EP1534223B1 - Compositions pour detergents capillaires - Google Patents

Compositions pour detergents capillaires Download PDF

Info

Publication number
EP1534223B1
EP1534223B1 EP03784613A EP03784613A EP1534223B1 EP 1534223 B1 EP1534223 B1 EP 1534223B1 EP 03784613 A EP03784613 A EP 03784613A EP 03784613 A EP03784613 A EP 03784613A EP 1534223 B1 EP1534223 B1 EP 1534223B1
Authority
EP
European Patent Office
Prior art keywords
group
acid
mixtures
hydrogen atom
hair
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP03784613A
Other languages
German (de)
English (en)
Other versions
EP1534223A1 (fr
Inventor
Eiji C/O KAO CORPORATION RESEARCH LAB. TERADA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=31711846&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1534223(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kao Corp filed Critical Kao Corp
Publication of EP1534223A1 publication Critical patent/EP1534223A1/fr
Application granted granted Critical
Publication of EP1534223B1 publication Critical patent/EP1534223B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/362—Polycarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair

Definitions

  • the present invention relates to silicone-containing hair detergent compositions which may provide benefits such as rich foaming during shampooing and excellent conditioning effects and luster to the hair.
  • a hair detergent composition comprising the following components (a), (b) and (c):
  • the present invention relates to a hair detergent composition providing good foaming during shampooing and which is capable of giving excellent conditioning effects and luster to the hair.
  • a hair detergent composition satisfying the above-described demand is obtainable by using, in combination, an anionic surfactant, a carboxylic acid, and a silicone derivative having a side chain containing both a hydroxy group and a nitrogen atom.
  • sulfate-, sulfonate- and carboxylate-type surfactants are preferred.
  • specific examples include alkyl sulfates, polyoxyalkylene alkyl ether sulfates, polyoxyalkylene alkenyl ether sulfates, alkyl sulfosuccinates, polyoxyalkylene alkyl sulfosuccinates, polyoxyalkylene alkylphenyl ether sulfates, and higher fatty acid salts.
  • polyoxyalkylene alkyl ether sulfates and alkyl sulfates are preferred, with those represented by the following formula (a1) or (a2) being particularly preferred.
  • R represents a C 10-18 alkyl or alkenyl group
  • R' represents a C 10-18 alkyl group
  • M represents an alkali metal, alkaline earth metal, ammonium, alkanolamine or basic amino acid
  • n stands for a number of from 1 to 5 on weight average.
  • Component (a) the above-described surfactants may be used as a combination of two or more thereof.
  • the content of Component (a) in the hair detergent composition of the invention preferably ranges from 0.5 to 60 wt.%, more preferably from 1 to 30 wt.%, especially preferably from 8 to 20 wt.%, from the viewpoints of foaming performance, liquid state during use and detergency.
  • Examples of the hydroxymonocarboxylic acid serving as Component (b) include glycolic acid, lactic acid, hydroxyacrylic acid, oxybutyric acid and glyceric acid, among which lactic acid and glycolic acid are especially preferred.
  • Examples of the dicarboxylic acid include malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, phthalic acid and oxalic acid, among which maleic acid is especially preferred.
  • Examples of the hydroxydicarboxylic acid include malic acid and tartaric acid, among which malic acid is especially preferred.
  • Component (b) these compounds may be used either singly or in combination as a combination of two or more thereof.
  • the content of Component (b) in the hair detergent composition of the invention ranges preferably from 0.05 to 10 wt.%, more preferably from 0.1 to 5 wt.%, especially preferably from 0.5 to 2 wt.% from the viewpoints of improvement in the finish of the hair such as luster and styling ease.
  • the silicone derivative as Component (c) has a group containing both a hydroxy group and a nitrogen atom as a side chain thereof bonded to a silicon atom.
