EP0972823B1 - Compositions détergents liquides, non aqueuses contenant un agent de blanchiment - Google Patents
Compositions détergents liquides, non aqueuses contenant un agent de blanchiment Download PDFInfo
- Publication number
- EP0972823B1 EP0972823B1 EP99113021A EP99113021A EP0972823B1 EP 0972823 B1 EP0972823 B1 EP 0972823B1 EP 99113021 A EP99113021 A EP 99113021A EP 99113021 A EP99113021 A EP 99113021A EP 0972823 B1 EP0972823 B1 EP 0972823B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alkyl
- group
- nonaqueous liquid
- agents
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 46
- 239000007788 liquid Substances 0.000 title claims abstract description 40
- 239000003599 detergent Substances 0.000 title claims abstract description 28
- -1 quaternary ammonium cations Chemical class 0.000 claims abstract description 45
- 239000000203 mixture Substances 0.000 claims abstract description 35
- 239000003381 stabilizer Substances 0.000 claims abstract description 35
- 125000002091 cationic group Chemical group 0.000 claims abstract description 24
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 18
- 150000001875 compounds Chemical class 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 238000005406 washing Methods 0.000 claims description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 150000004665 fatty acids Chemical class 0.000 claims description 16
- 239000000126 substance Substances 0.000 claims description 14
- 239000012190 activator Substances 0.000 claims description 12
- 150000001298 alcohols Chemical class 0.000 claims description 12
- 239000003205 fragrance Substances 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 11
- 150000004760 silicates Chemical class 0.000 claims description 11
- 102000004190 Enzymes Human genes 0.000 claims description 8
- 108090000790 Enzymes Proteins 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 6
- 239000002304 perfume Substances 0.000 claims description 6
- 239000000344 soap Substances 0.000 claims description 6
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 239000000969 carrier Substances 0.000 claims description 3
- 150000001767 cationic compounds Chemical class 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000007850 fluorescent dye Substances 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- 238000012546 transfer Methods 0.000 claims description 2
- 125000006727 (C1-C6) alkenyl group Chemical group 0.000 claims 2
- 125000006577 C1-C6 hydroxyalkyl group Chemical group 0.000 claims 2
- 239000004606 Fillers/Extenders Substances 0.000 claims 1
- 230000000087 stabilizing effect Effects 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 abstract description 10
- 125000003342 alkenyl group Chemical group 0.000 abstract description 9
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 150000002191 fatty alcohols Chemical class 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- 239000010457 zeolite Substances 0.000 description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- 239000002253 acid Substances 0.000 description 10
- 229910021536 Zeolite Inorganic materials 0.000 description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 108091005804 Peptidases Proteins 0.000 description 8
- 239000004365 Protease Substances 0.000 description 8
- 239000012459 cleaning agent Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229940088598 enzyme Drugs 0.000 description 7
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- 239000008139 complexing agent Substances 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- 102000004882 Lipase Human genes 0.000 description 5
- 108090001060 Lipase Proteins 0.000 description 5
- 239000004367 Lipase Substances 0.000 description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
- 150000002148 esters Chemical class 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 235000019421 lipase Nutrition 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000011837 pasties Nutrition 0.000 description 5
- 235000019419 proteases Nutrition 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 108010059892 Cellulase Proteins 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 235000006708 antioxidants Nutrition 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 229940106157 cellulase Drugs 0.000 description 4
- 235000015165 citric acid Nutrition 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- 102000013142 Amylases Human genes 0.000 description 3
- 108010065511 Amylases Proteins 0.000 description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 3
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 102000035195 Peptidases Human genes 0.000 description 3
- 239000004115 Sodium Silicate Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 235000019418 amylase Nutrition 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- 239000004305 biphenyl Substances 0.000 description 3
- 125000006267 biphenyl group Chemical group 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000002274 desiccant Substances 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- 230000032050 esterification Effects 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 235000019351 sodium silicates Nutrition 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 3
- 238000011105 stabilization Methods 0.000 description 3
- 238000006277 sulfonation reaction Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- ZGZHWIAQICBGKN-UHFFFAOYSA-N 1-nonanoylpyrrolidine-2,5-dione Chemical compound CCCCCCCCC(=O)N1C(=O)CCC1=O ZGZHWIAQICBGKN-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
- 235000021357 Behenic acid Nutrition 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 2
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- BTJXBZZBBNNTOV-UHFFFAOYSA-N Linalyl benzoate Chemical compound CC(C)=CCCC(C)(C=C)OC(=O)C1=CC=CC=C1 BTJXBZZBBNNTOV-UHFFFAOYSA-N 0.000 description 2
- 239000004435 Oxo alcohol Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 240000007313 Tilia cordata Species 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 239000003125 aqueous solvent Substances 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 229940116226 behenic acid Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920003086 cellulose ether Polymers 0.000 description 2
