EP1546060A2 - Suspensions - Google Patents
SuspensionsInfo
- Publication number
- EP1546060A2 EP1546060A2 EP03792403A EP03792403A EP1546060A2 EP 1546060 A2 EP1546060 A2 EP 1546060A2 EP 03792403 A EP03792403 A EP 03792403A EP 03792403 A EP03792403 A EP 03792403A EP 1546060 A2 EP1546060 A2 EP 1546060A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- suspensions
- aluminum sulfate
- weight
- bentonite
- setting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B22/00—Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
- C04B22/08—Acids or salts thereof
- C04B22/14—Acids or salts thereof containing sulfur in the anion, e.g. sulfides
- C04B22/142—Sulfates
- C04B22/148—Aluminium-sulfate
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
- C04B2111/00172—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite by the wet process
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
- C04B2111/1006—Absence of well-defined organic compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/10—Compositions or ingredients thereof characterised by the absence or the very low content of a specific material
- C04B2111/1025—Alkali-free or very low alkali-content materials
Definitions
- the present invention relates to suspensions, their preparation and their use to accelerate the setting and hardening of cement and mixtures containing it.
- Shotcrete has to set very quickly, e.g. to guarantee the highest level of security and smooth tunneling during tunnel construction.
- Setting accelerators are used for this purpose.
- Alkaline accelerators are highly caustic and therefore hazardous to health, they reduce the final strength of the concrete and force the shrinkage, which can lead to increased crack formation.
- the alkali metals of these accelerators can be washed out, which can lead to contamination of ground and drinking water and to the increased sintering of drainage.
- Aluminum sulfate and aluminum hydroxysulfates are based.
- Aluminum sulfate is well suited as a setting accelerator, although it is technically of great advantage to provide the setting accelerator in liquid form. Due to the low water solubility of aluminum sulfate of approximately 8% by weight as Al O 3 , large amounts of the aluminum sulfate solution would be necessary to achieve the above-mentioned
- the accelerators described above are offered both as powders and as liquids (solution or suspension), whereby in any case the liquid products are preferable to the powders because of their better meterability, the more homogeneous distribution and faster release of the active substance.
- EP 0 812 812 AI and US 5,935,318 describe an accelerating additive for cementitious compositions which contains aluminum sulfate, largely free of aluminum hydroxide, and at least one alkanolamine.
- the accelerating additive can also contain a stabilizer selected from polymer dispersions or sepiolite.
- EP 0 858 981 A1 describes a setting and hardening accelerator containing aluminum salt, preferably Al 2 (SO 4 ) 3; claimed, which is characterized in that it contains a) amorphous silica and b) an inorganic and / or organic thixotropic agent and / or an organic carbonic acid ester.
- This accelerator necessarily requires at least three components, using both organic and inorganic thickeners to keep the amorphous silica in suspension.
- Organic thickeners are described here by way of example, but bentonite is also mentioned as the inorganic thickener.
- the concentrations of the aluminum salts are also significantly below 8% by weight, so that relatively large amounts of the accelerating solution are necessary, which has a negative effect on the water / cement Ratio affects.
- the present invention was therefore based on the object of providing the market with a setting and hardening accelerator in liquid form which is free or almost free of COD-containing substances and has good effectiveness.
- suspensions which are characterized in that they contain aluminum sulfate in amounts of more than 8% by weight as Al 2 O 3 and suspended or dispersed bentonite in amounts of 1 to 7% by weight , In contrast to the prior art products cited above, these suspensions contain neither alkanolamines nor amorphous silica, nor organic thixotropic agents.
- suspensions is understood to mean systems which consist of several phases, one of which is continuous and at least one further is finely divided, the finely divided phase predominantly comprising solid particles with a particle size of less than 100 ⁇ m, preferably less than 70 ⁇ m.
- the suspensions are produced by a process which is characterized in that aluminum sulfate, which is partly in solid form, is stirred in the presence of bentonite in water at elevated temperatures, preferably at temperatures up to 100 ° C., so that a suspension is formed ,
- aluminum sulfate includes compounds of the formula
- the aluminum sulfate is used in an amount of more than 8% by weight to 15% by weight, in particular 10 to 12% by weight, based on Al O 3 .