  • Preferred specific examples include those represented by the following average formula (1): wherein, R 1 each independently represents a monovalent hydrocarbon group, a hydroxy group or an alkoxy group, R 2 each independently represents a monovalent hydrocarbon group, R 3 each independently represents a divalent C 1-10 hydrocarbon group, R 4 each independently represents a group represented by the following formula (2) or (3): wherein, Y each independently represents a hydrogen atom or a group: -CH 2 CH(OH)-R 3 -OH (R 3 has the same meaning as described above), R 5 each independently represents a hydrogen atom or a group -R 3 NY 2 (Y and R 3 have the same meanings as described above), with the proviso that all the Ys do not represent a hydrogen atom simultaneously, a stands for a number of from 25 to 1,000, b stands for a number of from 1 to
  • Examples of the monovalent hydrocarbon group as R 1 include alkyl groups and aryl groups.
  • R 1 C 1-3 alkyl groups (particularly, methyl group) and C 1-15 , especially C 10-15 , alkoxy groups are preferred.
  • Examples of the monovalent hydrocarbon group as R 2 include C 1-6 alkyl groups such as methyl, ethyl, propyl, butyl, pentyl and hexyl, C 6-10 aryl groups such as phenyl, tolyl and xylyl, and C 6-10 aralkyl groups such as benzyl and phenethyl.
  • C 1-6 alkyl groups such as methyl, ethyl, propyl, butyl, pentyl and hexyl
  • C 6-10 aryl groups such as phenyl, tolyl and xylyl
  • C 6-10 aralkyl groups such as benzyl and phenethyl.
  • an alkyl group, particularly a methyl group is preferred.
  • Examples of the divalent C 1-10 hydrocarbon group as R 3 include methylene group, alkylene groups such as ethylene, trimethylene, propylene, tetramethylene, methyltrimethylene, ethylethylene and dimethylethylene groups, and alkylenearylene groups such as a group represented by the formula: -(CH 2 ) 2 -C 6 H 4 -. Among these, C 2-4 alkylene groups are preferred.
  • Y represents a group: -CH 2 CH(OH)-R 3 -OH, it is preferably a 2,3-dihydroxypropyl group.
  • R 4 groups represented by the formula (3) are preferred, while as R 5 N-(2,3-dihydroxypropyl)aminoethyl and N,N-bis(2,3-dihydroxypropyl)aminoethyl groups are preferred.
  • a stands for a number of from 75 to 400 and b stands for a number of from 1 to 20.
  • the silicone derivative serving as Component (c) can be synthesized, for example, by reacting an amino-modified silicone with an epoxy functional compound such as glycidol as described in EP-0399706A2 .
  • examples of the silicone derivative as Component (c) include compounds represented by the below-described formula, while those of commercially available products include "8500 Conditioning Agent” (CAS No. 237753-63-8; product of Dow Corning Corp).
  • X 75% of -CH 2 CH(OH)CH 2 OH and 25% of hydrogen atom
  • Component (c) two or more of the compounds as described above may be used in combination.
  • the content of Component (c) in the hair detergent composition of the present invention preferably ranges from 0.05 to 4 wt.%, more preferably from 0.07 to 2 wt.%, especially preferably from 0.1 to 1.5 wt.%.
  • the hair detergent composition of the present invention may further contain, as Component (d), an organic solvent selected from the following (d1) to (d5):
  • those corresponding to (d1) include ethanol, 1-propanol, 2-propanol, butanol, isobutanol, ethylene glycol, propylene glycol, 1,3-butanediol, benzyl alcohol, cinnamyl alcohol, phenethyl alcohol, p-anisyl alcohol, p-methylbenzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methylcarbitol, ethyl carbitol, propyl carbitol, butyl carbitol, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, and glycerin; those corresponding to (d2) include N-methylpyrrolidone, N-octylpyrrolidone and N-laurylpyrrolidone; those corresponding to (d3) include ethylene carbonate and propylene carbonate; and, as the propylene glycol of
  • R 9 and R 10 in formulas (5) to (7) include linear, branched or cyclic alkyl groups, a hydroxy group, a sulfonic acid group, a phosphoric acid group, a carboxyl group, a phenyl group, sulfoalkyl groups, alkyl phosphate groups and carboxyalkyl groups.
  • linear or branched C 1-6 alkyl groups for example, methyl, ethyl, propyl, isopropyl and butyl groups, substituted at the ⁇ -position in the case of ⁇ -lactone and at the ⁇ -position in the case of ⁇ -lactone (the position of the methylene adjacent to the hetero oxygen atom).
  • they preferably have, as R 9 or R 10 , an acid group such as sulfonic acid group, phosphoric acid group or carboxy group, or an alkyl group substituted therewith.
  • lactone as (d5) examples include ⁇ -butyrolactone, ⁇ -caprolactone, ⁇ -valerolactone, ⁇ -valerolactone, ⁇ -caprolactone and ⁇ -heptanolactone. From the viewpoint of stability of the lactone, ⁇ -lactones, especially ⁇ -butyrolactone and ⁇ -caprolactone are preferred.
