Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
  • B41C1/00—Forme preparation
  • B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
  • B41C1/1008—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
  • B41C1/1025—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials using materials comprising a polymeric matrix containing a polymeric particulate material, e.g. hydrophobic heat coalescing particles
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
  • B41C1/00—Forme preparation
  • B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
  • B41C1/1066—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by spraying with powders, by using a nozzle, e.g. an ink jet system, by fusing a previously coated powder, e.g. with a laser
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
  • B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
  • B41C2210/08—Developable by water or the fountain solution
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
  • B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
  • B41C2210/22—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by organic non-macromolecular additives, e.g. dyes, UV-absorbers, plasticisers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
  • B41C2210/00—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
  • B41C2210/24—Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions involving carbon-to-carbon unsaturated bonds, e.g. acrylics, vinyl polymers

Definitions

• the present invention relates to a method for preparing a heat sensitive element by spray-coating.
• Lithography is the process of printing from specially prepared surfaces, some areas of which are capable of accepting lithographic ink, whereas other areas, when moistened with water, will not accept the ink.
• the areas which accept ink form the printing image areas and the ink-rejecting areas form the background areas.
• a photographic material is made imagewise receptive to oily or greasy ink in the photo-exposed (negative working) or in the non-exposed areas (positive working) on a hydrophilic background.
• lithographic plates also called surface litho plates or planographic printing plates
• a support that has affinity to water or obtains such affinity by chemical treatment is coated with a thin layer of a photosensitive composition.
• Coatings for that purpose include light-sensitive polymer layers containing diazo compounds, dichromate-sensitized hydrophilic colloids and a large variety of synthetic photopolymers. Particularly diazo-sensitized systems are widely used.
• the exposed image areas become insoluble and the unexposed areas remain soluble.
• the plate is then developed with a suitable liquid to remove the diazonium salt or diazo resin in the unexposed areas.
• thermoplastic polymer particles By image-wise exposure to an infrared laser, the thermoplastic polymer particles are image-wise coagulated thereby rendering the surface of the imaging element at these areas ink acceptant without any further development.
• a disadvantage of this method is that the printing plate obtained is easily damaged since the non-printing areas may become ink accepting when some pressure is applied thereto. Moreover, under critical conditions, the lithographic performance of such a printing plate may be poor and accordingly such printing plate has little lithographic printing latitude.
• EP-A- 514 145 discloses a heat sensitive imaging element including a coating comprising core-shell particles having a water insoluble heat softenable core component and a shell component which is soluble or swellable in aqueous alkaline medium.
• Red or infrared laser light directed image-wise at said imaging element causes selected particles to coalesce, at least partially, to form an image and the non-coalesced particles are then selectively removed by means of an aqueous alkaline developer. Afterwards a baking step is performed.
• the printing endurance of a so obtained printing plate is low.
• EP-A- 599 510 discloses a heat sensitive imaging element which comprises a substrate coated with (i) a layer which comprises (1) a disperse phase comprising a water-insoluble heat softenable component A and (2) a binder or continuous phase consisting of a component B which is soluble or swellable in aqueous, preferably aqueous alkaline medium, at least one of components A and B including a reactive group or precursor therefor, such that insolubilisation of the layer occurs at elevated temperature and/or on exposure to actinic radiation, and (ii) a substance capable of strongly absorbing radiation and transferring the energy thus obtained as heat to the disperse phase so that at least partial coalescence of the coating occurs.
