EP1555898A2 - Cigarette chauffee electriquement comprenant un arome a liberation controlee - Google Patents
Cigarette chauffee electriquement comprenant un arome a liberation controleeInfo
- Publication number
- EP1555898A2 EP1555898A2 EP03776589A EP03776589A EP1555898A2 EP 1555898 A2 EP1555898 A2 EP 1555898A2 EP 03776589 A EP03776589 A EP 03776589A EP 03776589 A EP03776589 A EP 03776589A EP 1555898 A2 EP1555898 A2 EP 1555898A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- electrically heated
- flavoring
- heated cigarette
- cigarette
- release additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 255
- 238000013270 controlled release Methods 0.000 title description 9
- 241000208125 Nicotiana Species 0.000 claims abstract description 83
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 83
- 239000000654 additive Substances 0.000 claims abstract description 65
- 230000000391 smoking effect Effects 0.000 claims abstract description 63
- 239000002594 sorbent Substances 0.000 claims abstract description 61
- 230000000996 additive effect Effects 0.000 claims abstract description 53
- 239000011324 bead Substances 0.000 claims abstract description 46
- 239000000779 smoke Substances 0.000 claims abstract description 39
- 239000000470 constituent Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 27
- 239000000835 fiber Substances 0.000 claims description 22
- 239000010457 zeolite Substances 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 18
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical group O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 17
- 229910021536 Zeolite Inorganic materials 0.000 claims description 16
- 239000000796 flavoring agent Substances 0.000 claims description 15
- 235000019634 flavors Nutrition 0.000 claims description 15
- 229920000858 Cyclodextrin Polymers 0.000 claims description 12
- 239000011800 void material Substances 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 8
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims description 6
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims description 6
- CBOQJANXLMLOSS-UHFFFAOYSA-N ethyl vanillin Chemical group CCOC1=CC(C=O)=CC=C1O CBOQJANXLMLOSS-UHFFFAOYSA-N 0.000 claims description 6
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 claims description 6
- 229940041616 menthol Drugs 0.000 claims description 6
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 239000001730 (5R)-5-butyloxolan-2-one Substances 0.000 claims description 5
- 239000001116 FEMA 4028 Substances 0.000 claims description 5
- 235000006679 Mentha X verticillata Nutrition 0.000 claims description 5
- 235000002899 Mentha suaveolens Nutrition 0.000 claims description 5
- 235000001636 Mentha x rotundifolia Nutrition 0.000 claims description 5
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical group OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 5
- 235000011175 beta-cyclodextrine Nutrition 0.000 claims description 5
- 229960004853 betadex Drugs 0.000 claims description 5
- IPBFYZQJXZJBFQ-UHFFFAOYSA-N gamma-octalactone Chemical compound CCCCC1CCC(=O)O1 IPBFYZQJXZJBFQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 claims description 3
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 claims description 3
- 235000001453 Glycyrrhiza echinata Nutrition 0.000 claims description 3
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 3
- 235000017382 Glycyrrhiza lepidota Nutrition 0.000 claims description 3
- 235000019501 Lemon oil Nutrition 0.000 claims description 3
- 244000299461 Theobroma cacao Species 0.000 claims description 3
- 239000008376 breath freshener Substances 0.000 claims description 3
- 235000019219 chocolate Nutrition 0.000 claims description 3
- 239000001926 citrus aurantium l. subsp. bergamia wright et arn. oil Substances 0.000 claims description 3
- 229940073505 ethyl vanillin Drugs 0.000 claims description 3
- 239000008369 fruit flavor Substances 0.000 claims description 3
- 239000010648 geranium oil Substances 0.000 claims description 3
- 235000019717 geranium oil Nutrition 0.000 claims description 3
- 239000010649 ginger oil Substances 0.000 claims description 3
- 239000010501 lemon oil Substances 0.000 claims description 3
- 229940010454 licorice Drugs 0.000 claims description 3
- 229930007744 linalool Natural products 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229960001047 methyl salicylate Drugs 0.000 claims description 3
- 235000013599 spices Nutrition 0.000 claims description 3
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920001817 Agar Polymers 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920002148 Gellan gum Polymers 0.000 claims description 2
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 2
- 229920002752 Konjac Polymers 0.000 claims description 2
- 235000019482 Palm oil Nutrition 0.000 claims description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 2
- 229920002494 Zein Polymers 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 239000008272 agar Substances 0.000 claims description 2
- 235000010419 agar Nutrition 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 235000010492 gellan gum Nutrition 0.000 claims description 2
- 239000000216 gellan gum Substances 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 2
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 2
- 229940071676 hydroxypropylcellulose Drugs 0.000 claims description 2
- 239000000252 konjac Substances 0.000 claims description 2
- 235000019823 konjac gum Nutrition 0.000 claims description 2
- 239000000845 maltitol Substances 0.000 claims description 2
- 235000010449 maltitol Nutrition 0.000 claims description 2
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 claims description 2
- 229940035436 maltitol Drugs 0.000 claims description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 2
- 239000002540 palm oil Substances 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 229960002920 sorbitol Drugs 0.000 claims description 2
- 235000010356 sorbitol Nutrition 0.000 claims description 2
- MWOOGOJBHIARFG-UHFFFAOYSA-N vanillin Chemical compound COC1=CC(C=O)=CC=C1O MWOOGOJBHIARFG-UHFFFAOYSA-N 0.000 claims description 2
- FGQOOHJZONJGDT-UHFFFAOYSA-N vanillin Natural products COC1=CC(O)=CC(C=O)=C1 FGQOOHJZONJGDT-UHFFFAOYSA-N 0.000 claims description 2
- 235000012141 vanillin Nutrition 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 239000000811 xylitol Substances 0.000 claims description 2
- 235000010447 xylitol Nutrition 0.000 claims description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 2
- 229960002675 xylitol Drugs 0.000 claims description 2
- 239000005019 zein Substances 0.000 claims description 2
- 229940093612 zein Drugs 0.000 claims description 2
- 244000303040 Glycyrrhiza glabra Species 0.000 claims 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 16
- 239000011148 porous material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 230000008569 process Effects 0.000 description 10
- 239000002808 molecular sieve Substances 0.000 description 9
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 9
- 239000003570 air Substances 0.000 description 7
- 230000005012 migration Effects 0.000 description 7
- 238000013508 migration Methods 0.000 description 7
- 238000001179 sorption measurement Methods 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical group O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000001914 filtration Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 235000019640 taste Nutrition 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- WYTGDNHDOZPMIW-RCBQFDQVSA-N alstonine Natural products C1=CC2=C3C=CC=CC3=NC2=C2N1C[C@H]1[C@H](C)OC=C(C(=O)OC)[C@H]1C2 WYTGDNHDOZPMIW-RCBQFDQVSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 240000004670 Glycyrrhiza echinata Species 0.000 description 2
- 244000024873 Mentha crispa Species 0.000 description 2
- 235000014749 Mentha crispa Nutrition 0.000 description 2
- 244000246386 Mentha pulegium Species 0.000 description 2
- 235000016257 Mentha pulegium Nutrition 0.000 description 2
- 235000004357 Mentha x piperita Nutrition 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000002745 absorbent Effects 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000019568 aromas Nutrition 0.000 description 2
- 235000017803 cinnamon Nutrition 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 229940097362 cyclodextrins Drugs 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000004924 electrostatic deposition Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 235000001050 hortel pimenta Nutrition 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000013618 particulate matter Substances 0.000 description 2
- 230000037361 pathway Effects 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229920001450 Alpha-Cyclodextrin Polymers 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 1
- 229940043377 alpha-cyclodextrin Drugs 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- -1 cyclic oligosaccharides Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011325 microbead Substances 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 206010048828 underweight Diseases 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
- A24B15/284—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances the additive being bound to a host by chemical, electrical or like forces, e.g. use of precursors, inclusion complexes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/01—Making cigarettes for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/08—Cigars; Cigarettes with lighting means
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/17—Filters specially adapted for simulated smoking devices
Definitions
- BACKGROUND Traditional cigarettes are smoked by lighting an end of a wrapped tobacco rod and drawing air predominately through the lit end by suction at a mouthpiece end of the cigarette. Traditional cigarettes deliver smoke as a result of combustion, during which tobacco is combusted at temperatures that typically exceed 800 °C during a puff. The heat of combustion releases various gaseous combustion products and distillates from the tobacco. As these gaseous products are drawn through the cigarette, they cool and condense to form an aerosol, which provides the flavors and aromas associated with smoking. [0002] Traditional cigarettes produce sidestream smoke during smoldering between puffs. Once lit, they normally are fully consumed or discarded. Relighting a traditional cigarette is possible, but is not desirable for subjunctive reasons including flavor, taste and odor.
- An alternative to the more traditional cigarette is the electrically heated cigarette used in electrical smoking systems.
- electrical smoking systems significantly reduce sidestream smoke, and also permit smokers to suspend and reinitiate smoking as desired.
- Exemplary electrical smoking systems are disclosed in commonly-assigned U.S. Patents Nos. 6,026,820; 5,988,176; 5,915,387; 5,692,526; 5,692,525; 5,666,976; 5,499,636; and 5,388,594, each of which is hereby incorporated by reference in its entirety.
- Electrical smoking systems include an electrically powered lighter and an electrically heated cigarette, which is constructed to cooperate with the lighter.
- electrical smoking systems be capable of delivering smoke in a manner similar to the smoker's experiences with traditional cigarettes, such as by providing an immediacy response (smoke delivery occurring immediately upon draw), a desired level of delivery (that correlates with FTC tar level), a desired resistance to draw (RTD), as well as puff-to-puff and cigarette-to-cigarette consistency.
- Nolatile flavorings have been incorporated in traditional cigarettes to add flavors and aromas to mainstream and sidestream tobacco smoke. See, for example, U.S. Patents ⁇ os. 3,006,347; 3,236,244; 3,344,796; 3,426,011; 3,972,335; 4,715,390; 5,137,034; 5,144,964; and 6,325,859, and commonly- owned International Publication No. WO 01/80671.
- the added flavorings are desirably volatilized when the cigarette is smoked.
- volatile flavorings tend to migrate in the cigarette to other components and possibly through the entire cigarette. Nolatile flavorings can be lost from cigarettes during storage and distribution at ordinary conditions prior to smoking of the cigarettes.
- Flavorings that have been incorporated in traditional cigarettes also can chemically and/or physically deteriorate by contacting and/or reacting with other components of the cigarette, as well as with the environment.
- activated carbon has been incorporated in traditional cigarettes to remove gas- phase constituents from mainstream smoke.
- flavorings that have been incorporated in the cigarettes along with the activated carbon have been adsorbed by the activated carbon, clogging pores of the activated carbon and consequently deactivating the activated carbon, thereby diminishing its ability to filter tobacco smoke.
- an electrically heated cigarette which includes a sorbent and a controlled-release flavoring.
- the electrically heated cigarette comprises a sorbent and a flavoring incorporated in the cigarette in a form that preferably minimizes release and migration of the flavoring in the cigarette prior to smoking, for example, at ambient conditions, and thus preferably minimizes deactivation of the sorbent by the flavoring.
- the flavoring preferably is released in the cigarette in a controlled manner during smoking. Consequently, the flavoring preferably enhances subjective characteristics of the cigarette while the sorbent maintains its ability to remove gas-phase constituents from mainstream smoke.
- a preferred embodiment of the electrically heated cigarette comprises at least one sorbent and a flavoring-release additive including one or more flavorings.
- the flavoring is releasable in the cigarette upon the flavoring-release additive being heated to at least a minimum temperature, which occurs during smoking of the cigarette.
- the flavoring-release additive can be incorporated in various forms in the electrically heated cigarette.
- the flavoring-release additive comprises beads.
- the flavoring-release additive is a film.
- the flavoring-release additive is an inclusion complex including a selected host molecule, and the flavoring as a guest molecule in the inclusion complex.
- two or more different flavoring-release additives having different flavoring release temperatures are located at different locations in an electrically heated cigarette that reach different temperatures from each other.
- the flavoring-release additives can be located at locations in the electrically heated cigarette that reach the flavoring release temperature for those flavoring-release additives.
- the flavoring-release additive can provide efficient, controlled release of the flavoring during smoking.
- the electrically heated cigarette can comprise various sorbents.
- the flavoring in the flavoring-release additive which preferably minimizes release and/or migration of the flavoring until the flavoring-release additive reaches the flavoring release temperature, the flavoring is preferably substantially prevented from being sorbed by, and thus deactivating, the sorbent, thereby not adversely affecting the sorbent' s ability to remove selected gas-phase constituents from mainstream tobacco smoke.
- the flavoring is temperature released in the cigarette, it can be effectively delivered to a smoker in a controlled manner during puff cycles of the cigarette.