  • cyclic ketone as (d5) examples include cyclopentanone, cyclohexanone, cycloheptanone and 4-methylcycloheptanone.
  • Component (d) particularly preferred are benzyl alcohol, benzyloxyethanol, propylene carbonate and propylene glycol.
  • Component (d) two or more of the compounds as described above may be used in combination.
  • the content of the Component (d) in the hair detergent composition of the invention preferably ranges from 0.01 to 50 wt.%, more preferably from 0.1 to 35 wt.%, especially preferably from 0.5 to 10 wt.%, from the viewpoints of improvement in feeling upon use, luster and flexibility.
  • a nonionic surfactant or amphoteric surfactant may be added in order to improve foaming performance.
  • nonionic surfactant examples include polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene sorbit fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyoxyalkylene fatty acid esters, polyoxyalkylene alkyl ethers, polyoxyalkylene alkyl phenyl ethers, polyoxyalkylene (hydrogenated) castor oils, sucrose fatty acid esters, polyglycerin alkyl ethers, polyglycerin fatty acid esters, fatty acid alkanolamides and alkyl glycosides.
  • alkyl glycosides polyoxyalkylene alkyl ethers, polyoxyalkylene (C 8 to C 20 ) fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hydrogenated castor oils, and fatty acid alkanolamides are preferred.
  • fatty acid alkanolamides those having a C 8-18 , especially C 10-16 , acyl group are preferred.
  • the fatty acid alkanolamides may be either monoalkanolamides or dialkanolamides, and those having a C 2-3 hydroxyalkyl group are preferred.
  • Examples include oleic diethanolamide, palm kernel fatty acid diethanolamide, coconut fatty acid diethanolamide, lauric diethanolamide, polyoxyethylene coconut fatty acid monoethanolamide, coconut fatty acid monoethanolamide, lauric isopropanolamide and lauric monoethanolamide.
  • betaine surfactants are usable.
  • alkyldimethylaminoacetic betaines and fatty acid amidopropyl betaines are more preferred, with fatty acid amidopropyl betaines being particularly preferred.
  • the fatty acid amidopropyl betaines preferably have a C 8-18 , especially C 10-16 , acyl group.
  • lauramidopropyl betaine, palm kernel amidopropyl betaine and cocamidopropyl betaine are especially preferred.
  • a conditioning component selected from cationic polymers, cationic surfactants, silicones other than Component (c) and oils can be added in order to improve the finish after drying.
  • cationic polymer examples include cationized cellulose derivatives, cationic starch, cationized guar gum derivatives, homopolymers of diallyl quaternary ammonium salts, diallyl quaternary ammonium salt/acrylamide copolymers, quaternized polyvinylpyrrolidone derivatives, polyglycol polyamine condensates, vinylimidazolium trichloride/vinylpyrrolidone copolymers, hydroxyethyl cellulose/dimethyldiallylammonium chloride copolymers, vinylpyrrolidone/quaternized dimethylaminoethyl methacrylate copolymers, polyvinylpyrrolidone/alkylamino acrylate copolymers, polyvinylpyrrolidone/alkylamino acrylate/vinylcaprolactam copolymers, vinylpyrrolidone/methacrylamidopropyl trimethylammonium chloride cop
  • cationic surfactant examples include lauryl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, stearyl trimethyl ammonium chloride, stearyl trimethyl ammonium bromide, lauryl trimethyl ammonium bromide, behenyl trimethyl ammonium chloride, dialkyl dimethyl ammonium chloride, dicetyl dimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dicocoyl dimethyl ammonium chloride, myristyl dimethyl benzyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, lanolin fatty acid amidopropyl ethyldimethyl ammonium ethyl sulfate, lanolin fatty acid amidoethyl triethyl ammonium ethyl sulfate, stearyl amidopropyl dimethylamine (and salts thereof
  • silicones other than Component (c) the following compounds can be given as examples.
  • Examples include compounds represented by the following formula: (Me) 3 SiO-[(Me) 2 SiO] d -Si(Me) 3 wherein, Me represents a methyl group and d stands for a number of from 3 to 2,000.
  • amino-modified silicones are usable, but those having an average molecular weight of from about 3,000 to 100,000 and described under the name of Amodimethicone in the CTFA Dictionary (Cosmetic Ingredient Dictionary, USA), third edition are particularly preferred.
