EP0883676B1 - Nettoyant pour installations de l'industrie alimentaire, son utilisation et procede de nettoyage de ces installations - Google Patents
Nettoyant pour installations de l'industrie alimentaire, son utilisation et procede de nettoyage de ces installations Download PDFInfo
- Publication number
- EP0883676B1 EP0883676B1 EP97903331A EP97903331A EP0883676B1 EP 0883676 B1 EP0883676 B1 EP 0883676B1 EP 97903331 A EP97903331 A EP 97903331A EP 97903331 A EP97903331 A EP 97903331A EP 0883676 B1 EP0883676 B1 EP 0883676B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cleaning
- cleaning solution
- hydroxide
- edta
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000012459 cleaning agent Substances 0.000 title description 2
- 239000003795 chemical substances by application Substances 0.000 title 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 73
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 60
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 235000013305 food Nutrition 0.000 claims abstract description 7
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 33
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 21
- 239000012466 permeate Substances 0.000 claims description 20
- 239000012141 concentrate Substances 0.000 claims description 17
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 17
- 239000012528 membrane Substances 0.000 claims description 16
- 241001465754 Metazoa Species 0.000 claims description 15
- 238000001728 nano-filtration Methods 0.000 claims description 13
- 239000000654 additive Substances 0.000 claims description 12
- 238000005374 membrane filtration Methods 0.000 claims description 10
- 239000003513 alkali Substances 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 7
- 159000000001 potassium salts Chemical class 0.000 claims description 5
- 235000013365 dairy product Nutrition 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000006052 feed supplement Substances 0.000 claims 2
- 238000004090 dissolution Methods 0.000 claims 1
- 150000004679 hydroxides Chemical class 0.000 claims 1
- 230000001172 regenerating effect Effects 0.000 abstract 1
- 238000011026 diafiltration Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- 241000283690 Bos taurus Species 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000009419 refurbishment Methods 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 235000019730 animal feed additive Nutrition 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000003977 dairy farming Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 235000007879 food anti-foaming agent Nutrition 0.000 description 1
- 235000003084 food emulsifier Nutrition 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/044—Hydroxides or bases
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/06—Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/20—Industrial or commercial equipment, e.g. reactors, tubes or engines
Definitions
- the invention relates to a method for cleaning plants Food industry using an alkaline detergent solution Membrane filtration is regenerated, with the permeate being recycled.
- EDTA ethylenediaminetetraacetic acid
- the used cleaning solution again via membrane filtration systems work up. To do this, part of the cleaning solution is removed from a collection container discharged into a buffer tank and from there in a circle via a membrane system pumped, the filtration taking place in cross flow.
- Such a thing Processing method is known from WO 95/27681 A1. That from water and sodium hydroxide solution existing permeate becomes the collection container for the Cleaning solution returned.
- In the buffer tank of the membrane cleaning system accumulate the organic contaminants that are taken from time to time to dispose of them.
- the invention is based on the object a process for cleaning plants in the food industry at the beginning Provide mentioned type, which is a significantly more economical cleaning than enabled in the prior art.
- This object is achieved by a method for cleaning plants Food industry using an alkaline detergent solution Regeneration of the nanomembrane filtration, recycling the permeate, characterized in that one uses a cleaning solution, the Hydroxide component exclusively from potassium hydroxide solution or from a mixture of potassium hydroxide solution and another alkali, in particular sodium hydroxide solution, with at least 20% by weight Potassium hydroxide solution, calculated as hydroxide and based on the total in the The hydroxide solution contained in the cleaning solution.
- the inventors have found that a partial or complete replacement of sodium hydroxide with potassium hydroxide performance membrane system increases by at least 10 to 50%.
- the performance relates here on the permeate flows reached. This allows the plant investment and reduce the energy consumption of the membrane filtration system. Higher concentrations of the separated dirt load are possible, so that the Reduced the amount of dirt and the yield of regenerated lye is increased.
- the performance of the membrane filtration system is also increased by replacing the sodium salts with potassium salts. Disadvantages that occur during filtration through the use of EDTA can be compensated for or simply overcompensated by simply using potassium hydroxide solution and EDTA in the form of the free acid or its potassium salt. Use of the disodium salt of EDTA is also possible if the sodium ion content in the lye does not exceed certain limits. If all alkali metal ions are calculated as alkali hydroxide, the potassium hydroxide solution in the base, based on the total amount of hydroxide in the cleaning base, must not drop below 20% by weight. In general, the performance of the filtration system increases with the ratio of potassium to sodium ions in the cleaning liquor, which means that sodium-free cleaning solutions give the highest flow rates in l / m 2 h.
