EP1197445B1 - Tissu antistatique pour recipients flexibles pour produits en vrac - Google Patents

Tissu antistatique pour recipients flexibles pour produits en vrac Download PDF

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Publication number
EP1197445B1
EP1197445B1 EP20010123100 EP01123100A EP1197445B1 EP 1197445 B1 EP1197445 B1 EP 1197445B1 EP 20010123100 EP20010123100 EP 20010123100 EP 01123100 A EP01123100 A EP 01123100A EP 1197445 B1 EP1197445 B1 EP 1197445B1
Authority
EP
European Patent Office
Prior art keywords
antistatic
quasi
bulk goods
goods container
conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP20010123100
Other languages
German (de)
English (en)
Other versions
EP1197445A1 (fr
Inventor
Siegfried Hartmann
Egon Wurr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eurea Verpackungs GmbH and Co KG
Original Assignee
Eurea Verpackungs GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eurea Verpackungs GmbH and Co KG filed Critical Eurea Verpackungs GmbH and Co KG
Publication of EP1197445A1 publication Critical patent/EP1197445A1/fr
Application granted granted Critical
Publication of EP1197445B1 publication Critical patent/EP1197445B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/441Yarns or threads with antistatic, conductive or radiation-shielding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D88/00Large containers
    • B65D88/16Large containers flexible
    • B65D88/1612Flexible intermediate bulk containers [FIBC]
    • B65D88/165Flexible intermediate bulk containers [FIBC] with electrically conductive properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/533Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads antistatic; electrically conductive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1362Textile, fabric, cloth, or pile containing [e.g., web, net, woven, knitted, mesh, nonwoven, matted, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2918Rod, strand, filament or fiber including free carbon or carbide or therewith [not as steel]
    • Y10T428/292In coating or impregnation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2929Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
    • Y10T428/2931Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2973Particular cross section
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2418Coating or impregnation increases electrical conductivity or anti-static quality

