EP0816479B1 - Geschirrspülmittel mit verringerter Neigung zur Gelierung - Google Patents

Geschirrspülmittel mit verringerter Neigung zur Gelierung Download PDF

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Publication number
EP0816479B1
EP0816479B1 EP96870086A EP96870086A EP0816479B1 EP 0816479 B1 EP0816479 B1 EP 0816479B1 EP 96870086 A EP96870086 A EP 96870086A EP 96870086 A EP96870086 A EP 96870086A EP 0816479 B1 EP0816479 B1 EP 0816479B1
Authority
EP
European Patent Office
Prior art keywords
composition according
compositions
composition
gelling
dishes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96870086A
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English (en)
French (fr)
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EP0816479A1 (de
EP0816479B2 (de
Inventor
Suchareeta Patil
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to EP96870086A priority Critical patent/EP0816479B2/de
Priority to DE69633116T priority patent/DE69633116T3/de
Priority to ES96870086T priority patent/ES2227577T5/es
Priority to AT96870086T priority patent/ATE273375T1/de
Priority to PCT/US1997/009697 priority patent/WO1998000488A1/en
Priority to BR9710061A priority patent/BR9710061A/pt
Priority to AU34767/97A priority patent/AU3476797A/en
Priority to CZ984184A priority patent/CZ418498A3/cs
Priority to CN97197278A priority patent/CN1228112A/zh
Priority to JP10504130A priority patent/JPH11513067A/ja
Priority to ARP970102848A priority patent/AR007644A1/es
Publication of EP0816479A1 publication Critical patent/EP0816479A1/de
Publication of EP0816479B1 publication Critical patent/EP0816479B1/de
Publication of EP0816479B2 publication Critical patent/EP0816479B2/de
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3723—Polyamines or polyalkyleneimines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • the invention relates to liquid dishwashing compositions.
  • the compositions have a robust surfactant system, they are relatively soluble in water and have an improved resistance to gelling.
  • Liquid dishwashing compositions having good grease removal benefits are much desired by consumers and it is therefore necessary that these compositions should have a robust surfactant system.
  • Such robust surfactant systems cause an increase in viscosity which renders such compositions inconvenient to use. Therefore, solvents are added which decrease the viscosity of the composition to an acceptable value. But a problem which occurs with these compositions is that the solvent tends to evaporate with time, and thus the compositions tend to gel.
  • compositions which additionally comprise a hydrotrope which improves the solubility (and stability) of the composition.
  • a hydrotrope which improves the solubility (and stability) of the composition.
  • compositions comprising a salt of an alcohol ether sulphate can be diluted without undue problems due to gel formation if a suitable quantity of a compound of molecular weight 500 to 10,000 which comprises at least one polyalkylene glycol chain and at least two ether linkages per seven carbon atoms is present.
  • inorganic salts such as chlorine salts
  • inorganic salts can alleviate the gelling effect to some extent.
  • drawbacks to the use of inorganic salts namely, they can negatively impact the solubility of the compositions, and furthermore can cause formulability or corrosivity problems.
  • liquid dishwashing compositions which comprise a robust surfactant system, which are easy to dissolve and which have an improved resistance to gelling.
  • compositions of the present invention are liquid dishwashing compositions which comprise:
  • the invention further encompasses a method of washing dishes with these compositions.
  • Alkyl ethoxy sulfate surfactant Alkyl ethoxy sulfate surfactant :
  • the compositions herein comprise an alkyl ethoxy sulfate surfactant.
  • Such surfactants are according to formula (1) R 1 O(CH 2 CH 2 O) n SO 3 M wherein, R 1 represents a straight chain or a branched alkyl group or an alkenyl group having 9 to 15 carbons, n represents 0.5 to 7 of real number in average, and M shows an alkalic metal, alkalic earth metal, ammonium group or alkanol substitution ammonium group. If the number of carbons of R 1 is less than 9, the detergency is insufficient, and if more than 16, the stability at low temperature of the composition deteriorates remarkably and is not preferable. Especially, preferable number of carbons is 10 to 13.
  • the desirable range of the number of adduct moles of ethylene oxide is 0.5 to 3.
  • compositions of the present invention comprise from 15% to 60% by weight of the total composition of such surfactant, or mixtures thereof, preferably from 15% to 40%, most preferably 20% to 30%.
  • Amine oxide surfactant :
  • compositions of the invention may further comprise an amine oxide surfactant.
  • an amine oxide surfactant are according to formula (2) wherein R 2 represents a straight chain or a branched alkyl group or an alkenyl group having 10 to 16 carbons, and R 3 and R 4 represent a methyl group or an ethyl group respectively.