- a preferred embodiment of an electrical smoking system comprises a lighter and at least one electrically heated cigarette including at least one sorbent and a flavoring-release additive.
- a preferred embodiment of a method of making an electrically heated cigarette comprises incorporating a sorbent and a flavoring-release additive into an electrically heated cigarette.
- FIG. 1 illustrates a preferred embodiment of an electrically heated cigarette for use in an electrical smoking system with the cigarette in a partially unassembled condition.
- FIG. 2 illustrates the electrically heated cigarette shown in FIG. 1 in the assembled condition with one end of the cigarette contacting a stop piece of an electrically operated lighter of the electrical smoking system.
- FIG. 3 illustrates another preferred embodiment of an electrically heated cigarette for use in an electrical smoking system with the cigarette in a partially unassembled condition.
- FIG. 4 illustrates a preferred embodiment of an electrical smoking system with an electrically heated cigarette inserted into the electrically operated lighter.
- FIG. 5 illustrates the electrical smoking system shown in FIG. 4 with the cigarette withdrawn from the lighter.
- FIG. 6 illustrates a heater fixture of the electrical smoking system.
- An electrically heated cigarette includes one or more sorbents and at least one flavoring for affecting flavor, taste, and/or aroma of tobacco smoke.
- the flavoring is incorporated in the cigarette in a flavoring- release additive, which preferably minimizes the release and/or migration of the flavoring in the cigarette prior to smoking.
- the flavoring is released from the flavoring-release additive in a controlled manner during smoking of the cigarette.
- the flavoring-release additive enables the flavoring to enhance subjective characteristics of the cigarette while avoiding an adverse impact on the effectiveness of the sorbent in removing selected gas-phase constituents from mainstream smoke.
- the flavoring is released in the cigarette upon the flavoring-release additive being heated to at least a minimum temperature (flavoring release temperature), which occurs when a smoker draws mainstream smoke through the cigarette.
- different flavoring-release additives are selectively disposed at two or more locations in the electrically heated cigarette that respectively reach at least the minimum temperature at which the flavoring is released from the flavoring-release additive disposed at that location.
- the flavoring-release additive can have various constructions and compositions and can be located at one or more locations, and/or incorporated in one or more components of the electrically heated cigarette.
- the flavoring-release additives can be designed to have different associated flavoring release temperatures.
- the flavoring-release additives can be incorporated in the electrically heated cigarette at locations that are most suitable for providing efficient release of the flavoring from the particular flavoring-release additive.
- the electrically heated cigarette can comprise one or more sorbents capable of removing selected gas-phase constituents from mainstream smoke.
- the flavoring-release additive enables the flavoring to be effectively delivered to a smoker in a controlled manner.
- sorption denotes filtration by adsorption and/or absorption. Sorption is intended to encompass interactions on the outer surface of the sorbent, as well as interactions within the pores and channels of the sorbent.
- a "sorbent” is a substance that has the ability to condense or hold molecules of other substances on its surface, and/or the ability to take up other substances, i.e., through penetration of the other substances into its inner structure, or into its pores.
- sorbent refers to either an adsorbent, an absorbent, or a substance that can function as both an adsorbent and an absorbent.
- mainstream smoke includes the mixture of gases passing down the tobacco rod and issuing through the filter end, i.e., the amount of smoke issuing or drawn from the mouth end of a cigarette during smoking of the cigarette.
- mainstream smoke contains air that is drawn in through the heated region of the cigarette and through the paper wrapper.
- FIGS. 1 and 2 illustrate a preferred embodiment of the electrically heated cigarette 23.
- the electrically heated cigarette 23 comprises a tobacco rod 60 and a filter tipping 62 joined together by tipping paper 64.
- the tobacco rod 60 preferably includes a tobacco web or "mat" 66 folded into a tubular form about a free-flow filter 74 at one end and a tobacco plug 80 at the other end.
- An over wrap 71 surrounds the tobacco-containing mat 66 and is held together along a longitudinal seam. The over wrap 71 retains the mat 66 in a wrapped condition about the free-flow filter 74 and tobacco plug 80.
- the mat 66 preferably comprises a base web 68 and a layer of tobacco material 70. The tobacco material 70 can be located along the inside surface or the outside surface of the base web 68. At the tipped end of the tobacco rod 60, the mat 66 and the over wrap 71 are wrapped about the free-flow filter plug 74.
- the tobacco plug 80 comprises a relatively short tobacco column 82 of cut filler tobacco, which is retained by a surrounding inner wrap 84.
- a void 90 is between the free-flow filter 74 and the tobacco plug 80.
- the void 90 is an unfilled portion of the tobacco rod 60 and is in fluid communication with the tipping 62 through the free flow filter 74.
- the tipping 62 preferably comprises a free-flow filter 92 located adjacent the tobacco rod 60 and a mouthpiece filter plug 94 at the distal end of the tipping 62 from the tobacco rod 60.
- the free-flow filter 92 is tubular and transmits air with very low pressure drop.
- the mouthpiece filter plug 94 closes off the free end of the tipping 62.
- the cigarette 23 optionally includes at least one row of perforations 12 adjacent the free end 15 of the cigarette 23.
- the perforations can be formed as slits 17, which preferably extend through the over wrap 71, the mat 66 and the inner wrap 84.
- At least one additional row of perforations 14 comprising slits 17 can optionally be formed at a location along the tobacco plug 80.
- the perforations 12 or 14 may comprise a single row or a dual row of slits 17.
- the number and extent of the slits 17 can be selected to control the resistance to draw (RTD) along the side walls of the cigarettes 23 and the delivery.
- RTD resistance to draw
- Optional holes 16 provided in the mat 66 are covered by the over wrap 71.
- the perforations 12, 14 can be used to approximate desired delivery levels for the cigarette 23, with the holes 16 being used to adjust delivery with a lesser effect on the RTD.
- the cigarette 23 preferably has a substantially constant diameter along its length.
- the diameter of the cigarette 23, like more traditional cigarettes, is preferably between about 7.5 mm to 8.5 mm so that the electrical smoking system 21 provides a smoker with a familiar "mouth feel" during smoking.
- the tobacco column 82 preferably comprises cut filler of a typical blend of tobaccos, such as blends comprising bright, Burley, and Oriental tobaccos together with, optionally, reconstituted tobaccos and other blend components, including traditional cigarette flavors.
- the free-flow filter 92 and the mouthpiece filter plug 94 are preferably joined together as a combined plug with a plug wrap 101.
- the plug wrap 101 is preferably a porous, low- weight plug wrap. The combined plug is attached to the tobacco rod 60 by the tipping paper 64.
- the electrically heated cigarette 23 can comprise one or more sorbents that remove gas-phase constituents of tobacco smoke.
- the sorbent can comprise one or more porous materials through which tobacco smoke can flow.
- the sorbent is activated carbon.
- the sorbent can comprise activated carbon granules located in a void in the filter, or activated carbon particles loaded on fibrous material or paper.
- the activated carbon can be in various forms including particles, fibers, beads, and the like.
- the activated carbon can have different porosity characteristics, such as a selected pore size and total pore volume.
- the sorbent is one or more suitable molecular sieve sorbent materials.
- Molecular sieve sorbents that may be used in the electrically heated cigarette 23 include, but are not limited to, one or more of the zeolites, mesoporous silicates, alumino phosphates, mesoporous aluminosilicates, and other related porous materials, such as mixed oxide gels, which may optionally further comprise inorganic or organic ions and/or metals. See, for example, commonly-owned International Publication No. WO 01/80973, which is incorporated herein by reference in its entirety.
- the sorbent is one or more zeolites.
- Zeolites include crystalline aluminosilicates having pores, such as channels and/or cavities of uniform, molecular sized dimensions. There are many known unique zeolite structures having different sized and shaped pores, which can significantly affect the properties of these materials with regard to sorption and separation processes. Molecules can be separated by zeolites by size and shape effects related to the possible orientation of the molecules in the pores, and/or by differences in strength of sorption.
- One or more zeolites having pores larger than one or more selected gas phase components of a gas that is desired to be filtered can be used in the electrically heated cigarette 23 , such that only selected molecules that are small enough to pass through the pores of the molecular sieve material are able to enter the cavities and be sorbed on the zeolite.
- the zeolite can be, but is not limited to, one or more of zeolite A; zeolite
- zeolite ZSM-5 and/or zeolite BETA is used.
- ZSM-5 is in the MFI structural classification family and represented by the crystal chemical data [Na n (Al n Si 96 . n O 192 ) ⁇ 16H 2 O, with n ⁇ 27, orthorhombic, Pnma], while zeolite BETA is in the BEA structural classification family and represented by the crystal chemical data [Na 7 (Al 7 Si 57 O 128 ) tetragonal, P4 X 22] .
- the sorbent incorporated in the electrically heated cigarette 23 has a composite composition.
- the sorbent comprises, for example, activated carbon and one or more molecular sieve materials, such as those described above.
- sorbent fibers can be impregnated with at least one sorbent.
- Microporous, mesoporous, and/or macroporous molecular sieves may be used in the electrically heated cigarette 23 , depending on the selected component(s) desired to be removed from mainstream tobacco smoke.
- the sorbent can be incorporated in one or more locations of the electrically heated cigarette 23.
- the sorbent can placed in the passageway of the tubular free-flow filter 74, in the free-flow filter 92, and/or in the void space 90.
- the sorbent can additionally or alternatively be incorporated in the tobacco plug 80.
- FIG. 3 shows another preferred embodiment of an electrically heated cigarette 23 including a filter 150.
- the filter 150 comprises a sorbent in the form of oriented fibers 152 and a sleeve 154, such as paper, surrounding the fibers.
- the sorbent can be, for example, one or more of activated carbon, silica gel, zeolite, and other molecular sieves in fibrous forms.
- the sorbents can be surface modified materials, for example, surface modified silica gel, such as amino propyl silyl (APS) silica gel. Sorbent mixtures can provide different filtration characteristics to achieve a targeted filtered mainstream smoke composition.
- the fibers 152 can comprise one or more sorbent materials, such as carbon, silica, zeolite and the like, impregnated in microcavity fibers, such as TRIADTM micro-cavity fiber, as disclosed in commonly-owned International Publication No. WO 01/80973.
- the fibers are shaped microcavity fibers impregnated with particles of one or more sorbent materials, or alternatively continuous activated carbon fibers.
- the fibers preferably have a diameter of from about 10 microns to about 100 microns.
- the fibers can have a length of from about 10 microns to about 200 microns, for example.
- the fibers are bundles of non- continuous fibers, which are preferably oriented parallel to the direction of mainstream smoke flow through the electrically heated cigarette.
- the filters 150 including fibers 152 can be formed, for example, by stretching a bundle of non-crimped sorbent fiber material, preferably having a controlled total and per filament denier, through a pre-formed or in-situ formed sleeve 154 during the filter making process.
- the formed filter can be sized by cutting to a desired length.
- the filters can have a length of from about 5 mm to about 30 mm.
- the filter 150 including fibers 152 can be incorporated in the electrically heated cigarette at one or more desired locations.
- the filter 150 can be substituted for the entire free-flow filter 92.
- the free-flow filter 150 can be substituted for a portion of the free-flow filter 92.
- the filter 150 can be in contact with (i.e., abut) the free-flow filter 74, positioned between the free-flow filter 74 and the mouthpiece filter plug 94, or in contact with (i.e., abut) the mouthpiece filter plug 94.
- the filter 150 preferably has a diameter substantially equal to that of the outer diameter of the free-flow filter 92 to minimize by-pass of smoke during the filtration process.
- the fibrous sorbents preferably have a high loft with a suitable packing density and fiber length such that parallel pathways are created between fibers.
- Such structure can effectively remove significant amounts of selected gas-phase constituents, such as formaldehyde and/or acrolein, while preferably removing only a minimal amount of particulate matter from the smoke, thereby achieving a significant reduction of the selected gas-phase constituents, while not significantly affecting the total particulate matter (TPM) in the gas.
- a sufficiently low packing density and a sufficiently short fiber length are preferred to achieve such filtration performance.
- the amount of sorbent used in preferred embodiments of the electrically heated cigarette 23 depends on the amount of selected gas-phase constituents in the tobacco smoke and the amount of the constituents that is desired to be removed from the tobacco smoke.
- the electrically heated cigarette 23 also comprises at least one flavoring-release additive.
- the flavoring can be, for example, one or more flavorings including, but not limited to, menthol, mint, such as peppermint and spearmint, chocolate, licorice, citrus and other fruit flavors, gamma octalactone, vanillin, ethyl vanillin, breath freshener flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil, and tobacco flavor.
- the flavoring is menthol and optionally at least one mint flavoring.
- the flavoring-release additive can have different structures and compositions in the electrically heated cigarette.
