EP1436364A2 - Dispositif de production d'un melange gazeux combustible - Google Patents

Dispositif de production d'un melange gazeux combustible

Info

Publication number
EP1436364A2
EP1436364A2 EP02745106A EP02745106A EP1436364A2 EP 1436364 A2 EP1436364 A2 EP 1436364A2 EP 02745106 A EP02745106 A EP 02745106A EP 02745106 A EP02745106 A EP 02745106A EP 1436364 A2 EP1436364 A2 EP 1436364A2
Authority
EP
European Patent Office
Prior art keywords
reactor
starting material
gas mixture
wood
feed unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02745106A
Other languages
German (de)
English (en)
Other versions
EP1436364B1 (fr
EP1436364B2 (fr
Inventor
Bernd Joos
Claus Raach
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Joos Bernd
Original Assignee
Joos Bernd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Joos Bernd filed Critical Joos Bernd
Publication of EP1436364A2 publication Critical patent/EP1436364A2/fr
Publication of EP1436364B1 publication Critical patent/EP1436364B1/fr
Application granted granted Critical
Publication of EP1436364B2 publication Critical patent/EP1436364B2/fr
Anticipated expiration legal-status Critical
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/723Controlling or regulating the gasification process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/30Fuel charging devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/34Grates; Mechanical ash-removing devices
    • C10J3/40Movable grates
    • C10J3/42Rotary grates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/20Apparatus; Plants
    • C10J3/44Apparatus; Plants adapted for use on vehicles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/156Sluices, e.g. mechanical sluices for preventing escape of gas through the feed inlet
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/15Details of feeding means
    • C10J2200/158Screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903Feed preparation
    • C10J2300/0909Drying
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0916Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0956Air or oxygen enriched air
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0969Carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1693Integration of gasification processes with another plant or parts within the plant with storage facilities for intermediate, feed and/or product

Definitions

  • the invention relates to a device for producing a combustible gas mixture from a carbon-containing starting material, in particular from lumpy wood, according to the preamble of claim 1.
  • Wood gasifiers have been used for engine combustion for decades. For example, in 1923 the descending gasifier system was developed in direct current, the so-called /
  • the "Imbert wood gas plant” or comparable devices work in direct current, with lump wood in particular being fed to the reactor of the gas generator.
  • Special, generic gas generators are described, for example, in documents DE 198 30 069 AI, DE 196 43 109 AI or EP 137 461 A2 disclosed.
  • the wood is generally thermally broken down into different components in a first stage. This takes place above all in the reactor in a region of appropriately arranged air nozzles or the like by means of substoichiometric combustion or oxidation, heat being released and temperatures of a few hundred degrees, for example approx. 800 ° C., being reached.
  • the wood in the upper area of the reactor is partially pre-dried by rising heat.
  • coked wood or coal, water and other combustion products are produced which contain both combustible gas components and non-combustible gaseous intermediates, such as carbon monoxide (CO) and carbon dioxide (C0 2 ).
  • CO carbon monoxide
  • C0 2 carbon dioxide
  • the coked wood or the coal produced generally moves downwards from the oxidation zone into a reduction unit, thereby reducing some of the combustion products to other combustible gas components.
  • carbon dioxide is produced using coal, among other things. reduced to additional carbon monoxide, whereby a relatively high proportion of carbon monoxide can be achieved in the combustible gas mixture generated.
  • the combustible gas mixture mainly contains carbon monoxide, hydrogen and methane.
  • the volume of the wood is greatly reduced during the coking, so that a constriction of the reactor in the transition area of the oxidation zone to the reduction zone must be provided to form a comparatively compact reduction zone.
  • This constriction is often carried out using firebricks, steel elements or the like.
  • the compact reduction zone advantageously enables a reduction of the gas flow and at least partially one Filtration of solid components of the combustion products from the oxidation zone.
  • the combustible gas mixture generated is primarily discharged or sucked in from the reduction zone to a gas engine, gas storage device or the like. With the help of a movable grate, coal dust or possibly excess ash is separated from the coal.
  • the disadvantage here is that, above all, the quality of the gas mixture produced is reduced and, moreover, tar or tar gas is formed.
  • the relatively hot, gaseous tar optionally condenses on mechanically movable parts, in particular a feed unit for feeding the wood into the reactor, as a result of which tar is loaded and the functioning of the corresponding parts is severely impaired or the corresponding parts become stuck.
  • the wood is generally fed in above the oxidation zone.
  • the feed unit with or without a lock device, is arranged above the reactor, so that the feed takes place by opening a flap, a slide, a paddle wheel or the like.