  • R 2 represents a straight chain or a branched alkyl group or an alkenyl group having 10 to 16 carbons
  • R 3 and R 4 represent a methyl group or an ethyl group respectively.
  • compositions of the present invention comprise from 0% to 30% by weight of the total composition of such surfactant, preferably 1.5% to 15%, most preferably 1.5% to 10%.
  • compositions of the invention from 0% to 2.0%, preferably 0.1% to 2%, most preferably from 0.3% to 2% by weight of the composition, of magnesium ions may be added to the liquid detergent compositions of the invention for improved product stability, as well as improved sudsing and skin mildness.
  • the magnesium ions are introduced by neutalization of the acid form of alkylethoxy surfactants with a magnesium oxide or magnesium hydroxide slurry in water. Normally, this method is limited by the amount of anionic surfactants in the composition.
  • An alternative method is to use MgCl2, MgSO4 or other inorganic Mg salts. These materials are less desirable because they can cause corrosivity problems (chloride salts), decrease the solubility of the formulations, or cause formulatibility/stability problems in the compositions. It is desirable for these reasons to limit the addition of inorganic salts to less than 2%, preferably less than 1% by weight of the anionic inorganic counterion.
  • compositions of the invention comprise a solvent in an effective amount so that the viscosity of the compositions herein be of from 50 cps to 2000 cps, preferably 100 cps to 450 cps, most preferably from 100 cps to 350 cps, measured at 20°C, with a Brookfield viscometer, spindle no. 18.
  • Suitable solvents for use herein include low molecular weight alcohols such as C 1 -C 10 , preferably C 1 -C 4 mono- and dihydric alcohols, preferably ethyl alcohol, isopropyl alcohol, propylene glycol and hexylene glycol.
  • low molecular weight alcohols such as C 1 -C 10 , preferably C 1 -C 4 mono- and dihydric alcohols, preferably ethyl alcohol, isopropyl alcohol, propylene glycol and hexylene glycol.
  • compositions herein typically comprise from 3% to 20% by weight of the total composition of a solvent, or mixtures thereof, preferably 3% to 15%, most preferably 5% to 10%.
  • compositions of the invention comprise a hydrotrope in an effective amount so that the compositions are appropriately soluble in water.
  • appropriately soluble in water it is meant that the product dissolves quickly enough in water as dictated by both the washing habit and conditions of use. Products which do not dissolve quickly in water can lead to negatives in performance regarding grease cleaning, sudsing, ease of rinsing of product from dishes/glasses etc. or product remaining on dishes/glasses after washing.
  • Suitable hydrotropes for use herein include anionic-type hydrotropes, particularly sodium, potassium, and ammonium xylene sulfonate (preferred), sodium, potassium and ammonium toluene sulfonate, sodium potassium and ammonium cumene sulfonate (most preferred), and mixtures thereof, and related compounds (as disclosed in U.S. Patent 3,915,903).
  • Preferred hydrotropes are selected from sodium cumene sulphanate, sodium xylene sulphanate, sodium toluene sulphanate and mixtures thereof.
  • compositions of the invention typically comprise from 1.5% to 20% by weight of the total composition of a hydrotropic, or mixtures thereof, preferably from 3% to 10%, most preferably from 3% to 6%.
  • Anti-gelling polymer
  • compositions of the invention comprise an anti-gelling polymer which improves the compositions' resistance to gelling.
  • Suitable polymers for use herein have a molecular weight of at least 500, preferably from 500 to 20000, more preferably 1000 to 5000, most preferably 1000 to 3000.
  • compositions herein comprise from 0.5% to 10%, typically 0.5% to 6% by weight of the total composition of an anti-gelling polymer, or mixtures thereof, preferably 0.5% to 4%, most preferably 1.5% to 3%.
  • Suitable polymers for use herein include :
  • ethoxylated polyethylene amine in particular ethoxylated tetraethylenepentamine, and quatemized ethoxylated hexamethylene diamine.
  • Hihgly preferred polymers for use herein are polymers of the formula : in which X can be any suitable capping group, with each X being selected from the group consisting of H, and alkyl or acyl groups containing from 1 to about 4 carbon atoms, preferably 1 to 2 carbon atoms, most preferably alkyl. Furthermore, the alkyl group may contain anionic, cationic or nonionic substituents such as sulphonate, sulphato, ammonium, hydroxy etc. groups. n is selected for water solubility and is a range of values which generally averages from about 10 to about 50, preferably from about 10 to about 25.
  • the R 1 moieties are essentially 1,4-phenylene moieties.
  • the term "the R 1 moieties are essentially 1,4-phenylene moieties” refers to compounds where the R 1 moieties consist entirely of 1,4-phenylene moieties, or are partially substituted with other arylene or alkarylene moieties, alkylene moieties, alkenylene moieties, or mixtures thereof.
