EP0952393A1 - Procédé et dispositif pour la mise en oeuvre d'un four de fusion dans les installations de traîtement des déchets - Google Patents

Procédé et dispositif pour la mise en oeuvre d'un four de fusion dans les installations de traîtement des déchets Download PDF

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Publication number
EP0952393A1
EP0952393A1 EP98302146A EP98302146A EP0952393A1 EP 0952393 A1 EP0952393 A1 EP 0952393A1 EP 98302146 A EP98302146 A EP 98302146A EP 98302146 A EP98302146 A EP 98302146A EP 0952393 A1 EP0952393 A1 EP 0952393A1
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EP
European Patent Office
Prior art keywords
melting furnace
furnace
pyrolysis
plasma
treatment facilities
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP98302146A
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German (de)
English (en)
Other versions
EP0952393B1 (fr
Inventor
Hiroaki c/o Kobe Steel Ltd. Kawabata
Hiroyuki c/o Kobe Steel Ltd. Hosoda
Mamoru c/o Kobe Steel Ltd. Suyari
Tadashi c/o Kobe Steel Ltd. Ito
Tadayuki c/o Kobe Steel Ltd. Minoura
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Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP8252961A priority Critical patent/JPH10103634A/ja
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to DE69820986T priority patent/DE69820986T2/de
Priority to EP98302146A priority patent/EP0952393B1/fr
Publication of EP0952393A1 publication Critical patent/EP0952393A1/fr
Application granted granted Critical
Publication of EP0952393B1 publication Critical patent/EP0952393B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/32Incineration of waste; Incinerator constructions; Details, accessories or control therefor the waste being subjected to a whirling movement, e.g. cyclonic incinerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/08Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
    • F23G5/085High-temperature heating means, e.g. plasma, for partly melting the waste
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/303Burning pyrogases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment
    • F23G2201/30Pyrolysing
    • F23G2201/304Burning pyrosolids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2202/00Combustion
    • F23G2202/20Combustion to temperatures melting waste
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/12Heat utilisation in combustion or incineration of waste

