EP0891208B1 - Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes - Google Patents
Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes Download PDFInfo
- Publication number
- EP0891208B1 EP0891208B1 EP97915442A EP97915442A EP0891208B1 EP 0891208 B1 EP0891208 B1 EP 0891208B1 EP 97915442 A EP97915442 A EP 97915442A EP 97915442 A EP97915442 A EP 97915442A EP 0891208 B1 EP0891208 B1 EP 0891208B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- inert gas
- extinguishing
- liquid
- extinguishing agent
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 52
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000009434 installation Methods 0.000 title description 2
- 239000011261 inert gas Substances 0.000 claims abstract description 41
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000000889 atomisation Methods 0.000 claims abstract description 3
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 239000000443 aerosol Substances 0.000 claims description 3
- 230000001276 controlling effect Effects 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 2
- 238000011144 upstream manufacturing Methods 0.000 claims 2
- 239000007789 gas Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C99/00—Subject matter not provided for in other groups of this subclass
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C99/00—Subject matter not provided for in other groups of this subclass
- A62C99/0009—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames
- A62C99/0072—Methods of extinguishing or preventing the spread of fire by cooling down or suffocating the flames using sprayed or atomised water
Definitions
- the invention relates to a method and an apparatus for mixing liquid inert gas with a liquid extinguishing agent (such as water) and subsequent atomization for fire fighting. This takes place in stationary - and application in mobile fire extinguishing systems.
- a liquid extinguishing agent such as water
- WO 95/24274 describes a method and an apparatus for atomizing Liquid extinguishing agent with a feed for extinguishing agent, a dispenser for Gas, a reservoir and an admixing unit are known.
- the proposed The process works with a plug flow that only emerges at the nozzle outlet takes on a pulsating character.
- both media point to the Mixing device to the same pressure since the gaseous agent from the Container is used as a blowing agent for the extinguishing agent.
- the use of liquid inert gas is not described.
- the object of the invention was, in the case of stationary spray water extinguishing systems for Extinguishing the amount of liquid extinguishing agent usually required in conventional extinguishing systems is used to reduce.
- inert gas is added to the liquid extinguishing agent in liquid form in front of the nozzle.
- inert gas here does not refer to the state of matter at the time of addition to the liquid extinguishing agent, but the inert gas is added to the liquid extinguishing agent in liquid form.
- Liquid inert gas can be added either by adding it to the extinguishing agent at elevated pressure or by adding the extinguishing agent to it at elevated pressure.
- the liquid extinguishing agent (water) is usually in the network with one Pressure of 8-10 bar performed, regardless of the water supply, such as. B. City water network, tanks, etc.
- the liquid inert gas is fed into the pipeline network at an increased pressure.
- suitable admixing devices and devices for controlling the pressure in the line network such as check valve, shut-off valve, control valve for the media
- Drop sizes and throwing distances can be influenced by different nozzles become. Throwing distances of up to 10 m can be achieved.
- Liquid CO 2 is preferably added to the liquid extinguishing agent water.
- Bubble Flow is generated by adding more inert gas than in solution can go.
- This two-phase bubble flow in the piping system can on the nozzle with simple means an aerosol with the optimal drop size for the Firefighting are generated.
- the advantage here is that the liquid inert gas is in the liquid extinguishing agent high pressure predominantly dissolves and in this way with the drops generated Cause of the fire, since the dynamic process of degassing takes longer than the transportation time. This leads to an improvement in the extinguishing effect because thereby further splitting the drops in flight to the source of the fire with the Advantage that with the fine water mist generated also hidden fire better can be deleted.
- the surface area of the liquid extinguishing agent is considerably enlarged by the formation of microdroplets in the area of the fire, in particular by the segregation of liquid extinguishing agent and inert gas.
- the inert gas e.g. CO 2
- the excess of energy in the fire area is reduced to such an extent that a high extinguishing effect is achieved which cannot be achieved by using microdroplets alone without the addition of preferably liquid inert gas.
- the amount of inert gas added is optimized.
- the optimization can either already take place during the project planning by specifying a maximum amount of CO 2 in relation to the extinguishing object.
- the amount of liquid inert gas added is regulated depending on the concentration in the extinguishing area during the extinguishing in order not to exceed the maximum MAK value of 10,000 ppm or, as is customary in Inergen extinguishing systems ( ⁇ 4% by volume).
