EP1205567A2 - Herstellung von einer ultrafeinen Korngefüge in Aluminium-Legierungen im Gusszustand - Google Patents

Herstellung von einer ultrafeinen Korngefüge in Aluminium-Legierungen im Gusszustand Download PDF

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Publication number
EP1205567A2
EP1205567A2 EP01126694A EP01126694A EP1205567A2 EP 1205567 A2 EP1205567 A2 EP 1205567A2 EP 01126694 A EP01126694 A EP 01126694A EP 01126694 A EP01126694 A EP 01126694A EP 1205567 A2 EP1205567 A2 EP 1205567A2
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EP
European Patent Office
Prior art keywords
alloy
ingot
melt
grain refiner
grain
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Granted
Application number
EP01126694A
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English (en)
French (fr)
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EP1205567B1 (de
EP1205567A3 (de
Inventor
Men Glenn Chu
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Howmet Aerospace Inc
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Alcoa Inc
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Publication of EP1205567A3 publication Critical patent/EP1205567A3/de
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/03—Making non-ferrous alloys by melting using master alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C1/00—Making non-ferrous alloys
    • C22C1/02—Making non-ferrous alloys by melting
    • C22C1/026—Alloys based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C21/00—Alloys based on aluminium

Definitions

  • This invention relates to production of as-cast aluminum alloys with ultra-fine grain structure. More particularly, it relates to methods of adding a grain refiner to a molten aluminum alloy at levels which reduce the grain size to less than about 200 microns.
  • the size and shape of grains in as-cast aluminum alloy impacts properties of wrought or cast products. Casting with large grains, particularly dendritic grains, is highly prone to cracking during casting and reduce ductility, fracture toughness and fatigue properties. Reduction of the size as well as the form of the grains may be accomplished by mechanical or electromagnetic stirring to break up the grains. Grain size may also be controlled metallurgically by adding a grain refiner to the aluminum alloy melt.
  • a typical grain refiner used for aluminum alloys is cither an Al-Ti-B alloy or an Al-Ti-C alloy in the form of a rod or waffle.
  • a gain refiner consists of numerous fine boride or carbide particles in an aluminum matrix.
  • grain refiners When these grain refiners are added to the aluminum alloy melt, the boride or carbide particles are dispersed into the melt and serve as nucleating sites for grains during solidification.
  • Commercially available grain refiners include alloys containing about 3-5 wt, % Ti and about 0.15-1 wt. % B or C and the balance Al. According to this practice, a residual amount of Ti is present in or is added to the aluminum melt (e.g. less than 0.015wt. %), and a controlled amount of the grain refiner is added thereto which increases the total Ti concentration in the final melt by about 0.001-0.003 wt. %. In this manner, the amount of B or C added to the melt via the grain refiner is about 0.0001-0.001 wt. %.
  • the addition of grain refiners at these conventional levels can control the size of dendritic grains to be about 250-1000 microns, For certain cast or wrought aluminum prodllots, such a grain structure is sufficiently fine and cracking
  • ultra-fine grain size may be achieved by supersaturating a molten alloy with dispersoid-forming elements such as Zr, Mn, Cr, V, Ti, Sc and Hf as disclosed in U.S. Patent No. 6,004,506. That process requires the addition of a specialized, pre-alloyed ribbon of material containing the dispersoid-forming elements into a pool of molten metal formed during ingot casting. Accordingly, a need remains for a method of producing aluminum alloys with ultra-fine grain structure using readily available additives.
  • the inventive method includes the steps of a) providing a molten aluminum alloy including an alloying element selected from the group consisting of Ti, Sc, Zr, V, Hf, Nb and Y; b) adding a grain refiner to the molten aluminum alloy to form a melt, wherein the grain refiner comprises (i) Ti and (ii) B or C, such that the concentration in the melt of B or C after addition of grain refiner is about 0.003-0.010 wt. %; and c) solidifying the melt to form an ingot.