  • disadvantageous "false air” is introduced into the reactor, which greatly affects the gasification of the wood.
  • the gas engine downstream of the wood gasifier is impaired or destroyed by relatively high tar contents in the gas mixture.
  • the gas engine can be used, for example, for a vehicle to generate heat, etc. be used by means of a corresponding generator for generating electricity and / or heat and / or the like.
  • the tar content in the wood gas should contain less than approx. 50 milligrams per cubic meter, as otherwise residues will occupy or stick to the valves of the gas engine. The result is that they block and cause the motor to stop. For these reasons, gas washing with cyclone separators, filters or the like is often connected upstream of the gas engine.
  • the object of the invention is to provide a device for producing a combustible gas mixture from a carbon-containing starting material, in particular from lumpy wood, with a supply unit for supplying the starting material to an oxidation zone of a reactor for oxidizing the
  • a supply unit for supplying the starting material to an oxidation zone of a reactor for oxidizing the
  • a device is characterized in that the feed unit is arranged laterally on the side of the reactor in the horizontal direction and the feed unit comprises at least one storage device for intermediate storage of the starting material.
  • the storage device can be used as a second storage unit of the device according to the invention.
  • This measure enables the supply of the starting material to the device according to the invention to be advantageously decoupled from the supply of the starting material to the reactor.
  • the largely continuous supply of the starting material to the reactor enables advantageous gasification of the starting material or wood, so that high quality Gas mixture can be generated.
  • the discontinuous, in particular comparatively short, supply of the starting material to the device according to the invention enables the quantity of “false air” to be reduced as much as possible by charging the device.
  • the storage device is advantageously designed to be gas-permeable in the direction of the reactor and to be largely gas-tight for charging.
  • the device according to the invention is generally charged, as in the prior art, by means of a storage or silo, day bunker or the like, ie a third storage device, which is largely independent of the pressure and reaction conditions of the reactor and is in particular not gas-tightly closed or "open" to the environment ,
  • the starting material arranged in the storage device forms a certain barrier, in particular for incoming or inflowing “false air”, so that it only enters the reactor with a delay and cannot largely impair the gasification.
  • an at least partially filled storage device also has a certain filter function for tar or the like that may be generated.
  • Corresponding tar, etc. is attached to the starting material or lumpy wood or the like, among other things, so that the tar can advantageously not impair a closing device for opening or largely gas-tight closing of the device according to the invention, in particular movable elements thereof.
  • the tar preferably comes back into the reactor together with the starting material, and it can be reacted accordingly.
  • the supply unit or parts of it cannot be impaired by tar that may be generated by the fact that the relatively hot tar gases rising in the reactor advantageously condense at the cover area or the like and may be discharged or preferably returned to the reaction zones for energy recovery ,
  • the lid area of the reactor is advantageously designed without mechanically movable elements or the like.
  • a reclosable reactor or a cover element can be provided, which in particular has to be sealed largely gas-tight, so that no disadvantageous “false air” can get into the reactor.
  • the tar in the reactor is preferably returned to the reaction zone (s) for shaping, so that the energy contained in the tar can be utilized by the device according to the invention.
  • the overall efficiency of the device according to the invention is significantly increased.
  • a largely continuous and / or automatic mode of operation of the device according to the invention can advantageously be implemented with relatively high operational reliability.
  • This enables a preferred, economical use of the device according to the invention in power plants for generating electrical energy or in combined heat and power plants, vehicles or the like, even under high operational and environmental requirements in corresponding systems.
  • any carbon-containing raw materials in particular renewable biomass, or any kind of wood.
  • softwood and / or hardwood can be used as wood chips, sawdust and / or pellet, other renewable raw materials such as straw and sewage sludge or the like, or corresponding mixtures.
  • the use of frequently occurring waste or residual wood ensures a particularly economical and environmentally friendly operation of the device according to the invention.
  • the starting material generally falls onto the oxidation zone in free fall, as a result of which a certain compression of the starting material is produced in the region of the oxidation zone.
  • the lateral arrangement of the feed unit according to the invention advantageously requires the starting material to be introduced laterally into the area of the oxidation zone, so that a largely loose layering of the starting material or of the wood in the reactor is achieved, in particular in the oxidation zone. This ensures an advantageous automatic advancement of the starting material into or from the oxidation zone and, if appropriate, into the reduction zone arranged underneath, which can effectively prevent so-called “hollow burning” of the reactor.
  • the possible lateral advancement of the starting material leads to a certain movement or rummaging through of the starting material in the region of the oxidation zone, as a result of which the gasification is additionally improved or “hollow burning” is prevented.