- the flavoring-release additive is in the form of beads. The beads preferably encapsulate the flavoring and provide for controlled release of the flavoring in the cigarette during puff cycles.
- the beads preferably comprise at least one encapsulating material and at least one flavoring.
- the encapsulating material preferably comprises a binder, which can be, for example, one or more of palm oil, konjac gum, xylitol, zein, hydroxypropylcellulose, sorbitol, maltitol, and hydroxypropylmethy .cellulose.
- a binder which can be, for example, one or more of palm oil, konjac gum, xylitol, zein, hydroxypropylcellulose, sorbitol, maltitol, and hydroxypropylmethy .cellulose.
- Other materials known in the art that can improve the bead-forming characteristics of the encapsulating material or enhance its stability can optionally also be added in the beads.
- the beads have a substantially homogenous composition in which flavoring is substantially uniformly distributed.
- the flavoring can be released from the beads in a more uniform manner during smoking.
- the n inimum temperature at which the beads release the flavoring can be adjusted.
- Beads comprising one or more of the above-described binders preferably have a minimum temperature at which the flavoring is released of at least about 40°C, such as about 40 °C to about 150 °C.
- the beads protect the flavoring from exposure to undesired substances in the atmosphere (e.g., ambient air, inside a package) and undesired substances in the cigarette, and preferably minimize release and/or migration of the flavoring until the flavoring-release additive is heated to a sufficiently high temperature during smoking of the cigarette. Consequently, the flavoring is preferably substantially prevented from migrating in the cigarette, reacting with other substances in the cigarette or with the environment, and deactivating sorbent present in the cigarette.
- the beads can have any desired shape, such as different regular and irregular shapes, including round, square, rectangular, oval, other polygonal shapes, cylindrical, fibrous, and the like.
- the beads can have various sizes.
- the beads are microbeads having a maximum particle size of less than about 25 microns, and more preferably less than about 1 micron. Decreasing the size of the beads can provide a more homogenous and controlled release of flavoring by providing increased surface area of the beads.
- the beads can be manufactured by any suitable process that produces beads having the desired structure, composition, and size.
- the beads can be manufactured by extrusion, spray drying, coating, or other suitable processes.
- the beads are formed by forming a solution, dispersion or emulsion containing a binder, flavoring and optional additives to form beads, which can be isolated and dried.
- the electrically heated cigarette 23 preferably comprises an amount of the beads that provides a desired amount of the flavoring in the cigarette.
- the electrically heated cigarette comprises, based on the total weight of tobacco in the cigarette, up to about 20%, and more preferably about 10% to about 15%, of the beads.
- a cigarette containing 100 mg of tobacco preferably contains up to about 20 mg of beads.
- the beads can preferably comprise up to about 20% of flavoring.
- the cigarette can comprise, for example, from about 1 mg to about 15 mg of flavoring.
- the beads are disposed in at least one location in the electrically heated cigarette 23 that reaches at least the minimum temperature at which the flavoring is released from the beads and into the cigarette during smoking.
- the beads can be disposed in the tobacco rod 60, in the void 90 between the tobacco plug 80 and the free-flow filter 74, on one or more surfaces of the free-flow filter 74, on or in the mat 66, and/or on or in the inner wrap 84 surrounding the tobacco plug 80.
- different bead compositions having two or more different minimum flavoring-release temperatures can be incorporated at two or more locations in an electrically heated cigarette that reaches different temperatures at such locations during smoking.
- beads having a first flavoring release temperature can be located at a first location in the cigarette that reaches the first flavoring-release temperature
- beads having a second flavoring-release temperature higher than the first flavoring-release temperature can be located at a second location in the cigarette that reaches the second flavoring-release temperature.
- the two flavoring release temperatures can vary by up to about 100 °C.
- these two temperatures can vary by up to about 10°C, 20°C, 30°C, 40°C, 50°C, 60°C, 70°C, 80°C, 90°C, or 100°C.
- the flavoring-release additive includes a film.
- the film preferably encapsulates the flavoring and enables the controlled temperature release of the flavoring in the cigarette during smoking.
- the film comprises by weight up to 20% , more preferably about 10% to about 15% , of the flavoring.
- the film encapsulates menthol and optionally also mint.
- the film-type flavoring-release additive preferably comprises at least one encapsulating material and at least one flavoring.
- the encapsulating material preferably comprises a binder, which can be, for example, one or more of carraghenan, gelatin, agar, gellan gum, gum arabic, guar gum, xanthum gum, and pectin.
- a binder which can be, for example, one or more of carraghenan, gelatin, agar, gellan gum, gum arabic, guar gum, xanthum gum, and pectin.
- Other materials known in the art that can improve the film-forming characteristics of the encapsulating material or enhance its stability can optionally be added to the film.
- the film has a substantially homogenous composition in which flavoring is substantially uniformly distributed. By such structure, the flavoring can be released from the film in a more desired manner during smoking.
- the film encapsulating material provides a barrier to the release of the flavoring.
- the minimum temperature at which the film releases the flavoring can be adjusted/selected.
- a film comprising one or more of the above-described binders preferably has a minimum temperature at which the flavoring is released of at least about 50 °C, such as up to about 120°C. The film protects the flavoring from exposure to undesired substances in the cigarette and atmosphere and substantially prevents the flavoring from being released until the film is heated to the flavoring release temperature during smoking of the cigarette.
- the film can be applied to one or more components of the electrically heated cigarette as a liquid coating, which is dried to a film.
- the dimensions of the dried film are not limited.
- the dried film has a maximum thickness of about 50 microns to about 150 microns, and more preferably about 75 microns.
- the film can be manufactured by any suitable process that produces a film having the desired structure, composition, and dimensions.
- the film can be applied by a coating process, such as spray coating, a dipping process, electrostatic deposition, printing wheel application, gravure printing, ink jet application, and the like.
- an emulsion, suspension or slurry comprising the binder, flavoring, and optional additives is prepared and then applied as a coating to one or more selected surfaces of one or more selected components of the electrically heated cigarette.
- the coating is preferably dried to remove water and/or other solvents and form a solid film having desired dimensions. Exemplary processes that can be used to prepare the films are described in U.S. Patents Nos. 3,006,347 and commonly-owned 4,715,390, each of which is incorporated herein by reference in its entirety.
- the electrically heated cigarette 23 preferably comprises an amount of the film that releases a desired amount of the flavoring during smoking of the cigarette.
- the electrically heated cigarette comprises, based on the total weight of tobacco in the cigarette to which the film is applied, up to about 20% , and more preferably about 10% to about 15% , of the film.
- the weight of tobacco contained in the mat preferably is the weight basis for the amount of the film.
- the total weight of tobacco contained in the mat and the tobacco plug preferably is the weight basis for the amount of film applied in the cigarette.
- the weight of tobacco contained in the mat is the weight basis for the amount of film applied to the mat
- the weight of tobacco contained in the tobacco plug is the weight basis for the amount of film applied to the tobacco plug.
- the cigarette can comprise from about 1 mg to about 15 mg of flavoring.
- the film is disposed in at least one location in the electrically heated cigarette 23 that reaches at least the flavoring release temperature.
- the film can be disposed on the tobacco plug 80, on the inner wrap 84 surrounding the tobacco plug 80, on the mat 66, and/or on the over wrap 71 surrounding the mat.
- the weight of the inner wrap 84 and/or over wrap 71 is the weight basis for the amount of the film.
- the film can be preformed, shredded and incorporated in the tobacco plug 80, and/or other selected locations that reach the flavoring release temperature.
- different flavored films having two or more different minimum flavoring-release temperatures can be incorporated at different locations in an electrically heated cigarette, where during smoking of the cigarette, the temperatures at the different locations exceed the minimum release temperatures of the different films.
- the flavoring-release additive is an inclusion complex.
- the inclusion complex comprises a "host molecule,” and the flavoring is the "guest molecule" in the inclusion complex.
- the inclusion complex provides for controlled release of the flavoring in the cigarette during smoking.
- the flavoring is a lipophilic organic flavoring, which preferably concentrates within a hydrophobic cavity of the host molecule.
- Suitable flavorings include, but are not limited to, menthol, mint, such as peppermint and spearmint, chocolate, licorice, citrus and other fruit flavors, gamma octalactone, vanillin, ethyl vanillin, breath freshener flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil,, and tobacco flavor.
- the flavoring includes vanillin and gamma octalactone.
- the inclusion complex comprises by weight up to about 20%, more preferably from about 10% to about 15% , of the flavoring.
- the host molecule of the inclusion complex is preferably a cyclodextrin.
- Cyclodextrins are cyclic oligosaccharides including glucopyranose subunits, as described, for example, in U.S. Patents No. 3,426,011 and commonly-owned U.S. Patent No. 5,144,964, each of which is incorporated herein by reference in its entirety.
- the inclusion complex is formed when a flavoring material is mixed with a selected cyclodextrin in solution. The flavoring resides inside the cyclodextrin ring structure.
- the cyclodextrins and flavoring are typically co-precipitated, filtered, and dried.
- Alpha-cyclodextrin, beta-cyclodextrin and gamma-cyclodextrin include six, seven and eight glucopyranose subunits, respectively.
- the inclusion complex comprises beta-cyclodextrin, which can desirably accommodate a wide variety of guest molecules and is readily available.
- Beta-cyclodextrin has a ring structure of the linked subunits with a three- dimensional torus configuration including a hydrophobic cavity with a 7.5 A diameter and hydrophillic upper and lower edges.
- the minimum temperature at which the inclusion complex comprising a cyclodextrin releases the flavoring is preferably at least about 60 °C, such as from about 60 °C to about 125 °C.
- the flavoring can be protected from exposure to undesired substances in the cigarette and the atmosphere release and/or migration of the flavoring is preferably minimized until the flavoring-release additive is heated to the flavoring release temperature during smoking of the cigarette.
- the inclusion complex is preferably in powder form. The powder preferably has maximum size of less than about 200 microns.
- the inclusion complex can be made by forming an aqueous solution of beta-cyclodextrin and the flavoring.
- the inclusion complex can be recovered from the solution in powder form. However, the solution can be applied directly to one or more selected locations of one or more components of the electrically heated cigarette by any suitable process.
- the inclusion complex powder can alternatively be used to form a solution or a suspension.
- the inclusion complex can be applied by a coating process, such as slurry coating, spraying, a dipping process, electrostatic deposition, printing wheel application, gravure printing, ink jet application, and the like.
- a solution, suspension or slurry comprising the cyclodextrin and flavoring is prepared and applied as a coating to selected surfaces of selected components of the electrically heated cigarette. Exemplary processes that can be used to apply the inclusion complex in the electrically heated cigarette are described in commonly-owned U.S.
- the electrically heated cigarette 23 preferably comprises an amount of the inclusion complex that provides a desired amount of the flavoring in the cigarette.
- the electrically heated cigarette comprises, based on the weight of the over wrap or mat, up to about 15% , and more preferably less than about 8% , of the inclusion complex.
- the weight of the mat preferably is the weight basis for the amount of the inclusion complex applied to the mat.
- the total weight of the mat and the over wrap preferably is the weight basis for the amount of the inclusion complex applied to the mat and the over wrap.
- the weight percent of the inclusion complex that is applied to the mat and/or over wrap can be the same or different.
- the cigarette comprises from about 1 mg to about 50 mg of flavoring.
- the inclusion complex is disposed in at least one location in the electrically heated cigaretto 23 that reaches at least the minimum temperature at which the flavoring is released from the inclusion complex in the cigarette during smoking.
- the inclusion complex can be disposed on the inner wrap 84, mat 66, and/or the over wrap 71.
- the electrically heated cigarette comprises two or more different types of flavoring-release additives, for example, a bead and a film and/or an inclusion complex, with each flavoring-release additive having a different flavoring release temperature.
- FIGS. 4 and 5 illustrate a preferred embodiment of an electrical smoking system in which preferred embodiments of the electrically heated cigarette can be used.
- the electrical smoking system 21 includes an electrically heated cigarette 23 and a reusable lighter 25.
- the cigarette 23 is constructed to be inserted into and removed from a cigarette receiver 27, which is open at a front end portion 29 of the lighter 25.
- each cigarette 23 provides a total of at least eight puffs (puff cycles) per smoke.
- the cigarette 23 can be constructed to provide a lesser or greater total number of available puffs.. . . .
- the lighter 25 includes a housing 31 having front and rear housing portions 33 and 35 ' , respectively.
- a power source 35a such as one or more batteries, is located within the rear housing portion 35 and supplies energy to a heater fixture 39.
- the heater fixture 39 includes a plurality of electrically resistive, heating elements 37 (FIG. 6).
- the heating elements 37 are arranged within the front housing portion 33 to slidingly receive the cigarette 23.
