EP1079964B1 - Verfahren zur erzeugung von gradientenindex-brechzahlprofilen in polymeren optischen fasern - Google Patents
Verfahren zur erzeugung von gradientenindex-brechzahlprofilen in polymeren optischen fasern Download PDFInfo
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- EP1079964B1 EP1079964B1 EP99924856A EP99924856A EP1079964B1 EP 1079964 B1 EP1079964 B1 EP 1079964B1 EP 99924856 A EP99924856 A EP 99924856A EP 99924856 A EP99924856 A EP 99924856A EP 1079964 B1 EP1079964 B1 EP 1079964B1
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- fibre
- preform
- fiber
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Images
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/02—Optical fibres with cladding with or without a coating
- G02B6/02033—Core or cladding made from organic material, e.g. polymeric material
- G02B6/02038—Core or cladding made from organic material, e.g. polymeric material with core or cladding having graded refractive index
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00663—Production of light guides
- B29D11/00682—Production of light guides with a refractive index gradient
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00663—Production of light guides
- B29D11/00721—Production of light guides involving preforms for the manufacture of light guides
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/045—Light guides
Definitions
- the invention relates to a method for generating Gradient index refractive index profiles in polymer optical Fibers.
- optical fibers made of quartz glass fibers Optical signal transmission is common practice in today Telecommunications. Apart from the material specifications and the numerical aperture are the transmission properties and the transmission quality is generally significantly different from that radially symmetrical refractive index curve determined in the fiber core. Characteristic transmission characteristics are that Fiber attenuation, the material and mode dispersion, the Transmission rate or the bandwidth-length product (like shown for example in: John M. Senior: Optical Fiber Communications, Second Edition; Prentice Hall international series in optoelectronics, 1992).
- Multi-mode gradient index fibers have an axially symmetrical one parabolic refractive index curve.
- the diameter of the fiber core is usually 50 ⁇ m.
- standard Single-mode step index fibers in the core area a step-shaped Refractive index curve with a field diameter in the core of normally 9 ⁇ m to 10 ⁇ m.
- the usual one used The total diameter of both fiber types is 125 ⁇ m.
- a decisive factor for the good transmission properties of these fibers is the mode dispersion, which is greatly reduced due to the chosen refractive index profile, as a result of which the interlocking or overlapping of the signals, which can be ascertained over long transmission distances, is considerably reduced.
- only one mode can be propagated in a single-mode fiber, which accordingly has excellent transmission properties.
- polymer optical fibers are also used for optical signal transmission.
- PMMA polymethyl methacrylate
- the currently usable transmission wavelengths are in the visible spectral range.
- the main disadvantages of polymer optical fibers PMMA lie in the material-related high damping of approx. 150 dB / km at the commonly used transmission wavelength of 650 nm and the fact that it is currently commercial only available fiber type as a result of the pure Step index profile has a very large mode dispersion.
- the step index profile of a polymeric optical fiber shows a constant over almost the entire fiber diameter Refractive index profile. Hence the possible transfer rate relatively low and it also depends significantly on the Coupling conditions.
- As practically feasible for the interesting data rate for example 125 Mbit / s can be used for a transmission distance of approx. 100 m be considered.
- the bandwidth-length product is used for about 25 m fiber length calculated with 1.5 MHz ⁇ km and with 5 MHz ⁇ km to 6 MHz ⁇ km measured.
- polymeric optical fibers made of PMMA are used especially in Area of machine control with low transmission rates used as well as in the field of sensors, robotronics and for simple lighting systems.
- Automotive use of the more temperature-stable Polycarbonate fiber discussed.
- polymeric optical fibers on short Stretch, d. H. on the so-called “last 100 m to the house”, “in the house”, or in the area of office communication (local area network LAN).
