EP1555898B1 - Cigarette chauffee electriquement comprenant un arome a liberation controlee - Google Patents
Cigarette chauffee electriquement comprenant un arome a liberation controlee Download PDFInfo
- Publication number
- EP1555898B1 EP1555898B1 EP03776589.8A EP03776589A EP1555898B1 EP 1555898 B1 EP1555898 B1 EP 1555898B1 EP 03776589 A EP03776589 A EP 03776589A EP 1555898 B1 EP1555898 B1 EP 1555898B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- flavoring
- electrically heated
- cigarette
- heated cigarette
- release additive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
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Images
Classifications
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/283—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances
- A24B15/284—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by encapsulation of the chemical substances the additive being bound to a host by chemical, electrical or like forces, e.g. use of precursors, inclusion complexes
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24C—MACHINES FOR MAKING CIGARS OR CIGARETTES
- A24C5/00—Making cigarettes; Making tipping materials for, or attaching filters or mouthpieces to, cigars or cigarettes
- A24C5/01—Making cigarettes for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/08—Cigars; Cigarettes with lighting means
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- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/20—Cigarettes specially adapted for simulated smoking devices
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/17—Filters specially adapted for simulated smoking devices
Definitions
- Traditional cigarettes are smoked by lighting an end of a wrapped tobacco rod and drawing air predominately through the lit end by suction at a mouthpiece end of the cigarette.
- Traditional cigarettes deliver smoke as a result of combustion, during which tobacco is combusted at temperatures that typically exceed 800°C during a puff. The heat of combustion releases various gaseous combustion products and distillates from the tobacco. As these gaseous products are drawn through the cigarette, they cool and condense to form an aerosol, which provides the flavors and aromas associated with smoking.
- electrical smoking systems significantly reduce sidestream smoke, and also permit smokers to suspend and reinitiate smoking as desired.
- Exemplary electrical smoking systems are disclosed in commonly-assigned U. S. Patents Nos. 6,026,820 ; 5,988,176 ; 5,915,387 ; 5,692,526 ; 5,692,525 ; 5,666,976 ; 5,499,636 ; and 5,388,594 .
- Electrical smoking systems include an electrically powered lighter and an electrically heated cigarette, which is constructed to cooperate with the lighter.
- electrical smoking systems be capable of delivering smoke in a manner similar to the smoker's experiences with traditional cigarettes, such as by providing an immediacy response (smoke delivery occurring immediately upon draw), a desired level of delivery (that correlates with FTC tar level), a desired resistance to draw (RTD), as well as puff-to-puff and cigarette-to-cigarette consistency.
- US 6,125,853 discloses a flavor-generation device comprising a flavour body adjacent to a heat reservoir.
- the flavour body contains a flavourant which, on heating the body, is released.
- the heat reservoir and the flavour body are heated by an electrical heater. The heat reservoir allows continued flavour generation when the device is moved from the heater.
- Volatile flavorings have been incorporated in traditional cigarettes to add flavors and aromas to mainstream and sidestream tobacco smoke. See, for example, U. S. Patents Nos. 3,006,347 ; 3,236,244 ; 3,344,796 ; 3,426,011 ; 3,972,335 ; 4,715,390 ; 5,137,034 ; 5,144,964 ; and 6,325,859 , and commonly-owned International Publication No. WO 01/80671 .
- the added flavorings are desirably volatilized when the cigarette is smoked. However, volatile flavorings tend to migrate in the cigarette to other components and possibly through the entire cigarette.
- Volatile flavorings can be lost from cigarettes during storage and distribution at ordinary conditions prior to smoking of the cigarettes.
- the degree of migration of volatile flavorings in cigarettes depends on different factors, including the flavoring's vapor pressure, the solubility of the flavoring in other components of the cigarette, and temperature and humidity conditions.
- a large portion of the added flavoring can be lost to the side stream smoke in traditional cigarettes.
- Flavorings that have been incorporated in traditional cigarettes also can chemically and/or physically deteriorate by contacting and/or reacting with other components of the cigarette, as well as with the environment.
- activated carbon has been incorporated in traditional cigarettes to remove gas-phase constituents from mainstream smoke.
- flavorings that have been incorporated in the cigarettes along with the activated carbon have been adsorbed by the activated carbon, clogging pores of the activated carbon and consequently deactivating the activated carbon, thereby diminishing its ability to filter tobacco smoke.
- flavorings that have been incorporated in traditional cigarettes have not been totally satisfactorily delivered to the smoker. Consequently, the flavorings incorporated in some traditional cigarettes have not satisfactorily provided the desired taste effect to the smoker and the flavorings desired value to the subjective quality of the cigarette has been less than desired. Due to the flavoring loss, the uniformity of flavored cigarettes has not been totally satisfactory. In addition, the sorption of flavorings by sorbents in the cigarettes has deactivated the sorbents and thereby reduced their ability to remove gas phase constituents from tobacco smoke.
- an electrically heated cigarette for an electrical smoking system comprising at least one sorbent and a flavoring-release additive including at least one flavoring releasable in the electrically heated cigarette upon the flavoring-release additive being electrically heated to at least a minimum temperature, wherein the flavoring-release additive is an inclusion complex which includes a host molecule and the flavoring is a guest molecule in the inclusion complex.
- the electrically heated cigarette comprises a sorbent and a flavoring incorporated in the cigarette in a form that preferably minimizes release and migration of the flavoring in the cigarette prior to smoking, for example, at ambient conditions, and thus preferably minimizes deactivation of the sorbent by the flavoring.
- the flavoring is released in the cigarette in a controlled manner during smoking. Consequently, the flavoring preferably enhances subjective characteristics of the cigarette while the sorbent maintains its ability to remove gas-phase constituents from mainstream smoke.
- a method of making an electrically heated cigarette as described above comprising incorporating into an electrically heated cigarette the at least one sorbent and the flavoring-release additive including at least one flavoring releasable in the electrically heated cigarette upon the flavoring-release additive being electrically heated to at least the minimum temperature, wherein the flavoring-release additive is an inclusion complex which includes a host molecule and the flavoring is a guest molecule in the inclusion complex.
- a method of smoking the electrically heated cigarette as described above comprising electrically heating a portion of the electrically heated cigarette to form smoke and drawing the smoke through the electrically heated cigarette, the sorbent removing at least one selected gas-phase constituent from mainstream smoke.
- an electrical smoking system comprising a lighter and at least one electrically heated cigarette including at least one sorbent and a flavoring-release additive including at least one flavoring which is releasable in the electrically heated cigarette upon the flavoring-release additive being heated to at least a minimum temperature, wherein the flavoring-release additive is an inclusion complex which includes a host molecule and the flavoring is a guest molecule in the inclusion complex.
- an electrically heated cigarette comprising at least one sorbent and at least one flavoring-release additive in a form selected from the group consisting of beads, film, and an inclusion complex, each flavoring-release additive including at least one flavoring releasable in the electrically heated cigarette upon the flavoring-release additive being electrically heated to at least a minimum temperature, wherein the flavoring-release additive is an inclusion complex which includes a host molecule and the flavoring is a guest molecule in the inclusion complex.
- a method of making an electrically heated cigarette as described above comprising incorporating into an electrically heated cigarette the at least one sorbent and the at least one flavoring-release additive in the form of an inclusion complex, the flavoring-release additive including at least one flavoring releasable in the electrically heated cigarette upon the flavoring-release additive being electrically heated to at least the minimum temperature.
- a method of smoking the electrically heated cigarette as described above comprising heating a portion of the electrically heated cigarette to form smoke and drawing the smoke through the electrically heated cigarette, the sorbent removing at least one selected gas-phase constituent from mainstream smoke.
- two or more different flavoring-release additives having different flavoring release temperatures are located at different locations in an electrically heated cigarette that reach different temperatures from each other.
- the flavoring-release additives can be located at locations in the electrically heated cigarette that reach the flavoring release temperature for those flavoring-release additives. Accordingly, the flavoring-release additive can provide efficient, controlled release of the flavoring during smoking.
- the electrically heated cigarette can comprise various sorbents.
- the flavoring in the flavoring-release additive which minimizes release and/or migration of the flavoring until the flavoring-release additive reaches the flavoring release temperature, the flavoring is preferably substantially prevented from being sorbed by, and thus deactivating, the sorbent, thereby not adversely affecting the sorbent's ability to remove selected gas-phase constituents from mainstream tobacco smoke.
- the flavoring is temperature released in the cigarette, it can be effectively delivered to a smoker in a controlled manner during puff cycles of the cigarette.
- An electrically heated cigarette includes one or more sorbents and at least one flavoring for affecting flavor, taste, and/or aroma of tobacco smoke.
- the flavoring is incorporated in the cigarette in a flavoring-release additive, which preferably minimizes the release and/or migration of the flavoring in the cigarette prior to smoking.
- the flavoring is released from the flavoring-release additive in a controlled manner during smoking of the cigarette.
- the flavoring-release additive enables the flavoring to enhance subjective characteristics of the cigarette while avoiding an adverse impact on the effectiveness of the sorbent in removing selected gas-phase constituents from mainstream smoke.
- the flavoring is released in the cigarette upon the flavoring-release additive being heated to at least a minimum temperature (flavoring release temperature), which occurs when a smoker draws mainstream smoke through the cigarette.
- different regions of the electrically heated cigarette reach different temperatures when a smoker draws on the cigarette.
- different flavoring-release additives are selectively disposed at two or more locations in the electrically heated cigarette that respectively reach at least the minimum temperature at which the flavoring is released from the flavoring-release additive disposed at that location.
- the flavoring-release additive can have various constructions and compositions and can be located at one or more locations, and/or incorporated in one or more components of the electrically heated cigarette.
- the flavoring-release additives can be designed to have different associated flavoring release temperatures. Accordingly, the flavoring-release additives can be incorporated in the electrically heated cigarette at locations that are most suitable for providing efficient release of the flavoring from the particular flavoring-release additive.
- the electrically heated cigarette can comprise one or more sorbents capable of removing selected gas-phase constituents from mainstream smoke.
- the flavoring in the flavoring-release additive that preferably minimizes the release and/or migration of the flavoring in the cigarette until the flavoring-release additive reaches at least the minimum temperature, the flavoring is preferably substantially prevented from deactivating the sorbent.
- the ability of the sorbent to remove selected gas-phase constituents from mainstream tobacco smoke can be maintained.
- the flavoring-release additive enables the flavoring to be effectively delivered to a smoker in a controlled manner.
- sorption denotes filtration by adsorption and/or absorption. Sorption is intended to encompass interactions on the outer surface of the sorbent, as well as interactions within the pores and channels of the sorbent.
- a "sorbent” is a substance that has the ability to condense or hold molecules of other substances on its surface, and/or the ability to take up other substances, i.e., through penetration of the other substances into its inner structure, or into its pores.
- sorbent refers to either an adsorbent, an absorbent, or a substance that can function as both an adsorbent and an absorbent.
- the term “remove” refers to adsorption and/or absorption of at least some portion of a component of mainstream tobacco smoke.
- mainstream smoke includes the mixture of gases passing down the tobacco rod and issuing through the filter end, i.e., the amount of smoke issuing or drawn from the mouth end of a cigarette during smoking of the cigarette.
- the mainstream smoke contains air that is drawn in through the heated region of the cigarette and through the paper wrapper.
- molecular sieve refers to a porous structure comprised of an inorganic material and/or organic material. Molecular sieves include natural and synthetic materials. Molecular sieves can sorb molecules of certain dimensions, while rejecting molecules having larger dimensions.
- FIGS. 1 and 2 illustrate a preferred embodiment of the electrically heated cigarette 23.
- the electrically heated cigarette 23 comprises a tobacco rod 60 and a filter tipping 62 joined together by tipping paper 64.
- the tobacco rod 60 preferably includes a tobacco web or "mat" 66 folded into a tubular form about a free-flow filter 74 at one end and a tobacco plug 80 at the other end.
- An over wrap 71 surrounds the tobacco-containing mat 66 and is held together along a longitudinal seam.
