EP1509690B1 - Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie - Google Patents
Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie Download PDFInfo
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- EP1509690B1 EP1509690B1 EP03735135A EP03735135A EP1509690B1 EP 1509690 B1 EP1509690 B1 EP 1509690B1 EP 03735135 A EP03735135 A EP 03735135A EP 03735135 A EP03735135 A EP 03735135A EP 1509690 B1 EP1509690 B1 EP 1509690B1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F02G1/00—Hot gas positive-displacement engine plants
- F02G1/04—Hot gas positive-displacement engine plants of closed-cycle type
- F02G1/043—Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
Definitions
- Energy can not be "created” in the sense of being re-created. energy is present in many forms in nature, however not every available form of energy is equal to the human Needs usable. You can, for example, the energy in the wood very well use for heating purposes, but with it relatively poor light or cold for the Refrigerator, etc. produce.
- the Stirling engine is the second oldest after the steam engine Heat engine, that is, a machine's heat energy in can convert kinetic energy. And although the Stirling engine from the Principle ago has a substantially higher efficiency than the Steam engine and the gasoline or diesel engine, he has not today wider dissemination achieved. While steam engine and gasoline or Diesel engine continuously evolved to be in addition to the satisfied especially the corresponding power densities Achieving significantly increased efficiencies is the Stirling engine almost forgotten. Only recently he wins because of its lower environmental impact and independence from the Heat source increasingly interested. He does, however, have a considerable Pent-up demand for research and development work to a similar "Maturity", as today's steam engines or the gasoline engine in the car too to reach.
- the ideal Stirling process corresponds to a Carnot process and has therefore a very high efficiency. In practice, however, is one exact implementation, that is an exact replica of the ideal or better not possible of the theoretical process. When running Machines have a number of design-related deviations be tolerated, which adversely affect efficiency and Impact power density.
- the three types, the ⁇ -, ⁇ - and ⁇ -machine, correspond to the three until now developed basic constructive solutions to the ideal Stirling process as well as possible in the running machines to mimic can.
- the ⁇ - machine has two pistons in separate cylinders used, with one piston in the hot expansion space and the other Pistons are arranged in the cold compression chamber. Both pistons are ever after operation or crankshaft angle either working piston and then again displacer.
- a piston and a displacer is used, wherein Both piston and displacer are housed in the same cylinder.
- Both piston and displacer are housed in the same cylinder.
- pistons and displacers are in separate cylinders arranged.
- the complex sealing system of Displacement push rod in the compression piston avoided. For that increased the harmful to the efficiency dead volume.
- too double-acting Stirling machines designed and executed, in particular of the ⁇ type.
- the Franchot Stirling engine is known. at This engine runs in the space above the two pistons, but also below the piston each from a Stirling process, that is, the two Cylinders always carry two with the piston top and bottom different working cycles of two different Stirling processes to same time. This limit the two pistons and the associated Cylinder four variable volumes, which in pairs as two separate ⁇ - Machines can be viewed.
- the single-acting ⁇ - Machine must have the expansion piston and the compression piston Phase shift of about 90 °.
- Siemens Stirling engine which can be equipped with any number of Cylinders are the standard configuration of the most powerful Stirling engine represents, as the 4-95 'from United Stirling with a Power of approx. 52 kW mechanically. Also in this embodiment are Some designs have been developed, such as the arrangement of the Cylinder in row, as "U”, as "V”, in square or in circle. Although at Siemens - Stirling engine the arrangement of heaters, regenerators and Radiator was chosen so that the sealing of the piston in the Housing wall is in the cold part, remain the principal disadvantages of ⁇ - Machines received.
- the object of the invention is a method of the type mentioned on the one hand avoids the above disadvantages and that it on the other hand for the first time allows a Stirling engine to be designed so that its approach approached much better to the ideal Stirling process can be as before.
- the inventive method is characterized in that the Working medium between at least two closed workspaces flows back and forth, wherein for the delivery of useful work the working medium between the workrooms is passed over a working machine, wherein the heat absorption in front of the machine and the heat dissipation after the working machine takes place and that the working medium after the Heat dissipation is compressed in the working space and then by means of of the displacer from one side through the regenerator to the other Side of the displacer flows, whereby the flow of the working medium over Control organs, in particular valves, is controlled and each displacer is moved by a drive.