- the amount of the added liquid inert gas also regulated according to the course of the fire.
- a device which, in addition to a supply for liquid extinguishing agent and dispensing devices for liquid Extinguishing agent, characterized in that at least one reservoir for liquid Inert gas and at least one mixing unit for mixing liquid Extinguishing agent and liquid inert gas is provided.
- This special admixing unit is preferably placed horizontally or vertically in front of the nozzles in the pipeline network assembled.
- At least one detector for determining the Concentration of the inert gas in the extinguishing area with at least one Evaluation device, and this with at least one control device for control the amount of liquid inert gas associated.
- This detector can be used with the detector to determine the concentration of the Inert gases form a unit in the extinguishing area and in particular as a combined one Measuring device for electromagnetic radiation and according to the principle of Smoke detectors and heat detectors should be designed.
- the opening angles of the dispensing devices for liquid extinguishing agent are adjustable, the opening angle being determined by the admixed amount of liquid inert gas.
- the device according to the invention has a check valve (9).
- the extinguishing water is mixed with the liquid inert gas flowing out of the reservoir (2).
- Suitable shut-off devices and a control valve (8) are arranged between the reservoir (2) and the admixing unit (3).
- the control valve is preferably connected to an evaluation device (7) for a detector (6) for the extinguishing nozzles (5) defining the extinguishing area (4).
- the shut-off devices are e.g. B. opened via a fire alarm system, not shown, and after a delay time, depending on the water supply, the control valve (8) is switched. This circuit can switch the control valve (8) to intermittent or continuous flow in order to clear the way for the liquid inert gas as a pressure increasing and inerting medium.
- the pressure and temperature in the pipe system can be determined by the ratio of the Inert gas and adjusted by the amount of extinguishing agent dispensed per unit of time become.
- the gas dissolves during the residence time in the pipe system and due to the increased pressure in the extinguishing liquid. This increases the volume and thus the pressure in the pipe system.
- the extinguishing agent When the extinguishing agent emerges from the nozzle and on its way to the fire material, it segregates the extinguishing medium into its components with simultaneous aerosol formation liquid extinguishing agent. However, a large proportion of the gas passes without Separation directly into the fire zone.
- the amount of CO 2 released into the extinguishing area (4) remains below the toxicity limit.
- the water initially emerges as a jet when it leaves the pipe system and is broken down into the finest drops only on the flight to the source of the fire, which results in larger throwing distances, or it emerges as the finest drops with a short range.
Landscapes
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)
- Nozzles (AREA)
- Fire-Extinguishing Compositions (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Claims (13)
- Procédé pour atomiser un agent d'extinction liquide dans des installations d'extinction, caractérisé en ce que du gaz inerte sous forme liquéfiée est ajouté à l'agent d'extinction en amont de la buse pour produire un écoulement à bulles à deux phases, « bubble flow », le gaz inerte étant injecté sous une pression élevée par rapport à l'agent d'extinction.
- Procédé suivant la revendication 1, caractérisé en ce que du CO2 est ajouté comme gaz inerte à l'agent d'extinction.
- Procédé suivant l'une des revendications 1 et 2, caractérisé en ce que les gaz inertes sont ajoutés par intermittence.
- Procédé suivant les revendications 1 à 3, caractérisé en ce que la quantité de gaz inerte ajoutée est supérieure à celle passant en solution dans l'agent d'extinction liquide.
- Procédé suivant l'une des revendications 1 à 4, caractérisé en ce que les agents s'écoulant dans la canalisation sont atomisés à la sortie de cette dernière de sorte qu'ils forment un aérosol, brouillard d'eau.
- Procédé suivant l'une des revendications 1 à 5, caractérisé en ce que la quantité du gaz inerte liquéfié ajouté est réglée en fonction de la concentration de gaz inerte dans la zone d'extinction.
- Procédé suivant l'une des revendications 1 à 5, caractérisé en ce que la quantité du gaz inerte liquéfié ajouté est réglée d'après l'allure de l'incendie.
- Procédé suivant l'une des revendications 1 à 7, caractérisé en ce que l'atomisation est assurée au moyen de buses d'extinction d'un angle d'ouverture réglable, et l'angle d'ouverture est réglé en fonction du foyer et de l'allure de l'incendie, en particulier au moyen de la pression sur les buses d'extinction.
