EP1336001A1 - High-visibility textile surface - Google Patents
High-visibility textile surfaceInfo
- Publication number
- EP1336001A1 EP1336001A1 EP01982566A EP01982566A EP1336001A1 EP 1336001 A1 EP1336001 A1 EP 1336001A1 EP 01982566 A EP01982566 A EP 01982566A EP 01982566 A EP01982566 A EP 01982566A EP 1336001 A1 EP1336001 A1 EP 1336001A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- fibers
- family
- threads
- wires
- yarns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004753 textile Substances 0.000 title claims abstract description 14
- 239000000835 fiber Substances 0.000 claims description 109
- 238000009941 weaving Methods 0.000 claims description 13
- 239000004744 fabric Substances 0.000 claims description 11
- 239000011872 intimate mixture Substances 0.000 claims description 10
- -1 polymetaphenylene Polymers 0.000 claims description 10
- 239000004962 Polyamide-imide Substances 0.000 claims description 5
- 229920002312 polyamide-imide Polymers 0.000 claims description 5
- 229920002821 Modacrylic Polymers 0.000 claims description 4
- 239000004693 Polybenzimidazole Substances 0.000 claims description 4
- 229920002480 polybenzimidazole Polymers 0.000 claims description 4
- 230000003287 optical effect Effects 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 238000009987 spinning Methods 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000000203 mixture Substances 0.000 description 9
- 239000007789 gas Substances 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 5
- 239000004760 aramid Substances 0.000 description 4
- 229920003235 aromatic polyamide Polymers 0.000 description 4
- 241000531908 Aramides Species 0.000 description 3
- 101000700835 Homo sapiens Suppressor of SWI4 1 homolog Proteins 0.000 description 3
- 229920000297 Rayon Polymers 0.000 description 3
- 102100029338 Suppressor of SWI4 1 homolog Human genes 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 206010003497 Asphyxia Diseases 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920006277 melamine fiber Polymers 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
- D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3065—Including strand which is of specific structural definition
- Y10T442/313—Strand material formed of individual filaments having different chemical compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
- Y10T442/3187—Triaxially woven fabric
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
- Y10T442/3195—Three-dimensional weave [e.g., x-y-z planes, multi-planar warps and/or wefts, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
- Y10T442/322—Warp differs from weft
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
- Y10T442/322—Warp differs from weft
- Y10T442/3228—Materials differ
Definitions
- the present invention relates to the field of high visibility textile surfaces. It more particularly a woven textile article that can be used to make high visibility clothing 'and offering good protection to heat and flame.
- clothing is sometimes required to present a high visibility, in order to signal the presence of workers.
- fabrics of fluorescent yellow, fluorescent orange, fluorescent red colors There are thus fabrics of fluorescent yellow, fluorescent orange, fluorescent red colors.
- the use of different colors of clothing can serve as a distinctive sign, and can make it possible, for example, to distinguish several teams on a site or in an intervention area.
- Yellow yarns and orange yarns are thus known which, woven, allow a sufficient level of visibility to be obtained. Visibility criteria are for example defined in standard EN 471. In several sectors of activity, it is necessary for workers to wear clothing which is simultaneously protective against fire-related risks and highly visible. Yellow fabrics are known for this purpose that meet the criteria of high visibility and fire protection. These fabrics are obtained by weaving intrinsically heat-resistant threads containing yellow pigments. These fabrics also exhibit relatively poor color fastness.
- the object of the present invention is to propose a solution to this problem, and to propose new textile surfaces of high visibility and offering protection against risks linked to fire, in particular new yellow textile surfaces.
- the invention proposes a textile surface having at least one high visibility face, the chromatic coordinates and the luminance factor of the face being chosen from:
- wires or fibers A thermostable wires or fibers
- Yarns or fibers B choking yarns or fibers causing gas evolution 15 when subjected to a flame
- Yarns or fibers C yarns or fibers of optical properties such as a fabric produced solely from yarns or fibers would have chromaticity coordinates and a luminance factor chosen from: the chromaticity coordinates included in the ellipse defined by the pairs 0 coordinates (X; Y) (0.610; 0.390), (0.544; 0.376), (0.579, 0.341), (0.655;
- the textile surface has at least one side of high visibility, yellow or orange.
- High visibility is characterized by the chromaticity coordinates and the luminance factor, in accordance with standard EN 471.
- the methods for measuring the chromaticity coordinates and the luminance factor are specified in standard CIE 15: 2: 1968.
- the surface is obtained from threads or fibers of several types, threads or fibers 0 A, B, C. If a thread or fiber has both the characteristics of threads or fibers of two types A and B, it is of each of these natures.