- the cleaning solution preferably contains a mixture of potassium hydroxide solution and another alkali, preferably sodium hydroxide solution, with at least 50% by weight of potassium hydroxide solution, calculated and related as mentioned above.
- the advantage of the EDTA-free cleaning solution with at least 50% by weight potassium hydroxide solution lies in the possibility of immediately removing the filtered impurities Post-treatment as animal feed, e.g. B. as pig feed, because a increased salinity in the case of potassium salts rather than an increased sodium salt content can be tolerated.
- the cleaning solution contains additives that are all suitable as additives for animal feed.
- physiologically harmless cleaning enhancer which in the known cleaning agents not used, especially phosphates, Gluconates and / or food defoamers and emulsifiers suggested.
- the cleaning liquor contains, in addition to the hydroxide constituents, additives which are in the form of potassium salts.
- the performance of the membrane filtration system can be additionally increased in this case. If the permeate flow in a conventional sodium hydroxide-based cleaning solution such. B. is 50 l / m2 h, this performance is increased to 70 l / m 2 h by replacing the sodium hydroxide solution with potassium hydroxide solution. If the cleaning liquor also contains potassium tripolyphosphate as a cleaning booster, the permeate flow also increases to 74 l / m 2 h.
- Another advantage of these additives in the form of potassium salts is that particularly suitable as an animal feed additive.
- the method according to the invention can be used advantageous for plants in the food industry that use a regeneration system for used cleaning liquors.
- the use of the cleaning liquor in systems of the Dairy farming since the concentrate obtained without further treatment as Animal feed can be used. Diafiltration or another additional Refurbishment is usually not necessary. Not only is there an elaborate process Dispose of the separated contaminants, but this "Impurities" represent a new resource. Should the increased salt content however, they can be reduced by means of diafiltration Refurbishment in the case of the cleaning process according to the invention perform much faster and therefore more economically.
- EDTA falls with a much lower one Residual contamination content.
- the filtered EDTA can again with alkali converted into a soluble form and, for example, the permeate from the Nanofiltration can be added. Since certain portions of EDTA both in the felled Sludge as well as in the solution from which it has been precipitated can be removed Using this method, 80 - 90% of the EDTA originally used can be recycled.
- the filtered dirt is not due to its residual EDTA content more usable as cattle feed.
- the cleaning liquor is regenerated preferably alkali-resistant nanofiltration membranes with a D value from 100 to 2000 daltons.
- Such membranes are for molecules with permeable to a molecular weight up to the stated D value, but hold Molecules with higher molecular weights return.
- membrane filtration is operated in cross flow with a transmembrane Pressure difference from 8 to 25 bar.
- Cleaning dairy equipment uses a cleaning solution that in addition to the hydroxide components contains only additives that as Additives for animal feed are suitable, and that one in membrane filtration resulting concentrate used as animal feed or additive to animal feed.
- a concentrate with a particularly high potassium content is much better than Concentrates with high sodium levels for use as animal feed, e.g. B. as Pig feed suitable. Therefore, it is also proposed that the hydroxide components the cleaning solution consist exclusively of potassium hydroxide solution.
- the liquor which contains about 2 wt is tempered, fed to the systems to be cleaned, tanks, pipelines, etc., which are identified in FIG. 1 by reference number 2.
- the cleaning liquor is circulated.
- the contamination of the cleaning solution that accumulates over time are removed with the preparation part shown on the right in FIG.
- To part of the cleaning liquor is discharged into the buffer tank 4 via a line 3.
- This portion of the cleaning liquor is circulated via a pressure pump 5 and a membrane module 6 driven in the circuit.
- Accumulating and settling contaminants are over from time to time taken a line 7.
- the permeate emerging from the membrane module is returned to the collecting tank 1 via the return line 8.
- the permeate flow was 50 l / hm 2 .
- the permeate flow was 50 l / hm 2 .
