EP1349912B1 - Utilisation de produits a base d'acide percarboxylique, contenant des tensio-actifs et moussant peu pour la desinfection en circuit ferme - Google Patents
Utilisation de produits a base d'acide percarboxylique, contenant des tensio-actifs et moussant peu pour la desinfection en circuit ferme Download PDFInfo
- Publication number
- EP1349912B1 EP1349912B1 EP01271432A EP01271432A EP1349912B1 EP 1349912 B1 EP1349912 B1 EP 1349912B1 EP 01271432 A EP01271432 A EP 01271432A EP 01271432 A EP01271432 A EP 01271432A EP 1349912 B1 EP1349912 B1 EP 1349912B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- acid
- peracids
- agent
- ppm
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002253 acid Substances 0.000 title claims abstract description 31
- 239000004094 surface-active agent Substances 0.000 title claims abstract description 25
- 239000006260 foam Substances 0.000 title description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 27
- -1 alkylether sulfates Chemical class 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 150000007513 acids Chemical class 0.000 claims abstract description 17
- 150000004965 peroxy acids Chemical class 0.000 claims abstract description 17
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 15
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 14
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000003871 sulfonates Chemical class 0.000 claims abstract description 8
- 150000001875 compounds Chemical class 0.000 claims abstract description 7
- 150000003460 sulfonic acids Chemical class 0.000 claims abstract description 6
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 5
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 5
- 239000001257 hydrogen Substances 0.000 claims abstract description 5
- 150000003839 salts Chemical class 0.000 claims abstract description 3
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 24
- 230000000249 desinfective effect Effects 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000009434 installation Methods 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- 239000002537 cosmetic Substances 0.000 claims description 4
- 235000013305 food Nutrition 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- CVXHBROPWMVEQO-UHFFFAOYSA-N Peroxyoctanoic acid Chemical compound CCCCCCCC(=O)OO CVXHBROPWMVEQO-UHFFFAOYSA-N 0.000 claims description 2
- 230000002378 acidificating effect Effects 0.000 claims description 2
- ADKBGLXGTKOWIU-UHFFFAOYSA-N butanediperoxoic acid Chemical compound OOC(=O)CCC(=O)OO ADKBGLXGTKOWIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003651 drinking water Substances 0.000 claims description 2
- CZPZWMPYEINMCF-UHFFFAOYSA-N propaneperoxoic acid Chemical compound CCC(=O)OO CZPZWMPYEINMCF-UHFFFAOYSA-N 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 2
- 235000012206 bottled water Nutrition 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000243 solution Substances 0.000 description 33
- 239000000645 desinfectant Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 15
- 238000009736 wetting Methods 0.000 description 13
- 238000005187 foaming Methods 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- KEFJJXAABZFJSU-UHFFFAOYSA-N 2-hydroxy-n-(2-hydroxyethyl)ethanamine oxide Chemical compound OCC[NH+]([O-])CCO KEFJJXAABZFJSU-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- VUWCWMOCWKCZTA-UHFFFAOYSA-N 1,2-thiazol-4-one Chemical class O=C1CSN=C1 VUWCWMOCWKCZTA-UHFFFAOYSA-N 0.000 description 1
- BITAPBDLHJQAID-MDZDMXLPSA-N 2-[2-hydroxyethyl-[(e)-octadec-9-enyl]amino]ethanol Chemical compound CCCCCCCC\C=C\CCCCCCCCN(CCO)CCO BITAPBDLHJQAID-MDZDMXLPSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 229940120146 EDTMP Drugs 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 241000235070 Saccharomyces Species 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical compound OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 description 1
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 150000003977 halocarboxylic acids Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 235000015243 ice cream Nutrition 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- ONHFWHCMZAJCFB-UHFFFAOYSA-N myristamine oxide Chemical compound CCCCCCCCCCCCCC[N+](C)(C)[O-] ONHFWHCMZAJCFB-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Definitions
- the present invention relates to the use of low-foaming, surfactant-containing Percarboxylic acid agent for CIP disinfection.
- halogen-releasing substances such as Monobromoacetic acid
- oxidative compounds such as chlorine dioxide, peracetic acid, Active chlorine
- antimicrobial substances such as isothiazolinones for cleaning and / or disinfection of hard surfaces
- foaming Surfactants it may be that such agents in the cleaning solution the Promote formation of foam, which, for example, in some of the applications the food manufacturing industry but also in the pharmaceutical or cosmetic industry etc. is not desired.
- the object of the present invention was to simple To seek means in their use in disinfection in the CIP process a very good disinfection result is achieved and at the same time the wetting properties be positively influenced, without one for the CIP process disturbing foam behavior would be observed.