- Ca, Ca / Na and Na bentonites are preferred as bentonites, which in
- Water are dispersible. In particular, an amount of 2 to 6% by weight is used.
- the suspensions are prepared by introducing water into a reactor equipped with a stirrer, stirring aluminum sulfate in solid form and bentonite and homogeneously suspending both components at room temperature, preferably at elevated temperature. A large proportion of the aluminum sulfate dissolves, the rest is later in suspension, the suspended portions being stabilized by bentonite with regard to sedimentation.
- a preferred method is characterized in that bentonite is suspended in an aluminum sulfate solution in a first step, and solid aluminum sulfate is added to this suspension in a second step, and this is then homogeneously suspended at elevated temperature.
- the temperature does not exceed 100 ° C.
- the suspension is prepared so that a
- Aluminum sulfate is stirred in as a solid material with high shear rate.
- the suspension is then heated to 70 ° C, a further 15 to 120 min. with the
- Toothed washer stirred and cooled.
- the end product has an aluminum sulfate content, expressed as Al O 3 , of over
- the suspensions are preferably used in the range from 1 to 15%, based on the binder.
- a commercially available suspension (Meyco SA 160, MBT - Switzerland) with an Al 2 O 3 content of 10.3% by weight and a COD content of 99 g / kg served as a comparison.
- the suspensions according to the invention have advantages over the comparison in the Vicat test.
- the content of amorphous silica must be at least 5% by weight.
- the setting accelerator can contain up to 5% by weight bentonite.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10238789A DE10238789B4 (de) | 2002-08-23 | 2002-08-23 | Verfahren zur Herstellung von Suspensionen und deren Verwendung |
DE10238789 | 2002-08-23 | ||
PCT/EP2003/009256 WO2004018380A2 (fr) | 2002-08-23 | 2003-08-21 | Suspensions |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1546060A2 true EP1546060A2 (fr) | 2005-06-29 |
Family
ID=31197303
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03792403A Ceased EP1546060A2 (fr) | 2002-08-23 | 2003-08-21 | Suspensions |
Country Status (5)
Country | Link |
---|---|
US (1) | US7470317B2 (fr) |
EP (1) | EP1546060A2 (fr) |
AU (1) | AU2003264081A1 (fr) |
DE (1) | DE10238789B4 (fr) |
WO (1) | WO2004018380A2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2248780A1 (fr) | 2009-05-06 | 2010-11-10 | BK Giulini GmbH | Accélérateur de prise et de durcissement |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1724246A1 (fr) * | 2005-05-18 | 2006-11-22 | I.C.R.S. Industrial Ceramic Reinforcement Solution S.r.L. | Adjuvant auxiliaire pour matériaux à base de ciment |
KR20100105868A (ko) * | 2008-01-11 | 2010-09-30 | 컨스트럭션 리서치 앤 테크놀로지 게엠베하 | 수성 가속제 혼합물 |
JP2014019623A (ja) * | 2012-07-20 | 2014-02-03 | Denki Kagaku Kogyo Kk | 懸濁型セメント急結剤及びそれを用いた急結セメントコンクリート |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0858981A1 (fr) | 1997-02-14 | 1998-08-19 | Sika AG, vorm. Kaspar Winkler & Co. | Accelerateur de durcissement pour ciment |
EP1167317A1 (fr) | 2000-06-21 | 2002-01-02 | Sika AG, vorm. Kaspar Winkler & Co. | Accelerateur de prise et de durcissement exempt de métaux alcalins |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4069062A (en) * | 1973-05-08 | 1978-01-17 | Sika Ag, Vormals Kaspar Winkler & Co. | Additive for mortar and concrete |
US4359339A (en) * | 1980-12-16 | 1982-11-16 | Nl Industries, Inc. | Bentonite clay and water soluble aluminum salt compositions |