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Health & Medical Sciences (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Claims (15)
- Procédé de nettoyage d'installations de l'industrie alimentaire utilisant une lessive de nettoyage alcaline qui est régénérée au moyen d'une nanofiltration à membrane, dans lequel on réintroduit le produit de perméation,
caractérisé en ce qu'
on utilise une lessive de nettoyage dont le constituant hydroxyde se compose exclusivement de lessive de potasse ou d'un mélange de potasse et d'une autre base avec au moins 20 % en poids de lessive de potasse, cette valeur étant calculée sous forme d'hydroxyde et par rapport à l'ensemble de la quantité d'hydroxyde contenue dans la lessive de nettoyage. - Procédé selon la revendication 1,
caractérisé en ce que
la lessive de nettoyage contient un mélange de lessive de potasse et d'une autre base avec au moins 50 % de lessive de potasse, calculé et compris comme dans la revendication 1. - Procédé selon la revendication 1 ou 2,
caractérisé en ce que
la lessive de nettoyage contient comme autre base de la lessive de soude. - Procédé selon la revendication 1,
caractérisé en ce que
la lessive de nettoyage contient, comme constituant hydroxyde, exclusivement de la lessive de potasse. - Procédé selon une ou plusieurs des revendications 1 à 4,
caractérisé en ce qu'
on utilise pour nettoyer les installations de l'industrie laitière une lessive de nettoyage qui contient, outre les constituants hydroxydes, exclusivement des additifs qui conviennent comme additifs pour l'alimentation animale, et en ce qu'on utilise le concentré apparaissant lors de la filtration à membrane comme aliment pour animaux ou additifs aux aliments pour animaux. - Procédé selon la revendication 5,
caractérisé en ce que
la lessive de nettoyage contient comme additifs des phosphates, des gluconates et/ou des antimousses et émulsifiants admissibles pour les aliments. - Procédé selon la revendication 5 ou 6,
caractérisé en ce que
la lessive de nettoyage contient, outre des constituants hydroxydes, des additifs qui sont présents sous forme de sels de potassium. - Procédé selon une ou plusieurs des revendications 1 à 7,
caractérisé en ce que
la lessive de nettoyage contient, outre les constituants hydroxydes, de l'acide éthylène diamine tétraacétique (EDTA). - Procédé selon la revendication 8,
caractérisé en ce qu'
on utilise l'EDTA sous la forme de l'acide libre ou d'un sel de potassium. - Procédé selon la revendication 8,
caractérisé en ce qu'
on utilise le sel disodique de l'EDTA, la teneur en lessive de potasse, lorsqu'on compte tous les ions de métaux alcalins comme hydroxydes, par rapport à l'ensemble de la quantité d'hydroxyde contenue dans la lessive de nettoyage, s'élève à au moins 20 % en poids. - Procédé selon une ou plusieurs des revendications 8 à 10,
caractérisé en ce qu'
on récupère l'EDTA à partir des concentrés obtenus dans la nanofiltration de lessive de nettoyage, par précipitation fractionnée et filtration de la plus grande partie de la salissure avant la précipitation de l'EDTA, et on l'ajoute, après dissolution avec de la lessive alcaline, au produit de perméation de la nanofiltration. - Procédé selon l'une ou plusieurs des revendications 1 à 11,
caractérisé en ce qu'
on utilise pour la régénération de la lessive de nettoyage des membranes de nanofiltration résistantes aux bases ayant une valeur de D comprise entre 100 et 2000 daltons. - Procédé selon une ou plusieurs des revendications 1 à 12,
caractérisé en ce qu'
on fait fonctionner la filtration à membrane dans un courant transversal avec une différence de pression transmembranaire de 8 à 25 bars. - Utilisation d'une lessive de nettoyage selon une ou plusieurs des revendications 1 à 13 pour les installations de l'industrie alimentaire, ces installations étant équipées d'un dispositif de régénération au moyen d'une nanofiltration pour lessives de nettoyage usées.
