EP1157153A1 - Verfahren zum reinigen und zur auffrischung von textilien - Google Patents
Verfahren zum reinigen und zur auffrischung von textilienInfo
- Publication number
- EP1157153A1 EP1157153A1 EP00917682A EP00917682A EP1157153A1 EP 1157153 A1 EP1157153 A1 EP 1157153A1 EP 00917682 A EP00917682 A EP 00917682A EP 00917682 A EP00917682 A EP 00917682A EP 1157153 A1 EP1157153 A1 EP 1157153A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- temperature
- void space
- air
- relative humidity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 115
- 239000004744 fabric Substances 0.000 title claims abstract description 53
- 238000004140 cleaning Methods 0.000 title claims description 67
- 239000011800 void material Substances 0.000 claims abstract description 45
- 239000000203 mixture Substances 0.000 claims description 75
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 20
- 239000002304 perfume Substances 0.000 claims description 18
- 238000010438 heat treatment Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 230000008901 benefit Effects 0.000 claims description 6
- 230000007423 decrease Effects 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 230000008569 process Effects 0.000 description 42
- 239000000758 substrate Substances 0.000 description 22
- 235000019645 odor Nutrition 0.000 description 10
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 9
- -1 for example Substances 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 238000007654 immersion Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000005108 dry cleaning Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 102000002322 Egg Proteins Human genes 0.000 description 3
- 108010000912 Egg Proteins Proteins 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 210000003278 egg shell Anatomy 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- RQRTXGHHWPFDNG-UHFFFAOYSA-N 1-butoxy-1-propoxypropan-1-ol Chemical compound CCCCOC(O)(CC)OCCC RQRTXGHHWPFDNG-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920001213 Polysorbate 20 Polymers 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000001877 deodorizing effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 230000000153 supplemental effect Effects 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- COYBYPVEJCWBTB-UHFFFAOYSA-N 1,1-dipropoxypropan-1-ol Chemical compound CCCOC(O)(CC)OCCC COYBYPVEJCWBTB-UHFFFAOYSA-N 0.000 description 1
- LNFLHXZJCVGTSO-UHFFFAOYSA-N 1-(3-butoxypropoxy)propan-1-ol Chemical compound CCCCOCCCOC(O)CC LNFLHXZJCVGTSO-UHFFFAOYSA-N 0.000 description 1
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 1
- JDMRKOIYSDTDSE-UHFFFAOYSA-N 1-ethoxy-1-propoxypropan-1-ol Chemical compound CCCOC(O)(CC)OCC JDMRKOIYSDTDSE-UHFFFAOYSA-N 0.000 description 1
- SECOYKOXGNGFSK-UHFFFAOYSA-N 1-methoxy-1-propoxypropan-1-ol Chemical compound CCCOC(O)(CC)OC SECOYKOXGNGFSK-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical class CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical class CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical class CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 230000037331 wrinkle reduction Effects 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F73/00—Apparatus for smoothing or removing creases from garments or other textile articles by formers, cores, stretchers, or internal frames, with the application of heat or steam
- D06F73/02—Apparatus for smoothing or removing creases from garments or other textile articles by formers, cores, stretchers, or internal frames, with the application of heat or steam having one or more treatment chambers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
Definitions
- the present invention relates to methods useful for cleaning and refreshing fabrics in a non-immersion cleaning process. Temperature and relative humidity are controlled in the multi- step processes of this invention.
- the humidity in the bag was a function of the moisture loaded in the bag and the temperature setting. But once the time and temperature were selected, the one step process was set. Moreover, when using a conventional tumble dryer, the consumer is often limited to the manufacturer's pre-set temperature conditions, which are established for drying clothes, not for cleaning and refreshing them. Often these manufacturer's conditions are sub-optimal with respect to one or more of dewrmkling, deodorizing, and optionally perfume deposition.
- Such m-home processes are designed for use in a conventional clothes dryer, or the like apparatus.
- Such apparatuses are not always readily available, they are often uneconomical, and in many countnes clothes dryers are simply unnecessary
- m many warm tropical regions people do not typically own clothes dryers because their clothes can be dried year-round by hanging them outside in the sun
- products that require a heating apparatus, such as a clothes dryer are of little or no value.
- a method for treating at least one fabric article comprising the steps of: a) placing the tab ⁇ c article in a container having an opening and at least one wall that defines an interior void space; b) raising the temperature and relative humidity of the air withm the interior ⁇ o ⁇ d space of the container to a predetermined first temperature and a predetermined first relative humidity for a predetermined first period of time; and c) changing at least one of the temperature or the relative humidity of the air withm the interior void space of the container at the end of the first period of time to a predetermined second temperature and a predetermined second relative humidity for a predetermined second period of time.
