EP1536065B1 - Papier antistatique et panneau de plancher - Google Patents

Papier antistatique et panneau de plancher Download PDF

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Publication number
EP1536065B1
EP1536065B1 EP04103947A EP04103947A EP1536065B1 EP 1536065 B1 EP1536065 B1 EP 1536065B1 EP 04103947 A EP04103947 A EP 04103947A EP 04103947 A EP04103947 A EP 04103947A EP 1536065 B1 EP1536065 B1 EP 1536065B1
Authority
EP
European Patent Office
Prior art keywords
paper
abrasion
panel
resistant particles
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP04103947A
Other languages
German (de)
English (en)
Other versions
EP1536065B8 (fr
EP1536065A1 (fr
Inventor
Dr. Leonhard Schitter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Interglarion Ltd
Original Assignee
Kaindl Flooring GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaindl Flooring GmbH filed Critical Kaindl Flooring GmbH
Priority to SI200431042T priority Critical patent/SI1536065T1/sl
Priority to PL04103947T priority patent/PL1536065T3/pl
Publication of EP1536065A1 publication Critical patent/EP1536065A1/fr
Application granted granted Critical
Publication of EP1536065B1 publication Critical patent/EP1536065B1/fr
Publication of EP1536065B8 publication Critical patent/EP1536065B8/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/22—Structures being applied on the surface by special manufacturing processes, e.g. in presses
    • D21H27/26—Structures being applied on the surface by special manufacturing processes, e.g. in presses characterised by the overlay sheet or the top layers of the structures
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F2290/00—Specially adapted covering, lining or flooring elements not otherwise provided for
    • E04F2290/04—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire
    • E04F2290/048—Specially adapted covering, lining or flooring elements not otherwise provided for for insulation or surface protection, e.g. against noise, impact or fire against static electricity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Definitions

  • the invention relates to antistatic floor panels having a support and attached thereto paper, which is usually printed and decorative paper, have.
  • a counter-pull preferably in the form of another paper, is applied below the support of such panels.
  • the panels have laterally coupling elements and can be assembled with or without glue, such as in the WO 01/94721 A1 described.
  • the decor paper may have applied abrasion resistant particles of corundum, alumina or silicon carbide to be suitable for a walk.
  • the abrasion-resistant particles are embedded in a resin matrix.
  • resins melamine resins are preferably used for cost reasons, which may be mixed with urea resins.
  • Methods for producing a decorative paper for floor panels are from the publications US-A-4,940,503 .
  • WO 00/44984 A1 such as WO 02/066265 A1 known.
  • the backing paper may be attached to the backing by means of a resin.
  • a resin As the resin, urea resin is preferred because less resistance to moisture is required on the underside of the panels. It can therefore be dispensed with expensive additives such as melamine resin.
  • HDF is currently preferred as a carrier material, since this material is dimensionally stable and A manufacturing process for such a plate is in the DE 20210718 U1 described.
  • the support for laminate floor panels may also consist of several layers of paper that are glued together, such as the WO 96/27721 disclosed.
  • a consisting of such panels laminate flooring can static charge especially at low relative humidity during walking, a humidity below 50% is low in the context of the invention. Under unfavorable conditions, a person's body can charge up to 25,000 volts.
  • a panel may be so designated if the possible charging of persons is below 2000 V or 2 kV.
  • JP-A-2001 293819 So it was suggested ( JP-A-2001 293819 ) to provide a transparent antistatic layer on a decorative printed substrate containing an antistatic copolymer having on one chain an ammonium salt group on the one hand and a carboxyl group on the other.
  • the object of the invention is to provide a decorative paper provided with floor panel with improved antistatic properties.
  • a decorative paper and / or decorative paper and / or an overlay paper is provided with a resin mixture containing quaternary ammonium compounds, preferably quaternary amines.
  • quaternary ammonium compounds preferably quaternary amines.
  • the proportion of quaternary ammonium compounds in the resin mixture is at least 10% by weight. Since quaternary ammonium compounds are relatively expensive, the proportion of 20 wt .-% should not be exceeded.
  • the paper may be passed in the form of a paper web through a mixture containing urea and / or melamine resins in addition to said quaternary ammonium compounds.
  • the soaked paper is dried and pressed in due course with a carrier, preferably with the supply of heat.
  • the mixture may alternatively be sprayed on, for example.
  • the result is a panel with improved antistatic properties compared to a panel in which the paper has been impregnated with other conventional resins.
  • Through the quaternary Ammonium compounds increase the electrical conductivity in the surface area of the floor covering. This leads to a reduced charge of persons who enter the floor covering.
  • Abrasion-resistant particles can be applied to the top of the decor.
  • the mixture contains abrasion-resistant particles, and in particular alumina / corundum, since this material is usually barely visible and thus the view of the decor is hardly affected.
  • Abrasion-resistant particles are applied to the decor paper in one operation and at the same time the antistatic properties are improved.
  • the decorative paper is impregnated in a mixture with the abrasion-resistant particles and then the mixture is removed, at least in part, for example by means of a doctor blade from the underside of the decorative paper.
  • the mixture contains abrasion-resistant particles
  • the mixture advantageously additionally contains viscosity-increasing substances, such as cellulose derivatives. This ensures that the abrasion-resistant particles improved in the mixture are kept in suspension. This achieves a good uniform distribution of the abrasion-resistant particles on the paper surface.
  • an overlay is impregnated with a mixture containing a resin such as urea resin and / or melamine resin.
  • this mixture also contains substances that increase the electrical conductivity, namely the said quaternary ammonium compounds.
  • the proportion is again preferably from 1 to 20 wt .-%.
  • Carrier, decor paper and overlay are pressed together to form a panel, the panel.
  • a Gegenzugpapier is pressed with, which is located on the underside of the carrier.
  • abrasion-resistant particles such as corundum can be applied on one side to the overlay.
  • Carrier, decor paper and overlay and optionally a Gegenzugpapier be pressed together so that the abrasion-resistant particles between the decor paper and the overlay are. The decor is visible on the surface of the plate.
  • FIG. 1 an embodiment of a floor panel according to the invention is shown schematically in a vertical section.
  • the mixture comprises a urea and / or melamine resin, quaternary amines, cellulose fibers and powdered corundum.
  • the grain size of the corundum is on average between 60 microns and 1 20 microns.
  • the proportion of quaternary amines in the mixture is about 15 wt .-%, this decorative paper 1 is metered with the aid of metering rollers provided with the mixture, with about 150 g / m 2 (determined after drying).
  • the mixture is scraped off with a doctor blade. Abrasion-resistant particles 2 remain predominantly on the upper side. Subsequently, the decorative paper 1 with the abrasion-resistant particles 2 located thereon is dried in a floating dryer.
  • the dried decorative paper 1 is applied with its underside to an 8 mm thick HDF plate 3.
  • On the decor paper is a soaked with a mixture of melamine resin and quaternary amines so-called "overlay" 4 is placed.
  • Underneath the HDF plate a urea resin-soaked paper 5 serving as a countermove is placed.
  • a short-cycle press papers 1 and 5 including overlay 4 are pressed with the HDF plate 3 at temperatures of 180 ° C to 220 ° C.
  • a floor covering was made for testing purposes from seven panels made according to the above example.
  • the test area was about 1400 mm * 1400 mm.
  • the antistatic properties were tested according to EN 1815 (1 997), Method A.
  • the coating was applied to an insulating rubber mat. The measurements were carried out under two different climatic conditions, for which the sample was stored in a walk-in climate chamber.
  • the term "astatic" behavior is defined by a person charge of less than 2 kV.
  • a method of measuring the charging of people is not yet established.
  • a clear classification according to this test standard is not permitted.
  • the method used according to EN 1815 is a method that has been used and recognized for more than 20 years for measuring the loading of persons when walking on different types of floor coverings.