  • This amino-modified silicone is preferably employed in the form of an aqueous emulsion and "SM 8704C” (product of Dow Corning Toray Silicone), “DC 929” (product of Dow Corning), etc. are the commercially available products of the aqueous emulsion.
  • silicones in addition to the above-described silicones, usable are polyether-modified silicones, methylphenyl polysiloxane, fatty acid-modified silicones, alcohol-modified silicones, alkoxy-modified silicones, epoxy-modified silicones, fluorine-modified silicones, cyclic silicones, and alkyl-modified silicones.
  • oils to be used herein as the conditioning component means an oily substance other than silicones and examples include hydrocarbons such as squalene, squalane, liquid paraffin, liquid isoparaffin and cycloparaffin; glycerides such as castor oil, cacao oil, mink oil, avocado oil and olive oil; waxes such as beeswax, spermaceti, lanolin and carnauba wax; alcohols such as cetyl alcohol, oleyl alcohol, stearyl alcohol, isostearyl alcohol, 2-octyldodecanol and glycerin; esters such as isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, hexyl laurate, cetyl lactate, propylene glycol monostearate, oleyl oleate, hexadecyl 2-ethylhexanoate, isonony
  • the conditioning component two or more of these compounds may be used in combination.
  • Its content in the hair detergent composition of the invention ranges preferably from 0.05 to 10 wt.%, more preferably from 0.07 to 5 wt.%, especially preferably from 0.1 to 2 wt.% from the viewpoints of lubrication of foams, and smoothness during the period of time from shampooing to rinsing.
  • components conventionally used for a hair detergent can be incorporated in the hair detergent composition of the present invention, depending on the purpose.
  • Such optional components include antidandruff, vitamins, bactericides, anti-inflammatory agents, antiseptics, chelating agents, humectants such as sorbitol and pantenol, colorants such as dyes and pigments, viscosity regulators such as hydroxyethyl cellulose, methyl cellulose, polyethylene glycol and clay minerals; pH regulators such as potassium hydroxide; vegetable extracts; pearling agents; perfumes; coloring matters; ultraviolet absorbers; antioxidants; and the other components as described in the ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS).
  • the hair detergent compositions of the resent invention are adjusted to a pH of 1 to 4.5 (when diluted to 20 times the weight with water, at 25°C) upon application to the hair from the viewpoint of imparting the hair with luster and flexibility.
  • their pH is preferably adjusted from from 2 to 4.5, especially preferably from 3 to 3.9.
  • the carboxylic acid serving as Component (b) and also an alkali agent such as potassium hydroxide are usable.
  • the form of the hair detergent compositions of the invention can be selected as needed from liquid, powder, gel and granule, a liquid type using water as a solvent is preferred.
  • the hair detergent compositions of the invention are preferably used as a hair shampoo composition.
  • the shampoo compositions were evaluated by a panel of 10 experts based on the criteria described below and ranked based on the average score.
  • the shampoo (having pH 3.9 when diluted to 20 times the weight) thus obtained was excellent in smoothness during the period of time from foaming to rinsing, smoothness after drying and luster.
  • Purified water Balance *1 sold from Dow Corning under the name of "8500 CONDITIONING AGENT". It contains, as an effective ingredient, 60 wt.% of a silicone derivative (CAS No. 237753-63-8) having a group containing both a hydroxy group and a nitrogen atom as a side chain.
  • the shampoo thus obtained (having pH of 3.7 when diluted to 20 times the weight) was excellent in smoothness during the period of time from foaming to rinsing, smoothness after drying and luster.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition pour détergent capillaire comprenant les 3 composants (a), (b) et (c) suivants: (a) un tensioactif anionique, (b) un acide carboxylique choisi dans le groupe des acides hydroxymonocarboxylique, dicarboxylique, et hydroxydicarboxylique, ou l'un de leurs sels, et (c) un dérivé de silicium portant un groupe contenant à la fois un groupe hydroxy et un atome d'azote en chaîne latérale lié à un atome de silicium. Cette composition pour détergent capillaire assure un moussage abondant pendant le shampooinage, tout en assurant un excellent conditionnement et un bel éclat des cheveux.