• said plate After image-wise irradiation of the imaging element and developing the image-wise irradiated plate, said plate is heated and/or subjected to actinic irradiation to effect insolubilisation.
• the printing endurance of a so obtained printing plate is low.
• EP-A- 625 728 discloses an imaging element comprising a layer which is sensitive to UV- and IR-irradiation and which can be positive or negative working. This layer comprises a resole resin, a novolac resin, a latent Bronsted acid and an IR-absorbing substance. The printing results of a lithographic plate obtained by irradiating and developing said imaging element are poor.
• US-P- 5 340 699 is almost identical with EP-A- 625 728 but discloses the method for obtaining a negative working IR-laser recording imaging element.
• the IR-sensitive layer comprises a resole resin,a novolac resin, a latent Bronsted acid and an IR-absorbing substance.
• the printing results of a lithographic plate obtained by irradiating and developing said imaging element are poor.
• US-P- 4 708 925 discloses a positive working imaging element including a photosensitive composition comprising an alkali-soluble novolac resin and an onium-salt. This composition can optionally contain an IR-sensitizer. After image-wise exposing said imaging element to UV - visible - or eventually IR-radiation followed by a development step with an aqueous alkali liquid there is obtained a positive working printing plate. The printing results of a lithographic plate obtained by irradiating and developing said imaging element are poor.
• EP-A-0 800 928 discloses a heat sensitive imaging element comprising on a hydrophilic surface of a lithographic base an image forming layer comprising hydrophobic thermoplastic polymer particles dispersed in a water insoluble alkali soluble or swellable resin and a compound capable of converting light into heat, said compound being present in said image forming layer or a layer adjacent thereto, wherein said alkali swellable or soluble resin comprises phenolic hydroxy groups and/or carboxyl groups.
• said alkali swellable or soluble resin comprises phenolic hydroxy groups and/or carboxyl groups.
• Analogous imaging elements comprising on a hydrophilic surface of a lithographic base an image forming layer comprising hydrophobic thermoplastic polymer particles dispersed in a water or alkali soluble or swellable resin and a compound capable of converting light into heat, said compound being present in said image forming layer or a layer adjacent thereto are disclosed in e.g.
• poly(meth)acrylate latices are used as thermoplastic polymer particles and no specific hydrophilic resin is mentioned
• carbon black or an IR-dye are mentioned as the compound capable of converting light into heat.
• IR-dyes should be used. Carbon black causes indeed a soiling on the press when removing the unexposed areas. On the other hand when using IR-dyes the unexposed areas are not completely dissolved when developing on the press resulting in scumming.
• the appliance of the coatings which are used at the preparation of lithographic precursor plates happens mostly with coating techniques such as dipcoating, cascade coating and curtain coating.
• the use of spray techniques for applying lithographic layers fails usually at the attainable level of cosmetic quality of the end product.
• the conditions for high qualitative lithographic materials thermal printing plates well or not processable on press) whereat high resolution, sensitivity and reproducing characteristics are required, are very high with relation with the cosmetic quality of said printing plate.
• This cosmetic quality can be translated as the presence of lines, the general evenness and the presence of a mottle pattern. This mottle pattern appears at the slighest presence clearly in the printing process of large raster surfaces.
• a line is sprayed without transverse movement of the spray head.
• a well swelling receiving layer comprising gelatin, polyvinylpyrrolidone and polyethylene glycol ( Agfajet Photograde Paper HP Glossy 165TM, commercially available from Agfa-Gevaert) was used. This results in an immediate freezing of the spray pattern without the possibility of transverse flowing of the spray solution over the receiving surface.
• the density profile of the line is measured.