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000005956 quaternization reaction Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000006268 reductive amination reaction Methods 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 229910052707 ruthenium Inorganic materials 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000001509 sodium citrate Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- RUVINXPYWBROJD-ONEGZZNKSA-N trans-anethole Chemical compound COC1=CC=C(\C=C\C)C=C1 RUVINXPYWBROJD-ONEGZZNKSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- FFLHFURRPPIZTQ-UHFFFAOYSA-N (5-acetyloxy-2,5-dihydrofuran-2-yl) acetate Chemical compound CC(=O)OC1OC(OC(C)=O)C=C1 FFLHFURRPPIZTQ-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- YYMCVDNIIFNDJK-XFQWXJFMSA-N (z)-1-(3-fluorophenyl)-n-[(z)-(3-fluorophenyl)methylideneamino]methanimine Chemical compound FC1=CC=CC(\C=N/N=C\C=2C=C(F)C=CC=2)=C1 YYMCVDNIIFNDJK-XFQWXJFMSA-N 0.000 description 1
- LYPVKWMHGFMDPD-UHFFFAOYSA-N 1,5-diacetyl-1,3,5-triazinane-2,4-dione Chemical compound CC(=O)N1CN(C(C)=O)C(=O)NC1=O LYPVKWMHGFMDPD-UHFFFAOYSA-N 0.000 description 1
- WCIQNYOXLZQQMU-UHFFFAOYSA-N 1-Phenylethyl propanoate Chemical compound CCC(=O)OC(C)C1=CC=CC=C1 WCIQNYOXLZQQMU-UHFFFAOYSA-N 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N 1-Tetradecanol Natural products CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
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- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- RUVINXPYWBROJD-UHFFFAOYSA-N para-methoxyphenyl Natural products COC1=CC=C(C=CC)C=C1 RUVINXPYWBROJD-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- PATMLLNMTPIUSY-UHFFFAOYSA-N phenoxysulfonyl 7-methyloctanoate Chemical compound CC(C)CCCCCC(=O)OS(=O)(=O)OC1=CC=CC=C1 PATMLLNMTPIUSY-UHFFFAOYSA-N 0.000 description 1
- 229940067107 phenylethyl alcohol Drugs 0.000 description 1
- 150000003003 phosphines Chemical class 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000010670 sage oil Substances 0.000 description 1
- 239000010671 sandalwood oil Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 150000003336 secondary aromatic amines Chemical class 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003470 sulfuric acid monoesters Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 229940116411 terpineol Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 150000003626 triacylglycerols Chemical class 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 229940038773 trisodium citrate Drugs 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 239000010679 vetiver oil Substances 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Definitions
- the present invention relates to non-aqueous, liquid detergents for washing or cleaning, which contain non-ionic surfactant (s), builders (s) and bleach and one have increased bleach stability. Another aspect of the invention relates to Use of special stabilizers to stabilize bleach in non-aqueous liquid washing and / or cleaning agents.
- EP 340 989 proposes to use C 5-21 fatty acids, fatty acid salts or fatty acid glyceryl mono- or diesters as stabilizers in non-aqueous liquid detergents which contain bleaching agents and bleach activators.
- the use of vicinal hydroxy compounds for this purpose is disclosed in EP 344 909 (Colgate).
- WO93 / 06201 (Henkel) describes a non-aqueous, liquid to pasty washing or cleaning agent containing 5 to 20% by weight of hydrated zeolite A, 50 to 80% by weight of anionic and / or nonionic surfactant, 5 to 20% by weight. -% bleach, up to 6% by weight of bleach activator and up to 6% by weight of a complexing agent for heavy metals.
- WO96 / 10072 discloses a process for producing non-aqueous bleach-containing liquid detergents which have high chemical and physical stability and outstanding washing and bleaching results by suspending fine-grain detergent components in a non-aqueous liquid matrix made from alcohol ethoxylates.
- the present invention was based on the object of containing a stable bleach to provide liquid detergents and cleaners which are solid Contains bleach in the form of a stable dispersion.
- the bleaches are not supposed to Loss of activity, even if the funds are stored for a longer period become.
- non-aqueous includes means understand that only small amounts of free, so not as crystal water or in any other Way bound to contain water. Because even non-aqueous solvents and raw materials (especially such technical qualities) have certain water contents completely water-free agents on an industrial scale only with great effort and high cost to manufacture.
- non-aqueous agents of the present invention thus small amounts of free water tolerable, preferably less than 5% by weight below 2% by weight, based in each case on the finished composition.
- the liquid agents of the present invention can be used within a wide range of viscosities getting produced. So not only are viscous and easily movable according to the invention Medium can be produced, but also viscous to pasty medium higher viscosities. The consistency of the pasty agents can also be spreadable or be able to cut - the use of cationic stabilizers also leads to such agents to the effects of bleach stabilization according to the invention.
- the cationic stabilizing agents can be used in varying amounts in the inventive Funds are brought in.
- the content of the invention Agents of cationic stabilizers of the formulas mentioned 0.5 to 10 % By weight, preferably 1 to 6% by weight and in particular 2 to 4% by weight.
- Cationic stabilizers which are to be used preferentially are caused by the esterification obtained from triethanolamine with long-chain fatty acids and subsequent quaternization. Both the esterification and the quaternization take place in a manner known per se Manner, wherein the use of dimethyl sulfate as the quaternizing reagent is preferred is.
- Preferred agents contain one as a cationic stabilizing agent quaternized triethanolamine ester.
- Such cationic stabilizers are commercially available, for example, under the names Stepantex® VA 90, Stepantex® VS 90 (trademark of Stepan) or Dehyquart® AU 46 or Dehyquart® AU 57 (trademark of Henkel / Pulcra).
- the cationic stabilizers to be used according to the invention can be used alone or in combination with other stabilizing agents known from the prior art can be used together.
- the stabilizing agents described in the prior art can be divided into three large groups: antioxidants, drying agents and complexing agents.
- Phenols, bisphenols and thiobisphenols substituted by sterically hindered groups can be used as antioxidants.