- the surface is for example obtained by weaving or knitting, with a construction such that the son or fibers C appear on the face of high .visibility.
- the yarns or fibers A are arranged in the textile surface in two distinct directions, for example in two weaving directions.
- yarn we can mean a continuous multifilament object, a continuous fiber yarn, obtained from, a single type of fiber, or a mixture of fibers, for example fibers A and B in intimate mixture, or fibers A or B with other fibers.
- the wires or fibers A are thermostable. These are threads or fibers whose shrinkage and loss of mechanical properties are limited after short-term exposure to a flame (of the order of 3 to 4 seconds).
- a yarns can consist of a mixture of fibers, intimate mixture or heart / skin mixture (fiies of fibers with core). It may for example be a mixture of polyamide-imide fibers and flame-retardant viscose fibers, optionally with paraphenylene terephthalamide fibers.
- the yarns can also consist of polymetaphenylene isophtaiamide fibers, or mixtures of these fibers with in particular polyparaphenylene terephthalamide fibers.
- the threads or fibers B are threads or fibers of suffocation, causing a gassing during their combustion.
- the gas released is preferably a gas different from oxygen. These threads or fibers inhibit the combustion of neighboring threads or fibers.
- the gas evolution generally results from the decomposition of the material constituting the wire or the fiber. It can also be derived from an additive or primer.
- choking fibers mention is made of modacrylic fibers and PPAN fibers (preoxidized polyacrylonitrile).
- Composite yarns can be used comprising at least two twisted yarns, a thermostable yarn and a yarn comprising choking fibers, alone or as a mixture. It is also possible to use an untwisted yarn, comprising suffocation fibers, alone or in a mixture.
- the following gases can be used which cause gas evolution:
- thermostable fibers chosen, for example, from aramids, polybenzimidazole, PBO, phenolic resin fibers, glass fibers, carbon fibers, melamine fibers.
- yarns of fibers comprising modacrylic fibers mention may be made of Protex M or S fibers sold by the company Kaneka, Lufnen VF1 and VE1 fibers, Super valzer fibers.
- the yarns or fibers B preferably have a limit oxygen index greater than 30%.
- the threads or fibers C are threads or fibers of orange or yellow color, with optical properties such as a fabric produced solely from these threads or fibers would have chromaticity coordinates and a luminance factor chosen from: - the chromaticity coordinates included in the ellipse defined by the pairs of coordinates (X; Y) (0.610; 0.390), (0.544; 0.376), (0.579, 0.341), (0.655; 0.344) with a luminance factor ⁇ greater than 0.40. These are fluorescent orange wires or fibers. the chromaticity coordinates included in the ellipse defined by the pairs of coordinates (X; Y) (0.387; 0.610), (0.356; 0.494), (0.398, 0.452), (0.460;
- They may for example be threads or fibers based on polyethylene terephthalate comprising a pigment introduced before spinning and giving the required color to the threads or fibers.
- the pigment is advantageously orange in color. It may for example be orange threads marketed by the company Trevira under the reference Texturgarn Typ 501
- the surface is obtained by weaving at least three families of threads.
- the families of sons at least partially define the structure and construction of the surface.
- Each family can include threads or fibers of different types.
- a first family is called the family of superior sons. This family constitutes a warp or weft appearing on the high visibility face. It comprises yarns or fibers C. It can optionally also include yarns or fibers A and / or B.
- a second family is called the family of the lower sons. This family consists of threads parallel to the family of lower threads. The lower wires do not appear on the high visibility side.
- a third family is called the family of cross threads. This family consists of wires perpendicular to the lower wires. It is woven with at least the family of lower threads. It can also be woven with other families of threads, for example with the family of upper threads or with another family of fibers, different from the family of upper threads and the family of lower threads.
- At least one family chosen from the family of lower yarns and the family of transverse yarns comprises yarns or fibers B, and the family of lower yarns and the family of transverse yarns each include yarns or fibers A.
- One of the families, according to this embodiment, therefore comprises both yarns or fibers A and yarns or fibers B. It can be a yarn spun from fibers A and fibers B. This family can for example consist of yarns of fibers A and B in intimate mixture.
- the family of transverse wires consists of wires spun from fibers A and B in intimate mixture
- the family of lower wires consists of wires obtained from thermostable fibers, alone or in mixture, for example an intimate mixture with other fibers.
- These latter yarns can, for example, be intimate mixtures of aramid fibers and flame-retardant fibers based on viscose.
- the surface can for example be obtained by double warp or double weft weaving.
- double warp weaving the family of upper threads constitutes the upper warp
- the family of lower threads constitutes the lower warp
- the family of transverse threads constitutes the weft.