  • Arylene and alkarylene moieties which can be partially substituted for 1,4-phenylene include 1,3-phenylene, 1,2-phenylene, 1,8-naphthylene, 1,4-naphthylene, 2,2-biphenylene, 4,4'-biphenylene and mixtures thereof.
  • Alkylene and alkenylene moieties which can be partially substituted include ethylene, 1,2-propylene, 1,4-butylene, 1,5-pentylene, 1,6-hexamethylene, 1,7-heptamethylene, 1,8-octamethylene, 1,4-cyclohexylene, and mixtures thereof.
  • the R 1 moieties consist entirely of (i.e., comprise 100%) 1,4-phenylene moieties, i.e. each R 1 moiety is 1,4-phenylene.
  • suitable ethylene or substituted ethylene moieties include ethylene, 1,2-propylene, 1,2-butylene, 1,2-hexylene, 3-methoxy-1,2-propylene and mixtures thereof.
  • the R 2 moieties are essentially ethylene moieties, or, preferably, 1,2-propylene moieties or mixtures thereof.
  • from about 75% to about 100%, more preferably from about 90% to about 100% of the R 2 moieties are 1,2-propylene moieties.
  • n averages at least about 10, but a distribution of n values is present.
  • the value of each n usually ranges from about 10 to about 50.
  • the value for each n averages in the range of from about 10 to about 25.
  • the most preferred polymers for use herein are polymers according to the formula : wherein X is methyl, n is 16, R 1 is 1,4-phenylene moiety, R 2 is 1,2-propylene moiety and u is essentially between 3 and 5.
  • compositions herein can further comprise a number of optional ingredients described hereinafter.
  • compositions of this invention preferably contain certain co-surfactant to aid in the foaming, detergency, and/or mildness. Included in this category are several anionic surfactants commonly used in liquid or gel dishwashing detergents. Examples of anionic co-surfactants that are useful in the present invention are the following classes :
  • compositions can contain other optional components suitable for use in liquid dishwashing compositions such as perfume, dyes, opacifiers, enzymes, builders and chelants and pH buffering means so that the compositions herein generally have a pH of from 5 to 11, preferably 6.5 to 8.5, most preferably 7 to 8.
  • soiled dishes are contacted with an effective amount, typically from about 0.5 ml. to about 20 ml. (per 25 dishes being treated), preferably from about 3 ml. to about 10 ml., of the detergent composition of the present invention.
  • the actual amount of liquid detergent composition used will be based on the judgement of user, and will typically depend upon factors such as the particular product formulation of the composition, including the concentration of active ingredients in the compositon, the number of soiled dishes to be cleaned, the degree of soiling on the dishes, and the like.
  • the particular product formulation in turn, will depend upon a number of factors, such as the intended market (i.e., U.S., Europe, Japan, etc.) for the composition product.
  • a liquid detergent composition of the invention is combined with from about 2000 ml. to about 20000 ml., more typically from about 5000 ml. to about 15000 ml. of water in a sink having a volumetric capacity in the range of from about 1000 ml. to about 20000 ml., more typically from about 5000 ml. to about 15000 ml.
  • the soiled dishes are immersed in the sink containing the diluted compositions then obtained, where they are cleaned by contacting the soiled surface of the dish with a cloth, sponge, or similar article.
  • the cloth, sponge, or similar article may be immersed in the detergent composition and water mixture prior to being contacted with the dish surface, and is typically contacted with the dish surface for a period of time ranged from about 1 to about 10 seconds, although the actual time will vary with each application and user.
  • the contacting of cloth, sponge, or similar article to the dish surface is preferably accompanied by a concurrent scrubbing of the dish surface.
  • Another method of use will comprise immersing the soiled dishes into a water bath without any liquid dishwashing detergent.
  • a device for absorbing liquid dishwashing detergent such as a sponge, is placed directly into a separate quantity of undiluted liquid dishwashing compositon for a period of time typically ranging from about 1 to about 5 seconds.
  • the absorbing device, and consequently the undiluted liquid dishwashing composition is then contacted individually to the surface of each of the soiled dishes to remove said soiling.
  • the absorbing device is typically contacted with each dish surface for a period of time range from about 1 to about 10 seconds, although the actual dime of application will be dependent upon factors such as the degree of soiling of the dish.
  • the contacting of the absorbing device to the dish surface is preferably accompanied by concurrent scrubbing.
  • compositions are made by mixing the listed ingredients in the listed proportions.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (10)

