EP1058586A1 - Systeme robotique de nettoyage laser pour moule de pneus et son mode d'utilisation - Google Patents

Systeme robotique de nettoyage laser pour moule de pneus et son mode d'utilisation

Info

Publication number
EP1058586A1
EP1058586A1 EP98907570A EP98907570A EP1058586A1 EP 1058586 A1 EP1058586 A1 EP 1058586A1 EP 98907570 A EP98907570 A EP 98907570A EP 98907570 A EP98907570 A EP 98907570A EP 1058586 A1 EP1058586 A1 EP 1058586A1
Authority
EP
European Patent Office
Prior art keywords
laser
robot
arm
recited
output end
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP98907570A
Other languages
German (de)
English (en)
Inventor
Geary Victor Soska
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Publication of EP1058586A1 publication Critical patent/EP1058586A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B7/00Cleaning by methods not provided for in a single other subclass or a single group in this subclass
    • B08B7/0035Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like
    • B08B7/0042Cleaning by methods not provided for in a single other subclass or a single group in this subclass by radiant energy, e.g. UV, laser, light beam or the like by laser
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/70Maintenance
    • B29C33/72Cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/0601Vulcanising tyres; Vulcanising presses for tyres
    • B29D30/0662Accessories, details or auxiliary operations
    • B29D2030/0663Mould maintenance, e.g. cleaning, washing, repairing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2030/00Pneumatic or solid tyres or parts thereof

