EP1336001A1 - Textile flachengebilde mit hoher sichtbarkeit - Google Patents

Textile flachengebilde mit hoher sichtbarkeit

Info

Publication number
EP1336001A1
EP1336001A1 EP01982566A EP01982566A EP1336001A1 EP 1336001 A1 EP1336001 A1 EP 1336001A1 EP 01982566 A EP01982566 A EP 01982566A EP 01982566 A EP01982566 A EP 01982566A EP 1336001 A1 EP1336001 A1 EP 1336001A1
Authority
EP
European Patent Office
Prior art keywords
fibers
family
threads
wires
yarns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01982566A
Other languages
English (en)
French (fr)
Other versions
EP1336001B1 (de
Inventor
Laurent Thiriot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kermel SNC
Original Assignee
Kermel SNC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8856041&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1336001(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kermel SNC filed Critical Kermel SNC
Publication of EP1336001A1 publication Critical patent/EP1336001A1/de
Application granted granted Critical
Publication of EP1336001B1 publication Critical patent/EP1336001B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition
    • Y10T442/313—Strand material formed of individual filaments having different chemical compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/3187—Triaxially woven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/3195—Three-dimensional weave [e.g., x-y-z planes, multi-planar warps and/or wefts, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/322—Warp differs from weft
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/322—Warp differs from weft
    • Y10T442/3228—Materials differ