• the width at half height of this profile is divided by the total height (the maximum density) of the profile. This value is referred as profile value (P).
• the spray profile is determined by the air pressure of the spraying head, by the flow rate of the spraying head and by the nature of the receiving surface.
• This value lies preferably between 50 and 220 mm although this value has to be considered in the context of the given equation.
• the surface tension of the spray solution lies preferably between 22 mN/m and 60 mN/m.
• the pressure factor is preferably lower than 125 mN/m
• the distance between the spray head and the receiving member lies preferably between 25 and 100 mm.
• the spray solution is preferably an aqueous solution, which may comprise surfactants, preferably fluorosurfactants.
• the viscosity of the spraying solution is preferably at least 1.5 mPa.s.
• the dynamic contact angle of the receiving surface with water is preferably lower than 60° after 2 s contact time.
• the receiving surface can be a drum with a lithographic surface, which can be incorporated in a printing machine.
• the receiving surface can be a lithographic surface mounted on a drum.
• a preferred spraying solution is a dispersion of hydrophobic thermoplastic polymer particles in a hydrophilic binder.
• Said solution preferably includes thermoplastic particles of a homopolymer or a copolymer of styrene and a hydrophilic polymer containing carboxyl groups, and further a compound capable of converting light into heat.
• the receiving element is a lithographic surface on a support layer with a hydrophilic support which is not a grained and anodized aluminum support.
• this lithographic surface on a support layer comprises a flexible support coated with a hydrophilic, more preferably with a hardened hydrophilic layer.
• the imaging element obtained by spraying the spray solution on the receiving element can after exposure to an IR-laser be developed by rinsing the element with an aqueous solution.
• the exposed imaging element is mounted directly on the press.
• a 2.61 wt solution in water was prepared by mixing polystyrene latex, dye I and a hydrophilic binder. After spraying and drying, the resulting layer contained 75% W/W of the polystyrene latex, 10% of the dye A and 15%W/W of Glascol E 15TM. Glascol E 15 is a polyacrylic acid, commercially available at N.V. Allied Colloids Belgium. Additionally, 5 ml /1 of a fluorosurfactant was added.
• the structure of Dye I is as follows.
• Spray solution B is identical to spray solution A, except that no fluorosurfactant was added.
• an aqueous dispersion comprising 25 % by weight of TiO 2 with average particle size between 0.3 and 0.5 ⁇ m and 2.5 % by weight of polyvinylalcohol (marketed by Wacker Chemie GmbH, under the trade name Polyviol WXTM)
• 170 g of an aqueous dispersion of hydrolysed tetramethoxysilane (22% by weight of hydrolysed tetramethoxysilane) was added.
• a 4.1 % by weight of the non ionic surfactant Akypo OP80TM, available from Chemy was added.
• N-polyoxyethyleneethyl-perfluorooctanoic acid amide was added.
• the volume was adjusted to 1000 ml with distilled water.
• the pH was adjusted to 4.0 with NaOH.
• the solution was applied to a heat-set, biaxially oriented polyethylene terephthalate film with a thickness of 175 ⁇ m so that a total thickness of 6.83 g/m 2 of the coating was present.
• the coating was applied at a wet thickness of 50 ⁇ m and the film was dried under impigment drying with air from 50°C and a moisture content of 4 g/m 3 .
• lithographic base was sprayed spray solution A. Therefore, the lithographic base was mounted on a drum, rotating at a line speed of 164 m/min.
• the imaging element was coated by a spray nozzle moving in transverse direction at a speed of 1.5 m/min.
• the spray nozzle was mounted on a distance of 60 mm between nozzle and receiving substrate.
• the flow rate of the spray solution was set to 7 ml/min.
• an air pressure of 4.80x10 5 Pa was used on the spray head.
• the final coat weight is obtained by consecutively spraying during 6 passes of the spray head. This layer was dried on a temperature of 70°C during the spraying process and additionally during 30 s.
• the spray nozzle was of the type SUJ1, an air assisted spray nozzle, commercially available at Spraying Systems Belgium, Brussels
• an aqueous dispersion comprising 25 % by weight of TiO 2 with average particle size between 0.3 and 0.5 ⁇ m and 2.5 % by weight of polyvinylalcohol (marketed by Wacker Chemie GmbH, under the trade name Polyviol WXTM ), 79.1 g of an aqueous dispersion of hydrolysed tetramethoxysilane (22% by weight of hydrolysed tetramethoxysilane) was added.