- the fabrics are contacted with an aqueous composition prior to be placed m a container according to step a) defined below.
- vapor is used to raise the temperature and relative humidity of the air withm the interior void space of the container, and more preferably the vent remains open at all times.
- the vapor introduced into the interior void space of the container comprises water and a perfume.
- a method for treating a fabric article comprising the steps of: a) placing the fabric article in a container having an opening and at least one wall that defines an interior void space; b) introducing ozone into the interior void space for a predetermined first period of time; and c) changing at least one of the temperature or the relative humidity of the air within the interior void space of the container at the end of the first period of time to a predetermined second temperature and a predetermined second humidity for a predetermined second period of time.
- the ozone can be generated by an ozone source, such as an ultraviolet lamp, or even a high voltage source, within the interior void space of the container.
- the level of ozone that is provided withm the container is between 0.5 and 200ppm, preferably between 0.5 and 50ppm, more preferably between 0 5 and 20ppm. Levels lower than 0.5 ppm are not preferred as they would not provide sufficient bleaching performance and consequently not provide sufficient performance of the benefit linked to the bleach property.
- the present invention provides benefits over the p ⁇ or art by defining the optimal process steps for cleaning and refreshing delicate fabric articles in an -home non-immersion cleaning process. The methods of this invention can be carried out in any appropriate container, such as a plastic bag, a wardrobe, a cabinet, or a tumble dryer.
- the methods of this invention involve at least two distinct steps, and preferably three steps. It has been surprisingly found that the optimal conditions tor deodo ⁇ zing a fab ⁇ c article differ from the conditions that are best for dew ⁇ nklmg. Likew ise perfume deposition onto a fab ⁇ c article requires a third set of conditions for optimal performance.
- temperature, relative humidity or both can be manipulated and controlled.
- one step of the process can involve ⁇ mtroduction of ozone into the container to neutralize odor causing chemicals on the fab ⁇ c articles being cleaned and refreshed.
- the present invention provides a method of delivering an active ingredient, for example, perfume, to the fabrics being treated. Simultaneously, the methods herein minimize the amount of vapor delivered so that the actives are not wasted. And finally, the methods herein are designed to deliver only enough vapor to accomplish the fab ⁇ c treatment process, without the need for additional mechanical drying.
- an active ingredient for example, perfume
- the present invention provides methods for cleaning and refreshing fabric articles in a domestic, non-immersion process.
- the methods require at least two steps, and preferably three.
- the methods can be carried out in any approp ⁇ ate apparatus wherein temperature and relative humidity can be manipulated and controlled.
- one of the method steps involves the introduction of ozone into the container to neutralize odor causing chemicals on the fab ⁇ c articles being cleaned and refreshed.
- a warm, humid environment inside the container volatilizes malodor components in the manner of a "steam distillation" process, and moistens fab ⁇ cs and the soils thereon. This moistening of fab ⁇ cs can loosen pre-set wrinkles, and because the fab ⁇ c articles are hung in the container new w ⁇ nkles do not form.
- Proper selection of the amount of the vapor, and specifically the amount of water used m the process and, importantly, proper venting of the container in the present manner can minimize shrinkage of the fabrics.
- the volatilized malodorous materials removed from the fab ⁇ cs, which are not captured by the filter if present can undesirably be re-deposited thereon.
- Relative humidity is a well known concept to those in the fab ⁇ c care arts. As used herein, “relative humidity” means the ratio of the actual amount of water vapor m the air to the greatest amount possible at the same temperature.
- Temperature and relative humidity controllers are well known to those skilled in the art, as are passive and active controllers.
- an “active” controller is a controller that reads an input and supplies feedback to the device being controlled and that device adjusts based on the feedback received.
- a “passive” controller is a controller that turns a device on or off, or opens or closes a device, based on a predetermined setting such as time. For example, a passive temperature controller would turn on a heating element or close a vent to increase the temperature in a given environment and after a certain period of time the heating element is turned off or the vent is opened.
- an active temperature controller reads the temperature and if, for example, the temperature is too low, the power to the heating element is increased or the vent is closed to increase the temperature.
- the fab ⁇ c article should at least be substantially free of odor and wrinkles after a cleaning and refreshing operation. It is often preferred that the article be perfumed to give it a pleasant odor, and it should be free of localized stains.
- the methods of this invention require at least two steps designed toward deodorizing, dew ⁇ nklmg and/or perfume deposition on a fab ⁇ c article. Additionally, a manual spot removal process for removing localized stains is provided, but the spot removal process is conducted outside of the apparatus The conditions for each of these methods steps are desc ⁇ bed in greater detail below.
- Deodo ⁇ zation must be distinguished from odor- masking, which involves applying a pleasant scent to a fab ⁇ c to mask, or cover up the odors on the fab ⁇ c.