- a stop 183 located in the heater fixture 39 defines a terminal end of the cigarette receiver 27 (FIG. 2).
- Control circuitry 41 in the front housing portion 33 selectively establishes electrical communication between the power source 35a and one or more of the heating elements 37 during each puff cycle.
- the rear housing portion 35 of the housing 31 is constructed to be opened and closed to facilitate replacement of the power source 35a.
- the front housing portion 33 is removably attached to the rear housing portion 35 by mechanical engagement.
- the control circuitry 41 is activated by a puff-actuated sensor 45, which is sensitive to either changes in pressure or changes in the rate of air flow that occur upon initiation of a draw on the cigarette 23 by a smoker.
- the puff-actuated sensor 45 is preferably located within the front housing portion 33 of the lighter 25 and communicates with a space inside the heater fixture 39 via a port 45a extending through a side wall portion 182 of the heater fixture 39. Once actuated by the sensor 45, the control circuitry 41 directs electric current to an appropriate one of the heating elements
- an indicator 51 is provided at a location along the exterior of the lighter 25 to visually indicate the number of puffs remaining in a cigarette 23, or other selected information.
- the indicator 51 preferably includes a liquid crystal display.
- the indicator 51 displays a selected image when a cigarette detector 57 detects the presence of a cigarette in the heater fixture 39.
- the detector 57 can comprise any arrangement that senses the presence of an electrically heated cigarette.
- the detector can comprise an inductive coil 1102 adjacent the cigarette receiver 27 of the heater fixture 39 and electric leads 1104 that communicate the coil 1102 with an oscillator circuit within the control circuitry 41.
- the cigarette 23 can include a metallic element (not shown), which can affect inductance of the coil winding 1102 such that whenever a suitable cigarette 23 is inserted into the receiver 27, the detector 57 generates a signal to the circuitry 41 indicating the cigarette is present.
- the control circuitry 41 provides a signal to the indicator 51.
- the cigarette detector 57 no longer detects the presence of a cigarette 23 and the indicator 51 is turned off.
- the heater fixture 39 supports an inserted cigarette 23 in a fixed relation to the heating elements 37 such that the heating elements 37 are positioned alongside the cigarette 23 at approximately the same location for each newly inserted cigarette 23.
- the heater fixture 39 includes eight mutually parallel heater elements 37, which are disposed concentrically about the axis of symmetry of the cigarette receiver 27. The location where each heating element 37 touches a fully inserted cigarette 23 is referred to herein as the heater footprint or char zone 42.
- the heating elements 37 preferably each include at least first and second serpentine, elongate members 53a and 53b adjoined at a tip 54. The heater portions 53a,. 3b.
- each heating element 37 is electrically connected to the opposite poles of the power source 35a as selectively established by the controller 41.
- An electrical pathway through each heating element 37 is established, respectively, through a . terminal pin 104, a connection 121 between the pin 104 and a free end portion 56a of one of the serpentine members 53a, through at least a portion of the tip 54 to the other serpentine member 53b and its end portion 56b.
- a connection ring 110 provides a common electrical connection to each of the end portions 56b.
- the ring 110 is connected to the positive terminal of the power source 35a through a connection 123 between the ring 110 and a pin 105.
- the heating elements 37 are individually energized by the power source 35a under the control of the control circuitry 41 to heat the cigarette 23 preferably eight times at spaced locations about the periphery of the cigarette
- the heating renders " eight puffs from the cigarette 23, as is commonly achieved with the smoking of a more traditional cigarette. It may be preferred to activate more than one heating element simultaneously for one or more or all of the puffs.
- the heater fixture 39 includes an air inlet port 1200 through which air is drawn into the lighter. A pressure drop is induced upon the air entering the lighter such that the puff sensor 45 is operative to recognize initiation of a puff. The range of pressure drop induced is selected such that it is within the range of pressure drop detectable by the pressure sensor 45.
- the length of the tobacco plug 80 and its relative position along the tobacco rod 60 is preferably selected based on the construction and location of the heating elements 37 of the electrical smoking system.21.
- each heating element contacts the tobacco rod 60.
- This region of contact is referred to as a heater footprint 95, which is that region of the tobacco rod 60 w iere the heating element 37 is expected to reach a . temperature high enough to allow smoking of the cigarette without combustion of the cigarette paper, mat or tobacco.
- the heater foot print 95 can consistently locate along the tobacco rod 60 at the same predetermined distance 96 from the free end 78 of the tobacco rod 60 for every cigarette 23 that is fully inserted into the lighter 25.
- the length of the tobacco plug 80 of the cigarette 23, the length of the heater footprint 95, and the distance between the heater footprint 95 and the stop 182 are selected such that the heater footprint 95 extends beyond the tobacco plug 80 and superposes a portion of the void 91 by a distance 98.
- the distance 98 is also referred to as the "heater- void overlap” 98.
- the distance over which the remainder of the heater footprint 95 superposes the tobacco plug 80 is referred to as the "heater-filler overlap" 99.
- the length of the void 91 , tobacco plug 80, and the distribution of the perforation holes 263 may be adjusted to adjust the smoking characteristics of the cigarette 23, including adjustments in its taste, draw and delivery.
- the pattern of holes 263, the length of the void 90 and the amount of heater-filler overlap 99 (and heater-void overlap 98) may also be manipulated to adjust the immediacy of response, to promote consistency in delivery.
- Electrically heated cigarettes according to preferred embodiments can provide advantages. By encapsulating one or more added flavorings, especially volatile flavoring, the flavoring(s) can be retained in the cigarette until it is smoked.
- the flavoring is preferably temperature released in a controlled manner during smoking, thereby providing the smoker with an enhanced subjective characteristic of the cigarette.
- deactivation of the sorbent in the cigarette is preferably minimized. Consequently, the sorbent maintains it ability to remove selected gas phase constituents from mainstream smoke.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US42249702P | 2002-10-31 | 2002-10-31 | |
US422497P | 2002-10-31 | ||
PCT/US2003/034290 WO2004041007A2 (fr) | 2002-10-31 | 2003-10-30 | Cigarette chauffee electriquement comprenant un arome a liberation controlee |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1555898A2 true EP1555898A2 (fr) | 2005-07-27 |
EP1555898A4 EP1555898A4 (fr) | 2012-08-29 |
EP1555898B1 EP1555898B1 (fr) | 2016-03-16 |
Family
ID=32312516
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03776589.8A Expired - Lifetime EP1555898B1 (fr) | 2002-10-31 | 2003-10-30 | Cigarette chauffee electriquement comprenant un arome a liberation controlee |
Country Status (22)
Country | Link |
---|---|
US (1) | US20040129280A1 (fr) |
EP (1) | EP1555898B1 (fr) |
JP (1) | JP4889218B2 (fr) |
KR (1) | KR101072668B1 (fr) |
CN (1) | CN1317986C (fr) |
AU (1) | AU2003284199B2 (fr) |
BR (1) | BR0315829B1 (fr) |
CA (1) | CA2502171C (fr) |
DK (1) | DK1555898T3 (fr) |
EA (1) | EA006569B1 (fr) |
EG (1) | EG23930A (fr) |
ES (1) | ES2573479T3 (fr) |
HK (1) | HK1076013A1 (fr) |
HU (1) | HUE026909T2 (fr) |
IL (1) | IL168310A (fr) |
MA (1) | MA27484A1 (fr) |
MX (1) | MXPA05004683A (fr) |
NO (1) | NO338062B1 (fr) |
PL (1) | PL203915B1 (fr) |
UA (1) | UA90430C2 (fr) |
WO (1) | WO2004041007A2 (fr) |
ZA (1) | ZA200502781B (fr) |
Families Citing this family (257)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0019417D0 (en) * | 2000-08-09 | 2000-09-27 | Mat & Separations Tech Int Ltd | Mesoporous carbons |
US8591855B2 (en) * | 2000-08-09 | 2013-11-26 | British American Tobacco (Investments) Limited | Porous carbons |
US20050172976A1 (en) * | 2002-10-31 | 2005-08-11 | Newman Deborah J. | Electrically heated cigarette including controlled-release flavoring |
US7827996B2 (en) * | 2003-12-22 | 2010-11-09 | Philip Morris Usa Inc. | Amphiphile-modified sorbents in smoking articles and filters |
US20060090769A1 (en) * | 2004-11-02 | 2006-05-04 | Philip Morris Usa Inc. | Temperature sensitive powder for enhanced flavor delivery in smoking articles |
US8408216B2 (en) * | 2004-12-22 | 2013-04-02 | Philip Morris Usa Inc. | Flavor carrier for use in smoking articles |
US8539957B2 (en) | 2005-01-14 | 2013-09-24 | Philip Morris Usa Inc. | Cigarettes and cigarette filters including activated carbon for removing nitric oxide |
GB0506278D0 (en) | 2005-03-29 | 2005-05-04 | British American Tobacco Co | Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials |
US7878209B2 (en) * | 2005-04-13 | 2011-02-01 | Philip Morris Usa Inc. | Thermally insulative smoking article filter components |
US9675109B2 (en) * | 2005-07-19 | 2017-06-13 | J. T. International Sa | Method and system for vaporization of a substance |
US11647783B2 (en) | 2005-07-19 | 2023-05-16 | Juul Labs, Inc. | Devices for vaporization of a substance |
US20160345631A1 (en) | 2005-07-19 | 2016-12-01 | James Monsees | Portable devices for generating an inhalable vapor |
US8685478B2 (en) * | 2005-11-21 | 2014-04-01 | Philip Morris Usa Inc. | Flavor pouch |
US9491971B2 (en) * | 2005-12-13 | 2016-11-15 | Philip Morris Usa Inc. | Specifically-defined smoking article with activated carbon sorbent and sodium bicarbonate-treated fibers and method of treating mainstream smoke |
US20070267033A1 (en) * | 2006-02-09 | 2007-11-22 | Philip Morris Usa Inc. | Gamma cyclodextrin flavoring-release additives |
US7726320B2 (en) | 2006-10-18 | 2010-06-01 | R. J. Reynolds Tobacco Company | Tobacco-containing smoking article |
GB0700889D0 (en) * | 2007-01-17 | 2007-02-21 | British American Tobacco Co | Tobacco, tobacco derivative and/or tobacco substitute products, preparation and uses thereof |
US20080302376A1 (en) * | 2007-06-08 | 2008-12-11 | Philip Morris Usa Inc. | Smoking article with controlled flavor release |
WO2009010881A2 (fr) * | 2007-07-16 | 2009-01-22 | Philip Morris Products S.A. | Produits en dosettes orales comportant des particules d'agent de flaveur immobilisées |
WO2009010884A2 (fr) | 2007-07-16 | 2009-01-22 | Philip Morris Products S.A. | Produit en sachet pour l'administration orale d'arôme exempt de tabac |
JPWO2010110226A1 (ja) | 2009-03-23 | 2012-09-27 | 日本たばこ産業株式会社 | 非燃焼タイプ香味吸引物品 |
US10420374B2 (en) | 2009-09-18 | 2019-09-24 | Altria Client Services Llc | Electronic smoke apparatus |
US8747562B2 (en) * | 2009-10-09 | 2014-06-10 | Philip Morris Usa Inc. | Tobacco-free pouched product containing flavor beads providing immediate and long lasting flavor release |
GB0918129D0 (en) * | 2009-10-16 | 2009-12-02 | British American Tobacco Co | Control of puff profile |
