EP1594942A1 - Neue verwendung von phosphor-stickstoff-metall-komplex - Google Patents
Neue verwendung von phosphor-stickstoff-metall-komplexInfo
- Publication number
- EP1594942A1 EP1594942A1 EP04701638A EP04701638A EP1594942A1 EP 1594942 A1 EP1594942 A1 EP 1594942A1 EP 04701638 A EP04701638 A EP 04701638A EP 04701638 A EP04701638 A EP 04701638A EP 1594942 A1 EP1594942 A1 EP 1594942A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- combustion zones
- application according
- combustion
- nitrogen
- phosphorus
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000446 fuel Substances 0.000 claims abstract description 28
- 239000000126 substance Substances 0.000 claims abstract description 15
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 7
- 230000000536 complexating effect Effects 0.000 claims abstract description 4
- 238000002485 combustion reaction Methods 0.000 claims description 43
- 239000000654 additive Substances 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 239000003502 gasoline Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000010779 crude oil Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 10
- 230000003247 decreasing effect Effects 0.000 abstract description 6
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 21
- 239000007789 gas Substances 0.000 description 19
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000003921 oil Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 239000002283 diesel fuel Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000003345 natural gas Substances 0.000 description 6
- 230000007423 decrease Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910000398 iron phosphate Inorganic materials 0.000 description 5
- 229910021645 metal ion Inorganic materials 0.000 description 5
- 235000019391 nitrogen oxide Nutrition 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 239000002737 fuel gas Substances 0.000 description 4
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- GODZNYBQGNSJJN-UHFFFAOYSA-N 1-aminoethane-1,2-diol Chemical compound NC(O)CO GODZNYBQGNSJJN-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- CPSYWNLKRDURMG-UHFFFAOYSA-L hydron;manganese(2+);phosphate Chemical compound [Mn+2].OP([O-])([O-])=O CPSYWNLKRDURMG-UHFFFAOYSA-L 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 230000009916 joint effect Effects 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229940077478 manganese phosphate Drugs 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical group [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- 229940077935 zinc phosphate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/02—Use of additives to fuels or fires for particular purposes for reducing smoke development
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
Definitions
- the present invention relates to new applications of the alkali metal-phosphorus-nitrogen complex for reducing emission and decreasing fuel consumption.
- the present invention relates to the formation of alkali metal- phosphorus-nitrogen complex surfaces with complexing chemicals introduced into the fuels, for reducing emission and decreasing fuel consumption.
- the reduced emission, accompanied by fuel saving, is partly due to the newly formed surface, and to the result of catalytic processes.
- Iron-phosphate surfaces were used in Great-Britain even in
- 5,540,788 describes a procedure, in which an inorganic polimer complexing substance is added to the lubricating oil, this way creating an alkali-iron-phosphate surface on the inner surfaces of the combustion zone of the engines, and this results in the improvement of the efficiency of the engine, and the reduction of friction. But the procedure didn't provide solution for other highly used equipments, without direct lubricating in the combustion zone, like for example for the gas turbines, in which the surface of the combustion zone is exposed to extreme thermal and corrosive effects.
- the burner is suitable for the use of vanadium containing additives, because the vanadium-pentoxide, reacting with the magnesium ions in the introduced aqueous solution, inhibits their corrosive deposition.
- vanadium containing additives because the vanadium-pentoxide, reacting with the magnesium ions in the introduced aqueous solution, inhibits their corrosive deposition.
- iron-phosphate surfaces are the most widely used surfaces in the industry. Due to their numerous advantages they are excellently suitable for example for the application in the vehicle industry, for example for the priming of the car-body. Moreover these surfaces provide excellent corrosion protection for the different, iron containing structural components.
- the friction-coefficient of the iron- phosphate surface is significantly lower than that of the steel, and provides dry lubrication on the moving-gliding steel surfaces. Moreover the surface has many characteristics, which improve the efficiency of the oil lubrication.
- organic phosphate compounds are widely used, for example in the lubricating oil. It is known, that certain organic phosphates slowly burn into the gears and into another moving components, and provide excellent protection for the metals. But at the same time the burning shows random distribution, which reduces the application possibilities in the different machines.
- the present invention provides method for the formation of alkali metal-phosphorus-nitrogen complex surfaces in the combustion zone of gas turbines and similar equipments, in such a way that the surface builder substance is introduced into the combustion zone by mixing into the fuel and/ or into the air necessary for combustion.
- the surface builder substance can also be mixed with gasoline or diesel oil, and must be injected into natural gas.
- the surface builder substance and the gas can never be in the same state of condition - the natural gas is characteristically in gas state, while the surface builder substance is liquid. According to this, typically the surface builder substances must be injected into the natural gas used as fuel, because they form surface, and reduce the formation of deleterious element, and the total oxidation of the C-containing compound, and at the same time inhibit the formation of thermic nitrogen oxides. This results in the reduced emission and the higher performance per unit fuel.
- Solution 2 is added in portions to solution 1 while mixing, until the pH of the solution is 7,0.
- the resulting water soluble solution contains the alkali metal-phosphorus-nitrogen-metal complex.
