steel rods |
DE3217794C2 (en) | 1982-05-12 | 1984-05-03 | Rudolf 5000 Köln Klefisch | Transport basket for annealing material in roller hearth furnaces |
JPS6120553U (en) * | 1984-07-07 | 1986-02-06 | トヨタ自動車株式会社 | heat treatment jig |
JPS6120553A (en) * | 1984-07-09 | 1986-01-29 | 西野 善夫 | Multiple rod type health step board |
DE3444507A1 (en) * | 1984-12-06 | 1986-06-12 | Rudolf 5000 Köln Klefisch | Transport basket for roller-hearth furnaces |
JP2895499B2 (en) * | 1989-03-07 | 1999-05-24 | 株式会社豊田中央研究所 | Heat treatment method and apparatus |
CN2221030Y (en) * | 1994-02-26 | 1996-02-28 | 冶金工业部重庆钢铁设计研究院 | Switch quenching apparatus |
US5492552A (en) * | 1994-03-03 | 1996-02-20 | Minnesota Mining And Manufacturing Company | Holder for annealing fiber optic coils |
JP3327436B2 (en) * | 1994-11-30 | 2002-09-24 | 大平洋特殊鋳造株式会社 | Jig for casting heat treatment |
DE19830485C2 (en) * | 1998-07-08 | 2002-10-24 | Wieland Werke Ag | Device for annealing copper tube coils |
EP0997541A1 (en) * | 1998-10-26 | 2000-05-03 | ALUMINIUM RHEINFELDEN GmbH | Heat treating box for annealing and degreasing pieces made of aluminium |
JP2001207212A (en) * | 2000-01-25 | 2001-07-31 | Daido Steel Co Ltd | Container for heat treatment |
MXPA03000577A (en) | 2001-05-29 | 2004-12-13 | Demmer Corp | Heat treatment container. |
-
2003
- 2003-04-03 DE DE10315354A patent/DE10315354A1/en not_active Ceased
- 2003-05-13 MX MXPA03004193A patent/MXPA03004193A/en active IP Right Grant
-
2004
- 2004-03-31 WO PCT/EP2004/003396 patent/WO2004087969A2/en active Application Filing
- 2004-03-31 JP JP2006504928A patent/JP4884208B2/en not_active Expired - Fee Related
- 2004-03-31 BR BRPI0409145-0A patent/BRPI0409145A/en not_active Application Discontinuation
- 2004-03-31 EP EP04724567A patent/EP1611261A2/en not_active Withdrawn
- 2004-03-31 CN CNB2004800085786A patent/CN100392119C/en not_active Expired - Fee Related
- 2004-03-31 US US10/550,706 patent/US7790100B2/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
---|
See references of WO2004087969A2 * |
Also Published As
Publication number | Publication date |
---|---|
MXPA03004193A (en) | 2004-10-29 |
CN1768153A (en) | 2006-05-03 |
DE10315354A1 (en) | 2004-10-28 |
WO2004087969A2 (en) | 2004-10-14 |
US7790100B2 (en) | 2010-09-07 |
WO2004087969A3 (en) | 2005-01-13 |
JP4884208B2 (en) | 2012-02-29 |
US20070267788A1 (en) | 2007-11-22 |
BRPI0409145A (en) | 2006-03-28 |
CN100392119C (en) | 2008-06-04 |
JP2006522219A (en) | 2006-09-28 |
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