- the over wrap 71 retains the mat 66 in a wrapped condition about the free-flow filter 74 and tobacco plug 80.
- the mat 66 preferably comprises a base web 68 and a layer of tobacco material 70.
- the tobacco material 70 can be located along the inside surface or the outside surface of the base web 68.
- the mat 66 and the over wrap 71 are wrapped about the free-flow filter plug 74.
- the tobacco plug 80 comprises a relatively short tobacco column 82 of cut filler tobacco, which is retained by a surrounding inner wrap 84.
- a void 90 is between the free-flow filter 74 and the tobacco plug 80.
- the void 90 is an unfilled portion of the tobacco rod 60 and is in fluid communication with the tipping 62 through the free flow filter 74.
- the tipping 62 preferably comprises a free-flow filter 92 located adjacent the tobacco rod 60 and a mouthpiece filter plug 94 at the distal end of the tipping 62 from the tobacco rod 60.
- the free-flow filter 92 is tubular and transmits air with very low pressure drop.
- the mouthpiece filter plug 94 closes off the free end of the tipping 62.
- the cigarette 23 optionally includes at least one row of perforations 12 adjacent the free end 15 of the cigarette 23.
- the perforations can be formed as slits 17, which preferably extend through the over wrap 71, the mat 66 and the inner wrap 84.
- At least one additional row of perforations 14 comprising slits 17 can optionally be formed at a location along the tobacco plug 80.
- the perforations 12 or 14 may comprise a single row or a dual row of slits 17.
- the number and extent of the slits 17 can be selected to control the resistance to draw (RTD) along the side walls of the cigarettes 23 and the delivery.
- Optional holes 16 provided in the mat 66 are covered by the over wrap 71.
- the perforations 12, 14 can be used to approximate desired delivery levels for the cigarette 23, with the holes 16 being used to adjust delivery with a lesser effect on the RTD.
- the cigarette 23 preferably has a substantially constant diameter along its length.
- the diameter of the cigarette 23, like more traditional cigarettes, is preferably between about 7.5 mm to 8.5 mm so that the electrical smoking system 21 provides a smoker with a familiar "mouth feel" during smoking.
- the tobacco column 82 preferably comprises cut filler of a typical blend of tobaccos, such as blends comprising bright, Burley, and Oriental tobaccos together with, optionally, reconstituted tobaccos and other blend components, including traditional cigarette flavors.
- a typical blend of tobaccos such as blends comprising bright, Burley, and Oriental tobaccos together with, optionally, reconstituted tobaccos and other blend components, including traditional cigarette flavors.
- the free-flow filter 92 and the mouthpiece filter plug 94 are preferably joined together as a combined plug with a plug wrap 101.
- the plug wrap 101 is preferably a porous, low-weight plug wrap.
- the combined plug is attached to the tobacco rod 60 by the tipping paper 64.
- the electrically heated cigarette 23 can comprise one or more sorbents that remove gas-phase constituents of tobacco smoke.
- the sorbent can comprise one or more porous materials through which tobacco smoke can flow.
- the sorbent is activated carbon.
- the sorbent can comprise activated carbon granules located in a void in the filter, or activated carbon particles loaded on fibrous material or paper.
- the activated carbon can be in various forms including particles, fibers, beads, and the like.
- the activated carbon can have different porosity characteristics, such as a selected pore size and total pore volume.
- the sorbent is one or more suitable molecular sieve sorbent materials.
- Molecular sieve sorbents that may be used in the electrically heated cigarette 23 include, but are not limited to, one or more of the zeolites, mesoporous silicates, alumino phosphates, mesoporous aluminosilicates, and other related porous materials, such as mixed oxide gels, which may optionally further comprise inorganic or organic ions and/or metals. See, for example, commonly-owned International Publication No. WO 01/80973 .
- the sorbent is one or more zeolites.
- Zeolites include crystalline aluminosilicates having pores, such as channels and/or cavities of uniform, molecular sized dimensions. There are many known unique zeolite structures having different sized and shaped pores, which can significantly affect the properties of these materials with regard to sorption and separation processes. Molecules can be separated by zeolites by size and shape effects related to the possible orientation of the molecules in the pores, and/or by differences in strength of sorption.
- One or more zeolites having pores larger than one or more selected gas phase components of a gas that is desired to be filtered can be used in the electrically heated cigarette 23, such that only selected molecules that are small enough to pass through the pores of the molecular sieve material are able to enter the cavities and be sorbed on the zeolite.
- the zeolite can be, but is not limited to, one or more of zeolite A; zeolite X; zeolite Y; zeolite K-G; zeolite ZK-5; zeolite BETA; zeolite ZK-4 and zeolite ZSM-5.
- zeolite ZSM-5 and/or zeolite BETA is used.
- ZSM-5 is in the MFI structural classification family and represented by the crystal chemical data [Na n (Al n Si 96-n O 192 ) ⁇ 16H 2 O, with n ⁇ 27, orthorhombic, Pnma], while zeolite BETA is in the BEA structural classification family and represented by the crystal chemical data [Na 7 (Al 7 Si 57 O 128 ) tetragonal, P4 1 22].
- These two zeolites are thermally stable at temperatures up to about 800°C, allowing them to be incorporated in cigarette filters and/or the tobacco rod of the electrically heated cigarette 23.
- the sorbent incorporated in the electrically heated cigarette 23 has a composite composition.
- the sorbent comprises, for example, activated carbon and one or more molecular sieve materials, such as those described above.
- sorbent fibers can be impregnated with at least one sorbent.
- Microporous, mesoporous, and/or macroporous molecular sieves may be used in the electrically heated cigarette 23, depending on the selected component(s) desired to be removed from mainstream tobacco smoke.
- the sorbent can be incorporated in one or more locations of the electrically heated cigarette 23.
- the sorbent can placed in the passageway of the tubular free-flow filter 74, in the free-flow filter 92, and/or in the void space 90.
- the sorbent can additionally or alternatively be incorporated in the tobacco plug 80.
- FIG. 3 shows another preferred embodiment of an electrically heated cigarette 23 including a filter 150.
- the filter 150 comprises a sorbent in the form of oriented fibers 152 and a sleeve 154, such as paper, surrounding the fibers.
- the sorbent can be, for example, one or more of activated carbon, silica gel, zeolite, and other molecular sieves in fibrous forms.
- the sorbents can be surface modified materials, for example, surface modified silica gel, such as amino propyl silyl (APS) silica gel. Sorbent mixtures can provide different filtration characteristics to achieve a targeted filtered mainstream smoke composition.
- the fibers 152 can comprise one or more sorbent materials, such as carbon, silica, zeolite and the like, impregnated in microcavity fibers, such as TRIADTM micro-cavity fiber, as disclosed in commonly-owned International Publication No. WO 01/80973 .
- the fibers are shaped microcavity fibers impregnated with particles of one or more sorbent materials, or alternatively continuous activated carbon fibers.
- the fibers preferably have a diameter of from about 10 microns to about 100 microns.
- the fibers can have a length of from about 10 microns to about 200 microns, for example.
- the fibers are bundles of non-continuous fibers, which are preferably oriented parallel to the direction of mainstream smoke flow through the electrically heated cigarette.
- the filters 150 including fibers 152 can be formed, for example, by stretching a bundle of non-crimped sorbent fiber material, preferably having a controlled total and per filament denier, through a pre-formed or in-situ formed sleeve 154 during the filter making process.
- the formed filter can be sized by cutting to a desired length.
- the filters can have a length of from about 5 mm to about 30 mm.
- the filter 150 including fibers 152 can be incorporated in the electrically heated cigarette at one or more desired locations.
- the filter 150 can be substituted for the entire free-flow filter 92.
- the free-flow filter 150 can be substituted for a portion of the free-flow filter 92.
- the filter 150 can be in contact with (i.e., abut) the free-flow filter 74, positioned between the free-flow filter 74 and the mouthpiece filter plug 94, or in contact with (i.e., abut) the mouthpiece filter plug 94.
- the filter 150 preferably has a diameter substantially equal to that of the outer diameter of the free-flow filter 92 to minimize by-pass of smoke during the filtration process.
- the fibrous sorbents preferably have a high loft with a suitable packing density and fiber length such that parallel pathways are created between fibers.
- Such structure can effectively remove significant amounts of selected gas-phase constituents, such as formaldehyde and/or acrolein, while preferably removing only a minimal amount of particulate matter from the smoke, thereby achieving a significant reduction of the selected gas-phase constituents, while not significantly affecting the total particulate matter (TPM) in the gas.
- TPM total particulate matter
- the amount of sorbent used in preferred embodiments of the electrically heated cigarette 23 depends on the amount of selected gas-phase constituents in the tobacco smoke and the amount of the constituents that is desired to be removed from the tobacco smoke.
- the electrically heated cigarette 23 also comprises at least one flavoring-release additive.
- the flavoring can be, for example, one or more flavorings including, but not limited to, menthol, mint, such as peppermint and spearmint, chocolate, licorice, citrus and other fruit flavors, gamma octalactone, vanillin, ethyl vanillin, breath freshener flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil, and tobacco flavor.
- the flavoring is menthol and optionally at least one mint flavoring.
- the flavoring-release additive can have different structures and compositions in the electrically heated cigarette.
- the flavoring-release additive is in the form of beads. The beads preferably encapsulate the flavoring and provide for controlled release of the flavoring in the cigarette during puff cycles.
- the beads preferably comprise at least one encapsulating material and at least one flavoring.
- the encapsulating material preferably comprises a binder, which can be, for example, one or more of palm oil, konjac gum, xylitol, zein, hydroxypropylcellulose, sorbitol, maltitol, and hydroxypropylmethylcellulose.
- Other materials known in the art that can improve the bead-forming characteristics of the encapsulating material or enhance its stability can optionally also be added in the beads.
- the beads have a substantially homogenous composition in which flavoring is substantially uniformly distribute. By such structure, the flavoring can be released from the beads in a more uniform manner during smoking.
- the minimum temperature at which the beads release the flavoring can be adjusted.
- Beads comprising one or more of the above-described binders preferably have a minimum temperature at which the flavoring is released of at least about 40°C, such as about 40°C to about 150°C.
- the beads protect the flavoring from exposure to undesired substances in the atmosphere (e.g., ambient air, inside a package) and undesired substances in the cigarette, and preferably minimize release and/or migration of the flavoring until the flavoring-release additive is heated to a sufficiently high temperature during smoking of the cigarette. Consequently, the flavoring is preferably substantially prevented from migrating in the cigarette, reacting with other substances in the cigarette or with the environment, and deactivating sorbent present in the cigarette.
- the beads can have any desired shape, such as different regular and irregular shapes, including round, square, rectangular, oval, other polygonal shapes, cylindrical, fibrous, and the like.
- the beads can have various sizes.
- the beads are microbeads having a maximum particle size of less than about 25 microns, and more preferably less than about 1 micron. Decreasing the size of the beads can provide a more homogenous and controlled release of flavoring by providing increased surface area of the beads.
- the beads can be manufactured by any suitable process that produces beads having the desired structure, composition, and size.
- the beads can be manufactured by extrusion, spray drying, coating, or other suitable processes.
- the beads are formed by forming a solution, dispersion or emulsion containing a binder, flavoring and optional additives to form beads, which can be isolated and dried. Processes for preparing beads containing an active ingredient, such as a flavor, are disclosed in U.S. Patent No. 6,325,859 .
- the electrically heated cigarette 23 preferably comprises an amount of the beads that provides a desired amount of the flavoring in the cigarette.
- the electrically heated cigarette comprises, based on the total weight of tobacco in the cigarette, up to about 20%, and more preferably about 10% to about 15%, of the beads.
- a cigarette containing 100 mg of tobacco preferably contains up to about 20 mg of beads.
- the beads can preferably comprise up to about 20% of flavoring.
- the cigarette can comprise, for example, from about 1 mg to about 15 mg of flavoring.
- the beads are disposed in at least one location in the electrically heated cigarette 23 that reaches at least the minimum temperature at which the flavoring is released from the beads and into the cigarette during smoking.