- Other substance classes are aromatic amines, preferably secondary aromatic amines and substituted p-phenylenediamines, phosphorus compounds with trivalent phosphorus such as phosphines, phosphites and phosphonites, compounds containing endiol groups, so-called reductones, such as ascorbic acid and its derivatives, organosulfur compounds, such as the esters of 3 , 3'-thiodipropionic acid with C 1-18 alkanols, in particular C 10-18 alkanols, metal ion deactivators which are able to complex the metal ions catalyzing the autooxidation, such as copper, such as EDTA, nitrilotriacetic acid, etc and their mixtures.
- a large number of examples of such antioxidants is summarized in DE 196 16 570 (BASF AG) - the antioxidants
- Desiccants in the context of the present invention in combination with cationic Stabilizers can be used, for example, inorganic Salts that are capable of hydrate formation and thereby bind free water.
- exemplary anhydrous magnesium or sodium sulfate may be mentioned here.
- over-dried Silicates and aluminum silicates such as aerogels or over-dried zeolites belong to this connection class.
- organic ones can also be used
- Use desiccants examples of which are substances that absorb water swell and the absorbed water under the conditions in the non-aqueous Do not dispense liquid washing or cleaning agents. For example, fall into this class Cellulose and starch and their derivatives such as carboxymethyl cellulose and starch, hydroxypropyl cellulose and starch, etc.
- alkali metal salts of ethylenediaminetetraacetic acid fall into the group of complexing agents (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polyacrylates, polymaleates and polysulfonates.
- EDTA complexing agents
- NTA nitrilotriacetic acid
- anionic polyelectrolytes such as polyacrylates, polymaleates and polysulfonates.
- Farther are low molecular weight hydroxycarboxylic acids such as citric acid, tartaric acid, malic acid or gluconic acid and its salts.
- Suitable complexing agents can also be selected from organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), Aminotri (methylenephosphonic acid) (ATMP), Diethylenetriaminepenta (methylenephosphonic acid) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM). These complexing agents can be used, for example, in amounts between 0.1 and 5% by weight, preferably in amounts of around 1% by weight, in the agents according to the invention be introduced.
- organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), Aminotri (methylenephosphonic acid) (ATMP), Diethylenetriaminepenta (methylenephosphonic acid) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM).
- organophosphonates such as 1-hydroxyethane-1,1-diphosphonic acid (HEDP), Aminotri (methylenephosphonic acid) (ATMP
- the agents according to the invention contain one or more nonionic surfactant (s) as an essential component.
- the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or can contain linear and methyl-branched radicals in the mixture, as are usually present in oxo alcohol radicals.
- EO ethylene oxide
- alcohol ethoxylates with linear residues of alcohols of native origin with 12 to 18 carbon atoms for example from coconut, palm, tallow fat or oleyl alcohol, and an average of 2 to 8 EO per mole of alcohol are particularly preferred.
- the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 3 EO or 4 EO, C 9-11 alcohol with 7 EO, C 13-15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18 alcohols with 3 EO, 5 EO or 7 EO and mixtures thereof, such as mixtures of C 12-14 alcohol with 3 EO and C 12-18 alcohol with 5 EO.
- the degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product.
- Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
- fatty alcohols with more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
- alkyl glycosides of the general formula RO (G) x can also be used as further nonionic surfactants, in which R denotes a primary straight-chain or methyl-branched, in particular methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18, C atoms and G is the symbol which stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
- the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; x is preferably 1.2 to 1.4.
- nonionic surfactants which are used either as the sole nonionic surfactant or in combination with other nonionic surfactants, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably with 1 to 4 carbon atoms in the alkyl chain, in particular fatty acid methyl esters, such as them are described, for example, in Japanese patent application JP 58/217598 or which are preferably produced by the process described in international patent application WO-A-90/13533 .
- nonionic surfactants of the amine oxide type for example N-cocoalkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides can be suitable.
- the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half of it.
- Suitable surfactants are polyhydroxy fatty acid amides of the formula (IV), in which RCO stands for an aliphatic acyl radical with 6 to 22 carbon atoms, R 5 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms and [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
- the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
- the group of polyhydroxy fatty acid amides also includes compounds of the formula (V) in which R represents a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R 6 represents a linear, branched or cyclic alkyl radical or an aryl radical having 2 to 8 carbon atoms and R 7 represents a linear, branched or cyclic alkyl radical or an aryl radical or an oxyalkyl radical having 1 to 8 carbon atoms, C 1-4 -alkyl or phenyl radicals being preferred and [Z] being a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this remainder.
- V formula (V) in which R represents a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms, R 6 represents a linear, branched or cyclic alkyl radical
- [Z] is preferably obtained by reductive amination of a reduced sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
- a reduced sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
- the N-alkoxy- or N-aryloxy-substituted compounds can then, for example according to the teaching of international application WO-A-95/ 07331, be converted into the desired polyhydroxy fatty acid amides by reaction with fatty acid methyl esters in the presence of an alkoxide as catalyst.
- non-aqueous liquid detergents are preferred the 5 to 70% by weight, preferably 15 to 65% by weight and in particular 20 to 60% by weight one or more nonionic surfactants from the group of the alkoxylated, preferably ethoxylated or ethoxylated and propoxylated, alcohols and / or carboxylic acids with 8 to 28, preferably 10 to 20 and in particular 12 to 18 carbon atoms, contain.
- the agents according to the invention can contain anionic surfactants.