Claims (6)

  1. Composition détergente capillaire ayant un pH de 1 à 4,5 à 25°C lorsque elle est diluée à 20 fois son poids avec de l'eau et comprenant les composants suivants (a), (b) et (c):
    (a) un tensioactif anionique,
    (b) un acide carboxylique sélectionné dans le groupe consistant en des acides hydroxymonocarboxyliques, des acides dicarboxyliques et des acides hydroxydicarboxyliques, et un sel de ceux-ci, et des mélanges de ceux-ci et
    (c) un dérivé de silicone ayant un groupe contenant à la fois un groupe hydroxyle et un atome d'azote comme étant une chaîne latérale correspondante reliée à un atome de silicium.
  2. Composition détergente capillaire de la revendication 1, comprenant en plus, en tant que composant (d), un solvant organique sélectionné parmi groupe consistant en (d1), (d2), (d3), (d4), (d5), et des mélanges de ceux-ci:
    (d1) des composés représentés par la formule (4) :
    Figure imgb0015
     où, R6 représente un atome d'hydrogène, un groupe alkyle inférieur ou un groupe R7-Ph-R8-(R7: un atome d'hydrogène, un groupe méthyle ou un groupe méthoxy, R8: une liaison, ou un groupe hydrocarbure en C1-3 divalent saturé ou insaturé, Ph: un groupe paraphénylène), Z1 et Z2 chacun représente un atome d'hydrogène ou un groupe hydroxy, et p, q et r chacun représente un nombre entier allant de 0 à 5, avec la condition que lorsque p=q=0, Z1 ne représente pas un atome d'hydrogène et R6 ne représente ni un atome d'hydrogène ni un groupe R7-Ph-,
    (d2) des N-alkylpyrrolidones ayant un groupe alkyle en C1-18 lié à l'atome d'azote,
    (d3) des carbonates d'alkylène ayant 1 à 4 atomes de carbone,
    (d4) des polypropylènes glycol ayant un poids moléculaire allant de 200 à 5000, et
    (d5) des lactones ou des cétones cycliques représentées par les formules suivantes (5), (6) ou (7) :
    Figure imgb0016
    où, X représente un groupe méthylène ou un atome d'oxygène, R9 et R10 représentent des substituants, respectivement, qui sont différents les uns des autres, et s et t représentent chacun un nombre de 0 ou 1.
  3. Composition détergente capillaire de la revendication 1, où le tensioactif anionique en tant que composant (a) est sélectionné dans le groupe consistant en des tensioactifs du type sulfate-, sulfonate-, carboxylate-, et des mélanges de ceux-ci.
  4. Composition détergente capillaire de la revendication 1, où l'acide hydroxymonocarboxylique en tant que composant (b) est sélectionné dans le groupe consistant en un acide glycolique, un acide lactique, un acide hydroxyacrylique, un acide oxybutyrique, un acide glycérique, et des mélanges de ceux-ci, où l'acide dicarboxylique en tant que composant (b) est sélectionné dans le groupe consistant en un un acide malonique, un acide succinique, un acide glutarique, un acide adipique, un acide maléique, un acide fumarique, un acide phtalique, un acide oxalique, et des mélanges de ceux-ci, et où l'acide hydroxydicarboxylique en tant que composant (b) est sélectionné dans le groupe consistant en un acide malique, un acide tartrique, et des mélanges de ceux-ci.
  5. Composition détergente capillaire de la revendication 1, où le dérivé de silicone en tant que composant (c) est représenté par la formule moyenne (1) suivante:
    Figure imgb0017
     où, R1 chacun représente indépendamment un groupe d'hydrocarbure monovalent, un groupe hydroxy ou un groupe alcoxy,
    R2 chacun représente indépendamment un groupe d'hydrocarbure monovalent,
    R3 chacun représente indépendamment un groupe d'hydrocarbure en C1-10 divalent,
    R4 chacun représente indépendamment un groupe représenté par les formules suivantes (2) ou (3):
    Figure imgb0018
     où, Y chacun représente indépendamment un atome d'hydrogène ou un groupe: -CH2CH(OH)-R3-OH (R3 a la même signification comme décrit ci-dessus), R5 chacun représente indépendamment un atome d'hydrogène ou un groupe -R3NY2 (Y et R3 ont les mêmes significations comme décrit ci-dessus), avec la condition que tous les Y ne représentent pas simultanément un atome d'hydrogène,
    a est un nombre allant de 25 à 1000,
    b est un nombre allant de 1 à 200.
  6. Composition détergente capillaire de la revendication 2, où (d1) est sélectionné dans le groupe consistant en de l'éthanol, 1-propanol, 2-propanol, butanol, isobutanol, éthylène glycol, propylène glycol, 1,3-butanediol, alcool benzylique, alcool cinnamylique, alcool phénéthylique, alcool p-anisylique, alcool p-méthylbenzylique, phénoxyéthanol, 2-benzyloxyéthanol, méthyl carbitol, éthyl carbitol, propyl carbitol, butyl carbitol, éther monoéthylique de triéthylène glycol, éther monobutylique de triéthylène glycol, glycérine, et des mélanges de ceux-ci, (d2) est sélectionné dans le groupe consistant en de la N-méthylpyrrolidone, N-octylpyrrolidone, N-laurylpyrrolidone, et des mélanges de celles-ci, (d3) est sélectionné dans le groupe consistant en du carbonate d'éthylène, carbonate de propylène, et des mélanges de ceux-ci, (d4) est un propylène glycol ayant un poids moléculaire allant de 200 à 10000, et (d5) est sélectionné dans le groupe consistant en du γ-butyrolactone, γ-caprolactone, γ-valérolactone, δ-valérolactone, δ-caprolactone, δ-heptanolactone, γ-butyrolactone, γ-caprolactone, cyclopentanone, cyclohexanone, cycloheptanone, 4-méthylcycloheptanone et des mélanges de ceux-ci.
EP03784613A 2002-08-09 2003-08-08 Compositions pour detergents capillaires Expired - Lifetime EP1534223B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2002232733 2002-08-09
JP2002232733A JP4127777B2 (ja) 2002-08-09 2002-08-09 毛髪洗浄剤組成物
PCT/JP2003/010139 WO2004014327A1 (fr) 2002-08-09 2003-08-08 Compositions pour detergents capillaires