- the beads can be disposed in the tobacco rod 60, in the void 90 between the tobacco plug 80 and the free-flow filter 74, on one or more surfaces of the free-flow filter 74, on or in the mat 66, and/or on or in the inner wrap 84 surrounding the tobacco plug 80.
- different bead compositions having two or more different minimum flavoring-release temperatures can be incorporated at two or more locations in an electrically heated cigarette that reaches different temperatures at such locations during smoking.
- beads having a first flavoring release temperature can be located at a first location in the cigarette that reaches the first flavoring-release temperature
- beads having a second flavoring-release temperature higher than the first flavoring-release temperature can be located at a second location in the cigarette that reaches the second flavoring-release temperature.
- the two flavoring release temperatures can vary by up to about 100°C.
- these two temperatures can vary by up to about 10°C, 20°C, 30°C, 40°C, 50°C, 60°C, 70°C, 80°C, 90°C, or 100°C.
- the flavoring-release additive includes a film.
- the film preferably encapsulates the flavoring and enables the controlled temperature release of the flavoring in the cigarette during smoking.
- the film comprises by weight up to 20%, more preferably about 10% to about 15%, of the flavoring.
- the film encapsulates menthol and optionally also mint.
- the film-type flavoring-release additive preferably comprises at least one encapsulating material and at least one flavoring.
- the encapsulating material preferably comprises a binder, which can be, for example, one or more of carraghenan, gelatin, agar, gellan gum, gum arabic, guar gum, xanthum gum, and pectin. Other materials known in the art that can improve the film-forming characteristics of the encapsulating material or enhance its stability can optionally be added to the film.
- the film has a substantially homogenous composition in which flavoring is substantially uniformly distributed. By such structure, the flavoring can be released from the film in a more desired manner during smoking.
- the film encapsulating material provides a barrier to the release of the flavoring.
- the minimum temperature at which the film releases the flavoring can be adjusted/selected.
- a film comprising one or more of the above-described binders preferably has a minimum temperature at which the flavoring is released of at least about 50°C, such as up to about 120°C. The film protects the flavoring from exposure to undesired substances in the cigarette and atmosphere and substantially prevents the flavoring from being released until the film is heated to the flavoring release temperature during smoking of the cigarette.
- the film can be applied to one or more components of the electrically heated cigarette as a liquid coating, which is dried to a film.
- the dimensions of the dried film are not limited.
- the dried film has a maximum thickness of about 50 microns to about 150 microns, and more preferably about 75 microns.
- the film can be manufactured by any suitable process that produces a film having the desired structure, composition, and dimensions.
- the film can be applied by a coating process, such as spray coating, a dipping process, electrostatic deposition, printing wheel application, gravure printing, ink jet application, and the like.
- a coating process such as spray coating, a dipping process, electrostatic deposition, printing wheel application, gravure printing, ink jet application, and the like.
- an emulsion, suspension or slurry comprising the binder, flavoring, and optional additives is prepared and then applied as a coating to one or more selected surfaces of one or more selected components of the electrically heated cigarette.
- the coating is preferably dried to remove water and/or other solvents and form a solid film having desired dimensions. Exemplary processes that can be used to prepare the films are described in U.S. Patents Nos. 3,006,347 and commonly-owned 4,715,390 .
- the electrically heated cigarette 23 preferably comprises an amount of the film that releases a desired amount of the flavoring during smoking of the cigarette.
- the electrically heated cigarette comprises, based on the total weight of tobacco in the cigarette to which the film is applied, up to about 20%, and more preferably about 10% to about 15%, of the film.
- the weight of tobacco contained in the mat preferably is the weight basis for the amount of the film.
- the total weight of tobacco contained in the mat and the tobacco plug preferably is the weight basis for the amount of film applied in the cigarette.
- the weight of tobacco contained in the mat is the weight basis for the amount of film applied to the mat
- the weight of tobacco contained in the tobacco plug is the weight basis for the amount of film applied to the tobacco plug.
- the cigarette can comprise from about 1 mg to about 15 mg of flavoring.
- the film is disposed in at least one location in the electrically heated cigarette 23 that reaches at least the flavoring release temperature.
- the film can be disposed on the tobacco plug 80, on the inner wrap 84. surrounding the tobacco plug 80, on the mat 66, and/or on the over wrap 71 surrounding the mat.
- the weight of the inner wrap 84 and/or over wrap 71 is the weight basis for the amount of the film.
- the film can be preformed, shredded and incorporated in the tobacco plug 80, and/or other selected locations that reach the flavoring release temperature.
- different flavored films having two or more different minimum flavoring-release temperatures can be incorporated at different locations in an electrically heated cigarette, where during smoking of the cigarette, the temperatures at the different locations exceed the minimum release temperatures of the different films.
- the flavoring-release additive is an inclusion complex.
- the inclusion complex comprises a "host molecule,” and the flavoring is the "guest molecule" in the inclusion complex.
- the inclusion complex provides for controlled release of the flavoring in the cigarette during smoking.
- the flavoring is a lipophilic organic flavoring, which preferably concentrates within a hydrophobic cavity of the host molecule.
- Suitable flavorings include, but are not limited to, menthol, mint, such as peppermint and spearmint, chocolate, licorice, citrus and other fruit flavors, gamma octalactone, vanillin, ethyl vanillin, breath freshener flavors, spice flavors, such as cinnamon, methyl salicylate, linalool, bergamot oil, geranium oil, lemon oil, ginger oil; and tobacco flavor.
- the flavoring includes vanillin and gamma octalactone.
- the inclusion complex comprises by weight up to about 20%, more preferably from about 10% to about 15%, of the flavoring.
- the host molecule of the inclusion complex is preferably a cyclodextrin.
- Cyclodextrins are cyclic oligosaccharides including glucopyranose subunits, as described, for example, in U.S. Patents No. 3,426,011 and commonly-owned U.S. Patent No. 5,144,964 .
- the inclusion complex is formed when a flavoring material is mixed with a selected cyclodextrin in solution. The flavoring resides inside the cyclodextrin ring structure.
- the cyclodextrins and flavoring are typically co-precipitated, filtered, and dried.
- Alpha-cyclodextrin, beta-cyclodextrin and gamma-cyclodextrin include six, seven and eight glucopyranose subunits, respectively.
- the inclusion complex comprises beta-cyclodextrin, which can desirably accommodate a wide variety of guest molecules and is readily available.
- Beta-cyclodextrin has a ring structure of the linked subunits with a three-dimensional torus configuration including a hydrophobic cavity with a 7.5 ⁇ diameter and hydrophillic upper and lower edges.
- the minimum temperature at which the inclusion complex comprising a cyclodextrin releases the flavoring is preferably at least about 60°C, such as from about 60°C to about 125°C.
- the inclusion complex is preferably in powder form.
- the powder preferably has maximum size of less than about 200 microns.
- the inclusion complex can be made by forming an aqueous solution of beta-cyclodextrin and the flavoring.
- the inclusion complex can be recovered from the solution in powder form. However, the solution can be applied directly to one or more selected locations of one or more components of the electrically heated cigarette by any suitable process.
- the inclusion complex powder can alternatively be used to form a solution or a suspension.
- the inclusion complex can be applied by a coating process, such as slurry coating, spraying, a dipping process, electrostatic deposition, printing wheel application, gravure printing, ink jet application, and the like.
- a solution, suspension or slurry comprising the cyclodextrin and flavoring is prepared and applied as a coating to selected surfaces of selected components of the electrically heated cigarette. Exemplary processes that can be used to apply the inclusion complex in the electrically heated cigarette are described in commonly-owned U.S. Patent No. 5,144,964 .
- the electrically heated cigarette 23 preferably comprises an amount of the inclusion complex that provides a desired amount of the flavoring in the cigarette.
- the electrically heated cigarette comprises, based on the weight of the over wrap or mat, up to about 15%, and more preferably less than about 8%, of the inclusion complex.
- the weight of the mat preferably is the weight basis for the amount of the inclusion complex applied to the mat.
- the total weight of the mat and the over wrap preferably is the weight basis for the amount of the inclusion complex applied to the mat and the over wrap.
- the weight percent of the inclusion complex that is applied to the mat and/or over wrap can be the same or different.
- the cigarette comprises from about 1 mg to about 50 mg of flavoring.
- the inclusion complex is disposed in at least one locations in the electrically heated cigarette 23 that reaches at least the minimum temperature at which the flavoring is released from the inclusion complex in the cigarette during smoking.
- the inclusion complex can be disposed on the inner wrap 84, mat 66, and/or the over wrap 71.
- the electrically heated cigarette comprises two oF more different types of flavoring-release additives, for example, a bead and a film and/or an inclusion complex, with each flavoring-release additive having a different flavoring release temperature.
- the different flavoring-release additives can be incorporated at two or more locations in the same electrically heated cigarette that reach different temperatures during smoking in order to provide further controlled release of the flavoring during smoking.
- FIGS. 4 and 5 illustrate a preferred embodiment of an electrical smoking system in which preferred embodiments of the electrically heated cigarette can be used.
- the electrical smoking system 21 includes an electrically heated cigarette 23 and a reusable lighter 25.
- the cigarette 23 is constructed to be inserted into and removed from a cigarette receiver 27, which is open at a front end portion 29 of the lighter 25. Once the cigarette 23 is inserted, the smoking system 21 is used in a similar manner as a more traditional cigarette, but without lighting or smoldering of the cigarette 23. The cigarette 23 is discarded after smoking.
- each cigarette 23 provides a total of at least eight puffs (puff cycles) per smoke.
- the cigarette 23 can be constructed to provide a lesser or greater total number of available puffs.
- the lighter 25 includes a housing 31 having front and rear housing portions 33 and 35, respectively.
- a power source 35a such as one or more batteries, is located within the rear housing portion 35 and supplies energy to a heater fixture 39.
- the heater fixture 39 includes a plurality of electrically resistive, heating elements 37 ( FIG. 6 ).
- the heating elements 37 are arranged within the front housing portion 33 to slidingly receive the cigarette 23.
- a stop 183 located in the heater fixture 39 defines a terminal end of the cigarette receiver 27 ( FIG. 2 ).
- Control circuitry 41 in the front housing portion 33 selectively establishes electrical communication between the power source 35a and one or more of the heating elements 37 during each puff cycle.
- the rear housing portion 35 of the housing 31 is constructed to be opened and closed to facilitate replacement of the power source 35a.
- the front housing portion 33 is removably attached to the rear housing portion 35 by mechanical engagement.
- the control circuitry 41 is activated by a puff-actuated sensor 45, which is sensitive to either changes in pressure or changes in the rate of air flow that occur upon initiation of a draw on the cigarette 23 by a smoker.
- the puff-actuated sensor 45 is preferably located within the front housing portion 33 of the lighter 25 and communicates with a space inside the heater fixture 39 via a port 45a extending through a side wall portion 182 of the heater fixture 39. Once actuated by the sensor 45, the control circuitry 41 directs electric current to an appropriate one of the heating elements 37.
- an indicator 51 is provide at a location along the exterior of the lighter 25 to visually indicate the number of puffs remaining in a cigarette 23, or other selected information.
- the indicator 51 preferably includes a liquid crystal display.
- the indicator 51 displays a selected image when a cigarette detector 57 detects the presence of a cigarette in the heater fixture 39.
- the detector 57 can comprise any arrangement that senses the presence of an electrically heated cigarette.
- the detector can comprise an inductive coil 1102 adjacent the cigarette receiver 27 of the heater fixture 39 and electric leads 1104 that communicate the coil 1102 with an oscillator circuit within the control circuitry 41.
- the cigarette 23 can include a metallic element (not shown), which can affect inductance of the coil winding 1102 such that whenever a suitable cigarette 23 is inserted into the receiver 27, the detector 57 generates a signal to the circuitry 41 indicating the cigarette is present.
- the control circuitry 41 provides a signal to the indicator 51.
- the cigarette detector 57 no longer detects the presence of a cigarette 23 and the indicator 51 is turned off.