- Anionic surfactants used are, for example, those of the sulfonate and sulfate type.
- the surfactants of the sulfonate type are preferably C 9-13- alkylbenzenesulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkanesulfonates and disulfonates such as are obtained, for example, from C 12-18 monoolefins with a terminal or internal double bond by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products.
- alkanesulfonates obtained from C 12-18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
- the esters of ⁇ -sulfofatty acids for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids, are also suitable.
- Suitable anionic surfactants are sulfonated fatty acid glycerol esters.
- fatty acid glycerol esters the mono-, di- and triesters and their mixtures are to be understood as they in the production by esterification of a monoglycerin with 1 to 3 moles of fatty acid or obtained in the transesterification of triglycerides with 0.3 to 2 mol of glycerol.
- Preferred sulfonated fatty acid glycerol esters are the sulfonation products of saturated Fatty acids with 6 to 22 carbon atoms, for example caproic acid, caprylic acid, Capric acid, myristic acid, lauric acid, palmitic acid, stearic acid or behenic acid.
- alk (en) yl sulfates are the alkali and especially the sodium salts of the sulfuric acid half esters of C 12 -C 18 fatty alcohols, for example from coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxo alcohols and those half-esters of secondary alcohols of this chain length are preferred. Also preferred are alk (en) yl sulfates of the chain length mentioned, which contain a synthetic, petrochemical-based straight-chain alkyl radical which have a degradation behavior analogous to that of the adequate compounds based on oleochemical raw materials.
- C 12 -C 16 alkyl sulfates and C 12 -C 15 alkyl sulfates as well as C 14 -C 15 alkyl sulfates are preferred from the point of view of washing technology.
- 2,3-Alkyl sulfates which are produced, for example, according to US Pat. Nos. 3,234,258 or 5,075,041 and can be obtained as commercial products from the Shell Oil Company under the name DAN®, are also suitable anionic surfactants.
- the sulfuric acid monoesters of the straight-chain or branched C 7-21 alcohols ethoxylated with 1 to 6 mol of ethylene oxide such as 2-methyl-branched C 9-11 alcohols with an average of 3.5 mol of ethylene oxide (EO) or C 12-18 - Fatty alcohols with 1 to 4 EO are suitable. Because of their high foaming behavior, they are used in cleaning agents only in relatively small amounts, for example in amounts of 1 to 5% by weight.
- Suitable anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters and which are monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably fatty alcohols and especially ethoxylated fatty alcohols.
- alcohols preferably fatty alcohols and especially ethoxylated fatty alcohols.
- Preferred sulfosuccinates contain C 8-18 fatty alcohol residues or mixtures thereof.
- Particularly preferred sulfosuccinates contain a fatty alcohol residue, which is derived from ethoxylated fatty alcohols, which in themselves are nonionic surfactants (description see below).
- sulfosuccinates the fatty alcohol residues of which are derived from ethoxylated fatty alcohols with a narrow homolog distribution, are particularly preferred. It is also possible to use alk (en) ylsuccinic acid with preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
- Soaps are particularly suitable as further anionic surfactants.
- saturated fatty acid soaps such as the salts of lauric acid, myristic acid, palmitic acid, Stearic acid, hydrogenated erucic acid and behenic acid and in particular from natural Fatty acids, e.g. Coconut, palm kernel or tallow fatty acids, derived soap mixtures.
- the anionic surfactants including the soaps can be in the form of their sodium, potassium or ammonium salts and as soluble salts of organic bases, such as mono- or dioder Triethanolamine.
- the anionic surfactants are preferably in the form their sodium or potassium salts, especially in the form of the sodium salts.
- Preferred liquid detergents additionally contain anionic surfactants, preferably from the group of alkyl sulfates, alkyl sulfonates, alkyl benzene sulfonates and fatty acid soaps.
- non-aqueous liquid builders In addition to surfactant components and the cationic stabilizer the non-aqueous liquid builders according to the invention.
- Builders usually used in detergents and cleaning agents in the washing and Detergent tablets are introduced, in particular thus zeolites, silicates, Carbonates, organic cobuilders and -where no ecological prejudices against theirs Use also - the phosphates.
- Suitable crystalline, layered sodium silicates have the general formula NaMSi x O 2x + 1 .H 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2, 3 or 4.
- M sodium or hydrogen
- x is a number from 1.9 to 4
- y is a number from 0 to 20 and preferred values for x 2, 3 or 4.
- Such crystalline layered silicates are described, for example, in European patent application EP-A-0 164 514 .
- Preferred crystalline layered silicates of the formula given are those in which M represents sodium and x assumes the values 2 or 3.
- both ⁇ - and ⁇ -sodium disilicate Na 2 Si 2 O 5 .yH 2 O are preferred, wherein ⁇ -sodium disilicate can be obtained, for example, by the method described in international patent application WO-A-91/08171 .
- the delay in dissolution compared to conventional amorphous sodium silicates can be caused in various ways, for example by surface treatment, compounding, compacting / compression or by overdrying.
- the term “amorphous” is also understood to mean “X-ray amorphous”.
- silicates in X-ray diffraction experiments do not provide sharp X-ray reflections, as are typical for crystalline substances, but at most one or more maxima of the scattered X-rays, which have a width of several degree units of the diffraction angle.
- it can very well lead to particularly good builder properties if the silicate particles provide washed-out or even sharp diffraction maxima in electron diffraction experiments. This is to be interpreted as meaning that the products have microcrystalline areas of size 10 to a few hundred nm, values up to max. 50 nm and in particular up to max. 20 nm are preferred.
