EP1185387A1 - Verfahren zum stranggiessen zwischen zylindern von austenitischen rostfreien stahlbändern hoher oberflächenqualität und die so hergestellten bänder - Google Patents

Verfahren zum stranggiessen zwischen zylindern von austenitischen rostfreien stahlbändern hoher oberflächenqualität und die so hergestellten bänder

Info

Publication number
EP1185387A1
EP1185387A1 EP00915237A EP00915237A EP1185387A1 EP 1185387 A1 EP1185387 A1 EP 1185387A1 EP 00915237 A EP00915237 A EP 00915237A EP 00915237 A EP00915237 A EP 00915237A EP 1185387 A1 EP1185387 A1 EP 1185387A1
Authority
EP
European Patent Office
Prior art keywords
steel
cylinders
gas
strips
austenitic stainless
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00915237A
Other languages
English (en)
French (fr)
Other versions
EP1185387B1 (de
Inventor
Christian Marchionni
Frédéric Mazurier
Jean-Michel Damasse
Frédéric Descaves
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
USINOR SA
Original Assignee
USINOR SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by USINOR SA filed Critical USINOR SA
Priority to SI200030035T priority Critical patent/SI1185387T1/xx
Publication of EP1185387A1 publication Critical patent/EP1185387A1/de
Application granted granted Critical
Publication of EP1185387B1 publication Critical patent/EP1185387B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637—Accessories therefor
    • B22D11/0648—Casting surfaces
    • B22D11/0651—Casting wheels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/001—Continuous casting of metals, i.e. casting in indefinite lengths of specific alloys
    • B22D11/002—Stainless steels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0622—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by two casting wheels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
    • B22D11/0637—Accessories therefor
    • B22D11/0697—Accessories therefor for casting in a protected atmosphere
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel

