EP0804659B1 - Couverture en zinc pour toiture - Google Patents
Couverture en zinc pour toiture Download PDFInfo
- Publication number
- EP0804659B1 EP0804659B1 EP95942113A EP95942113A EP0804659B1 EP 0804659 B1 EP0804659 B1 EP 0804659B1 EP 95942113 A EP95942113 A EP 95942113A EP 95942113 A EP95942113 A EP 95942113A EP 0804659 B1 EP0804659 B1 EP 0804659B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- polyester
- paint
- acrylic
- thickness
- micrometres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 239000011701 zinc Substances 0.000 title claims abstract description 41
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 41
- 238000000576 coating method Methods 0.000 claims abstract description 40
- 239000011248 coating agent Substances 0.000 claims abstract description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000728 polyester Polymers 0.000 claims description 26
- 239000003973 paint Substances 0.000 claims description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- 239000002313 adhesive film Substances 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 13
- 229920002635 polyurethane Polymers 0.000 claims description 12
- 239000004814 polyurethane Substances 0.000 claims description 12
- -1 polyethylene Polymers 0.000 claims description 10
- 229920001296 polysiloxane Polymers 0.000 claims description 10
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000004593 Epoxy Substances 0.000 claims description 6
- 239000002033 PVDF binder Substances 0.000 claims description 6
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 6
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 6
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 5
- 229920001944 Plastisol Polymers 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 5
- 239000008397 galvanized steel Substances 0.000 claims description 5
- 229920001684 low density polyethylene Polymers 0.000 claims description 5
- 239000004702 low-density polyethylene Substances 0.000 claims description 5
- 239000004999 plastisol Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920002620 polyvinyl fluoride Polymers 0.000 claims description 5
- 238000004381 surface treatment Methods 0.000 claims description 5
- 239000000463 material Substances 0.000 abstract description 4
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- 238000009833 condensation Methods 0.000 description 7
- 230000005494 condensation Effects 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 5
- 239000004567 concrete Substances 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 241001163841 Albugo ipomoeae-panduratae Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
- E04D3/24—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like
- E04D3/30—Roof covering by making use of flat or curved slabs or stiff sheets with special cross-section, e.g. with corrugations on both sides, with ribs, flanges, or the like of metal
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D3/00—Roof covering by making use of flat or curved slabs or stiff sheets
- E04D3/02—Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant
- E04D3/16—Roof covering by making use of flat or curved slabs or stiff sheets of plane slabs, slates, or sheets, or in which the cross-section is unimportant of metal
Definitions
- the present invention relates to a roof comprising a covering support on which a cover is laid, the cover comprising an assembly of sheets of zinc or galvanized steel having one side facing said support, said side being provided with a organic coating.
- Zinc covers are traditionally placed on ventilated fir supports. AT because of the high cost of this traditional support, we are looking to replace it with supports cheaper, in particular non-ventilated supports possibly not compatible with the zinc or galvanized steel such as particle board, plywood, concrete and rigid insulation. However, many corrosion phenomena of zinc coverings have been reported on these non-ventilated supports. To solve these problems it would be necessary, according to document EP-B-0410822, to improve the ventilation between the support of cover and zinc plates to avoid condensation and to isolate the zinc from the support non-ventilated, especially if the support is made of concrete.
- the object of the present invention is to provide a blanket as defined above, which avoids the disadvantages mentioned above.
- said support is non-ventilated and said covering has a thickness of 50 to 150 micrometers, is elastic, durable and waterproof to water vapor, the other side of the sheets being either uncoated or coated by any surface treatment process applied for purely aesthetic purposes.
- the coating quality it is highly recommended that it be applied continuously, in particular between a unwinding station and a winding station, at the zinc sheet producer or in a workshop specializing in application of coatings; the elasticity of the coating must therefore be such that the coated sheet can undergo, on the site or in the workshop of the roofer-zinc-worker, the shaping operations necessary for its installation without the coating being damaged. It is obvious that the coating must be hard enough so that the various manipulations, that the coated sheet must undergo until it is finally placed on the support, do not leave traces in the coating or in any case not deep traces. The thickness of at least 50 micrometers is essential to avoid for sure that possible small scratches undergone as a result of the above manipulations can not discover zinc.
- the coating cannot crack or flake, as it is essential that it remains waterproof to water vapor. It should be noted here that there is a perfect synergy between the zinc sheet and its coating in the sense that they protect each other against the worst of their respective enemies, namely ultraviolet radiation in the case coating and condensation in the case of zinc or galvanized steel.