Definitions

  • the present invention relates to the field of high visibility textile surfaces. It more particularly a woven textile article that can be used to make high visibility clothing 'and offering good protection to heat and flame.
  • clothing is sometimes required to present a high visibility, in order to signal the presence of workers.
  • fabrics of fluorescent yellow, fluorescent orange, fluorescent red colors There are thus fabrics of fluorescent yellow, fluorescent orange, fluorescent red colors.
  • the use of different colors of clothing can serve as a distinctive sign, and can make it possible, for example, to distinguish several teams on a site or in an intervention area.
  • Yellow yarns and orange yarns are thus known which, woven, allow a sufficient level of visibility to be obtained. Visibility criteria are for example defined in standard EN 471. In several sectors of activity, it is necessary for workers to wear clothing which is simultaneously protective against fire-related risks and highly visible. Yellow fabrics are known for this purpose that meet the criteria of high visibility and fire protection. These fabrics are obtained by weaving intrinsically heat-resistant threads containing yellow pigments. These fabrics also exhibit relatively poor color fastness.
  • the object of the present invention is to propose a solution to this problem, and to propose new textile surfaces of high visibility and offering protection against risks linked to fire, in particular new yellow textile surfaces.
  • the invention proposes a textile surface having at least one high visibility face, the chromatic coordinates and the luminance factor of the face being chosen from:
  • wires or fibers A thermostable wires or fibers
  • Yarns or fibers B choking yarns or fibers causing gas evolution 15 when subjected to a flame
  • Yarns or fibers C yarns or fibers of optical properties such as a fabric produced solely from yarns or fibers would have chromaticity coordinates and a luminance factor chosen from: the chromaticity coordinates included in the ellipse defined by the pairs 0 coordinates (X; Y) (0.610; 0.390), (0.544; 0.376), (0.579, 0.341), (0.655;
  • the textile surface has at least one side of high visibility, yellow or orange.
  • High visibility is characterized by the chromaticity coordinates and the luminance factor, in accordance with standard EN 471.
  • the methods for measuring the chromaticity coordinates and the luminance factor are specified in standard CIE 15: 2: 1968.
  • the surface is obtained from threads or fibers of several types, threads or fibers 0 A, B, C. If a thread or fiber has both the characteristics of threads or fibers of two types A and B, it is of each of these natures.
  • the surface is for example obtained by weaving or knitting, with a construction such that the son or fibers C appear on the face of high .visibility.
  • the yarns or fibers A are arranged in the textile surface in two distinct directions, for example in two weaving directions.
  • yarn we can mean a continuous multifilament object, a continuous fiber yarn, obtained from, a single type of fiber, or a mixture of fibers, for example fibers A and B in intimate mixture, or fibers A or B with other fibers.
  • the wires or fibers A are thermostable. These are threads or fibers whose shrinkage and loss of mechanical properties are limited after short-term exposure to a flame (of the order of 3 to 4 seconds).
  • a yarns can consist of a mixture of fibers, intimate mixture or heart / skin mixture (fiies of fibers with core). It may for example be a mixture of polyamide-imide fibers and flame-retardant viscose fibers, optionally with paraphenylene terephthalamide fibers.
  • the yarns can also consist of polymetaphenylene isophtaiamide fibers, or mixtures of these fibers with in particular polyparaphenylene terephthalamide fibers.
  • the threads or fibers B are threads or fibers of suffocation, causing a gassing during their combustion.
  • the gas released is preferably a gas different from oxygen. These threads or fibers inhibit the combustion of neighboring threads or fibers.
  • the gas evolution generally results from the decomposition of the material constituting the wire or the fiber. It can also be derived from an additive or primer.
  • choking fibers mention is made of modacrylic fibers and PPAN fibers (preoxidized polyacrylonitrile).
  • Composite yarns can be used comprising at least two twisted yarns, a thermostable yarn and a yarn comprising choking fibers, alone or as a mixture. It is also possible to use an untwisted yarn, comprising suffocation fibers, alone or in a mixture.
  • the following gases can be used which cause gas evolution:
  • thermostable fibers chosen, for example, from aramids, polybenzimidazole, PBO, phenolic resin fibers, glass fibers, carbon fibers, melamine fibers.
  • yarns of fibers comprising modacrylic fibers mention may be made of Protex M or S fibers sold by the company Kaneka, Lufnen VF1 and VE1 fibers, Super valzer fibers.
  • the yarns or fibers B preferably have a limit oxygen index greater than 30%.
  • the threads or fibers C are threads or fibers of orange or yellow color, with optical properties such as a fabric produced solely from these threads or fibers would have chromaticity coordinates and a luminance factor chosen from: - the chromaticity coordinates included in the ellipse defined by the pairs of coordinates (X; Y) (0.610; 0.390), (0.544; 0.376), (0.579, 0.341), (0.655; 0.344) with a luminance factor ⁇ greater than 0.40. These are fluorescent orange wires or fibers. the chromaticity coordinates included in the ellipse defined by the pairs of coordinates (X; Y) (0.387; 0.610), (0.356; 0.494), (0.398, 0.452), (0.460;
  • They may for example be threads or fibers based on polyethylene terephthalate comprising a pigment introduced before spinning and giving the required color to the threads or fibers.
  • the pigment is advantageously orange in color. It may for example be orange threads marketed by the company Trevira under the reference Texturgarn Typ 501
  • the surface is obtained by weaving at least three families of threads.
  • the families of sons at least partially define the structure and construction of the surface.
  • Each family can include threads or fibers of different types.
  • a first family is called the family of superior sons. This family constitutes a warp or weft appearing on the high visibility face. It comprises yarns or fibers C. It can optionally also include yarns or fibers A and / or B.
  • a second family is called the family of the lower sons. This family consists of threads parallel to the family of lower threads. The lower wires do not appear on the high visibility side.
  • a third family is called the family of cross threads. This family consists of wires perpendicular to the lower wires. It is woven with at least the family of lower threads. It can also be woven with other families of threads, for example with the family of upper threads or with another family of fibers, different from the family of upper threads and the family of lower threads.
  • At least one family chosen from the family of lower yarns and the family of transverse yarns comprises yarns or fibers B, and the family of lower yarns and the family of transverse yarns each include yarns or fibers A.
  • One of the families, according to this embodiment, therefore comprises both yarns or fibers A and yarns or fibers B. It can be a yarn spun from fibers A and fibers B. This family can for example consist of yarns of fibers A and B in intimate mixture.
  • the family of transverse wires consists of wires spun from fibers A and B in intimate mixture
  • the family of lower wires consists of wires obtained from thermostable fibers, alone or in mixture, for example an intimate mixture with other fibers.
  • These latter yarns can, for example, be intimate mixtures of aramid fibers and flame-retardant fibers based on viscose.
  • the surface can for example be obtained by double warp or double weft weaving.
  • double warp weaving the family of upper threads constitutes the upper warp
  • the family of lower threads constitutes the lower warp
  • the family of transverse threads constitutes the weft.
  • the family of upper yarns constitutes the upper weft
  • the family of lower yarns constitutes the lower weft
  • the family of transverse yarns constitutes the warp.
  • the family of lower threads is not visible on the high visibility face.
  • the family of upper wires is not apparent.
  • the two faces are respectively weavings of the transverse threads with respectively upper and lower threads.
  • the weaving weaves can be weaves derived from canvas, satin, twill.
  • a preferred weave is the 4 double warp or double weft twill weave.
  • the proportion by weight in the textile surface of yarns or fibers A is preferably greater than 35%.
  • the proportion by weight of yarns or fibers C for example based on polyethylene terephthalate, is preferably less than 50% and even more preferably less than 30%.
  • the weight ratio of yarns or fibers B relative to fuses or fibers C for example based on polyethylene terephthalate, is preferably between 25/75 and 75/25.
  • all the threads of the family of transverse threads are threads obtained by assembling a thread A and a thread B, or by intimate mixing of fibers A and fibers B.
  • all of the wires of the family of lower wires are wires A.
  • the yarns of the upper yarn family preferably cover at least 70% of the upper face of the surface.
  • FIG. 1 We weave a fabric using the double warp weaving technique, on a twill weave base of 4.
  • the threads used are as follows:
  • - lower chain (2) spun of fibers composed of an intimate mixture of aramid (polyamide-imide) / viscose FR in the proportion by weight 70/30.
  • FIG 1 schematically shows the structure of the tissue.
  • the fabric is subjected to the tests defined in standards EN 471 and EN 531.
  • the fabric conforms to these standards, with classification A, B1, C1, E1 for standard EN 531.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
EP01982566A 2000-11-03 2001-10-26 Textile flachengebilde mit hoher sichtbarkeit Expired - Lifetime EP1336001B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0014124 2000-11-03
FR0014124A FR2816176B1 (fr) 2000-11-03 2000-11-03 Surface textile de haute visibilite
PCT/FR2001/003333 WO2002036870A1 (fr) 2000-11-03 2001-10-26 Surface textile de haute visibilite