- PMMA fibers which have a fiber core with a gradient refractive index profile. It is known to try to build up the desired parabolic refractive index profile by the so-called "interfacial gel copolymerization". The different diffusion rates of various monomeric PMMA derivatives are used to produce a preform. PMMA fibers produced in this way with a parabolic refractive index curve and with a core diameter of 600 ⁇ m are not yet commercially available. However, they are characterized by significantly higher data transmission rates and good attenuation values. However, the processing speed is very slow due to the speed of the diffusion. Since the substances to be diffused always penetrate from the outside, i.e. the outer surface of the fiber, the shape of the refractive index profile is clearly limited.
- the Task to provide a method that makes it simple It is possible to use a polymeric optical fiber with a Defined refractive index curve with the highest possible Processing speed and as large as possible Flexibility in the design of the refractive index profile too produce.
- This task is characterized by the characteristics of the Claim 1 solved.
- ionizing Radiation chemical-physical changes in the material a polymeric optical fiber that triggers the refractive index in change the polymeric optical fiber so that along the entire fiber length, preferably in the core area uniform radial gradient index refractive index profile perpendicular to the longitudinal axis of the polymeric optical fiber established.
- the method is also suitable for The refractive index profile of the fiber cladding is also required to change.
- instead of the polymer optical fiber can also be irradiated with a fiber preform.
- fiber core preform As well it is possible to use the later designed as a preform Fiber core (hereinafter, for simplicity, "fiber core preform” to be irradiated alone when used for Fiber production a so-called “rod-in-tube” process is chosen.
- the polymeric optical fiber, the preform or the fiber core preform is irradiated with the ionizing radiation at least once in the longitudinal direction during the feed.
- the irradiation must be rotationally symmetrical so that a uniform, radial gradient index refractive index profile is actually achieved.
- the change in the refractive index caused by the radiation produces the correct refractive index profile if the type and duration of the ionizing radiation are suitable.
- Annealing holding the polymeric optical fiber, the preform or the fiber core preform at a specific temperature higher than the use temperature for a predetermined time) finally optimizes the refractive index profile so that the desired uniform radial gradient index refractive index profile is formed ,
- the rotationally symmetrical radiation is according to claim 2 thereby achieved that either the polymeric optical fiber, the Preform or the fiber core preform a rotating movement makes a predetermined angle about the central fiber axis or that the system of optical elements, together with a or several radiation sources at a predetermined angle rotates around the central fiber axis.
- Claim 3 describes the design of the method Use of electromagnetic radiation (for example UV light, X-rays or gamma radiation, etc.) as ionizing Radiation.
- electromagnetic radiation for example UV light, X-rays or gamma radiation, etc.
- particle radiation is instead (e.g. electrons, positrons, heavy ions, etc.) used.
- optical elements can be reflective surfaces, lenses, cylindrical lenses or diaphragms.
- Claims 9 to 12 show further developments of the invention, in which the nature, the speed and the course of the refractive index change and its attenuation are influenced by various additives to the starting material of the fiber.
- Additives can also be used to influence the wavelength or the effect of the particle type of the ionizing radiation required for changing the refractive index.
- certain additives can be used to cause visible light to trigger a change in the refractive index.
- active and passive control elements can be built into the fiber using special additives.
- the course of the refractive index n over the cross section of a POF 1 is shown schematically in FIGS. 1a and 1b.
- the refractive index along any line parallel to the longitudinal axis of the POF 1 is constant.
- the simplest type of fiber has a so-called step index refractive index profile, as shown in FIG. 1a.
- the POF 1 with the core radius a and the total radius b consists of two layers concentrically around the fiber core with the different refractive indices n 1 and n 2 .
- the refractive index n is plotted over the distance r from the zero point 0 of the fiber center axis.
- the core of the POF 1 with the radius a consists of a plastic with the refractive index n 1 .
- the fiber cladding a ⁇ r b b has a refractive index n 2 , the refractive index n 1 being greater than n 2 .
- the light propagation takes place within the core with the refractive index n 1 .
- the smaller the radius of the fiber core a the fewer modes of light of one wavelength can be guided through the fiber. In the optimal limit, only one mode of one wavelength can pass through the optical fiber.
- Polymer optical fibers with a common core diameter of ⁇ 1 mm are far from this ideal case.