Definitions

  • the present invention relates to devices and methods for cleaning tire molds, particularly to methods and apparatuses for cleaning tire molds using a laser light mounted onto a robot control apparatus .
  • BACKGROUND OF THE INVENTION Presently, two-piece tire molds and segmented tire molds are typically cleaned in semi-automatic machines which use metal shot, plastic beads, or glass beads as the cleaning or blasting agent. All of these blasting agents are abrasive and cause rapid wear to tire mold lettering and sidewall designs.
  • Another problem encountered by the past cleaning machines was recovery of the blasting agent, such as the sand or glass beads. After the blasting agent had been used to clean a tire mold, it had to be recovered or removed. The recovery of the blasting agent increased the time necessary to clean tire molds and caused a housekeeping problem in the plant.
  • U.S. Patent No. 5,373,140 to Nagy discloses a system for cleaning molds within presses including a laser to clean surfaces within the mold.
  • the light source may be formed as a portable unit moving between different presses or may be in the form of a single laser with a plurality of light paths leading from the laser to individual presses to clean the molds within the presses.
  • the present invention contemplates a new and improved tire mold cleaning method and apparatus which is simple in design, effective in use, and overcomes the foregoing difficulties and others while providing better and more advantageous overall results .
  • the present invention is a cleaning device for removing residual material from a mold having a molding surface.
  • the device comprises a robot including an arm movable in a plurality of degrees of freedom, the arm having a free end.
  • a laser is connected with the robot and has an output end mounted to the arm proximal to the free end so as to be positionable by the robot.
  • the robot positions the output end of the laser with respect to the molding surface to direct light from the laser to impinge on the surface and remove residual material from the surface.
  • the present invention is a method of cleaning residual material from the molding surface of a mold comprising the following steps : providing a robot having an arm movable in a plurality of degrees of freedom and a laser connected with the robot and having an output end mounted to the arm; automatically moving the arm to align the output end of the laser with the molding surface; and activating the laser such that laser light impinges on the molding surface and removes residual material disposed on the surface.
  • the present invention is a system for cleaning a metallic object.
  • the system comprises a robot including an arm movable in a plurality of degrees of freedom, the arm having a free end.
  • a laser is connected with the robot and has an output end mounted to the arm proximal to the free end so as to be positionable by the robot.
  • a rotatable support is disposed proximal to the robot and is configured to support the object and rotate the object with respect to the output end of the laser.
  • One advantage of the present invention is that the cleaning apparatus is completely automatic. Another advantage of the present invention is that the beam of laser light is non-abrasive and does not damage the tire mold.
  • Another advantage of the present invention is that the laser light provides single pass cleaning of the tire mold as opposed to multiple passes required by existing systems.
  • Another advantage of the present invention is that the laser light also cleans the tire molds without generating a loud noise level. Still other benefits and advantages of the invention will become apparent to those skilled in the art to which it pertains upon a reading and understanding of the following detailed specification.
  • Figure 1 is a top plan view of the robotic laser cleaning device in accordance with the present invention
  • Figure 2 is a side elevational view of the robot and a tire mold on one rotatable support, shown performing a cleaning operation
  • Figure 3 is an enlarged, partially broken-away side view of the forearm and wrist portions of the robotic arm;
  • Figure 4 is a greatly enlarged side cross-sectional view of the laser delivery head;
  • Figure 5 is a view through line 5-5 of Figure 4;
  • Figure 6 is an enlarged, broken-away perspective view of the end of the delivery head and a section of the molding surface, showing an exemplary light stripe
  • Figure 7 is a view of an alternate embodiment of the laser delivery head incorporating optical reflectors in accordance with the invention.
  • FIG. 1 a presently preferred embodiment of a robotic laser cleaning device 10 for cleaning residual material from the molding surface 13 of a tire mold 12.
  • the cleaning device 10 primarily comprises a robot 14 having an arm 16 movable within a plurality of degrees of freedom and a laser 18 connected with the robot 14 and having an output end 20 attached to the free end of the arm 16 of the robot 14.
  • the robot 14 positions the output end 20 of the laser 18 with respect to the molding surface 13 such that activation of laser 18 directs laser light 18a to impinge on the surface 13 and remove residual material from the surface 13.
  • the robot 14 is preferably a commercially available industrial robot having an arm 16 that is movable within six degrees of freedom (“DOF") . More specifically, the robot 14 preferably includes a base 22 configured to rotate within a horizontal plane (first DOF), to which is mounted a "shoulder" 24 of the robotic arm 16.
  • the robotic arm 16 further includes an "upper arm” 26 having a lower end 26a pivotally attached (second DOF) to the shoulder 24 by means of a laterally extending shaft 25.
  • the arm 16 also includes a "forearm” 28 having a first end 28a pivotally attached (third DOF) to the free end 26b of the upper arm 26 by means of a pivot shaft 27.
  • the forearm 28 is pivoted about shaft 27 by movement of actuator arm 29 pivotably connected at end 29a to forearm 28 and at end 29b to shoulder 24.
  • a "wrist" 30 of the arm 16 is attached to the free end 28b of the forearm 28 and is capable of moving in the following three manners: by pivoting about the free end 28b of the forearm 28 (fourth DOF), by "spinning" about an axis 31 extending along the centerline of the forearm 28 (fifth DOF), and by spinning about the axis 31 (sixth DOF) .
  • the robotic arm 16 includes an "end effector" mounted to the wrist 30, which is preferably a laser delivery head 32 as described hereinafter.
  • an end effector is the working tool that is positionable by movement of the robotic arm 16 within one or more of the degrees of freedom.
  • the robot 14 includes a plurality of electric 8
  • servomotors (not shown) actuating and controlling the movement of the base 22 and the various portions of the arm 16 described above.
  • the robot 14 can alternatively have a wrist 30 that is configured to spin, to rotate within a vertical plane, and to rotate in horizontal plane as opposed to spinning along axis 31.
  • the robot 14 may optionally include a machine vision system provided by, for example, video cameras (none shown) connected to a video processor (not shown) , so that the robot 14 can recognize the location of the end effector and adjust its position to ensure that the cleaning device 10 performs as desired during a cleaning operation, as described below.
  • the laser 18 is a standard, solid-state Nd:YAG (i.e., Neodymium doped Yttrium Aluminum Garnet) continuous wave laser, which are well known in the laser field of art.
  • the laser 18 is a commercially available Nd:YAG laser.
  • the laser 18 has sufficient power/intensity such that laser light 18a emitted from the output end 19 of the laser 18 vaporizes residual material in the tire mold 12 upon contact.
  • a Nd:YAG laser is preferred, it is within the scope of the present invention for the laser 18 to be a pulsed C0 laser, a pulsed excimer laser, or any other appropriate type of laser that enables the cleaning device 10 to function as described in the present disclosure.
  • the term "laser" as used in the present disclosure is intended to cover any high-energy irradiation source, including pulsed or continuous wave lasers and high-energy lamps .
  • the laser 18 is mounted on the robot 14, and is most preferably enclosed within a housing section 36 of the forearm 28 of the robotic arm 16.
  • the laser 18 can alternatively be mounted on a separate platform (not shown) located proximal to the robot 14 or can be mounted at any other appropriate location on the robot 14, such as for example, in the base 22.
  • a standard power supply (not shown) connected with the laser 18 provides power to operate the laser 18 and is also preferably mounted on a separate platform (not shown) located proximal to the robot 14.
  • the laser 18 includes an optical delivery system 38 having a pathway extending between the laser 18 and the terminal end 20 of the delivery head 32.
  • a first end 39 of optical fibers 42 are connected with the laser 18 and a second end 40 of the optical fibers are mounted to the wrist 30 of the robotic arm 16.