- CIP is a common abbreviation in the professional world and stands for Cleaning in place.
- the skilled artisan understands that hard surfaces of objects, containers, tanks, such as milk or fermentation tanks in breweries usually automatically by locally stored cleaning and / or disinfecting agent via installed on site or in the object to be cleaned devices and devices, such as lines, pumps, nozzles, containers, spray heads, are treated.
- CIP purification is Cleaning and / or disinfecting hard surfaces in a specific Procedure, the CIP procedure. Due to the turbulent movement of the cleaning and the disinfectant solution by pumping, spraying and other operations are agents and solutions that tend to foam, for the CIP process completely unsuitable.
- Another disadvantage of common aqueous disinfectant solutions for CIP processes is also that they due to their poor wetting properties are unable to penetrate into microscopically small gaps, surfaces, Scratches and imperfect corners and edges of stainless steel equipment areas to get rid of harmful microorganisms completely.
- Surfactants which work low foams in the CIP range are, for example, substances such as fatty alcohol ethoxylates and propoxylates. These substance classes prohibit in the application, as they are beyond the mechanism of the cloud point only at elevated (> 30 ° C) temperatures low in foam. Since the according to present invention to be considered percarboxylic acids, preferably cold (5 ° C to 30 ° C), the mechanism of these surfactants can not be used. Other tested surfactants, which are good even in the cold Low foaming, have the disadvantage that they are due to the strong oxidizing power of Disinfectants (percarboxylic acid) are destroyed, or that they themselves destroy the disinfectant.
- the agent to be used according to the invention contains sulfonic acids or sulfonates which are selected from xylene, octyl, naphthyl and alkylbenzenesulfonic acids or sulfonates, in which case the alkyl group contains between 6 and 16 carbon atoms.
- the surfactants used in the agent to be used according to the invention are alkylbenzenesulfonic acids or sulfonates and / or ethercarboxylic acids.
- alkylamine oxides are contained as preferred components in the agent to be used in the present invention, these are preferably selected from the trialkylamine oxides having an alkyl group containing 8 to 20 carbon atoms and two alkyl groups having a smaller number of carbon atoms in the alkyl chain, the two shorter alkyl groups being the same or different it being most particularly preferred that the selected amine oxide (s) include tallow fatty bis (2-hydroxyethyl) amine oxide, oleyl bis (2-hydroxyethyl) amine oxide, coconut bis (2-hydroxyethyl -) - amine oxide, tetradecyldimethyl-amine oxide and / or alkyldimethyl-amine oxide having 12 to 18 carbon atoms in the alkyl chain are.
- the agents to be used according to the invention or their diluted solutions for CIP disinfection in the food, pharmaceutical or cosmetics industry.
- the agents to be used according to the invention contain additional Components with complexing properties.
- Suitable phosphonic acids are, for example, 1-hydroxyethane-1,1-diphosphonic acid, diethylenetriaminepentamethylenephosphonic acid or ethylenediamine tetramethylenephosphonic acid and, in each case, their alkali metal salts.
- Preferred application forms of the agents to be used according to the invention are aqueous solutions, gel, emulsion or paste.
- the antimicrobial effect was surfactant as well corresponding surfactant-free peracetic acid disinfecting solutions Saccharomyces cerivisiae var. Diastaticus examined.
- the agents V1 and E1 with water to a concentration of 0.5% by weight and 1% by weight, respectively adjusted to the entire solution.
- Said comparison means V1 and the agent E1 to be used according to the invention are contained in Table 1. It should be noted that the preparation of E1 and V1 was carried out so that in the agent to be used in both cases about 4.5 wt .-% peracetic acid, based on the total agent, were present.
- the wetting behavior was 0.1% by weight, Containing 0.5 wt .-% and 1.0 wt .-% peracetic acid disinfecting solutions examined by E1 and V1.
- the correspondingly diluted solutions of E1 or V1 were prepared in 250 ml beakers. Subsequently, previously degreased stainless steel sheets were immersed in these solutions. In the next step, the sheets were removed from the solutions with tweezers. The remaining solution is allowed to drain for 10 seconds. Thereafter, the extent of surface wetting was visually estimated. It was found that at all three concentrations of E1, the degreased stainless steel sheets were wetted to about 95%.