- On signal-relevant signal has a certain spectral signal width and therefore consists of several Wavelengths, each in multiple modes is spreadable. But since the different wavelengths in their spreadable modes due to the different optical paths at different speeds the original form of the Signals already on relatively short transmission paths and makes separation impossible at an early stage.
- FIG. 1b A parabolic refractive index profile is shown in FIG. 1b as an example.
- the POF 1 has a fiber cladding with a refractive index n 2 .
- the core of POF 1 no longer has a uniform refractive index. Instead, it falls parabolically from a refractive index n max in the middle of the fiber within the range 0 bis r a a to the value n 2 .
- Such a refractive index gradient has the property that it breaks the different modes to the fiber center to different degrees. As a result, the runtime differences of the modes are largely compensated for, the signals do not broaden so quickly and the effective range of the signal transmission increases considerably.
- the method according to the invention has the purpose of those above described gradient index refractive index profiles in the polymer optical fiber, in a polymeric preform or Easy and variable to produce fiber core preform.
- FIG. 2 A structure is sketched in FIG. 2, on the basis of which the The inventive method is explained in more detail by way of example. It shows a POF 1 with a fiber central axis 7, one Radiation source 5, a mirror 7, and a sleeve 2 with a window 4.
- the POF 1 is through the radiation source 5 exposed to ionizing radiation in this variant the process is homogeneous, for focusing on the Fiber center axis 7 particularly favorable, radiation characteristic should have.
- the radiation source 5 can be a UV lamp his.
- the POF preferably consists of polymethyl methacrylate (PMMA), the effective wavelength range begins at Wavelengths of ⁇ ⁇ 380 nm, since here the UV absorption edge is reached by PMMA and the radiation in this area most suitably changed the chemical-physical structure.
- PMMA polymethyl methacrylate
- the effective wavelength range begins at Wavelengths of ⁇ ⁇ 380 nm, since here the UV absorption edge is reached by PMMA and the radiation in this area most suitably changed the chemical-physical structure.
- PMMA polymethyl methacrylate
- particle radiation for example Electrons, positrons, etc.
- the radiation stands u. a. in the form of radioactive Preparations are available and could be done through, for example Exposure to suitable electrical or magnetic fields Form to be focused on the POF 1.
- the ionizing radiation of the radiation source 5 must now be on the POF 1 are directed that an inhomogeneous distribution in radial direction of the radiation intensity in the POF 1 is achieved.
- this is the ionizing one Radiation focused on the fiber central axis 7 of the POF 1, see above that the change in refractive index is greatest there.
- To the edge of the POF 1 takes the refractive index, as in Figure 1b shown, from.
- the focus is in this example with the help of the mirror 3, which ideally, for example parabolic or elliptical about the fiber central axis 7 of the POF 1 is curved.
- the fiber center axis 7 of the POF 1 must be are exactly on the focal line of the mirror 3.
- the POF 1 and / or the mirror 3 by at least rotate a certain angle around the longitudinal axis of the POF 1.
- the angle is determined from the geometry of the Mirror 3. With a rotation angle of 180 ° and larger achieved uniform radiation.
- further mirrors 3 and further radiation sources 5 for uniform radiation from all sides of the POF 1 to use.
- an annular Radiation source is used.
- Guiding the POF 1 parallel to the fiber axis serves the sleeve 2, in which the window 4 is introduced. According to the invention cantilever fiber guidance also closer to that in Figure 4 described form.
- the entire POF 1 is in the direction of the radiation Longitudinal axis through the system mirror 3, radiation source 5 and Pulled sleeve 2. This ensures that the refractive index along the fiber central axis 7 of the POF 1 remains constant.
- the Pulling speed is adapted to the respective time is necessary to change the desired refractive index to reach.
- the arrangement has the advantage that by change the shape of the mirror 3, the distribution of the radiation intensity in POF 1 and thus the course of the refractive index profile can be controlled.
- the course of the process can be increased by sensitizing additives be accelerated or slowed down, which is an additional chemical and / or physical change in POF 1 during of radiation.
- sensitizing additives be accelerated or slowed down, which is an additional chemical and / or physical change in POF 1 during of radiation.