- the heater fixture 39 supports an inserted cigarette 23 in a fixed relation to the heating elements 37 such that the heating elements 37 are positioned alongside the cigarette 23 at approximately the same location for each newly inserted cigarette 23.
- the heater fixture 39 includes eight mutually parallel heater elements 37, which are disposed concentrically about the axis of symmetry of the cigarette receiver 27. The location where each heating element 37 touches a fully inserted cigarette 23 is referred to herein as the heater footprint or char zone 42.
- the heating elements 37 preferably each include at least first and second serpentine, elongate members 53a and 53b adjoined at a tip 54.
- the heater portions 53a, 53b and 54 form a heater blade 120.
- the tips 54 are adjacent the opening 55 of the cigarette receiver 27.
- the opposite ends 56a and 56b of each heating element 37 are electrically connected to the opposite poles of the power source 35a as selectively established by the controller 41.
- An electrical pathway through each heating element 37 is established, respectively, through a terminal pin 104, a connection 121 between the pin 104 and a free end portion 56a of one of the serpentine members 53a, through at least a portion of the tip 54 to the other serpentine member 53b and its end portion 56b.
- connection ring 110 provides a common electrical connection to each of the end portions 56b.
- the ring 110 is connected to the positive terminal of the power source 35a through a connection 123 between the ring 110 and a pin 105.
- the heating elements 37 are individually energized by the power source 35a under the control of the control circuitry 41 to heat the cigarette 23 preferably eight times at spaced locations about the periphery of the cigarette 23.
- the heating renders eight puffs from the cigarette 23, as is commonly achieved with the smoking of a more traditional cigarette. It may be preferred to activate more than one heating element simultaneously for one or more or all of the puffs.
- the heater fixture 39 includes an air inlet port 1200 through which air is drawn into the lighter. A pressure drop is induced upon the air entering the lighter such that the puff sensor 45 is operative to recognize initiation of a puff.
- the range of pressure drop induced is selected such that it is within the range of pressure drop detectable by the pressure sensor 45.
- the length of the tobacco plug 80 and its relative position along the tobacco rod 60 is preferably selected based on the construction and location of the heating elements 37 of the electrical smoking system 21.
- a portion of each heating element contacts the tobacco rod 60.
- This region of contact is referred to as a heater footprint 95, which is that region of the tobacco rod 60 where the heating element 37 is expected to reach a temperature high enough to allow smoking of the cigarette without combustion of the cigarette paper, mat or tobacco.
- the heater foot print 95 can consistently locate along the tobacco rod 60 at the same predetermined distance 96 from the free end 78 of the tobacco rod 60 for every cigarette 23 that is fully inserted into the lighter 25.
- the length of the tobacco plug 80 of the cigarette 23, the length of the heater footprint 95, and the distance between the heater footprint 95 and the stop 182 are selected such that the heater footprint 95 extends beyond the tobacco plug 80 and superposes a portion of the void 91 by a distance 98.
- the distance 98 is also referred to as the "heater-void overlap” 98.
- the distance over which the remainder of the heater footprint 95 superposes the tobacco plug 80 is referred to as the "heater-filler overlap" 99.
- the length of the void 91, tobacco plug 80, and the distribution of the perforation holes 263 may be adjusted to adjust the smoking characteristics of the cigarette 23, including adjustments in its taste, draw and delivery.
- the pattern of holes 263, the length of the void 90 and the amount of heater-filler overlap 99 (and heater-void overlap 98) may also be manipulated to adjust the immediacy of response, to promote consistency in delivery.
- Electrically heated cigarettes can provide advantages.
- the flavoring(s) can be retained in the cigarette until it is smoked.
- the flavoring- is preferably temperature released in a controlled manner during smoking, thereby providing the smoker with an enhanced subjective characteristic of the cigarette.
- deactivation of the sorbent in the cigarette is preferably minimized. Consequently, the sorbent maintains it ability to remove selected gas phase constituents from mainstream smoke.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
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- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Manufacture Of Tobacco Products (AREA)
Claims (20)
- Cigarette chauffée électriquement (23) pour un système à fumer électrique (21), comprenant :au moins un sorbant ; etun additif libérateur d'arômes comprenant au moins un arôme libérable dans la cigarette chauffée électriquement (23) lorsque l'additif libérateur d'arôme est chauffé électriquement à au moins une température minimale, dans lequel l'additif libérateur d'arômes est un complexe d'inclusion qui comprend une molécule hôte et l'arôme est une molécule hôte dans le complexe d'inclusion.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle le sorbant est du charbon actif.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle le sorbant est une zéolite.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle l'arôme est (i) menthol, ou (ii) de vanilline et gamma octalactone.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle l'arôme est au moins un arôme choisi dans le groupe constitué de menthol, de menthe, de chocolat, de réglisse, d'arômes de fruits, de gamma octalactone, de vanilline, d'éthylvanilline, d'arômes rafraîchisseur d'haleine, d'arômes d'épices, de salicylate de méthyle, de linalol, d'huile de bergamote, d'huile de géranium, d'huile de citron, d'huile de gingembre, et d'arôme de tabac.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle la molécule hôte est la cyclodextrine bêta.
- Cigarette chauffée électriquement (23) selon la Revendication 1, qui comprend, par rapport au poids d'une surenveloppe (71) et/ou une natte (66), moins d'environ 15 % en poids du complexe d'inclusion.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle le complexe d'inclusion comprend jusqu'à environ 20 % de l'arôme.
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle la température minimale est d'environ 60 °C, et le complexe d'inclusion est placé dans au moins un emplacement dans la cigarette chauffée électriquement qui atteint au moins environ 60 °C pendant le fumage de la cigarette (23).
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle l'additif libérateur d'arôme est disposé sur une enveloppe intérieure (84) qui entoure une plaquette de tabac (80), sur un mat contenant du tabac (66), et/ou sur une surenveloppe (71) entourant la natte (66).
- Cigarette chauffée électriquement (23) selon la Revendication 1, dans laquelle le sorbant est constitué de fibres.
- Cigarette chauffée électriquement (23) selon la Revendication 11, dans laquelle les fibres sont des fibres continues ou non continues.
- Cigarette chauffée électriquement (23) selon la Revendication 11, dans laquelle les fibres sont imprégnées avec au moins un sorbant.
- Procédé de fabrication d'une cigarette chauffée électriquement (23) selon la Revendication 1, comprenant l'incorporation dans une cigarette chauffée électriquement (23) (a) de l'au moins un agent de sorption, et (b) de l'additif libérateur d'arôme comprenant au moins un aromatisant libérable dans la cigarette chauffée électriquement (23) lorsque l'additif libérateur d'arôme est chauffé électriquement à au moins la température minimale, où l'additif libérateur d'arôme est un complexe d'inclusion qui comprend une molécule hôte et l'arôme est une molécule hôte dans le complexe d'inclusion.
- Procédé de fumage de la cigarette chauffée électriquement (23) selon la Revendication 1, comprenant un chauffage électrique d'une partie de la cigarette chauffée électriquement (23) pour former et aspirer de la fumée à travers la cigarette chauffée électriquement (23), le sorbant éliminant au moins un constituant sélectionné en phase gazeuse de la fumée principale.
- Système de fumage électrique (21), comprenant :un briquet (25) ; etau moins une cigarette chauffée électriquement (23) incluant :au moins un agent de sorption ; etun additif libérateur d'arôme incluant au moins un arôme qui est libérable dans la cigarette chauffée électriquement (23) lorsque l'additif libérateur d'arôme est chauffé à au moins une température minimale, où l'additif libérateur d'arôme est un complexe d'inclusion qui comprend une molécule hôte et l'arôme est une molécule hôte dans le complexe d'inclusion.
- Cigarette chauffée électriquement (23), comprenant :au moins un adsorbant ; etau moins un additif libérateur d'arôme sous une forme choisie dans le groupe constitué de perles, de films, et un complexe d'inclusion, chaque additif libérateur d'arôme comprenant au moins un arôme libérable dans la cigarette chauffée électriquement (23) lorsque l'additif libérateur d'arôme est chauffé à au moins une température minimale, où l'additif libérateur d'arôme est un complexe d'inclusion qui comprend une molécule hôte et l'arôme est une molécule hôte dans le complexe d'inclusion.
- Cigarette chauffée électriquement (23) selon la Revendication 17, dans laquelle l'additif libérateur d'arôme comprend au moins deux additifs libérateurs d'arôme sous la forme d'un complexe d'inclusion, chaque additif libérateur d'arôme ayant une température minimale différente à laquelle l'arôme est libéré pendant le fumage de la cigarette chauffée électriquement (23).
- Procédé de fabrication d'une cigarette chauffée électriquement (23) selon la revendication 17, comprenant l'incorporation dans une cigarette chauffée électriquement (23) (a) de l'au moins un agent de sorption, et (b) de l'au moins un additif libérateur d'arôme sous la forme d'un complexe d'inclusion, l'additif libérateur d'arôme incluant au moins un aromatisant libérable dans la cigarette chauffée électriquement (23) lorsque l'additif libérateur d'arôme est chauffé électriquement à au moins la température minimale.
- Procédé de fumage de la cigarette chauffée électriquement (23) selon la Revendication 17, comprenant le chauffage d'une partie de la cigarette chauffée électriquement (23) pour former et aspirer de la fumée à travers la cigarette chauffée électriquement (23), le sorbant éliminant au moins un constituant sélectionné en phase gazeuse de la fumée principale.