  • a thermal insulation layer formed from the starting material can be realized over the particularly hot section of the oxidation zone, thereby advantageously dissipating increasing heat can be reduced from the oxidation zone. Above all, this ensures an advantageous oxidation of the starting material.
  • the storage device is advantageously arranged between a feed opening of the reactor and a closure element of the feed unit for opening or largely gas-tight closing of the device.
  • this measure makes it possible to dispense with a closing device on the reactor or closing the feed opening of the reactor or the like.
  • the closure element ensures the supply to the device according to the invention and, moreover, is not to be arranged in the area of hot tar gases, so that tar is advantageously condensed or separated in front of the movable closure element.
  • the closure element is designed as a rotatable or pivotable flap or the like.
  • the closure element is preferably designed as a slide, which ensures, among other things, by means of an eccentric element that the loading opening of the device according to the invention is closed almost gas-tight. This increases the operational safety of the device.
  • an advantageous open and direct feed of the starting material or of the wood into the reactor can be provided.
  • a closing or the like between the reactor and the feed unit can advantageously be omitted. Accordingly, no corresponding movable element required for the closure can be impaired or destroyed in its function by tar which may be formed in the reactor.
  • a device can be implemented without movable elements or components of the feed unit in the relatively hot area of the device according to the invention, so that Tar gas cannot affect this.
  • At least one fill level sensor for measuring or determining the fill level or the fill level of the reactor is advantageously to be provided.
  • the fill level sensor can be designed, for example, as a partially mechanical, optical, radar, infrared, ultrasonic, sensor and / or the like.
  • a sensor that mechanically scans the fill level can be implemented in a comparatively simple manner, above all because of the lateral arrangement of the feed unit.
  • the senor has an at least partially rotatably supported and / or deformable impact element, e.g. a baffle plate or filler tab against which the starting material is moved or transported and / or which is arranged or rests on the oxidation zone.
  • the sensor element is advantageously cleaned of any deposits or the like that may be present, which can improve the operational safety of the device.
  • At least the shaft or axis of the sensor is advantageously protected by means of a protective element, e.g. a condensation element or a tar bell or the like, from impairments such as the deposition of contaminants, mechanical damage, etc. protected.
  • a protective element e.g. a condensation element or a tar bell or the like
  • the rotatably mounted element may be arranged on a lever arm or the like.
  • the protective element has an opening e.g. in the form of a slot in which the lever arm is arranged.
  • the sensor interacts, among other things, with an electrical switching element and an electronic control or regulating unit to change the position and / or angular deflection of the element, which is in particular rotatably mounted.
  • an electrical switching element and an electronic control or regulating unit to change the position and / or angular deflection of the element, which is in particular rotatably mounted.
  • a control or regulating unit is preferably provided for the almost fully automatic control or regulation of the device according to the invention.
  • this enables a controlled and metered supply of the starting material, inter alia in cooperation with the level sensor of the reactor.
  • a largely constant filling level can be adjusted in the reactor.
  • the air supply to the reactor can be regulated or depending on the level of the reactor and / or the quantity of the starting material or the quantity of the combustible gas mixture, etc. adjust.
  • the feed unit comprises at least one transport device for transporting the starting material from the storage device into the reactor.
  • the transport device has an at least partially ascending or oblique transport direction of the starting material in the vertical direction.
  • the transport device is designed as a transport device which rises obliquely in the direction of the reactor, in particular a channel-shaped or tubular transport device.
  • an upper end of the transport device opens into or on the reactor and a lower end or a lower region of the transport device is arranged essentially in the vertical direction below the storage device.
  • the storage device advantageously has a clearing element for clearing or supplying the starting material to the transport device or to the reactor. This advantageously prevents that relatively bulky wood or the like can get caught in the storage device or clog it and thus prevent it from moving up of the starting material to the reactor is interrupted or impaired.
  • the storage device is arranged essentially to the side of the reactor, so that a comparatively compact device according to the invention can be realized with a relatively low height. If necessary, the device according to the invention can be integrated in a structural unit which is preferably designed with thermal insulation or the like, as a result of which the thermal energy can be advantageously integrated.
  • the transport device may have an almost vertically ascending section and / or both a section ascending in the area of the reactor and a section descending in the area of the storage device.
  • condensed liquids can optionally be drained off in the depression created in this way or in a transport device which, as viewed in the direction of transport, largely rises steadily.
  • the transport device optionally comprises a transport and / or vibrating belt.
  • the transport device comprises at least one spiral transport element.
  • a so-called worm drive can be provided for the transport device.