- these substances during the manufacture of the fiber, preform or Fiber core preform by mixing the starting materials or can be introduced subsequently by diffusion. It is the same possible, through the amount and distribution of additives, the course of the To influence the refractive index profile or the damping.
- the POF 1 will remain for a certain time annealed so that there is a stable refractive index profile over time can adjust. This can be done, for example, by stopping at a certain temperature (higher than the usage temperature) done, a process that is often already part of the Manufacturing process.
- the method according to the invention is thus characterized by a easy to use due to flexibility in the choice of Refractive index profile and in that one at least partially continuous process management is conceivable.
- a method variant is shown in FIG at least one focusing unit 6, preferably a lens, is used for radiation focusing.
- the POF 1 rotates in rotationally symmetrical radiation Longitudinal fiber direction around the central fiber axis 7.
- the focusing unit around the The fiber center axis 7 rotates, the radiation source being synchronous can be carried with.
- Figure 4 shows schematically an advantageous constructive Embodiment of the invention through the use of several Cylindrical lenses 10, 10 '.
- the POF 1 over the distance d by two circular disks 8, 8 'with corresponding ones concentric openings 9, 9 'with the smallest possible tolerance freely led.
- the position of the cylindrical lenses 10, 10 ' is determined by retaining webs 11 to 11 '' 'secured, which also serve as an adjustment device can.
- the cylindrical lenses 10, 10 ' rotate synchronously with the rod-shaped radiation sources 12, 12 'preferably around the Fiber center axis 7 of the POF 1, whereby the desired Refractive index profile is formed.
- This method is suitable especially good for UV light.
- FIG. 5 shows a method variant that is suitable for a Gradient index refractive index profile in a POF 1 through use of x-ray or gamma radiation.
- the for example from several high-energy radiation sources 13, 13 ', 13 "outgoing radiation is here by a appropriate number of apertures 14, 14 'and 14' 'more suitable Geometry led to a corresponding number of narrow Hide beams 15, 15 'and 15' 'and place them radially in Radiate direction on the fiber central axis 7.
- At the Interface of the beam 16 is increased by the Radiation intensity produces an increase in refractive index.
- the POF 1 is in the direction of its longitudinal axis during irradiation moved forward. Rotate here to achieve the required high-energy refractive index profile Radiation sources 13, 13 ', 13' 'with the diaphragms 14, 14' and 14 '' preferably around the fiber central axis 7 of the POF 1.
- non-polymeric materials can also be read (e.g. glass) in the manner described provided a change in the refractive index due to ionizing radiation can be caused.
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- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Ophthalmology & Optometry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Optics & Photonics (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Optical Couplings Of Light Guides (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Optical Integrated Circuits (AREA)
Description
Neben den Fasern auf Quarzglasbasis werden auch polymere Lichtwellenleiter zur optischen Signalübertragung verwendet. (zum Stand der Entwicklung vergleiche: O. Zieman: Grundlagen und Anwendungen optischer Polymerfasern, Der Fernmeldeingenieur, 50 , Heft 11/12, 1996). Favorisierte Materialien sind zur Zeit neben Fasern aus Polykarbonat, Polystyrol und Polyvinylchlorid ganz überwiegend Fasern aus Polymethylmethacrylat (im folgenden mit PMMA abgekürzt). Die Vorteile der PMMA-Fasern, die einen Standarddurchmesser von 1 mm haben, sind neben den vergleichsweise niedrigen Herstellungskosten, ihre einfachen Handhabung bei der Herstellung von Verbindungen (Stecker, Spleiße) und beim Aufbau von Verzweigungs- und Kopplungselementen sowie der einfachen Endflächenbehandlung und ihre geringe Empfindlichkeit gegenüber äußeren mechanischen, physikalischen und Umwelteinflüssen. Die gegenwärtig nutzbaren Übertragungswellenlängen liegen im sichtbaren Spektralbereich.