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Floor Finish (AREA)
  • Laminated Bodies (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Claims (5)

  1. Panneau de plancher avec un support (3) et un papier décoratif (1) comprimé avec celui-ci, un élément de recouvrement (4) et des particules (2) résistantes à l'abrasion se trouvant au milieu,
    caractérisé en ce que
    l'élément de recouvrement (4) et le papier décoratif (1) sont imprégnés d'un mélange qui contient une résine d'urée et/ou une résine de mélamine ainsi que des amines quaternaires.
  2. Panneau selon la revendication 1, caractérisé en ce que les particules (2) résistantes à l'abrasion sont du corindon.
  3. Panneau selon la revendication 1 ou 2, caractérisé en ce que le dessous est pourvu d'un papier (5) qui est imprégné de préférence de résine d'urée.
  4. Panneau selon l'une quelconque des revendications 1 à 3, caractérisé en ce qu'il présente une plaque de support (3) en HDF.
  5. Panneau selon l'une quelconque des revendications précédentes, caractérisé en ce qu'il est pourvu latéralement d'éléments d'accouplement.
EP04103947A 2003-11-26 2004-08-18 Papier antistatique et panneau de plancher Not-in-force EP1536065B8 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SI200431042T SI1536065T1 (sl) 2003-11-26 2004-08-18 Antistatični papir in panel
PL04103947T PL1536065T3 (pl) 2003-11-26 2004-08-18 Papier antystatyczny i panel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE20318290U 2003-11-26
DE20318290U DE20318290U1 (de) 2003-11-26 2003-11-26 Antistatisches Papier nebst Paneel

Publications (3)

Publication Number Publication Date
EP1536065A1 EP1536065A1 (fr) 2005-06-01
EP1536065B1 true EP1536065B1 (fr) 2009-02-25
EP1536065B8 EP1536065B8 (fr) 2009-04-15

Family

ID=32087606

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04103947A Not-in-force EP1536065B8 (fr) 2003-11-26 2004-08-18 Papier antistatique et panneau de plancher

Country Status (10)