- Such so-called X-ray amorphous silicates which also have a delay in dissolution compared to conventional water glasses, are described, for example, in German patent application DE-A-44 00 024 .
- Compacted / compacted amorphous silicates, compounded amorphous silicates and over-dried X-ray amorphous silicates are particularly preferred.
- the finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P.
- zeolite P zeolite MAP® (commercial product from Crosfield) is particularly preferred.
- zeolite X and mixtures of A, X and / or P are also suitable.
- zeolite X and zeolite A (about 80% by weight of zeolite X)
- VEGOBOND AX® sold by CONDEA Augusta SpA under the brand name VEGOBOND AX® and by the formula nNa 2 O ⁇ (1-n) K 2 O ⁇ Al 2 O 3 ⁇ (2 - 2.5) SiO 2 ⁇ (3.5 - 5.5) H 2 O
- Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution; measurement method: Coulter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22% by weight, of bound water.
- the zeolites can also be used as over-dried zeolites with lower water contents and are then suitable due to their hygroscopicity for removing unwanted traces of free water.
- the sodium salts of the orthophosphates are particularly suitable, the pyrophosphates and especially the tripolyphosphates.
- Useful organic builders are, for example, those in the form of their sodium salts usable polycarboxylic acids, such as citric acid, adipic acid, succinic acid, Glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), if such use is not objectionable for ecological reasons, and Mixtures of these.
- Preferred salts are the salts of polycarboxylic acids such as citric acid, Adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures from these, with sodium citrate being particularly preferred.
- the amount of builders in the agents according to the invention is usually 1 to 30 % By weight, preferably 10 to 25% by weight.
- Preferred non-aqueous liquid detergents contain as builders water-soluble builders, preferably from the group of Oligo- and polycarboxylates, the carbonates and the crystalline and / or amorphous silicates.
- the salts of citric acid have been found to be special proven suitable, the alkali and, in particular, the sodium salts preferred are.
- the non-aqueous liquid detergents for washing or cleaning contain one or more bleaching agents.
- bleaching agents include sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
- Further bleaching agents which can be used are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, phthaloiminoperic acid or diperdodecanedioic acid.
- the amount of bleaching agent in the agents according to the invention is usually above 10% by weight, preferably between 15 and 35% by weight and in particular between 20 and 30% by weight, in each case based on the total agent.
- the agents according to the invention can contain further ingredients of detergents and cleaning agents, for example from the group bleach activators, enzymes, pH regulators, fragrances, perfume carriers, fluorescent agents, Dyes, foam inhibitors, silicone oils, anti-redeposition agents, optical Brighteners, graying inhibitors, color transfer inhibitors and corrosion inhibitors.
- group bleach activators enzymes, pH regulators, fragrances, perfume carriers, fluorescent agents, Dyes, foam inhibitors, silicone oils, anti-redeposition agents, optical Brighteners, graying inhibitors, color transfer inhibitors and corrosion inhibitors.
- bleach activators can be incorporated into the agents according to the invention become.
- bleach activators can be compounds that are under perhydrolysis conditions aliphatic peroxocarboxylic acids with preferably 1 to 10 carbon atoms, in particular 2 to 4 carbon atoms, and / or optionally substituted perbenzoic acid, be used.
- Suitable substances are the O- and / or N-acyl groups of the above C number of carbon atoms and / or optionally substituted benzoyl groups.
- TAED tetraacety
- bleaching catalysts can be incorporated into the agents according to the invention.
- These substances are bleach-enhancing transition metal salts or Transition metal complexes such as Mn, Fe, Co, Ru or Mo salt complexes or carbonyl complexes.
- Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with N-containing tripod ligands and Co, Fe, Cu and Ru amine complexes can be used as bleaching catalysts.
- the content of bleach activators or bleach catalysts in the agents according to the invention can be between 1 and 15% by weight, preferably between 2 and 12% by weight and in particular between 5 and 10% by weight.
- Enzymes come from the class of proteases, lipases, amylases, cellulases or their mixtures in question.
- Bacterial strains or are particularly well suited Mushrooms such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus enzymatic agents.
- Proteases of the subtilisin type and in particular are preferred Proteases obtained from Bacillus lentus are used.
- enzyme mixtures for example from protease and amylase or protease and lipase or Protease and cellulase or from cellulase and lipase or from protease, amylase and Lipase or protease, lipase and cellulase, but in particular mixtures containing cellulase of special interest.
- Peroxidases or oxidases have also been found in some Cases proved to be suitable.
- the enzymes can be adsorbed on carriers and / or embedded in coating substances in order to prevent them from premature decomposition protect.
- the proportion of the enzymes, enzyme mixtures or enzyme granules in the inventive For example, about 0.1 to 10 wt .-%, preferably 0.5 to be about 5% by weight.
- the agents according to the invention can also contain components which positively affect the oil and fat washability from textiles (so-called soil repellents). This effect becomes particularly clear when a textile is soiled previously several times with a detergent according to the invention, the oil and contains fat-dissolving component, was washed.
- nonionic cellulose ethers such as methyl cellulose and methylhydroxy-propyl cellulose with a proportion of methoxyl groups of 15 to 30 wt .-% and of hydroxypropoxyl groups of 1 to 15 wt .-%, each based on the non-ionic cellulose ether, as well as those known from the prior art
- Polymers of phthalic acid and / or terephthalic acid or of their derivatives in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionically and / or nonionically modified derivatives of these.