- This water soluble, neutralized complex is added to a "poly-oil".
- the "poly-oil” is any one of a member of poly-glycol or poly-glycol-amine oils, which has a water solubility of at least ten percent, and has a solubility at least ten percent in the liquid hydrocarbon used for the introduction into the combustion zone. All the precipitated materials are filtered off the solution containing the alkali-phosphorus-nitrogen-metal complex, and is mixed into the chosen "poly-oil".
- one part of the complex is mixed into 9-25 part "poly- 5 oil".
- the mixture is continuously stirred, and heated just under the boiling point of 100 °C.
- the mixture is kept at this temperature, and stirred to drive out the water. Once the water is "cooked off, the remaining mixture will turn to a clear amber color very quickly. Then the heat is removed, and the o solution is allowed to cool.
- the color of the solution is normally determined by the used "poly-oil".
- concentration is computed for the amount required.
- concentration in diesel fuel is about 20 parts of phosphorus- 5 nitrogen-metal complex per billion parts of fuel.
- concentration of the surface builder substance must be 500 per one million.
- Characterization of the formed surface is as follows: 0l . Improved heat transfer properties for turbine blades, that make the turbine system perform closer to adiabatic conditions; 2. Improved wear properties for all combustion zone of the engine. 5 There are other benefits that can be associated with the
- the present invention relates to the use of the complex foming additive in the industrial turbines and jet engines.
- One characteristic of the surface builder substance is its ease of use in a variety of common hydrocarbon fuels.
- the surface builder can be formulated to be directly mixed with either gasoline, diesel fuel or aviation diesel (JP-4 and others) and in natural gas.
- the fuel gas pressure ranges from 4 to 10 atmospheres, and the surface builder is injected into the gas stream ranging in pressure from 20 to 500 atmospheres. By injecting the surface builder in this manner, the surface builder enters the gas stream in colloid state.
- FIG. 1 shows an uncoated metal surface
- Figure 2 and Figure 3 show a surface "under construction”.
- the clusters of the alkali-phosphorus-nitrogen-metal complexes can be noticed.
- Figure 2 and Figure 3 the clusters of the alkali-phosphorus- nitrogen complexes have reacted with the surface of the combustion zone, to form the new alkali-phosphorus-nitrogen- metal complex surface.
- the thickness of the new surface is measured in microne, but as it can be seen on Figure 2 and Figure 3, this alkali- phosphorus-nitogen-metal complex is sufficient to present a different surface composition with the fuel air mixture in the combustion zone.
- the alkali-phosphorus-nitrogen-metal surface catalyzes the fuel-air reaction, reducing the unburned hydrocarbon (UHC) and the CO, reduces the secondary reactions, producing nitrogen oxides. After formation of the new surface the nitrogen and the oxigen can not react directly with the metal surface, and the main source of the nitrogen- oxides ceases to exist. (Because the Ni and Cr containing metals catalyze the formation of NO x ).
- the emission reducing and fuel saving effects of the surface builder realizes to a greater extent.
- the complex forming additive can also be used in explosion engines. Certain complexes can be added to the fuel- system of the explosion engines or continuous combustion engines, which form a thin, new layer on the wall of the combustion zone and on the surfaces exposed to the combustion gas.
- This thin layer has beneficial effects for the operation characteristics of the engine, as a result of which the emission of carbon-monoxide (CO), the unburned hydrocarbon (UHC), the nitrogen oxides (NO x ), and the fuel consumption of the vehicle decreases. These beneficial characteristics can be attributed to the better and more complete combustion of the fuels, what is caused by the interaction between the fuel and the thin layer (The carbon deposit disappeared from the exhaust pipe of the experimental vehicles).
- the surface builder may be used with both diesel and gasoline engines, by simply adding the surface builder to the fuel system. The composition of the surface builder has been changed from the original water soluble form to oil soluble form, and as a result of this change the surface builder became soluble in gasoline and in diesel oil, and in any other hydrocarbon based fuel.
- the first step is a "clean-up" phase, when the carbon buildup, particularly carbon deposits in diesel engines are cleaned from the internal working surface, due to the increased reactivity of the surface builder and diesel fuel.
- This "cleanup phase” takes place at any time duration within hours up to two weeks.
- the second step is where the vehicle driver experiences a "sudden" increase in performance. This can be experienced as in sudden engine surge or an increased performance, quieter engine and decreased fuel consumption. This is the joint effect of the complex surface formed and the catalyzed combustion.
- the third and final step when the emission and the fuel consumption is reduced.
- the surface builder described above is only one of the thousand complexes, capable of changing the surface of the combustion zones.
- the surface builder can be any molecule group, which is characterized by joining a metal ion and an alkali-phosphorus-nitrogen bond.
- the present invention not only makes easier the use of the earlier described surface builders, but also by making possible their use in combustion equipments results in the decrease of emission to such an extent, which can initiate changes in the environmental protection up to now unthinkable.
- combustion equipments can be for example the gas firing heat treating furnaces, coal heating boilers and refuse burners.