- Deodo ⁇ zation involves the actual removal or neutralization of malodor causing chemicals. When the malodor causing constituents are removed or neutralized, the fabric article should have little or no residual odor.
- This step of the process can be earned out with ozone, which neutralizes odors, or with high temperatures and venting, and/or by filter capturing, which removes the odor causing constituents.
- ozone which neutralizes odors, or with high temperatures and venting, and/or by filter capturing, which removes the odor causing constituents.
- the deodo ⁇ zation step is desc ⁇ bed herein as the first step as a matter of convenience. It is understood that the deodo ⁇ zation and dew ⁇ nkling steps can be earned out in any order. If a perfume deposition step is employed, it necessa ⁇ ly should follow the deodo ⁇ zation step, so that the perfume is not st ⁇ pped off of the fabnc immediately after it is laid down.
- the first temperature should be at least about 45°C, preferably at least about 60°C, and most preferably at least about 70°C and the first relative humidity should be least about 20%.
- the vent comprises a filter so that the odorous emanations do not enter the environment outside of the container.
- ozone can be introduced into the container from any appropriate source, such as an ultraviolet lamp.
- ozone sources can be used and they can be placed in any convenient place in, or adjacent the exterior of the container.
- the ozone source must be sized according to the volume of the container with consideration for the surface area of the fabric articles being cleaned and refreshed. Those skilled in the art will know what type and size of equipment to use for a given container.
- the second step of the present invention is directed to dew ⁇ nklmg, which requires relatively high temperature and relative humidity. Good air circulation is beneficial to the dew ⁇ nkling step, but not necessary.
- RH2 is preferably of at least 50%, preferably of at least 75%, more preferably of at least about 85%, and even more preferably at least about 90%.
- the second temperature is less than about 90°C, more preferably less than about 80°C, and most preferably less than about 70°C.
- the process time that is, the second time
- a third step which involves a gradual cool down of the mte ⁇ or void space. As the temperature decrease, the amount of vapor that the air can retain m the air decreases, and when the air becomes saturated the vapors begin to condense. Naturally, vapors will condense on the fabric articles on the inside of the bag, and as these articles dry, the active ingredients, such as perfume, remain behind.
- the methods steps of this invention are designed to deliver actives without undue waste and without saturating the fabrics to the point where they need additional drying.
- the temperature withm the mte ⁇ or void space decreases to a third temperature wherein the third temperature is less than about 45°C, preferably less than about 40°C, and more preferably less than about 35°C.
- This third step can last for a third pe ⁇ od of time, which can be from about 2 minutes to about 20 minutes, preferably from about 3 minutes to about 10 minutes, and even more preferably from about 3 minutes to about 5 minutes.
- the vapor inside the container is preferably a cleaning and refreshment composition.
- the cleaning refreshment composition can be added to the container directly, via a sheet/substrate, in a cartridge or any other means that will be known to those skilled in the art.
- the cleaning and refreshment composition is in a cartridge that is introduced into the interior void space of the container and the cleaning and refreshment composition is released from the cartridge into the interior void space of the container.
- the methods of this invention can be conducted in any approp ⁇ ate apparatus
- Such apparatuses require a container that substantially encloses the fabric articles being cleaned and refreshed.
- substantially encloses it is meant that the fabric articles are enclosed in the container, but that the container can, and preferably will, include one or more vents.
- the container must have an opening to access the fab ⁇ c articles, and preferably, there is a bar, hook or other device on which to hang the fabric articles
- the garments hung in treatment apparatus can also be weighted or stretched to improve wrinkle reduction. Hanging weights and stretching devices will be known to those skilled in the art Preferably, the garments to be treated are mechanically stretched after placing them into the container and before starting the process.
- stretching or so-called tensionmg of the garment helps the relaxation of w ⁇ nkles du ⁇ ng the process.
- Preferred stretching systems include weighted clamps as well as light weight compactable or retractible stretching systems, wherein the system comprises a tensionmg device like a sp ⁇ ng.
- the latter systems have the benefit of not adding extra weight to the cleaning and refreshing apparatus, along with the possibility of adjusting tensionmg force and direction as required.
- these systems are mounted inside the container at its bottom.
- One example of such as system is a rollerblmd that is conventionally used as sunfilter for cars and commercially available from Halfords.
- This system is a rollerblmd which can be extended or compacted by means of a roll-up spring mechanism Only slight modification of this system are needed to adapt it to the tensionmg of garment
- One preferred adaptation involves attaching the housing of this system at the bottom of the apparatus and providing one or more clamp at the other side so that the clamping and thus the stretching or tensionmg of the garment in the apparatus is obtained.
- the tension of the sp ⁇ ng can also be adjusted to the desired stretching force for a given garment.