  1. Flüssige Geschirrspülzusammensetzung, umfassend:
    15% bis 60% eines Alkylethoxysulfat-Tensids;
    0% bis 30% eines Aminoxid-Tensids;
    0% bis 2% Magnesiumionen;
    ein Lösungsmittel in einer wirksamen Menge, sodass die Viskosität der Zusammensetzung 50 cps bis 2.000 cps beträgt;
    ein Hydrotrop in einer wirksamen Menge, sodass die Zusammensetzung zweckentsprechend in Wasser löslich ist; und
    eine antigelierende Menge eines antigelierenden Polymeren, dass die Beständigkeit der Zusammensetzung gegenüber Gelieren verbessert.
  2. Zusammensetzung nach Anspruch 1, umfassend:
    15% bis 60% des Alkylethoxysulfat-Tensids;
    0% bis 30% des Aminoxid-Tensids;
    0% bis 2% der Magnesiumionen;
    3% bis 20% des Lösungsmittels;
    1,5% bis 20% des Hydrotrops; und
    0,5% bis 6% des antigelierenden Polymeren.
  3. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, welche eine Viskosität von 50 cps bis 2.000 cps aufweist.
  4. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, wobei das antigelierende Polymer aus der Gruppe gewählt ist, bestehend aus Polyalkylenglykolen, Polyaminen und Polymeren auf Terephthalatbasis.
  5. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, wobei das antigelierende Polymer ein Molekulargewicht von 500 bis 20.000 besitzt.
  6. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, umfassend 0,5% bis 10% des antigelierenden Polymeren.
  7. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, wobei das Hydrotrop aus der Gruppe gewählt ist, bestehend aus Hydrotropen vom anionischen Typ, vorzugsweise Natriumcumolsulfonat, Natriumxylolsulfonat, Natriumtoluolsulfonat und Mischungen hiervon.
  8. Zusammensetzung nach mindestens einem der vorangehenden Ansprüche, wobei das Lösungsmittel aus der Gruppe gewählt ist, bestehend aus einwertigen und zweiwertigen C1-C10-Alkoholen und Mischungen hiervon.
  9. Verfahren zum Geschirrspülen, bei dem 0,01 ml bis 150 ml einer Zusammensetzung gemäß mindestens einem der vorangehenden Ansprüche in 2.000 ml bis 20.000 ml Wasser verdünnt werden, und das Geschirr in die so erhaltene verdünnte Zusammensetzung eingetaucht und gereinigt wird durch Kontaktieren der verschmutzten Oberfläche des Geschirrs mit einem Tuch, Schwamm oder ähnlichem Gegenstand.
  10. Verfahren zum Geschirrspülen, wobei das Geschirr in ein Wasserbad eingetaucht wird, eine wirksame Menge einer Zusammensetzung gemäß mindestens einem der Ansprüche 1-8 auf einer Vorrichtung absorbiert wird, und die Vorrichtung mit der absorbierten Zusammensetzung einzeln mit der Oberfläche eines jeden Teils des verschmutzten Geschirrs kontaktiert wird.
EP96870086A 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter Neigung zur Gelierung Expired - Lifetime EP0816479B2 (de)