Allerdings ist die Verarbeitungsgeschwindigkeit, bedingt durch die Geschwindigkeit der Diffusion, doch sehr langsam. Da die einzudiffundierenden Stoffe immer von Außen, also der Mantelfläche der Faser, eindringen, ist man hinsichtlich der Form des Brechungsindexprofils deutlich eingeschränkt.
Die durch die Bestrahlung hervorgerufene Änderung der Brechzahl erzeugt bei geeigneter Art und Dauer der ionisierenden Strahlung das richtige Brechzahlprofil. Eine Temperung (das Halten der polymeren optischen Faser, der Vorform oder der Faserkern-Vorform auf einer bestimmten, höher als die Gebrauchstemperatur liegenden Temperatur, für eine vorgegebene Zeit) optimiert das Brechzahlprofil schließlich so, daß das gewünschte einheitliche, radiale Gradientenindex-Brechzahlprofil ausgebildet wird.
Diese optischen Elemente können reflektierende Oberflächen, Linsen, Zylinderlinsen oder Blenden sein.
Außerdem können durch spezielle Zusätze aktive und passive Steuerelemente in die Faser eingebaut werden.
- Figur 1a:
- einen Querschnitt durch eine optische Faser mit einem Stufenindexprofil,
- Figur 1b:
- einen Querschnitt durch eine optische Faser mit einem Gradientenindexprofil,
- Figur 2:
- schematisch die Ausgestaltung des Verfahrens bei Verwendung eines Parabolspiegel als Beispiel für eine reflektierende und fokussierende Oberfläche,
- Figur 3:
- schematisch die Ausgestaltung des Verfahrens mit rotierender Faser und fokussiertem Strahl,
- Figur 4:
- schematisch eine Ausgestaltung des Verfahrens bei Verwendung mehrere Zylinderlinsen zur Strahlungsfokussierung und
- Figur 5:
- schematisch, wie mit einer Anordnung von mehreren Blenden eine entsprechende Anzahl von Strahlenbündeln auf den Faserkern gerichtet wird, um dort eine Erhöhung der Strahlungsintensität zu bewirken.
- n
- optische Brechzahl
- n1
- Kernbrechzahl der Faser als Lichtwellenleiter
- n2
- Mantelbrechzahl der Faser als Lichtwellenleiter: n2 < n1
- nmax
- maximale Kernbrechzahl bei parabolischem Brechzahlverlauf
- r
- radialer Abstand von der Fasermittelachse
- a
- Radius des Faserkerns
- b
- Radius der Gesamtfaser
- 0
- Mittelpunkt der kreisförmigen Faserquerschnittsfläche
- d
- freie Faserlänge
- 1
- POF
- 2
- Hülse
- 3
- reflektierende Oberfläche
- 5
- Strahlungsquelle
- 6
- Linse
- 7
- Fasermittelachse
- 8, 8'
- Kreisscheiben
- 9, 9'
- konzentrische Öffnungen
- 10, 10'
- Zylinderlinsen
- 11 bis 11'''
- Haltesbege
- 12, 12'
- stabförmige Strahlungsquellen
- 13, 13', 13''
- hochenergetische Strahlungsquellen
- 14, 14', 14''
- Blenden
- 15, 15', 15''
- Strahlenbündel
- 16
- Schnittstelle der Strahlenbündel
Claims (12)
- Verfahren zur Erzeugung von Gradientenindex-Brechzahlprofilen in polymeren optischen Fasern, dadurch gekennzeichnet,daß entweder eine polymere optische Faser, oder deren Vorform oder Faserkern-Vorform (1) während eines Vorschubs entlang der Fasermittelachse (7) bei vorgegebener Geschwindigkeit einer ionisierender Strahlung vorbestimmter Dosis und Wellenlänge ausgesetzt wird,daß dabei die räumliche Verteilung der Intensität der ionisierenden Strahlung in der polymere optische Faser, oder deren Vorform oder Faserkern-Vorform (1) auf der gesamten bestrahlten Länge durch ein System aus optischen Elementen definiert vorgegeben wird, wobei die Bestrahlung rotationssymmetrisch erfolgt, unddaß anschließend die polymere optische Faser, oder deren Vorform oder Faserkern-Vorform (1) für eine vorbestimmte Zeit bei einer vorbestimmten Temperatur derart getempert wird, daß sich die Brechzahl der bestrahlten Bereiche dergestalt ändert, so daß ein einheitliches, radiales Gradientenindex-Brechzahlprofil ausbildet wird.