Definitions

  • the present invention relates to a method and apparatus for operating a melting furnace in water treatment facilities for thermally pyrolizing industrial waste, municipal solid waste, and the like, in which the pyrolysis gases generated by pyrolysis are burnt to melt ashes contained in the gases.
  • the pyrolysis furnace consist of a fluidised bed with a bottom layer of sand particles, while the waste fed into the fluidized bed is burned, it is fluidizing together with the sand particles to thermally decompose the waste into pyrolysis gases, char, ashes, and the like.
  • the melting furnace functions to burn the combustible components and char in the pyrolysis gases. Through the heat of combustion, the ashes are melted and obtained as slag.
  • Fig. 6 shows an example of the melting furnace.
  • the pyrolysis gases sent through a pipe (80) are introduced into a primary combustion chamber (82) located in the furnace portion, and the flame of a main burner (84) and combustion air injected from an air supply nozzle (86) are supplied to the combustion chamber (82).
  • the combustible components and the char in the pyrolysis gases are ignited and then burnt in a secondary combustion chamber (88).
  • the ashes in the gases are melted by combustion to form molten slag.
  • the molten slag is discharged from a slag discharge portion (92) below the slag separation portion (90), while the remaining combustion gases are discharged as exhaust gases from a gas discharge portion 94 above the slag separation portion (90).
  • auxiliary fuel is supplied to the melting furnace and is burnt by a pilot burner or the like to be used as an ignition source. This compensates for the shortage of the quantity of heat.
  • a purpose of the present invention is to provide a method and apparatus for operating a melting furnace in waste treatment facilities, which are capable of ensuring good ignitionability and a sufficient quantity of heat in the melting furnace while eliminating the need for supplementary fuel or significantly decreasing the amount of the supplementary fuel supplied.
  • the present invention provides a method of operating a melting furnace in waste treatment facilities comprising of a pyrolysis furnace for thermally pyrolizing the fed waste, and a melting furnace for burning the pyrolysis gases discharged from the pyrolysis furnace and to melt the ashes included in the gases.
  • This method blows plasma, as a heat source, into the melting furnace to ignite the combustible components and char included in pyrolysis gases. The ashes are melted by the heat of combustion .
  • the plasma reaches a very high temperature, as compared with the flee supplied from, for example, a burner.
  • the plasma also has a high heat density. Therefore, even if the pyrolysis gases introduced into the melting furnace contain a relatively large amount of char, the char can be securely ignited. Even if the lower calorific value of the combustible components in the gases is low, the ashes can sufficiently he melted by the heat generated from the plasma.
  • the plasma can be produced by utilizing electric energy, steam that is generated by the heat of the exhaust gases from the melting furnace.
  • the energy of the stream is converted into electric energy so that the electric energy can be recycled as an energy source for generating the plasma.
  • the present invention also provides an apparatus for operating the melting furnace in the waste treatment facilities wherein the melting furnace is equipped with a plasma torch for blowing the plasma, as a heat source into the melting furnace.
  • the apparatus is also equipped with a boiler for generating steam. This is done by utilizing the heat possessed by the exhaust gases of the melting furnace.
  • a generator is installed for converting the energy of the steam into electric energy. The electric energy is used as a driving source to the plasma torch.
  • the position and direction of the plasma torch may be appropriately set.
  • An air supply is used to create a swirl in the combustion chamber of the melting furnace.
  • the plasma torch is arranged to blow the plasma in substantially the same direction as the normal line of the swirl.
  • the swirl can be strengthened by utilizing the plasma flow blown at a high speed, with a corresponding increase in the residence time of the ash particles in the combustion chamber. Therefore, the ash particles can securely be melted during passage through the combustion chamber.
  • the waste treatment facilities shown in Fig. 3 comprise a fluidised bed pyrolysis furnace (10), a melting furnace (12), a heat exchanger (14), a boiler (16), a desuperheating scrubber (exhaust gas treatment means) (17), a dehumidification scrubber (exhaust gas treatment means) (18), and a induced draft fan 20, which are provided in turn from the upstream side.
  • the fluidized bed pyrolysis furnace (10) has a fluidized bed comprising sand particles at the bottom. This process pyrolizing the waste fed to the fluidized bed to discharge pyrolysis gases containing ashes and char.
  • a conventional known fluidized bed pyrolysis furnace can be applied to the fluidized bed pyrolysis furnace (10).
  • the pyrolysis furnace of the present invention is not limited to the fluidized bed type, and any type can be used as long as waste is thermally decomposed.
  • the melting furnace (12) functions to further burn the pyrolysis gases discharged from the fluidized bed pyrolysis furnace (10), and melt the ashes in the gases by utilizing the heat generated by combustion to discharge slag.
  • the melting furnace (12) has such a structure as shown in Fig. 1.
  • the melting furnace consists of the following components, from top to bottom; a combustion chamber (32), a slag separation portion(34), with a slag discharge port (36), an exhaust gas discharge port (38) provided in the lower portion of the slag separation portion (34).
  • the upper portion of the combustion chamber (32) is connected to a pipe (40) that extends from the fluidised bed thermal decomposition furnace (10), with a plurality of secondary air injection nozzles (air supply means) (42) provided below the pipe (40).
  • the direction of these secondary air injection nozzles (42) is set to form a swirl in the combustion chamber (32) by injecting secondary air in the direction close to the normal line of the furnace wall which has a circular sectional shape. Also a starting burner (44) is located above the pipe (40).
  • the melting furnace (12) is also equipped with a plasma torch (46).
  • the plasma torch (46) functions to generate a strong discharge in the torch to inject a plasma downward toward the center of the swirl.
  • a non-transfer type and transfer type can be applied to the plasma torch.
  • an electrode may be arranged at an intermediate narrow part of the furnace.
  • the heat exchanger (14) functions to heat the combustion air is supplied to the fluidized bed pyrolysis furnace (10) by utilizing the heat possessed by the high temperature combustion gases discharged from the melting furnace (12).