- the sulfonated derivatives of phthalic and are particularly preferred Terephthalic acid polymers.
- the non-aqueous agents for washing or cleaning can be used as optical brighteners contain the diaminostilbenedisulfonic acid or its alkali metal salts. Suitable are e.g. Salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'disulfonic acid or similarly structured compounds that replace the morpholino group a diethanolamino group, a methylamino group, an anilino group or carry a 2-methoxyethylamino group. Brighteners of the substituted type can also be used Diphenyl styrenes are present, e.g.
- Dyes and fragrances are added to the agents according to the invention in order to improve the aesthetics Improve impression of the products and the consumer in addition to the washing or Cleaning performance a visually and sensory "typical and distinctive" product to provide.
- perfume oils or fragrances individual fragrance compounds, e.g. synthetic products of the ester, ether, aldehyde, ketone type, Alcohols and hydrocarbons can be used. Fragrance compounds of the type the esters are e.g.
- the ethers include, for example, benzyl ethyl ether and the aldehydes e.g.
- the linear alkanals with 8-18 C atoms citral, citronellal, citronellyloxyacetaldehyde, Cyclamenaldehyde, Hydroxycitronellal, Lilial and Bourgeonal
- ketones e.g. the Jonone, ⁇ -isomethyl ionone and methyl cedryl ketone
- Citronellol Citronellol
- eugenol geraniol
- linalool phenylethyl alcohol and terpineol
- perfume oils can also contain natural fragrance mixtures included as they are available from plant sources, e.g. Pine, Citrus, Jasmine, patchouly, rose or ylang-ylang oil. Muscatels are also suitable, Sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, Vetiver oil, olibanum oil, galbanum oil and labdanum oil as well as orange blossom oil, Neroliol, orange peel oil and sandalwood oil.
- the fragrances can be incorporated directly into the agents according to the invention but it can also be advantageous to apply the fragrances to the carrier, which have the liability of the perfume on the laundry and by a slower fragrance release for long-lasting fragrance of the textiles.
- Such carrier materials have, for example Cyclodextrins have proven themselves, with the cyclodextrin-perfume complexes additionally can be coated with other auxiliaries.
- the agents according to the invention can be dyed with suitable dyes.
- Preferred dyes their selection the expert has no difficulty, have a high storage stability and Insensitivity to the other ingredients of the agent and to light as well no pronounced substantivity towards textile fibers in order not to dye them.
- the viscosity of the non-aqueous liquid compositions according to the invention can be adapted to the special requirements of different fields of application. In this way it is possible to formulate viscous and easily movable agents, but also viscous to pasty agents for washing or cleaning, which are known in the market as gels, can be produced. Agents which do not flow under the influence of gravity, that is to say are no longer pourable and have a consistency which can be spread or cut, can also be produced without problems in the context of the present invention.
- T 70 ° C., shear rate: 100 s -1
- a significantly higher viscosity may be indicated - this can lead to dimensionally stable masses in which a viscosity in the above sense can no longer be meaningfully stated .
- the agents according to the invention are produced in a manner known per se Mixing the ingredients in stirred tanks. Unless it's for a specific end product is desired, the solids contained in the agents according to the invention can by be further crushed a wet grinding step to ensure the separation stability of the agents to increase further.
- Such operations familiar to the person skilled in the art are suitable, for example Colloid mills, roller mills or annular gap or agitator ball mills.
- the cationic stabilizing agents to be used according to the invention can be added take place at any point in such a conventional manufacturing process. For example it is possible to coat the bleach with the cationic stabilizers and these coat bleach particles in a stirred tank to the other ingredients to give, whereby here, of course, a grinding step can follow. Also one Add the cationic stabilizing agent as a solid or pasty pure substance or as Solution is easily possible both before and after a grinding step. Usually bleach and bleach activators are not used together before Grinding incorporated into the media because the intimate contact of the substances during the grinding process decomposes them can promote. If the bleach activators are added after a grinding step, the cationic stabilizers can be added in this stirring and homogenization step be, it is of course also possible to use the bleach activators to coat the cationic stabilizers.
- the use of the compounds mentioned leads to liquid agents which have increased bleach stability and which also maintain this property over long storage intervals.
- the isothermal microcalometry has proven to be particularly suitable.
- the heat of the usually exothermic decomposition reaction is also detected very sensitively in small sample quantities.
- the stability compared to the decomposition of a given system the smaller the smaller in one amount of heat produced is in joules for a certain period of time.
- TAM 2277 microcalorimeter was used for the present investigations (Thermometric AB, Sweden). This continuously records the pro Unit of heat generated in a sample in watts.
- the investigated liquid detergent E according to the invention contained a cationic stabilizing agent, while the comparative example V was free of the stabilizing agents used according to the invention. Small amounts of water and Fe (III) ions were added to both formulations in order to simulate realistic conditions (contamination from production plants, etc.).
- the composition of the liquid detergents is shown in Table 1.