- Verfahren nach Anspruch 1, dadurch gekennzeichnet,daß entweder die polymere optische Faser, oder deren Vorform oder Faserkern-Vorform (1) eine rotierende Bewegung um einen vorbestimmten Winkel um die Fasermittelachse (7) ausführt oderdaß das System aus optischen Elementen, zusammen mit einer oder mehreren Strahlungsquellen um die Fasermittelachse (7) um einen vorbestimmten Winkel rotiert.
- Verfahren nach Anspruch 2 dadurch gekennzeichnet, daß als ionisierende Strahlung elektromagnetische Strahlung verwendet wird.
- Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß als ionisierende Strahlung Partikelstrahlung verwendet wird.
- Verfahren nach einem der Ansprüche 3 oder 4, dadurch gekennzeichnet, daß das System aus optischen Elementen aus einer oder mehreren reflektierenden Oberflächen (3) gebildet wird.
- Verfahren nach einem der Ansprüche 3 oder 4, dadurch gekennzeichnet, daß das System aus optischen Elementen aus einer oder mehreren Linsen (6) gebildet wird.
- Verfahren nach einem der Ansprüche 3 oder 4, dadurch gekennzeichnet, daß das System aus optischen Elementen aus einer oder mehreren Zylinderlinsen (10, 10') gebildet wird.
- Verfahren nach einem der Ansprüche 3 oder 4, dadurch gekennzeichnet, daß das System aus optischen Elementen aus einer oder mehreren Blenden (14, 14', 14'') gebildet wird.
- Verfahren nach einem der vorstehenden Ansprüche dadurch gekennzeichnet,daß durch spezielle Zusätze zum Ausgangsmaterial der polymere optische Faser, deren Vorform oder Faserkern-Vorform (1) die Geschwindigkeit der Brechzahländerung beeinflußt wird und,daß durch spezielle Zusätze zum Augangsmaterial der polymere optische Faser, deren Vorform oder Faserkern-Vorform (1) der Verlauf des Brechzahlprofils beeinflußt wird.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß durch spezielle Zusätze zum Ausgangsmaterial der polymere optische Faser, deren Vorform oder Faserkern-Vorform (1) die Dämpfung gezielt beeinflußt wird.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß durch spezielle Zusätze zum Ausgangsmaterial der polymere optische Faser, deren Vorform oder Faserkern-Vorform (1) oder durch spätere Eindiffussion solcher Zusätze und nachfolgender Bestrahlung passive und/oder aktive Steuerungselemente in der Faser erzeugt werden.