- the invention it is possible for the first time To achieve a much higher efficiency than with all previously executed Stirling engines.
- the higher efficiency is mainly due to the better alignment of the executed work process to the theoretical cycle, which with the method according to the invention is achieved, to lead back.
- the temperature difference of the working medium in the two coupled Work spaces and the resulting pressure differences it flows into the cold work space and does it over one Work machine work.
- the resulting equilibrium state is on it attributed to the fact that most of the working medium is in the cold Workspace is located.
- the pressure difference builds in mirror image Wake up again between the work rooms and will be back over the work Work machine converted to work. This behavior is analogous to a resonant circuit and allows for the same Camot efficiency a higher power density based on the amount of Working medium than the theoretical ideal Stirling process.
- the working space separated by the displacer in a double-acting workspace thereby The process can run faster because overflow distances are eliminated. About that In addition, any seals omitted from an otherwise necessary Buffer space.
- each displacer over moved its own drive.
- crank mechanisms or crank-like drives that are mainly responsible for the poor rimpedement of the executed ones Processes to the ideal Stirling process.
- crank drives is a Linear drive used, independent of other movements can be controlled so that as many and as long as you like Downtime can be achieved, for example, with the displacers.
- the displacer of coupled working spaces via a rigid connection via a drive emotional thereby, a simple structure can be achieved, wherein For example, two hot or cold work spaces coupled together become.
- the two Displacers are interconnected by a rigid push rod, the absorbs the forces acting between the displacers. To exercise the displacer has only the frictional resistance and the Flow losses are overcome.
- the regenerators can also inside or outside the push rod.
- the push rod itself does not have to be sealed.
- the theoretical power density based on the amount of working medium is higher than the ideal one Stirling process. This embodiment allows the use of Low temperature for power generation as well as the extraction of Cold.
- This version is the so-called "cold" engine.
- the work machine can be easily executed, since they are not high Temperature stress is exposed.
- through the Expansion of cooled by the regenerator cold working medium Cold generated, if necessary, before flowing into the cold Work area is used via a heat exchanger.
- the efficiency and the power density are higher than in a ⁇ -type Stirling engine of flanged on the cold side of the working piston.
- the working space is through divided the displacer into an expansion and a compression space, wherein the working medium used for the useful work after leaving the expansion area for the delivery of useful work, possibly over a heater, flows over the working machine and then over the Regenerator and possibly a compressor, if necessary via another cooler, in the compression space of the coupled Häraumes flows and then by the movement of the Displacer from the compression side through this working space associated regenerator in the same expansion space Working space flows.
- This version is the so-called "hot” engine.
- the theoretical efficiency of this type is approximately that of the Camot efficiency, the theoretical power density based on the quantity of the working medium is higher than that of the ideal Stirling process.
- the working space is through the displacer in two expansion or two compression chambers divided, with the working medium used for work after leaving an expansion space on the assigned this working space Regenerator for delivering useful work on the working machine flows and after the working machine in the compression space of the coupled Workspace flows and then through the movement of the displacer from the compression side by the working space associated with this Regenerator flows into the other expansion space of the working space.
- this "low temperature” engine allows the use of Low temperature for power generation as well as production of cold.
- the Heat absorption isobar especially directly, in front of the machine.
- the main advantage is the fact that the temperature in the displacers is limited to the maximum regenerator temperature, the Regenerator temperature is below the heater temperature.
- the compression takes place by means of pressure equalization and / or by a compressor. Should the compression take place solely by means of pressure equalization, so eliminates a rotating Machine, so the compressor. The process will certainly be easier. Under Integration of a compressor, an even higher efficiency is achieved.
- the inventive device for carrying out the method is characterized characterized in that at least two closed working spaces provided are, each work space by a movable via a drive Displacer is divided into two sections, with a section of a heater and the another section has a radiator and each working space a him associated regenerator, both sections with this Regenerator are connected and that at least one section each Workspace is connected to a work machine, with the to Subsequent submission of the Nutzarbeit used section with the corresponding section of the other working space is connected and that for controlling the working medium control organs, in particular valves, are provided.