Definitions

  • the invention relates to the continuous casting of metals, and more precisely the continuous casting, directly from liquid metal, of stainless steel strips of the austenitic type, the thickness of which is of the order of a few mm, by the so-called process. of "casting between cylinders".
  • process. of "casting between cylinders" significant progress has been made in the development of processes for casting thin strips of carbon or stainless steel directly from liquid metal.
  • the method mainly used today is the casting of said liquid metal between two internally cooled cylinders, rotating around their horizontal axes in opposite directions, and arranged opposite one another, the minimum distance between their surfaces being substantially equal to the thickness that you want to give to the cast strip (for example a few mm).
  • the pouring space containing the liquid steel is defined by the lateral surfaces of the cylinders, on which the solidification of the strip is initiated, and by refractory side closure plates applied against the ends of the cylinders.
  • the liquid metal initiates its solidification on contact with the outer surfaces of the cylinders, on which it forms solidified "skins", which are made to meet at the "neck", that is to say the area where the distance between the cylinders is minimal.
  • microcracks appearing on the strip. These are small cracks which are nevertheless sufficient to make the cold processed products which result from them unfit for use. They form during the solidification of the steel and have a depth of the order of 40 ⁇ m and an opening of approximately 20 ⁇ m. Their appearance is linked to the contractions of the metal during the solidification of the skins in contact with the cylinders, over the length of their contact arc. This solidification can be described as comprising two successive stages. The first stage occurs during the initial contact between the liquid steel and the surface of the cylinder, which results in the formation of a solid steel skin on the surface of the cylinders.
  • the second step concerns the growth of this skin up to the neck, where, as we said, it joins the skin formed on the other cylinder to form the fully solidified strip.
  • the contact between the steel and the surface of the cylinder is conditioned by the topography of the surface of the casting rolls, combined with the nature of the inerting gas surrounding the casting space and with the chemical composition of the steel. All these parameters intervene in the establishment of heat transfers between the steel and the cylinder and govern the conditions of solidification of the skins.
  • solidification and cooling of the skins they undergo contractions. They depend in particular on the extent of the phase transformation ⁇ - » ⁇ , which takes place with a significant variation in the density of the metal, at the microscopic level. It is determined by the composition of the cast metal.
  • Ni eq (%) Ni% + 0.31 Mn% + 22 C% + 14.2 N% + Cu%
  • EP-A-0 409 645 It combines a defined geometry of the "dimples" (hollow engravings of roughly circular or elliptical shape) present on the surface of the cylinders with the use as inerting gas of a gas mixture containing 30 90% of a gas soluble in steel, which fills the dimples at the time of the first cylinder / liquid steel contact.
  • the dimples can conventionally be produced by shot blasting or laser machining. In all the preceding documents, it is required that these dimples are separated from each other.
  • Document EP-A-0 679 114 proposes the use of circumferential grooves formed on the surface of the cylinders, which give said surface a roughness Ra of 2.5 to
  • Document EP-A-0 796 685 teaches to cast a steel whose Cr e q / Ni e q ratio is greater than 1.55 so as to minimize the phase changes at high temperature, and to carry out this casting using cylinders the surface of which has joined dimples of diameter 100-1500 ⁇ m and depth 20-150 ⁇ m and by inerting the vicinity of the meniscus (the intersection between the surface of the liquid steel and the surface of the cylinders) with a soluble gas in steel, or a mixture of gases mainly composed of such a soluble gas.
  • the roughness peaks serve as priming sites for solidification, while the roughness hollows constitute contraction joints of the metal during solidification, and allow a better distribution of the stresses.
  • the object of the invention is to propose a process for casting thin strips of austenitic stainless steel, the surface of which would be free from microcracks and other major defects, not requiring particularly restrictive casting conditions for its implementation, and making it possible to cast steels with a Cr eq / Ni eq ratio which is more extensive than in existing processes.
  • the subject of the invention is a process for the continuous casting of a strip of austenitic stainless steel of thickness less than or equal to 10 mm, directly from liquid metal, between two cooled horizontal cylinders, characterized in that than :
  • composition of said steel in weight percent, comprises: C% ⁇ 0.08; If% ⁇ 1; P% ⁇ 0.04; Mn% ⁇ 2; Cr% between 17 and 20; Ni% between 8 and 10.5; S% between 0.007 and 0.040; the remainder being iron and impurities resulting from processing;
  • the surface of the cylinders has contiguous dimples of approximately circular or elliptical section, with a diameter of 100 to 1500 ⁇ m and a depth of 20 to 150 ⁇ m;
  • the inerting gas surrounding the meniscus is a gas soluble in steel or a mixture of such gases, or consists at least of 50% by volume of such a gas or mixture of gases.
  • the invention also relates to bands which can be produced by this method.
  • the invention consists in combining conditions relating to the composition of the cast metal, the surface condition of the cylinders and the composition of the meniscus inerting gas, so as to obtain a strip-free surface. of micro cracks.
  • the main originality of the required composition is that the metal must contain a quantity of sulfur greater than the quantities most commonly encountered (without however being so great as to compromise the resistance of the products to corrosion), and that this content must be combined with a precise range of Cr eq / Ni e q ratios.
  • the conditions of the first contact between the liquid steel and the cylinders constitute a very important factor in the process of solidification of the strip, and notably influence the surface quality of the latter. Their good control is therefore very important to guarantee the absence of microcracks on the casting strip.
  • the inevitable fluctuations in the level of the surface of the liquid metal present between the cylinders complicate this control, in particular in that they are a source of irregularities in the heat exchanges which take place in this zone of first contact.
  • Other such irregularities are due, during the later stages of the solidification of the skins, to the contractions of the metal during solidification, which result in particular from phase transformations at high temperature characteristic of austenitic stainless steels. These contractions can cause micro cracks.
  • FIG. 1 shows a micrograph produced on a sample of a thin strip 1 of austenitic stainless steel, seen in longitudinal section.
  • This strip 1 has on its surface 2 a microcrack 3, of the type that the invention seeks precisely to avoid.