SU956529A1 (ru) * | 1981-01-05 | 1982-09-07 | Волжский Филиал Всесоюзного Научно-Исследовательского Института Абразивов И Шлифования | Суспензи дл механической обработки металлов |
JP2598646B2 (ja) | 1987-08-13 | 1997-04-09 | 日本ピー・エム・シー株式会社 | ベントナイト粉末の分散方法 |
US4883536A (en) * | 1988-08-05 | 1989-11-28 | Aqualon Company | Suspension of water-soluble polymers in aqueous media containing dissolved salts |
CA2115390C (fr) * | 1993-03-22 | 1999-08-24 | Bharat B. Patel | Composition liquide constituee d'un aluminate metallique ou d'un promoteur de viscosite et d'un compose de magnesium, et methode d'utilisation de ladite composition |
DE4312290A1 (de) * | 1993-04-15 | 1994-10-20 | Degussa | Fäll- und Flockungsmittel |
DE4410728A1 (de) | 1994-03-28 | 1995-10-05 | Sued Chemie Ag | Hilfsmittel für mineralische Bindemittelsysteme |
AU723970B2 (en) * | 1996-06-14 | 2000-09-07 | Construction Research & Technology Gmbh | Concrete spraying additives |
EP0812812B1 (fr) | 1996-06-14 | 2003-01-29 | Mbt Holding Ag | Additif pour béton projeté |
JP3384547B2 (ja) | 1998-11-30 | 2003-03-10 | 電気化学工業株式会社 | ノロ低減剤 |
DE10029869C2 (de) * | 2000-06-16 | 2003-10-30 | Rex Ind Produkte Graf Von Rex | Faserfreies, nicht brennbares, geschäumtes Isolier- und Brandschutzmaterial und Verfahren zu seiner Herstellung |
-
2002
- 2002-08-23 DE DE10238789A patent/DE10238789B4/de not_active Expired - Fee Related
-
2003
- 2003-08-21 EP EP03792403A patent/EP1546060A2/fr not_active Ceased
- 2003-08-21 WO PCT/EP2003/009256 patent/WO2004018380A2/fr not_active Application Discontinuation
- 2003-08-21 US US10/528,798 patent/US7470317B2/en not_active Expired - Lifetime
- 2003-08-21 AU AU2003264081A patent/AU2003264081A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0858981A1 (fr) | 1997-02-14 | 1998-08-19 | Sika AG, vorm. Kaspar Winkler & Co. | Accelerateur de durcissement pour ciment |
EP1167317A1 (fr) | 2000-06-21 | 2002-01-02 | Sika AG, vorm. Kaspar Winkler & Co. | Accelerateur de prise et de durcissement exempt de métaux alcalins |
Non-Patent Citations (1)
Title |
---|
See also references of WO2004018380A3 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2248780A1 (fr) | 2009-05-06 | 2010-11-10 | BK Giulini GmbH | Accélérateur de prise et de durcissement |
Also Published As
Publication number | Publication date |
---|---|
US20060249055A1 (en) | 2006-11-09 |
AU2003264081A1 (en) | 2004-03-11 |
WO2004018380A3 (fr) | 2004-05-21 |
DE10238789B4 (de) | 2006-01-05 |
AU2003264081A8 (en) | 2004-03-11 |
DE10238789A1 (de) | 2004-03-04 |
US7470317B2 (en) | 2008-12-30 |
WO2004018380A2 (fr) | 2004-03-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
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17P | Request for examination filed |
Effective date: 20050323 |
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AK | Designated contracting states |
Kind code of ref document: A2 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR |
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AX | Request for extension of the european patent |
Extension state: AL LT LV MK |
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RIC1 | Information provided on ipc code assigned before grant |
Ipc: 7C 04B 22/02 A |
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TPAC | Observations filed by third parties |
Free format text: ORIGINAL CODE: EPIDOSNTIPA |
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RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: KURITA WATER INDUSTRIES LTD. |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R003 |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED |
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18R | Application refused |
Effective date: 20161015 |