EP0853492A1 - Procede permettant le passage en continu de fluides a haute viscosite lors de la production de produits de polycondensation et pour l'introduction de gaz, l'elimination de gaz dans des fluides a haute viscosite ou la vaporisation desdits fluides - Google Patents
Procede permettant le passage en continu de fluides a haute viscosite lors de la production de produits de polycondensation et pour l'introduction de gaz, l'elimination de gaz dans des fluides a haute viscosite ou la vaporisation desdits fluidesInfo
- Publication number
- EP0853492A1 EP0853492A1 EP96931818A EP96931818A EP0853492A1 EP 0853492 A1 EP0853492 A1 EP 0853492A1 EP 96931818 A EP96931818 A EP 96931818A EP 96931818 A EP96931818 A EP 96931818A EP 0853492 A1 EP0853492 A1 EP 0853492A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- highly viscous
- viscous fluids
- cylindrical
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/785—Preparation processes characterised by the apparatus used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F27/00—Mixers with rotary stirring devices in fixed receptacles; Kneaders
- B01F27/80—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis
- B01F27/94—Mixers with rotary stirring devices in fixed receptacles; Kneaders with stirrers rotating about a substantially vertical axis with rotary cylinders or cones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/84—Venting or degassing ; Removing liquids, e.g. by evaporating components
- B29B7/845—Venting, degassing or removing evaporated components in devices with rotary stirrers
Definitions
- the invention relates to a device in particular for treating melts in the production of polycondensates, comprising a cylindrical or columnar or conical container, at least one cylindrical or columnar or conical stirring element which is rotatably arranged in the container in close proximity to the container wall.
- an apparatus which comprises a thin film polymerization tank, at least one columnar or cylindrical, roller-shaped impeller which rotates along a substantially cylindrical, vertical tank wall and in close proximity thereof, and, in the upper part of the tank, a planetary gear in order to drive the impeller, with the propeller being mounted on the fly.
- a polyester-forming monomer and / or an oligomer thereof in the form of a thin film is dropped onto the inner surface of the tank wall at elevated temperature.
- the agitator blade is moved epicyclically along the tank wall and in the circumferential direction thereof. The monomer begins to polymerize and the resulting polymer melt is withdrawn from the polymerization tank after a certain time, which corresponds to the desired degree of polymerization (cf. also DE 1 495 665).
- the known device has the disadvantages that, due to the flying mounting of the agitator blades, the distance of the agitator blade to the tank wall from top to bottom must be greater, resulting in an uneven layer thickness the melt leads.
- the reactor is also not suitable for the treatment of highly viscous melts, because this would bend the mixing paddle towards the middle of the tank. Thin films can then no longer be produced and the apparatus would also be damaged.
- the invention seeks to remedy this.
- this is done by a device of the type mentioned at the outset, which is characterized in that at least one of the stirring elements is mounted on both sides.
- the invention thus relates to a device for treating melts, in particular in the production of polycondensates, comprising a cylindrical or columnar or conical container, at least one cylindrical or columnar or conical stirring element which is rotatably arranged in the container in close proximity to the container wall, characterized in that at least one of the stirring elements is mounted on both sides.
- Preferred refinements of the device according to the invention result from claims 2 to 4.
- Individual or more of the individual features mentioned in the refinements can each represent independent solutions according to the invention, and the individual features can also be combined as desired.
- the advantage of the invention can be seen essentially in the fact that deflection of the rolls is prevented and that highly viscous melts can thereby be treated.
- the device is particularly suitable for the treatment of highly viscous fluids, in particular for carrying out processes for the production of polycondensates, in particular polyester (PET), by means of melt polymerization, the viscosities also from melts up to 2000 Pas, still thin films can be produced.
- PET polyester
- the device according to the invention it is possible to carry out the polymerization process in such a way that almost the entire surfaces inside the container are continuously rewetted with melt.
- one or both bearings can rotate partially or completely in the melt.
- the device can be operated vertically, inclined or lying.
- Containers and scrambled elements can preferably be cylindrical, conical or barrel-shaped. Cylindrical rollers are particularly suitable as stirring elements. The surfaces of the stirring elements can be smooth or structured, for example in order to move the melt to the outlet of the container with spiral grooves.
- rollers rotating around the container can be supported by a central roller, similar to the sun gear of a planetary gear. This results in a harmonious movement with constantly newly wetted surfaces.