  • the worm drive is designed in particular as a U-shaped tubular element, so that generally viewed in the vertical direction above there are cavities for, for example, relatively bulky starting materials such as lumpy wood or the like. These measures largely prevent jamming or the like of the worm drive.
  • the worm drive or the transport device has a comparatively large play, whereby sticking or the like can be largely prevented.
  • the lower region of the storage device preferably tapers, so that advantageous emptying can be achieved.
  • the outlet opening of the storage device is smaller than the cross section of the transport device and / or is adapted to the slope of the spiral transport element. This improves the regulation of the quantity of starting material to be transported, which can lead, among other things, to advantageous heat treatment in the area of the transport device, which may be provided. In addition, jamming of the starting material in the region of the outlet opening of the storage device is effectively prevented.
  • a slide or the like is also conceivable for closing the outlet opening of the storage device, which could additionally reduce the penetration of “false air” during loading. In this case, the storage device would be designed as a lock.
  • the feed unit advantageously comprises a distribution element for largely uniform distribution of the starting material over almost the entire cross section of the oxidation zone of the reactor.
  • the distribution element is designed, for example, as an element tapering in the transport direction and arranged under the transport element.
  • the feed unit has at least one heating device for heating the starting material.
  • This enables the starting material to be fed to the reactor to be fed to the reactor relatively warm and / or dry, if necessary. If necessary, it can also be comparatively moist Starting material or moist wood of the device according to the invention or the storage device can be supplied, for example wood with relatively high moisture and / or partially moist sewage sludge or the like.
  • a starting material is to be provided in which the moisture is such that comparatively little or almost no water is obtained in the region of the transport device and / or the storage device.
  • heating devices can be used, e.g. by means of electrical, chemical energy, in particular by means of combustion, and / or supply of a relatively hot heating medium.
  • the starting material is advantageously heated or dried in such a way that it is prepared for the subsequent gasification in the reactor.
  • the heating device advantageously has at least one first heat exchanger element for cooling the gas mixture.
  • This advantageously enables the supply unit to be heated and additionally the combustible gas mixture to be cooled.
  • a gas engine or the like that is relatively downstream of the device according to the invention, or a relatively cold gas mixture, in particular without a comparatively large intermediate storage unit, can be provided almost immediately.
  • a relatively cold gas mixture advantageously improves combustion in the gas engine, so that a higher overall efficiency of the entire system can be achieved.
  • the heating device comprises at least one further, second heat exchanger element with a heating fluid.
  • the so-called second can of course also be used alone as a heating device without the so-called first heat exchanger element.
  • This Heat exchanger element if necessary, can be used to heat the starting material in the region of the feed unit, in particular relatively strongly, which can additionally improve the gasification in the reactor.
  • Exhaust gas from the downstream gas engine or the like can advantageously be used as the heating fluid.
  • the exhaust gas can possibly be several hundred degrees Celsius. It is conceivable that the starting material is heated to such an extent that it partially oxidizes in the area of the feed unit, which may have a positive effect on the conversion of the starting material in the reactor.
  • the feed unit or transport device is at least partially designed as a pre-reactor.
  • the heating device is preferably arranged at least in the region of the transport device.
  • the device according to the invention is largely coated with at least one thermal insulation device, so that thermal losses can be largely prevented.
  • This enables advantageous heat management of the entire device according to the invention, as a result of which the gasification of the starting material can advantageously be implemented.
  • the reactor has an operating temperature of approximately 800 ° C. This ensures both advantageous oxidation and reduction in the corresponding zones of the reactor.
  • the reduction zone of the reactor has an operating temperature which, in addition to a reduction of carbon dioxide and / or the like, above all also a conversion of dust or generated in the oxidation zone the like. This measure in particular improves the quality of the gas mixture to be generated for use or combustion in a gas engine.
  • the arrangement of the heating device in the region of the transport device enables a relatively large heat-transfer area to be achieved in relation to the amount of the starting material to be heated, as a result of which the heating of the starting material to be fed to the reactor can advantageously be achieved.
  • a comparatively long-lasting heating in particular in the case of a relatively long or stretched variant of the transport device, can also be implemented, as a result of which, for example, the drying of the starting material, in particular wood, is improved.
  • Relatively long transport devices allow, for example, an advantageous adaptation to the spatial framework conditions of the installation site or the space available for the device according to the invention.
  • an adaptation in particular the temperature conditions in the feed unit, to the operating conditions of the device according to the invention or in the reactor can preferably be provided, such as Feeding, start-up phase, type of wood, reactor and / or air temperature, etc.
