EP1510534A1 - Catalyseurs au cyanure bimetallique contenant de l'hydroxyde - Google Patents

Catalyseurs au cyanure bimetallique contenant de l'hydroxyde Download PDF

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Publication number
EP1510534A1
EP1510534A1 EP04019263A EP04019263A EP1510534A1 EP 1510534 A1 EP1510534 A1 EP 1510534A1 EP 04019263 A EP04019263 A EP 04019263A EP 04019263 A EP04019263 A EP 04019263A EP 1510534 A1 EP1510534 A1 EP 1510534A1
Authority
EP
European Patent Office
Prior art keywords
group
organic ligand
catalyst
butanol
process according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04019263A
Other languages
German (de)
English (en)
Other versions
EP1510534B1 (fr
Inventor
George G. Combs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro NV
Original Assignee
Bayer Antwerpen NV
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Publication date
Application filed by Bayer Antwerpen NV filed Critical Bayer Antwerpen NV
Publication of EP1510534A1 publication Critical patent/EP1510534A1/fr
Application granted granted Critical
Publication of EP1510534B1 publication Critical patent/EP1510534B1/fr
Not-in-force legal-status Critical Current
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
    • C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
    • C08G65/08—Saturated oxiranes
    • C08G65/10—Saturated oxiranes characterised by the catalysts used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B01J27/26—Cyanides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4866—Polyethers having a low unsaturation value
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2663—Metal cyanide catalysts, i.e. DMC's

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • General Health & Medical Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Polyesters Or Polycarbonates (AREA)
EP04019263.5A 2003-08-26 2004-08-13 Catalyseurs au cyanure bimetallique contenant de l'hydroxyde Not-in-force EP1510534B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/649,520 US6855658B1 (en) 2003-08-26 2003-08-26 Hydroxide containing double metal cyanide (DMC) catalysts
US649520 2003-08-26

Publications (2)

Publication Number Publication Date
EP1510534A1 true EP1510534A1 (fr) 2005-03-02
EP1510534B1 EP1510534B1 (fr) 2016-05-11

Family

ID=34104678

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04019263.5A Not-in-force EP1510534B1 (fr) 2003-08-26 2004-08-13 Catalyseurs au cyanure bimetallique contenant de l'hydroxyde

Country Status (11)

Country Link
US (2) US6855658B1 (fr)
EP (1) EP1510534B1 (fr)
JP (1) JP2005068436A (fr)
KR (1) KR101168425B1 (fr)
CN (2) CN100450615C (fr)
BR (1) BRPI0403520B1 (fr)
CA (1) CA2478778C (fr)
HK (1) HK1078818A1 (fr)
MX (1) MXPA04008285A (fr)
RU (1) RU2004125640A (fr)
SG (2) SG127868A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1634644A1 (fr) * 2004-09-13 2006-03-15 Bayer MaterialScience LLC Procédé de préparation de catalyseurs à base de cyanures métalliques doubles (catalyseurs DMC)
CN112156797A (zh) * 2020-09-10 2021-01-01 中国科学院山西煤炭化学研究所 环状碳酸酯和甲醇酯交换合成碳酸二甲酯的催化剂及其制备方法和应用

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100349949C (zh) * 2005-07-12 2007-11-21 黎明化工研究院 一种多金属氰化物络合物催化剂及其制备方法
US7834082B2 (en) 2007-01-17 2010-11-16 Bayer Materialscience Llc Polyether-polysiloxane polyols
DE102007005960A1 (de) * 2007-02-07 2008-08-14 Bayer Materialscience Ag Ruß-gefüllte Polyurethane mit hoher Dielektrizitätskonstante und Durchschlagsfestigkeit
KR101404702B1 (ko) 2011-03-08 2014-06-17 에스케이이노베이션 주식회사 에테르 결합 단위체를 함유한 이산화탄소/에폭사이드 공중합체의 제조 방법
CN103508894B (zh) * 2012-06-19 2015-08-05 嘉兴学院 一种合成碳酸二甲酯的方法
US9562134B2 (en) 2013-03-12 2017-02-07 Covestro Llc Catalyst for the production of polyols having lower amounts of high molecular weight tail
GB201515350D0 (en) 2015-08-28 2015-10-14 Econic Technologies Ltd Method for preparing polyols
GB201703324D0 (en) 2017-03-01 2017-04-12 Econic Tech Ltd Method for preparing polyether carbonates
GB201717441D0 (en) 2017-10-24 2017-12-06 Econic Tech Ltd A polymerisation process
CN110684187B (zh) * 2018-07-06 2022-10-11 中国石油化工股份有限公司 多金属氰化络合物催化剂及其制备方法和应用
GB201814526D0 (en) 2018-09-06 2018-10-24 Econic Tech Ltd Methods for forming polycarbonate ether polyols and high molecular weight polyether carbonates
GB201906214D0 (en) 2019-05-02 2019-06-19 Econic Tech Ltd A polyol block copolymer, compositions and processes therefor
GB201906210D0 (en) 2019-05-02 2019-06-19 Econic Tech Limited A polyol block copolymer, compositions and processes therefor
GB202003003D0 (en) 2020-03-02 2020-04-15 Econic Tech Ltd A polyol block copolymer
GB202003002D0 (en) 2020-03-02 2020-04-15 Crane Ltd Method of preparation of a polyol block copolymer
GB202017531D0 (en) 2020-11-05 2020-12-23 Econic Tech Limited (poly)ol block copolymer
WO2023017276A1 (fr) 2021-08-11 2023-02-16 Econic Technologies Ltd Procédé de préparation de tensioactifs par copolymérisation d'epoxydes et de co2 à l'aide d'un mélange composé d'un catalyseur bimétallique macrocyclique et d'un catalyseur à base de cyanure bimétallique
GB202115335D0 (en) 2021-10-25 2021-12-08 Econic Tech Ltd Surface-active agent
CN114230783B (zh) * 2022-01-12 2023-05-26 万华化学集团股份有限公司 一种用于环氧开环的复合催化剂及其制备方法和应用