  • the alloying clement is Ti at a concentration of about 0.015-0.030 wt.
  • the alloy may be a wrought alloy of the 1XXX, 2XXX, 3XXX, 5XXX, 6XXX, 7XXX or 8XXX Aluminum Association (AA) series, preferably an alloy of the 2XXX or 7XXX AA series or a casting alloy such as a 2XX, 3XX, 1XX, 5XX, 7XX or 8XX series alloy.
  • Particularly preferred wrought alloys are 7055 and 7050 alloys.
  • the grains in the ingot formed according to the present invention are sited about 200 microns or less, preferably 100 microns or less.
  • the present invention includes a method of controlling the grain size in cast aluminum alloys to about 200 microns or less.
  • an alloying clement is added to a molten aluminum alloy.
  • Preferred residual alloying elements are Ti, Sc, Zr, V, Hf, Nb and Y, more preferably Ti and Sc.
  • a preferred concentration of the alloying element Ti in the molten aluminum alloy is about 0.015-0.030 wt. %.
  • the alloying element is Sc
  • a preferred concentration of residual Sc in the molten aluminum alloy is about 0.030-0.1 wt, %.
  • the alloying element is Zr, V, Hf, Nb or Y
  • the preferred concentration thereof is on the order of the preferred concentrations of Ti and Sc.
  • a grain refiner is added to tho molten aluminum alloy containing the residual alloying element to form a melt.
  • Commercially available grain refiners are alloys consisting of Ti and B or C with the balance aluminum. Typical concentrations in the grain refiner are about 3-5 wt. % Ti and about 0.15-1 wt. % B or C. The final concentration of B or C in the melt from the grain refiner is about 0.003-0.010 wt. %.
  • Suitable commercially available grain refiners have compositions such as 3 wt. % Ti, 1 wt. % B and balance Al (referred to as Al-3%Ti-1%B).
  • Al-3%Ti-1%B Al-5%Ti-1%B, Al-3%Ti-0.2%B, Al-5%Ti-0.2%B, Al-3%Ti-0.15%C, or Al-3%Ti-0.3%C.
  • These grain refiners typically are provided in the form of a rod or waffle, The ratio of B or C to Ti in the grain refiner is normally fixed; hence, the amount of grain refiner added to the melt controls the final amount of Ti present in the melt. For example, in order to achieve a concentration of B of about 0.003-0.010 wt.
  • the present invention may be used to control grain size in wrought and cast alloys.
  • Suitable alloys include Aluminum Association (AA) wrought alloys of the 1XXX, 2XXX, 3XXX, 5XXX, 6XXX, 7XXX and 8XXX series and cast alloys of the AA 2XX, 3 XX, 4XX, 5XX, 7XX and 8XX series. Alloys of the AA 2XXX and 7XXX series are particularly suited to treatment according to the present invention.
  • As-cast aluminum alloy produced according to the present invention has globular grains which are about 200 microns or less in size, typically about 80 microns in size.
  • conventional grain refining practice of adding a grain refiner of Al-3%Ti-1%B such that the concentration of B in the melt is 0.001 wt. % produces dendritic grains sized about 1000 microns. These large dendritic grains interlock with each other and render the cast alloy rigid and prone to cracking, whereas the small, globular grains formed by the method of the present invention reduce crack initiation during casting and improve formability during deformation.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Manufacture And Refinement Of Metals (AREA)
EP20010126694 2000-11-10 2001-11-08 Herstellung von einer ultrafeinen Korngefüge in Aluminium-Legierungen im Gusszustand Revoked EP1205567B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US710175 1985-03-11
US71017500A 2000-11-10 2000-11-10

Publications (3)

Publication Number Publication Date
EP1205567A2 true EP1205567A2 (de) 2002-05-15
EP1205567A3 EP1205567A3 (de) 2002-06-05
EP1205567B1 EP1205567B1 (de) 2005-05-04

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ID=24852923

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20010126694 Revoked EP1205567B1 (de) 2000-11-10 2001-11-08 Herstellung von einer ultrafeinen Korngefüge in Aluminium-Legierungen im Gusszustand

Country Status (3)

Country Link
EP (1) EP1205567B1 (de)
CA (1) CA2361484A1 (de)
DE (1) DE60110523D1 (de)