- Document DE-A-3444669 describes strips of plastic covering of a thickness of about 5 mm, protected by a metallic film of about 0.05 mm on the face outside.
- the metallic film protects the synthetic material from atmospheric influences and also plays an aesthetic role.
- the document recommends a flexible synthetic material and foamy such as polyethylene or expanded polyurethane to promote insulation thermal and sonic; the metallic film can be copper, stainless steel or alloys based on aluminum. This document does not address the issue of ventilation of the media. roofing.
- Document FR-A-2471859 describes a metal sheet with composite coating for use in the production of exterior building materials.
- This sheet metal carries a coating of a composition containing a chloride resin polyvinyl, a powdered metal, a plasticizer and a stabilizing agent, this product having a excellent resistance to atmospheric factors, as shown by a test of accelerated aging entitled "Sunshine Weather Meter Test".
- galvanized sheets covered with either a layer of resin-based paint thermosetting, either a polyvinyl chloride film and / or polyacrylate do not not always suitable from an economic point of view and as regards their resistance for the production of exterior building materials.
- the coating may consist of a layer of paint based on polyester (standard symbol: SP), silicone polyester (SPSI), polyester polyamide (SPPA), epoxy (EP), polyurethane (PUR), polyvinylidene fluoride (PVDF) organosol chloride vinyl (PVCO), vinyl chloride plastisol (PVCP), acrylic (AY) or silicone acrylic (AYS), the thickness of the layer in the dry state being advantageously from 50 to 70 micrometers.
- the painting is advantageously carried out continuously at the sheet producer or in a painting workshop by depositing the paint in liquid or powder form and baking subsequent by passage through an oven. Preference is given to polyester paint deposited in powder form. Such a paint is marketed under the name "Beckryspeed®" by the firm BICHON S.A.
- the coating can also consist of an adhesive film of polyvinyl chloride (PVCF), polyvinyl fluoride (PVFF), acrylic (PMMAF), polyethylene (PEF), polyurethane or polyester, the thickness of the film advantageously being from 80 to 150 micrometers.
- PVCF polyvinyl chloride
- PVFF polyvinyl fluoride
- PMMAF acrylic
- PETF polyethylene
- polyurethane polyurethane
- polyester polyurethane or polyester
- the thickness of the film advantageously being from 80 to 150 micrometers.
- the application of film is advantageously carried out continuously by the sheet producer. Preference is granted to polyethylene film.
- An example of such a film is the low polyethylene adhesive film. density with a thickness of 100 micrometers, which is sold under the reference 4118 by NOVACEL S.A. for economic reasons, adhesive film coating is prefer to paint coating.
- the coating can also consist of a layer of paint as defined above, which is itself covered with an adhesive film as defined above. Needless to say, such coating is even more effective than coating with paint or adhesive film.
- the other side of the sheet is either uncoated or coated with any surface treatment process applied for purely aesthetic purposes. This is how example that this face can be prepatinated.
- the present invention also relates to the use of zinc or steel sheets galvanized, one side of which is provided with a coating as defined and described above and of which the other side is either uncoated or coated for purely aesthetic purposes, for the realization of the cover according to the invention, this embodiment comprising the operations of shaping the sheets necessary for their laying and the laying proper of the shaped sheets.
- the shaping and laying of coated sheets, supplied by the sheet producer, can be do according to current practice.
- a roll of rolled zinc is unwound on a line of finishing together with a roll of plastic film of the same width which includes one side covered with adhesive.
- the film After unwinding, the film is plated on the rolled zinc by means of a set of rollers pressers and the whole is rewound into a reel. This coil will then be cut into width and length suitable for use on construction sites.
- the thickness of zinc is that commonly used for roofing, between 0.65 and 1 mm.
- the plastic film is made of low density polyethylene 100 micrometers thick.
- the adhesive is a mixture of rubber and resin 10 micrometers thick.
- Zinc samples coated with the film were placed in an oven, at 100 ° C. for 6 months, either at 70 ° C for 8 months, or at 40 ° C for 15 months, durations which correspond to more than 10 years of real site exposure on a cover.
- Zinc samples coated with the film were placed in an oven for 60 days, ie at 90 ° C. either at 100 ° C. Beforehand we made folds and stampings on the samples to simulate the deformations that the product will undergo on a site.