EP2340730A1 (fr) | 2009-12-30 | 2011-07-06 | Philip Morris Products S.A. | Chauffage formé pour système de génération d'aérosol |
US8757147B2 (en) | 2010-05-15 | 2014-06-24 | Minusa Holdings Llc | Personal vaporizing inhaler with internal light source |
US10136672B2 (en) | 2010-05-15 | 2018-11-27 | Rai Strategic Holdings, Inc. | Solderless directly written heating elements |
US9861772B2 (en) | 2010-05-15 | 2018-01-09 | Rai Strategic Holdings, Inc. | Personal vaporizing inhaler cartridge |
US9999250B2 (en) | 2010-05-15 | 2018-06-19 | Rai Strategic Holdings, Inc. | Vaporizer related systems, methods, and apparatus |
US9095175B2 (en) | 2010-05-15 | 2015-08-04 | R. J. Reynolds Tobacco Company | Data logging personal vaporizing inhaler |
US9259035B2 (en) | 2010-05-15 | 2016-02-16 | R. J. Reynolds Tobacco Company | Solderless personal vaporizing inhaler |
US11344683B2 (en) | 2010-05-15 | 2022-05-31 | Rai Strategic Holdings, Inc. | Vaporizer related systems, methods, and apparatus |
US10159278B2 (en) | 2010-05-15 | 2018-12-25 | Rai Strategic Holdings, Inc. | Assembly directed airflow |
US9743691B2 (en) | 2010-05-15 | 2017-08-29 | Rai Strategic Holdings, Inc. | Vaporizer configuration, control, and reporting |
MY156715A (en) | 2011-03-02 | 2016-03-15 | Japan Tobacco Inc | Method for preparing flavor-containing sheet for smoking article, flavor-containing sheet for smoking article prepared by the method, and smoking article comprising the same |
US9078473B2 (en) | 2011-08-09 | 2015-07-14 | R.J. Reynolds Tobacco Company | Smoking articles and use thereof for yielding inhalation materials |
DE202012013641U1 (de) | 2011-08-16 | 2018-11-16 | Juul Labs Uk Holdco Limited | Elektronische Vorrichtung zur Verdampfung bei niedriger Temperatur |
UA111622C2 (uk) | 2011-09-06 | 2016-05-25 | Брітіш Амерікан Тобакко (Інвестментс) Лімітед | Пристрій для нагрівання та спосіб нагрівання курильного матеріалу |
PL2574247T3 (pl) | 2011-09-28 | 2020-03-31 | Philip Morris Products S.A. | Odparowywacz z przepuszczalną elektryczną termoodporną folią i membrana odparowywacza |
CN110353311A (zh) | 2011-12-30 | 2019-10-22 | 菲利普莫里斯生产公司 | 具有前部塞的发烟制品及方法 |
EP2609820A1 (fr) * | 2011-12-30 | 2013-07-03 | Philip Morris Products S.A. | Détection d'un substrat formant un aérosol dans un dispositif de génération d'aérosol |
MY170381A (en) * | 2011-12-30 | 2019-07-27 | Philip Morris Products Sa | Smoking article with front-plug and aerosol-forming substrate and method |
AR089602A1 (es) | 2011-12-30 | 2014-09-03 | Philip Morris Products Sa | Articulo generador de aerosoles para usar con un dispositivo generador de aerosoles |
PL2797447T3 (pl) * | 2011-12-30 | 2017-11-30 | Philip Morris Products S.A. | Układ wytwarzania aerozolu z monitorowaniem zużycia oraz mechanizm zwrotny |
EP2625975A1 (fr) | 2012-02-13 | 2013-08-14 | Philip Morris Products S.A. | Article de génération d'aérosol avec un élément de refroidissement d'aérosol |
US20130255702A1 (en) | 2012-03-28 | 2013-10-03 | R.J. Reynolds Tobacco Company | Smoking article incorporating a conductive substrate |
GB2502053B (en) | 2012-05-14 | 2014-09-24 | Nicoventures Holdings Ltd | Electronic smoking device |
DK2854570T3 (en) | 2012-05-31 | 2016-10-03 | Philip Morris Products Sa | Strings added aroma for use in aerosol generating articles. |
AR091509A1 (es) | 2012-06-21 | 2015-02-11 | Philip Morris Products Sa | Articulo para fumar para ser usado con un elemento de calentamiento interno |
US10004259B2 (en) | 2012-06-28 | 2018-06-26 | Rai Strategic Holdings, Inc. | Reservoir and heater system for controllable delivery of multiple aerosolizable materials in an electronic smoking article |
GB2504076A (en) | 2012-07-16 | 2014-01-22 | Nicoventures Holdings Ltd | Electronic smoking device |
GB2504075A (en) | 2012-07-16 | 2014-01-22 | Nicoventures Holdings Ltd | Electronic smoking device |
US8881737B2 (en) | 2012-09-04 | 2014-11-11 | R.J. Reynolds Tobacco Company | Electronic smoking article comprising one or more microheaters |
US8910639B2 (en) | 2012-09-05 | 2014-12-16 | R. J. Reynolds Tobacco Company | Single-use connector and cartridge for a smoking article and related method |
US9854841B2 (en) | 2012-10-08 | 2018-01-02 | Rai Strategic Holdings, Inc. | Electronic smoking article and associated method |
US10117460B2 (en) | 2012-10-08 | 2018-11-06 | Rai Strategic Holdings, Inc. | Electronic smoking article and associated method |
US10034988B2 (en) | 2012-11-28 | 2018-07-31 | Fontem Holdings I B.V. | Methods and devices for compound delivery |
US8910640B2 (en) | 2013-01-30 | 2014-12-16 | R.J. Reynolds Tobacco Company | Wick suitable for use in an electronic smoking article |
US10031183B2 (en) | 2013-03-07 | 2018-07-24 | Rai Strategic Holdings, Inc. | Spent cartridge detection method and system for an electronic smoking article |
US20140261486A1 (en) * | 2013-03-12 | 2014-09-18 | R.J. Reynolds Tobacco Company | Electronic smoking article having a vapor-enhancing apparatus and associated method |
US9277770B2 (en) | 2013-03-14 | 2016-03-08 | R. J. Reynolds Tobacco Company | Atomizer for an aerosol delivery device formed from a continuously extending wire and related input, cartridge, and method |
US9918495B2 (en) | 2014-02-28 | 2018-03-20 | Rai Strategic Holdings, Inc. | Atomizer for an aerosol delivery device and related input, aerosol production assembly, cartridge, and method |
US10279934B2 (en) | 2013-03-15 | 2019-05-07 | Juul Labs, Inc. | Fillable vaporizer cartridge and method of filling |
US9609893B2 (en) | 2013-03-15 | 2017-04-04 | Rai Strategic Holdings, Inc. | Cartridge and control body of an aerosol delivery device including anti-rotation mechanism and related method |
US9491974B2 (en) | 2013-03-15 | 2016-11-15 | Rai Strategic Holdings, Inc. | Heating elements formed from a sheet of a material and inputs and methods for the production of atomizers |
AU2014230132B2 (en) * | 2013-03-15 | 2018-03-08 | Philip Morris Products S.A. | Aerosol-generating system with differential heating |
US9220302B2 (en) | 2013-03-15 | 2015-12-29 | R.J. Reynolds Tobacco Company | Cartridge for an aerosol delivery device and method for assembling a cartridge for a smoking article |
US9423152B2 (en) | 2013-03-15 | 2016-08-23 | R. J. Reynolds Tobacco Company | Heating control arrangement for an electronic smoking article and associated system and method |
CN103202536B (zh) * | 2013-04-16 | 2015-10-21 | 湖北中烟工业有限责任公司 | 烟斗式电吸烟系统 |
US11229239B2 (en) | 2013-07-19 | 2022-01-25 | Rai Strategic Holdings, Inc. | Electronic smoking article with haptic feedback |
US10172387B2 (en) | 2013-08-28 | 2019-01-08 | Rai Strategic Holdings, Inc. | Carbon conductive substrate for electronic smoking article |
GB2518598B (en) | 2013-08-30 | 2016-06-01 | Nicoventures Holdings Ltd | Apparatus with battery power control |
WO2015042412A1 (fr) | 2013-09-20 | 2015-03-26 | E-Nicotine Technology. Inc. | Dispositifs et procédés de modification de dispositifs de distribution |
GB201318055D0 (en) | 2013-10-11 | 2013-11-27 | British American Tobacco Co | Additive Releasing Materials |
US10292424B2 (en) | 2013-10-31 | 2019-05-21 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a pressure-based aerosol delivery mechanism |
BE1022113B1 (fr) * | 2013-11-08 | 2016-02-16 | Serenity Sa | Cigarette electronique. |
US9839237B2 (en) | 2013-11-22 | 2017-12-12 | Rai Strategic Holdings, Inc. | Reservoir housing for an electronic smoking article |
EP3082481B1 (fr) | 2013-12-20 | 2024-08-28 | Philip Morris Products S.A. | Système de diffusion d'arômes de zéolite encapsulés de cire pour le tabac |
JP6974940B2 (ja) * | 2013-12-20 | 2021-12-01 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | たばこ用のろう封入された風味送達システム |
US10159282B2 (en) | 2013-12-23 | 2018-12-25 | Juul Labs, Inc. | Cartridge for use with a vaporizer device |
USD842536S1 (en) | 2016-07-28 | 2019-03-05 | Juul Labs, Inc. | Vaporizer cartridge |
USD825102S1 (en) | 2016-07-28 | 2018-08-07 | Juul Labs, Inc. | Vaporizer device with cartridge |
US20160366947A1 (en) | 2013-12-23 | 2016-12-22 | James Monsees | Vaporizer apparatus |
US10058129B2 (en) | 2013-12-23 | 2018-08-28 | Juul Labs, Inc. | Vaporization device systems and methods |
US10076139B2 (en) | 2013-12-23 | 2018-09-18 | Juul Labs, Inc. | Vaporizer apparatus |
PL3498115T3 (pl) | 2013-12-23 | 2021-12-20 | Juul Labs International Inc. | Systemy urządzeń do odparowywania |
RU2670544C2 (ru) * | 2013-12-31 | 2018-10-23 | Филип Моррис Продактс С.А. | Курительное изделие с двойной системой доставки добавок |
US9974334B2 (en) | 2014-01-17 | 2018-05-22 | Rai Strategic Holdings, Inc. | Electronic smoking article with improved storage of aerosol precursor compositions |
CN103750535B (zh) * | 2014-01-22 | 2015-12-02 | 红云红河烟草(集团)有限责任公司 | 一种加热非燃烧型卷烟烟块的制备方法 |
EP3099363A4 (fr) * | 2014-01-31 | 2018-03-28 | Cannakorp, Inc. | Procédés et appareil de production de vapeur à base d'herbes |
US10575558B2 (en) | 2014-02-03 | 2020-03-03 | Rai Strategic Holdings, Inc. | Aerosol delivery device comprising multiple outer bodies and related assembly method |
US9451791B2 (en) | 2014-02-05 | 2016-09-27 | Rai Strategic Holdings, Inc. | Aerosol delivery device with an illuminated outer surface and related method |
US20150224268A1 (en) | 2014-02-07 | 2015-08-13 | R.J. Reynolds Tobacco Company | Charging Accessory Device for an Aerosol Delivery Device and Related System, Method, Apparatus, and Computer Program Product for Providing Interactive Services for Aerosol Delivery Devices |
US9833019B2 (en) | 2014-02-13 | 2017-12-05 | Rai Strategic Holdings, Inc. | Method for assembling a cartridge for a smoking article |
US9839238B2 (en) | 2014-02-28 | 2017-12-12 | Rai Strategic Holdings, Inc. | Control body for an electronic smoking article |
US9597466B2 (en) | 2014-03-12 | 2017-03-21 | R. J. Reynolds Tobacco Company | Aerosol delivery system and related method, apparatus, and computer program product for providing control information to an aerosol delivery device via a cartridge |
US11696604B2 (en) | 2014-03-13 | 2023-07-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device and related method and computer program product for controlling an aerosol delivery device based on input characteristics |
US9877510B2 (en) | 2014-04-04 | 2018-01-30 | Rai Strategic Holdings, Inc. | Sensor for an aerosol delivery device |
US9924741B2 (en) | 2014-05-05 | 2018-03-27 | Rai Strategic Holdings, Inc. | Method of preparing an aerosol delivery device |
US9955726B2 (en) | 2014-05-23 | 2018-05-01 | Rai Strategic Holdings, Inc. | Sealed cartridge for an aerosol delivery device and related assembly method |
US9421793B2 (en) * | 2014-06-26 | 2016-08-23 | Cellresin Technologies, Llc | Electrostatic printing of cyclodextrin compositions |
GB2527597B (en) * | 2014-06-27 | 2016-11-23 | Relco Induction Dev Ltd | Electronic Vapour Inhalers |
US10888119B2 (en) | 2014-07-10 | 2021-01-12 | Rai Strategic Holdings, Inc. | System and related methods, apparatuses, and computer program products for controlling operation of a device based on a read request |
US10058123B2 (en) | 2014-07-11 | 2018-08-28 | R. J. Reynolds Tobacco Company | Heater for an aerosol delivery device and methods of formation thereof |
JP6697437B2 (ja) | 2014-07-11 | 2020-05-20 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | 保護箔を備えるエアロゾル形成カートリッジ |
CN105725261A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 一种葡萄风味的电子烟液及其制备方法 |
CN105725262A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 葡萄风味的电子烟液及其制备方法 |