- the inventive device achieves a higher power density.
- Another advantage of the device according to the invention is to be seen in that the machine can be operated with a low clock frequency.
- the workrooms have no real piston seals and handle so that the sealing problem, especially with larger piston volume occurs.
- By eliminating this problem can be voluminous Workrooms are used with low clock frequency and can be operated discontinuously. This will be an approximation reached to the ideal Stirling process.
- Dead space the volume that is not at the thermodynamic process participates and thus has a detrimental effect on the efficiency. He arises virtually by sinusoidal movement of the working pistons, and real through the volume of the regenerator through which the working medium flows, the heater pipes, etc.
- the ratio of large volume Workspaces and the related small-volume components such as Work machine, regenerator, heater and radiator results in a favorable Ratio of dead space to work space and is much lower the currently built machines.
- each at least one Control member in particular a valve provided. These serve for decoupling of the work and regenerator cycle. Instead of controlling via valves could also a slot control can be used.
- the working machine is a Turbine, in particular an axial, radial or Tesla turbine.
- Turbine By the Use of turbines is the elimination of moving, temperature polluted and dry baptized, given gaskets, which is the main problem with pistons operated Stirling engines represent.
- the slices or Teslaturbine is in particular a better isothermal expansion or compression possible.
- the working machine is a Piston engine.
- This design has the advantage that it is cheap and with Standard components can be executed.
- the working machine is a Screw motor.
- the screw motor like the turbines, has the advantage of dropping seals.
- the drive for the Displacer a linear actuator.
- the linear drive ensures a precise controllable acceleration and deceleration of the displacer. This is a discontinuous movement, as is the ideal thermodynamic Process corresponds, low loss possible. All bushings and thus Seals for linkage or crank mechanism can be omitted.
- a possible Fast power regulation is by changing the Displacer clock frequency immediately possible and does not have to by the Change in the upper temperature can be induced. This is in the Part load range a very good control possible.
- the regenerator if necessary, a heater upstream and / or downstream.
- the heater leads In addition to the heater head of the working space to the working medium energy, he thus increases the total receiving area in the hot area.
- a particular embodiment of the invention is characterized in that that the work space through the displacer into an expansion and a Compression space is shared, that the expansion space with this Workspace associated with regenerator and the regenerator with the Working machine is connected to the downstream side of the working machine with the compression space of the coupled other working space is connected and this compression space associated with this working space Regenerator is connected to the expansion space of the same working space, between Regenerator and upstream side of the working machine and Outflow side of the working machine and compression space one each Control member, in particular a valve, is provided.
- the work space through the displacer into an expansion and a Compression space is shared, that the expansion space with this Workspace associated with regenerator and the regenerator with the Working machine is connected to the downstream side of the working machine with the compression space of the coupled other working space is connected and this compression space associated with this working space Regenerator is connected to the expansion space of the same working space, between Regenerator and upstream side of the working machine and Outflow side of the working machine and compression space one each Control member, in particular
- Another particular embodiment of the invention is characterized that the work space through the displacer into an expansion and a Compression space is shared, that the expansion space with the upstream side of the Work machine and the working machine with their downstream side over the Regenerator and optionally a compressor with the Compression space of the coupled other working space is connected and this compression space assigned to this working space Regenerator is connected to the expansion space of the same working space, being between the expansion space and upstream side of the working machine and Outlet side of the regenerator and compression space each have a control member, in particular, a valve is provided.
- a control member in particular, a valve is provided.
- Another alternative embodiment of the invention is characterized in that that the working space through the displacer in two expansion and two Compression spaces is shared, that each expansion space over one Regenerator with the upstream side of the working machine and the downstream side of the Working machine with the compression room of coupled another Anlagenraumes is connected and this compression space over a Regenerator is connected to the expansion space of the other working space, wherein between the expansion space downstream regenerator and the upstream side of the working machine and the outlet side of the working machine and compression space each have a control member, in particular a valve, is provided.