Definitions

  • the invention relates to an antistatic flexible bulk container with the features of the preamble of the claim 1.
  • a fabric of this type is for the high mechanical stresses, like when using the fabric for one flexible bulk container, well suited, and through the woven electrically conductive threads will be a safe discharge reached by electrostatic charge.
  • a fabric called “electrically conductive” has a resistance to earth of less than 10 8 ⁇ .
  • Such a leakage resistance is generally required for explosion protection measures based on various technical safety regulations, including flexible bulk material containers made of polypropylene tape type "C” in accordance with the classification of the German industrial working group "Combustible Dusts / Electrostatics”.
  • the fabric has an adverse effect entails: due to the low resistance can charges become very fast and with a high charge density move and move across the entire surface of the fabric then at a point where a touch by an opposing one charged charge carrier or for example a or grounded person, suddenly discharge. thats why always before the start of a filling process that separates the charge cause a connection to the earth, resulting charges immediately from the surface of the tissue can flow off against earth.
  • GB 21 01 559 A1 is a bulk container known, which is made of a fabric in the metal threads are incorporated over the electrostatic charges of the tissue can be derived.
  • Tissues to which an antistatic is applied are also known is so that the finished fabric is electrical Can derive charges.
  • the fabric produced in this way only fulfills that as new goods Fire and explosion hazard requirements; the conductive antistatic coating according to the state the technology is not permanent, rather it is temporal is limited.
  • Equipment with an applied antistatic Coating has been used in such applications proven unsuitable in which the fabric is strong mechanical Abrasion is subject to, even with bulk containers scrape together when stacking over large areas or over be ground. With the high strains one highly stressed plastic fabric tears the coating and / or flakes. In addition, these containers are on loan used several times. Then it is particularly dangerous that the loss of electrical conductivity caused by abrasion is not recognizable during the period of use, so that protection requirements are assumed for users, that are no longer there.
  • FIBC flexible Intermediate bulk containers
  • corona discharge occurs on a charge carrier with a very small one Radius of curvature, so also on thin woven threads or on Tips on. With the corona discharge a very arises weak, limited to the immediate vicinity of the tip Discharge to the air, which is continuous and over one longer period expires, so manual grounding over ground wire is not required.
  • the conductivity of the tissue is so great that a fast charge transfer when in contact with a large charge sink and an associated sudden discharge can occur with spark formation.
  • Another disadvantage is that the antistatic, quasi-conductive It is difficult to produce threads in the known fabric and are to be processed. Already applying one metallic surface on a plastic thread formed core is complex and expensive. The antistatic Sheathing is subject to mechanical wear as before has been described for full-area coatings.
  • the antistatic thread has a cross-sectional geometry, those of those commonly used for bulk containers Ribbon tissues deviate and thus in terms of Processability causes problems.
  • the diameter of the coated thread can for reasons of Processability and mechanical resilience too not be kept as small as it would be desirable to the effect of corona discharge over the length of the thread and not only at the ends - to be able to use. Therefore can still local charge fields in unfavorable conditions form on the tissue surface that is not due to corona discharge are degradable, but degrade suddenly can.
  • thermoplastic Polymer mass is an electrically conductive Includes network of non-metallic, microcrystalline needles. This network is fusible, so that it can the usual processing methods of plastics technology is processable and with cooling of a plastic melt crystallized again.
  • the microcrystalline network is in the polymer mass is embedded and therefore wear-resistant because it not be abrasively removed from the surface of a component can.
  • the invention has for its object a bulk container of the type mentioned at the outset, the has permanent antistatic properties and thus in explosive and fire hazardous areas can be used and which, in particular, are not earthed in all applications got to.
  • the task with an antistatic flexible bulk container with the characteristics of the generic term of claim 1 in that the antistatic, quasi-conductive threads made of a thermoplastic Made of plastic in which the conductivity increases Is mixed in additive, which is a thermoplastic, thermosetting or cross-linked polymer that is electrically conductive network of microcrystalline needles is permeated as a means of forming current paths in the threads to enable a braked charge transport.
  • a thermoplastic Made of plastic in which the conductivity increases Is mixed in additive, which is a thermoplastic, thermosetting or cross-linked polymer that is electrically conductive network of microcrystalline needles is permeated as a means of forming current paths in the threads to enable a braked charge transport.
  • a fabric is called "antistatic, quasi-conductive" here, the surface resistance of which, measured according to DIN 53482, is greater than 10 8 ⁇ and less than 10 11 ⁇ .
  • the electron flow is strongly slowed down at this resistance, but is still possible.
  • Plastic tapes are understood to be in cross section have a large width in relation to their thickness and which can be processed using web technology.
  • the thread By mixing the conductive additive into the polymer mass the thread is achieved on the one hand that an electron line is made possible within the thread.
