EP1027302B1 - Verfahren zum färben von beton mittels kompaktierten anorganischen granulat - Google Patents

Verfahren zum färben von beton mittels kompaktierten anorganischen granulat Download PDF

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Publication number
EP1027302B1
EP1027302B1 EP98938453A EP98938453A EP1027302B1 EP 1027302 B1 EP1027302 B1 EP 1027302B1 EP 98938453 A EP98938453 A EP 98938453A EP 98938453 A EP98938453 A EP 98938453A EP 1027302 B1 EP1027302 B1 EP 1027302B1
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EP
European Patent Office
Prior art keywords
compacted
granules
inorganic granules
inorganic
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP98938453A
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English (en)
French (fr)
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EP1027302A1 (de
EP1027302A4 (de
Inventor
James T. Will
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Elementis Pigments Inc
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Elementis Pigments Inc
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Application filed by Elementis Pigments Inc filed Critical Elementis Pigments Inc
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02—Agglomerated materials, e.g. artificial aggregates

Definitions

  • This invention relates to a method for coloring cementitious systems using compacted inorganic granules, wherein said compacted inorganic granules comprise an inorganic pigment and a dispersing agent.
  • the invention relates to a method for coloring cementitious systems using compacted inorganic granules according to claim 1.
  • Inorganic pigments such as metal oxides, for example, iron oxides, are conventionally used as coloring components in the construction, paint, plastic and other industries. These inorganic pigments are incorporated for coloring into the desired application system such as cementitious systems usually through intensive mixing. Some key performance properties for the pigments are dispersibility of the pigment throughout the application system, the coloring effect associated with the pigment and the ease of handling.
  • the dispersibility is a measure of the ease with which the pigment particles can be uniformly and intimately mixed in the application system. Poor dispersion of the pigment particles can cause large agglomerates of pigment particles which may result in surface imperfections, color streaks, non uniform coloration or incomplete color development within the end product.
  • the color effect is a measure of the degree of coloration measured against a powder pigment standard.
  • the powder pigment standard being defined as the color effect achieved in the application system using a crude inorganic pigment alone, wherein the crude inorganic pigment is the inorganic pigment incorporated into the compacted iron oxide pigments of the invention.
  • an equal quantity of crude inorganic pigment in powder form and product compacted iron oxide pigment would be dispersed into two separate but equal volumes of concrete.
  • the color effect achieved using the crude inorganic pigment powder represents the benchmark standard to which the product compacted pigment/concrete system is compared.
  • the ease of handling takes into consideration difficulty associated with storing, transporting and mixing of the pigments in the application system.
  • the mechanical stability of the pigments or granules is responsible for good storage, transporting and dosing of the granules into a cementitious system. Mechanical stability is brought about by high adhesive forces within the individual granules and depends on the compaction pressure used in forming the granules. It should be noted that the goals of achieving good dispersibility and good mechanical stability are counter to one another.
  • a method for coloring cementitious systems comprising: dispersing compacted inorganic granules in the cementitious system; wherein said compacted inorganic granules comprise an inorganic pigment and a dispersing agent; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing at least one inorganic pigment and at least one dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the milled compacted mixture into at least three streams, namely at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules.
  • It is another object of the invention to provide a method for coloring concrete comprising: (a) providing compacted inorganic granules, wherein said compacted inorganic granules are produced by a process consisting of: (a.1) mixing at least one inorganic pigment and at least one dispersing agent, (a.2) compacting the mixture, (a.3) milling the compacted mixture, and (a.4) classifying the milled compacted mixture into at least three streams, namely at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; (b) mixing said compacted inorganic granules with concrete at conditions sufficient to form a homogeneous dispersal of said compacted inorganic granules in the concrete; and, (c) allowing the mixture to set; wherein the coloring effect of the compacted inorganic granules in the concrete equals or exceeds the powder standard.