  • the delivery system 38 includes a plurality of optical fibers 42 extending from the output port 19 of the 10
  • the delivery head 32 is a tubular housing 44 having a first end 44a attached to the wrist 30, through which the optical fibers 42 enter the delivery head 32, and a second or "delivery" end 44b out of which is directed laser light 18a emitted from the output ends 43 of the optical fibers 42.
  • the tubular housing 44 is preferably curved to facilitate placement of laser light 18a onto complex surfaces 13 of the mold 12.
  • a vacuum device or "smoke sucker” (not shown) is preferably mounted to the delivery head 32 so as to evacuate residual material vaporized during a cleaning operation through the tubular housing 44, as described below.
  • the output ends 43 of the optical fibers 42 are aligned such that laser light 18a outputted from the laser 18 forms a stripe of light 18b.
  • the diameter "d" of the optical fibers 42 and the spacing distance "s" between the individual fibers 42 is such that a stripe of light 18b having a length in the range of about 1.92 centimeters (cm) [0.75 inches] to about 3.81 cm [1.5 inches] .
  • the width of the stripe 18b of light is in the range 11
  • the robot 14 is preferably programmed to ensure that the output ends 43 of the fibers 42 are always normal to the section of the molding surface 13 upon which the stripe 18b is projected, so that the light stripe 18b is of a sufficient intensity to ablate residual material, as described further below.
  • the delivery system 38 may alternatively be provided by a series of optical reflectors 90, such as mirrors 92 and 94 as shown in Figure 7, mounted on or within the tubular housing 44 of delivery head 32 and configured to direct laser light 18a from the wrist 30 of the robotic arm 16, to which it can be delivered through optical fibers 42, as shown in Figure 3, and then to a desired target, such as the molding surface 13 of a tire mold 12.
  • a desired target such as the molding surface 13 of a tire mold 12.
  • the robotic laser cleaning device 10 further includes a controller 46 for controlling the operation of the robot 14 and for interfacing the robot operation with the laser 18. During a cleaning operation 12
  • the controller 46 directs the robotic arm 16 so that the delivery head 32 is moved through at least one predetermined set of movements with respect to the tire mold 12.
  • the predetermined set of movements causes laser light 18a directed from the head 32 to impinge on all sections of the molding surface 13.
  • the controller 46 also controls the activation and deactivation of the laser 18 so that the laser 18 is turned on and off at appropriate times during the cleaning operation.
  • the controller 46 is fully programmable so as to be capable of actuating the robotic arm 16 to move through a plurality of different predetermined sets of movements. Such controller programmability allows the cleaning device 10 to be used with various molds 12 having different sizes and/or shapes.
  • the controller 46 is preferably the standard control system provided with a commercially available robot 14, although the controller 46 can alternatively be a separately provided personal computer, a programmable logic controller (“PLC”) or any other such programmable device (none shown) connected with the robot 14 and with the laser 18.
  • the robotic laser cleaning device 10 preferably further includes at least one rotatable support 48 configured to both locate the mold 12 in a specific position with respect to the robot 14 and to rotate the mold with respect to the robot 14.
  • the rotatable support 48 preferably includes a rotary table 50 rotatably mounted to a stationary base 52 so as to turn about a vertical axis 53, although another rotatable device such as a cylindrical platform 13
  • a centering apparatus (not shown) connected with the rotatable support 48 centers a tire mold 12 placed upon the table 50 about the axis 53 and is preferably provided by three centering guide members (none shown) slidably attached to the table 50 and movable in radial directions.
  • a servomotor (not shown) drives the rotary table 50 and is preferably controlled by the controller 46, although alternatively the servomotor can be controlled by a separate controller (not shown) or by a manually operated switch and speed control (neither shown) .
  • the controller 46 regulates the speed at which the servomotor rotates the support 48, and thus a mold 12 on the table 50, and coordinates the rotation of the table 50 with movement of the robotic arm 16, as described further below.
  • the cleaning device 10 is able to operate by using the table 50 to rotate the mold 12 about the delivery head 32, the rotation of the table 50 aligning different circumferential sections of the molding surface 13 with the output ends 43 of the optical fibers 42.
  • rotation of the table 50 enables the laser stripe 18b to sweep around the entire circumference of the molding surface 13.
  • the robotic arm 16 would be required to rotate the head 32 about the central axis 53 so that the laser stripe 18b reaches all sections of the molding surface 13.
  • the additional degree of freedom provided by the rotatable support 48 minimizes the amount of twisting and turning required by the robotic arm 16 and thereby reduces the 14
  • the cleaning device 10 preferably includes a second rotatable support 54 disposed adjacent to the robot 14 such that the two supports 48 and 54 are spaced generally equidistant from the robot 14. With two supports 48, 54, a cleaned mold 12 can be removed from one support 48 or 54 and replaced with another mold 12 to be cleaned while the cleaning device 10 is performing a cleaning operation on a mold 12 disposed on the other support 54 or 48.
  • the robotic laser cleaning device 10 is most preferably used to remove residual material remaining in a tire mold 12 after a tire molding operation is performed.
  • Such material includes particles of uncured and cured rubber, bladder release agents, and other foreign materials such as dust, dirt particles, oils or lubricants from associated manufacturing equipment .
  • the cleaning device 10 it is within the scope of the present invention to utilize the cleaning device 10 to remove other residual materials from any other type of mold, such as injection molding equipment (not shown), or from any other manufacturing equipment constructed of a material suitable to be cleaned by laser light.
  • the cleaning device 10 operates by rotating the table 50 to turn the mold 12 while, simultaneously, the robot 14 positions and repositions the delivery head 32 so that the laser 15
  • the first step in using the cleaning device 10 is to place a tire mold 12 one or both rotatable supports 48 and 54, and then center the mold 12 on the rotary table 40 about the axis 53.
  • the controller 46 is programmed to "know" the location of the entire molding surface 13 of the mold 12, and can thereby accurately position the robotic arm 16 within the tire mold 12.
  • the controller 46 activates the robot 14 so that the delivery head 32 is placed within the interior of the tire mold 12 at an initial position with respect to the molding surface 13.
  • the controller 46 thereafter activates the laser 18 and rotates the rotary table 50 so that the mold 12 turns about the axis 53, and thus the delivery head 32, at a rotational speed preferably between about 0.5 rotations per minute ("rp ") and about 6.0 rpm.
  • the robotic arm 16 executes a predetermined set of movements such that the delivery head 32 directs the light stripe 18b to impinge on all sections of the molding surface 13. As the light stripe 18b impinges on the molding surface 13, the stripe 18b contacts any residual material thereupon and causes the material to become vaporized.
  • the vaporized material can then be evacuated from the mold 12 by the smoke sucker (not shown) .
  • the mold 12 is completely cleaned of residual material from one "pass" of the light stripe 18b over the entire molding surface 13. However, the cleaning process can be repeated if necessary, such as if a thick accumulation of 16
  • the cleaning device 10 of the present invention has a number of advantages over prior art mold cleaning systems. For example, by being mounted to a robot 14, the laser cleaning process is fully automated and therefore operator error, due to such factors as fatigue and/or carelessness, is virtually eliminated. Thus, a tire mold 12 cleaned by the device 10 of the present invention is much more likely to be free of residual materials than a mold 12 cleaned using the hand-held laser system disclosed in the 5,373,140 patent to Nagy. Further, by having the rotatable support 48, 50, wear on the optical fibers that occurs with the Nagy device is not present with the robotic laser cleaning device 10. Further, the cleaning system 10 is quieter than cleaning systems using C0 2 pellets.
  • the life of a mold 12 cleaned by the cleaning device 10 of the present invention is greater than with molds repeatedly cleaned by an existing abrasive process such as those involving impact by glass or plastic beads, or metal shot.