Publications (2)

Publication Number Publication Date
EP1534223A1 EP1534223A1 (fr) 2005-06-01
EP1534223B1 true EP1534223B1 (fr) 2008-03-05

Family

ID=31711846

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03784613A Expired - Lifetime EP1534223B1 (fr) 2002-08-09 2003-08-08 Compositions pour detergents capillaires

Country Status (8)

Country Link
US (1) US7838478B2 (fr)
EP (1) EP1534223B1 (fr)
JP (1) JP4127777B2 (fr)
CN (1) CN1325038C (fr)
AU (1) AU2003256072A1 (fr)
DE (1) DE60319547T2 (fr)
TW (1) TWI338586B (fr)
WO (1) WO2004014327A1 (fr)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4050676B2 (ja) * 2003-08-22 2008-02-20 花王株式会社 洗浄料
DE102004030885A1 (de) * 2004-06-25 2006-02-09 Henkel Kgaa Haarreinigungsmittel mit aminofunktionellen Siliconen
JP2006282615A (ja) * 2005-04-01 2006-10-19 Kao Corp 毛髪洗浄剤
CA2603598A1 (fr) * 2005-04-07 2006-10-12 Unilever Plc Compositions pour soins capillaires
JP2007131583A (ja) * 2005-11-11 2007-05-31 Kao Corp スカルプケア剤
FR2895250B1 (fr) 2005-12-22 2012-08-17 Oreal Composition cosmetique comprenant au moins un poly(vinyllactame) cationique, au moins un alcool gras et au moins un polyol, procede de traitement des fibres keratiniques et utilisation de la composition
JP5075345B2 (ja) * 2006-03-23 2012-11-21 花王株式会社 毛髪洗浄剤組成物
JP5235102B2 (ja) * 2008-06-16 2013-07-10 花王株式会社 水性毛髪洗浄剤
JP2010235523A (ja) * 2009-03-31 2010-10-21 Kao Corp 水性毛髪洗浄剤
JP5341029B2 (ja) * 2010-06-18 2013-11-13 花王株式会社 水性毛髪洗浄剤
JP5717401B2 (ja) * 2010-11-04 2015-05-13 花王株式会社 スカルプケア剤
US9346023B2 (en) 2012-08-21 2016-05-24 General Electric Company Flux enhancing agent for improving composite polyamide reverse osmosis membrane performance
MX2017013983A (es) 2015-05-01 2018-03-15 Oreal Uso de agentes activos durante tratamientos quimicos.
JP6930994B2 (ja) 2015-11-24 2021-09-01 ロレアル 毛髪をトリートメントするための組成物
BR112018010341B1 (pt) 2015-11-24 2021-08-10 L'oreal Método para alteração da cor de cabelo
BR112018010344B1 (pt) 2015-11-24 2021-08-10 L'oreal Composição para cabelo, sistema e método para tratamento do cabelo, métodos para alteração da cor do cabelo e do formato do cabelo, e, kits de multicompartimentos
US11135150B2 (en) 2016-11-21 2021-10-05 L'oreal Compositions and methods for improving the quality of chemically treated hair
US9974725B1 (en) 2017-05-24 2018-05-22 L'oreal Methods for treating chemically relaxed hair
WO2019133785A1 (fr) 2017-12-29 2019-07-04 L'oreal Compositions modifiant la couleur des cheveux
US11090249B2 (en) 2018-10-31 2021-08-17 L'oreal Hair treatment compositions, methods, and kits for treating hair
US11419809B2 (en) 2019-06-27 2022-08-23 L'oreal Hair treatment compositions and methods for treating hair