- a control member in particular a valve
- the hot gases could be expanded, according to the Working principle of the hot engine.
- a further embodiment of the invention is characterized in that Flow direction after the section connected to the working machine, a heater is arranged. As a result, higher in front of the work machine Temperatures reached, which lead to a better power yield.
- the heater is local arranged separately from the section, for example in the combustion chamber of a Boiler.
- the device comprises using a Working medium for converting thermal energy into kinetic energy two closed workrooms 1, 2, wherein each working space 1, 2 by a movable displacer 3, 4 in two sections, namely in an expansion and a compression room, is divided.
- everyone Displacer 3, 4 is via a drive, in particular via a Linear drive 5, movable.
- Each working space 1, 2 has a him associated regenerator 6, 7 on. Both sections of the workspace 1 or 2 are with this regenerator 6 and 7 via lines 8, 9 and 10, 11 connected.
- control organs in particular Valves 13, provided between the working machine 12 and the individual sections of the working space 1 and 2 are arranged.
- Valves 13 could also find a slot control application.
- a turbine in particular an axial or Radial turbine use find.
- a piston or screw motor possible as a work machine 12 too a piston or screw motor possible.
- the working machine 12 is over a shaft 17 connected to the generator 18.
- the working medium between the two double-acting, closed work spaces 1, 2 flows back and forth.
- Delivery of useful work is the working medium between the workspaces 1, 2 passed over a working machine 12.
- the working medium flows in the double-acting working space 1, 2 by means of the displacer 3 and 4 of a Side through the regenerator 6 and 7 on the other side of the displacer 3rd 4, wherein the flow of the working medium is controlled via the valves 13 and each displacer 3, 4 is moved via a drive 5.
- the device is also a 4-quadrant turbine referred to as "hot” engine indicated as the working fluid in its highest temperature state is performed on the working machine 12.
- the expansion space is with the upstream side of the working machine 12 and the Working machine 12 with its downstream side via the regenerator 6 and 7 and via a compressor 19 with the compression space of the coupled other Workroom 2 connected.
- This compression space is about this Working space 2 associated regenerator 7 with the same expansion space Working space 2 connected, wherein between expansion space and upstream side the working machine 12 and outlet side of the regenerator 7 and Compression space each have a valve 13 is provided.
- the regenerator 6 or 7 consists of a heater 14, a Koppelregenerator 15 and a cooler 16, wherein the expansion space with the heater 14 and the compression space connected to the radiator 16 are.
- the regenerator 6 and 7 in the vertical direction in divided into individual sectors. These sectors are related to each other sealed. In the inner sectors, the working fluid flows from the Work machine 12 to the compressor 19 and the outer sectors are used for the regenerator cycle of the working medium.
- the expansion space is associated with the this working space 1 associated heater 14th of the regenerator 6 and the regenerator 6 with the working machine 12 connected.
- the downstream side of the working machine 12 is via the radiator 16 with the compression space of the coupled other working space 2 connected and this compression space is assigned via this working space 2 Regenerator 7 connected to the expansion space of the same working space 2.
- regenerator 6 and 7 and the upstream side of the working machine 12 and Outflow side of the working machine 12 or compressor 19 and compression space in each case a valve 13 is provided.
- the 4-quadrant turbine is shown as a "cold" engine.
- Working space 1 2 is again through the displacer 3, 4 in an expansion and shared a compression space.
- the working medium used for the useful work flows after Leaving the expansion space on the this working space 1 associated Regenerator 6 for delivery of useful work on the working machine 12 and after the work machine 12 in the compression space of the coupled Working space 2. Subsequently, the working medium flows through the movement the displacer 4 from the compression side through this working space. 2 associated regenerator 7 in the expansion space of the same working space. 2
- the device is shown as a low-temperature motor. there the displacers 3, 4 via a rigid connection 20 via a drive. 5 emotional.
- the working space 1, 2 is by the displacer 3, 4 in two Shared expansion or two compression rooms. Every expansion space of the Working space 1 is a regenerator 6, 7 with the upstream side of the Work machine 12 and the downstream side of the working machine 12 with the Compression space of the coupled other working space 2 connected.