CN105725263A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 葡萄风味的电子烟液的制备方法 |
JP6218948B2 (ja) * | 2014-08-07 | 2017-10-25 | 日本たばこ産業株式会社 | フィルター付きシガレット |
US9609895B2 (en) | 2014-08-21 | 2017-04-04 | Rai Strategic Holdings, Inc. | System and related methods, apparatuses, and computer program products for testing components of an aerosol delivery device |
US10765144B2 (en) | 2014-08-21 | 2020-09-08 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a moveable cartridge and related assembly method |
US9913493B2 (en) | 2014-08-21 | 2018-03-13 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a moveable cartridge and related assembly method |
US11051554B2 (en) | 2014-11-12 | 2021-07-06 | Rai Strategic Holdings, Inc. | MEMS-based sensor for an aerosol delivery device |
KR102682702B1 (ko) | 2014-12-05 | 2024-07-09 | 쥴 랩스, 인크. | 교정된 투여량 제어 |
US10500600B2 (en) | 2014-12-09 | 2019-12-10 | Rai Strategic Holdings, Inc. | Gesture recognition user interface for an aerosol delivery device |
GB201501429D0 (en) * | 2015-01-28 | 2015-03-11 | British American Tobacco Co | Apparatus for heating aerosol generating material |
US10321711B2 (en) | 2015-01-29 | 2019-06-18 | Rai Strategic Holdings, Inc. | Proximity detection for an aerosol delivery device |
US10694783B2 (en) * | 2015-02-27 | 2020-06-30 | Philip Morris Products S.A. | Feedback controlled RTD adjustment for an aerosol-generating device |
US10027016B2 (en) | 2015-03-04 | 2018-07-17 | Rai Strategic Holdings Inc. | Antenna for an aerosol delivery device |
US9980516B2 (en) | 2015-03-09 | 2018-05-29 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a wave guide and related method |
US10172388B2 (en) | 2015-03-10 | 2019-01-08 | Rai Strategic Holdings, Inc. | Aerosol delivery device with microfluidic delivery component |
GB201505595D0 (en) | 2015-03-31 | 2015-05-13 | British American Tobacco Co | Cartridge for use with apparatus for heating smokeable material |
GB201505597D0 (en) | 2015-03-31 | 2015-05-13 | British American Tobacco Co | Article for use with apparatus for heating smokable material |
US11000069B2 (en) | 2015-05-15 | 2021-05-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device and methods of formation thereof |
US10238145B2 (en) | 2015-05-19 | 2019-03-26 | Rai Strategic Holdings, Inc. | Assembly substation for assembling a cartridge for a smoking article |
GB201511358D0 (en) * | 2015-06-29 | 2015-08-12 | Nicoventures Holdings Ltd | Electronic aerosol provision systems |
CN104983073A (zh) * | 2015-07-07 | 2015-10-21 | 深圳市赛尔美电子科技有限公司 | 一种卷烟蒸馏装置 |
US10966460B2 (en) | 2015-07-17 | 2021-04-06 | Rai Strategic Holdings, Inc. | Load-based detection of an aerosol delivery device in an assembled arrangement |
CN105001988B (zh) * | 2015-07-17 | 2018-07-24 | 云南中烟工业有限责任公司 | 一种三层夹心结构香料缓释滤嘴添加剂的制备装置及其应用方法 |
US11504489B2 (en) | 2015-07-17 | 2022-11-22 | Rai Strategic Holdings, Inc. | Contained liquid system for refilling aerosol delivery devices |
US11134544B2 (en) | 2015-07-24 | 2021-09-28 | Rai Strategic Holdings, Inc. | Aerosol delivery device with radiant heating |
US11033054B2 (en) | 2015-07-24 | 2021-06-15 | Rai Strategic Holdings, Inc. | Radio-frequency identification (RFID) authentication system for aerosol delivery devices |
US10015987B2 (en) | 2015-07-24 | 2018-07-10 | Rai Strategic Holdings Inc. | Trigger-based wireless broadcasting for aerosol delivery devices |
US10206429B2 (en) | 2015-07-24 | 2019-02-19 | Rai Strategic Holdings, Inc. | Aerosol delivery device with radiant heating |
EP3135138B1 (fr) | 2015-08-28 | 2019-10-02 | Fontem Holdings 1 B.V. | Dispositif à fumer électronique |
US20170055583A1 (en) * | 2015-08-31 | 2017-03-02 | British American Tobacco (Investments) Limited | Apparatus for heating smokable material |
US11924930B2 (en) | 2015-08-31 | 2024-03-05 | Nicoventures Trading Limited | Article for use with apparatus for heating smokable material |
US10034494B2 (en) | 2015-09-15 | 2018-07-31 | Rai Strategic Holdings, Inc. | Reservoir for aerosol delivery devices |
EP3349604A1 (fr) * | 2015-09-16 | 2018-07-25 | Alexandra DILLMANN | Procédé et agencement de distribution pour traiter un flux de liquide vaporisé apporté par une cigarette électronique et cigarette électronique pour l'administration par voie orale de liquide vaporisé contenant une composition supplémentaire |
US10058125B2 (en) | 2015-10-13 | 2018-08-28 | Rai Strategic Holdings, Inc. | Method for assembling an aerosol delivery device |
US20170112194A1 (en) | 2015-10-21 | 2017-04-27 | Rai Strategic Holdings, Inc. | Rechargeable lithium-ion capacitor for an aerosol delivery device |
US10918134B2 (en) | 2015-10-21 | 2021-02-16 | Rai Strategic Holdings, Inc. | Power supply for an aerosol delivery device |
US10582726B2 (en) | 2015-10-21 | 2020-03-10 | Rai Strategic Holdings, Inc. | Induction charging for an aerosol delivery device |
US20170119046A1 (en) | 2015-10-30 | 2017-05-04 | British American Tobacco (Investments) Limited | Apparatus for Heating Smokable Material |
US10201187B2 (en) | 2015-11-02 | 2019-02-12 | Rai Strategic Holdings, Inc. | User interface for an aerosol delivery device |
AU2016347736B2 (en) * | 2015-11-05 | 2020-08-27 | Philip Morris Products S.A. | Homogenized tobacco material with improved volatile transfer |
US10820630B2 (en) | 2015-11-06 | 2020-11-03 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a wirelessly-heated atomizer and related method |
ES2923767T3 (es) * | 2015-11-24 | 2022-09-30 | Reynolds Tobacco Co R | Sistema de administración de aerosol eléctricamente accionado |
US9955733B2 (en) | 2015-12-07 | 2018-05-01 | Rai Strategic Holdings, Inc. | Camera for an aerosol delivery device |
US10440992B2 (en) | 2015-12-07 | 2019-10-15 | Rai Strategic Holdings, Inc. | Motion sensing for an aerosol delivery device |
US11291252B2 (en) | 2015-12-18 | 2022-04-05 | Rai Strategic Holdings, Inc. | Proximity sensing for an aerosol delivery device |
US10092036B2 (en) | 2015-12-28 | 2018-10-09 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a housing and a coupler |
US10194694B2 (en) | 2016-01-05 | 2019-02-05 | Rai Strategic Holdings, Inc. | Aerosol delivery device with improved fluid transport |
US10051891B2 (en) | 2016-01-05 | 2018-08-21 | Rai Strategic Holdings, Inc. | Capacitive sensing input device for an aerosol delivery device |
US10258086B2 (en) | 2016-01-12 | 2019-04-16 | Rai Strategic Holdings, Inc. | Hall effect current sensor for an aerosol delivery device |
US10104912B2 (en) | 2016-01-20 | 2018-10-23 | Rai Strategic Holdings, Inc. | Control for an induction-based aerosol delivery device |
US10015989B2 (en) | 2016-01-27 | 2018-07-10 | Rai Strategic Holdings, Inc. | One-way valve for refilling an aerosol delivery device |
WO2017139675A1 (fr) | 2016-02-11 | 2017-08-17 | Pax Labs, Inc. | Cartouches fixées de manière sure pour des dispositifs de vaporisation |
MX2018009702A (es) | 2016-02-11 | 2019-07-08 | Juul Labs Inc | Cartucho rellenable de vaporizador y metodo de relleno. |
US11412781B2 (en) | 2016-02-12 | 2022-08-16 | Rai Strategic Holdings, Inc. | Adapters for refilling an aerosol delivery device |
US9936733B2 (en) | 2016-03-09 | 2018-04-10 | Rai Strategic Holdings, Inc. | Accessory configured to charge an aerosol delivery device and related method |
US10405582B2 (en) | 2016-03-10 | 2019-09-10 | Pax Labs, Inc. | Vaporization device with lip sensing |
US10334880B2 (en) | 2016-03-25 | 2019-07-02 | Rai Strategic Holdings, Inc. | Aerosol delivery device including connector comprising extension and receptacle |
US11207478B2 (en) | 2016-03-25 | 2021-12-28 | Rai Strategic Holdings, Inc. | Aerosol production assembly including surface with micro-pattern |
US20170280769A1 (en) * | 2016-04-04 | 2017-10-05 | Altria Client Services Llc | Electronic vaping device and kit |
US10945462B2 (en) | 2016-04-12 | 2021-03-16 | Rai Strategic Holdings, Inc. | Detachable power source for an aerosol delivery device |
US10333339B2 (en) | 2016-04-12 | 2019-06-25 | Rai Strategic Holdings, Inc. | Charger for an aerosol delivery device |
US10028534B2 (en) | 2016-04-20 | 2018-07-24 | Rai Strategic Holdings, Inc. | Aerosol delivery device, and associated apparatus and method of formation thereof |
US10405579B2 (en) | 2016-04-29 | 2019-09-10 | Rai Strategic Holdings, Inc. | Methods for assembling a cartridge for an aerosol delivery device, and associated systems and apparatuses |
GB201608947D0 (en) * | 2016-05-20 | 2016-07-06 | British American Tobacco Co | Consumable for aerosol generating device |
USD849996S1 (en) | 2016-06-16 | 2019-05-28 | Pax Labs, Inc. | Vaporizer cartridge |
US10959458B2 (en) | 2016-06-20 | 2021-03-30 | Rai Strategic Holdings, Inc. | Aerosol delivery device including an electrical generator assembly |
USD851830S1 (en) | 2016-06-23 | 2019-06-18 | Pax Labs, Inc. | Combined vaporizer tamp and pick tool |
USD836541S1 (en) | 2016-06-23 | 2018-12-25 | Pax Labs, Inc. | Charging device |
CN105876855A (zh) * | 2016-07-06 | 2016-08-24 | 南通烟滤嘴有限责任公司 | 含可自溶胶囊的滤棒及其滤嘴 |
US10085485B2 (en) | 2016-07-06 | 2018-10-02 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a reservoir housing and a vaporizer assembly |
US10463078B2 (en) | 2016-07-08 | 2019-11-05 | Rai Strategic Holdings, Inc. | Aerosol delivery device with condensing and non-condensing vaporization |
US10405581B2 (en) | 2016-07-08 | 2019-09-10 | Rai Strategic Holdings, Inc. | Gas sensing for an aerosol delivery device |
US10231485B2 (en) | 2016-07-08 | 2019-03-19 | Rai Strategic Holdings, Inc. | Radio frequency to direct current converter for an aerosol delivery device |
US10617151B2 (en) | 2016-07-21 | 2020-04-14 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a liquid transport element comprising a porous monolith and related method |
US10602775B2 (en) | 2016-07-21 | 2020-03-31 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a unitary reservoir and liquid transport element comprising a porous monolith and related method |
US11019847B2 (en) | 2016-07-28 | 2021-06-01 | Rai Strategic Holdings, Inc. | Aerosol delivery devices including a selector and related methods |
US10765146B2 (en) | 2016-08-08 | 2020-09-08 | Rai Strategic Holdings, Inc. | Boost converter for an aerosol delivery device |
US11937647B2 (en) | 2016-09-09 | 2024-03-26 | Rai Strategic Holdings, Inc. | Fluidic control for an aerosol delivery device |
US10080387B2 (en) | 2016-09-23 | 2018-09-25 | Rai Strategic Holdings, Inc. | Aerosol delivery device with replaceable wick and heater assembly |
US10477896B2 (en) | 2016-10-12 | 2019-11-19 | Rai Strategic Holdings, Inc. | Photodetector for measuring aerosol precursor composition in an aerosol delivery device |
US10524508B2 (en) | 2016-11-15 | 2020-01-07 | Rai Strategic Holdings, Inc. | Induction-based aerosol delivery device |
US9864947B1 (en) | 2016-11-15 | 2018-01-09 | Rai Strategic Holdings, Inc. | Near field communication for a tobacco-based article or package therefor |
US10492530B2 (en) | 2016-11-15 | 2019-12-03 | Rai Strategic Holdings, Inc. | Two-wire authentication system for an aerosol delivery device |
US11103012B2 (en) | 2016-11-17 | 2021-08-31 | Rai Strategic Holdings, Inc. | Satellite navigation for an aerosol delivery device |
US10524509B2 (en) | 2016-11-18 | 2020-01-07 | Rai Strategic Holdings, Inc. | Pressure sensing for an aerosol delivery device |
US10653183B2 (en) | 2016-11-18 | 2020-05-19 | Rai Strategic Holdings, Inc. | Power source for an aerosol delivery device |
US10206431B2 (en) | 2016-11-18 | 2019-02-19 | Rai Strategic Holdings, Inc. | Charger for an aerosol delivery device |