- Utilisation d'une lessive de nettoyage selon la revendication 14 pour les installations de l'industrie laitière.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19607800A DE19607800A1 (de) | 1996-03-01 | 1996-03-01 | Reinigungsmittel für Anlagen der Lebensmittelindustrie, seine Verwendung und Verfahren zum Reinigen dieser Anlagen |
DE19607800 | 1996-03-01 | ||
PCT/EP1997/000799 WO1997032000A2 (fr) | 1996-03-01 | 1997-02-20 | Nettoyant pour installations de l'industrie alimentaire, son utilisation et procede de nettoyage de ces installations |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0883676A2 EP0883676A2 (fr) | 1998-12-16 |
EP0883676B1 true EP0883676B1 (fr) | 2001-04-25 |
Family
ID=7786862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97903331A Expired - Lifetime EP0883676B1 (fr) | 1996-03-01 | 1997-02-20 | Nettoyant pour installations de l'industrie alimentaire, son utilisation et procede de nettoyage de ces installations |
Country Status (14)
Country | Link |
---|---|
US (1) | US6204231B1 (fr) |
EP (1) | EP0883676B1 (fr) |
JP (1) | JP2000506910A (fr) |
AT (1) | ATE200792T1 (fr) |
AU (1) | AU714812B2 (fr) |
BR (1) | BR9707898A (fr) |
CA (1) | CA2248080A1 (fr) |
DE (2) | DE19607800A1 (fr) |
DK (1) | DK0883676T3 (fr) |
ES (1) | ES2156360T3 (fr) |
GR (1) | GR3035881T3 (fr) |
NO (1) | NO983115L (fr) |
NZ (1) | NZ331625A (fr) |
WO (1) | WO1997032000A2 (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19726287A1 (de) | 1997-06-20 | 1998-12-24 | Henkel Ecolab Gmbh & Co Ohg | Verfahren zum Waschen von Wäsche, insbesondere von Berufsbekleidung |
US7909179B2 (en) * | 2005-08-16 | 2011-03-22 | Ge Osmonics, Inc. | Modified polyamide matrices and methods for their preparation |
US7575687B2 (en) * | 2005-08-16 | 2009-08-18 | Ge Osmonics, Inc. | Membranes and methods useful for caustic applications |
US20100151094A1 (en) * | 2008-12-16 | 2010-06-17 | Choudhury Gour S | Methods, apparatuses, and systems for the removal of peels from agricultural produce |
PL2859074T3 (pl) * | 2012-06-07 | 2021-09-13 | Diversey, Inc. | Kompozycje i sposoby czyszczenia, dezynfekcji i odkażania neutralne w odniesieniu do ścieków |
US8835140B2 (en) | 2012-06-21 | 2014-09-16 | Ecolab Usa Inc. | Methods using peracids for controlling corn ethanol fermentation process infection and yield loss |
PT3156475T (pt) * | 2015-10-16 | 2018-10-19 | Georg Hagleitner Hans | Concentrado de limpeza líquido |
GB201801230D0 (en) * | 2018-01-25 | 2018-03-14 | Univ Leuven Kath | Cross-linked nanofiltration membranes |
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US4243543A (en) * | 1979-05-11 | 1981-01-06 | Economics Laboratory, Inc. | Stabilized liquid enzyme-containing detergent compositions |
US4230592A (en) * | 1979-05-31 | 1980-10-28 | Chemed Corporation | Controlled foam detergent additive |
EG18543A (en) * | 1986-02-20 | 1993-07-30 | Albright & Wilson | Protected enzyme systems |
US5093031A (en) * | 1986-06-27 | 1992-03-03 | Isp Investments Inc. | Surface active lactams |
US4787999A (en) * | 1986-09-22 | 1988-11-29 | Dingess John A | Compositions for cleaning aluminum |
US4836948A (en) * | 1987-12-30 | 1989-06-06 | Lever Brothers Company | Viscoelastic gel detergent compositions |
US5273675A (en) * | 1990-02-16 | 1993-12-28 | Rohm And Haas Company | Phosphate-free liquid cleaning compositions containing polymer |
US5064561A (en) * | 1990-05-09 | 1991-11-12 | Diversey Corporation | Two-part clean-in-place system |
DE4206772A1 (de) | 1992-03-04 | 1993-09-09 | Kramaschke Gmbh Dr | Reinigungsmittel fuer oelkuehler |