- This Compression space is via the regenerators 6 and 7 with the expansion space the other working space 1 connected, between which the Expansion space downstream regenerator 6 and 7 and the upstream side the work machine 12 and the exit side of the work machine 12 and Compression space each have a valve 13 is provided.
- the working medium used for the useful work flows after leaving a Expansion space on the this working space 1 associated regenerator. 6 or 7 for delivery of useful work on the working machine 12 and after the Work machine 12 in the compression space of the coupled working space. 2 Subsequently, by the movement of the displacer 3 and 4 flows Working fluid from the compression side through this working space. 2 associated regenerator 6 and 7 in the other expansion space of the Workroom 1.
- this can for example in the soil to be ordered.
- displacers 3 and 4 can also be coupled membranes be executed.
- each working space 1, 2 by the displacer 3, 4 in an expansion space and divided into a compression room.
- Everyone Displacer 3, 4 is via a drive, in particular via a Linear drive 5, movable.
- each displacer 3, 4 in one Guide 22 stored.
- Each working space 1, 2 has an associated with him Regenerator 6, 7 up. Both sections of the work space 1 and 2 are with this regenerator 6 and 7 connected via lines.
- the expansion space is equipped with a reheater 21.
- This reheater 21 can be used as a layered reheater 21st be executed or constructed in the form of disk packs.
- the Compression space is provided with a cooler 16.
- the expansion space is optionally via the reheater 21 with a locally separate heater 14 connected.
- the heater 14 could be in be arranged a boiler.
- the isobaric Heating In the heater 14, the isobaric Heating.
- the working medium flows from the heater 14 via the Work machine 12.
- the work machine 12, preferably a Tesla turbine, is coupled to a generator 18 by a direct shaft 17.
- the working fluid flows through the regenerator. 7 and the radiator 16 in the compression space of the working space 2 and is through the afterflow or a compressor isothermal compressed.
- the Compression heat is released in the cooler 16 of the working space 2.
- the working medium passes through a figure-eight loop, with the Work machine 12 is provided in the center.
- the single ones Process steps are represented by the corresponding - not shown - Valves controlled.
- Fig. 5 the operation of the device with the valve control on Hand of a real example described.
- the working medium has a temperature To of 530 ° C and a pressure Po of 30 bar up.
- the working space 2 with the displacer 4 there is a Temperature Pu of 30 ° C and a pressure Pu of 10 bar.
- the 530 ° C hot Working fluid now flows from the working space 1 via the valve 23 in the Heater 14, where it is overheated to 630 ° C and then in the Working machine 12 by the polytrope relaxation back to 530 ° C. is brought.
- valve 24 the regenerator 7, where it is cooled to 60 ° C, the cooler 16, where it on 30 ° C is cooled, in the working space 2.
- the valves 25 and 26 are located in Locking direction to the pressure difference and open only after that following regenerator cycle, i. at the next working cycle.
- the Regeneratortakt begins after the power stroke pressure equalization between the two workrooms 1, 2 has made; i.e. all in one System prevails the same pressure (medium pressure).
- the displacers 3, 4 Now move to the opposite dead center and move doing the working medium through the regenerator cooler unit on the each other side of the displacer 3, 4.