US10172392B2 (en) | 2016-11-18 | 2019-01-08 | Rai Strategic Holdings, Inc. | Humidity sensing for an aerosol delivery device |
US10537137B2 (en) | 2016-11-22 | 2020-01-21 | Rai Strategic Holdings, Inc. | Rechargeable lithium-ion battery for an aerosol delivery device |
US11013266B2 (en) | 2016-12-09 | 2021-05-25 | Rai Strategic Holdings, Inc. | Aerosol delivery device sensory system including an infrared sensor and related method |
WO2018112768A1 (fr) * | 2016-12-20 | 2018-06-28 | 惠州市吉瑞科技有限公司深圳分公司 | Élément de gaine de vaporisateur |
US9980522B1 (en) * | 2016-12-30 | 2018-05-29 | National Concessions Group Inc. | Self-locking cartridge |
GB201700136D0 (en) | 2017-01-05 | 2017-02-22 | British American Tobacco Investments Ltd | Aerosol generating device and article |
GB201700620D0 (en) | 2017-01-13 | 2017-03-01 | British American Tobacco Investments Ltd | Aerosol generating device and article |
GB201700812D0 (en) | 2017-01-17 | 2017-03-01 | British American Tobacco Investments Ltd | Apparatus for heating smokable material |
US10517326B2 (en) | 2017-01-27 | 2019-12-31 | Rai Strategic Holdings, Inc. | Secondary battery for an aerosol delivery device |
US10827783B2 (en) | 2017-02-27 | 2020-11-10 | Rai Strategic Holdings, Inc. | Digital compass for an aerosol delivery device |
US10314340B2 (en) | 2017-04-21 | 2019-06-11 | Rai Strategic Holdings, Inc. | Refillable aerosol delivery device and related method |
US11297876B2 (en) | 2017-05-17 | 2022-04-12 | Rai Strategic Holdings, Inc. | Aerosol delivery device |
US10517330B2 (en) | 2017-05-23 | 2019-12-31 | RAI Stategic Holdings, Inc. | Heart rate monitor for an aerosol delivery device |
US11589621B2 (en) | 2017-05-23 | 2023-02-28 | Rai Strategic Holdings, Inc. | Heart rate monitor for an aerosol delivery device |
CN107057854A (zh) * | 2017-05-24 | 2017-08-18 | 昆明理工大学 | 一种烟用香精香料的微囊制备及在卷烟嘴棒中的应用 |
US10499686B2 (en) | 2017-06-23 | 2019-12-10 | Altria Client Services Llc | Smoking article filter with flavorant delivery system |
US10842197B2 (en) | 2017-07-12 | 2020-11-24 | Rai Strategic Holdings, Inc. | Detachable container for aerosol delivery having pierceable membrane |
US10349674B2 (en) | 2017-07-17 | 2019-07-16 | Rai Strategic Holdings, Inc. | No-heat, no-burn smoking article |
US11337456B2 (en) | 2017-07-17 | 2022-05-24 | Rai Strategic Holdings, Inc. | Video analytics camera system for an aerosol delivery device |
CN107252672B (zh) * | 2017-07-21 | 2021-02-02 | 云南中烟工业有限责任公司 | 一种改性磷铝分子筛滤嘴吸附材料及其制备方法与应用 |
USD887632S1 (en) | 2017-09-14 | 2020-06-16 | Pax Labs, Inc. | Vaporizer cartridge |
US11039645B2 (en) | 2017-09-19 | 2021-06-22 | Rai Strategic Holdings, Inc. | Differential pressure sensor for an aerosol delivery device |
US10505383B2 (en) | 2017-09-19 | 2019-12-10 | Rai Strategic Holdings, Inc. | Intelligent charger for an aerosol delivery device |
US10660370B2 (en) | 2017-10-12 | 2020-05-26 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a control body, an atomizer body, and a cartridge and related methods |
US10517332B2 (en) | 2017-10-31 | 2019-12-31 | Rai Strategic Holdings, Inc. | Induction heated aerosol delivery device |
GB201720338D0 (en) | 2017-12-06 | 2018-01-17 | British American Tobacco Investments Ltd | Component for an aerosol-generating apparatus |
US10806181B2 (en) | 2017-12-08 | 2020-10-20 | Rai Strategic Holdings, Inc. | Quasi-resonant flyback converter for an induction-based aerosol delivery device |
GB201721821D0 (en) | 2017-12-22 | 2018-02-07 | Nicoventures Holdings Ltd | Electronic aerosol provision system |
US20210100279A1 (en) * | 2017-12-22 | 2021-04-08 | G.D S.P.A. | Sub-unit of a smoking article and method for making it |
US10555558B2 (en) | 2017-12-29 | 2020-02-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device providing flavor control |
CN109998171A (zh) * | 2018-01-05 | 2019-07-12 | 深圳御烟实业有限公司 | 一种气溶胶生成制品及系统 |
US11019850B2 (en) | 2018-02-26 | 2021-06-01 | Rai Strategic Holdings, Inc. | Heat conducting substrate for electrically heated aerosol delivery device |
JP6890864B2 (ja) * | 2018-05-17 | 2021-06-18 | 株式会社東亜産業 | 芳香カートリッジ |
GB201808526D0 (en) * | 2018-05-24 | 2018-07-11 | Nicoventures Trading Ltd | Aerosol Generation |
GB201812497D0 (en) | 2018-07-31 | 2018-09-12 | Nicoventures Holdings Ltd | Aerosol generation |
GB201812506D0 (en) * | 2018-07-31 | 2018-09-12 | Nicoventures Holdings Ltd | Aerosol generation |
CN108968154A (zh) * | 2018-08-01 | 2018-12-11 | 声海电子(深圳)有限公司 | 一种香烟用具及其工作方法 |
CN108813713B (zh) * | 2018-08-07 | 2024-05-03 | 四川三联新材料有限公司 | 一种加热式发烟烟支及加热式发烟制品 |
US11432581B2 (en) | 2018-09-07 | 2022-09-06 | Altria Client Services Llc | Capsule containing a matrix, device with the matrix, and method of forming the matrix |
US11395507B2 (en) | 2018-09-07 | 2022-07-26 | Altria Client Services Llc | Filter for an e-vaping device, e-vaping device with the filter, and method of forming the filter |
WO2020079845A1 (fr) * | 2018-10-19 | 2020-04-23 | 株式会社 東亜産業 | Composition de générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée, générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée utilisant la composition, cartouche d'aspiration de substance volatile chauffée utilisant le générateur de parfum chauffé, et procédé de production d'un générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée |
WO2020089120A1 (fr) * | 2018-10-29 | 2020-05-07 | Nerudia Limited | Consommable de substitution à l'acte de fumer |
GB201817860D0 (en) * | 2018-11-01 | 2018-12-19 | Nicoventures Trading Ltd | Aerosolised formulation |
US20200221785A1 (en) * | 2019-01-10 | 2020-07-16 | Altria Client Services Llc | Vaping device with insert |
CN109588787A (zh) * | 2019-01-22 | 2019-04-09 | 云南中烟工业有限责任公司 | 一种细支电子烟及其制备方法 |
CN113347895A (zh) | 2019-01-25 | 2021-09-03 | 日本烟草产业株式会社 | 吸烟物品用滤嘴 |
CN113329645A (zh) | 2019-01-25 | 2021-08-31 | 日本烟草产业株式会社 | 吸烟物品用滤嘴 |
CN110771945A (zh) * | 2019-04-01 | 2020-02-11 | 株式会社东亚产业 | 受热芳香发生体组成物、使用组成物的受热芳香发生体及使用受热芳香发生体的熏香芯 |
KR20210149101A (ko) * | 2019-04-08 | 2021-12-08 | 필립모리스 프로덕츠 에스.에이. | 에어로졸 발생 필름 |
JP2020065534A (ja) | 2019-05-08 | 2020-04-30 | 株式会社 東亜産業 | 加熱式揮発物吸引カートリッジ用被加熱芳香発生体組成物、その組成物を用いた加熱式揮発物吸引カートリッジ用被加熱芳香発生体、その被加熱芳香発生体を用いた加熱式揮発物吸引カートリッジ、及び、その加熱式揮発物吸引カートリッジ用被加熱芳香発生体の製造方法 |
JP2020167989A (ja) * | 2019-05-22 | 2020-10-15 | 株式会社 東亜産業 | スティック型被加熱芳香発生体組成物、その組成物を用いたスティック型被加熱芳香発生体、及び、そのスティック型被加熱芳香発生体を用いた喫煙カートリッジ |
KR102228286B1 (ko) * | 2019-12-09 | 2021-03-17 | 가부시키가이샤 도아 산교 | 방향(芳香) 카트리지 |
WO2021117264A1 (fr) * | 2019-12-09 | 2021-06-17 | 株式会社東亜産業 | Cartouche de parfum |
GB201918980D0 (en) * | 2019-12-20 | 2020-02-05 | Nicoventures Trading Ltd | Article for use in an aerosol provision system |
GB201919104D0 (en) * | 2019-12-20 | 2020-02-05 | Nicoventures Trading Ltd | An article for use in a non-combustible aerosol provision system |
US11712059B2 (en) | 2020-02-24 | 2023-08-01 | Nicoventures Trading Limited | Beaded tobacco material and related method of manufacture |
EP4115747A4 (fr) * | 2020-03-04 | 2024-01-17 | Japan Tobacco Inc. | Élément constitutif porteur de parfum de produit de tabac, produit de tabac et son procédé de production |
US12016369B2 (en) | 2020-04-14 | 2024-06-25 | Nicoventures Trading Limited | Regenerated cellulose substrate for aerosol delivery device |
CN112438420B (zh) * | 2020-12-03 | 2022-08-30 | 山东瑞博斯烟草有限公司 | 一种降低造纸法烟草薄片刺激性的方法 |
US11789476B2 (en) | 2021-01-18 | 2023-10-17 | Altria Client Services Llc | Heat-not-burn (HNB) aerosol-generating devices including intra-draw heater control, and methods of controlling a heater |
JP7084060B2 (ja) * | 2021-03-10 | 2022-06-14 | Future Technology株式会社 | 芳香カートリッジ |
CN113058557B (zh) * | 2021-03-15 | 2024-09-24 | 云南中烟工业有限责任公司 | 一种N掺杂MOF(Fe)吸附剂及其制备方法与应用 |
WO2023041438A1 (fr) * | 2021-09-20 | 2023-03-23 | Nerudia Limited | Élément de distribution d'arôme et dispositif de substitution d'article à fumer |
JPWO2023112152A1 (fr) * | 2021-12-14 | 2023-06-22 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5845649A (en) * | 1994-01-26 | 1998-12-08 | Japan Tobacco Inc. | Flavor-tasting article |
US6125853A (en) * | 1996-06-17 | 2000-10-03 | Japan Tobacco, Inc. | Flavor generation device |
Family Cites Families (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3006347A (en) | 1959-09-21 | 1961-10-31 | Reynolds Tobacco Co R | Additives for smoking tobacco products |
NL282359A (fr) | 1961-09-19 | |||
US3344796A (en) * | 1965-05-17 | 1967-10-03 | Dai Nippon Seito Kabushiki Kai | Flavored tobacco smoke filter containing higher fatty acid ester of sucrose |
US3426011A (en) * | 1967-02-13 | 1969-02-04 | Corn Products Co | Cyclodextrins with anionic properties |
US3623489A (en) * | 1969-11-18 | 1971-11-30 | Int Flavors & Fragrances Inc | Tobacco smoking article |
BE791758A (fr) * | 1971-11-24 | 1973-05-22 | Olin Corp | Enveloppe chargee de carbone pour article a fumer et article a fumer presentant une telle enveloppe |
US3972335A (en) * | 1972-09-20 | 1976-08-03 | Calgon Corporation | Mentholated cigarette filter |
US4068671A (en) * | 1975-07-25 | 1978-01-17 | Amf Incorporated | Nicotine removal process |
US4195645A (en) * | 1978-03-13 | 1980-04-01 | Celanese Corporation | Tobacco-substitute smoking material |
US4715390A (en) | 1985-11-19 | 1987-12-29 | Philip Morris Incorporated | Matrix entrapment of flavorings for smoking articles |
US4893639A (en) * | 1986-07-22 | 1990-01-16 | R. J. Reynolds Tobacco Company | Densified particulate materials for smoking products and process for preparing the same |
US5137034A (en) | 1988-05-16 | 1992-08-11 | R. J. Reynolds Tobacco Company | Smoking article with improved means for delivering flavorants |
US4991605A (en) * | 1989-04-24 | 1991-02-12 | Philip Morris Incorporated | Container for additive materials for smoking articles |
US5388594A (en) | 1991-03-11 | 1995-02-14 | Philip Morris Incorporated | Electrical smoking system for delivering flavors and method for making same |
US5144964A (en) * | 1991-03-14 | 1992-09-08 | Philip Morris Incorporated | Smoking compositions containing a flavorant-release additive |
US5144946A (en) * | 1991-08-05 | 1992-09-08 | Siemens Pacesetter, Inc. | Combined pacemaker substrate and electrical interconnect and method of assembly |
US5692526A (en) * | 1992-09-11 | 1997-12-02 | Philip Morris Incorporated | Cigarette for electrical smoking system |
US5692525A (en) * | 1992-09-11 | 1997-12-02 | Philip Morris Incorporated | Cigarette for electrical smoking system |
US5666976A (en) | 1992-09-11 | 1997-09-16 | Philip Morris Incorporated | Cigarette and method of manufacturing cigarette for electrical smoking system |
US5499636A (en) | 1992-09-11 | 1996-03-19 | Philip Morris Incorporated | Cigarette for electrical smoking system |
JPH08322538A (ja) * | 1995-05-30 | 1996-12-10 | Japan Tobacco Inc | シガレット用フィルタ |
DE69717810T2 (de) * | 1996-04-26 | 2003-09-18 | Shionogi & Co., Ltd. | S1452-tabletten mit schneller freisetzung |
ID21348A (id) * | 1996-10-09 | 1999-05-27 | Givaudan Roure Int | Proses untuk pembuatan butiran-butiran sebagai aditif makanan atau tembakau |
US6040560A (en) * | 1996-10-22 | 2000-03-21 | Philip Morris Incorporated | Power controller and method of operating an electrical smoking system |
JPH11178562A (ja) * | 1997-12-19 | 1999-07-06 | Japan Tobacco Inc | 非燃焼型香味発生品 |
JP2949114B1 (ja) * | 1998-08-04 | 1999-09-13 | 日本たばこ産業株式会社 | 電気式香味生成物品加熱制御装置 |
MY138902A (en) | 2000-04-20 | 2009-08-28 | Philip Morris Prod | "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials" |
ES2345976T5 (es) * | 2001-02-22 | 2015-08-28 | Philip Morris Products S.A. | Cigarrillo y filtro con adición de sabor aguas abajo |