  • the specific electrical resistance of the obtained thermoplastic mixture however so high that the electron flow is possible only very slowly. This ensures that a constant flow of electrons and a constant Delivery of cargo to the environment is possible, however cannot flow as much charge in a short time, that there is a sudden high energy discharge can come under the formation of an ignition spark.
  • the thread Due to the geometry of the quasi-conductive ribbon-shaped
  • the thread has very narrow, sharp edges. On these edges Corona discharge can occur over the entire length of the ribbon take place through which constantly in controlled Wise charge from the surface of the tissue to the environment can drain off.
  • corona discharge to the Narrow edges gives the further advantage that the relative wide ribbons have a large surface and therefore one have a large capacity for receiving electrical charge. The charges are seen across the large surface of the fabric distributed, and local charge concentrations leading to sudden high energy discharges, are avoided.
  • the aforementioned can be used Establish a manual earth connection via earth clamp and cable in most applications to be dispensed with, since contactless electrical derivation Charges to the environment is enabled.
  • To form "islands" of electrostatically insulating Fabric sections in the middle of the grid made of electrically conductive Avoiding threads is the distance between the threads not less than 1 cm and not more than 5 cm. Preferably a distance of 3 cm is selected.
  • the fabric advantageously has the warp threads, the weft threads and covering the antistatic, quasi-conductive threads antistatic plastic coating made from a thermoplastic consists of a conductivity increasing additive is mixed. Through this coating it is achieved that a load is large can spread over the fabric surface and local charge peaks can be broken down.
  • FIG. 1 shows a flexible fabric made from a fabric 100 Bulk goods container 10 with a carrying bag 15 there is a carrying strap designed as transport loops 17, 17 '.
  • the carrying bag 15 In its lid area 14, the carrying bag 15 has a filler neck 18 and in its bottom area 11 an outlet nozzle 19 on.
  • the carrying bag 15 is made of the anti-static Fabric 100 of the invention made.
  • in the collar area 16 in Lid area 14 and in the area of the filler 18 and outlet nozzle 19 can be used to optimize the discharge behavior Compaction of the grid 12 from antistatic, quasi-conductive Threads are provided.
  • in the material for the carrying straps 17, 17 'to ensure the derivation conductive material incorporated.
  • FIG. 2 shows a schematic view of an antistatic, quasi-conductive warp 4 or weft 5 as they offers itself under the microscope.
  • this preferred embodiment are 20% by mass of an additive, as described in WO 96/09629 is described, in a base polymer, here polypropylene, mixed.
  • a matrix 8 of the base polymer there are a large number of microcrystalline needles 6 embedded, which are meltable and which crystallize out on cooling. In order to the mixture is extrudable, sprayable and otherwise can be processed with the techniques of plastics processing.
  • the needles 6 are in such a density within the matrix 8 arranged so that they touch or overlap.
  • the example of the detail shown here forms between any point 7.1 and another Point 7.2 at the other end of a thread section through the microcrystalline needles 6 a multiplicity of current paths 7 , one of which is shown here as thick Line is marked.
  • a current path 7 braked charge transport is possible.
  • acicular metal particles of macroscopic size so with about 0.1 to 2 mm in length, embedded in the matrix 8 are. These metal particles appear as fine tips on the Surfaces of the antistatic, quasi-conductive threads; on A corona spray discharge can take place at each of these tips.
  • Fig. 3 is a portion of one made in accordance with the invention Fabric 100 shown.
  • Both warp threads 3 and Weft threads 4 are tapes made of a thermoplastic material. Such tapes are easily obtained by that a film is made from the plastic, which is then cut into ribbons by a knife in the direction of the web becomes; the ribbons are then stretched.
  • There standard plastics, especially polypropylene, are also suitable and the ribbons are one in comparison to textile yarns Large widths of approximately 0.5 to 5 mm can be inexpensive large-area fabrics are produced.
  • In the tissue 100 are antistatic, quasi-conductive threads 4 woven into the here for better illustration schematically as a bold double line are drawn.
  • the antistatic, quasi-conductive threads 4 are preferably in woven into a chain at a distance of about 3 cm from each other. Around especially in the event of breakage of the antistatic, quasi-conductive thread a derivative of the electrical charge ensure even at greater intervals of preferably 30 cm antistatic, quasi-conductive threads 5 in Weft to be woven. About these weft threads 5 can Interruption of a quasi-conductive warp thread 4 a diversion of the electrical charge flow until the next intact Warp thread 4 can be reached.
  • antistatic, quasi-conductive threads 4 mainly to be woven as weft or warp threads is for the electrical Properties of the fabric according to the invention irrelevant and can be chosen according to the needs of the weaver.
  • non-conductive threads 2, 3 and antistatic, quasi-conductive threads 4, 5 is preferably the same, there are no weaving difficulties, when the antistatic, quasi-conductive threads are woven together in the weft become.
  • round threads with mixed additives can also be used Use if they are very thin and therefore the possibility a good corona discharge.
  • Fig. 4 shows the discharge of the tissue.
  • the voltage drop is plotted over time. Starting from a high potential U H , the charge supply is interrupted at time t 1 . As the solid, upper line shows, the charge continuously degrades due to continuous corona discharge at the edges of the ribbon, the thread ends and any macroscopic metal particle tips that have been mixed in, until it reaches a minimum at the level of U L1 at time t 2 . Grounding was not carried out here.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)
  • Elimination Of Static Electricity (AREA)