  • compacted inorganic granules comprising: an inorganic pigment and a dispersing agent; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing at least one inorganic pigment and at least one dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the milled compacted mixture into at least three streams, namely at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules.
  • the invention recognizes that the particle size of the compacted inorganic granules and the compressive force used to compact the granules affect the dispersibility and coloring affect of the granules in the cementitious system to which the granules are added.
  • the invention is briefly, a method for coloring a cementitious system, comprising: dispersing compacted inorganic granules in the cementitious system; wherein said compacted inorganic granules comprise at least one inorganic pigment and at least one dispersing agent; wherein said compacted inorganic granules are produced by a process consisting of: (a) mixing the at least one inorganic pigment and the at least one dispersing agent, (b) compacting the mixture, (c) milling the compacted mixture, and (d) classifying the milled compacted mixture into at least three streams, namely at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; and, wherein the coloring effect of the compacted inorganic granules in the cementitious system equals or exceeds the powder standard.
  • the compacted inorganic granules of the invention may be dispersed in a cementitious system using well known processing techniques.
  • the at least one inorganic pigment used to produce the compacted inorganic granules may be selected from the group comprising all pigments as per ASTM C979-82; preferably iron oxides, chrome oxides, cobalt blues, mixed metal oxides, carbon blacks, titanium oxides and mixtures thereof; most preferably iron oxide.
  • the at least one dispersing agent used to produce the compacted inorganic granules may be selected from the group comprising all chemicals known as plasticizers and superplasticizers as per Ramachandran, Concrete Admixtures Handbook (Noyes 1984); perferably stearates, acetates, alkylphenols, cellulosics, lignins, acrylics, epoxies, urethanes, sulfates, phosphates, formaldehyde condensates, silicates, silanes, siloxanes, titanates and mixtures thereof; most preferably lignin sulphonate.
  • the dispersing agent should be added in sufficient quantity to provide compacted inorganic granules comprising between 0.5 to 10 wt% dispersing agent; preferably between 2 to 5 wt% dispersing agent; most preferably when the dispersing agent is lignin sulphonate, about 3 wt% dispersing agent.
  • the at least one inorganic pigment and at least one dispersing agent are mixed using well known techniques.
  • the components may be mixed using a continuous turbulizer with volumetric feeders attached for each component.
  • the components may be mixed in a thirty gallon ribbon blender for 20 to 30 minutes at about 50 revolutions per minute.
  • the components could also be mixed in a 10-20,000 pound drum blender for 10 to 20 hours at 2 to 5 revolutions per minute.
  • the mixture of at least one inorganic pigment and at least one dispersing agent may be compacted using known compaction techniques.
  • the components may be compacted using a Hosokawa Bepex MS-60 compactor.
  • the compaction force used to form the compacted inorganic granules should be in the range from 500 to 1,700 psi; preferably, the compaction force should be in the range from 500 to 700 psi.
  • the gap size between the rollers should be about 0.04" and the roller speed should be about 5.5 to 12.5 revolutions per minute.
  • the compaction force used should be such that the coloring effect of the product compacted inorganic granules in a cementitious system exceeds the powder standard.
  • the material discharged from the milling step preferably has a particle size distribution between 12 to 400 mesh with a yield of about 40% having a particle size between 30 to 80 mesh.
  • the compacted material discharged from the milling step is classified according to size using known techniques. For example, the compacted material may be classified using a screener (i.e., Kason Screener K48-2-CS) with a top 30 mesh screen and a bottom 80 mesh screen with both clearing rings and a sweep brush.
  • a screener i.e., Kason Screener K48-2-CS