- the rollers can be dragged along and driven by the friction between the inner cylinder wall and the outer cylinder roller wall. It is also possible to drive the rollers from the outside or by sprockets with more effort, so that they run ahead or run after.
- the vapors can be removed or fumigation media can be added.
- the melt moves in the container due to the melt level and / or due to the inclination of the entire device to exit, for example on the end of the container opposite the melt inlet.
- All moving and stationary parts of the apparatus inside the container can be continuously flushed with fluid so that no deposits are formed.
- the device can be erected with a diameter of up to 2.5 or 3 m and a length of up to 7.5 m.
- the device can e.g. at the melting range of polyester (PET), between 250 and 300 ° C and a vacuum of a few millibars or less or with overpressure compared to the environment.
- PET polyester
- the device can e.g. at the melting range of polyester (PET), between 250 and 300 ° C and a vacuum of a few millibars or less or with overpressure compared to the environment.
- Figure 1 an embodiment of the device according to the invention in the axial
- Sectional view Figure 2 a cross section along the plane shown in Figure 1.
- melt is introduced through an inlet 3.
- the melt is evenly distributed on the inner wall of the container 1 and on the outer wall of the cylindrical rollers 4, 5 in that the cylindrical rollers 5 roll on the longitudinal inner wall of the container 1.
- the cylindrical roller package 4, 5 is provided with bearing elements 6 on both sides. It can also be driven on both sides via these bearing elements 6.
- the melt In the operating state, the melt is rolled out as a film on which is constantly form new surfaces. This facilitates gas delivery or absorption from or into the melt.
- the melt is also thoroughly mixed and rolled over by the movement of the cylindrical roller 4, 5. These processes are repeated cyclically, according to the given geometry.
- the central roller 4 on the one hand supports the outer rollers 5, and on the other hand it creates an additional surface for the melt.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
L'invention a pour objet un dispositif pour le traitement de matières en fusion, en particulier lors de la production de polycondensats, ledit dispositif comprenant un récipient cylindrique ou en forme de colonne ou conique, au moins un élément agitateur cylindrique ou en forme de colonne ou conique, monté rotatif dans le récipient, à faible distance des parois de ce récipient. Ce dispositif est caractérisé en ce qu'au moins l'un des éléments agitateurs est monté des deux côtés.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19536790A DE19536790A1 (de) | 1995-10-02 | 1995-10-02 | Vorrichtung zum kontinuierlichen Durchsatz von hochviskosen Fluiden bei der Herstellung von Polykondensationsprodukten und zum Begasen, Entgasen oder Verdampfen von hochviskosen Fluiden |
DE19536790 | 1995-10-02 | ||
PCT/EP1996/004118 WO1997012667A1 (fr) | 1995-10-02 | 1996-09-20 | Procede permettant le passage en continu de fluides a haute viscosite lors de la production de produits de polycondensation et pour l'introduction de gaz, l'elimination de gaz dans des fluides a haute viscosite ou la vaporisation desdits fluides |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0853492A1 true EP0853492A1 (fr) | 1998-07-22 |
Family
ID=7773895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96931818A Withdrawn EP0853492A1 (fr) | 1995-10-02 | 1996-09-20 | Procede permettant le passage en continu de fluides a haute viscosite lors de la production de produits de polycondensation et pour l'introduction de gaz, l'elimination de gaz dans des fluides a haute viscosite ou la vaporisation desdits fluides |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0853492A1 (fr) |
JP (1) | JPH11513301A (fr) |
AU (1) | AU7085896A (fr) |
DE (1) | DE19536790A1 (fr) |
TW (1) | TW366305B (fr) |
WO (1) | WO1997012667A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8679231B2 (en) | 2011-01-19 | 2014-03-25 | Advanced Technology Materials, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL126771C (fr) * | 1965-02-01 | |||