- Film coated zinc samples underwent temperature cycles from -20 ° C to + 90 ° C to simulate in real time what is actually happening on a blanket. After 300 cycles (1400 hours) it can be seen that the film has remained well adhered. After 5 days of Kestemich trial (5 cycles) it is noted after removal of the film that the protected face is not corroded then that the other is excessively.
- a zinc coil After rolling, a zinc coil is subjected to a surface treatment operation by conversion, giving on both sides a surface layer of zinc phosphate, i.e. light gray in color, or dark gray in color, the zinc thus obtained being called prepatinated zinc.
- the pre-patinated zinc is rewound into a coil.
- the pre-weathered zinc coil undergoes the same operations as the rolled zinc coil in Example 1 and the material thus obtained is subjected to the same tests as the material obtained in example 1: the same results are obtained as in example 1.
- the zinc coil coated with example 1 was used to make a cover above a room in which water vapor has been produced.
- the interior of the room is maintained at 30 ° C with a relative humidity of 100% and its walls are thermally insulated so that moisture condenses preferentially on the face rolled zinc protected by the film.
- a roll of rolled zinc is unwound at a speed of 5m / min on a lacquering installation including a surface preparation station (degreasing, chemical conversion, rinsing, drying), a powder coating booth with powder guns for depositing on a face of rolled zinc a layer of more than 50 micrometers of powder, a polymerization oven at 250 ° C, a cooler and a rewinder. This coil will then be cut into width and length suitable for use on construction sites.
- the thickness of rolled zinc is that commonly used for roofing, between 0.65 and 1 mm.
- the powder is a "Beckryspeed®" polyester powder specially made to combine the performance and benefits of powder to continuous application technology. The following tests confirm the good performance of the coating. They were carried out on flat test pieces with a coating of 60 micrometers, including an Erichsen stamping according to ISO 1520, an impact stamping according to ISO 6272, and an OT fold on a side.
- test pieces underwent the accelerated salt spray corrosion test according to the NFX standard. 41002 for 1000 hours. After the test, it is found that the appearance of the coating has not been modified, even on deformed areas, when the unprotected side has been excessively corroded.
- test pieces underwent the Kestemich test, according to DIN 50017 for 1000 hours (42 cycles). After the test, it can be seen that the appearance of the coating has not been changed, even on the deformed areas, while the unprotected face has been uniformly corroded by the condensation, by the formation of white rust.
- Example 4 The operations and tests of Example 4 are repeated, but starting this time with a coil of pre-patinated zinc and the same results are obtained as in Example 4.
- Example 4 The operations and tests of Example 4 are repeated, but in the powder installation, between the cooler and the rewinder, an adhesive film is continuously deposited on the coated side low density polyethylene 50 microns thick. We get the same results as in example 4.
- Example 6 The operations and tests of Example 6 are repeated, but starting this time with a coil of pre-patinated zinc. The same results are obtained as in Example 4.
- Example 3 The operations of Example 3 are repeated, but this time using the coated zinc coil of example 4. We arrive at the same result as in example 3.
Landscapes
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Glass Compositions (AREA)
- Roof Covering Using Slabs Or Stiff Sheets (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Non-Insulated Conductors (AREA)
- Primary Cells (AREA)
- Physical Vapour Deposition (AREA)
- Coating With Molten Metal (AREA)
- Building Environments (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Arc Welding In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9415568A FR2728604A1 (fr) | 1994-12-23 | 1994-12-23 | Couverture en zinc pour toiture |