Priority Applications (11)

Application Number Priority Date Filing Date Title
EP96870086A EP0816479B2 (de) 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter Neigung zur Gelierung
DE69633116T DE69633116T3 (de) 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter Neigung zur Gelierung
ES96870086T ES2227577T5 (es) 1996-06-28 1996-06-28 Composiciones lavavajillas con resistencia a la gelificacion mejorada.
AT96870086T ATE273375T1 (de) 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter neigung zur gelierung
AU34767/97A AU3476797A (en) 1996-06-28 1997-06-23 Dishwashing compositions with improved resistance to gelling
BR9710061A BR9710061A (pt) 1996-06-28 1997-06-23 Composições de lavagem de pratos com resistência melhorada a gelação
PCT/US1997/009697 WO1998000488A1 (en) 1996-06-28 1997-06-23 Dishwashing compositions with improved resistance to gelling
CZ984184A CZ418498A3 (cs) 1996-06-28 1997-06-23 Tekutý čistící prostředek se zvýšenou stabilitou proti zgelovatění
CN97197278A CN1228112A (zh) 1996-06-28 1997-06-23 具有改进的抗胶凝性的洗餐具组合物
JP10504130A JPH11513067A (ja) 1996-06-28 1997-06-23 改善された耐ゲル化性を有する皿洗い組成物
ARP970102848A AR007644A1 (es) 1996-06-28 1997-06-27 Composiciones de lavar platos con resistencia mejorada a la gelificacion y metodos de lavar platos utilizando dichas composiciones

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP96870086A EP0816479B2 (de) 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter Neigung zur Gelierung

Publications (3)

Publication Number Publication Date
EP0816479A1 EP0816479A1 (de) 1998-01-07
EP0816479B1 true EP0816479B1 (de) 2004-08-11
EP0816479B2 EP0816479B2 (de) 2008-10-01

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ID=8226154

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96870086A Expired - Lifetime EP0816479B2 (de) 1996-06-28 1996-06-28 Geschirrspülmittel mit verringerter Neigung zur Gelierung

Country Status (11)

Country Link
EP (1) EP0816479B2 (de)
JP (1) JPH11513067A (de)
CN (1) CN1228112A (de)
AR (1) AR007644A1 (de)
AT (1) ATE273375T1 (de)
AU (1) AU3476797A (de)
BR (1) BR9710061A (de)
CZ (1) CZ418498A3 (de)
DE (1) DE69633116T3 (de)
ES (1) ES2227577T5 (de)
WO (1) WO1998000488A1 (de)