DE2132884A1 (de) * | 1971-07-01 | 1973-01-11 | Yoshio Terauchi | Knet- und/oder mischmaschine |
US3797550A (en) * | 1971-08-16 | 1974-03-19 | Monsanto Co | Wiped film devolatilizer construction |
DE3513536C1 (fr) * | 1985-04-16 | 1987-01-02 | Rudolf Paul 7000 Stuttgart De Fritsch | |
ATA105393A (de) * | 1993-06-01 | 1998-03-15 | Blach Josef Alois | Mischer für viskose flüssigkeiten und massen |
-
1995
- 1995-10-02 DE DE19536790A patent/DE19536790A1/de not_active Withdrawn
-
1996
- 1996-09-20 WO PCT/EP1996/004118 patent/WO1997012667A1/fr not_active Application Discontinuation
- 1996-09-20 AU AU70858/96A patent/AU7085896A/en not_active Abandoned
- 1996-09-20 JP JP9513929A patent/JPH11513301A/ja active Pending
- 1996-09-20 EP EP96931818A patent/EP0853492A1/fr not_active Withdrawn
- 1996-09-30 TW TW085111990A patent/TW366305B/zh active
Non-Patent Citations (1)
Title |
---|
See references of WO9712667A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1997012667A1 (fr) | 1997-04-10 |
AU7085896A (en) | 1997-04-28 |
DE19536790A1 (de) | 1997-04-03 |
TW366305B (en) | 1999-08-11 |
JPH11513301A (ja) | 1999-11-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE4312249C1 (de) | Planetengetriebe für einen Mehrschneckenextruder | |
EP1985738B1 (fr) | Procédé et dispositif de traitement humide d'articles textiles en forme de faisceaux | |
EP0320586A1 (fr) | Appareil pour traiter des substances à forte viscosité | |
DE102006047942B3 (de) | Vorrichtung und Verfahren für die chargenweise Polykondensation von Polymeren | |
DE19919521A1 (de) | Vorrichtung zum Mischen und Entgasen einer fliessfähigen Masse | |
AT411429B (de) | Verfahren und vorrichtung zum extrahieren von stoffen aus flüssigkeiten oder feststoffdispersionen | |
DE2128468B2 (de) | Mischer | |
EP1048342A2 (fr) | Mélangeur pour des masses aptes à couler | |
DE2129336A1 (de) | Verfahren zur Durchführung einer Gas Flussigkeits Kontaktreaktion und da für geeignete Vorrichtung | |
DE2541939C3 (de) | Kontinuierlich arbeitender Mischer für hochviskoses Material | |
DE2449489A1 (de) | Verfahren und vorrichtung zur herstellung von auf enddichte vorplastizierten werkstoffen aus hoch molekularen pulverfoermigen fertigmischungen | |
DE2204558C3 (de) | Vorrichtung zur Polykondensation von flüssigem viskosem Material | |
WO1997012667A1 (fr) | Procede permettant le passage en continu de fluides a haute viscosite lors de la production de produits de polycondensation et pour l'introduction de gaz, l'elimination de gaz dans des fluides a haute viscosite ou la vaporisation desdits fluides | |
DE102018216250B4 (de) | Reaktor zur Entgasung einer Polymerschmelze und Polykondensation | |
DE2817535A1 (de) | Verfahren und vorrichtung zur herstellung von polyurethanschaum | |
DE1925063A1 (de) | Verfahren und Vorrichtung zur Behandlung von Polymeren mittlerer und hoher Viskositaet bei Verfahren der Endkondensation,der Demonomerisation u.dgl. | |
DE1745541A1 (de) | Polykondensationsverfahren und -vorrichtung | |
CH689444A5 (de) | Vorrichtung zur thermischen Behandlung eines viskosen Gutes, insbesondere eines thermoplastischen Elastomers. | |
DE4415220C2 (de) | Verfahren und Vorrichtung zur Herstellung von Polyestern | |
DE1938749A1 (de) | Verfahren und Vorrichtung zur Bildung eines ringfoermigen Fluessigkeitsstromes,der entlang der Innenflaeche einer Rohrwand laeuft | |
EP2625260B1 (fr) | Procédé et dispositif permettant notamment l'empâtage lors de la fabrication de bière | |
DE1642906A1 (de) | Vorrichtung zur Behandlung hochviskoser Substanzen sowie Anwendung dieser Vorrichtung | |
DE1545209C3 (de) | Vorrichtung zur Durchführung von Polykondensationsreaktionen, insbesondere zur Herstellung von Polyester-Kunststoffen | |
WO2004071647A1 (fr) | Dispositif pour traiter un produit particulaire et procede permettant d'actionner ledit dispositif | |
DE60214522T2 (de) | Vorrichtung zum kontinuierlichen Rühren und Verwendung zur kontinuierlichen Polykondensation von Polymerharz |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19980504 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): CH DE LI |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
|
18W | Application withdrawn |
Withdrawal date: 19990123 |