  • the classified material may be separated into at least three streams.
  • the classified material is separated into at least one undersize material stream containing those granules having a particle size below 80 mesh; at least one oversize material stream containing those granules having a particle size above 30 mesh; and at least one product stream containing those granules having a particle size between 30 to 80 mesh.
  • the undersize material in the at least one undersize material stream may preferably be recycled back to the process wherein the at least one inorganic pigment and at least one dispersing agent are mixed.
  • the oversize material in the at least one oversize material stream may preferably be regranulated and classified with any oversize material regranulated, any undersize material may be recycled back to the mixing step, and the remaining material may be combined with the at least one product stream.
  • the compacted inorganic granules used in the method of the invention should be essentially water free. Particularly, the compacted inorganic granules used preferably should contain less than 0.3 wt% water.
  • the invention resides in a method for coloring concrete, comprising: (a) providing compacted inorganic granules, wherein said compacted inorganic granules are produced by a process consisting of: (a.1) mixing an inorganic pigment and a dispersing agent, (a.2) compacting the mixture, (a.3) milling the compacted mixture, and (a.4) classifying the milled compacted mixture into at least three streams, namely at least one oversize material stream, at least one undersize material stream and at least one product stream of compacted inorganic granules; (b) mixing said compacted inorganic granules with concrete at conditions sufficient to form a homogeneous dispersal of said compacted inorganic granules in the concrete; and, (c) allowing the mixture to set; wherein the coloring effect of the compacted inorganic granules in the concrete equals or exceeds the powder standard.
  • compacted inorganic granules were produced according to the invention. Comparative testing was conducted to demonstrate the improved dispersion and coloring properties of the compacted inorganic granules compared with a powder standard.
  • Two K-tron volumetric feeders were set to feed a TCJS-8 Turbulizer.
  • the feeders were pre-set to yield a mix of 97% red iron oxide (RB-4097) and 3 % lignosulfonate (823 Lignosite).
  • the turbulizer speed was set at 2500 revolutions per minute and the discharges were directed into a high force feed screw running at 70 revolutions per minute.
  • the discharge from the screw was feed to a MS-60 roll compactor set up having a 0.04" gap, an 18 amp load, and a 900 psi compaction force.
  • the throughput rate was 900 lb./hr.
  • the compacted material discharged from the roll compactor was in the form of compacted sticks which were subsequently milled in a Disintegrator mill model #RD-8-P32 running at 1000 revolutions per minute with 22 hammers and a 0.085" screen.
  • the output from the mill was feed to a Kason screener model #K48-2-CS with 30 mesh top screen and an 80 mesh bottom screen with an operational sweep brush.
  • 43.43% was product material having a particle size between 30 and 80 mesh.
  • the 30 to 80 mesh product compacted inorganic granules collected off the screener were mixed in a concrete system and its coloring effect was compared to that of a powder standard. Specifically, the product compacted inorganic granules were mixed in a concrete system using the following procedure:
  • a batch ribbon blender model #IM-16 was charged with 48.5 lbs. of yellow iron oxide (YO-2087) and 1.5 lbs. of lignosulfonate (823 Lignosite). The constituents were mixed for 30 minutes. The resultant mixture was fed into an MS-60 compactor set up with a stick roll surface having a 0.04" gap, a stick roll rate of 5.5 revolutions per minute, an 18 amp load, with a compaction force of 1,000 psi and with a vacuum system engaged. The output from the blender was fed into a high compression screw feeder set at 75 rpm and 5.5 amps at no load. The throughput through the screw feeder was 1,500 lbs./hr.
  • the screw feeder discharged into an RD-8 granulator set at 750 rpm having 22 hammers and a 0.85" screen.
  • the granulated material was feed to a Kason screener having a 30 mesh top and a 50 mesh screen bottom and both a sweep brush and clean rings operating.
  • 29.2% was product material having a particle size between 30 and 50 mesh.
  • the 30 to 50 mesh product compacted inorganic granules collected off the screener were mixed in concrete system and its coloring effect was compared to that of a powder standard. Specifically, the product compacted inorganic granules were mixed in a concrete system using the following procedure:

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Road Paving Structures (AREA)

Claims (9)

  1. Verfahren zur Färbung eines zementartigen Systems, umfassend: Dispergieren von kompaktierten anorganischen Granulaten in dem zementartigen System, wobei die kompaktierten anorganischen Granulate ein anorganisches Pigment und ein dispergierendes Mittel umfassen; wobei die kompaktierten anorganischen Granulate erhältlich sind durch ein Verfahren, umfassend:
    (a) Mischen eines anorganischen Pigments und eines dispergierenden Mittels,
    (b) Kompaktieren des Gemisches,
    (c) Mahlen des kompaktierten Gemisches, und
    (d) Klassifizieren des gemahlenen kompaktierten Gemisches in mindestens drei Ströme, nämlich mindestens einen übergroßen Materialstrom, mindestens einen untergroßen Materialstrom und mindestens einen Produktstrom von kompaktierten anorganischen Granulaten,
    dadurch gekennzeichnet, daß
    die kompaktierten anorganischen Granulate in dem mindestens einen Produktstrom in einer Größenordnung von zwischen 30 und 80 Mesh liegen, zwischen 0,5 bis 10 Gewichtsprozent Dispersionsmittel enthalten und weniger als 0,3 Gewichtsprozent Wasser, wobei das Gemisch in Schritt (b) mit einer Kompaktierkraft im Bereich von 34,5 bis 48,3 Bar (500 bis 700 psi) kompaktiert wurde, und wobei der färbende Effekt der kompaktierten anorganischen Granulate in dem zementartigen System den Pulverstandard übersteigt.
  2. Verfahren nach Anspruch 1, wobei das anorganische Pigment ausgewählt ist aus der Gruppe umfassend Eisenoxide, Chromoxide, Kobaltblau-Pigmente, gemischte Metalloxide, Carbonschwarz-Pigmente, Titanoxide und Gemischen davon.
  3. Verfahren nach Anspruch 1 oder 2, wobei das dispergierende Mittel ausgewählt ist aus der Gruppe umfassend Stearate, Azetate, Alkylphenole, Cellulosika, Lignine, Acryle, Epoxies, Urethane, Sulfate, Phosphate, Formaldehydkondensate, Silicate, Silane, Siloxane, Titanate und Gemischen davon und bevorzugterweise Ligninsulphanat ist.
  4. Verfahren nach einem der voranstehenden Ansprüche, wobei die kompaktierten anorganischen Granulate in dem mindestens einen Produktstrom zwischen 30 und 50 Mesh in der Größe sind.
  5. Verfahren nach einem der voranstehenden Ansprüche, wobei die kompaktierten anorganischen Granulate in dem mindestens einen Untergrößen-Materialstrom zu (a) zurückgeführt werden, wo sie mit anorganischem Pigment und Dispersionsmittel gemischt werden und kommpaktiert werden.
  6. Verfahren nach einem der voranstehenden Ansprüche, wobei die kompaktierten anorganischen Granulate in dem mindestens einen Übergrößen-Materialstrom re-granuliert werden.
  7. Verfahren nach Anspruch 6, wobei das re-granulierte Material eine Partikelgröße zwischen 30 und 80 Mesh, bevorzugterweise zwischen 30 und 50 Mesh aufweist.
  8. Verfahren nach Anspruch 6 oder 7, wobei das re-granulierte Material mit den kompaktierten anorganischen Granulaten in dem mindestens einem Produktstrom gemischt wird.
  9. Verfahren nach einem der voranstehenden Ansprüche, wobei die kompaktierten anorganischen Granulate mit Beton unter Bedingungen gemischt werden, die ausreichend sind, um eine homogene Dispersion von den kompaktierten anorganischen Granulaten in dem Beton zu bilden; und wobei es dem Gemisch ermöglicht wird, abzubilden.
EP98938453A 1997-08-11 1998-08-07 Verfahren zum färben von beton mittels kompaktierten anorganischen granulat Expired - Lifetime EP1027302B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US909156 1978-05-24
US08/909,156 US5853476A (en) 1997-08-11 1997-08-11 Process for coloring concrete using compacted inorganic granules
PCT/US1998/016483 WO1999007646A1 (en) 1997-08-11 1998-08-07 Process for coloring concrete using compacted inorganic granules

Publications (3)

Publication Number Publication Date
EP1027302A1 EP1027302A1 (de) 2000-08-16
EP1027302A4 EP1027302A4 (de) 2002-07-24
EP1027302B1 true EP1027302B1 (de) 2005-03-23

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EP98938453A Expired - Lifetime EP1027302B1 (de) 1997-08-11 1998-08-07 Verfahren zum färben von beton mittels kompaktierten anorganischen granulat

Country Status (9)

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US (1) US5853476A (de)
EP (1) EP1027302B1 (de)
CN (1) CN1199902C (de)
AU (1) AU733152B2 (de)
CA (1) CA2301268C (de)
DE (1) DE69829499T2 (de)
DK (1) DK1027302T3 (de)
ES (1) ES2241155T3 (de)
WO (1) WO1999007646A1 (de)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1754755A2 (de) 2005-07-27 2007-02-21 Lanxess Deutschland GmbH Pigment-Hilfsmittel-Kombination mit verbesserten Farbeigenschaften
DE102009006342A1 (de) 2009-01-27 2010-07-29 Hoyer, Manfred Gefärbte Steine und Verfahren zur Herstellung

Also Published As

Publication number Publication date
US5853476A (en) 1998-12-29
WO1999007646A1 (en) 1999-02-18
CN1199902C (zh) 2005-05-04
AU8697798A (en) 1999-03-01
AU733152B2 (en) 2001-05-10
ES2241155T3 (es) 2005-10-16
DK1027302T3 (da) 2005-07-11
DE69829499D1 (de) 2005-04-28
CA2301268A1 (en) 1999-02-18
EP1027302A1 (de) 2000-08-16
CA2301268C (en) 2007-11-20
DE69829499T2 (de) 2006-02-09
EP1027302A4 (de) 2002-07-24
CN1266415A (zh) 2000-09-13

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