EP1028853B1 - Feuille d'impression thermosensible comportant des microcapsules sensibles a la pression utilisees comme element de securite - Google Patents
Feuille d'impression thermosensible comportant des microcapsules sensibles a la pression utilisees comme element de securite Download PDFInfo
- Publication number
- EP1028853B1 EP1028853B1 EP99944458A EP99944458A EP1028853B1 EP 1028853 B1 EP1028853 B1 EP 1028853B1 EP 99944458 A EP99944458 A EP 99944458A EP 99944458 A EP99944458 A EP 99944458A EP 1028853 B1 EP1028853 B1 EP 1028853B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat
- sensitive recording
- sensitive
- microcapsules
- color
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003094 microcapsule Substances 0.000 title claims abstract description 28
- 239000000370 acceptor Substances 0.000 claims abstract description 13
- 239000000758 substrate Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 238000001514 detection method Methods 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 11
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 208000001613 Gambling Diseases 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/14—Security printing
- B41M3/142—Security printing using chemical colour-formers or chemical reactions, e.g. leuco-dye/acid, photochromes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/30—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using chemical colour formers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/124—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components
- B41M5/165—Duplicating or marking methods; Sheet materials for use therein using pressure to make a masked colour visible, e.g. to make a coloured support visible, to create an opaque or transparent pattern, or to form colour by uniting colour-forming components characterised by the use of microcapsules; Special solvents for incorporating the ingredients
Definitions
- the invention relates to a heat-sensitive recording sheet, the one Substrate, a heat sensitive applied to one side of the substrate Recording layer used to create a typeface under the influence contains heat-reactive color formers and color acceptors, and has a security element.
- Heat-sensitive recording sheets have been known for a long time. Most of these materials are used to record remote copies, over public telephone networks - so-called fax procedure to be dispatched. An increasingly important area of application for heat-sensitive Recording materials have been in use lately as receipts, parking tickets from parking machines, entrance tickets and tickets as well Evidence of all kinds of games of chance.
- Microcapsules have also been used in the manufacture of heat-sensitive recording sheet proposed.
- the known suggestions mainly concern the improvement of shelf life and the Development of pressure and heat sensitive recording materials, which also enable heat-sensitive image transmission.
- a heat-sensitive image transfer recording sheet which has a heat-sensitive recording layer on one side of its support and a heat and pressure-sensitive image transfer layer on the other side.
- Microcapsules containing a colorless color former in a non-volatile solvent and microcapsules containing a color acceptor in a non-volatile solvent are arranged in the heat and pressure-sensitive image transfer layer.
- Also in the image transfer layer is a solid, colorless, electron-donating color former and a solid, colorless, electron-accepting color developer and a wax.
- the heat-sensitive image transfer recording sheet is placed on a simple sheet of paper and a thermal head is applied to the heat-sensitive recording layer, an image is formed on the heat-sensitive recording layer and the image of the recording is formed on the plain paper by heat transfer.
- a thermal head is applied to the heat-sensitive recording layer
- an image is formed on the heat-sensitive recording layer and the image of the recording is formed on the plain paper by heat transfer.
- an image can also be formed on the simple paper sheet.
- DE-37 04 627 A1 sees a heat-sensitive recording material in which the color reaction between a diazo compound and an associated coupling component takes place before that at least one of the two reaction components is contained in a microcapsule in order to improve the shelf life of the blank material and the sensitivity.
- a 1 discloses a two-color recording material in which a heat-sensitive color-forming layer known per se and a light-sensitive, heat-sensitive color-forming layer which contains microcapsules in which a leuco dye and a photo-oxidizing agent are contained and a are applied successively to a support Reducing agent is present in the light-sensitive, heat-sensitive color formation layer.
- the photosensitive, heat-sensitive recording layer is formed by heating with a heating block and subsequent irradiation with an ultra-high pressure mercury lamp.
- JP 08 300 810 A discloses a heat-sensitive recording material which, in addition to the heat-sensitive coating applied to its front, provides a layer of color formers and acceptors applied to the front of its support, which attempts to make counterfeiting visible on the front of the heat-sensitive recording material. At least one of the reactants is encapsulated. The layer consisting of color formers and acceptors is covered with a polyolefin resin layer, not disclosed in any more detail, on which a transparent or translucent paper is arranged.
- a disadvantage of this proposal in addition to the complicated structure of the recording material, is that the image created by the attempted forgery does not stand out clearly enough from the image produced by heat on the front side.
- US-A-5,401,060 is a document paper which can be written on by means of a laser printer.
- a locally limited application of a coating or printing ink composition is provided on the document, which has a color developer and a dye precursor contained in microcapsules.
- the microcapsules break open under the influence of pressure and thus release the dye precursor contained therein, which under the influence of heat simultaneously acting on the document reacts with the color developer to form a color.
- US-A-5,395,138 provides a coating color or printing ink composition in which the dye precursor contained in microcapsules reacts with the color developer under the capsule-destroying pressure without the additional influence of heat. Since the authenticity proof field charged with the coating color or printing ink composition is sensitive to pressure, the authenticity proof field and the normal use area to be labeled must be spatially separated in this known document paper.