  • one or more cleaning stages or devices can be arranged between the gas engine and the device according to the invention, for example gravitational separators, inertial cleaners such as centrifugal separators or cyclone or baffle plate cleaners, wet washers, oil bath, gravel or sand bed, electrical, , Adsorption filters such as fabric, cork, activated carbon or ceramic filters, catalytically active cleaning elements, etc.
  • the cleaning device is preferably designed to be regenerable. For example, a so-called afterburning of gravel bed filters or the like can take place, so that they can be reused and almost exclusively "white" ash is generated as waste.
  • appropriately contaminated oil from an oil bath filter can be introduced into the storage device of the supply unit, so that on the one hand its energy is utilized and on the other hand the amount of waste is reduced.
  • At least two, in particular time-operated, cleaning devices or filters are provided.
  • a filter is regenerated, cleaned or afterburned while another filter is operated in the filter phase.
  • sensors can be used in the device according to the invention, in particular in the reactor.
  • These sensors cooperate in particular with a corresponding evaluation and / or control unit for the largely automatic operation of the device according to the invention.
  • At least one condensation element for holding condensable substances or substance mixtures is arranged in the upper region of the reactor.
  • Preferably two condensation elements are provided, with one condensation element, in particular, condensing tar gas in a special operating case as tar, and in particular also discharging it into the reaction zones is returned, for example in the approximately 800 ° C hot area of the reactor for combustion and / or out of the reactor.
  • the second condensation element is provided for the condensation of possibly occurring water vapor or the like, so that, in particular, relatively unpolluted water can advantageously be removed from the reactor.
  • An air supply device for supplying air to the oxidation zone advantageously has at least one heating unit for heating the air to be supplied. This enables advantageous preheating of the air to be fed to the reactor. This improves the gasification of the raw material or the wood and also increases the quality of the flammable gas mixture.
  • the oxygen in the air is generally decisive for the gasification, so that, in a special variant of the invention, almost pure oxygen can also be fed to the reactor.
  • a humidification unit for regulating or humidifying and / or dehumidifying the air to be supplied must also be provided.
  • the heating unit is preferably designed as a heat exchanger element for heat exchange of the air to be supplied with the reactor.
  • the air supply device is advantageously arranged essentially along the circumference of the reactor. With the help of these measures, extensive energy management of the device according to the invention can be implemented.
  • the temperature in the reactor is of crucial importance, particularly in the gasification of wood, so that a particularly advantageous gasification is made possible by extensive energy management.
  • the air supply device is arranged at least in the upper region of the oxidation zone. This ensures that the relatively hot upper area of the reactor, ie in the area of the oxidation zone, can be used for the relatively hot preheating of the air or the like. This additionally improves the conversion of the starting material, which leads to a particularly high quality of the combustible gas mixture.
  • the reactor advantageously has a smaller diameter and / or cross section at least in the area of the supply unit than in the area of the air supply device.
  • this measure makes it possible for the starting material in the region of the air supply device to fill up or fall apart and thus to have more or larger gaps.
  • the air or oxygen can advantageously oxidize the starting material or the wood.
  • air, oxygen, carbon dioxide or the like can advantageously be supplied in particular by the air supply device by means of a pressure generating unit, e.g. Blower, pump, etc., are introduced into the reactor.
  • a pressure generating unit e.g. Blower, pump, etc.
  • pressure equalization is preferably implemented in the reactor, so that the “supply of false air” and thus the risk of hollow fire is further reduced.
  • an apparatus is at least partially movable Grate element for removing coal dust, ash and / or the like from the reactor.
  • coal dust and / or possibly accumulated ash can be separated from the coal or the reduction zone and / or removed.
  • the grate element has openings such as slots or the like.
  • the grate element has at least one section sloping vertically towards the edge region. This measure essentially avoids the accumulation of material in the central area of the grate element due to the shaking. In addition, this enables the coal dust, the ashes or the like to be separated from the reduction zone, in particular towards the jacket region of the lower section of the reactor, so that the ashes or the like can be carried out comparatively easily from the reactor manually and / or largely automatically.
  • the grate element is designed as a collecting element, in particular a filter element or sieve or the like, for retaining the intermediate product.
  • the collecting element is preferably designed such that it largely closes the reactor at the bottom and / or at the side.
  • the grate element is arranged as an almost closed element or cage, basket or the like around the lower region of the reactor or the reduction zone.
  • ash or the like can be removed from the reactor.
  • the ash or the like is preferably suctioned off from the reactor area, in particular with the aid of the gas mixture or gas engine.
  • a gas mixture removal opening is arranged in the lower area or at the bottom of the reactor, so that ash or the like advantageously comes out of the reactor is removable.
