EP1099478A3 - Einlagerungsverbindung sowie ein Vanadium/Phosphormischoxid und Verfahren zu deren Herstellung - Google Patents

Einlagerungsverbindung sowie ein Vanadium/Phosphormischoxid und Verfahren zu deren Herstellung Download PDF

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Publication number
EP1099478A3
EP1099478A3 EP00202249A EP00202249A EP1099478A3 EP 1099478 A3 EP1099478 A3 EP 1099478A3 EP 00202249 A EP00202249 A EP 00202249A EP 00202249 A EP00202249 A EP 00202249A EP 1099478 A3 EP1099478 A3 EP 1099478A3
Authority
EP
European Patent Office
Prior art keywords
monohydric alcohol
intercalation compound
mixed oxide
preparation
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00202249A
Other languages
English (en)
French (fr)
Other versions
EP1099478B1 (de
EP1099478A2 (de
Inventor
Yuichi Kamiya
Eiichiro Nishikawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tonen Chemical Corp
Original Assignee
Japan Chemical Industry Association
Tonen Sekiyu Kagaku KK
Tonen Chemical Corp
Japan Chemical Industry Association JCIA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP11319860A external-priority patent/JP2000247617A/ja
Priority claimed from JP2000067377A external-priority patent/JP2001253715A/ja
Priority claimed from JP2000178741A external-priority patent/JP2002003210A/ja
Application filed by Japan Chemical Industry Association, Tonen Sekiyu Kagaku KK, Tonen Chemical Corp, Japan Chemical Industry Association JCIA filed Critical Japan Chemical Industry Association
Priority to EP04077957A priority Critical patent/EP1502647A3/de
Publication of EP1099478A2 publication Critical patent/EP1099478A2/de
Publication of EP1099478A3 publication Critical patent/EP1099478A3/de
Application granted granted Critical
Publication of EP1099478B1 publication Critical patent/EP1099478B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00Phosphorus; Compounds thereof
    • C01B25/16Oxyacids of phosphorus; Salts thereof
    • C01B25/26Phosphates
    • C01B25/37Phosphates of heavy metals
    • C01B25/372Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/186Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/082Decomposition and pyrolysis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/10Infrared [IR]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15X-ray diffraction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/617500-1000 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
EP00202249A 1999-11-10 2000-06-27 Einlagerungsverbindung Expired - Lifetime EP1099478B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP04077957A EP1502647A3 (de) 1999-11-10 2000-06-27 Verfahren zur Herstellung einer Einlagerungsverbindung

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP31986099 1999-11-10
JP11319860A JP2000247617A (ja) 1998-12-28 1999-11-10 層間化合物およびその製造方法
JP2000067377A JP2001253715A (ja) 2000-03-10 2000-03-10 バナジウム‐リン複合酸化物およびその製造方法
JP2000067377 2000-03-10
JP2000178741 2000-06-14
JP2000178741A JP2002003210A (ja) 2000-06-14 2000-06-14 層間化合物の製造方法

Related Child Applications (1)

Application Number Title Priority Date Filing Date
EP04077957A Division EP1502647A3 (de) 1999-11-10 2000-06-27 Verfahren zur Herstellung einer Einlagerungsverbindung

Publications (3)

Publication Number Publication Date
EP1099478A2 EP1099478A2 (de) 2001-05-16
EP1099478A3 true EP1099478A3 (de) 2001-08-01
EP1099478B1 EP1099478B1 (de) 2005-12-14

Family

ID=27339754

Family Applications (2)

Application Number Title Priority Date Filing Date
EP00202249A Expired - Lifetime EP1099478B1 (de) 1999-11-10 2000-06-27 Einlagerungsverbindung
EP04077957A Withdrawn EP1502647A3 (de) 1999-11-10 2000-06-27 Verfahren zur Herstellung einer Einlagerungsverbindung

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP04077957A Withdrawn EP1502647A3 (de) 1999-11-10 2000-06-27 Verfahren zur Herstellung einer Einlagerungsverbindung

Country Status (3)