Publications (2)

Publication Number Publication Date
EP1336001A1 true EP1336001A1 (de) 2003-08-20
EP1336001B1 EP1336001B1 (de) 2007-01-24

Family

ID=8856041

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01982566A Expired - Lifetime EP1336001B1 (de) 2000-11-03 2001-10-26 Textile flachengebilde mit hoher sichtbarkeit

Country Status (21)

Country Link
US (1) US7312166B2 (de)
EP (1) EP1336001B1 (de)
JP (1) JP3994054B2 (de)
KR (1) KR100563797B1 (de)
CN (1) CN1281801C (de)
AT (1) ATE352649T1 (de)
AU (2) AU1411502A (de)
BR (1) BR0115391B1 (de)
CA (1) CA2427598A1 (de)
CZ (1) CZ300205B6 (de)
DE (1) DE60126315T2 (de)
DK (1) DK1336001T3 (de)
ES (1) ES2280409T3 (de)
FR (1) FR2816176B1 (de)
HU (1) HU227954B1 (de)
NO (1) NO20031947L (de)
NZ (1) NZ525663A (de)
PL (1) PL205696B1 (de)
PT (1) PT1336001E (de)
RU (1) RU2244770C1 (de)
WO (1) WO2002036870A1 (de)

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JP6173053B2 (ja) * 2013-06-07 2017-08-02 株式会社クラレ 高視認性を有する難燃布帛
JP6158602B2 (ja) * 2013-06-11 2017-07-05 帝人株式会社 伸縮性難燃布帛および繊維製品
FR3008434A1 (fr) 2013-07-11 2015-01-16 Europrotect France Sa Procede de coloration d'un support textile non feu en un coloris haute visibilite
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JP6278755B2 (ja) * 2014-03-07 2018-02-14 株式会社クラレ 高視認性を有する難燃布帛
JP6468746B2 (ja) * 2014-07-24 2019-02-13 ユニチカトレーディング株式会社 高視認性織物
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Also Published As

Publication number Publication date
KR100563797B1 (ko) 2006-03-28
FR2816176B1 (fr) 2002-12-20
FR2816176A1 (fr) 2002-05-10
DE60126315T2 (de) 2007-11-15
DE60126315D1 (de) 2007-03-15
US7312166B2 (en) 2007-12-25
NO20031947D0 (no) 2003-04-29
RU2244770C1 (ru) 2005-01-20
CZ20031200A3 (cs) 2003-09-17
ES2280409T3 (es) 2007-09-16
PL205696B1 (pl) 2010-05-31
HU227954B1 (hu) 2012-07-30
PT1336001E (pt) 2007-05-31
PL365580A1 (en) 2005-01-10
NZ525663A (en) 2004-06-25
EP1336001B1 (de) 2007-01-24
JP3994054B2 (ja) 2007-10-17
RU2003116242A (ru) 2005-01-10
CN1478159A (zh) 2004-02-25
AU1411502A (en) 2002-05-15
ATE352649T1 (de) 2007-02-15
NO20031947L (no) 2003-06-19
BR0115391B1 (pt) 2009-12-01
KR20030063371A (ko) 2003-07-28
JP2004513252A (ja) 2004-04-30
CZ300205B6 (cs) 2009-03-18
CN1281801C (zh) 2006-10-25
WO2002036870A1 (fr) 2002-05-10
BR0115391A (pt) 2003-08-19
US20040035489A1 (en) 2004-02-26
DK1336001T3 (da) 2007-05-21
HUP0400838A2 (en) 2008-02-28
CA2427598A1 (fr) 2002-05-10
AU2002214115B2 (en) 2005-01-06

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