  • the boiler (16) evaporates water by utilizing the heat of the exhaust gases sent from the heat exchanger (14).
  • the steam generated by the boiler (16) is supplied to the generator (24) so that a steam turbine of the generator (24) is rotated by the energy possessed by the stream. Electric energy is generated by rotation of the steam turbine, and part of the electric energy is supplied as an electric source to the plasma torch (46) provided on the melting furnace (12). The residue is recovered as surplus power or electric power for the facilities.
  • the desuperheating scrubber (17) desuperheats the exhaust gases sent from the boiler (16) by contact between the exhaust gases and cooling water, settles dust in the gases and removes it.
  • the dehumidification scrubber (18) further desuperheats the exhaust gases to condense water vapor (steam) in the exhaust gases, and remove water from the exhaust gases.
  • the waste such a municipal solid waste
  • the fluidized bed pyrolysis furnace (10) is primarily burnt by the fluidised bed.
  • the gases generated by combustion flow upward from the fluidized bed and are discharged as pyrolysis gases containing ashes and char.
  • the pyrolysis gases are introduced into the combustion chamber (32) of the melting furnace (12) through the pipe (40).
  • the pyrolysis gases swirl together with secondary air, and a high temperature plasma is blown to the center of the swirl from the plasma torch (46).
  • the combustible components and the char in the pyrolysis gases are ignited by the plasma, and the ashes in the gases are melted by the heat generated by combustion and the heat possessed by the plasma to form slag.
  • the melted slag is separated from the combustion gases in the lower slag separation portion (34), and the combustion gases are discharged from the exhaust gas discharge port (38), while the melted slag is discharged from the slag discharge port (36).
  • a conventional melting furnace comprising only of a burner as an ignition source requires a supply of auxiliary fuel, and combustion air corresponding to the auxiliary fuel to the furnace in order to ensure a sufficient amount of heat to melt the ashes or securely perform ignition.
  • a high temperature plasma is used as an ignition source, as described above, the plasma reaches a high temperature (the center 10000°C, the periphery 2000°C), as compared with the flame of the burner, the char can be ignited without combustion of the auxiliary fuel. A sufficient quantity of heat to melt the ashes can also be supplied by the plasma.
  • auxiliary fuel not only is auxiliary fuel not necessary but also combustion air corresponding to the amount of the auxiliary fuel supplied is not needed.
  • the lack of combustion air can significantly decrease the quantity of the heat carried away by the exhaust gases, thus improving thermal efficiency. Since the amount of the exhaust gases is also decreased, the boiler (16), both scrubbers (17) and (18) and the induced draft fan (20) does not require a high capacity, therefor reducing the size and cost of the entire facility.
  • the high temperature combustion gases (exhaust gases) discharged from the exhaust gas discharge port (38) of the melting furnace (12) are subjected to heat exchange with the combustion air in the heat exchanger (14), passed through the boiler (16) for evaporating water and through the both scrubbers (17) and (18) for desuperheating, and then discharged to the outside of the system by the fan (20).
  • the water vapor (steam) generated in the boiler (16) is used for rotating the steam turbine of the generator (24) to generate electric energy, part of which is supplied as a driving source to the plasma torch (46) of the melting furnace (12).
  • the energy possessed by the high temperature combustion gases discharged from the melting furnace (12) can be recycled as ignition electric power in the melting furnace (12), with a corresponding improvement in operation efficiency.
  • Figs. 4 and 5 show a second embodiment.
  • the plasma torch (46) is fixed to the side wall of the furnace parallel to the pipe (40), for injecting a plasma substantially horizontally.
  • the direction of the plasma injection is set to the same direction as the normal line of the secondary air.
  • a range is set a range in which the plasma does not directly contact the inner wall.
  • the swirl in the combustion chamber (32) can be strengthened by utilizing high-speed blowing of the plasma (generally, a flow rate of 200 m/s or more), and the residence of ash particles in the combustion chamber (32) can be prolonged by strengthening the swirl, thereby obtaining the advantage that the ash particles can securely be melted during passage through the combustion chamber (32).
  • both the plasma torch (46) and auxiliary fuel may be used.
  • the amount of the auxiliary fuel supplied can be significantly decreased, as compared with a conventional melting furnace, and thus the same effect as described above can be obtained.
  • the plasma torch (46) is not necessarily immovably fixed to the furnace wall, and may be provided so that the position thereof can be axially adjusted.
  • the plasma torch (46) may also be made oscillatable so that the blowing direction of the plasma can finely be adjusted.
  • the invention in waste treatment facilities in which thermal decomposition gases are introduced into a melting furnace from a thermal decomposition furnace, a plasma is blown as a heat source into the melting furnace to ignite the combustible components and char in the thermal decomposition gases, and the ashes are melted by the heat generated by combustion. Therefore, the invention has the effects of eliminating the need for supply of auxiliary fuel into the melting furnace, significantly decreasing the amount of the auxiliary fuel supplied, securely performing ignition in the melting furnace and ensuring a necessary quantity of heat for melting the ashes.
  • water vapor is generated by the heat possessed by the exhaust gases of the melting furnace, and the energy of the water vapor (steam) is converted into electric energy which can be recycled as an energy source for generating the plasma, therefor, significantly improving the total operation efficiency of the facilities.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Incineration Of Waste (AREA)
EP98302146A 1996-09-25 1998-03-23 Procédé et dispositif pour la mise en oeuvre d'un four de fusion dans les installations de traítement des déchets Expired - Lifetime EP0952393B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP8252961A JPH10103634A (ja) 1996-09-25 1996-09-25 廃棄物処理設備における溶融炉の運転方法及び装置
DE69820986T DE69820986T2 (de) 1998-03-23 1998-03-23 Verfahren und Vorrichtung zum Betrieb eines Schmelzofens in Abfallbehandlungsanlagen
EP98302146A EP0952393B1 (fr) 1996-09-25 1998-03-23 Procédé et dispositif pour la mise en oeuvre d'un four de fusion dans les installations de traítement des déchets