  • the metallographic attack carried out on the sample highlights a clear area 4 located around the microcrack 3 and in its extension: it corresponds to a segregated area enriched with certain elements such as nickel and manganese.
  • the curve in FIG. 2 translates the results of these investigations, which were carried out on strips of thickness 3 mm cast at a speed of 50 m / min.
  • the surfaces casting rolls were roughened by contiguous dimples of average depth 80 ⁇ m and average diameter 1000 ⁇ m.
  • the composition of the cast steels fell within the limits: C: 0.02-0.06%; Mn: 1.3-1.6%; P: 0.019-0.024%; If: 0.34-0.45%; Cr: 18.0-18.7%; Ni: 8.6-9.8%; S: 0.0005-0.446%.
  • the Cr eq / Ni eq ratios of these steels ranged from 1.79 to 1.85.
  • the inert gas surrounding the meniscus contained 60% by volume of nitrogen and 40% by volume of argon.
  • the inventors have determined a set of conditions to be respected so that the casting of austenitic stainless steels in thin strips takes place without the formation of microcracks on the surface of the strips, and they have been mentioned above. They are justified by the following considerations.
  • the sulfur content is less than 0.007%, the fluctuations in the level of the meniscus become too great, and the irregularities of the heat transfers which result therefrom cause the formation of microcracks, in particular when the Cr eq / Ni eq ratio is greater than 1 , 70.
  • the upper limit of the sulfur content is set at 0.04% because beyond this value, the influence of the sulfur content on the stability of the meniscus no longer increases significantly, and on the other hand, there is an increased risk of deterioration in the resistance to corrosion by pitting of the finished product made from these strips.
  • the phosphorus content must be kept below 0.04%, in order to avoid risks of hot cracking of the bands when the Cr eq / Ni eq ratio is close to 1.55, that is to say when solidification takes place partially in primary austenite, and not mainly in primary ferrite.
  • the Cr eq / Ni eq ratio must be at least 1.55, in that below this value, the steel solidifies at least partially into primary austenite, which increases the sensitivity to cracking of the strip and promotes the appearance of longitudinal cracks, which must be absolutely avoided, too.
  • a Cr eq / Ni eq ratio greater than 1.90 the contraction linked to the ferrite-austenite transformation becomes too great, and the microcracks are then inevitable.
  • the ferrite level in the strip becomes too high, which can lead to ruptures after the shaping of the finished products made from the strips thus cast.
  • the other analytical conditions on cast steel are conventional on the most common austenitic stainless steels, in particular those of type 304 and related. It is understood that elements other than those explicitly mentioned in the foregoing may be present in the steel, as impurities or alloying elements in small quantities, insofar as they would not significantly modify the solidification conditions and the surface tension of the liquid steel on the surface of the cylinders, which would be confirmed by the absence of microcracks on the strips produced.
  • the nature of the inerting gas surrounding the meniscus has a strong influence on the conditions of contact between the steel and the surface of the cylinders, in particular on the manner in which the transfer takes place "in negative" the roughness of the cylinders on the surface of the strip, and the risks of microcracks forming.
  • a gas wholly or mainly insoluble in steel such as argon or helium
  • the steel in the course of solidification does not penetrate little or little into the depressions of the surface of the cylinder. Heat extraction is therefore practically only carried out at the roughness peaks, which makes it very heterogeneous on the surface of the cylinder. This heterogeneity is favorable to the appearance of numerous microcracks.
  • an inerting gas containing a significant quantity of a gas soluble in steel such as nitrogen, hydrogen, ammonia, CO, a fortiori if it is entirely constituted by a such gas or a mixture of such gases
  • the steel penetrates well into the depressions of the surface of the cylinders, and the extraction of heat at the first contact is important.
  • this decreases the heterogeneity of heat extraction at the level of peaks and depressions. All this goes in the direction of limiting the risks of micro-crack formation.
  • the lower limit of the content of the inerting gas in a gas (or mixture of gas) soluble in steel taking into account the other casting conditions required for the composition of the metal and the roughness of the surfaces of the rolls.
  • Strips of austenitic stainless steel 3 mm thick were poured between cylinders.
  • the cylinder surfaces included joined dimples with an average diameter of 1000 ⁇ m and an average depth of 100 ⁇ m.
  • the inert gas surrounding the meniscus contained 40% argon and 60% nitrogen.
  • the composition of the steel varied within the following limits: C: 0.02-0.06%; Mn: 1.3-1.6%; P: 0.019-0.024%; If: 0.34-0.45%; Cr: 18.0-18.7%; Ni: 8.6-9.8%; S: 0.0005-0.0446%.
  • the Cr eq / Ni e q ratio of cast steels varied from 1.79 to 1.85.
  • the surface density of the microcracks on the strips thus cast was measured, and the results of these measurements were compared with the sulfur contents in the cast steels. Table 1 presents the conclusions of these tests.
  • Strips of thickness 3.8 mm in austenitic stainless steel were poured between cylinders, the compositions of which are shown in Table 2.
  • the cylinders had surface roughnesses characterized by the presence of contiguous dimples of average diameter 1000 ⁇ m and average depth 120 ⁇ m.
  • Table 3 Influence of the composition of the inerting gas on the surface density of the strip microcracks, according to the sulfur content and the Cr eq / Ni eq ratio of the cast steel
  • the composition of the inerting gas is a parameter on which we often wish to play to control the intensity of the heat transfers between the cylinders and the metal, for example to vary the bulging of the cylinders which affects the shape of the strip. (see document EP-A-0 736 350).
  • the results obtained with steel C therefore lead to the conclusion that a sulfur content of 0.005% cannot fall within the scope of the invention.
  • the strips cast with steels B and D do not exhibit microcracks as long as the nitrogen content of the inerting gas is at least 50%.
  • Their sulfur contents are respectively 0.019 and 0.039%, and their Cr eq / Ni eq ratios are respectively 1.82 and 1.64.
  • the invention applies preferably to the case of steels having a Cr e q / Ni eq ratio of between 1.70 and 1.90, since this range corresponds to steels in which have added less gammagenic elements (such as nickel) than for steels with a lower Cr eq / Ni eq ratio, and which are therefore more economical to manufacture.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Metal Extraction Processes (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Articles (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)
EP00915237A 1999-04-22 2000-04-12 Verfahren zum stranggiessen zwischen zylindern von austenitischen rostfreien stahlbändern hoher oberflächenqualität und die so hergestellten bänder Expired - Lifetime EP1185387B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SI200030035T SI1185387T1 (en) 1999-04-22 2000-04-12 Method for continuously casting between two rolls austenitic stainless steel strips with excellent surface quality and resulting strips