- Verfahren nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß durch spezielle Zusätze zum Ausgangsmaterial der polymere optische Faser, deren Vorform oder Faserkern-Vorform (1) die Wellenlänge oder die Wirkung der Partikelart der ionisierenden Strahlung beeinflußt wird, die zur Erzeugung der Brechzahländerung notwendig ist.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19822684 | 1998-05-20 | ||
| DE19822684A DE19822684A1 (de) | 1998-05-20 | 1998-05-20 | Verfahren zur Erzeugung von Gradientenindex-Brechzahlprofilen in polymeren optischen Fasern |
| PCT/EP1999/002954 WO1999059803A1 (de) | 1998-05-20 | 1999-04-30 | Verfahren zur erzeugung von gradientenindex-brechzahlprofilen in polymeren optischen fasern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1079964A1 EP1079964A1 (de) | 2001-03-07 |
| EP1079964B1 true EP1079964B1 (de) | 2002-02-20 |
Family
ID=7868444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99924856A Expired - Lifetime EP1079964B1 (de) | 1998-05-20 | 1999-04-30 | Verfahren zur erzeugung von gradientenindex-brechzahlprofilen in polymeren optischen fasern |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6527985B1 (de) |
| EP (1) | EP1079964B1 (de) |
| JP (1) | JP4386580B2 (de) |
| AT (1) | ATE213458T1 (de) |
| CA (1) | CA2325528C (de) |
| DE (2) | DE19822684A1 (de) |
| WO (1) | WO1999059803A1 (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7485883B2 (en) * | 2003-12-19 | 2009-02-03 | Gardner Iii William G | Variable wavelength radiation source |
| US20080019659A1 (en) * | 2005-10-26 | 2008-01-24 | Xiaoming Tao | Photonic fabric display with controlled graphic pattern, color, luminescence intensity, and light self-amplification |
| US7466896B2 (en) | 2005-10-26 | 2008-12-16 | The Hong Kong Polytechnic University | Photonic fabric display with controlled pattern, color, luminescence intensity, scattering intensity and light self-amplification |
| DE102013009169B4 (de) | 2013-05-28 | 2016-05-12 | Freundes- und Förderkreis des Institutes für Textiltechnik der RWTH Aachen e.V. | Verfahren zum Schmelzspinnen einer über ihren Querschnitt variierenden Faser sowie ihre Verwendung |
| US11880061B2 (en) | 2021-10-16 | 2024-01-23 | ZSquare Ltd. | Optical fiber from a single polymer |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3778361A (en) * | 1972-09-01 | 1973-12-11 | Bell Telephone Labor Inc | Process for rendering transparent media artificially opalescent and resulting product |
| US4455267A (en) * | 1980-07-31 | 1984-06-19 | Rockwell International Corporation | Fabrication of birefringent electromagnetic transmission line |
| NO853303L (no) * | 1985-08-22 | 1987-02-23 | Norsk Hydro As | Preform med gradert brytningsindeks og fremgangsmaate for fremstilling av samme. |
| JPS6333705A (ja) * | 1986-07-28 | 1988-02-13 | Mitsubishi Rayon Co Ltd | 屈折率分布型プラスチツク光フアイバの製法 |
| DE3820011A1 (de) * | 1988-06-11 | 1989-12-14 | Deutsche Bundespost | Verfahren zur gezielten veraenderung von brechungsindices in polymeren materialien |
| DE19627536A1 (de) * | 1996-07-09 | 1998-01-15 | Deutsche Telekom Ag | Wellenleitende Struktur mit gezielt einstellbarem Polarisationsverhalten in einem Polymer und Verfahren zur Herstellung einer solchen wellenleitenden Struktur |
| US6200503B1 (en) * | 1996-09-13 | 2001-03-13 | Mohammad W. Katoot | Graded index polymer optical fibers and process for manufacture thereof |
-
1998
- 1998-05-20 DE DE19822684A patent/DE19822684A1/de not_active Withdrawn
-
1999
- 1999-04-30 WO PCT/EP1999/002954 patent/WO1999059803A1/de not_active Ceased
- 1999-04-30 AT AT99924856T patent/ATE213458T1/de not_active IP Right Cessation
- 1999-04-30 CA CA002325528A patent/CA2325528C/en not_active Expired - Fee Related
- 1999-04-30 EP EP99924856A patent/EP1079964B1/de not_active Expired - Lifetime
- 1999-04-30 DE DE59900879T patent/DE59900879D1/de not_active Expired - Fee Related
- 1999-04-30 JP JP2000549450A patent/JP4386580B2/ja not_active Expired - Fee Related
- 1999-04-30 US US09/700,896 patent/US6527985B1/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002515615A (ja) | 2002-05-28 |
| DE59900879D1 (de) | 2002-03-28 |
| WO1999059803A1 (de) | 1999-11-25 |
| US6527985B1 (en) | 2003-03-04 |
| CA2325528C (en) | 2006-12-12 |
| JP4386580B2 (ja) | 2009-12-16 |
| DE19822684A1 (de) | 1999-12-09 |
| EP1079964A1 (de) | 2001-03-07 |
| CA2325528A1 (en) | 1999-11-25 |
| ATE213458T1 (de) | 2002-03-15 |
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