- the size of the clamp can vary so that more than one clamp are attached to this system. Still, another variation involves having only one clamp which run along or partly along the blind tensionmg system located opposite the housing of the system.
- the container preferably has only one wall configured like an egg shell. It has been found that the vapor, and subsequently the active ingredients, preferentially condense in the corners and along the sharp edges of a more conventional rectangular shaped cabinet. This is not to say that the methods of this invention cannot be conducted m rectangular cabinets; they can But the fewer sharp edges and corners the cabinet has, the more efficient it is. Thus, cabinets, wardrobes, and garment bags are all appropriate for use in the present invention Moreover, a common tumble dryer may be an appropriate container, but these apparatuses do not normally have humidity controllers, nor do they have the ability to program a multi-step process with respect to both temperature and humidity. Thus, with some additional programming and controllers, a common tumble dryer could be used for the methods of this invention.
- the containers of this invention preferably compnse: a vent and/or filter; a heating element, which is capable of heating liquids to produce vapors and which can run dry to heat air; a humidity provider; and an air circulation device, for example, a fan. More preferably, the container additionally comp ⁇ ses an active temperature controller capable of changing and maintaining the air temperature within the interior void space of the container; a passive humidity controller capable of changing and maintaining the relative humidity of the air withm the interior void space of the container, and/or a humidity sink like a condenser.
- the air circulation device is a fan and the fan mlet is withm the inte ⁇ or void space of the container so that at least a portion of the air withm the void space of the container is recirculated.
- it preferred to have air velocities around the garment between 0.05 to 10 m/s, more preferably between 0J and 5, most preferably between 0.5 and 2 m.s-1.
- a filter in, or adjacent the exte ⁇ or of the container
- the water and actives can be added to the container in any appropnate way.
- the composition can be poured into the bag, poured into a reservoir that feeds into the heating element/humidifier, canisters can be used to inject the composition, or an absorbent substrate saturated with the composition can be placed in the bag
- Substrates and compositions suitable for use in the methods of this invention are desc ⁇ bed in greater detail below. It is understood that those skilled in the art will know of other methods ot adding actives to the container and those methods are within the scope of this invention.
- the cleaning/refreshment composition preferably compnses water and optionally a member selected from the group consisting of surfactants, perfumes, preservatives, bleaches, auxiliary cleaning agents, shrinkage reducing compositions, organic solvents and mixtures thereof.
- the preferred organic solvents are glycol ethers, specifically, methoxy propoxy propanol, ethoxy propoxy propanol, propoxy propoxy propanol, butoxy propoxy propanol, butoxy propanol, ethanol, isopropanol and mixtures thereof.
- Fabric shrinkage reducing compositions that are suitable for use in the present invention are selected from the group consisting of ethylene glycol, all isomers of propanediol, butanediol, pentanediol, hexanediol and mixtures thereof. More preferably, the fabric shrinkage reducing compositions are selected from the group consisting of neopentyl glycol, polyethylene glycol, 1,2-propaned ⁇ ol, 1,3-butaned ⁇ ol, 1- octanol and mixtures thereof.
- the surfactant is preferably a noniomc surfactant, such as an ethoxylated alcohol or ethoxylated alkyl phenol, and is present at up to about 2%, by weight of the cleaning/refreshment composition.
- Typical fabric cleaning/refreshment compositions herein can comprise at least about 80%, by weight, water, preferably at least about 90%, and more preferably at least about 95% water.
- shrinkage reducing compositions for use in this invention can be found in co-pendmg U.S. Provisional Application No. 60/097,596, entitled “Cleaning Compositions that Reduce Fabnc Shrinkage", which was filed by Strang and Siklosi, on August, 24, 1998. The entire disclosure of the Strang and Siklosi application is incorporated herein by reference.
- the cleaning/refreshment composition can be used to pre-treat the fabrics before their placement into the container defined m step a) of the present invention. Indeed, this pre-treatment of the fab ⁇ cs has been found highly beneficial for the JO-
- this pre-treatment step has also been found beneficial for improving the deodorising as well as the dewrmkling performance of the apparatus on the treated fabrics.
- a method for treating the fabrics whereby the fabrics are contacted with a cleaning/refreshing composition as defined herein prior to being placed in the container defined m step a)
- the contacting occurs by spraying the fabrics with a handspray bottle commercially available under the reference 7292458 for the 1000ml and 7292457 for the 500ml from VEL or aerosol spray like the aluminium aerosol cans with polyethylene coating and a 18 bar pressure resistance as commercially available from Boxal part of the Al group Wheaton.
- Suitable valves for the cans are aluminium cup spray valves from Seaquist.
- the filling of the can by propellant is done with nitrogen at 10 bar for the initial pressure filling while the cans are filled with the pre- treatment composition up to 60% of the can total volume.