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9905052A FR2792560B1 (fr) 1999-04-22 1999-04-22 Procede de coulee continue entre cylindres de bandes d'acier inoxydable austenitique d'excellente qualite de surface, et bandes ainsi obtenues
FR9905052 1999-04-22
PCT/FR2000/000780 WO2000064612A1 (fr) 1999-04-22 2000-04-12 Procede de coulee continue entre cylindres de bandes d'acier inoxydable austentique d'excellente qualite de surface, et bandes ansi obtenues

Publications (2)

Publication Number Publication Date
EP1185387A1 true EP1185387A1 (de) 2002-03-13
EP1185387B1 EP1185387B1 (de) 2002-12-11

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ID=9544705

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00915237A Expired - Lifetime EP1185387B1 (de) 1999-04-22 2000-04-12 Verfahren zum stranggiessen zwischen zylindern von austenitischen rostfreien stahlbändern hoher oberflächenqualität und die so hergestellten bänder

Country Status (22)

Country Link
US (1) US6739383B1 (de)
EP (1) EP1185387B1 (de)
JP (1) JP4454868B2 (de)
KR (1) KR100636868B1 (de)
CN (1) CN1187148C (de)
AT (1) ATE229391T1 (de)
AU (1) AU767990B2 (de)
BR (1) BR0009894A (de)
CZ (1) CZ296650B6 (de)
DE (1) DE60000997T2 (de)
DK (1) DK1185387T3 (de)
ES (1) ES2188523T3 (de)
FR (1) FR2792560B1 (de)
PL (1) PL194231B1 (de)
PT (1) PT1185387E (de)
RU (1) RU2239518C2 (de)
SI (1) SI1185387T1 (de)
SK (1) SK286180B6 (de)
TR (1) TR200103014T2 (de)
TW (1) TW434058B (de)
WO (1) WO2000064612A1 (de)
ZA (1) ZA200108666B (de)