- Dispositif pour atomiser un agent d'extinction dans des installations d'extinction avec une arrivée (1) pour de l'agent d'extinction liquide, avec un dispositif de distribution (5) pour l'agent d'extinction, caractérisé en ce que sont prévus au moins une unité de mélange (3) pour du gaz inerte liquéfié, disposée en amont du dispositif de distribution (5), et au moins un réservoir (2) pour du gaz inerte liquéfié.
- Dispositif suivant la revendication 9, caractérisé en ce qu'un réservoir est disposé comme unité de mélange, réservoir dans lequel le gaz inerte liquéfié est ajouté en continu à l'agent d'extinction en circulation.
- Dispositif suivant l'une des revendications 9 et 10, caractérisé en ce qu'au moins un détecteur (6) pour la détermination de la concentration du gaz inerte dans la zone d'extinction (4) est relié à au moins un dispositif d'évaluation (7), et ce dernier est relié à au moins un dispositif de réglage (8) de la quantité du gaz inerte.
- Dispositif suivant l'une des revendications 9 à 11, caractérisé en ce qu'au moins un détecteur est disposé pour la détermination de l'allure de l'incendie et pour la commande de l'extinction.
- Dispositif suivant l'une des revendications 9 à 12, caractérisé en ce que les dispositifs de distribution (5) pour de l'agent d'extinction liquide présentent des angles d'ouverture réglables et l'angle d'ouverture est réglable en fonction de la quantité de gaz inerte liquéfié ajoutée.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97915442A EP0891208B1 (fr) | 1996-03-30 | 1997-03-26 | Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96105159 | 1996-03-30 | ||
EP96105159 | 1996-03-30 | ||
EP96114586A EP0798019A1 (fr) | 1996-03-30 | 1996-09-12 | Méthode et appareil pour l'atomisation d'un agent extincteur liquide pour installation d'extinction d'incendie stationnaire |
EP96114586 | 1996-09-12 | ||
EP97915442A EP0891208B1 (fr) | 1996-03-30 | 1997-03-26 | Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes |
PCT/EP1997/001550 WO1997036651A1 (fr) | 1996-03-30 | 1997-03-26 | Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0891208A1 EP0891208A1 (fr) | 1999-01-20 |
EP0891208B1 true EP0891208B1 (fr) | 2000-10-18 |
Family
ID=26141841
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96114586A Withdrawn EP0798019A1 (fr) | 1996-03-30 | 1996-09-12 | Méthode et appareil pour l'atomisation d'un agent extincteur liquide pour installation d'extinction d'incendie stationnaire |
EP97915442A Expired - Lifetime EP0891208B1 (fr) | 1996-03-30 | 1997-03-26 | Procede et dispositif pour atomiser un agent d'extinction dans des installations d'extinction fixes |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96114586A Withdrawn EP0798019A1 (fr) | 1996-03-30 | 1996-09-12 | Méthode et appareil pour l'atomisation d'un agent extincteur liquide pour installation d'extinction d'incendie stationnaire |
Country Status (12)
Country | Link |
---|---|
US (1) | US6173790B1 (fr) |
EP (2) | EP0798019A1 (fr) |
JP (1) | JP4031832B2 (fr) |
KR (1) | KR20000005148A (fr) |
CN (1) | CN1092071C (fr) |
AT (1) | ATE196996T1 (fr) |
AU (1) | AU722952B2 (fr) |
DE (1) | DE59702499D1 (fr) |
ES (1) | ES2153188T3 (fr) |
NZ (1) | NZ332157A (fr) |
PT (1) | PT891208E (fr) |
WO (1) | WO1997036651A1 (fr) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