  • ash or the like advantageously comes out of the reactor is removable.
  • the grate element preferably has areas, structures or elements which increase the surface area, so that, inter alia, the gas flowing through the reactor has a relatively long residence time or reaction time therein and thus the generation of the combustible gas mixture is improved.
  • this measure reduces the gas resistance, which in particular increases the degree of engine filling and thus the gas engine can be operated advantageously.
  • the grate element is designed to be height-adjustable or adjustable in the longitudinal direction of the reactor.
  • the amount of material or the volume of the reduction zone and / or the residence time of the reaction gas in the reduction zone can be changed or regulated.
  • Foreign material such as stones, etc. may collect. in the reactor, so that the volume or the amount of the intermediate product in the reduction zone can be adjusted by means of the aforementioned measure. This additionally improves the generation of the combustible gas mixture.
  • a reactor can be used with the device according to the invention be realized, the an approximately constant level, a largely constant amount of coal in the reduction zone, a glowing, relatively hot, e.g. about 800 ° C hot, coal in the reduction zone, almost no waste, except possibly relatively small amounts of coal dust, in Generally no so-called hollow burning or burning through and above all largely no tar or tar gas.
  • the coal dust is returned to the oxidation zone in an advantageous manner, so that the device according to the invention is largely free of waste.
  • an automatic loading of the device according to the invention can be provided. In general, you can also load manually.
  • FIG. 1 shows a schematic representation of a device according to the invention
  • FIG. 2 shows a schematic section of a further device according to the invention
  • Figure 3 is a schematic detail of a feed of the starting material
  • Figure 4 is a schematic detail of a storage device.
  • the storage silo 3 comprises a storage volume that is many times larger than the volume of a storage device 4 of the feed unit 2.
  • the comparatively large volume of the silo 3 enables wood chips to be stored for a relatively long operating time of the device according to the invention, e.g. one or more weeks or months.
  • the wood in the silo 3 is preferably predried by means of heat, in particular waste heat from the reactor 1.
  • the silo 3 is optionally designed as an open silo 3, storage space with a loading device for loading the device according to the invention or the like.
  • the storage device 4 has, for example, a volume which is sufficient to operate the reactor 1 for approximately several hours or approximately one day without opening a nearly gas-tight flap 6 or without loading from the silo 3.
  • the gas-tight closure of the storage device 4 can alternatively also be implemented by means of a slide or the like.
  • the wood chips are fed to the device according to the invention by means of a screw feed 5.
  • the flap 6, which closes largely gas-tight, is opened for loading.
  • the loading phase can take several minutes last, in particular until the storage device 4 is largely filled and the flap 6 can be closed again almost gastight.
  • a fill level sensor 22 may determine the fill level of the storage device 4, e.g. a full wing detector, ultrasonic sensor or the like.
  • the flap 6 is preferably to be actuated hydraulically, pneumatically, mechanically and / or electrically, a flap 6 which can be actuated and actuated largely automatically being advantageous.
  • the wood chips are transported or fed from the storage device 4 into the reactor 1 by means of a worm drive 7.
  • An electric motor 8 is advantageously provided for this.
  • both a heat exchanger for cooling the combustible gas mixture generated and a heat exchanger for heat recovery of the heat contained in an exhaust gas stream of the gas engine, not shown, are arranged in a manner not shown.
  • the two heat exchangers are preferably arranged as half-shell-like elements arranged around the worm drive and / or as tubular elements around the worm drive 7.
  • a multi-stage heating of the wood chips in the area of the worm drive 7 with different temperature levels can be realized in an advantageous manner.
  • the combustible gas mixture generated by the reactor 1 is discharged from the reactor 1 by means of a gas connection 9 to a gas engine (not shown in more detail), the gas mixture generally being cleaned beforehand by means of a cyclone filter and mixed with air by means of an air mixer.
  • the worm drive 7 can also be a have electrical heating of the screw element. Already in the area of the worm drive 7, the wood chips are partially pre-dried and preheated under certain operating conditions.
  • the reactor 1 comprises in particular an oxidation zone 10 and a reduction zone 11, a firebrick wall 12 being provided as a constriction 12 in the transition area of the two zones 10 and 11.
  • a firebrick wall 12 being provided as a constriction 12 in the transition area of the two zones 10 and 11.
  • glowing or oxidizing wood chips 10 with substoichiometric combustion and largely below the constriction glowing coal 11 are provided according to the invention largely above the firebrick wall 12 during operation of the reactor 1.