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4185087A (en) * 1977-12-28 1980-01-22 Union Carbide Corporation Hair conditioning compositions containing dialkylamino hydroxy organosilicon compounds and their derivatives
JPS5566506A (en) 1978-11-15 1980-05-20 Lion Corp Cosmetic
JPS5758605A (en) * 1980-09-25 1982-04-08 Pola Chem Ind Inc Cosmetic having excellent makeup durability
JPS57171768A (en) * 1981-04-15 1982-10-22 Shinetsu Chem Ind Co Fiber treating agent
CA1261276A (fr) 1984-11-09 1989-09-26 Mark B. Grote Shampooings
US4915938A (en) * 1987-11-13 1990-04-10 Zawadzki Mary E Hair treating composition
US5137715A (en) * 1990-12-07 1992-08-11 Helene Curtis, Inc. Hair shampoo-conditioner composition
US6262007B1 (en) * 1991-06-14 2001-07-17 The Procter & Gamble Company Self-thickened cleaning compositions
FR2677995B1 (fr) * 1991-06-21 1994-07-22 Oreal Composition de lavage et/ou de conditionnement des matieres keratiniques, contenant une silicone et un polymere amphotere derive de diallyldialkylammonium et d'un monomere anionique.
FR2678633B1 (fr) * 1991-07-04 1993-10-22 Oreal Composition de lavage et/ou de conditionnement des matieres keratiniques a base d'une silicone a fonction hydroxyacylamino et de polymeres substantifs.
GB9116871D0 (en) 1991-08-05 1991-09-18 Unilever Plc Hair care composition
US5691295A (en) * 1995-01-17 1997-11-25 Cognis Gesellschaft Fuer Biotechnologie Mbh Detergent compositions
JPH08301724A (ja) 1995-05-08 1996-11-19 Kanebo Ltd パール光沢状組成物
JP3859723B2 (ja) * 1996-03-04 2006-12-20 オーエスアイ スペシャルティーズ インコーポレーテッド シリコーンアミノポリアルキレンオキシドブロックコポリマー
FR2749507B1 (fr) * 1996-06-07 1998-08-07 Oreal Compositions cosmetiques detergentes et utilisation
JP4074352B2 (ja) 1997-01-27 2008-04-09 花王株式会社 毛髪化粧料
EP0978272A1 (fr) 1998-08-07 2000-02-09 Kao Corporation Préparation pour les soins de la medulla
US6425959B1 (en) * 1999-06-24 2002-07-30 Ecolab Inc. Detergent compositions for the removal of complex organic or greasy soils
US6171515B1 (en) * 1999-09-02 2001-01-09 Dow Corning Corporation Fiber treatment composition containing amine-, polyol-, functional siloxanes
DE60116339T3 (de) * 2000-09-11 2013-09-05 The Procter & Gamble Company Waschkit sowie verfahren zur kombinierten pflege und reinigung von gewebe
US6528070B1 (en) * 2000-09-15 2003-03-04 Stepan Company Emulsion comprising a ternary surfactant blend of cationic, anionic, and bridging surfactants, oil and water, and methods of preparing same
US6838427B2 (en) * 2001-06-08 2005-01-04 Kao Corporation Softener composition
GB0202631D0 (en) * 2002-02-05 2002-03-20 Dow Corning Hair care compositions containing polysiloxanes