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RU2131379C1 (ru) * | 1998-02-06 | 1999-06-10 | Научно-исследовательский институт низких температур при Московском государственном авиационном институте - техническом университете | Способ пожаротушения с использованием летательного аппарата и устройство для его осуществления |
EP1078653A1 (fr) | 1999-08-24 | 2001-02-28 | Asea Brown Boveri Ag | Dispositif pour introduire un gaz inerte dans un agent extincteur de feu |
JP2003509179A (ja) * | 1999-09-20 | 2003-03-11 | フオン・ファン・ディン | 消火剤の分配を規制するために液化co2を使用した自動消火方法、化学薬品およびシステム |
GB2375047B (en) * | 2001-03-29 | 2004-11-10 | Kidde Plc | Fire and explosion suppression |
WO2002078790A2 (fr) * | 2001-03-29 | 2002-10-10 | Kidde Ip Holdings Limited | Extinction du feu et suppression de l'explosion |
KR100441310B1 (ko) * | 2002-02-22 | 2004-07-21 | 주식회사 윈 | 소방용 워트 미스트 장치. |
GB2386835B (en) * | 2002-03-28 | 2005-04-27 | Kidde Plc | Fire and explosion suppression |
US7258140B2 (en) * | 2002-10-16 | 2007-08-21 | Richard Acree | Portable pressurized gas supply apparatus for pneumatic equipment |
US20040226301A1 (en) * | 2003-05-14 | 2004-11-18 | Airwars Defense Lp, A Colorado Limited Partnership | Liquid nitrogen enabler |
DE102005023101B4 (de) * | 2005-05-13 | 2013-10-10 | Minimax Gmbh & Co. Kg | Verfahren zum Einbringen eines Inertgases und Anlage zum Inertisieren |
SG128596A1 (en) * | 2005-06-13 | 2007-01-30 | Victaulic Co Of America | High velocity low pressure emitter |
US7810577B2 (en) * | 2005-08-30 | 2010-10-12 | Federal Express Corporation | Fire sensor, fire detection system, fire suppression system, and combinations thereof |
EP1993977A4 (fr) * | 2006-02-13 | 2010-01-20 | Halkey Roberts Corp | Appareil et procédé d'utilisation de matériau énergétique à base de tétrazine |
AR062764A1 (es) * | 2006-11-06 | 2008-12-03 | Victaulic Co Of America | Metodo y aparato para secar redes de canerias equipadas con rociadores |
US8360162B2 (en) * | 2007-09-24 | 2013-01-29 | Utc Fire & Security Corporation | Hybrid inert gas fire suppression system |
KR101269878B1 (ko) * | 2010-07-29 | 2013-06-07 | 충북대학교 산학협력단 | 화학반응을 이용한 미세 물분무 소화시스템 |
US10532237B2 (en) | 2010-08-05 | 2020-01-14 | Victaulic Company | Dual mode agent discharge system with multiple agent discharge capability |
WO2013055350A1 (fr) * | 2011-10-14 | 2013-04-18 | Utc Fire & Security Corporation | Système de pulvérisation comprenant un dispositif de mélange en amont d'un pulvérisateur |
US10058722B2 (en) * | 2015-02-18 | 2018-08-28 | Apparatebau Gauting Gmbh | Fire protection device and method for fire fighting |
CN106693237A (zh) * | 2017-01-23 | 2017-05-24 | 山东宏达科技集团有限公司 | 一种雪雹发生及喷射装置 |
CN106823220A (zh) * | 2017-04-07 | 2017-06-13 | 山东宏达科技集团有限公司 | 一种灭火方法、灭火系统和设置该系统的消防车 |
CN106823221A (zh) * | 2017-04-07 | 2017-06-13 | 山东宏达科技集团有限公司 | 一种液氮动力消防炮 |
WO2018213214A1 (fr) * | 2017-05-16 | 2018-11-22 | Robert Czarnek | Système d'extinction d'incendie à brouillard d'eau |
US11129848B2 (en) | 2017-08-08 | 2021-09-28 | Perricone Hydrogen Water Company, Llc | Medication enhancement using hydrogen |
US20190046561A1 (en) | 2017-08-08 | 2019-02-14 | Perricone Hydrogen Water Company, Llc | Barriers for glass and other materials |
CN109125997B (zh) * | 2018-07-26 | 2022-03-29 | 国家电网有限公司 | 一种灭火剂喷射装置 |