- the surface builder is introduced into the combustion zone by mixing/ vaporizing into the fuel and/ or into the air necessary for combustion.
- the surface builder has corrosion reduction effects in each metal containing combustion zones. By catalyzing combustion, it reduces fuel consumption, and as a consequence of the more complete combustion, the emission also decreases.
- the additive according to the present invention is injected into the gas firing tube of a natural gas powered 10 MW General Electric gas turbine, before introducing it into the combustion zone.
- Digitally controlled injector is used for compounding, which keeps the fuel gas/ surface builder ratio constant during the 6 hour ' s measurement, i.e. 30-60 ml additive is vaporized into 100 Nm 3 natural gas.
- the emission of the gas turbine is constantly registered.
- the level of the unburned hydrocarbon drops under 0, 1 ppm from the starting 25-35 ppm value.
- the amount of carbon-monoxide drops under the measuring range of the instrument from the starting 0,01% value.
- the amount of nitrogen oxides (NO x ) drops under 2 ppm from the starting 80-90 ppm value.
- Example 1 With the gas turbine used in Example 1. the experiment is repeated for 72 hours, in such a way that the complex is dissolved in diesel fuel, which is more difficult to vaporize. This way additive of bigger particle size enters the combustion zone, which reduces its efficiency, because of the higher viscosity and the weaker vapour-liquid ratio. Despite this the turbine met the more rigorous emission requirements during the measuring.
- a carbon steel piece is heated with gas flame, under standard conditions, at 1100-1300 °C, for 6 hours, with and without additive.
- the addition of the complex compound in the gas in 1/ 1280 ratio results differences visible with the unaided eye both in scale formation and in corrosion.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU0300105 | 2003-01-13 | ||
| HU0300105A HUP0300105A3 (en) | 2003-01-13 | 2003-01-13 | A new application of phosphorus-nitrogen-metal complex layer |
| PCT/HU2004/000001 WO2004069965A1 (en) | 2003-01-13 | 2004-01-13 | Novel use of phosphor-nitrogen-metal complex |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1594942A1 true EP1594942A1 (de) | 2005-11-16 |
Family
ID=89981077
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP04701638A Withdrawn EP1594942A1 (de) | 2003-01-13 | 2004-01-13 | Neue verwendung von phosphor-stickstoff-metall-komplex |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1594942A1 (de) |
| JP (1) | JP2006516301A (de) |
| HU (1) | HUP0300105A3 (de) |
| PL (1) | PL377902A1 (de) |
| WO (1) | WO2004069965A1 (de) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EA008844B1 (ru) | 2003-06-23 | 2007-08-31 | Инвайрофьюэлз Л.П. | Добавка к углеводородному топливу, топливо на ее основе и способы их получения |
| UY29142A1 (es) * | 2004-09-28 | 2006-11-30 | Envirofuels Lp | Aditivo para combustible hidrocarbonado liquido o licuado para quemadores de fuego directo, llamas abiertas y procesos relacionados |
| AR052791A1 (es) * | 2004-11-15 | 2007-04-04 | Envirofuels Lp | Aditivo para combustible hidrocarbonado solido en quemadores de fuego directo, hornos, llamas abiertas y procesos relacionados |
| WO2010026598A1 (en) * | 2008-09-08 | 2010-03-11 | Raju Alluri Sreenivasa | Fuel saving process using hollow micro spheres in internal combustion engine |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB776502A (en) * | 1954-07-12 | 1957-06-05 | Bataafsche Petroleum | Method of lubricating solid surfaces |
| US3483178A (en) * | 1968-04-18 | 1969-12-09 | Monsanto Co | Esters,salts,and acids of organo-phosphono-amine oxides |
| US3734963A (en) * | 1969-03-18 | 1973-05-22 | Exxon Co | Inorganic lithium-amine complexes |
| SG71668A1 (en) * | 1992-09-11 | 2000-04-18 | Chevron Usa Inc | Fuel composition for two-cycle engines |
| US5540788A (en) * | 1995-02-24 | 1996-07-30 | Mdechem, Inc. | Method of preparing iron-phosphate conversion surfaces |
-
2003
- 2003-01-13 HU HU0300105A patent/HUP0300105A3/hu unknown
-
2004
- 2004-01-13 WO PCT/HU2004/000001 patent/WO2004069965A1/en active Application Filing
- 2004-01-13 JP JP2006502342A patent/JP2006516301A/ja active Pending
- 2004-01-13 EP EP04701638A patent/EP1594942A1/de not_active Withdrawn
- 2004-01-13 PL PL377902A patent/PL377902A1/pl unknown
Non-Patent Citations (1)
| Title |
|---|
| See references of WO2004069965A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| HU0300105D0 (en) | 2003-03-28 |
| WO2004069965A1 (en) | 2004-08-19 |
| PL377902A1 (pl) | 2006-02-20 |
| WO2004069965A8 (en) | 2005-08-25 |
| HUP0300105A3 (en) | 2005-05-30 |
| JP2006516301A (ja) | 2006-06-29 |
| HUP0300105A2 (hu) | 2004-05-28 |
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