- EP-A-0 623 909 proposes a recording sheet with a plurality of coatings which are applied to different fields in a spatially limited manner and which are partially pressure-sensitive and partially heat-sensitive.
- the known recording sheet is intended to enable typefaces of different colors by using combinations of different dye precursors and color acceptors in the different coating fields.
- the multi-colored typefaces on the known recording sheet are intended to enable clear and more user-oriented use of forms or labels without the need for color printers.
- the use of this known recording sheet as a heat-sensitive recording sheet with a security element is not disclosed.
- the object of the present invention is to provide a heat sensitive Record sheet with a security element available too who are responsible for the production of tickets, tickets, receipts and can be used in gambling and the detection of fake ones Documents without using the recording sheet according to the invention are made without the use of mechanical or electrical Auxiliary devices such as UV lamps or those to be applied to the recording material Chemicals.
- the invention provides a recording sheet in front of one substrate, one applied to one side of the substrate heat-sensitive recording layer which is used to produce a Typeface under the influence of heat reacting color formers and contains color acceptors, and has a security element
- the Record sheet is characterized in that the security element in the heat-sensitive recording layer made of pressure-sensitive microcapsules consists of one or more color formers in a solvent contain the after destroying the microcapsules with the color acceptors Formation of a color react.
- Coating base papers with a mass per unit area of 45 to 250 g / m 2, preferably 70 to 150 g / m 2, are suitable as substrates. Wood-free coating base papers or those with a low proportion of wood pulp are particularly suitable.
- the substrates can also be provided with a primer with a mass per unit area of 3 to 12 g / m 2 .
- the heat-sensitive recording layer is suitably applied with a mass per unit area in the range from 3 to 6 g / m 2 .
- the mass per unit area of the finished heat-sensitive recording sheet is 48 to 268 g / m 2 , preferably 73 to 168 g / m 2 .
- the heat-sensitive recording layer contains (otro-) Total weight 5 to 50 parts by weight of microcapsules with a particularly preferred Range between 12 and 30 parts by weight.
- the microcapsules incorporated in the heat sensitive recording layer contain 1 to 8 parts by weight, preferably 2.5 to 6.5 parts by weight of color former based on the (otro-) total weight of the microcapsules.
- microcapsules in the heat sensitive recording layer there is e.g. with an admission control the possibility an image in the heat-sensitive recording layer by the action of pressure to produce and in this way the authenticity of the paper used to control.
- the microcapsules are e.g. one Destroyed metal stamp
- the released color formers react with the acceptors the heat-sensitive recording layer and provide a stamp impression corresponding picture.
- the color formers are preferably too choose between that generated by heat in the recording layer Image and the color former released in the recording layer resulting image there is a color contrast.
- a pigmented primer of 4 g / m 2 is applied to a wood-free paper with a mass per unit area of 76 g / m 2 and dried.
- the dried precoat is coated with a coating color to form a heat-sensitive recording layer which, in addition to the color formers and color acceptors required by means of heat to form an image, also contains microcapsules with a color former composition dissolved in solvent.
- the application weight is otro 5 g / m 2 .
- the weight ratio of temperature sensitive components and pressure sensitive components in the dried recording layer is 3.5: 1, which means that 22 parts by weight of microcapsules are contained in the heat sensitive recording layer.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Color Printing (AREA)
Claims (6)
- Feuille d'enregistrement thermosensible comprenant :un substrat,une couche d'enregistrement thermosensible appliquée sur une des faces du substrat, laquelle couche contient des agents chromogène et des accepteurs de couleur qui réagissent, sous l'action de là chaleur, les uns avec les autres pour former une suite de caractères, etun élément de sécurité,
- Feuille d'enregistrement thermosensible selon la revendication 1, caractérisée par le fait que la couche d'enregistrement thermosensible contient de 5 à 50 parties en poids de microcapsules, rapporté au poids total (après séchage au four) de la couche d'enregistrement.
- Feuille d'enregistrement thermosensible selon la revendication 2, caractérisée par le fait que la couche d'enregistrement thermosensible contient de 12 à 30 parties en poids de microcapsules, rapporté au poids total (après séchage au four) de la couche d'enregistrement.
- Feuille d'enregistrement thermosensible selon une des revendications 1 à 3, caractérisée par le fait que les microcapsules contiennent de 1 à 8 parties en poids d'agent chromogène, rapporté au poids total (après séchage au four) des microcapsules.
- Feuille d'enregistrement thermosensible selon une des revendications 1 à 4, caractérisée par le fait que les microcapsules contiennent de 2,5 à 6,5 parties en poids d'agent chromogène, rapporté au poids total (après séchage au four) des microcapsules.