- the family of upper yarns constitutes the upper weft
- the family of lower yarns constitutes the lower weft
- the family of transverse yarns constitutes the warp.
- the family of lower threads is not visible on the high visibility face.
- the family of upper wires is not apparent.
- the two faces are respectively weavings of the transverse threads with respectively upper and lower threads.
- the weaving weaves can be weaves derived from canvas, satin, twill.
- a preferred weave is the 4 double warp or double weft twill weave.
- the proportion by weight in the textile surface of yarns or fibers A is preferably greater than 35%.
- the proportion by weight of yarns or fibers C for example based on polyethylene terephthalate, is preferably less than 50% and even more preferably less than 30%.
- the weight ratio of yarns or fibers B relative to fuses or fibers C for example based on polyethylene terephthalate, is preferably between 25/75 and 75/25.
- all the threads of the family of transverse threads are threads obtained by assembling a thread A and a thread B, or by intimate mixing of fibers A and fibers B.
- all of the wires of the family of lower wires are wires A.
- the yarns of the upper yarn family preferably cover at least 70% of the upper face of the surface.
- FIG. 1 We weave a fabric using the double warp weaving technique, on a twill weave base of 4.
- the threads used are as follows:
- - lower chain (2) spun of fibers composed of an intimate mixture of aramid (polyamide-imide) / viscose FR in the proportion by weight 70/30.
- FIG 1 schematically shows the structure of the tissue.
- the fabric is subjected to the tests defined in standards EN 471 and EN 531.
- the fabric conforms to these standards, with classification A, B1, C1, E1 for standard EN 531.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Woven Fabrics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0014124A FR2816176B1 (en) | 2000-11-03 | 2000-11-03 | HIGH VISIBILITY TEXTILE SURFACE |
FR0014124 | 2000-11-03 | ||
PCT/FR2001/003333 WO2002036870A1 (en) | 2000-11-03 | 2001-10-26 | High-visibility textile surface |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1336001A1 true EP1336001A1 (en) | 2003-08-20 |
EP1336001B1 EP1336001B1 (en) | 2007-01-24 |
Family
ID=8856041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP01982566A Expired - Lifetime EP1336001B1 (en) | 2000-11-03 | 2001-10-26 | High-visibility textile surface |
Country Status (21)
Country | Link |
---|---|
US (1) | US7312166B2 (en) |
EP (1) | EP1336001B1 (en) |
JP (1) | JP3994054B2 (en) |
KR (1) | KR100563797B1 (en) |
CN (1) | CN1281801C (en) |
AT (1) | ATE352649T1 (en) |
AU (2) | AU2002214115B2 (en) |
BR (1) | BR0115391B1 (en) |
CA (1) | CA2427598A1 (en) |
CZ (1) | CZ300205B6 (en) |
DE (1) | DE60126315T2 (en) |
DK (1) | DK1336001T3 (en) |
ES (1) | ES2280409T3 (en) |
FR (1) | FR2816176B1 (en) |
HU (1) | HU227954B1 (en) |
NO (1) | NO20031947L (en) |
NZ (1) | NZ525663A (en) |
PL (1) | PL205696B1 (en) |
PT (1) | PT1336001E (en) |
RU (1) | RU2244770C1 (en) |
WO (1) | WO2002036870A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040192134A1 (en) * | 2001-05-09 | 2004-09-30 | Gibson Richard M. | Flame-resistant and high visibility fabric and apparel formed therefrom |
FR2826669B1 (en) * | 2001-06-28 | 2003-08-15 | Kermel | COMPOSITE YARN |
US20070094763A1 (en) * | 2002-08-30 | 2007-05-03 | Safety-Short Workwair Inc. | Safety outerwear with fire resistant mesh |
ITVI20030037A1 (en) * | 2003-02-25 | 2004-08-26 | Q2 Roma Srl | HIGH FIREPROOF PROPERTIES FABRIC. |
FR2854547B1 (en) * | 2003-05-06 | 2005-08-05 | Kermel | TEXTILE SURFACE USEFUL FOR CARRYING OUT PROTECTIVE CLOTHING, ESPECIALLY FOR FLAME-FIREFIGHTERS AND MULTILAYER COMPLEXES COMPRISING SAID SURFACE |
US7681417B2 (en) | 2005-06-17 | 2010-03-23 | Hayashi Yarn Twisting Co., Ltd. | Heat-resistant fabric and garment and heat-resistant glove using the same |
US20080003905A1 (en) * | 2006-06-30 | 2008-01-03 | Canbelin Industrial Co., Ltd. | Mat |