• a aqueous dispersion of hydrolysed tetramethoxysilane 22% by weight of hydrolysed tetramethoxysilane
• N-polyoxyethyleneethyl-perfluorooctanoic acid amide was added.
• the volume was adjusted to 1000 ml with distilled water.
• the pH was adjusted to 4.0 with NaOH.
• the solution was applied to a heat-set, biaxially oriented polyethylene terephthalate film with a thickness of 175 ⁇ m so that a total thickness of 6.83 g/m 2 of the coating was present.
• the coating was applied at a wet thickness of 50 ⁇ m and the film was dried under impigment drying with air from 50°C and a moisture content of 4 g/m 3 .
• lithographic base was sprayed spray solution B according to the procedure described in example 1 with the changed pressure setting to 6.21x10 5 Pa and a spray nozzle distance of 80 mm to the receiving surface.
• lithographic base was sprayed spray solution A according to the procedure described in example 1 with the changed pressure setting to 4.83x10 5 Pa and a spray nozzle distance of 60 mm to the receiving surface.
• a receiving surface containing 170 mg/m 2 of a latex of copoly(vinylidenechloride/methylmethacrylate/itaconic acid) and 40 mg/m 2 of silica with a surface area of 100 m 2 /g were applied to a heat-set, biaxially oriented polyethylene terephthalate film with a thickness of 175 ⁇ m.
• biaxially oriented polyethylene terephthalate film with a thickness of 175 ⁇ m was applied a receiving surface, coated from a 23.6% wt aqueous solution adjusted to pH 4, with a wet coating thickness of 50 ⁇ m.
• This layer was, after chilling for 30 s at 10°C, dried at a temperature of 50°C with a moisture content of the air of 4 g/m3 for at least 3 minutes.
• the resulting layer contained 9040 mg/m 2 of TiO 2 , 900 mg/m 2 of SiO 2 , 990 mg/m 2 of vinylalcohol, 250 mg/m 2 of Mylbond 211TM, 23.6 mg/m 2 of Akypo OP80 and 0.25 mg/m 2 of a perfluorosurfactant.
• a dispersion comprising the above mentioned TiO 2 , SiO 2 and polyvinylalcohol.
• Mylbond 211 is a chemically treated starch with an average particle size of 21 ⁇ m, commercially available at Amylum.
• For the TiO 2 Bayertitan RKB2, commercially available at Bayer, was used.
• Spray solution A was sprayed following the procedure as described in example 6.
• Spray solution A was sprayed following the procedure as described in example 6.
• Spray solution A was sprayed following the procedure as described in example 6.
• the surface tension of the spray solutions was measured by the common known Wilhelmy plate method. In this method the surface tension is calculated from the measured force to disrupt the contact between a platinum plate and the liquid surface.
• Spray Solution Surface Tension ( ⁇ ) A 34 mN/m B 56 mN/m
• the dynamic contact angle was determined by monitoring the geometry of a drop after falling on the receiving surface. Therefore, a commercially available measuring instrument, FibroDat 1121 TM Dynamic absorption and contact angle tester, was used. A camera system coupled with frame grabber and image analysis system registrates the contact angle as function of time. This measurement was carried out 5 times for each receiving surface with distilled water. The mean of the values at 2 s contact time was calculated and represents the dynamic contact angle value.
• the FibroDat instrument is marketed by Fibro Systems AB in Sweden
• the pressure factor (PF) is calculated by dividing the profile (P) by the distance between spray head and receiver in mm (d), followed by multiplication by the sum of the surface tension ( ⁇ ) of the spray solution and the dynamic contact angle of water to the receiving surface ( ⁇ ).

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• Physics & Mathematics (AREA)
• Optics & Photonics (AREA)
• Engineering & Computer Science (AREA)
• Manufacturing & Machinery (AREA)
• Thermal Sciences (AREA)
• Printing Plates And Materials Therefor (AREA)
• Photosensitive Polymer And Photoresist Processing (AREA)
• Application Of Or Painting With Fluid Materials (AREA)

Priority Applications (4)

Applications Claiming Priority (1)

Publications (2)

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• 1999
  • 1999-09-15 EP EP19990203065 patent/EP1084862B1/en not_active Expired - Lifetime
  • 1999-09-15 DE DE69912775T patent/DE69912775T2/de not_active Expired - Lifetime
• 2000
  • 2000-09-06 JP JP2000269944A patent/JP2001121835A/ja not_active Withdrawn

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