- composition of liquid detergents (parts by weight) e V C 12-18 fatty alcohol with 7 EO 50.0 50.0 Sodium perborate monohydrate 20.0 20.0 3,5-di-tert-butyl-4-hydroxytoluene 0.1 0.1 Hydroxyethane-1,1-diphosphonic 0.6 0.6 trisodium citrate 10.0 10.0 C 12-18 fatty acid, Na salt 0.2 0.2 tetraacetylethylenediamine 6.0 6.0 Stepantex® VA 90 2.0 - water 1.0 1.0 Fe 3+ 10 ppm 10 ppm
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (9)
- Agent liquide non aqueux pour le lavage ou le nettoyage, contenant un ou des tensioactifs non ioniques, un ou des builders et un agent de blanchiment, caractérisé en ce qu'il contient, en tant que stabilisant, un ou plusieurs composés cationiques de formule I, II ou III : où chaque groupe R1 est choisi indépendamment parmi les groupes alkyle en C1-6, alcényle en C1-6 ou hydroxyalkyle en C1-6 ; chaque groupe R2 est choisi indépendamment parmi les groupes alkyle en C8-28 ou alcényle en C8-28 ; R3 = R1 ou (CH2)n-T- R2; R4 = R1 ou R2 ou (CH2)n-T- R2 ; T = -O-CO- ou -CO-O- et n est un nombre entier de 0 à 5.
- Agent de lavage liquide non aqueux selon la revendication 1, caractérisé en ce qu'il contient de 0,5 à 10 % en poids, de préférence de 1 à 6 % en poids et en particulier, de 2 à 4 % en poids du stabilisant cationique.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 ou 2, caractérisé en ce que, comme agent stabilisant cationique, on met en oeuvre un ester de triéthanolamine quaternaire.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 à 3, caractérisé en ce que, comme stabilisant cationique, on met en oeuvre un composé de formule I dans laquelle chaque groupe R1 est choisi indépendamment parmi les groupes méthyle, éthyle et 2-hydroxyéthyle ; chaque groupe R2 est choisi indépendamment parmi les groupes alkyle en C8-28 ou alcényle en C8-28, de préférence alkyle en C10-20 ou alcényle en C10-20, et en particulier, alkyle en C12-18 ou alcényle en C12-18, T = -O-CO- et n = 1, 2 ou 3.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 à 4, caractérisé en ce qu'il contient de 5 à 70 % en poids, de préférence de 15 à 65 % en poids et en particulier, de 20 à 60 % en poids d'un ou plusieurs tensioactifs non ioniques, appartenant au groupe constitué par des alcools et/ou acides carboxyliques alcoxylés, de préférence éthoxylés, ou éthoxylés et propoxylés, comprenant de 8 à 28, de préférence de 10 à 20 et en particulier, de 12 à 18 atomes de carbone.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 à 5, caractérisé en ce qu'il contient en outre des tensioactifs anioniques, choisis de préférence dans le groupe constitué par les sulfates d'alkyle, des sulfonates d'alkyle, des benzènesulfonates d'alkyle et des savons d'acides gras.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 à 6, caractérisé en ce que, comme adjuvant, on met en oeuvre des agents de structure hydrosolubles, appartenant de préférence au groupe constitué par des oligo- et polycarboxylates, des carbonates et des silicates cristallins et/ou amorphes.
- Agent de lavage liquide non aqueux selon l'une quelconque des revendications 1 à 7, contenant en outre une ou plusieurs substances appartenant au groupe constitué par des activateurs de blanchiment, des enzymes, des agents d'ajustement du pH, des parfums, des supports de parfum, des agents fluorescents, des colorants, des inhibiteurs de moussage, des huiles de silicone, des agents anti-redéposition, des azurants optiques, des inhibiteurs de grisaille, des inhibiteurs de transfert de coloration et des inhibiteurs de corrosion.
- Utilisation de stabilisants cationiques de formule I, II ou III : où chaque groupe R1 est choisi indépendamment parmi les groupes alkyle en C1-6, alcényle en C1-6 ou hydroxyalkyle en C1-6 ; chaque groupe R2 est choisi indépendamment parmi les groupes alkyle en C8-28 ou alcényle en C8-28 ; R3 = R1 ou (CH2)n-T- R2 ; R4 = R1 ou R2 ou (CH2)n-T- R2 ; T = -O-CO- ou -CO-O- et n est un nombre entier de 0 à 5, pour la stabilisation d'agents de blanchiment dans des agents de lavage liquides non aqueux.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19831702 | 1998-07-15 | ||
DE19831702A DE19831702A1 (de) | 1998-07-15 | 1998-07-15 | Nichtwäßrige Flüssigwaschmittel mit Bleiche |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0972823A1 EP0972823A1 (fr) | 2000-01-19 |
EP0972823B1 true EP0972823B1 (fr) | 2004-09-22 |
Family
ID=7874101
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99113021A Expired - Lifetime EP0972823B1 (fr) | 1998-07-15 | 1999-07-06 | Compositions détergents liquides, non aqueuses contenant un agent de blanchiment |
Country Status (4)
Country | Link |
---|---|
US (1) | US6372703B1 (fr) |
EP (1) | EP0972823B1 (fr) |
AT (1) | ATE277164T1 (fr) |