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Publication number Priority date Publication date Assignee Title
AR017745A1 (es) 1999-02-08 2001-09-12 Procter & Gamble Composiciones detergentes para lavar vajilla, que contienen diaminas organicas y magnesio, para una mejor limpieza con aguas blandas.
JP2002201498A (ja) * 2000-12-21 2002-07-19 Clariant Internatl Ltd 石灰石鹸分散剤及びこれを含有する洗浄剤組成物並びに清掃剤組成物
JP3255637B1 (ja) * 2001-01-23 2002-02-12 花王株式会社 液体洗浄剤組成物
EP1370636A1 (de) 2001-03-21 2003-12-17 The Procter & Gamble Company Zusammensetzung zum manuellen reinigen von geschirr
WO2003104375A1 (en) * 2002-06-05 2003-12-18 The Procter & Gamble Company Surface treating compositions and methods for using same
JP4514436B2 (ja) * 2003-11-21 2010-07-28 ライオン株式会社 液体洗浄剤組成物
JP3987028B2 (ja) * 2003-12-12 2007-10-03 花王株式会社 液体洗浄剤組成物
DE102005027605A1 (de) * 2005-06-15 2006-12-28 Clariant Produkte (Deutschland) Gmbh Geschirrspülmittelformulierungen enthaltend Oligoester
EP1969105B1 (de) * 2005-11-15 2009-06-17 The Procter and Gamble Company Flüssigdetergenzmittel mit natürlich basiertem alkyl- oder hydroxyalkylsulfat- oder sulfonattensid und mittkettig verzweigten aminooxidtensiden
EP2014753A1 (de) * 2007-07-11 2009-01-14 The Procter and Gamble Company Flüssiges Reinigungsmittel
JP4628486B2 (ja) 2009-04-17 2011-02-09 花王株式会社 液体洗浄剤組成物
JP4897933B1 (ja) 2011-04-22 2012-03-14 花王株式会社 液体洗浄剤組成物
DE102016204272A1 (de) * 2016-03-15 2017-09-21 Henkel Ag & Co. Kgaa Aminoxid-haltige Reinigungsmittel
EP3663383B1 (de) 2018-12-05 2021-01-20 The Procter & Gamble Company Flüssige handgeschirrspülmittelzusammensetzung
EP3971273B1 (de) 2020-09-17 2023-01-25 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung
PL3971271T3 (pl) 2020-09-17 2023-03-20 The Procter & Gamble Company Płynna kompozycja czyszcząca do ręcznego zmywania naczyń
EP3971275B1 (de) 2020-09-17 2022-11-02 The Procter & Gamble Company Flüssige handspülreinigungszusammensetzung

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US4368147A (en) * 1974-10-03 1983-01-11 Colgate-Palmolive Company Liquid detergent of controlled viscosity
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EP0059043B1 (de) * 1981-02-19 1985-08-21 Imperial Chemical Industries Plc Oberflächenaktive Zusammensetzungen
FR2588013B1 (fr) * 1985-10-01 1988-05-13 Zschimmer Schwarz France Compositions tensio-actives liquides aptes a former des dilutions aqueuses visqueuses notamment pour le nettoyage de la vaisselle
EP0656046A4 (de) * 1992-08-21 1995-09-20 Procter & Gamble Konzentrierte flüssigwaschmittelzusammensetzung alkylethersulfat enhaltend and verfahren zur herstellung dieser zusammensetzung.
US5415801A (en) † 1993-08-27 1995-05-16 The Procter & Gamble Company Concentrated light duty liquid or gel dishwashing detergent compositions containing sugar
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US5534197A (en) † 1994-01-25 1996-07-09 The Procter & Gamble Company Gemini polyhydroxy fatty acid amides
US5512699A (en) † 1994-01-25 1996-04-30 The Procter & Gamble Company Poly polyhydroxy fatty acid amides
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PE6995A1 (es) † 1994-05-25 1995-03-20 Procter & Gamble Composicion que comprende un polimero de polialquilenoamina etoxilado propoxilado como agente de separacion de sucio

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ES2227577T5 (es) 2009-04-01
CN1228112A (zh) 1999-09-08
AR007644A1 (es) 1999-11-10
JPH11513067A (ja) 1999-11-09
AU3476797A (en) 1998-01-21
EP0816479A1 (de) 1998-01-07
ATE273375T1 (de) 2004-08-15
DE69633116T2 (de) 2005-07-28
BR9710061A (pt) 1999-08-10
ES2227577T3 (es) 2005-04-01
DE69633116D1 (de) 2004-09-16
WO1998000488A1 (en) 1998-01-08
EP0816479B2 (de) 2008-10-01
DE69633116T3 (de) 2009-07-02
CZ418498A3 (cs) 1999-07-14

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