Also Published As

Publication number Publication date
DE60319547D1 (de) 2008-04-17
CN1325038C (zh) 2007-07-11
TW200406225A (en) 2004-05-01
TWI338586B (en) 2011-03-11
JP2004067639A (ja) 2004-03-04
US7838478B2 (en) 2010-11-23
EP1534223A1 (fr) 2005-06-01
DE60319547T2 (de) 2009-03-26
AU2003256072A1 (en) 2004-02-25
WO2004014327A1 (fr) 2004-02-19
US20060166845A1 (en) 2006-07-27
JP4127777B2 (ja) 2008-07-30
CN1674858A (zh) 2005-09-28

Similar Documents

Publication Publication Date Title
EP1534223B1 (fr) Compositions pour detergents capillaires
EP1531783B1 (fr) Compositions detergentes
US7776806B2 (en) Hair cleansing composition
US20120039835A1 (en) Hair cleansing compositions
US6914038B2 (en) Hair cleansing compositions
US20090075854A1 (en) Hair cleansing compositions
EP1531789B1 (fr) Compositions pour detergents capillaires
JP4050676B2 (ja) 洗浄料
JP4856386B2 (ja) 毛髪洗浄剤
JP2006282615A (ja) 毛髪洗浄剤
JP2008037849A (ja) 毛髪化粧料
JP3887283B2 (ja) シャンプー組成物
JP2005060270A (ja) 毛髪化粧料
JP4782369B2 (ja) 毛髪化粧料
JP2007262043A (ja) 毛髪化粧料

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20050204

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK

DAX Request for extension of the european patent (deleted)
RBV Designated contracting states (corrected)

Designated state(s): DE FR GB

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: A61K 8/365 20060101ALI20070928BHEP

Ipc: A61Q 5/12 20060101ALI20070928BHEP

Ipc: A61K 8/46 20060101ALI20070928BHEP

Ipc: A61Q 5/02 20060101ALI20070928BHEP

Ipc: A61K 8/362 20060101AFI20070928BHEP

Ipc: A61K 8/898 20060101ALI20070928BHEP

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60319547

Country of ref document: DE

Date of ref document: 20080417

Kind code of ref document: P

ET Fr: translation filed
PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

26 Opposition filed

Opponent name: HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN

Effective date: 20081203

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PLAF Information modified related to communication of a notice of opposition and request to file observations + time limit

Free format text: ORIGINAL CODE: EPIDOSCOBS2

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PLCK Communication despatched that opposition was rejected

Free format text: ORIGINAL CODE: EPIDOSNREJ1

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 20100923

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 15

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 16

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20190711

Year of fee payment: 17

Ref country code: DE

Payment date: 20190723

Year of fee payment: 17

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20190814

Year of fee payment: 17

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 60319547

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20200808

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210302

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200808