DE102007050175A1 (en) * | 2007-10-19 | 2009-04-23 | W. L. Gore & Associates Gmbh | Material structure with flameproof material, especially for warning clothing |
US20090107575A1 (en) * | 2007-10-29 | 2009-04-30 | Yucheng Ma | Mixed Fabric Woven by Untwisted Yarns and Twisted Yarns |
GB201004692D0 (en) * | 2010-03-19 | 2010-05-05 | Toray Textiles Europ Ltd | Fabric for personal protection garments |
WO2012016124A2 (en) * | 2010-07-29 | 2012-02-02 | Drifire, Llc | Fire resistant woven fabrics and garments |
DE102011102428A1 (en) | 2011-05-24 | 2012-11-29 | Glanzstoff Bohemia S.R.O. | Luminescent cellulosic regenerated fiber and process for its preparation |
DE202012013159U1 (en) * | 2012-01-20 | 2015-05-15 | Lilian Haferkamp | Knit and knitting machine for making a knit |
DE102012106920A1 (en) | 2012-07-30 | 2014-01-30 | Rofa Bekleidungswerk GmbH & Co. KG | Textile fabric for flame retardant protective clothing with high visibility |
JP6162447B2 (en) * | 2013-03-25 | 2017-07-12 | ユニチカトレーディング株式会社 | High visibility layered fabric |
JP6173053B2 (en) * | 2013-06-07 | 2017-08-02 | 株式会社クラレ | Flame retardant fabric with high visibility |
JP6158602B2 (en) * | 2013-06-11 | 2017-07-05 | 帝人株式会社 | Elastic flame retardant fabric and textile products |
FR3008434A1 (en) | 2013-07-11 | 2015-01-16 | Europrotect France Sa | METHOD FOR COLORING A NON-FIRE TEXTILE SUPPORT IN HIGH VISIBILITY COLOR |
US10451780B2 (en) | 2013-12-12 | 2019-10-22 | 3M Innovative Properties Company | Retroreflective article |
JP6278755B2 (en) * | 2014-03-07 | 2018-02-14 | 株式会社クラレ | Flame retardant fabric with high visibility |
JP6468746B2 (en) * | 2014-07-24 | 2019-02-13 | ユニチカトレーディング株式会社 | High visibility fabric |
WO2016045712A1 (en) | 2014-09-23 | 2016-03-31 | Sanko Tekstil Isletmeleri San. Ve Tic. A.S. | Woven fabric having the aspect of a scuba fabric, and method for producing the same |
WO2016152814A1 (en) * | 2015-03-24 | 2016-09-29 | 東レ株式会社 | Fabric and garment |
RU2673610C1 (en) * | 2015-06-17 | 2018-11-28 | Куджукджалык Текстил Санайы Ве Тиджарет Аноним Сиркети | Yarn and fabric designed for shielded applications and also a method of their manufacture |
DK3231907T3 (en) | 2016-04-11 | 2022-04-25 | Calik Denim Tekstil San Ve Tic A S | WOVEN FABRIC AND METHOD OF PRODUCTION THEREOF |
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2000
- 2000-11-03 FR FR0014124A patent/FR2816176B1/en not_active Expired - Fee Related
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2001
- 2001-10-26 RU RU2003116242/12A patent/RU2244770C1/en not_active IP Right Cessation
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- 2001-10-26 KR KR1020037006134A patent/KR100563797B1/en active IP Right Grant
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- 2001-10-26 AU AU2002214115A patent/AU2002214115B2/en not_active Ceased
- 2001-10-26 EP EP01982566A patent/EP1336001B1/en not_active Expired - Lifetime
- 2001-10-26 JP JP2002539604A patent/JP3994054B2/en not_active Expired - Fee Related
- 2001-10-26 PT PT01982566T patent/PT1336001E/en unknown
- 2001-10-26 US US10/415,747 patent/US7312166B2/en not_active Expired - Lifetime
- 2001-10-26 CA CA002427598A patent/CA2427598A1/en not_active Abandoned
- 2001-10-26 DE DE60126315T patent/DE60126315T2/en not_active Expired - Lifetime
- 2001-10-26 NZ NZ525663A patent/NZ525663A/en not_active IP Right Cessation
- 2001-10-26 AU AU1411502A patent/AU1411502A/en active Pending
- 2001-10-26 DK DK01982566T patent/DK1336001T3/en active
- 2001-10-26 WO PCT/FR2001/003333 patent/WO2002036870A1/en active IP Right Grant
- 2001-10-26 PL PL365580A patent/PL205696B1/en unknown
- 2001-10-26 CZ CZ20031200A patent/CZ300205B6/en not_active IP Right Cessation
- 2001-10-26 HU HU0400838A patent/HU227954B1/en not_active IP Right Cessation
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2003
- 2003-04-29 NO NO20031947A patent/NO20031947L/en not_active Application Discontinuation
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