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US42249702P | 2002-10-31 | 2002-10-31 | |
US422497P | 2002-10-31 | ||
PCT/US2003/034290 WO2004041007A2 (fr) | 2002-10-31 | 2003-10-30 | Cigarette chauffee electriquement comprenant un arome a liberation controlee |
Publications (3)
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EP1555898A2 EP1555898A2 (fr) | 2005-07-27 |
EP1555898A4 EP1555898A4 (fr) | 2012-08-29 |
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US (1) | US20040129280A1 (fr) |
EP (1) | EP1555898B1 (fr) |
JP (1) | JP4889218B2 (fr) |
KR (1) | KR101072668B1 (fr) |
CN (1) | CN1317986C (fr) |
AU (1) | AU2003284199B2 (fr) |
BR (1) | BR0315829B1 (fr) |
CA (1) | CA2502171C (fr) |
DK (1) | DK1555898T3 (fr) |
EA (1) | EA006569B1 (fr) |
EG (1) | EG23930A (fr) |
ES (1) | ES2573479T3 (fr) |
HK (1) | HK1076013A1 (fr) |
HU (1) | HUE026909T2 (fr) |
IL (1) | IL168310A (fr) |
MA (1) | MA27484A1 (fr) |
MX (1) | MXPA05004683A (fr) |
NO (1) | NO338062B1 (fr) |
PL (1) | PL203915B1 (fr) |
UA (1) | UA90430C2 (fr) |
WO (1) | WO2004041007A2 (fr) |
ZA (1) | ZA200502781B (fr) |
Families Citing this family (257)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0019417D0 (en) * | 2000-08-09 | 2000-09-27 | Mat & Separations Tech Int Ltd | Mesoporous carbons |
US8591855B2 (en) * | 2000-08-09 | 2013-11-26 | British American Tobacco (Investments) Limited | Porous carbons |
US20050172976A1 (en) * | 2002-10-31 | 2005-08-11 | Newman Deborah J. | Electrically heated cigarette including controlled-release flavoring |
US7827996B2 (en) * | 2003-12-22 | 2010-11-09 | Philip Morris Usa Inc. | Amphiphile-modified sorbents in smoking articles and filters |
US20060090769A1 (en) * | 2004-11-02 | 2006-05-04 | Philip Morris Usa Inc. | Temperature sensitive powder for enhanced flavor delivery in smoking articles |
US8408216B2 (en) * | 2004-12-22 | 2013-04-02 | Philip Morris Usa Inc. | Flavor carrier for use in smoking articles |
US8539957B2 (en) | 2005-01-14 | 2013-09-24 | Philip Morris Usa Inc. | Cigarettes and cigarette filters including activated carbon for removing nitric oxide |
GB0506278D0 (en) | 2005-03-29 | 2005-05-04 | British American Tobacco Co | Porous carbon materials and smoking articles and smoke filters therefor incorporating such materials |
US7878209B2 (en) * | 2005-04-13 | 2011-02-01 | Philip Morris Usa Inc. | Thermally insulative smoking article filter components |
US10244793B2 (en) | 2005-07-19 | 2019-04-02 | Juul Labs, Inc. | Devices for vaporization of a substance |
US11647783B2 (en) | 2005-07-19 | 2023-05-16 | Juul Labs, Inc. | Devices for vaporization of a substance |
US9675109B2 (en) * | 2005-07-19 | 2017-06-13 | J. T. International Sa | Method and system for vaporization of a substance |
US8685478B2 (en) | 2005-11-21 | 2014-04-01 | Philip Morris Usa Inc. | Flavor pouch |
US9491971B2 (en) * | 2005-12-13 | 2016-11-15 | Philip Morris Usa Inc. | Specifically-defined smoking article with activated carbon sorbent and sodium bicarbonate-treated fibers and method of treating mainstream smoke |
US20070267033A1 (en) * | 2006-02-09 | 2007-11-22 | Philip Morris Usa Inc. | Gamma cyclodextrin flavoring-release additives |
US7726320B2 (en) | 2006-10-18 | 2010-06-01 | R. J. Reynolds Tobacco Company | Tobacco-containing smoking article |
GB0700889D0 (en) * | 2007-01-17 | 2007-02-21 | British American Tobacco Co | Tobacco, tobacco derivative and/or tobacco substitute products, preparation and uses thereof |
US20080302376A1 (en) * | 2007-06-08 | 2008-12-11 | Philip Morris Usa Inc. | Smoking article with controlled flavor release |
US8424541B2 (en) | 2007-07-16 | 2013-04-23 | Philip Morris Usa Inc. | Tobacco-free oral flavor delivery pouch product |
WO2009010881A2 (fr) * | 2007-07-16 | 2009-01-22 | Philip Morris Products S.A. | Produits en dosettes orales comportant des particules d'agent de flaveur immobilisées |
ES2674139T5 (es) | 2009-03-23 | 2024-05-08 | Japan Tobacco Inc | Artículo para inhalación de aroma, de tipo sin combustión |
US10420374B2 (en) | 2009-09-18 | 2019-09-24 | Altria Client Services Llc | Electronic smoke apparatus |
US8747562B2 (en) * | 2009-10-09 | 2014-06-10 | Philip Morris Usa Inc. | Tobacco-free pouched product containing flavor beads providing immediate and long lasting flavor release |
GB0918129D0 (en) | 2009-10-16 | 2009-12-02 | British American Tobacco Co | Control of puff profile |
EP2340730A1 (fr) | 2009-12-30 | 2011-07-06 | Philip Morris Products S.A. | Chauffage formé pour système de génération d'aérosol |
US9259035B2 (en) | 2010-05-15 | 2016-02-16 | R. J. Reynolds Tobacco Company | Solderless personal vaporizing inhaler |
US9999250B2 (en) | 2010-05-15 | 2018-06-19 | Rai Strategic Holdings, Inc. | Vaporizer related systems, methods, and apparatus |
US11344683B2 (en) | 2010-05-15 | 2022-05-31 | Rai Strategic Holdings, Inc. | Vaporizer related systems, methods, and apparatus |
US9743691B2 (en) | 2010-05-15 | 2017-08-29 | Rai Strategic Holdings, Inc. | Vaporizer configuration, control, and reporting |
US10159278B2 (en) | 2010-05-15 | 2018-12-25 | Rai Strategic Holdings, Inc. | Assembly directed airflow |
US9095175B2 (en) | 2010-05-15 | 2015-08-04 | R. J. Reynolds Tobacco Company | Data logging personal vaporizing inhaler |
US8757147B2 (en) | 2010-05-15 | 2014-06-24 | Minusa Holdings Llc | Personal vaporizing inhaler with internal light source |
US10136672B2 (en) | 2010-05-15 | 2018-11-27 | Rai Strategic Holdings, Inc. | Solderless directly written heating elements |
US9861772B2 (en) | 2010-05-15 | 2018-01-09 | Rai Strategic Holdings, Inc. | Personal vaporizing inhaler cartridge |
EP2682008B1 (fr) | 2011-03-02 | 2019-04-10 | Japan Tobacco Inc. | Procédé pour produire une feuille contenant un parfum conçue pour un article pour fumeur |
US9078473B2 (en) | 2011-08-09 | 2015-07-14 | R.J. Reynolds Tobacco Company | Smoking articles and use thereof for yielding inhalation materials |
EP2740506A1 (fr) | 2011-08-16 | 2014-06-11 | Ploom, Inc. | Dispositif de vaporisation électronique basse température et procédés associés |
UA110646C2 (uk) | 2011-09-06 | 2016-01-25 | Брітіш Амерікан Тобакко (Інвестментс) Лімітед | Пристрій для нагрівання курильного матеріалу |
EP2574247B1 (fr) | 2011-09-28 | 2019-08-28 | Philip Morris Products S.A. | Feuille chauffante électrique perméable pour l'évaporation de liquides à partir d'embouts buccaux à usage unique avec membranes d'évaporation |
US10448670B2 (en) * | 2011-12-30 | 2019-10-22 | Philip Morris Products S.A. | Aerosol generating system with consumption monitoring and feedback |
AR089602A1 (es) | 2011-12-30 | 2014-09-03 | Philip Morris Products Sa | Articulo generador de aerosoles para usar con un dispositivo generador de aerosoles |
EP2609820A1 (fr) * | 2011-12-30 | 2013-07-03 | Philip Morris Products S.A. | Détection d'un substrat formant un aérosol dans un dispositif de génération d'aérosol |
US11039642B2 (en) | 2011-12-30 | 2021-06-22 | Philip Morris Products S.A. | Smoking article with front-plug and aerosol-forming substrate and method |
CN110353311A (zh) | 2011-12-30 | 2019-10-22 | 菲利普莫里斯生产公司 | 具有前部塞的发烟制品及方法 |
EP2625975A1 (fr) | 2012-02-13 | 2013-08-14 | Philip Morris Products S.A. | Article de génération d'aérosol avec un élément de refroidissement d'aérosol |
US20130255702A1 (en) | 2012-03-28 | 2013-10-03 | R.J. Reynolds Tobacco Company | Smoking article incorporating a conductive substrate |
GB2502053B (en) | 2012-05-14 | 2014-09-24 | Nicoventures Holdings Ltd | Electronic smoking device |
PL2854570T3 (pl) | 2012-05-31 | 2017-08-31 | Philip Morris Products S.A. | Aromatyzowane pręty do zastosowania w wyrobach do wytwarzania aerozolu |
AR091509A1 (es) | 2012-06-21 | 2015-02-11 | Philip Morris Products Sa | Articulo para fumar para ser usado con un elemento de calentamiento interno |
US10004259B2 (en) | 2012-06-28 | 2018-06-26 | Rai Strategic Holdings, Inc. | Reservoir and heater system for controllable delivery of multiple aerosolizable materials in an electronic smoking article |
GB2504075A (en) | 2012-07-16 | 2014-01-22 | Nicoventures Holdings Ltd | Electronic smoking device |
GB2504076A (en) | 2012-07-16 | 2014-01-22 | Nicoventures Holdings Ltd | Electronic smoking device |
US8881737B2 (en) | 2012-09-04 | 2014-11-11 | R.J. Reynolds Tobacco Company | Electronic smoking article comprising one or more microheaters |
US8910639B2 (en) | 2012-09-05 | 2014-12-16 | R. J. Reynolds Tobacco Company | Single-use connector and cartridge for a smoking article and related method |
US9854841B2 (en) | 2012-10-08 | 2018-01-02 | Rai Strategic Holdings, Inc. | Electronic smoking article and associated method |
US10117460B2 (en) | 2012-10-08 | 2018-11-06 | Rai Strategic Holdings, Inc. | Electronic smoking article and associated method |
US10034988B2 (en) | 2012-11-28 | 2018-07-31 | Fontem Holdings I B.V. | Methods and devices for compound delivery |
US8910640B2 (en) | 2013-01-30 | 2014-12-16 | R.J. Reynolds Tobacco Company | Wick suitable for use in an electronic smoking article |
US10031183B2 (en) | 2013-03-07 | 2018-07-24 | Rai Strategic Holdings, Inc. | Spent cartridge detection method and system for an electronic smoking article |
US20140261486A1 (en) * | 2013-03-12 | 2014-09-18 | R.J. Reynolds Tobacco Company | Electronic smoking article having a vapor-enhancing apparatus and associated method |
US9918495B2 (en) | 2014-02-28 | 2018-03-20 | Rai Strategic Holdings, Inc. | Atomizer for an aerosol delivery device and related input, aerosol production assembly, cartridge, and method |
US9277770B2 (en) | 2013-03-14 | 2016-03-08 | R. J. Reynolds Tobacco Company | Atomizer for an aerosol delivery device formed from a continuously extending wire and related input, cartridge, and method |
AR095306A1 (es) * | 2013-03-15 | 2015-10-07 | Philip Morris Products Sa | Sistema generador de aerosol con calor diferencial |
US10279934B2 (en) | 2013-03-15 | 2019-05-07 | Juul Labs, Inc. | Fillable vaporizer cartridge and method of filling |
US9609893B2 (en) | 2013-03-15 | 2017-04-04 | Rai Strategic Holdings, Inc. | Cartridge and control body of an aerosol delivery device including anti-rotation mechanism and related method |
US9423152B2 (en) | 2013-03-15 | 2016-08-23 | R. J. Reynolds Tobacco Company | Heating control arrangement for an electronic smoking article and associated system and method |