  • An approx. 10 to 20 cm thick non-glowing wood chip layer covering the glowing wood chips is formed on the glowing wood chips, which is thermally insulated, in particular, the glowing zone 10 and at the same time is provided as a drying zone or heating zone for the wood chips.
  • the reactor 1 In order to determine the fill level of the wood chips, the reactor 1 has a fill level indicator 15, which is shown folded up according to FIG. 1 or 2. As a mechanical sensor 15, the latter can detect the filling level of the reactor 1 and actuate an electrical switching element at a predetermined filling level, so that 7 chips are fed to the reactor 1 by means of the worm drive 7. Both a phased and almost continuous feeding of wood chips can be realized.
  • the supply of oxygen to the reactor or to the oxidation zone 10 takes place in particular by means of several, for example about five, air nozzles 16.
  • the use of individual air nozzles 16 has the advantage that the air flowing through them can be used for advantageous cooling of the air nozzles 16, as a result of which a complex cooling of the nozzles 16 and / or relatively low heat-resistant materials can be provided for the air nozzles 16.
  • the air to be fed to the reactor 1 flows through a heat exchanger 18, which is preferably arranged in the region of the relatively hot oxidation zone 10 and / or in the circumferential direction largely completely in the jacket region of the reactor 1.
  • the air supply also comprises an advantageous air ring 17, which enables an almost uniform or evenly heated supply of the air by means of all radially arranged air nozzles 16 to the oxidation zone 10.
  • the heat exchanger 18 is additionally preheated by the outflowing gas mixture.
  • the reactor 1 has a so-called sniffer flap 14, especially for supplying the outside air to the air rings 17 and 18.
  • a condensation element 24 enables condensation of tar and a condensation element 23 enables condensation of water in the upper region of reactor 1, so that an advantageous separation of tar and water takes place and the tar is returned to reaction zones 10 and 11 in a manner not shown can be.
  • the water is preferably discharged from the reactor 1.
  • FIG. 2 shows a section of a further device according to the invention.
  • the reactor 1 has, in particular, a sensor 15 designed as a baffle plate 15 or filler tab 15.
  • the reactor 1 according to FIG. 2 also has a smaller diameter in the area of the feed unit 2 than in the area of the air nozzles 16, so that introduced lumpy wood or the like cannot get caught and that it is loose, with relatively large gaps in the oxidation zone 10. As a result, the oxidation of the starting material is improved or hollow burning of the reactor 1 is avoided.
  • a grate element 19 designed as a grate basket 19 is provided.
  • the grate basket 19 encloses the fireclay wall 12 almost completely, so that generally no coal gets into the ash box 20.
  • an ash tray 22 and the gas connection 9 arranged under the reduction zone 11 the ash produced is removed from the reactor 1 and then separated from the gas mixture by means of a filter. As a result, there is no need to open the reactor 1 to remove the ash, so that penetration of “false air” is counteracted effectively.
  • the vibrating grate 19 has an elevation 24 in the central region of the axis of rotation, so that accumulation of material by rotation or shaking in the region of the axis of rotation is prevented.
  • the reactor 1 can have both a round, elliptical, rectangular, star-shaped or similar cross section, or a cross section having ribs or branches or the like, in particular in the region of the air nozzles 16.
  • a comparatively powerful or large-sized reactor 1 can be implemented without disadvantageous oxidation.
  • FIG. 4 shows a top view of the lower region of the storage device 4 with a scraper 25 and an outlet opening 26.
  • the scraper 25 and the opening 26 which is smaller in comparison to the diameter of the screw conveyor 7 and which is also adapted to the screw pitch, advantageously regulate the Reactor 1 transported amount of wood chips can be realized, which among other things improves the predrying of the starting material in the area of the transport device 7.
  • a closure element is conceivable for closing the opening 26 while the storage device 4 is being loaded.
  • the device according to the invention can largely be realized with relatively ordinary steel or the like, which, in addition to a comparatively good thermal conductivity of the material used, which has an advantageous effect on the gasification, also enables economically advantageous production.
  • the device according to the invention for fuel production for a gas engine in particular one Vehicle, cogeneration, electrical power generation, or the like can be used.
  • a corresponding system with a device according to the invention is to be provided together with a gas engine and optionally an electrical generator.
  • the reactor can have two or more feed units. This enables a separate supply of different starting materials such as sawdust, wood chips, straw, sewage sludge or the like to the reactor, as a result of which advantageous mixing of the starting materials in the reactor can be achieved. A possible disadvantageous separation of the starting materials can be prevented in this way. As an alternative or in combination with this, different starting materials can also be loaded into a single feed device or storage device.