CN110242344B (zh) * | 2019-07-30 | 2024-04-30 | 鄂尔多斯市中北煤化工有限公司 | 一种向煤矿综采支架后方自动喷洒粉状防火材料的装置 |
US11123365B2 (en) | 2019-11-18 | 2021-09-21 | Perricone Hydrogen Water Company, Llc | Compositions comprising palmitoylethanolamide and hydrogen water, and methods thereof |
CN112675460A (zh) * | 2020-01-20 | 2021-04-20 | 湖北及安盾消防科技有限公司 | 快速释放的脉冲式灭火装置及电器设备 |
CN112675463A (zh) * | 2020-01-20 | 2021-04-20 | 湖北及安盾消防科技有限公司 | 密闭的脉冲式灭火装置及电器设备 |
CN111810218B (zh) * | 2020-06-16 | 2021-06-25 | 山东科技大学 | 一种井下液态co2相变动力多功能灌注系统及使用方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
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US3592270A (en) * | 1968-10-24 | 1971-07-13 | Factory Mutual Res Corp | Double rate flow controller |
US4585173A (en) * | 1985-03-18 | 1986-04-29 | Bete Fog Nozzle, Inc. | Pressure activated conical spray nozzle |
SU1326282A1 (ru) * | 1985-07-02 | 1987-07-30 | Э.А.Попов, О.Э.Толкачев и М.А.Яремчук | Способ газификации сжиженного инертного газа при тушении пожара в горных выработках |
US5377765A (en) * | 1993-02-22 | 1995-01-03 | Valkyrie Scientific Proprietary, L.C. | Method and means for extinguishing tank fires |
RU2074544C1 (ru) * | 1994-03-10 | 1997-02-27 | Владимир Семенович Терпигорьев | Способ пожаротушения газожидкостной смесью и газожидкостная форсунка для его осуществления |
FI98494C (sv) * | 1994-04-14 | 1997-07-10 | Goeran Sundholm | Anordning för eldsläckning |
AU684017B2 (en) * | 1994-04-14 | 1997-11-27 | Marioff Corporation Oy | A fire fighting installation for discharging a liquid-gas fog |
DE4423400C2 (de) * | 1994-07-04 | 1998-02-05 | Siemens Ag | Verfahren und Vorrichtung zur Erzeugung eines Inertisierungsgases |
DE29510982U1 (de) * | 1995-07-13 | 1995-09-21 | Broemme, Albrecht, Dipl.-Ing., 12203 Berlin | Feuerlöscher |
-
1996
- 1996-09-12 EP EP96114586A patent/EP0798019A1/fr not_active Withdrawn
-
1997
- 1997-03-26 WO PCT/EP1997/001550 patent/WO1997036651A1/fr not_active Application Discontinuation
- 1997-03-26 AT AT97915442T patent/ATE196996T1/de active
- 1997-03-26 CN CN97193540A patent/CN1092071C/zh not_active Expired - Fee Related
- 1997-03-26 US US09/155,625 patent/US6173790B1/en not_active Expired - Fee Related
- 1997-03-26 ES ES97915442T patent/ES2153188T3/es not_active Expired - Lifetime
- 1997-03-26 PT PT97915442T patent/PT891208E/pt unknown
- 1997-03-26 EP EP97915442A patent/EP0891208B1/fr not_active Expired - Lifetime
- 1997-03-26 KR KR1019980707811A patent/KR20000005148A/ko not_active Application Discontinuation
- 1997-03-26 AU AU22919/97A patent/AU722952B2/en not_active Ceased
- 1997-03-26 JP JP53491697A patent/JP4031832B2/ja not_active Expired - Fee Related
- 1997-03-26 NZ NZ332157A patent/NZ332157A/xx unknown
- 1997-03-26 DE DE59702499T patent/DE59702499D1/de not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0798019A1 (fr) | 1997-10-01 |
CN1218416A (zh) | 1999-06-02 |
PT891208E (pt) | 2001-03-30 |
NZ332157A (en) | 2000-08-25 |
AU722952B2 (en) | 2000-08-17 |
AU2291997A (en) | 1997-10-22 |
US6173790B1 (en) | 2001-01-16 |
DE59702499D1 (de) | 2000-11-23 |
WO1997036651A1 (fr) | 1997-10-09 |
JP2001501839A (ja) | 2001-02-13 |
JP4031832B2 (ja) | 2008-01-09 |
EP0891208A1 (fr) | 1999-01-20 |
CN1092071C (zh) | 2002-10-09 |
ATE196996T1 (de) | 2000-11-15 |
KR20000005148A (ko) | 2000-01-25 |
ES2153188T3 (es) | 2001-02-16 |
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