Citations (4)

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US4477589A (en) * 1982-03-31 1984-10-16 Shell Oil Company Catalysts for the polymerization of epoxides and process for the preparation of such catalysts
EP0755716A1 (fr) * 1995-07-24 1997-01-29 ARCO Chemical Technology, L.P. Catalyseurs à base de complexe de cyanure de deux métaux hautement actifs
US5783513A (en) * 1997-03-13 1998-07-21 Arco Chemical Technology, L.P. Process for making double metal cyanide catalysts
US5952261A (en) * 1998-03-20 1999-09-14 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts modified with Group IIA compounds

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GB1063525A (en) * 1963-02-14 1967-03-30 Gen Tire & Rubber Co Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3829505A (en) * 1970-02-24 1974-08-13 Gen Tire & Rubber Co Polyethers and method for making the same
US3941849A (en) * 1972-07-07 1976-03-02 The General Tire & Rubber Company Polyethers and method for making the same
US5158922A (en) * 1992-02-04 1992-10-27 Arco Chemical Technology, L.P. Process for preparing metal cyanide complex catalyst
US5712216A (en) * 1995-05-15 1998-01-27 Arco Chemical Technology, L.P. Highly active double metal cyanide complex catalysts
US5470813A (en) * 1993-11-23 1995-11-28 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts
DE19709031A1 (de) * 1997-03-06 1998-09-10 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
DE19742978A1 (de) * 1997-09-29 1999-04-01 Basf Ag Multimetallcyanidkomplexe als Katalysatoren
DE19809539A1 (de) * 1998-03-05 1999-09-09 Basf Ag Verfahren zur Herstellung von Doppelmetallcyanidkatalysatoren
US6800583B2 (en) * 1999-06-02 2004-10-05 Basf Aktiengesellschaft Suspension of multimetal cyanide compounds, their preparation and their use
US6613714B2 (en) * 1999-06-02 2003-09-02 Basf Aktiengesellschaft Multimetal cyanide compounds, their preparation and their use
AU2001252134A1 (en) * 2000-02-29 2001-09-12 Basf Aktiengesellschaft Method for producing multimetal cyanide compounds
JP2003147071A (ja) * 2001-08-31 2003-05-21 Asahi Glass Co Ltd アルキレンオキシド開環重合用複合金属シアン化物錯体触媒及びその製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4477589A (en) * 1982-03-31 1984-10-16 Shell Oil Company Catalysts for the polymerization of epoxides and process for the preparation of such catalysts
EP0755716A1 (fr) * 1995-07-24 1997-01-29 ARCO Chemical Technology, L.P. Catalyseurs à base de complexe de cyanure de deux métaux hautement actifs
US5783513A (en) * 1997-03-13 1998-07-21 Arco Chemical Technology, L.P. Process for making double metal cyanide catalysts
US5952261A (en) * 1998-03-20 1999-09-14 Arco Chemical Technology, L.P. Double metal cyanide complex catalysts modified with Group IIA compounds

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1634644A1 (fr) * 2004-09-13 2006-03-15 Bayer MaterialScience LLC Procédé de préparation de catalyseurs à base de cyanures métalliques doubles (catalyseurs DMC)
CN112156797A (zh) * 2020-09-10 2021-01-01 中国科学院山西煤炭化学研究所 环状碳酸酯和甲醇酯交换合成碳酸二甲酯的催化剂及其制备方法和应用
CN112156797B (zh) * 2020-09-10 2022-02-15 中国科学院山西煤炭化学研究所 环状碳酸酯和甲醇酯交换合成碳酸二甲酯的催化剂及其制备方法和应用

Also Published As

Publication number Publication date
KR101168425B1 (ko) 2012-07-25
EP1510534B1 (fr) 2016-05-11
CA2478778A1 (fr) 2005-02-26
US7034103B2 (en) 2006-04-25
US20050159629A1 (en) 2005-07-21
CA2478778C (fr) 2013-07-16
BRPI0403520A (pt) 2005-05-31
CN101230133B (zh) 2013-07-24
US20050049142A1 (en) 2005-03-03
BRPI0403520B1 (pt) 2014-10-21
KR20050021256A (ko) 2005-03-07
RU2004125640A (ru) 2006-02-10
MXPA04008285A (es) 2005-06-08
CN101230133A (zh) 2008-07-30
US6855658B1 (en) 2005-02-15
CN1623661A (zh) 2005-06-08
SG127868A1 (en) 2006-12-29
CN100450615C (zh) 2009-01-14
SG141232A1 (en) 2008-04-28
HK1078818A1 (en) 2006-03-24
JP2005068436A (ja) 2005-03-17

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