Landscapes

  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Cleaning In General (AREA)
  • Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)

Abstract

Dispositif de nettoyage (10) qui permet de faire sortir le matériau résiduel d'un moule (12) possédant une surface de moulage (13). Le dispositif comprend un robot (14) doté d'un bras (16) pouvant se déplacer selon une pluralité de degrés de liberté et comportant une extrémité libre. Un laser (18) connecté au robot (14) comporte une extrémité de sortie montée sur le bras (16), près de son extrémité libre, de façon à pouvoir être positionnée par ledit robot. Un système de distribution optique (38) comprend une pluralité de fibres optiques, chaque fibre ayant une première extrémité connectée au laser (18) et une seconde extrémité, l'extrémité de sortie, fixée sur l'extrémité libre du bras du robot (14). Les extrémités de sortie des fibres optiques (42) sont alignées de façon que le laser forme un ruban de lumière (18b) sur la surface de moulage (13). Une unité de commande (46) connectée au robot (14) dirige le bras (16) de façon à lui faire effectuer au moins une série prédéterminée de mouvements. Un support rotatif (48, 54) est placé à proximité du robot (14) et le moule (12) est posé sur le support. Le robot (14) positionne l'extrémité de sortie du laser (18) par rapport à la surface de moulage (13) de façon à diriger la lumière (18a) émise par le laser. La lumière frappe la surface et en fait sortir le matériau résiduel, pendant que la rotation du support (48, 54) aligne les différentes parties de la surface de moulage avec l'extrémité de sortie du laser.
EP98907570A 1998-02-20 1998-02-20 Systeme robotique de nettoyage laser pour moule de pneus et son mode d'utilisation Ceased EP1058586A1 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1998/003401 WO1999042228A1 (fr) 1998-02-20 1998-02-20 Systeme robotique de nettoyage laser pour moule de pneus et son mode d'utilisation