DE59303689D1 (de) | 1992-03-06 | 1996-10-17 | Filtrox Werk Ag | Verfahren zur Filtration verschmutzter Lauge und Anlage zur Durchführung des Verfahrens |
DE4319935A1 (de) * | 1993-06-16 | 1994-12-22 | Basf Ag | Verwendung von Glycin-N,N-diessigsäure-Derivaten als Komplexbildner für Erdalkali- und Schwermetallionen |
US5484549A (en) * | 1993-08-30 | 1996-01-16 | Ecolab Inc. | Potentiated aqueous ozone cleaning composition for removal of a contaminating soil from a surface |
US5514282A (en) * | 1994-04-01 | 1996-05-07 | Hibbard; David C. | Food processing wastewater treatment and recovery process |
IL109249A0 (en) * | 1994-04-07 | 1994-07-31 | Weizmann Kiryat Membrane Prod | Process and system for purifying a contaminated caustic feed solution |
US5486315A (en) * | 1994-05-20 | 1996-01-23 | Lonza Inc. | Low foam branched alkyldimethylamine oxides |
US5746920A (en) * | 1994-06-08 | 1998-05-05 | Fraunhofer-Gesellschaft Zur Foerder Der Angewandten Forschung E.V. | Process for purifying dairy wastewater |
EP0765292B1 (fr) * | 1994-06-09 | 1999-10-06 | Agricultural Research Institute Of Ontario | Procede pour clarifier les rejets liquides de laiterie |
NO942341L (no) * | 1994-06-20 | 1995-12-21 | Arne Pedersen | Flytende, vandig rengjöringsmiddel |
ZA955295B (en) * | 1994-06-27 | 1996-02-13 | Diversey Corp | Non-silicated soft metal safe product |
US5520835A (en) * | 1994-08-31 | 1996-05-28 | The Procter & Gamble Company | Automatic dishwashing compositions comprising multiquaternary bleach activators |
DE19524211A1 (de) | 1995-07-03 | 1997-01-09 | Henkel Ecolab Gmbh & Co Ohg | Anlagen-Reinigungsverfahren mit integrierter Vorspülung |
US5571446A (en) * | 1995-07-27 | 1996-11-05 | Diversey Corporation | Anionic stabilized enzyme based clean-in-place system |
US5770555A (en) * | 1995-11-20 | 1998-06-23 | Rohm And Haas Company | High alkali-containing cleaning concentrates |
-
1996
- 1996-03-01 DE DE19607800A patent/DE19607800A1/de not_active Withdrawn
-
1997
- 1997-02-20 BR BR9707898A patent/BR9707898A/pt not_active Application Discontinuation
- 1997-02-20 DK DK97903331T patent/DK0883676T3/da active
- 1997-02-20 WO PCT/EP1997/000799 patent/WO1997032000A2/fr active IP Right Grant
- 1997-02-20 AT AT97903331T patent/ATE200792T1/de not_active IP Right Cessation
- 1997-02-20 JP JP9530558A patent/JP2000506910A/ja active Pending
- 1997-02-20 AU AU17929/97A patent/AU714812B2/en not_active Ceased
- 1997-02-20 CA CA002248080A patent/CA2248080A1/fr not_active Abandoned
- 1997-02-20 ES ES97903331T patent/ES2156360T3/es not_active Expired - Lifetime
- 1997-02-20 NZ NZ331625A patent/NZ331625A/xx unknown
- 1997-02-20 EP EP97903331A patent/EP0883676B1/fr not_active Expired - Lifetime
- 1997-02-20 US US09/142,098 patent/US6204231B1/en not_active Expired - Fee Related
- 1997-02-20 DE DE59703437T patent/DE59703437D1/de not_active Expired - Fee Related
-
1998
- 1998-07-06 NO NO983115A patent/NO983115L/no unknown
-
2001
- 2001-05-16 GR GR20010400734T patent/GR3035881T3/el not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
DE19607800A1 (de) | 1997-09-04 |
JP2000506910A (ja) | 2000-06-06 |
WO1997032000A2 (fr) | 1997-09-04 |
DK0883676T3 (da) | 2001-08-13 |
ATE200792T1 (de) | 2001-05-15 |
DE59703437D1 (de) | 2001-05-31 |
EP0883676A2 (fr) | 1998-12-16 |
AU714812B2 (en) | 2000-01-13 |
US6204231B1 (en) | 2001-03-20 |
BR9707898A (pt) | 1999-07-27 |
GR3035881T3 (en) | 2001-08-31 |
NO983115L (no) | 1998-07-06 |
AU1792997A (en) | 1997-09-16 |
CA2248080A1 (fr) | 1997-09-04 |
WO1997032000A3 (fr) | 1997-12-11 |
NZ331625A (en) | 1999-11-29 |
ES2156360T3 (es) | 2001-06-16 |
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