| FR9415568 | 1994-12-23 | ||
| PCT/EP1995/004886 WO1996020320A1 (fr) | 1994-12-23 | 1995-12-07 | Couverture en zinc pour toiture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0804659A1 EP0804659A1 (fr) | 1997-11-05 |
| EP0804659B1 true EP0804659B1 (fr) | 1999-03-17 |
Family
ID=9470183
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95942113A Expired - Lifetime EP0804659B1 (fr) | 1994-12-23 | 1995-12-07 | Couverture en zinc pour toiture |
Country Status (16)
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10082678D2 (de) * | 1999-09-02 | 2002-11-21 | Nanogate Gmbh | Ein der Witterung ausgesetzter Dachbaustoff, insbesondere Dachziegel, oder andere glatte oder poröse und/oder mikrostrukturierte Dachbaustoffe |
| EP1460196A1 (en) * | 2003-03-21 | 2004-09-22 | Icopal A/S | A metal roofing element |
| CN102409810A (zh) * | 2011-12-07 | 2012-04-11 | 常熟市东涛金属复合材料有限公司 | 一种复合金属瓦 |
| ES2544006B2 (es) * | 2015-03-31 | 2016-01-12 | Asturiana De Laminados, S.A. | Productos laminados basados en zinc y utilización de los mismos |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH634120A5 (en) * | 1979-03-01 | 1983-01-14 | Neomat Ag | Process for surface coating a roof snow guard |
| GB2065155B (en) * | 1979-12-17 | 1984-02-29 | Toyo Kohan Co Ltd | Coated or laminated metal sheet for use as a building material |
| IT8123129U1 (it) * | 1981-10-06 | 1983-04-06 | Fiorio Guido | Elemento di copertura per tetti di edifici |
| DE3444669A1 (de) * | 1984-12-07 | 1986-06-12 | Karl 6920 Sinsheim Serwane | Deckung fuer daecher, gebaeudefassaden u.a. |
| FR2650319B1 (fr) * | 1989-07-26 | 1991-11-08 | Vieille Montagne France Sa | Couverture metallique pour toiture et supports pour une telle couverture |
| DE4014711A1 (de) * | 1990-05-08 | 1990-11-29 | Gerhard Fabritz | Dachdeckungselement |
-
1994
- 1994-12-23 FR FR9415568A patent/FR2728604A1/fr active Granted
-
1995
- 1995-12-07 WO PCT/EP1995/004886 patent/WO1996020320A1/fr active IP Right Grant
- 1995-12-07 EP EP95942113A patent/EP0804659B1/fr not_active Expired - Lifetime
- 1995-12-07 ES ES95942113T patent/ES2133178T3/es not_active Expired - Lifetime
- 1995-12-07 PL PL95320788A patent/PL320788A1/xx unknown
- 1995-12-07 DE DE69508437T patent/DE69508437T2/de not_active Expired - Lifetime
- 1995-12-07 SK SK822-97A patent/SK284822B6/sk not_active IP Right Cessation
- 1995-12-07 CN CN95197622A patent/CN1079476C/zh not_active Expired - Lifetime
- 1995-12-07 DK DK95942113T patent/DK0804659T3/da active
- 1995-12-07 AU AU43430/96A patent/AU4343096A/en not_active Abandoned
- 1995-12-07 AT AT95942113T patent/ATE177810T1/de active
- 1995-12-07 JP JP52015196A patent/JP3803778B2/ja not_active Expired - Fee Related
- 1995-12-07 HU HU9702105A patent/HU220542B1/hu not_active IP Right Cessation
- 1995-12-07 CZ CZ19971949A patent/CZ287617B6/cs not_active IP Right Cessation
-
1997
- 1997-06-20 NO NO19972918A patent/NO310118B1/no not_active IP Right Cessation
-
1999
- 1999-06-10 GR GR990401578T patent/GR3030503T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NO972918D0 (no) | 1997-06-20 |
| WO1996020320A1 (fr) | 1996-07-04 |
| DE69508437T2 (de) | 1999-10-28 |
| NO310118B1 (no) | 2001-05-21 |
| GR3030503T3 (en) | 1999-10-29 |
| CZ287617B6 (en) | 2001-01-17 |
| HUT77267A (hu) | 1998-03-02 |
| NO972918L (no) | 1997-08-25 |
| EP0804659A1 (fr) | 1997-11-05 |
| SK82297A3 (en) | 1998-02-04 |
| FR2728604B1 (enrdf_load_stackoverflow) | 1997-02-21 |
| PL320788A1 (en) | 1997-10-27 |
| CN1079476C (zh) | 2002-02-20 |
| ATE177810T1 (de) | 1999-04-15 |
| CZ194997A3 (en) | 1997-11-12 |
| FR2728604A1 (fr) | 1996-06-28 |
| DK0804659T3 (da) | 1999-10-11 |
| JPH11503500A (ja) | 1999-03-26 |
| CN1175297A (zh) | 1998-03-04 |
| SK284822B6 (sk) | 2005-12-01 |
| ES2133178T3 (es) | 1999-09-01 |
| HU220542B1 (hu) | 2002-03-28 |
| HK1008232A1 (en) | 1999-05-07 |
| AU4343096A (en) | 1996-07-19 |
| JP3803778B2 (ja) | 2006-08-02 |
| DE69508437D1 (de) | 1999-04-22 |
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Legal Events
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