Claims (9)

  1. Récipient (10) flexible et antistatique pour produits en vrac, formé d'un sac flexible et de dispositifs de transport fixés à celui-ci, tels qu'anse (17, 17'), boucle, sangle de transport ou analogue, le sac au moins étant constitué d'un tissu (100) antistatique qui présente des fils (2, 3) électriquement non conducteurs et des fils (4) antistatiques, quasi-conducteurs, le fil antistatique, quasi-conducteur étant réalisé en forme de bandelette avec une section approximativement rectangulaire et un bord étroit et vif ou étant un fin fil rond,
       caractérisé en ce que les fils (4) antistatiques, quasi-conducteurs sont en une matière thermoplastique à laquelle est mélangé un additif augmentant la conductibilité qui est un polymère thermoplastique, thermodurcissable ou réticulé qui est traversé par un réseau électriquement conducteur d'aiguilles (6) microcristallines, comme moyen de formation de trajets de courant (7) dans les fils (4) aux fins de permettre un transport de charge ralenti.
  2. Récipient (10) flexible pour produits en vrac selon la revendication 1, caractérisé en ce que l'additif est mélangé selon un rapport de masse de 5 à 30% dans la matière thermoplastique des fils (4) antistatiques, quasi-conducteurs.
  3. Récipient (10) flexible pour produits en vrac selon la revendication 1 ou 2, caractérisé en ce qu'en plus de l'additif, des particules métalliques, en forme d'aiguille, isolées les unes par rapport aux autres et permettant une décharge en couronne, sont noyées dans la matière thermoplastique des fils (4) antistatiques, quasi-conducteurs.
  4. Récipient (10) flexible pour produits en vrac selon l'une des revendications 1 à 3, caractérisé en ce que le fil en forme de bandelette présente une épaisseur de 100 à 500 µm et que la largeur représente 10 à 100 fois l'épaisseur.
  5. Récipient (10) flexible pour produits en vrac selon l'une des revendications 1 à 4, caractérisé en ce que l'écartement mutuel des fils (4) antistatiques, quasi-conducteurs dans le sens de la chaíne (3) est de 1 à 5 cm, de préférence de 3 cm.
  6. Récipient (10) flexible pour produits en vrac selon l'une des revendications 1 à 5, caractérisé en ce que l'écartement mutuel des fils (4) antistatiques, quasi-conducteurs dans le sens de la trame est de 10 à 60 cm, de préférence de 30 cm.
  7. Récipient (10) flexible pour produits en vrac selon l'une des revendications 1 à 6, caractérisé par un revêtement antistatique en matière plastique qui recouvre les fils de chaíne (2), les fils de trame (3) et les fils (4) antistatiques quasi-conducteurs et est constitué d'une matière thermoplastique à laquelle est mélangé un additif augmentant la conductibilité.
  8. Récipient (.10) flexible pour produits en vrac selon l'une des revendications 1 à 6, caractérisé en ce qu'un revêtement antistatique en matière plastique est appliqué sur la surface, tournée vers l'extérieur, du tissu antistatique formant le sac.
  9. Récipient (10) flexible pour produits en vrac selon l'une des revendications 1 à 8, caractérisé en ce que le tissu (100) antistatique du récipient pour produits en vrac, dans la région du couvercle (14) et du rebord (16) de celui-ci, présente un nombre plus important de fils (4) antistatiques, quasi-conducteurs que dans le reste du tissu formant le sac.
EP20010123100 2000-09-29 2001-09-27 Tissu antistatique pour recipients flexibles pour produits en vrac Expired - Lifetime EP1197445B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10048765A DE10048765C2 (de) 2000-09-29 2000-09-29 Antistatisches Gewebe für flexible Schüttgutbehälter
DE10048765 2000-09-29

Publications (2)

Publication Number Publication Date
EP1197445A1 EP1197445A1 (fr) 2002-04-17
EP1197445B1 true EP1197445B1 (fr) 2003-12-10

Family

ID=7658415

Family Applications (1)

Application Number Title Priority Date Filing Date
EP20010123100 Expired - Lifetime EP1197445B1 (fr) 2000-09-29 2001-09-27 Tissu antistatique pour recipients flexibles pour produits en vrac

Country Status (4)

Country Link
US (1) US6572942B2 (fr)
EP (1) EP1197445B1 (fr)
AT (1) ATE256054T1 (fr)
DE (2) DE10048765C2 (fr)