Country Link
US (2) US6495486B1 (de)
EP (2) EP1099478B1 (de)
DE (1) DE60024760T2 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1110603A1 (de) * 1999-12-22 2001-06-27 Haldor Topsoe A/S Verfahren für die Synthese von VPO Katalysatoren
JP5140674B2 (ja) * 2006-09-05 2013-02-06 ハンツマン ペトロケミカル エルエルシー 改善されたマレイン酸無水物触媒およびその製造方法
CN101952038B (zh) 2007-10-22 2013-04-24 亨斯迈石油化学有限责任公司 用于马来酸酐生产的改进的氧化催化剂
KR101624871B1 (ko) 2008-10-21 2016-05-27 헌츠만 페트로케미칼 엘엘씨 말레산 무수물 제조를 위한 고 기공 용적의 vpo 촉매
US11289700B2 (en) 2016-06-28 2022-03-29 The Research Foundation For The State University Of New York KVOPO4 cathode for sodium ion batteries
CN110935479B (zh) * 2018-09-25 2022-07-12 中国石油化工股份有限公司 正丁烷氧化制顺酐的催化剂及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0520972A1 (de) * 1991-06-27 1992-12-30 Monsanto Company Verfahren zur Umwandlung einer Vanadium/Phosphor-Mischoxydkatalysatorvorstufe in einen aktiven Katalysator zur Herstellung vom Maleinsäureanhydrid
WO1998015353A1 (en) * 1996-10-08 1998-04-16 E.I. Du Pont De Nemours And Company Vanadyl pyrophosphate oxidation catalyst precursors
DE19840224A1 (de) * 1998-09-03 2000-03-09 Consortium Elektrochem Ind Verfahren zur Herstellung von Katalysatoren für die Synthese von Maleinsäureanhydrid durch Gasphasenoxidation

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4187235A (en) * 1972-09-18 1980-02-05 Chevron Research Company Method for preparing maleic anhydride
US4472527A (en) * 1982-03-31 1984-09-18 Mitsubishi Chemical Industries Ltd. Process for preparing an oxidation catalyst composition
US4518534A (en) * 1983-08-22 1985-05-21 Exxon Research & Engineering Co. Layered vanadium compounds containing phosphorus or arsenic and pendant organic groups
US4632915A (en) * 1985-10-28 1986-12-30 Monsanto Company Iron/lithium--promoted catalysts for the production of maleic anhydride
US5072031A (en) * 1987-03-09 1991-12-10 Mobil Oil Corp. Layered divalent metal phosphates containing pendent substituent groups and their preparation
US5275996A (en) * 1992-05-22 1994-01-04 Monsanto Company Phosphorous/vanadium oxide catalyst and process of preparation thereof
DE69411404T2 (de) * 1993-01-29 1999-03-04 Mitsubishi Chemical Corp., Tokio/Tokyo Verfahren zur Herstellung eines Vanadium - Phosphoroxid enthaltenden Katalysatorvorläufers
US5641722A (en) * 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
US5532385A (en) * 1994-11-14 1996-07-02 Trustees Of Princeton University Catalytic process for the production of maleic anhydride
JPH08259208A (ja) 1995-03-23 1996-10-08 Tosoh Corp 層間化合物及びその製造方法
IT1290407B1 (it) * 1996-04-29 1998-12-03 Lonza Spa Procedimento per la trasformazione di un precursore di catalizzatore a base di ossido misto di vanadio/fosforo nel catalizzatore attivo
US5885919A (en) * 1997-07-30 1999-03-23 Scientific Design Company, Inc. Phosphorus/vanadium catalyst preparation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0520972A1 (de) * 1991-06-27 1992-12-30 Monsanto Company Verfahren zur Umwandlung einer Vanadium/Phosphor-Mischoxydkatalysatorvorstufe in einen aktiven Katalysator zur Herstellung vom Maleinsäureanhydrid
WO1998015353A1 (en) * 1996-10-08 1998-04-16 E.I. Du Pont De Nemours And Company Vanadyl pyrophosphate oxidation catalyst precursors
DE19840224A1 (de) * 1998-09-03 2000-03-09 Consortium Elektrochem Ind Verfahren zur Herstellung von Katalysatoren für die Synthese von Maleinsäureanhydrid durch Gasphasenoxidation

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
HUTCHINGS G J ET AL: "IMPROVED METHOD OF PREPARATION OF VANADIUM PHOSPHATE CATALYSTS", CATALYSIS TODAY,NL,AMSTERDAM, vol. 33, no. 1/03, 17 January 1997 (1997-01-17), pages 161 - 171, XP002055708 *
JOHNSON J W ET AL.: "Molecular Recognition of Alcohols by Layered Compounds with Alternating Organic and Inorganic Layers", J. AM. CHEM. SOC., vol. 111, 1989, pages 381 - 383, XP002160695 *

Also Published As

Publication number Publication date
US6762146B2 (en) 2004-07-13
DE60024760T2 (de) 2006-08-17
EP1099478B1 (de) 2005-12-14
US6495486B1 (en) 2002-12-17
EP1502647A2 (de) 2005-02-02
EP1099478A2 (de) 2001-05-16
US20020141927A1 (en) 2002-10-03
EP1502647A3 (de) 2005-03-23
DE60024760D1 (de) 2006-01-19

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