DE (2) | DE19831702A1 (fr) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6683036B2 (en) * | 2000-07-19 | 2004-01-27 | The Procter & Gamble Company | Cleaning composition |
GB0021182D0 (en) * | 2000-08-29 | 2000-10-18 | Unilever Plc | Cleaning aid |
DE10257389A1 (de) * | 2002-12-06 | 2004-06-24 | Henkel Kgaa | Flüssiges saures Waschmittel |
DE10313457A1 (de) * | 2003-03-25 | 2004-10-14 | Henkel Kgaa | Wasch- oder Reinigungsmittel |
DE10313458A1 (de) * | 2003-03-25 | 2004-11-18 | Henkel Kgaa | Wasch- oder Reinigungsmittel |
DE10313455A1 (de) * | 2003-03-25 | 2004-10-14 | Henkel Kgaa | Wasch- und Reinigungsmittel |
JP2008516105A (ja) * | 2004-10-18 | 2008-05-15 | ザ プロクター アンド ギャンブル カンパニー | 濃縮布地柔軟剤活性物質組成物 |
US20100179368A1 (en) * | 2008-11-07 | 2010-07-15 | Aries Associates, Inc. | Novel Chemistries, Solutions, and Dispersal Systems for Decontamination of Chemical and Biological Systems |
US9273270B2 (en) | 2014-02-20 | 2016-03-01 | Church & Dwight Co., Inc. | Unit dose cleaning products for delivering a peroxide-containing bleaching agent |
DE102015215039A1 (de) * | 2015-08-06 | 2017-02-09 | Henkel Ag & Co. Kgaa | Wasserarme Mittel für die Textilbehandlung, enthaltend mindestens eine spezielle kationische Verbindung und mindestens ein zusätzliches Tensid |
US10633614B2 (en) * | 2015-11-02 | 2020-04-28 | Vanguard Soap LLC | Natural laundry soaps |
AU2021306216B2 (en) | 2020-07-09 | 2023-12-21 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants |
US12071578B2 (en) | 2020-07-13 | 2024-08-27 | Advansix Resins & Chemicals Llc | Branched amino acid surfactants for electronics products |
CA3185045A1 (fr) | 2020-07-13 | 2022-01-20 | Edward Asirvatham | Tensioactifs d'acides amines ramifies pour encres, peintures et adhesifs |
KR20230051181A (ko) | 2020-07-13 | 2023-04-17 | 어드밴식스 레진즈 앤드 케미컬즈 엘엘씨 | 건강관리 제품에 사용하기 위한 분지형 아미노산 계면활성제 |
CN116194548A (zh) | 2020-07-13 | 2023-05-30 | 艾德凡斯化学公司 | 用于油气开采的支链氨基酸表面活性剂 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58217598A (ja) | 1982-06-10 | 1983-12-17 | 日本油脂株式会社 | 洗剤組成物 |
DE3413571A1 (de) | 1984-04-11 | 1985-10-24 | Hoechst Ag, 6230 Frankfurt | Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung |
US4789496A (en) * | 1985-08-20 | 1988-12-06 | Colgate-Palmolive Company | Built nonaqueous liquid nonionic laundry detergent composition containing |
US4892673A (en) | 1988-05-02 | 1990-01-09 | Colgate-Palmolive Company | Non-aqueous, nonionic heavy duty laundry detergent with improved stability |
US4889652A (en) | 1988-05-02 | 1989-12-26 | Colgate-Palmolive Company | Non-aqueous, nonionic heavy duty laundry detergent with improved stability using microsperes and/or vicinal-hydroxy compounds |
DE3914131A1 (de) | 1989-04-28 | 1990-10-31 | Henkel Kgaa | Verwendung von calcinierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von fettsaeureestern |
YU221490A (sh) | 1989-12-02 | 1993-10-20 | Henkel Kg. | Postupak za hidrotermalnu izradu kristalnog natrijum disilikata |
DE4131906A1 (de) * | 1991-09-25 | 1993-04-01 | Henkel Kgaa | Fluessiges oder pastenfoermiges wasch- oder reinigungsmittel |
WO1995007331A1 (fr) | 1993-09-09 | 1995-03-16 | The Procter & Gamble Company | Detergents liquides comportant des tensioactifs d'amides d'acides gras n-alcoxy ou n-aryloxy polyhydroxy |
DE4400024A1 (de) | 1994-01-03 | 1995-07-06 | Henkel Kgaa | Silikatische Builder und ihre Verwendung in Wasch- und Reinigungsmitteln sowie Mehrstoffgemische für den Einsatz auf diesem Sachgebiet |
EP0688859A1 (fr) * | 1994-06-22 | 1995-12-27 | The Procter & Gamble Company | Procédé de traitement de textiles et compositions utilisées à cet effet |
WO1996010072A1 (fr) | 1994-09-26 | 1996-04-04 | The Procter & Gamble Company | Procede de preparation de compositions detergentes liquides, non aqueuses et contenant un agent de blanchiment |
DE19616570A1 (de) | 1996-04-25 | 1997-10-30 | Basf Ag | Vor exothermer Zersetzung durch Oxidation geschützte Waschmittelbestandteile |
US5853430A (en) * | 1997-09-03 | 1998-12-29 | The Procter & Gamble Company | Method for predissolving detergent compositions |
-
1998
- 1998-07-15 DE DE19831702A patent/DE19831702A1/de not_active Withdrawn
-
1999
- 1999-07-06 EP EP99113021A patent/EP0972823B1/fr not_active Expired - Lifetime
- 1999-07-06 AT AT99113021T patent/ATE277164T1/de not_active IP Right Cessation
- 1999-07-06 DE DE59910563T patent/DE59910563D1/de not_active Expired - Fee Related
- 1999-07-15 US US09/354,392 patent/US6372703B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
ATE277164T1 (de) | 2004-10-15 |
EP0972823A1 (fr) | 2000-01-19 |
DE59910563D1 (de) | 2004-10-28 |
US6372703B1 (en) | 2002-04-16 |
DE19831702A1 (de) | 2000-01-20 |
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