- Typical disclosure of such spray dispenser can be found in WO 96/04940 page 19 line 21 to page 22 line 27.
- cyclodext ⁇ n can be used, in particular ⁇ -cyclodextnn like the ⁇ -hydroxypropyl cyclodextrm or the ⁇ -methylated cyclodextrm, while for improved dewrmkling, lubncant like the D5 cyclomethicone from Dow Corning or diester quaternary ammonium compound like d ⁇ (tallowyloxyethyl)d ⁇ methyl ammonium in the cleaning/refreshment composition.
- Typical levels of such cyclodextrm are of from 0.01, preferably of from 0.1% to 5% by weight.
- the cleaning/refreshment composition can be releasably absorbed in an absorbent substrate, herein after referred to as a "substrate".
- the substrate releasably contains the composition
- “releasably contains” means that the composition is effectively released from the substrate onto the soiled fab ⁇ cs as part of the cleaning and fab ⁇ c refreshment processes herein. This release occurs mainly by volatilization of the composition due to the heat from the supplemental heat source.
- the substrate can be in any desired form, such as powders, flakes, shreds, and the like However, it is highly preferred that the substrate be in the form of an integral pad or "sheet” that substantially maintains its structural mtegnty throughout the process.
- the substrates and sheets of this invention are sometimes referred to in the literature as “earners” or “absorbent carrier sheets”; it is understood that all of these labels refer to liquid absorbing materials that can be used to conveniently transport liquids.
- Such substrates are described in detail in U.S. Patent No 5,789,368, to You et al. which was incorporated herein by reference above. The manufacture of these sheets forms no part of this invention and is already disclosed m the literature. See, for example, U.S.
- the substrate is intended to contain a sufficient amount of the cleaning/refreshment composition to be effective for the intended purpose.
- the capacity of the substrate for such a composition will vary according to the intended usage.
- the size of the substrate should not be so large as to be unhandy for the user.
- the dimensions of the substrate will be sufficient to provide a macroscopic surface area (both sides of the substrate) of at least about 360 cm ⁇ , preferably in the range from about 360 cn to about 3000 cm-2.
- a generally rectangular substrate may have the dimensions (X-direction) of from about 10 cm to about 35 cm, and (Y-direction) of from about 18 cm to about 45 cm.
- the substrate is either a dark material, or is covered with a dark material, such as a black fabric. It is well known that dark matenals absorb heat better than whiter matenals. Thus, a dark substrate would tend to absorb more heat and volatilize more cleaning and refreshing composition if, for example, solar radiation is used as the supplemental heat source.
- the substrate can optionally be covered with a fibrous, preferably heat resistant and, most preferably, hydrophobic, coversheet as described in detail in U S. Patent No 5,789,368, to You et al. which was incorporated herein by reference above.
- a fibrous, preferably heat resistant and, most preferably, hydrophobic, coversheet as described in detail in U S. Patent No 5,789,368, to You et al. which was incorporated herein by reference above.
- co- pending U.S. provisional application 60/077,556, which was filed on March 11, 1998, in the name of Wise et al. desc ⁇ bes certain improvements to the coversheets of this invention.
- the entire disclosure of the Wise et al. application is incorporated herein by reference Suitable combinations of the coversheets descnbed in You et al. with the improvements desc ⁇ bed in Wise et al. can be employed, according to the desires of the manufacturer, without departing from the spirit and scope of the
- the user of the present process can be provided with various spot cleaning compositions to use m the optional pre-spottmg procedure of this invention.
- These compositions are used to remove localized stains from the fab ⁇ cs being treated, either before or after the cleaning and refreshing process defined herein.
- the spot cleaning composition must be compatible with the fab ⁇ c being treated. That is, no meaningful amount of dye should be removed from the fab ⁇ c during the spot treatment and the spot cleaning composition should leave no visible stains on the fabric. Therefore, in a preferred aspect of this invention there are provided spot cleaning compositions which are substantially free of materials that leave visible residues on the treated fabrics.
- compositions are formulated to contain the highest level of volatile materials possible, preferably water, typically about 95%, preferably about 97.7%, and surfactant at levels of about 0 1% to about 0.7%.
- a preferred spot cleaning composition will also contain a cleaning solvent such as butoxy propoxy propanol (BPP) at a low, but effective, level, typically about 1% to about 4%, preferably about 2%.
- BPP butoxy propoxy propanol
- a treatment member is provided to assist in removing localized stains from fab ⁇ cs.
- the spot cleaning composition is provided in a dispenser, such as a bottle, and the dispenser has a distal tip that can serve as the treatment member.