JP2005508648A (ja) * | 2001-11-09 | 2005-04-07 | ベクター・タバコ・インコーポレーテッド | 炭でフィルターされた巻きタバコのメントール化のための組成物及び方法 |
MY135471A (en) * | 2002-01-09 | 2008-04-30 | Philip Morris Prod | Cigarette filter with beaded carbon |
-
2003
- 2003-10-30 AU AU2003284199A patent/AU2003284199B2/en not_active Ceased
- 2003-10-30 ES ES03776589.8T patent/ES2573479T3/es not_active Expired - Lifetime
- 2003-10-30 JP JP2004550175A patent/JP4889218B2/ja not_active Expired - Lifetime
- 2003-10-30 PL PL374939A patent/PL203915B1/pl unknown
- 2003-10-30 EP EP03776589.8A patent/EP1555898B1/fr not_active Expired - Lifetime
- 2003-10-30 HU HUE03776589A patent/HUE026909T2/en unknown
- 2003-10-30 MX MXPA05004683A patent/MXPA05004683A/es active IP Right Grant
- 2003-10-30 DK DK03776589.8T patent/DK1555898T3/en active
- 2003-10-30 CN CNB2003801024395A patent/CN1317986C/zh not_active Expired - Lifetime
- 2003-10-30 UA UAA200504030A patent/UA90430C2/uk unknown
- 2003-10-30 EA EA200500746A patent/EA006569B1/ru not_active IP Right Cessation
- 2003-10-30 CA CA2502171A patent/CA2502171C/fr not_active Expired - Fee Related
- 2003-10-30 BR BRPI0315829-2B1A patent/BR0315829B1/pt active IP Right Grant
- 2003-10-30 WO PCT/US2003/034290 patent/WO2004041007A2/fr active Application Filing
- 2003-10-30 US US10/695,760 patent/US20040129280A1/en not_active Abandoned
- 2003-10-30 KR KR1020057007597A patent/KR101072668B1/ko active IP Right Grant
-
2005
- 2005-04-06 ZA ZA200502781A patent/ZA200502781B/en unknown
- 2005-04-29 MA MA28248A patent/MA27484A1/fr unknown
- 2005-05-01 IL IL168310A patent/IL168310A/en active IP Right Grant
- 2005-05-30 NO NO20052600A patent/NO338062B1/no not_active IP Right Cessation
- 2005-07-26 EG EGNA2005000167 patent/EG23930A/xx active
- 2005-09-15 HK HK05108074.7A patent/HK1076013A1/zh not_active IP Right Cessation
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5845649A (en) * | 1994-01-26 | 1998-12-08 | Japan Tobacco Inc. | Flavor-tasting article |
US6125853A (en) * | 1996-06-17 | 2000-10-03 | Japan Tobacco, Inc. | Flavor generation device |
Non-Patent Citations (1)
Title |
---|
See also references of WO2004041007A2 * |
Also Published As
Publication number | Publication date |
---|---|
NO20052600L (no) | 2005-05-30 |
CN1317986C (zh) | 2007-05-30 |
DK1555898T3 (en) | 2016-05-09 |
ES2573479T3 (es) | 2016-06-08 |
HUE026909T2 (en) | 2016-07-28 |
WO2004041007A2 (fr) | 2004-05-21 |
CA2502171C (fr) | 2013-01-15 |
AU2003284199B2 (en) | 2009-12-17 |
BR0315829B1 (pt) | 2014-07-15 |
JP4889218B2 (ja) | 2012-03-07 |
EG23930A (en) | 2008-01-14 |
PL203915B1 (pl) | 2009-11-30 |
KR20050072127A (ko) | 2005-07-08 |
PL374939A1 (en) | 2005-11-14 |
EP1555898B1 (fr) | 2016-03-16 |
BR0315829A (pt) | 2005-09-13 |
UA90430C2 (uk) | 2010-04-26 |
MXPA05004683A (es) | 2005-08-18 |
HK1076013A1 (zh) | 2006-01-06 |
AU2003284199A1 (en) | 2004-06-07 |
NO20052600D0 (no) | 2005-05-30 |
NO338062B1 (no) | 2016-07-25 |
IL168310A (en) | 2013-09-30 |
KR101072668B1 (ko) | 2011-10-11 |
CN1708241A (zh) | 2005-12-14 |
WO2004041007A3 (fr) | 2004-07-08 |
EA200500746A1 (ru) | 2005-08-25 |
JP2006504431A (ja) | 2006-02-09 |
CA2502171A1 (fr) | 2004-05-21 |
MA27484A1 (fr) | 2005-08-01 |
US20040129280A1 (en) | 2004-07-08 |
ZA200502781B (en) | 2008-01-30 |
EP1555898A4 (fr) | 2012-08-29 |
EA006569B1 (ru) | 2006-02-24 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US11690395B2 (en) | Gamma cyclodextrin flavoring-release additives | |
CA2502171C (fr) | Cigarette chauffee electriquement comprenant un arome a liberation controlee | |
CA2584982C (fr) | Cigarette chauffee electriquement contenant un arome a liberation controlee | |
MX2008010207A (en) | Gamma cyclodextrin flavoring-release additives |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 20050516 |
|
AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK |
|
REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1076013 Country of ref document: HK |
|
RAX | Requested extension states of the european patent have changed |
Extension state: LV Payment date: 20050516 Extension state: LT Payment date: 20050516 |
|
A4 | Supplementary search report drawn up and despatched |
Effective date: 20120801 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: A24B 15/00 20060101AFI20120726BHEP Ipc: A24F 47/00 20060101ALI20120726BHEP |
|
17Q | First examination report despatched |
Effective date: 20130410 |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
RIC1 | Information provided on ipc code assigned before grant |
Ipc: A24B 15/00 20060101AFI20150817BHEP Ipc: A24B 15/28 20060101ALI20150817BHEP Ipc: A24F 47/00 20060101ALI20150817BHEP |
|
INTG | Intention to grant announced |
Effective date: 20150917 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
|
AX | Request for extension of the european patent |
Extension state: LT LV |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: RO Ref legal event code: EPE |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: REF Ref document number: 780376 Country of ref document: AT Kind code of ref document: T Effective date: 20160415 Ref country code: CH Ref legal event code: NV Representative=s name: BOHEST AG, CH |
|
REG | Reference to a national code |
Ref country code: PT Ref legal event code: SC4A Free format text: AVAILABILITY OF NATIONAL TRANSLATION Effective date: 20160413 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R096 Ref document number: 60348677 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: T3 Effective date: 20160503 |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: TRGR |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: FP |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2573479 Country of ref document: ES Kind code of ref document: T3 Effective date: 20160608 |
|
REG | Reference to a national code |
Ref country code: HU Ref legal event code: AG4A Ref document number: E026909 Country of ref document: HU |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: FG4A Ref document number: E011999 Country of ref document: EE Effective date: 20160615 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: T3 Ref document number: E 20982 Country of ref document: SK |
|
REG | Reference to a national code |
Ref country code: GR Ref legal event code: EP Ref document number: 20160401001 Country of ref document: GR Effective date: 20160628 |
|
REG | Reference to a national code |
Ref country code: HK Ref legal event code: GR Ref document number: 1076013 Country of ref document: HK |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 14 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R097 Ref document number: 60348677 Country of ref document: DE |
|
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20161219 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160316 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 15 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160316 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20160316 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: PLFP Year of fee payment: 16 |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: UEP Ref document number: 780376 Country of ref document: AT Kind code of ref document: T Effective date: 20160316 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CZ Payment date: 20190925 Year of fee payment: 17 Ref country code: PT Payment date: 20190919 Year of fee payment: 17 Ref country code: SK Payment date: 20190924 Year of fee payment: 17 Ref country code: RO Payment date: 20190923 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: LU Payment date: 20191021 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IE Payment date: 20191022 Year of fee payment: 17 Ref country code: HU Payment date: 20191016 Year of fee payment: 17 Ref country code: SE Payment date: 20191021 Year of fee payment: 17 Ref country code: BG Payment date: 20191023 Year of fee payment: 17 Ref country code: FI Payment date: 20191022 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: EE Payment date: 20191018 Year of fee payment: 17 Ref country code: BE Payment date: 20191021 Year of fee payment: 17 Ref country code: DK Payment date: 20191023 Year of fee payment: 17 Ref country code: GR Payment date: 20191022 Year of fee payment: 17 Ref country code: ES Payment date: 20191122 Year of fee payment: 17 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: TR Payment date: 20191021 Year of fee payment: 17 Ref country code: AT Payment date: 20191022 Year of fee payment: 17 |
|
REG | Reference to a national code |
Ref country code: EE Ref legal event code: MM4A Ref document number: E011999 Country of ref document: EE Effective date: 20201031 |
|
REG | Reference to a national code |
Ref country code: DK Ref legal event code: EBP Effective date: 20201031 |
|
REG | Reference to a national code |
Ref country code: FI Ref legal event code: MAE |
|
REG | Reference to a national code |
Ref country code: SE Ref legal event code: EUG |
|
REG | Reference to a national code |
Ref country code: AT Ref legal event code: MM01 Ref document number: 780376 Country of ref document: AT Kind code of ref document: T Effective date: 20201030 |
|
REG | Reference to a national code |
Ref country code: SK Ref legal event code: MM4A Ref document number: E 20982 Country of ref document: SK Effective date: 20201030 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 |
|
REG | Reference to a national code |
Ref country code: BE Ref legal event code: MM Effective date: 20201031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: RO Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210430 Ref country code: SK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 Ref country code: EE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 Ref country code: CZ Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 Ref country code: BG Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210430 Ref country code: FI Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 Ref country code: GR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20210510 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 Ref country code: AT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 Ref country code: SE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 Ref country code: HU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DK Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20220128 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20201030 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: NL Payment date: 20221019 Year of fee payment: 20 Ref country code: FR Payment date: 20221028 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: IT Payment date: 20221021 Year of fee payment: 20 Ref country code: GB Payment date: 20221019 Year of fee payment: 20 Ref country code: DE Payment date: 20221019 Year of fee payment: 20 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: CH Payment date: 20221026 Year of fee payment: 20 |
|
P01 | Opt-out of the competence of the unified patent court (upc) registered |
Effective date: 20230529 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R071 Ref document number: 60348677 Country of ref document: DE |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
REG | Reference to a national code |
Ref country code: NL Ref legal event code: MK Effective date: 20231029 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: PE20 Expiry date: 20231029 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20231029 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION Effective date: 20231029 |