- the thereby running isochore Heating or cooling of the working medium causes a Pressure change in the respective working space 1, 2; i.e. when pushing over from the cold to the hot, pressure increase occurs when sliding over from Hot in the cold occurs pressure reduction on the regenerator cycle is hereby finished and the pressure difference is for the next working cycle used.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Compressors, Vaccum Pumps And Other Relevant Systems (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT03735135T ATE306016T1 (de) | 2002-06-03 | 2003-06-02 | Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie |
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT8432002A AT500640B1 (de) | 2002-06-03 | 2002-06-03 | Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie |
| AT843022002 | 2002-06-03 | ||
| AT7672003A AT500641B8 (de) | 2002-06-03 | 2003-05-19 | Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie |
| AT767032003 | 2003-05-19 | ||
| PCT/AT2003/000160 WO2003102403A1 (de) | 2002-06-03 | 2003-06-02 | Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1509690A1 EP1509690A1 (de) | 2005-03-02 |
| EP1509690B1 true EP1509690B1 (de) | 2005-10-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP03735135A Expired - Lifetime EP1509690B1 (de) | 2002-06-03 | 2003-06-02 | Verfahren und einrichtung zur umwandlung von wärmeenergie in kinetische energie |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1509690B1 (da) |
| JP (1) | JP2005531708A (da) |
| CN (1) | CN1659371A (da) |
| AT (1) | AT500641B8 (da) |
| AU (1) | AU2003237553A1 (da) |
| CA (1) | CA2488241A1 (da) |
| DE (1) | DE50301321D1 (da) |
| DK (1) | DK1509690T3 (da) |
| MX (1) | MXPA04012100A (da) |
| WO (1) | WO2003102403A1 (da) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ297785B6 (cs) * | 2003-04-01 | 2007-03-28 | Zpusob a zarízení pro premenu tepelné energie na mechanickou | |
| DE102007039517B4 (de) | 2007-08-21 | 2010-04-29 | Waechter-Spittler, Freiherr von, Hartmut | Rotierende Hubkolbenmaschine |
| JP5317942B2 (ja) * | 2009-12-07 | 2013-10-16 | 横浜製機株式会社 | 外燃式クローズドサイクル熱機関 |
| JP5525371B2 (ja) * | 2010-08-02 | 2014-06-18 | 横浜製機株式会社 | 外燃式クローズドサイクル熱機関 |
| JP2014031726A (ja) * | 2012-08-01 | 2014-02-20 | Hidemi Kurita | スターリングエンジンの駆動制御方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US334153A (en) * | 1886-01-12 | George h | ||
| NL70865C (da) * | 1948-10-12 | |||
| US3248870A (en) * | 1960-07-29 | 1966-05-03 | Morgenroth Henri | Stirling cycle engine divided into a pressure generating unit and energy converting unit |
| US3678686A (en) * | 1970-02-20 | 1972-07-25 | Atomic Energy Commission | Modified stirling cycle engine-compressor having a freely reciprocable displacer piston |
| DE2402289C2 (de) * | 1974-01-18 | 1984-08-02 | M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8900 Augsburg | Mehrzylindrige Heißgaskolbenmaschine |
| US4012910A (en) * | 1975-07-03 | 1977-03-22 | Mark Schuman | Thermally driven piston apparatus having an angled cylinder bypass directing fluid into a thermal lag heating chamber beyond the bypass |
-
2003
- 2003-05-19 AT AT7672003A patent/AT500641B8/de not_active IP Right Cessation
- 2003-06-02 CA CA002488241A patent/CA2488241A1/en not_active Abandoned
- 2003-06-02 CN CN 03812774 patent/CN1659371A/zh active Pending
- 2003-06-02 DE DE50301321T patent/DE50301321D1/de not_active Expired - Fee Related
- 2003-06-02 WO PCT/AT2003/000160 patent/WO2003102403A1/de not_active Ceased
- 2003-06-02 MX MXPA04012100A patent/MXPA04012100A/es unknown
- 2003-06-02 DK DK03735135T patent/DK1509690T3/da active
- 2003-06-02 EP EP03735135A patent/EP1509690B1/de not_active Expired - Lifetime
- 2003-06-02 AU AU2003237553A patent/AU2003237553A1/en not_active Abandoned
- 2003-06-02 JP JP2004509264A patent/JP2005531708A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| DE50301321D1 (de) | 2005-11-10 |
| DK1509690T3 (da) | 2006-01-30 |
| JP2005531708A (ja) | 2005-10-20 |
| AT500641B1 (de) | 2006-08-15 |
| CA2488241A1 (en) | 2003-12-11 |
| AT500641A1 (de) | 2006-02-15 |
| WO2003102403A1 (de) | 2003-12-11 |
| AT500641B8 (de) | 2007-02-15 |
| EP1509690A1 (de) | 2005-03-02 |
| CN1659371A (zh) | 2005-08-24 |
| AU2003237553A1 (en) | 2003-12-19 |
| MXPA04012100A (es) | 2005-09-21 |
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