- the treatment member can compnse an absorbent base matenal which can be, for example, a natural or synthetic sponge, an absorbent cellulosic sheet or pad, or the like. In contact with and extending outward from this base material can be multiple protrusions. Specific examples of treatment members can be found in U S Patent No. 5,789,368, to You et al. which was incorporated herein by reference above.
- An absorbent stam receiving article can optionally be used m the optional pre-spottmg operations herein.
- stam receivers can be any absorbent material which imbibes the liquid composition used m the pre-spottmg operation Disposable paper towels, cloth towels such as BOUNTYTM brand towels, clean rags, etc., can be used.
- the stain receiv er is designed specifically to "wick” or "draw” the liquid compositions away from the stained area
- One preferred type of stain receiver consists of a nonwoven pad, such as a thermally bonded air laid fab ⁇ c ("TBAL").
- polymenc foam Another highly preferred type of stam receiver for use herein comprises polymenc foam, wherein the polyme ⁇ c foam compnses a polyme ⁇ zed water-in-oil emulsion, sometimes referred to as "poly- HEPE".
- poly- HEPE polyme ⁇ zed water-in-oil emulsion
- the various stam receivers described herein, and described in the references incorporated herein by reference, preferably comprise a liquid impermeable backsheet.
- the backsheet can be made of, for example, a thin layer of polypropylene, polyethylene and the like.
- the backsheet provides protection for the surface that the stain receiver rests on from the spot cleaning composition.
- spot cleaning processes are typically performed on a hard surface, such as a table top.
- the stain receiver is placed on the table and the fabnc to be treated in placed on the stam receiver.
- Spot cleaning composition is applied to the stained area of the fab ⁇ c and then drawn into the stam receiver. But in the absence of a back sheet, the spot cleaning composition can leak onto the table top, possibly causing damage thereto.
- EXAMPLE I Two extra-large men's jackets that have been exposed to cigarette smoke and wrinkled using standardized methods, are placed on clothes hangers. These jackets are then hung on the mside of a plastic bag that has two co-planer flat ends (the top and bottom) with the side walls being cylindrical and slightly outwardly bowed near the center.
- the bag can be thought of as shaped like an egg shell with the top and bottom cut off.
- the container has a door for accessing the mtenor, and the door is closed with a zipper.
- a small slit near the bottom of the bag serves as the vent and the vent remains open at all times du ⁇ ng this process
- a fan On the interior of the bag is a fan, a heating element, a thermocouple and a reservoir that is m fluid communication with the heating element Approximately 100 to 125 is ot a composition comprising approximately 99% water and 1% perfume, by weight, is poured into the reservoir and the door is closed.
- An exterior "on/off switch is turned on to begin the fabric refreshment process.
- the switch is connected to a programmable microprocessor that controls the multi-step process.
- the heating element is turned off and the mtenor of the bag cools naturally to about 45°C in less than about 10 minutes.
- the fan is turned off automatically, and an indicator light signals that the process is complete.
- the jackets are removed and they are substantially wnnkle free, deodorized and ready to wear.
- EXAMPLE ⁇ Two extra-large men's jackets that have been exposed to cigarette smoke and wnnkled using standardized methods, are placed on clothes hangers. The areas with the most w ⁇ nkles were then pre-treated with a hand-held spray commercially available under the reference 7292457 from Vel and containing demmerahsed water so that the wnnkled areas were slightly damp but not soaked. These jackets are then hung on the inside of a plastic bag that has two co-planer flat ends (the top and bottom) with the side walls being cylmdncal and slightly outwardly bowed near the center. For illustration purposes only, the bag can be thought of as shaped like an egg shell with the top and bottom cut off. The container has a door for accessing the mtenor, and the door is closed with a zipper. A vent is provided near the bottom of the bag, but the vent remains closed when the ozone is present m the bag.
- a fan On the mtenor of the bag is a fan, an ultra violet lamp, a heating element, a thermocouple and a receptacle for receiving a cartridge that contains a cleaning and refreshment composition.
- the receptacle is m fluid communication with the heating element.
- the cleaning and refreshment composition comp ⁇ ses approximately 100 to 125 mis of a composition comp ⁇ smg approximately 99% water and 1% perfume, by weight.
- the door is closed.
- An exterior "on off switch is turned on to begin the fabric refreshment process.
- the switch is connected to a programmable microprocessor that controls the multi-step process. First, the ultraviolet lamp is turned on to produce ozone. The lamp remains lit for approximately 10 minutes.
- the fan is optionally run during this first step.
- the temperature is raised to about 50°C and the relative humidity is raised to greater than about 95%. This is accomplished through the introduction of the vaporized cleaning and refreshment composition.
- the fan continues to run during this second step, which lasts for about 7 to 12 minutes.
- the heating element is turned off and the interior of the bag cools naturally to about 45°C in less than about 10 minutes.