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP8252961A JPH10103634A (ja) 1996-09-25 1996-09-25 廃棄物処理設備における溶融炉の運転方法及び装置
EP98302146A EP0952393B1 (fr) 1996-09-25 1998-03-23 Procédé et dispositif pour la mise en oeuvre d'un four de fusion dans les installations de traítement des déchets

Publications (2)

Publication Number Publication Date
EP0952393A1 true EP0952393A1 (fr) 1999-10-27
EP0952393B1 EP0952393B1 (fr) 2004-01-07

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EP (1) EP0952393B1 (fr)
JP (1) JPH10103634A (fr)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002086405A2 (fr) * 2001-04-20 2002-10-31 Ebara Corporation Four de combustion a scorification
EP1039221A4 (fr) * 1998-10-12 2002-12-04 Nippon Kokan Kk Dispositif d'evacuation des dechets
EP1312662A2 (fr) * 2001-05-07 2003-05-21 Cirad-Foret Procédé de gazéification de biomasse, appareil et utilisation
WO2003095072A1 (fr) * 2002-05-08 2003-11-20 Lau, Edmund, Kin, On Procede et dispositif de traitement de dechets toxiques
WO2007000607A1 (fr) * 2005-06-29 2007-01-04 Tetronics Limited Procede et appareil de traitement des dechets
CN1300504C (zh) * 2005-03-10 2007-02-14 中南大学 高温闪速气化装置和工艺
EP1914207A1 (fr) * 2006-09-27 2008-04-23 Impieco S.r.l. Installation integrée pour rendre inerte un mélange dangereux de boues organiques et inorganiques
WO2008096025A1 (fr) * 2007-02-05 2008-08-14 Qostquanto, S.L. Procédé de valorisation des boues provenant de stations d'épuration d'eaux usées
DE102007056353A1 (de) * 2007-11-16 2009-05-20 Jürgen Heinrich Verfahren und Anlage zur Abfallbehandlung
CN101213403B (zh) * 2005-06-29 2011-06-01 先进等离子动力有限公司 垃圾处理方法和装置
US8667914B2 (en) 2010-05-07 2014-03-11 Advanced Plasma Power Limited Waste treatment
GB2511756A (en) * 2013-03-11 2014-09-17 Envirofusion Ltd A Reactor for Processing Feed Material
US8957275B2 (en) 2010-03-19 2015-02-17 Advanced Plasma Power Limited Waste treatment
WO2021165694A1 (fr) * 2020-02-21 2021-08-26 Advanced Biofuel Solutions Ltd Système de traitement de déchets