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- External Artificial Organs (AREA)
Claims (10)
- Utilisation d'un agent, contenant des composants tensioactifs, choisis parmi les acides sulfoniques ou les sulfonates, les oxydes d'alkylamine, les acides éthercarboxyliques et les alkyléther-sulfates, en une quantité de, au total, 0,01 à 1% en poids, de préférence de 0,05 à 0,5% en poids, sur base de l'agent total, ainsi que un ou plusieurs peracides carboxyliques, choisis parmi :où R1 est un radical alkyle ou alcényle ayant 1 à 18 atomes de carbone,a) les peracides ou sels de peracide avec la formule générale Ib) les acides phtalimido-percarboxyliques (II), où la partie peracide carboxylique contient 1 à 18 atomes de carbone, et/ouc) les composés de la formule III :
pour la désinfection dans des procédés CIP. - Utilisation selon la revendication 1, caractérisée en ce que lesdits agents contiennent des acides sulfoniques ou sulfonates, qui sont choisis parmi les acides xylène-, octyl-, naphtyl- ou alkylbenzènesulfoniques ou leurs sulfonates, où dans le dernier cas, le radical alkyle contient de 6 à 16 atomes de carbone.
- Utilisation selon la revendication 1 ou 2, caractérisée en ce que dans l'agent à utiliser, sont présents comme tensioactifs, des acides alkylbenzènesulfoniques ou des alkylbenzènesulfonates et/ou des acides éthercarboxyliques.
- Utilisation selon l'une ou plusieurs des revendications 1 à 3, caractérisée en ce que le ou les peracides carboxyliques font au total, 1 à 40% en poids, de préférence 2,5 à 15% en poids, sur base de l'agent total.
- Utilisation selon l'une ou plusieurs des revendications 1 à 4, caractérisée en ce quea) comme peracide selon la formule générale I, sont présents des peracides dans lesquels R2 est l'atome d'hydrogène ou le radical méthyle, et/oub) comme peracide, sont présents des phtalimido-peracides, dans lesquels la partie peracide carboxylique contient 1 à 8 atomes de carbone, et/ouc) comme peracide selon la formule générale III, sont présents des peracides avec un radical alkyle ou alcényle avec 1 à 12 atomes de carbone.
- Utilisation selon la revendication 5, caractérisée en ce que comme peracide, on choisit un ou plusieurs composés parmi l'acide peracétique, l'acide perpropionique, l'acide peroctanoïque, le peracide phtalimidohexanoïque, le peracide phtalimidooctanoïque, l'acide persuccinique, l'ester monométhylique du peracide succinique, l'acide perglutarique, l'ester monométhylique du peracide glutarique, l'acide peradipique, l'ester monométhylique du peracide adipique.
- Utilisation selon l'une quelconque des revendications 1 à 6, caractérisée en ce que l'agent est dilué en une solution de désinfection avant l'utilisation dans un procédé CIP, qui contient, sur base de toute la solution de désinfection, 0,05 ppm à 100 ppm, de préférence de 0,5 ppm à 50 ppm des tensioactifs globaux.
- Utilisation selon l'une quelconque des revendications 1 à 7, caractérisée en ce que l'agent est dilué en une solution de désinfection avant l'utilisation dans un procédé CIP, qui contient, sur base de toute la solution de désinfection, 10 ppm à 2000 ppm, de préférence de 50 ppm à 1000 ppm des peracides carboxyliques globaux.
- Utilisation de l'agent à utiliser selon l'une quelconque des revendications 1 à 6, ou de la solution diluée selon une des revendications 7 ou 8, pour la désinfection CIP dans l'industrie alimentaire, pharmaceutique ou cosmétique.
- Procédé de purification et/ou de désinfection d'installations, dans lequela) dans une étape préalable, l'installation est nettoyée si nécessaire, par un agent alcalin et/ou acide, ensuiteb) le cas échéant, les surfaces de l'installation sont rincées avec de l'eau, et ensuitec) un agent à utiliser selon l'une quelconque des revendications 1 à 6 ou la solution diluée selon une des revendications 7 ou 8, est pompé manuellement ou par un système automatique, dans l'installation, et/ou pulvérisé, où les températures de mise en oeuvre se situent entre 0 et 50°C, de préférence entre 0 et 30°C et les durées de pompage ou de pulvérisation, entre 1 et 120 minutes, de préférence entre 5 et 60 minutes, et l'installation est, si souhaité, rincée après traitement, avec de l'eau de qualité potable.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10064372A DE10064372A1 (de) | 2000-12-21 | 2000-12-21 | Verwendung schaumarmer, tensidhaltiger Percarbonsäure-Mittel zur CIP-Desinfektion |
| DE10064372 | 2000-12-21 | ||