- Feuille d'enregistrement selon une des revendications 1 à 5, caractérisée par le fait que la masse surfacique de la feuille d'enregistrement thermosensible est comprise entre 48 et 268 g/m2.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19838893 | 1998-08-27 | ||
DE19838893A DE19838893C2 (de) | 1998-08-27 | 1998-08-27 | Wärmeempfindlicher Aufzeichnungsbogen |
PCT/EP1999/006122 WO2000012321A1 (fr) | 1998-08-27 | 1999-08-20 | Feuille d'impression thermosensible comportant des microcapsules sensibles a la pression utilisees comme element de securite |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1028853A1 EP1028853A1 (fr) | 2000-08-23 |
EP1028853B1 true EP1028853B1 (fr) | 2001-11-21 |
Family
ID=7878843
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99944458A Expired - Lifetime EP1028853B1 (fr) | 1998-08-27 | 1999-08-20 | Feuille d'impression thermosensible comportant des microcapsules sensibles a la pression utilisees comme element de securite |
Country Status (7)
Country | Link |
---|---|
US (1) | US6440898B1 (fr) |
EP (1) | EP1028853B1 (fr) |
JP (1) | JP2002523268A (fr) |
AT (1) | ATE209109T1 (fr) |
DE (2) | DE19838893C2 (fr) |
ES (1) | ES2165240T3 (fr) |
WO (1) | WO2000012321A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10113286A1 (de) | 2001-03-16 | 2002-10-02 | Mitsubishi Hitec Paper Flensbu | Wärmeempfindlicher Aufzeichnungsbogen und seine Verwendung |
FR2827618B1 (fr) * | 2001-07-18 | 2003-10-03 | Banque De France | Procede de securisation de documents |
FR2876714B1 (fr) * | 2004-10-20 | 2008-05-02 | Francois Charles Oberthur Fidu | Procede de securisation de documents de valeur |
DE102008005136A1 (de) * | 2008-01-16 | 2009-07-23 | U-Nica Technology Ag | Dokument sowie Verfahren zur Herstellung eines Dokumentes |
DE102013218754B4 (de) | 2013-09-18 | 2019-05-09 | Bundesdruckerei Gmbh | Manipulationsabgesichertes Wert- oder Sicherheitsprodukt und Verfahren zum Verifizieren der Echtheit des manipulationsabgesicherten Wert- oder Sicherheitsproduktes |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT37053B (de) | 1908-04-24 | 1909-04-26 | Ignatz Dr Palocz | Inhaliervorrichtung. |
JPS60168690A (ja) * | 1984-02-13 | 1985-09-02 | Mitsubishi Paper Mills Ltd | 感圧性を備えた無色の感熱熱転写記録紙 |
FR2566440B1 (fr) * | 1984-06-22 | 1988-07-22 | Jalon Michel | Fibres de securite et autres matieres rendues luminescentes par un procede de teinture, leurs procedes de realisation et leurs applications |
DE3601525A1 (de) | 1985-01-21 | 1986-07-24 | Mitsubishi Paper Mills, Ltd., Tokio/Tokyo | Waermeempfindliches und waermeuebertragbares aufzeichnungsblatt |
JPS62187080A (ja) | 1986-02-13 | 1987-08-15 | Fuji Photo Film Co Ltd | 感熱記録材料 |
JPH0832484B2 (ja) | 1988-11-25 | 1996-03-29 | 富士写真フイルム株式会社 | 多色記録材料 |
US5984363A (en) | 1993-05-03 | 1999-11-16 | The Standard Register Company | Business record having a thermally imagable surface |
US5401060A (en) | 1993-06-14 | 1995-03-28 | Wallace Computer Services, Inc. | Document with heat and pressure sensitive chromogentic composition thereon |
US5395138A (en) * | 1993-06-14 | 1995-03-07 | Wallace Computer Services, Inc. | Security document verification system with pressure-rupturable microcapsules |
DE19501289A1 (de) * | 1995-01-18 | 1996-07-25 | Feldmuehle Ag Stora | Wärmeempfindliches Aufzeichnungsmaterial und seine Verwendung |
JP3614931B2 (ja) * | 1995-05-10 | 2005-01-26 | 三菱製紙株式会社 | 記録シートおよび偽造検知方法 |
-
1998
- 1998-08-27 DE DE19838893A patent/DE19838893C2/de not_active Expired - Fee Related
-
1999
- 1999-08-20 WO PCT/EP1999/006122 patent/WO2000012321A1/fr active IP Right Grant
- 1999-08-20 DE DE59900676T patent/DE59900676D1/de not_active Expired - Lifetime
- 1999-08-20 ES ES99944458T patent/ES2165240T3/es not_active Expired - Lifetime
- 1999-08-20 US US09/530,297 patent/US6440898B1/en not_active Expired - Lifetime
- 1999-08-20 AT AT99944458T patent/ATE209109T1/de not_active IP Right Cessation
- 1999-08-20 JP JP2000567396A patent/JP2002523268A/ja active Pending
- 1999-08-20 EP EP99944458A patent/EP1028853B1/fr not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ES2165240T3 (es) | 2002-03-01 |
EP1028853A1 (fr) | 2000-08-23 |
ATE209109T1 (de) | 2001-12-15 |
DE19838893C2 (de) | 2000-09-28 |
WO2000012321A1 (fr) | 2000-03-09 |
US6440898B1 (en) | 2002-08-27 |
JP2002523268A (ja) | 2002-07-30 |
DE59900676D1 (de) | 2002-02-21 |
DE19838893A1 (de) | 2000-03-09 |
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