US9220302B2 (en) | 2013-03-15 | 2015-12-29 | R.J. Reynolds Tobacco Company | Cartridge for an aerosol delivery device and method for assembling a cartridge for a smoking article |
US9491974B2 (en) | 2013-03-15 | 2016-11-15 | Rai Strategic Holdings, Inc. | Heating elements formed from a sheet of a material and inputs and methods for the production of atomizers |
CN103202536B (zh) * | 2013-04-16 | 2015-10-21 | 湖北中烟工业有限责任公司 | 烟斗式电吸烟系统 |
US11229239B2 (en) | 2013-07-19 | 2022-01-25 | Rai Strategic Holdings, Inc. | Electronic smoking article with haptic feedback |
US10172387B2 (en) | 2013-08-28 | 2019-01-08 | Rai Strategic Holdings, Inc. | Carbon conductive substrate for electronic smoking article |
GB2518598B (en) | 2013-08-30 | 2016-06-01 | Nicoventures Holdings Ltd | Apparatus with battery power control |
US10194693B2 (en) | 2013-09-20 | 2019-02-05 | Fontem Holdings 1 B.V. | Aerosol generating device |
GB201318055D0 (en) | 2013-10-11 | 2013-11-27 | British American Tobacco Co | Additive Releasing Materials |
US10292424B2 (en) | 2013-10-31 | 2019-05-21 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a pressure-based aerosol delivery mechanism |
BE1022113B1 (fr) * | 2013-11-08 | 2016-02-16 | Serenity Sa | Cigarette electronique. |
US9839237B2 (en) | 2013-11-22 | 2017-12-12 | Rai Strategic Holdings, Inc. | Reservoir housing for an electronic smoking article |
WO2015092749A1 (fr) | 2013-12-20 | 2015-06-25 | Philip Morris Products, S.A. | Système de distribution d'arôme en zéolite encapsulée de cire, pour du tabac |
WO2015092748A1 (fr) * | 2013-12-20 | 2015-06-25 | Philip Morris Products, S.A. | Système de distribution d'arôme encapsulé dans de la cire pour du tabac |
US10076139B2 (en) | 2013-12-23 | 2018-09-18 | Juul Labs, Inc. | Vaporizer apparatus |
US20160366947A1 (en) | 2013-12-23 | 2016-12-22 | James Monsees | Vaporizer apparatus |
US10058129B2 (en) | 2013-12-23 | 2018-08-28 | Juul Labs, Inc. | Vaporization device systems and methods |
USD825102S1 (en) | 2016-07-28 | 2018-08-07 | Juul Labs, Inc. | Vaporizer device with cartridge |
ES2903145T3 (es) | 2013-12-23 | 2022-03-31 | Juul Labs Int Inc | Sistemas y métodos de dispositivo de vaporización |
USD842536S1 (en) | 2016-07-28 | 2019-03-05 | Juul Labs, Inc. | Vaporizer cartridge |
US10159282B2 (en) | 2013-12-23 | 2018-12-25 | Juul Labs, Inc. | Cartridge for use with a vaporizer device |
SG11201605138TA (en) * | 2013-12-31 | 2016-07-28 | Philip Morris Products Sa | Smoking article with dual additive delivery system |
US9974334B2 (en) | 2014-01-17 | 2018-05-22 | Rai Strategic Holdings, Inc. | Electronic smoking article with improved storage of aerosol precursor compositions |
CN103750535B (zh) * | 2014-01-22 | 2015-12-02 | 红云红河烟草(集团)有限责任公司 | 一种加热非燃烧型卷烟烟块的制备方法 |
AU2015210863B2 (en) * | 2014-01-31 | 2019-11-14 | Cannakorp, Inc. | Methods and apparatus for producing herbal vapor |
US10575558B2 (en) | 2014-02-03 | 2020-03-03 | Rai Strategic Holdings, Inc. | Aerosol delivery device comprising multiple outer bodies and related assembly method |
US9451791B2 (en) | 2014-02-05 | 2016-09-27 | Rai Strategic Holdings, Inc. | Aerosol delivery device with an illuminated outer surface and related method |
US20150224268A1 (en) | 2014-02-07 | 2015-08-13 | R.J. Reynolds Tobacco Company | Charging Accessory Device for an Aerosol Delivery Device and Related System, Method, Apparatus, and Computer Program Product for Providing Interactive Services for Aerosol Delivery Devices |
US9833019B2 (en) | 2014-02-13 | 2017-12-05 | Rai Strategic Holdings, Inc. | Method for assembling a cartridge for a smoking article |
US9839238B2 (en) | 2014-02-28 | 2017-12-12 | Rai Strategic Holdings, Inc. | Control body for an electronic smoking article |
US9597466B2 (en) | 2014-03-12 | 2017-03-21 | R. J. Reynolds Tobacco Company | Aerosol delivery system and related method, apparatus, and computer program product for providing control information to an aerosol delivery device via a cartridge |
US11696604B2 (en) | 2014-03-13 | 2023-07-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device and related method and computer program product for controlling an aerosol delivery device based on input characteristics |
US9877510B2 (en) | 2014-04-04 | 2018-01-30 | Rai Strategic Holdings, Inc. | Sensor for an aerosol delivery device |
US9924741B2 (en) | 2014-05-05 | 2018-03-27 | Rai Strategic Holdings, Inc. | Method of preparing an aerosol delivery device |
US9955726B2 (en) | 2014-05-23 | 2018-05-01 | Rai Strategic Holdings, Inc. | Sealed cartridge for an aerosol delivery device and related assembly method |
US9421793B2 (en) * | 2014-06-26 | 2016-08-23 | Cellresin Technologies, Llc | Electrostatic printing of cyclodextrin compositions |
GB2527597B (en) * | 2014-06-27 | 2016-11-23 | Relco Induction Dev Ltd | Electronic Vapour Inhalers |
US10888119B2 (en) | 2014-07-10 | 2021-01-12 | Rai Strategic Holdings, Inc. | System and related methods, apparatuses, and computer program products for controlling operation of a device based on a read request |
PT3166427T (pt) | 2014-07-11 | 2019-07-26 | Philip Morris Products Sa | Cartucho de formação de aerossol com folha protetora |
US10058123B2 (en) | 2014-07-11 | 2018-08-28 | R. J. Reynolds Tobacco Company | Heater for an aerosol delivery device and methods of formation thereof |
CN105725263A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 葡萄风味的电子烟液的制备方法 |
CN105725262A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 葡萄风味的电子烟液及其制备方法 |
CN105725261A (zh) * | 2014-07-28 | 2016-07-06 | 邹玉华 | 一种葡萄风味的电子烟液及其制备方法 |
CN106572698B (zh) * | 2014-08-07 | 2020-09-04 | 日本烟草产业株式会社 | 带过滤嘴香烟 |
US9609895B2 (en) | 2014-08-21 | 2017-04-04 | Rai Strategic Holdings, Inc. | System and related methods, apparatuses, and computer program products for testing components of an aerosol delivery device |
US9913493B2 (en) | 2014-08-21 | 2018-03-13 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a moveable cartridge and related assembly method |
US10765144B2 (en) | 2014-08-21 | 2020-09-08 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a moveable cartridge and related assembly method |
US11051554B2 (en) | 2014-11-12 | 2021-07-06 | Rai Strategic Holdings, Inc. | MEMS-based sensor for an aerosol delivery device |
CN107427067B (zh) | 2014-12-05 | 2020-10-23 | 尤尔实验室有限公司 | 校正剂量控制 |
US10500600B2 (en) | 2014-12-09 | 2019-12-10 | Rai Strategic Holdings, Inc. | Gesture recognition user interface for an aerosol delivery device |
GB201501429D0 (en) * | 2015-01-28 | 2015-03-11 | British American Tobacco Co | Apparatus for heating aerosol generating material |
US10321711B2 (en) | 2015-01-29 | 2019-06-18 | Rai Strategic Holdings, Inc. | Proximity detection for an aerosol delivery device |
MX2017010778A (es) | 2015-02-27 | 2017-11-28 | Philip Morris Products Sa | Ajuste de la rtd con control de retroalimentacion para un dispositivo generador de aerosol. |
US10027016B2 (en) | 2015-03-04 | 2018-07-17 | Rai Strategic Holdings Inc. | Antenna for an aerosol delivery device |
US9980516B2 (en) | 2015-03-09 | 2018-05-29 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a wave guide and related method |
US10172388B2 (en) | 2015-03-10 | 2019-01-08 | Rai Strategic Holdings, Inc. | Aerosol delivery device with microfluidic delivery component |
GB201505595D0 (en) | 2015-03-31 | 2015-05-13 | British American Tobacco Co | Cartridge for use with apparatus for heating smokeable material |
GB201505597D0 (en) | 2015-03-31 | 2015-05-13 | British American Tobacco Co | Article for use with apparatus for heating smokable material |
US11000069B2 (en) | 2015-05-15 | 2021-05-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device and methods of formation thereof |
US10238145B2 (en) | 2015-05-19 | 2019-03-26 | Rai Strategic Holdings, Inc. | Assembly substation for assembling a cartridge for a smoking article |
GB201511358D0 (en) * | 2015-06-29 | 2015-08-12 | Nicoventures Holdings Ltd | Electronic aerosol provision systems |
CN104983073A (zh) * | 2015-07-07 | 2015-10-21 | 深圳市赛尔美电子科技有限公司 | 一种卷烟蒸馏装置 |
US11504489B2 (en) | 2015-07-17 | 2022-11-22 | Rai Strategic Holdings, Inc. | Contained liquid system for refilling aerosol delivery devices |
CN105001988B (zh) * | 2015-07-17 | 2018-07-24 | 云南中烟工业有限责任公司 | 一种三层夹心结构香料缓释滤嘴添加剂的制备装置及其应用方法 |
US10966460B2 (en) | 2015-07-17 | 2021-04-06 | Rai Strategic Holdings, Inc. | Load-based detection of an aerosol delivery device in an assembled arrangement |
US11033054B2 (en) | 2015-07-24 | 2021-06-15 | Rai Strategic Holdings, Inc. | Radio-frequency identification (RFID) authentication system for aerosol delivery devices |
US11134544B2 (en) | 2015-07-24 | 2021-09-28 | Rai Strategic Holdings, Inc. | Aerosol delivery device with radiant heating |
US10206429B2 (en) | 2015-07-24 | 2019-02-19 | Rai Strategic Holdings, Inc. | Aerosol delivery device with radiant heating |
US10015987B2 (en) | 2015-07-24 | 2018-07-10 | Rai Strategic Holdings Inc. | Trigger-based wireless broadcasting for aerosol delivery devices |
PL3135138T3 (pl) | 2015-08-28 | 2020-05-18 | Fontem Holdings 1 B.V. | Elektroniczne urządzenie do palenia |
US11924930B2 (en) | 2015-08-31 | 2024-03-05 | Nicoventures Trading Limited | Article for use with apparatus for heating smokable material |
US20170055583A1 (en) * | 2015-08-31 | 2017-03-02 | British American Tobacco (Investments) Limited | Apparatus for heating smokable material |
US10034494B2 (en) | 2015-09-15 | 2018-07-31 | Rai Strategic Holdings, Inc. | Reservoir for aerosol delivery devices |
JP2018533916A (ja) * | 2015-09-16 | 2018-11-22 | アレクサンドラ ディルマン | 電子タバコによって供給される気化した液体の流れを処理するための方法および放出装置、および添加組成物を含有する気化した液体の経口摂取のための電子タバコ |
US10058125B2 (en) | 2015-10-13 | 2018-08-28 | Rai Strategic Holdings, Inc. | Method for assembling an aerosol delivery device |
US20170112194A1 (en) | 2015-10-21 | 2017-04-27 | Rai Strategic Holdings, Inc. | Rechargeable lithium-ion capacitor for an aerosol delivery device |
US10582726B2 (en) | 2015-10-21 | 2020-03-10 | Rai Strategic Holdings, Inc. | Induction charging for an aerosol delivery device |
US10918134B2 (en) | 2015-10-21 | 2021-02-16 | Rai Strategic Holdings, Inc. | Power supply for an aerosol delivery device |
US20170119046A1 (en) | 2015-10-30 | 2017-05-04 | British American Tobacco (Investments) Limited | Apparatus for Heating Smokable Material |