- the fan is turned off automatically, and an indicator light signals that the process is complete.
- the jackets are removed and they are substantially wrinkle free, deodorized and ready to wear.
- Emulsifier TWEEN 20* 0.5 0 Perfume 0.5 0.5 KATHON® 0.0003 0 Sodium Benzoate 0.1 0 Water Balance Balance
- compositions for use in the methods of this invention are as follows. Ingredient % (wt.) Range (% wt.)
- Hydrogen peroxide Optional to 4% pH range from about 6 to about 8.
- a spot cleaning composition for use in the present invention preferably with a dispenser as defined above, and with a TBAL or poly-HIPE foam stain receiver, is prepared as follows: INGREDIENT Anionic Composition (%)
- H2O2- containing pre-spotting compositions comprise the anionic or nonionic surfactant in an amount (by weight of composition) which is less than the amount of H2O2.
- the weight ratio of surfactant:H2 ⁇ 2 is in the range of about 1 : 10 to about 1: 1.5, most preferably about 1 :4 to about
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Treatment Of Fiber Materials (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00917682A EP1157153A1 (de) | 1999-03-02 | 2000-03-01 | Verfahren zum reinigen und zur auffrischung von textilien |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12241899P | 1999-03-02 | 1999-03-02 | |
US122418P | 1999-03-02 | ||
EP00870018 | 2000-02-07 | ||
EP00870018A EP1122352B1 (de) | 1999-03-02 | 2000-02-07 | Verfahren zum Reinigen und zur Auffrischung von Textilien |
PCT/US2000/005200 WO2000052249A1 (en) | 1999-03-02 | 2000-03-01 | Method for cleaning and refreshing fabrics |
EP00917682A EP1157153A1 (de) | 1999-03-02 | 2000-03-01 | Verfahren zum reinigen und zur auffrischung von textilien |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1157153A1 true EP1157153A1 (de) | 2001-11-28 |
Family
ID=26074220
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00870018A Expired - Lifetime EP1122352B1 (de) | 1999-03-02 | 2000-02-07 | Verfahren zum Reinigen und zur Auffrischung von Textilien |
EP00917682A Withdrawn EP1157153A1 (de) | 1999-03-02 | 2000-03-01 | Verfahren zum reinigen und zur auffrischung von textilien |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00870018A Expired - Lifetime EP1122352B1 (de) | 1999-03-02 | 2000-02-07 | Verfahren zum Reinigen und zur Auffrischung von Textilien |
Country Status (11)
Country | Link |
---|---|
EP (2) | EP1122352B1 (de) |
JP (1) | JP2002537920A (de) |
KR (1) | KR100431424B1 (de) |
CN (1) | CN1284898C (de) |
AU (1) | AU763258B2 (de) |
BR (1) | BR0008718A (de) |
CA (1) | CA2364519C (de) |
CZ (1) | CZ20013156A3 (de) |
DE (1) | DE60017542T2 (de) |
ES (1) | ES2234558T3 (de) |
WO (1) | WO2000052249A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115970B (zh) * | 2010-01-05 | 2015-04-08 | 海尔集团公司 | 一种用于洗衣机冲刷内桶外壁的高压喷淋装置及冲刷内桶外壁的方法 |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1182292A1 (de) * | 2000-08-16 | 2002-02-27 | The Procter & Gamble Company | Vorrichtung zum Reinigen und zum Auffrischen von Textilien mit Ultraschallvernebler und Ultraschallvernebler |
US7066412B2 (en) | 2002-05-28 | 2006-06-27 | Johnsondiversey, Inc. | Apparatus, methods, and compositions for adding fragrance to laundry |
KR101022217B1 (ko) * | 2004-05-27 | 2011-03-17 | 삼성전자주식회사 | 탈취수단을 구비한 세탁기 및 그 제어방법 |
US7749401B2 (en) | 2004-05-27 | 2010-07-06 | The Procter & Gamble Company | Self-steaming benefit composition |
KR101054126B1 (ko) | 2004-09-10 | 2011-08-03 | 엘지전자 주식회사 | 리프레쉬 기능이 구비된 세탁기 |
KR100732414B1 (ko) * | 2005-01-24 | 2007-06-27 | 삼성전자주식회사 | 의류의 구김제거방법 |
JP4520368B2 (ja) * | 2005-06-10 | 2010-08-04 | 花王株式会社 | 衣類のシワ除去及び/又は消臭方法 |