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Publication number Priority date Publication date Assignee Title
DE10349400B3 (de) * 2003-10-21 2005-06-16 Thyssenkrupp Nirosta Gmbh Verfahren zum Herstellen von gegossenem Stahlband
CN100493745C (zh) * 2006-06-23 2009-06-03 宝山钢铁股份有限公司 双辊薄带连铸方法
DE102007003548B3 (de) * 2007-01-24 2008-09-04 Thyssenkrupp Nirosta Gmbh Gießwalze für eine Zweiwalzengießvorrichtung und Zweiwalzengießvorrichtung
US7975754B2 (en) * 2007-08-13 2011-07-12 Nucor Corporation Thin cast steel strip with reduced microcracking
AU2008100847A4 (en) 2007-10-12 2008-10-09 Bluescope Steel Limited Method of forming textured casting rolls with diamond engraving
KR101239589B1 (ko) * 2010-12-27 2013-03-05 주식회사 포스코 고내식 마르텐사이트 스테인리스강 및 그 제조방법
WO2013075092A1 (en) 2011-11-17 2013-05-23 Nucor Corporation Method of continuous casting thin steel strip
KR101360660B1 (ko) * 2011-12-27 2014-02-07 주식회사 포스코 에지 품질이 우수한 오스테나이트계 스테인리스 강판의 제조방법
KR101510506B1 (ko) 2012-12-26 2015-04-08 주식회사 포스코 스컴의 생성을 저감시킨 쌍롤식 박판 주조 방법
CN103255352B (zh) * 2013-04-19 2015-05-20 山西太钢不锈钢股份有限公司 一种超低碳奥氏体不锈钢棒材中提高形成奥氏体的方法
JP6347864B1 (ja) * 2017-03-24 2018-06-27 日新製鋼株式会社 オーステナイト系ステンレス鋼スラブの製造方法
CN107030264B (zh) * 2017-04-27 2019-04-26 酒泉钢铁(集团)有限责任公司 一种超级奥氏体不锈钢双辊薄带铸轧生产工艺
CN109778077B (zh) * 2017-11-10 2021-01-08 大连华锐重工集团股份有限公司 一种核主泵泵壳材料的冶炼方法
BR112020016452A2 (pt) 2018-03-02 2020-12-15 Nippon Steel Corporation Método de produção de placa e equipamento de lingotamento contínuo
CN108239724A (zh) * 2018-03-29 2018-07-03 冯满 一种合金钢

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US5103895A (en) * 1989-07-20 1992-04-14 Nippon Steel Corporation Method and apparatus of continuously casting a metal sheet
JPH08505811A (ja) * 1993-11-18 1996-06-25 石川島播磨重工業株式会社 鋼ストリップ鋳造
FR2746333B1 (fr) * 1996-03-22 1998-04-24 Usinor Sacilor Procede de coulee continue d'une bande d'acier inoxydable austenitique sur une ou entre deux parois mobiles dont les surfaces sont pourvues de fossettes, et installation de coulee pour sa mise en oeuvre

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Also Published As

Publication number Publication date
AU3661800A (en) 2000-11-10
KR20010113824A (ko) 2001-12-28
TR200103014T2 (tr) 2002-03-21
PL351566A1 (en) 2003-05-05
EP1185387B1 (de) 2002-12-11
ZA200108666B (en) 2004-06-30
CN1187148C (zh) 2005-02-02
ES2188523T3 (es) 2003-07-01
DE60000997D1 (de) 2003-01-23
FR2792560B1 (fr) 2001-06-01
US6739383B1 (en) 2004-05-25
BR0009894A (pt) 2002-01-15
CZ296650B6 (cs) 2006-05-17
PL194231B1 (pl) 2007-05-31
CN1351528A (zh) 2002-05-29
PT1185387E (pt) 2003-04-30
KR100636868B1 (ko) 2006-10-19
WO2000064612A1 (fr) 2000-11-02
ATE229391T1 (de) 2002-12-15
DK1185387T3 (da) 2003-03-24
JP2002542039A (ja) 2002-12-10
JP4454868B2 (ja) 2010-04-21
RU2239518C2 (ru) 2004-11-10
CZ20013776A3 (cs) 2002-03-13
FR2792560A1 (fr) 2000-10-27
SI1185387T1 (en) 2003-04-30
DE60000997T2 (de) 2003-07-17
SK14602001A3 (sk) 2002-05-09
SK286180B6 (sk) 2008-04-07
AU767990B2 (en) 2003-11-27
TW434058B (en) 2001-05-16

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