US10201187B2 (en) | 2015-11-02 | 2019-02-12 | Rai Strategic Holdings, Inc. | User interface for an aerosol delivery device |
KR102032708B1 (ko) * | 2015-11-05 | 2019-10-17 | 필립모리스 프로덕츠 에스.에이. | 휘발성 물질의 전달이 개선된 균질화 담배 재료 |
US10820630B2 (en) | 2015-11-06 | 2020-11-03 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a wirelessly-heated atomizer and related method |
EP4292454A3 (fr) * | 2015-11-24 | 2024-01-17 | R.J. Reynolds Tobacco Company | Système de distribution d'aérosol à alimentation électrique |
US10440992B2 (en) | 2015-12-07 | 2019-10-15 | Rai Strategic Holdings, Inc. | Motion sensing for an aerosol delivery device |
US9955733B2 (en) | 2015-12-07 | 2018-05-01 | Rai Strategic Holdings, Inc. | Camera for an aerosol delivery device |
US11291252B2 (en) | 2015-12-18 | 2022-04-05 | Rai Strategic Holdings, Inc. | Proximity sensing for an aerosol delivery device |
US10092036B2 (en) | 2015-12-28 | 2018-10-09 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a housing and a coupler |
US10051891B2 (en) | 2016-01-05 | 2018-08-21 | Rai Strategic Holdings, Inc. | Capacitive sensing input device for an aerosol delivery device |
US10194694B2 (en) | 2016-01-05 | 2019-02-05 | Rai Strategic Holdings, Inc. | Aerosol delivery device with improved fluid transport |
US10258086B2 (en) | 2016-01-12 | 2019-04-16 | Rai Strategic Holdings, Inc. | Hall effect current sensor for an aerosol delivery device |
US10104912B2 (en) | 2016-01-20 | 2018-10-23 | Rai Strategic Holdings, Inc. | Control for an induction-based aerosol delivery device |
US10015989B2 (en) | 2016-01-27 | 2018-07-10 | Rai Strategic Holdings, Inc. | One-way valve for refilling an aerosol delivery device |
MX2018009703A (es) | 2016-02-11 | 2019-07-08 | Juul Labs Inc | Cartuchos de fijacion segura para dispositivos vaporizadores. |
SG11201806793TA (en) | 2016-02-11 | 2018-09-27 | Juul Labs Inc | Fillable vaporizer cartridge and method of filling |
US11412781B2 (en) | 2016-02-12 | 2022-08-16 | Rai Strategic Holdings, Inc. | Adapters for refilling an aerosol delivery device |
US9936733B2 (en) | 2016-03-09 | 2018-04-10 | Rai Strategic Holdings, Inc. | Accessory configured to charge an aerosol delivery device and related method |
US10405582B2 (en) | 2016-03-10 | 2019-09-10 | Pax Labs, Inc. | Vaporization device with lip sensing |
US11207478B2 (en) | 2016-03-25 | 2021-12-28 | Rai Strategic Holdings, Inc. | Aerosol production assembly including surface with micro-pattern |
US10334880B2 (en) | 2016-03-25 | 2019-07-02 | Rai Strategic Holdings, Inc. | Aerosol delivery device including connector comprising extension and receptacle |
US20170280769A1 (en) * | 2016-04-04 | 2017-10-05 | Altria Client Services Llc | Electronic vaping device and kit |
US10333339B2 (en) | 2016-04-12 | 2019-06-25 | Rai Strategic Holdings, Inc. | Charger for an aerosol delivery device |
US10945462B2 (en) | 2016-04-12 | 2021-03-16 | Rai Strategic Holdings, Inc. | Detachable power source for an aerosol delivery device |
US10028534B2 (en) | 2016-04-20 | 2018-07-24 | Rai Strategic Holdings, Inc. | Aerosol delivery device, and associated apparatus and method of formation thereof |
US10405579B2 (en) | 2016-04-29 | 2019-09-10 | Rai Strategic Holdings, Inc. | Methods for assembling a cartridge for an aerosol delivery device, and associated systems and apparatuses |
GB201608947D0 (en) * | 2016-05-20 | 2016-07-06 | British American Tobacco Co | Consumable for aerosol generating device |
USD849996S1 (en) | 2016-06-16 | 2019-05-28 | Pax Labs, Inc. | Vaporizer cartridge |
US10959458B2 (en) | 2016-06-20 | 2021-03-30 | Rai Strategic Holdings, Inc. | Aerosol delivery device including an electrical generator assembly |
USD851830S1 (en) | 2016-06-23 | 2019-06-18 | Pax Labs, Inc. | Combined vaporizer tamp and pick tool |
USD836541S1 (en) | 2016-06-23 | 2018-12-25 | Pax Labs, Inc. | Charging device |
CN105876855A (zh) * | 2016-07-06 | 2016-08-24 | 南通烟滤嘴有限责任公司 | 含可自溶胶囊的滤棒及其滤嘴 |
US10085485B2 (en) | 2016-07-06 | 2018-10-02 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a reservoir housing and a vaporizer assembly |
US10405581B2 (en) | 2016-07-08 | 2019-09-10 | Rai Strategic Holdings, Inc. | Gas sensing for an aerosol delivery device |
US10231485B2 (en) | 2016-07-08 | 2019-03-19 | Rai Strategic Holdings, Inc. | Radio frequency to direct current converter for an aerosol delivery device |
US10463078B2 (en) | 2016-07-08 | 2019-11-05 | Rai Strategic Holdings, Inc. | Aerosol delivery device with condensing and non-condensing vaporization |
US10617151B2 (en) | 2016-07-21 | 2020-04-14 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a liquid transport element comprising a porous monolith and related method |
US10602775B2 (en) | 2016-07-21 | 2020-03-31 | Rai Strategic Holdings, Inc. | Aerosol delivery device with a unitary reservoir and liquid transport element comprising a porous monolith and related method |
US11019847B2 (en) | 2016-07-28 | 2021-06-01 | Rai Strategic Holdings, Inc. | Aerosol delivery devices including a selector and related methods |
US10765146B2 (en) | 2016-08-08 | 2020-09-08 | Rai Strategic Holdings, Inc. | Boost converter for an aerosol delivery device |
US11937647B2 (en) | 2016-09-09 | 2024-03-26 | Rai Strategic Holdings, Inc. | Fluidic control for an aerosol delivery device |
US10080387B2 (en) | 2016-09-23 | 2018-09-25 | Rai Strategic Holdings, Inc. | Aerosol delivery device with replaceable wick and heater assembly |
US10477896B2 (en) | 2016-10-12 | 2019-11-19 | Rai Strategic Holdings, Inc. | Photodetector for measuring aerosol precursor composition in an aerosol delivery device |
US10492530B2 (en) | 2016-11-15 | 2019-12-03 | Rai Strategic Holdings, Inc. | Two-wire authentication system for an aerosol delivery device |
US9864947B1 (en) | 2016-11-15 | 2018-01-09 | Rai Strategic Holdings, Inc. | Near field communication for a tobacco-based article or package therefor |
US10524508B2 (en) | 2016-11-15 | 2020-01-07 | Rai Strategic Holdings, Inc. | Induction-based aerosol delivery device |
US11103012B2 (en) | 2016-11-17 | 2021-08-31 | Rai Strategic Holdings, Inc. | Satellite navigation for an aerosol delivery device |
US10206431B2 (en) | 2016-11-18 | 2019-02-19 | Rai Strategic Holdings, Inc. | Charger for an aerosol delivery device |
US10524509B2 (en) | 2016-11-18 | 2020-01-07 | Rai Strategic Holdings, Inc. | Pressure sensing for an aerosol delivery device |
US10653183B2 (en) | 2016-11-18 | 2020-05-19 | Rai Strategic Holdings, Inc. | Power source for an aerosol delivery device |
US10172392B2 (en) | 2016-11-18 | 2019-01-08 | Rai Strategic Holdings, Inc. | Humidity sensing for an aerosol delivery device |
US10537137B2 (en) | 2016-11-22 | 2020-01-21 | Rai Strategic Holdings, Inc. | Rechargeable lithium-ion battery for an aerosol delivery device |
US11013266B2 (en) | 2016-12-09 | 2021-05-25 | Rai Strategic Holdings, Inc. | Aerosol delivery device sensory system including an infrared sensor and related method |
WO2018112768A1 (fr) * | 2016-12-20 | 2018-06-28 | 惠州市吉瑞科技有限公司深圳分公司 | Élément de gaine de vaporisateur |
US9980522B1 (en) * | 2016-12-30 | 2018-05-29 | National Concessions Group Inc. | Self-locking cartridge |
GB201700136D0 (en) | 2017-01-05 | 2017-02-22 | British American Tobacco Investments Ltd | Aerosol generating device and article |
GB201700620D0 (en) | 2017-01-13 | 2017-03-01 | British American Tobacco Investments Ltd | Aerosol generating device and article |
GB201700812D0 (en) | 2017-01-17 | 2017-03-01 | British American Tobacco Investments Ltd | Apparatus for heating smokable material |
US10517326B2 (en) | 2017-01-27 | 2019-12-31 | Rai Strategic Holdings, Inc. | Secondary battery for an aerosol delivery device |
US10827783B2 (en) | 2017-02-27 | 2020-11-10 | Rai Strategic Holdings, Inc. | Digital compass for an aerosol delivery device |
US10314340B2 (en) | 2017-04-21 | 2019-06-11 | Rai Strategic Holdings, Inc. | Refillable aerosol delivery device and related method |
US11297876B2 (en) | 2017-05-17 | 2022-04-12 | Rai Strategic Holdings, Inc. | Aerosol delivery device |
US11589621B2 (en) | 2017-05-23 | 2023-02-28 | Rai Strategic Holdings, Inc. | Heart rate monitor for an aerosol delivery device |
US10517330B2 (en) | 2017-05-23 | 2019-12-31 | RAI Stategic Holdings, Inc. | Heart rate monitor for an aerosol delivery device |
CN107057854A (zh) * | 2017-05-24 | 2017-08-18 | 昆明理工大学 | 一种烟用香精香料的微囊制备及在卷烟嘴棒中的应用 |
US10499686B2 (en) | 2017-06-23 | 2019-12-10 | Altria Client Services Llc | Smoking article filter with flavorant delivery system |
US10842197B2 (en) | 2017-07-12 | 2020-11-24 | Rai Strategic Holdings, Inc. | Detachable container for aerosol delivery having pierceable membrane |
US10349674B2 (en) | 2017-07-17 | 2019-07-16 | Rai Strategic Holdings, Inc. | No-heat, no-burn smoking article |
US11337456B2 (en) | 2017-07-17 | 2022-05-24 | Rai Strategic Holdings, Inc. | Video analytics camera system for an aerosol delivery device |
CN107252672B (zh) * | 2017-07-21 | 2021-02-02 | 云南中烟工业有限责任公司 | 一种改性磷铝分子筛滤嘴吸附材料及其制备方法与应用 |
USD887632S1 (en) | 2017-09-14 | 2020-06-16 | Pax Labs, Inc. | Vaporizer cartridge |
US10505383B2 (en) | 2017-09-19 | 2019-12-10 | Rai Strategic Holdings, Inc. | Intelligent charger for an aerosol delivery device |
US11039645B2 (en) | 2017-09-19 | 2021-06-22 | Rai Strategic Holdings, Inc. | Differential pressure sensor for an aerosol delivery device |
US10660370B2 (en) | 2017-10-12 | 2020-05-26 | Rai Strategic Holdings, Inc. | Aerosol delivery device including a control body, an atomizer body, and a cartridge and related methods |
US10517332B2 (en) | 2017-10-31 | 2019-12-31 | Rai Strategic Holdings, Inc. | Induction heated aerosol delivery device |
GB201720338D0 (en) | 2017-12-06 | 2018-01-17 | British American Tobacco Investments Ltd | Component for an aerosol-generating apparatus |
US10806181B2 (en) | 2017-12-08 | 2020-10-20 | Rai Strategic Holdings, Inc. | Quasi-resonant flyback converter for an induction-based aerosol delivery device |
GB201721821D0 (en) | 2017-12-22 | 2018-02-07 | Nicoventures Holdings Ltd | Electronic aerosol provision system |
EP3727048A1 (fr) * | 2017-12-22 | 2020-10-28 | G.D. S.p.A | Sous-unité d'un article à fumer et son procédé de fabrication |
US10555558B2 (en) | 2017-12-29 | 2020-02-11 | Rai Strategic Holdings, Inc. | Aerosol delivery device providing flavor control |