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1590495A1 (de) * 2002-12-20 2005-11-02 Alcoa Inc. Al-ni-mn-gusslegierung für automobil- und luftfahrt-strukturkomponentenstrukturbestandteile
FR2875815A1 (fr) * 2004-09-24 2006-03-31 Pechiney Rhenalu Sa Produits en alliage d'aluminium a haute tenacite et procede d'elaboration
WO2007051162A2 (en) * 2005-10-28 2007-05-03 Alcoa Inc. A HIGH CRASHWORTHINESS AL-SI-Mg ALLOY AND METHODS FOR PRODUCING AUTOMOTIVE CASTING
CN100402681C (zh) * 2006-09-05 2008-07-16 中国铝业股份有限公司 一种Al-Ti-C中间合金的制备方法
CN101871052A (zh) * 2010-06-28 2010-10-27 江阴新仁科技有限公司 一种净化铝及铝合金熔体的方法
CN101994045A (zh) * 2010-12-10 2011-03-30 西南铝业（集团）有限责任公司 一种铝锆中间合金及制备方法
EP2357263A1 (de) * 2010-02-05 2011-08-17 Sun Xing Chemical & Metallurgical Materials (Shenzhen) Co. Ltd. Verfahren zur steuerung von variationen einer al-ti-c-legierungs-granverfeinerungskapazität durch steuerung des kompressionsverhältnisses
CN102212710A (zh) * 2011-08-02 2011-10-12 江苏中欧材料研究院有限公司 一种原位亚微米多元颗粒增强铝基复合新体系及材料
CN102212725A (zh) * 2011-06-10 2011-10-12 新星化工冶金材料(深圳)有限公司 铝-锆-钛-碳中间合金在镁及镁合金变形加工中的应用
CN102220525A (zh) * 2011-07-29 2011-10-19 哈尔滨中飞新技术股份有限公司 一种铝合金熔炼净化装置及熔炼净化方法
CN102225464A (zh) * 2011-06-10 2011-10-26 新星化工冶金材料(深圳)有限公司 镁及镁合金用铝-锆-钛-碳晶粒细化剂及其制备方法
CN102268620A (zh) * 2011-08-01 2011-12-07 南昌大学 一种Al3Ti颗粒增强Al-Zn-Mg-Cu基铝合金的固溶处理方法
CN102268621A (zh) * 2011-09-09 2011-12-07 西南铝业（集团）有限责任公司 一种铝合金棒材生产方法
CN102329993A (zh) * 2011-09-07 2012-01-25 山东大学 一种高硼高碳铝基中间合金及其制备方法
CN102409270A (zh) * 2011-11-07 2012-04-11 内蒙古北方重工业集团有限公司 一种大型铝合金环件轧制和电炉固溶处理方法
US8157932B2 (en) 2005-05-25 2012-04-17 Alcoa Inc. Al-Zn-Mg-Cu-Sc high strength alloy for aerospace and automotive castings
CN102433454A (zh) * 2011-09-22 2012-05-02 郑州大学 一种热膨胀系数可控的金属基陶瓷材料Al-Zr2P2WO12的烧结合成方法
WO2012065453A1 (zh) * 2011-06-10 2012-05-24 新星化工冶金材料(深圳)有限公司 铝-锆-钛-碳中间合金的制备方法
WO2012110788A2 (en) 2011-02-18 2012-08-23 Brunel University Method of refining metal alloys
CN102703738A (zh) * 2012-05-17 2012-10-03 上海交通大学 Al－Ti－B－C四元晶粒细化剂的制备方法
US8349462B2 (en) 2009-01-16 2013-01-08 Alcoa Inc. Aluminum alloys, aluminum alloy products and methods for making the same
CN105624481A (zh) * 2016-03-28 2016-06-01 福建省科源新型材料有限公司 一种降低成本及能耗的铝制品制备工艺
US20170022593A1 (en) * 2014-03-11 2017-01-26 Sapa Extrusions, Inc. High strength aluminum alloys
CN109385542A (zh) * 2018-09-17 2019-02-26 上海大学 用于晶粒细化的铝铌硼合金杆的制备方法
CN110983213A (zh) * 2019-11-12 2020-04-10 上海交通大学 一种超细结构高强韧薄带铝的制备方法

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CN103060584B (zh) * 2012-12-21 2015-05-20 佛山市深达美特种铝合金有限公司 一种超细晶6061铝合金及其制备方法
CN103614581B (zh) * 2013-12-20 2015-09-30 西南铝业（集团）有限责任公司 一种1系铝合金铸锭的生产工艺
CN108251675B (zh) * 2017-12-26 2020-04-03 上海大学 一种铸造铝硅合金用Al-Ti-Nb-B细化剂及其制备方法及应用
CN118308630B (zh) * 2024-06-07 2024-09-10 湘潭大学 一种合金铸造用Al-Ti-Nb-B-C细化剂及其制备方法和应用