Publications (1)

Publication Number Publication Date
EP1058586A1 true EP1058586A1 (fr) 2000-12-13

Family

ID=22266435

Family Applications (1)

Application Number Title Priority Date Filing Date
EP98907570A Ceased EP1058586A1 (fr) 1998-02-20 1998-02-20 Systeme robotique de nettoyage laser pour moule de pneus et son mode d'utilisation

Country Status (5)

Country Link
EP (1) EP1058586A1 (fr)
JP (1) JP2002503551A (fr)
AU (1) AU6334098A (fr)
CA (1) CA2314874A1 (fr)
WO (1) WO1999042228A1 (fr)

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EP3141367A4 (fr) * 2014-05-09 2018-01-10 The Yokohama Rubber Co., Ltd. Système de nettoyage de moule

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JP5246731B2 (ja) * 2006-12-19 2013-07-24 株式会社ブリヂストン 金型クリーニング方法及び装置
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JP6450093B2 (ja) * 2014-06-09 2019-01-09 住友ゴム工業株式会社 モールドの洗浄装置
JP5892198B2 (ja) * 2014-06-26 2016-03-23 横浜ゴム株式会社 モールドの洗浄システム
CN105170573A (zh) * 2015-07-24 2015-12-23 苏州市星科四达激光科技有限公司 一种油墨容器的激光清洗装置及方法
US10471632B2 (en) * 2015-11-05 2019-11-12 The Yokohama Rubber Co., Ltd. Mold cleaning system
CN108136449B (zh) * 2015-11-11 2019-06-07 横滨橡胶株式会社 轮胎的内表面的清洗系统
JP6583010B2 (ja) * 2016-01-19 2019-10-02 住友ゴム工業株式会社 ベントホール洗浄装置及びベントホール洗浄方法。
AT15974U1 (de) * 2016-09-01 2018-10-15 Miba Gleitlager Austria Gmbh Verfahren zur Herstellung eines Mehrschichtgleitlagerelementes
AT15618U3 (de) * 2017-08-18 2018-08-15 Miba Gleitlager Austria Gmbh Verfahren zur Herstellung eines Mehrschichtgleitlagerelementes
JP6590010B2 (ja) * 2018-02-09 2019-10-16 横浜ゴム株式会社 加硫用モールドの洗浄装置および方法
US11396150B2 (en) 2018-02-14 2022-07-26 Android Industries Llc Tire preparation for adhesive using laser ablation system and method
CN108202052A (zh) * 2018-02-28 2018-06-26 彭州启光科技有限公司 一种用于飞机零部件清洗的自动式激光清洗装置
CN108356035A (zh) * 2018-04-11 2018-08-03 陕西理工大学 一种利用激光检测并去除轮胎纵向沟槽异物的装置及方法
WO2020206500A1 (fr) * 2019-04-11 2020-10-15 Automation Innovation Pty Ltd Système de nettoyage laser amélioré
CN111299258A (zh) * 2020-04-01 2020-06-19 济南振宏机械有限公司 一种便于操作的激光清洗机械手
CN111673286A (zh) * 2020-06-15 2020-09-18 中国船舶重工集团公司第七一三研究所 一种水下导弹发射井筒凸膜压紧环的自动化激光除锈装置
CN113843948B (zh) * 2020-06-25 2023-07-28 株式会社大镐技术 透镜及模具移送系统
CN112677380B (zh) * 2020-12-31 2021-10-19 安徽美祥实业有限公司 一种超大硫化机

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EP3141367A4 (fr) * 2014-05-09 2018-01-10 The Yokohama Rubber Co., Ltd. Système de nettoyage de moule
US11072139B2 (en) 2014-05-09 2021-07-27 The Yokohama Rubber Co., Ltd. Mold cleaning system

Also Published As

Publication number Publication date
CA2314874A1 (fr) 1999-08-26
AU6334098A (en) 1999-09-06
JP2002503551A (ja) 2002-02-05
WO1999042228A1 (fr) 1999-08-26

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