CN109998171A (zh) * | 2018-01-05 | 2019-07-12 | 深圳御烟实业有限公司 | 一种气溶胶生成制品及系统 |
US11019850B2 (en) | 2018-02-26 | 2021-06-01 | Rai Strategic Holdings, Inc. | Heat conducting substrate for electrically heated aerosol delivery device |
KR20210009334A (ko) * | 2018-05-17 | 2021-01-26 | 가부시키가이샤 도아 산교 | 방향 카트리지 |
GB201808526D0 (en) * | 2018-05-24 | 2018-07-11 | Nicoventures Trading Ltd | Aerosol Generation |
GB201812497D0 (en) | 2018-07-31 | 2018-09-12 | Nicoventures Holdings Ltd | Aerosol generation |
GB201812506D0 (en) * | 2018-07-31 | 2018-09-12 | Nicoventures Holdings Ltd | Aerosol generation |
CN108968154A (zh) * | 2018-08-01 | 2018-12-11 | 声海电子(深圳)有限公司 | 一种香烟用具及其工作方法 |
CN108813713B (zh) * | 2018-08-07 | 2024-05-03 | 四川三联新材料有限公司 | 一种加热式发烟烟支及加热式发烟制品 |
US11432581B2 (en) | 2018-09-07 | 2022-09-06 | Altria Client Services Llc | Capsule containing a matrix, device with the matrix, and method of forming the matrix |
US11395507B2 (en) * | 2018-09-07 | 2022-07-26 | Altria Client Services Llc | Filter for an e-vaping device, e-vaping device with the filter, and method of forming the filter |
WO2020079845A1 (fr) * | 2018-10-19 | 2020-04-23 | 株式会社 東亜産業 | Composition de générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée, générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée utilisant la composition, cartouche d'aspiration de substance volatile chauffée utilisant le générateur de parfum chauffé, et procédé de production d'un générateur de parfum chauffé pour cartouche d'aspiration de substance volatile chauffée |
WO2020089120A1 (fr) * | 2018-10-29 | 2020-05-07 | Nerudia Limited | Consommable de substitution à l'acte de fumer |
GB201817860D0 (en) * | 2018-11-01 | 2018-12-19 | Nicoventures Trading Ltd | Aerosolised formulation |
US20200221785A1 (en) * | 2019-01-10 | 2020-07-16 | Altria Client Services Llc | Vaping device with insert |
CN109588787A (zh) * | 2019-01-22 | 2019-04-09 | 云南中烟工业有限责任公司 | 一种细支电子烟及其制备方法 |
EP3915406A4 (fr) | 2019-01-25 | 2022-11-02 | Japan Tobacco Inc. | Filtre pour article à fumer |
WO2020153491A1 (fr) | 2019-01-25 | 2020-07-30 | 日本たばこ産業株式会社 | Filtre pour article à fumer |
CN110771945A (zh) * | 2019-04-01 | 2020-02-11 | 株式会社东亚产业 | 受热芳香发生体组成物、使用组成物的受热芳香发生体及使用受热芳香发生体的熏香芯 |
CN117837794A (zh) * | 2019-04-08 | 2024-04-09 | 菲利普莫里斯生产公司 | 气溶胶生成膜 |
JP2020065534A (ja) | 2019-05-08 | 2020-04-30 | 株式会社 東亜産業 | 加熱式揮発物吸引カートリッジ用被加熱芳香発生体組成物、その組成物を用いた加熱式揮発物吸引カートリッジ用被加熱芳香発生体、その被加熱芳香発生体を用いた加熱式揮発物吸引カートリッジ、及び、その加熱式揮発物吸引カートリッジ用被加熱芳香発生体の製造方法 |
JP2020167989A (ja) * | 2019-05-22 | 2020-10-15 | 株式会社 東亜産業 | スティック型被加熱芳香発生体組成物、その組成物を用いたスティック型被加熱芳香発生体、及び、そのスティック型被加熱芳香発生体を用いた喫煙カートリッジ |
KR102228286B1 (ko) * | 2019-12-09 | 2021-03-17 | 가부시키가이샤 도아 산교 | 방향(芳香) 카트리지 |
US20220295882A1 (en) * | 2019-12-09 | 2022-09-22 | Future Technology Co., Ltd. | Aroma cartridge |
GB201918980D0 (en) * | 2019-12-20 | 2020-02-05 | Nicoventures Trading Ltd | Article for use in an aerosol provision system |
GB201919104D0 (en) * | 2019-12-20 | 2020-02-05 | Nicoventures Trading Ltd | An article for use in a non-combustible aerosol provision system |
US11712059B2 (en) | 2020-02-24 | 2023-08-01 | Nicoventures Trading Limited | Beaded tobacco material and related method of manufacture |
WO2021177023A1 (fr) * | 2020-03-04 | 2021-09-10 | 日本たばこ産業株式会社 | Élément constitutif porteur de parfum de produit de tabac, produit de tabac et son procédé de production |
US12016369B2 (en) | 2020-04-14 | 2024-06-25 | Nicoventures Trading Limited | Regenerated cellulose substrate for aerosol delivery device |
CN112438420B (zh) * | 2020-12-03 | 2022-08-30 | 山东瑞博斯烟草有限公司 | 一种降低造纸法烟草薄片刺激性的方法 |
US11789476B2 (en) | 2021-01-18 | 2023-10-17 | Altria Client Services Llc | Heat-not-burn (HNB) aerosol-generating devices including intra-draw heater control, and methods of controlling a heater |
JP7084060B2 (ja) * | 2021-03-10 | 2022-06-14 | Future Technology株式会社 | 芳香カートリッジ |
CN113058557B (zh) * | 2021-03-15 | 2024-09-24 | 云南中烟工业有限责任公司 | 一种N掺杂MOF(Fe)吸附剂及其制备方法与应用 |
EP4404776A1 (fr) * | 2021-09-20 | 2024-07-31 | Imperial Tobacco Limited | Élément de distribution d'arôme et dispositif de substitution d'article à fumer |
CN118401127A (zh) * | 2021-12-14 | 2024-07-26 | 日本烟草产业株式会社 | 非燃烧加热型烟杆 |
Family Cites Families (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3006347A (en) | 1959-09-21 | 1961-10-31 | Reynolds Tobacco Co R | Additives for smoking tobacco products |
NL282359A (fr) * | 1961-09-19 | |||
US3344796A (en) | 1965-05-17 | 1967-10-03 | Dai Nippon Seito Kabushiki Kai | Flavored tobacco smoke filter containing higher fatty acid ester of sucrose |
US3426011A (en) * | 1967-02-13 | 1969-02-04 | Corn Products Co | Cyclodextrins with anionic properties |
US3623489A (en) * | 1969-11-18 | 1971-11-30 | Int Flavors & Fragrances Inc | Tobacco smoking article |
BE791758A (fr) * | 1971-11-24 | 1973-05-22 | Olin Corp | Enveloppe chargee de carbone pour article a fumer et article a fumer presentant une telle enveloppe |
US3972335A (en) | 1972-09-20 | 1976-08-03 | Calgon Corporation | Mentholated cigarette filter |
US4068671A (en) * | 1975-07-25 | 1978-01-17 | Amf Incorporated | Nicotine removal process |
US4195645A (en) * | 1978-03-13 | 1980-04-01 | Celanese Corporation | Tobacco-substitute smoking material |
US4715390A (en) * | 1985-11-19 | 1987-12-29 | Philip Morris Incorporated | Matrix entrapment of flavorings for smoking articles |
US4893639A (en) * | 1986-07-22 | 1990-01-16 | R. J. Reynolds Tobacco Company | Densified particulate materials for smoking products and process for preparing the same |
US5137034A (en) | 1988-05-16 | 1992-08-11 | R. J. Reynolds Tobacco Company | Smoking article with improved means for delivering flavorants |
US4991605A (en) * | 1989-04-24 | 1991-02-12 | Philip Morris Incorporated | Container for additive materials for smoking articles |
US5388594A (en) * | 1991-03-11 | 1995-02-14 | Philip Morris Incorporated | Electrical smoking system for delivering flavors and method for making same |
US5144964A (en) * | 1991-03-14 | 1992-09-08 | Philip Morris Incorporated | Smoking compositions containing a flavorant-release additive |
US5144946A (en) * | 1991-08-05 | 1992-09-08 | Siemens Pacesetter, Inc. | Combined pacemaker substrate and electrical interconnect and method of assembly |
US5692525A (en) | 1992-09-11 | 1997-12-02 | Philip Morris Incorporated | Cigarette for electrical smoking system |
US5666976A (en) * | 1992-09-11 | 1997-09-16 | Philip Morris Incorporated | Cigarette and method of manufacturing cigarette for electrical smoking system |
US5692526A (en) * | 1992-09-11 | 1997-12-02 | Philip Morris Incorporated | Cigarette for electrical smoking system |
US5499636A (en) | 1992-09-11 | 1996-03-19 | Philip Morris Incorporated | Cigarette for electrical smoking system |
US5845649A (en) * | 1994-01-26 | 1998-12-08 | Japan Tobacco Inc. | Flavor-tasting article |
JPH08322538A (ja) * | 1995-05-30 | 1996-12-10 | Japan Tobacco Inc | シガレット用フィルタ |
US6056974A (en) * | 1996-04-26 | 2000-05-02 | Shionogi & Co., Ltd. | Rapid-release S1452 tablets |
CN1113621C (zh) * | 1996-06-17 | 2003-07-09 | 日本烟业产业株式会社 | 香味生成物和香味生成器 |
TR199900760T2 (xx) | 1996-10-09 | 1999-07-21 | Givaudan-Roure (International) S.A. | G�da veya t�t�n katk�s� boncuklar haz�rlama i�lemi. |
US6040560A (en) * | 1996-10-22 | 2000-03-21 | Philip Morris Incorporated | Power controller and method of operating an electrical smoking system |
JPH11178562A (ja) * | 1997-12-19 | 1999-07-06 | Japan Tobacco Inc | 非燃焼型香味発生品 |
JP2949114B1 (ja) * | 1998-08-04 | 1999-09-13 | 日本たばこ産業株式会社 | 電気式香味生成物品加熱制御装置 |
MY138902A (en) | 2000-04-20 | 2009-08-28 | Philip Morris Prod | "cigarette filters of shaped micro cavity fibers impregnated with flavorant materials" |
TWI249381B (en) * | 2001-02-22 | 2006-02-21 | Philip Morris Prod | Cigarette and filter with downstream flavor addition |
EP1441603A2 (fr) * | 2001-11-09 | 2004-08-04 | Vector Tobacco Inc. | Procede et composition pour additionner du menthol a des cigarettes comprenant un filtre au charbon |
MY135471A (en) * | 2002-01-09 | 2008-04-30 | Philip Morris Prod | Cigarette filter with beaded carbon |
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- 2003-10-30 WO PCT/US2003/034290 patent/WO2004041007A2/fr active Application Filing
- 2003-10-30 JP JP2004550175A patent/JP4889218B2/ja not_active Expired - Lifetime
- 2003-10-30 PL PL374939A patent/PL203915B1/pl unknown
- 2003-10-30 EP EP03776589.8A patent/EP1555898B1/fr not_active Expired - Lifetime
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- 2003-10-30 HU HUE03776589A patent/HUE026909T2/en unknown
- 2003-10-30 ES ES03776589.8T patent/ES2573479T3/es not_active Expired - Lifetime
- 2003-10-30 US US10/695,760 patent/US20040129280A1/en not_active Abandoned
- 2003-10-30 CA CA2502171A patent/CA2502171C/fr not_active Expired - Fee Related
- 2003-10-30 AU AU2003284199A patent/AU2003284199B2/en not_active Ceased
- 2003-10-30 EA EA200500746A patent/EA006569B1/ru not_active IP Right Cessation
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Also Published As
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---|---|
EP1555898A2 (fr) | 2005-07-27 |
UA90430C2 (uk) | 2010-04-26 |
PL203915B1 (pl) | 2009-11-30 |
HK1076013A1 (zh) | 2006-01-06 |
WO2004041007A2 (fr) | 2004-05-21 |
EP1555898A4 (fr) | 2012-08-29 |
BR0315829A (pt) | 2005-09-13 |
JP2006504431A (ja) | 2006-02-09 |
NO20052600L (no) | 2005-05-30 |
US20040129280A1 (en) | 2004-07-08 |
DK1555898T3 (en) | 2016-05-09 |
EA200500746A1 (ru) | 2005-08-25 |
MXPA05004683A (es) | 2005-08-18 |
NO338062B1 (no) | 2016-07-25 |
MA27484A1 (fr) | 2005-08-01 |
AU2003284199A1 (en) | 2004-06-07 |
CN1708241A (zh) | 2005-12-14 |
ES2573479T3 (es) | 2016-06-08 |
EA006569B1 (ru) | 2006-02-24 |
HUE026909T2 (en) | 2016-07-28 |
IL168310A (en) | 2013-09-30 |
CA2502171A1 (fr) | 2004-05-21 |
NO20052600D0 (no) | 2005-05-30 |
JP4889218B2 (ja) | 2012-03-07 |
PL374939A1 (en) | 2005-11-14 |
WO2004041007A3 (fr) | 2004-07-08 |
KR101072668B1 (ko) | 2011-10-11 |
ZA200502781B (en) | 2008-01-30 |
CA2502171C (fr) | 2013-01-15 |
AU2003284199B2 (en) | 2009-12-17 |
CN1317986C (zh) | 2007-05-30 |
KR20050072127A (ko) | 2005-07-08 |
EG23930A (en) | 2008-01-14 |
BR0315829B1 (pt) | 2014-07-15 |
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