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Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1590495A4 (de) * 2002-12-20 2006-02-08 Alcoa Inc Al-ni-mn-gusslegierung für automobil- und luftfahrt-strukturkomponentenstrukturbestandteile
EP1590495A1 (de) * 2002-12-20 2005-11-02 Alcoa Inc. Al-ni-mn-gusslegierung für automobil- und luftfahrt-strukturkomponentenstrukturbestandteile
EP2224026A1 (de) * 2002-12-20 2010-09-01 Alcoa Inc. Al-Ni-Mn-Gusslegierung für Automobil- und Luftfahrt-Strukturkomponentenstrukturbestandteile
CN101027419B (zh) * 2004-09-24 2010-06-16 爱尔康何纳吕公司 高强度铝合金制品及其制备方法
FR2875815A1 (fr) * 2004-09-24 2006-03-31 Pechiney Rhenalu Sa Produits en alliage d'aluminium a haute tenacite et procede d'elaboration
WO2006035133A1 (fr) * 2004-09-24 2006-04-06 Alcan Rhenalu Produits en alliage d ' aluminium a haute tenacite et procede d ' elaboration
US7615125B2 (en) 2004-09-24 2009-11-10 Alcan Rhenalu Aluminum alloy products with high toughness and production process thereof
US8157932B2 (en) 2005-05-25 2012-04-17 Alcoa Inc. Al-Zn-Mg-Cu-Sc high strength alloy for aerospace and automotive castings
WO2007051162A2 (en) * 2005-10-28 2007-05-03 Alcoa Inc. A HIGH CRASHWORTHINESS AL-SI-Mg ALLOY AND METHODS FOR PRODUCING AUTOMOTIVE CASTING
WO2007051162A3 (en) * 2005-10-28 2008-04-03 Alcoa Inc A HIGH CRASHWORTHINESS AL-SI-Mg ALLOY AND METHODS FOR PRODUCING AUTOMOTIVE CASTING
CN100402681C (zh) * 2006-09-05 2008-07-16 中国铝业股份有限公司 一种Al-Ti-C中间合金的制备方法
US8950465B2 (en) 2009-01-16 2015-02-10 Alcoa Inc. Aluminum alloys, aluminum alloy products and methods for making the same
US8349462B2 (en) 2009-01-16 2013-01-08 Alcoa Inc. Aluminum alloys, aluminum alloy products and methods for making the same
EP2357263A1 (de) * 2010-02-05 2011-08-17 Sun Xing Chemical & Metallurgical Materials (Shenzhen) Co. Ltd. Verfahren zur steuerung von variationen einer al-ti-c-legierungs-granverfeinerungskapazität durch steuerung des kompressionsverhältnisses
EP2357263A4 (de) * 2010-02-05 2012-12-05 Sun Xing Chemical & Metallurg Materials Shenzhen Co Ltd Verfahren zur steuerung von variationen einer al-ti-c-legierungs-granverfeinerungskapazität durch steuerung des kompressionsverhältnisses
CN101871052A (zh) * 2010-06-28 2010-10-27 江阴新仁科技有限公司 一种净化铝及铝合金熔体的方法
CN101871052B (zh) * 2010-06-28 2012-06-13 江阴新仁科技有限公司 一种净化铝及铝合金熔体的方法
CN101994045A (zh) * 2010-12-10 2011-03-30 西南铝业（集团）有限责任公司 一种铝锆中间合金及制备方法
CN101994045B (zh) * 2010-12-10 2012-07-11 西南铝业（集团）有限责任公司 一种铝锆中间合金的制备方法