  • the device according to the invention can be used to generate fuel from a fuel cell, i.e.
  • the generator or the internal combustion engine is designed as a fuel cell.
  • the hydrogen, methane or the like of the fuel gas or wood gas can be provided in corresponding fuel cells for generating electrical energy.
  • several or numerous devices according to the invention can be modularly coupled and operated, in particular for realizing comparatively powerful or large units. If necessary, one or more gas engines and / or electrical generators can be provided. If one module fails, another module can advantageously at least partially compensate for the failure.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Carbon And Carbon Compounds (AREA)
EP02745106.1A 2001-05-31 2002-05-31 Dispositif de production d'un melange gazeux combustible Expired - Lifetime EP1436364B2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10126426 2001-05-31
DE10126426 2001-05-31
PCT/DE2002/002002 WO2002097015A2 (fr) 2001-05-31 2002-05-31 Dispositif de production d'un melange gazeux combustible

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EP1436364A2 true EP1436364A2 (fr) 2004-07-14
EP1436364B1 EP1436364B1 (fr) 2010-06-30
EP1436364B2 EP1436364B2 (fr) 2016-02-10

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EP (1) EP1436364B2 (fr)
AT (1) ATE472590T1 (fr)
AU (1) AU2002317170A1 (fr)
DE (2) DE10224531B4 (fr)
WO (1) WO2002097015A2 (fr)

Cited By (3)

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EP2789675A1 (fr) 2013-04-08 2014-10-15 Markus Nyenhuis Système de réacteur de gazéification comprenant au moins un réacteur de gazéification pour la génération d'un mélange de gaz combustible
DE102017122380A1 (de) 2017-09-27 2019-03-28 Spanner RE2 GmbH Generatoranlage zur Erzeugung elektrischer Energie
WO2020058093A1 (fr) 2018-09-17 2020-03-26 Ecoloop Gmbh Procédé pour l'oxydation partielle de produits de dégradation générés par pyrolyse pour produire un gaz de synthèse dans un réacteur à courant continu

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DE102005028377B4 (de) * 2005-06-20 2013-07-25 Bernd Joos Vorrichtung zur Erzeugung eines brennbaren Gasgemisches
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DE202007002014U1 (de) * 2007-02-12 2007-05-24 Joos, Bernd Vorrichtung zur Erzeugung eines brennbaren Gasgemisches
DE102009012501B4 (de) 2008-03-12 2012-05-24 Alfred Heine Reaktor für eine Holzvergaseranlage und Verfahren zum Betreiben des Reaktors
DE102008021626A1 (de) * 2008-04-30 2009-11-12 Krones Ag Vergaser für Biomasse
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DE102009042104B4 (de) * 2009-09-21 2011-12-29 Bernhard Werner Holzgaskessel
WO2012082026A1 (fr) * 2010-12-13 2012-06-21 Lars Johansson Procédé et dispositif comprenant deux vis d'alimentation pour l'exploitation en continu d'un réacteur de pyrolyse
DE102012009200A1 (de) 2011-05-12 2012-11-15 Bernd Joos "Vorrichtung zur Erzeugung eines brennbaren Gasgemisches"
DE102013004441A1 (de) 2012-03-16 2013-09-19 Spanner RE2 GmbH "Vorrichtung zur Erzeugung eines brennbaren Gasgemisches"
DE102013003319A1 (de) 2013-02-28 2014-08-28 Spanner RE2 GmbH Vorrichtung zur Erzeugung eines brennbaren Gasgemisches
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Publication number Priority date Publication date Assignee Title
EP2789675A1 (fr) 2013-04-08 2014-10-15 Markus Nyenhuis Système de réacteur de gazéification comprenant au moins un réacteur de gazéification pour la génération d'un mélange de gaz combustible
DE102017122380A1 (de) 2017-09-27 2019-03-28 Spanner RE2 GmbH Generatoranlage zur Erzeugung elektrischer Energie
WO2020058093A1 (fr) 2018-09-17 2020-03-26 Ecoloop Gmbh Procédé pour l'oxydation partielle de produits de dégradation générés par pyrolyse pour produire un gaz de synthèse dans un réacteur à courant continu

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DE50214513D1 (de) 2010-08-12
AU2002317170A1 (en) 2002-12-09
DE10224531B4 (de) 2013-02-28
EP1436364B1 (fr) 2010-06-30
WO2002097015A3 (fr) 2004-05-06
ATE472590T1 (de) 2010-07-15
EP1436364B2 (fr) 2016-02-10
WO2002097015A2 (fr) 2002-12-05
DE10224531A1 (de) 2002-12-12

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