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KR19990017420A (ko) * 1997-08-23 1999-03-15 김징완 플라즈마를 이용한 난분해성 가스 처리방법
JP3460605B2 (ja) * 1998-10-12 2003-10-27 Jfeエンジニアリング株式会社 廃棄物焼却・熱処理炉
JP3847055B2 (ja) * 2000-05-15 2006-11-15 株式会社タクマ ダスト含有排ガスの二次燃焼装置
JP2001355820A (ja) * 2000-06-12 2001-12-26 Sumitomo Seika Chem Co Ltd 排ガスの処理方法および処理装置
KR100439684B1 (ko) * 2000-10-31 2004-07-12 채재우 유골 사리화 장치
JP4374776B2 (ja) * 2000-12-19 2009-12-02 富士電機ホールディングス株式会社 放射性廃棄物の減容装置およびその運転方法
KR100582753B1 (ko) * 2004-04-29 2006-05-23 주식회사 애드플라텍 선회식 플라즈마 열분해/용융로
KR100689075B1 (ko) 2006-03-03 2007-03-02 벽산건설 주식회사 슬러지 용융소각로
KR101110659B1 (ko) * 2009-08-13 2012-02-24 한국전력공사 플라스마를 이용하여 폴리염화비페닐로 오염된 폐유를 처리하는 장치 및 방법
KR101115400B1 (ko) 2011-04-07 2012-02-15 한국기계연구원 플라즈마를 이용한 용융식 슬래그 처리 가스화 반응로
JP2013155955A (ja) * 2012-01-31 2013-08-15 Kobelco Eco-Solutions Co Ltd 二段燃焼炉および二段燃焼方法
JP2013228207A (ja) * 2013-08-15 2013-11-07 Osaka Gas Co Ltd 管状火炎バーナ

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JPH04124515A (ja) * 1990-09-14 1992-04-24 Osaka Gas Co Ltd 廃棄物溶融炉
US5281790A (en) * 1991-07-24 1994-01-25 Hydro Quebec Process of immobilizing ashes by vitrification thereof in a plasma reactor
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GB2174691A (en) * 1985-02-15 1986-11-12 Skf Steel Eng Ab Waste destruction
FR2641993A1 (en) * 1989-01-25 1990-07-27 Skf Plasma Tech Process and device for causing leachable substances present in a waste material to move into a gas or into compounds which are stable to leaching
EP0409037A1 (fr) * 1989-07-19 1991-01-23 Siemens Aktiengesellschaft Chambre de combustion des matières au moins partiellement combustibles
FR2660415A1 (fr) * 1990-03-28 1991-10-04 Stein Industrie Procede et dispositif de traitement de dechets toxiques ou polluants solides ou liquides.
JPH04124515A (ja) * 1990-09-14 1992-04-24 Osaka Gas Co Ltd 廃棄物溶融炉
US5281790A (en) * 1991-07-24 1994-01-25 Hydro Quebec Process of immobilizing ashes by vitrification thereof in a plasma reactor
FR2695985A1 (fr) * 1992-09-18 1994-03-25 Commissariat Energie Atomique Procédé et installation de post-combustion de gaz notamment de résidus de pyrolyse.

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Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1039221A4 (fr) * 1998-10-12 2002-12-04 Nippon Kokan Kk Dispositif d'evacuation des dechets
WO2002086405A3 (fr) * 2001-04-20 2002-12-19 Ebara Corp Four de combustion a scorification
EP1489354A1 (fr) * 2001-04-20 2004-12-22 Ebara Corporation Four de scorification
WO2002086405A2 (fr) * 2001-04-20 2002-10-31 Ebara Corporation Four de combustion a scorification
EP1312662A2 (fr) * 2001-05-07 2003-05-21 Cirad-Foret Procédé de gazéification de biomasse, appareil et utilisation
EP1312662A3 (fr) * 2001-05-07 2003-09-24 Cirad-Foret Procédé de gazéification de biomasse, appareil et utilisation
CN100413564C (zh) * 2002-05-08 2008-08-27 刘健安 有害废物的处理方法及装备
WO2003095072A1 (fr) * 2002-05-08 2003-11-20 Lau, Edmund, Kin, On Procede et dispositif de traitement de dechets toxiques
US6810821B2 (en) 2002-05-08 2004-11-02 Benjamin Chun Pong Chan Hazardous waste treatment method and apparatus
EP2386347A1 (fr) * 2002-05-08 2011-11-16 Benjamin Chun Pong Chan Dispositif de traitement de déchets toxiques
CN1300504C (zh) * 2005-03-10 2007-02-14 中南大学 高温闪速气化装置和工艺
US8109218B2 (en) 2005-06-29 2012-02-07 Advanced Plasma Power Limited Waste treatment process and apparatus
WO2007000607A1 (fr) * 2005-06-29 2007-01-04 Tetronics Limited Procede et appareil de traitement des dechets
RU2554970C2 (ru) * 2005-06-29 2015-07-10 Эдванст Плазма Пауэр Лимитед Способ и устройство для обработки отходов
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EP0952393B1 (fr) 2004-01-07
JPH10103634A (ja) 1998-04-21

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