WO2012110788A3 (en) * 2011-02-18 2012-10-26 Brunel University Method of refining metal alloys
US10329651B2 (en) 2011-02-18 2019-06-25 Brunel University London Method of refining metal alloys
WO2012110788A2 (en) 2011-02-18 2012-08-23 Brunel University Method of refining metal alloys
GB2494353B (en) * 2011-06-10 2013-07-24 Shenzhen Sunxing Light Alloys Materials Co Ltd Use of aluminium-zirconium-titanium-carbon intermediate alloy in wrought processing of magnesium and magnesium alloys
CN102225464B (zh) * 2011-06-10 2013-07-10 深圳市新星轻合金材料股份有限公司 镁及镁合金用铝-锆-钛-碳晶粒细化剂及其制备方法
GB2494353A (en) * 2011-06-10 2013-03-06 Shenzhen Sunxing Light Alloys Materials Co Ltd Application of aluminium-zirconium-titanium-carbon intermediate alloy in deformation process of magnesium and magnesium alloys
WO2012065454A1 (zh) * 2011-06-10 2012-05-24 新星化工冶金材料(深圳)有限公司 铝-锆-钛-碳中间合金在镁及镁合金变形加工中的应用
WO2012065453A1 (zh) * 2011-06-10 2012-05-24 新星化工冶金材料(深圳)有限公司 铝-锆-钛-碳中间合金的制备方法
WO2012065455A1 (zh) * 2011-06-10 2012-05-24 新星化工冶金材料(深圳)有限公司 镁及镁合金用铝-锆-钛-碳晶粒细化剂及其制备方法
CN102225464A (zh) * 2011-06-10 2011-10-26 新星化工冶金材料(深圳)有限公司 镁及镁合金用铝-锆-钛-碳晶粒细化剂及其制备方法
CN102212725A (zh) * 2011-06-10 2011-10-12 新星化工冶金材料(深圳)有限公司 铝-锆-钛-碳中间合金在镁及镁合金变形加工中的应用
CN102220525A (zh) * 2011-07-29 2011-10-19 哈尔滨中飞新技术股份有限公司 一种铝合金熔炼净化装置及熔炼净化方法
CN102220525B (zh) * 2011-07-29 2012-10-17 哈尔滨中飞新技术股份有限公司 一种铝合金熔炼净化装置及熔炼净化方法
CN102268620A (zh) * 2011-08-01 2011-12-07 南昌大学 一种Al3Ti颗粒增强Al-Zn-Mg-Cu基铝合金的固溶处理方法
CN102212710A (zh) * 2011-08-02 2011-10-12 江苏中欧材料研究院有限公司 一种原位亚微米多元颗粒增强铝基复合新体系及材料
CN102212710B (zh) * 2011-08-02 2013-02-13 江苏中欧材料研究院有限公司 一种原位亚微米多元颗粒增强铝基复合新体系及材料
CN102329993A (zh) * 2011-09-07 2012-01-25 山东大学 一种高硼高碳铝基中间合金及其制备方法
CN102268621B (zh) * 2011-09-09 2013-03-20 西南铝业（集团）有限责任公司 一种铝合金棒材生产方法
CN102268621A (zh) * 2011-09-09 2011-12-07 西南铝业（集团）有限责任公司 一种铝合金棒材生产方法
CN102433454A (zh) * 2011-09-22 2012-05-02 郑州大学 一种热膨胀系数可控的金属基陶瓷材料Al-Zr2P2WO12的烧结合成方法
CN102409270A (zh) * 2011-11-07 2012-04-11 内蒙古北方重工业集团有限公司 一种大型铝合金环件轧制和电炉固溶处理方法
CN102703738A (zh) * 2012-05-17 2012-10-03 上海交通大学 Al－Ti－B－C四元晶粒细化剂的制备方法
US20170022593A1 (en) * 2014-03-11 2017-01-26 Sapa Extrusions, Inc. High strength aluminum alloys
CN105624481A (zh) * 2016-03-28 2016-06-01 福建省科源新型材料有限公司 一种降低成本及能耗的铝制品制备工艺
CN109385542A (zh) * 2018-09-17 2019-02-26 上海大学 用于晶粒细化的铝铌硼合金杆的制备方法
CN109385542B (zh) * 2018-09-17 2020-11-24 上海大学 用于晶粒细化的铝铌硼合金杆的制备方法
CN110983213A (zh) * 2019-11-12 2020-04-10 上海交通大学 一种超细结构高强韧薄带铝的制备方法
CN110983213B (zh) * 2019-11-12 2021-06-04 上交大(徐州)新材料研究院有限公司 一种超细结构高强韧薄带铝的制备方法

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