Country Link
US (2) US20050112335A1 (fr)
EP (1) EP1536065B8 (fr)
AT (1) ATE423869T1 (fr)
CA (1) CA2486629C (fr)
DE (2) DE20318290U1 (fr)
DK (1) DK1536065T3 (fr)
ES (1) ES2322258T3 (fr)
PL (1) PL1536065T3 (fr)
PT (1) PT1536065E (fr)
SI (1) SI1536065T1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020192432A1 (en) * 2001-05-07 2002-12-19 Vermillion Robert J. Dissipative layer suitable for use in protective package
DE102005002059A1 (de) 2005-01-14 2006-07-27 Kronotec Ag Holzwerkstoff mit ableitfähiger Oberfläche
EP1911578B1 (fr) * 2006-10-12 2009-05-20 Flooring Technologies Ltd. Procédé de fabrication d'un panneau de construction et panneau de construction fabriqué selon celui-ci
CN100422481C (zh) * 2007-04-21 2008-10-01 淄博统一陶瓷有限公司 防静电复古生态砖
EP2449283B1 (fr) * 2009-07-02 2014-10-15 The Gates Corporation Tissu amelioré pour courroie de transmission dentée et courroie
PL2537597T3 (pl) 2011-06-21 2017-02-28 Flooring Technologies Ltd. Płyta drewnopochodna oraz sposób jej wytwarzania
ES2833422T3 (es) 2015-02-13 2021-06-15 Centitvc Centro De Nanotecnologia E Materiais Tecnicos Funcionais E Inteligentes Producto multicapa derivado de madera con circuito eléctrico integrado y procedimiento de fabricación

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2986488A (en) * 1957-02-27 1961-05-30 Hercules Powder Co Ltd Method of sizing paper
JPS5774336A (en) * 1980-10-28 1982-05-10 Matsushita Electric Works Ltd Antistatic treatment for dry substance impregnated with thermosetting resin
US4645717A (en) * 1982-11-17 1987-02-24 Charleswater Products, Inc. Solution for use in impregnating paper for high-pressure antistatic laminates
US4784908A (en) * 1986-03-25 1988-11-15 Nevamar Corporation Static dissipative laminate for work surfaces
US5089327A (en) * 1987-05-15 1992-02-18 The Sorg Paper Company Anti-static sheet for use in high pressure laminates
US4826912A (en) * 1987-07-29 1989-05-02 Armstrong World Industries, Inc. Charge dissipative floor tiles
SE460274B (sv) * 1988-02-18 1989-09-25 Perstorp Ab Foerfarande foer framstaellning av ett noetningsbestaendigt, dekorativt haerdplastlaminat
US5866209A (en) * 1991-07-18 1999-02-02 International Paper Company Process for producing aesthetic surface layer composition and aesthetic surface layer
US5658651A (en) * 1995-09-29 1997-08-19 Creative Products Resource, Inc. Fabric treatment and softener system for in-dryer use
US5879781A (en) * 1997-08-20 1999-03-09 The Mead Corporation Flooring laminate having noise reduction properties
PT1068394E (pt) * 1999-01-26 2004-03-31 Kronospan Tech Co Ltd Processo para a impregnacao de papeis decorativos
DE19912149C2 (de) * 1999-03-18 2003-05-15 Technocell Dekor Gmbh & Co Kg Dekorrohpapier mit verbesserter Trockenfestigkeit sowie damit hergestellte(s) Dekorpapier oder Dekorfolie
US6440538B1 (en) * 2000-04-03 2002-08-27 Lg Chem Ltd. Abrasion resistant laminate
JP4327330B2 (ja) * 2000-04-14 2009-09-09 共同印刷株式会社 帯電防止性化粧シート
AT411374B (de) * 2000-06-06 2003-12-29 Kaindl M Belag, verkleidung od.dgl., paneele für dessen bildung sowie verfahren und gerät zur herstellung der paneele
MXPA03006716A (es) * 2001-01-31 2003-10-24 3M Innovative Properties Co Recubrimiento laminado curable resistente al ensuciamiento.
PT1274594E (pt) * 2001-02-20 2014-02-11 Kronoplus Technical Ag Papel decorativo, bem como processo para a impregnação de um papel decorativo
US20030127763A1 (en) * 2001-08-16 2003-07-10 Josef Stutz Mechanically glued board of wood material
US20060110600A1 (en) * 2004-11-19 2006-05-25 3M Innovative Properties Company Anisotropic conductive adhesive composition

Also Published As

Publication number Publication date
PT1536065E (pt) 2009-05-12
SI1536065T1 (sl) 2009-04-30
PL1536065T3 (pl) 2009-07-31
ATE423869T1 (de) 2009-03-15
EP1536065B8 (fr) 2009-04-15
ES2322258T3 (es) 2009-06-18
DE502004009041D1 (de) 2009-04-09
EP1536065A1 (fr) 2005-06-01
CA2486629C (fr) 2010-04-20
US20050112335A1 (en) 2005-05-26
DK1536065T3 (da) 2009-05-18
CA2486629A1 (fr) 2005-05-26
US20070269640A1 (en) 2007-11-22
DE20318290U1 (de) 2004-04-01

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