KR101137335B1 (ko) * | 2005-08-25 | 2012-04-19 | 엘지전자 주식회사 | 세탁 장치의 운전 방법 |
PL2273004T3 (pl) * | 2009-07-09 | 2013-04-30 | Elozo Oy | System czyszczący |
ES2363852B1 (es) * | 2009-10-27 | 2012-03-21 | Miguel �?Ngel Toledo Garc�?A | Perfumador de prendas de ropa |
CN111235819B (zh) * | 2018-11-09 | 2022-05-06 | 青岛海尔洗涤电器有限公司 | 用于衣物处理设备的控制方法 |
JP7333539B2 (ja) * | 2018-12-26 | 2023-08-25 | 青島海爾洗衣机有限公司 | 衣類処理装置 |
CN109972341B (zh) * | 2019-04-24 | 2020-08-04 | 珠海格力电器股份有限公司 | 洗衣机及其洗涤方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US3267701A (en) * | 1964-02-12 | 1966-08-23 | Whirlpool Co | Fabric conditioner for clothes dryer |
DE2318596B2 (de) * | 1973-04-13 | 1980-04-03 | Joh. A. Benckiser Gmbh, 6700 Ludwigshafen | Verfahren zur Behandlung von Wäsche in Wäschetrocknern |
DE2433909A1 (de) * | 1974-07-15 | 1976-02-05 | Sueddeutsche Metallwerke Gmbh | Geraet zur pflege von kleidungsstuecken |
DE2823351A1 (de) * | 1978-05-29 | 1979-12-13 | Henkel Kgaa | Verfahren zum konditionieren und trocknen von waesche und vorrichtung zur durchfuehrung des verfahrens |
JPS6375167A (ja) * | 1986-09-12 | 1988-04-05 | 落合 宏通 | 衣服の仕上加工方法 |
US5305484A (en) * | 1988-01-13 | 1994-04-26 | J.S.F. Holdings (Cork) Limited | Clothes steaming and drying cabinet |
FR2704008A1 (fr) * | 1993-04-14 | 1994-10-21 | Maitre Patrick | Armoire automatique de défroissage. |
US5789368A (en) * | 1996-01-26 | 1998-08-04 | The Procter & Gamble Company | Fabric care bag |
US5649372A (en) * | 1996-03-14 | 1997-07-22 | American Dryer Corporation | Drying cycle controller for controlling drying as a function of humidity and temperature |
US5815961A (en) * | 1996-06-26 | 1998-10-06 | Whirlpool Corporation | Clothes treating cabinet with inflatable hanger |
-
2000
- 2000-02-07 EP EP00870018A patent/EP1122352B1/de not_active Expired - Lifetime
- 2000-02-07 ES ES00870018T patent/ES2234558T3/es not_active Expired - Lifetime
- 2000-02-07 DE DE60017542T patent/DE60017542T2/de not_active Expired - Lifetime
- 2000-03-01 BR BR0008718-1A patent/BR0008718A/pt not_active IP Right Cessation
- 2000-03-01 JP JP2000602855A patent/JP2002537920A/ja active Pending
- 2000-03-01 CN CNB008042489A patent/CN1284898C/zh not_active Expired - Fee Related
- 2000-03-01 KR KR10-2001-7011118A patent/KR100431424B1/ko not_active IP Right Cessation
- 2000-03-01 CZ CZ20013156A patent/CZ20013156A3/cs unknown
- 2000-03-01 AU AU38616/00A patent/AU763258B2/en not_active Ceased
- 2000-03-01 WO PCT/US2000/005200 patent/WO2000052249A1/en not_active Application Discontinuation
- 2000-03-01 EP EP00917682A patent/EP1157153A1/de not_active Withdrawn
- 2000-03-01 CA CA002364519A patent/CA2364519C/en not_active Expired - Fee Related
Non-Patent Citations (1)
Title |
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See references of WO0052249A1 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102115970B (zh) * | 2010-01-05 | 2015-04-08 | 海尔集团公司 | 一种用于洗衣机冲刷内桶外壁的高压喷淋装置及冲刷内桶外壁的方法 |
Also Published As
Publication number | Publication date |
---|---|
AU3861600A (en) | 2000-09-21 |
CN1341175A (zh) | 2002-03-20 |
CN1284898C (zh) | 2006-11-15 |
CA2364519A1 (en) | 2000-09-08 |
KR20010109303A (ko) | 2001-12-08 |
CZ20013156A3 (cs) | 2002-02-13 |
WO2000052249A1 (en) | 2000-09-08 |
KR100431424B1 (ko) | 2004-05-14 |
DE60017542T2 (de) | 2006-03-30 |
BR0008718A (pt) | 2001-12-26 |
DE60017542D1 (de) | 2005-02-24 |
ES2234558T3 (es) | 2005-07-01 |
JP2002537920A (ja) | 2002-11-12 |
CA2364519C (en) | 2006-10-03 |
AU763258B2 (en) | 2003-07-17 |
EP1122352B1 (de) | 2005-01-19 |
EP1122352A1 (de) | 2001-08-08 |
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