| PCT/EP2001/014560 WO2002050233A1 (fr) | 2000-12-21 | 2001-12-12 | Utilisation de produits a base d'acide percarboxylique, contenant des tensio-actifs et moussant peu pour la desinfection en circuit ferme |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1349912A1 EP1349912A1 (fr) | 2003-10-08 |
| EP1349912B1 true EP1349912B1 (fr) | 2005-03-02 |
Family
ID=7668517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP01271432A Expired - Lifetime EP1349912B1 (fr) | 2000-12-21 | 2001-12-12 | Utilisation de produits a base d'acide percarboxylique, contenant des tensio-actifs et moussant peu pour la desinfection en circuit ferme |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US7226898B2 (fr) |
| EP (1) | EP1349912B1 (fr) |
| AT (1) | ATE290062T1 (fr) |
| DE (2) | DE10064372A1 (fr) |
| WO (1) | WO2002050233A1 (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7887641B2 (en) * | 2004-01-09 | 2011-02-15 | Ecolab Usa Inc. | Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them |
| DE102004022392B4 (de) * | 2004-05-06 | 2009-04-02 | Gerhard Ruff Gmbh | Desinfektionsmittel-Zusammensetzung enthaltend zumindest eine Persäure-Verbindung und deren Verwendung zur Raum- und Luftdesinfektion |
| US7641395B2 (en) | 2004-06-22 | 2010-01-05 | Halliburton Energy Serives, Inc. | Fiber optic splice housing and integral dry mate connector system |
| US7470655B2 (en) * | 2004-08-06 | 2008-12-30 | Ecolab Inc. | Method of inactivating prions |
| US8398781B2 (en) * | 2004-08-27 | 2013-03-19 | Ecolab Usa Inc. | Methods for cleaning industrial equipment with pre-treatment |
| US8114222B2 (en) | 2004-08-27 | 2012-02-14 | Ecolab Usa Inc. | Method for cleaning industrial equipment with pre-treatment |
| US7594763B2 (en) | 2005-01-19 | 2009-09-29 | Halliburton Energy Services, Inc. | Fiber optic delivery system and side pocket mandrel removal system |
| US8865226B2 (en) | 2006-04-27 | 2014-10-21 | Aseptix Research Bv | Low foaming enhanced biocidal hydrogen peroxide composition |
| US20090074881A1 (en) * | 2006-05-02 | 2009-03-19 | Bioneutral Laboratories Corporation Usa | Antimicrobial cidality formulations with residual efficacy, uses thereof, and the preparation thereof |
| US20090288683A1 (en) * | 2008-05-21 | 2009-11-26 | Ecolab Inc. | Alkaline peroxygen food soil cleaner |
| US9994799B2 (en) | 2012-09-13 | 2018-06-12 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US20140308162A1 (en) | 2013-04-15 | 2014-10-16 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
| US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
| US8871699B2 (en) | 2012-09-13 | 2014-10-28 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5567444A (en) * | 1993-08-30 | 1996-10-22 | Ecolab Inc. | Potentiated aqueous ozone cleaning and sanitizing composition for removal of a contaminating soil from a surface |
| US5861366A (en) | 1994-08-31 | 1999-01-19 | Ecolab Inc. | Proteolytic enzyme cleaner |
| AU695776B2 (en) | 1995-07-12 | 1998-08-20 | Novozymes A/S | Cleaning-in-place with a solution containing a protease and a lipase |
| US6326032B1 (en) | 1998-11-18 | 2001-12-04 | Ecolab Inc. | Beverage manufacture and cold aseptic bottling using peroxyacid antimicrobial composition |
| US6436445B1 (en) * | 1999-03-26 | 2002-08-20 | Ecolab Inc. | Antimicrobial and antiviral compositions containing an oxidizing species |
| US6627593B2 (en) * | 2001-07-13 | 2003-09-30 | Ecolab Inc. | High concentration monoester peroxy dicarboxylic acid compositions, use solutions, and methods employing them |
| US6679274B2 (en) * | 2001-08-10 | 2004-01-20 | Eastman Kodak Company | Clean-in-place method for cleaning solution delivery systemes/lines |
-
2000
- 2000-12-21 DE DE10064372A patent/DE10064372A1/de not_active Ceased
-
2001
- 2001-12-12 EP EP01271432A patent/EP1349912B1/fr not_active Expired - Lifetime
- 2001-12-12 WO PCT/EP2001/014560 patent/WO2002050233A1/fr active IP Right Grant
- 2001-12-12 DE DE50105496T patent/DE50105496D1/de not_active Expired - Lifetime
- 2001-12-12 AT AT01271432T patent/ATE290062T1/de not_active IP Right Cessation
- 2001-12-12 US US10/451,465 patent/US7226898B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20040029755A1 (en) | 2004-02-12 |
| DE50105496D1 (de) | 2005-04-07 |
| DE10064372A1 (de) | 2002-07-11 |
| EP1349912A1 (fr) | 2003-10-08 |
| US7226898B2 (en) | 2007-06-05 |
| ATE290062T1 (de) | 2005-03-15 |
| WO2002050233A1 (fr) | 2002-06-27 |
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