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TR200103444A2 (tr) * 2001-11-28 2003-06-23 Sunj�T@Sun�@J�T@Sanay�@Ve@T�C@A@� Daimi antistatik etki sağlayan çoklu ip formasyonuna sahip büyük çuval
US6900975B2 (en) * 2002-07-05 2005-05-31 Sunjit Suni Jut Sanayi Ve Tioaret A.S. Inner device for neutralization of electrostatic charges from material in contact
ES2225712T3 (es) * 2002-10-16 2005-03-16 Unsa Ambalaj Sanayi Ve Ticaret A.S. Contenedor flexible de uso intermedio para materiales a granel.
FI20022098A (fi) 2002-11-26 2004-05-27 Rosenlew Fibc Benelux N V Sähköä johtava säiliö
EP1510474A1 (fr) 2003-08-27 2005-03-02 Gunner Schroll Conteneur souple pour matières en vrac
DE102004006871A1 (de) * 2004-02-12 2005-09-01 Dr. Klaus Schulte Gmbh Chemisch-Technische Fabrikation Dauerhaft ableitfähiges und dauerhaft flammhemmendes Gewebe
US20080020161A1 (en) * 2004-04-01 2008-01-24 Shimon Shacham Antistatic Dissipative Flexible Intermediate Bulk Container
DE102004046579A1 (de) * 2004-09-23 2006-04-06 Nordenia Deutschland Emsdetten Gmbh Flexibler Schüttgutbehälter
US7431501B2 (en) * 2004-11-15 2008-10-07 The United States Of America As Represented By The Secretary Of The Navy Bag assembly providing electrostatic discharge protection
WO2006130637A2 (fr) * 2005-05-31 2006-12-07 Noble Fiber Technologies, Llc Contenant de masse intermediaire souple presentant une decharge optimale de charge dangereuse
US20070275787A1 (en) * 2005-12-09 2007-11-29 Bouchard Roland C Bowling ball having an RFID tag
US8360642B2 (en) * 2007-07-05 2013-01-29 Jianyi Sun Super air permeability and reinforced seams of peanuts bag (APC BAG-SBA)
CN102811925B (zh) * 2009-12-02 2015-11-25 英默里斯滑石美国有限公司 具有卸料斜槽的柔性散装存储容器
US20120149263A1 (en) * 2010-06-14 2012-06-14 Sava Cvek Elastomeric Mesh Fabric
US20140212070A1 (en) * 2013-01-31 2014-07-31 Yuan Da Plastic Fabric Corp. Bulk bag with lift loops
CN105307955B (zh) * 2013-03-15 2018-02-13 特克斯恩有限责任公司 具有感应控制的柔性中型集装容器
DE102014010273A1 (de) * 2014-07-11 2016-01-14 Bayer Technology Services Gmbh Erdungsfähiger flexibler Schüttgutbehälter

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GB2101559B (en) * 1981-07-09 1985-12-04 Humber Fabrics Limited Electrically conductive container
DE3938414C2 (de) * 1989-08-19 1994-04-14 Eurea Verpackung Schüttgutbehälter aus einem gewebten Tragbeutel und daran befestigten Tragvorrichtungen
GB2297518B (en) * 1993-10-21 1998-04-01 Linq Ind Fabrics Inc Anti-incendiary flexible intermediate bulk container system
US5478154A (en) * 1994-06-01 1995-12-26 Linq Industrial Fabrics, Inc. Quasi-conductive anti-incendiary flexible intermediate bulk container
GB9418955D0 (en) * 1994-09-21 1994-11-09 Ciba Geigy Ag Novel electroconductive composition
US6112772A (en) * 1995-06-01 2000-09-05 Linq Industrial Fabrics, Inc. Low discharge anti-incendiary flexible intermediate bulk container
DE19826120C2 (de) * 1998-03-20 2001-06-07 Eurea Verpackung Flammhemmendes, elektrisch leitendes Gewebe

Also Published As

Publication number Publication date
EP1197445A1 (fr) 2002-04-17
DE50101123D1 (de) 2004-01-22
DE10048765C2 (de) 2003-02-20
US20020039631A1 (en) 2002-04-04
US6572942B2 (en) 2003-06-03
DE10048765A1 (de) 2002-04-25
ATE256054T1 (de) 2003-12-15

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