Classifications

• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/37—Polymers
  • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
  • C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
  • C11D3/16—Organic compounds
  • C11D3/36—Organic compounds containing phosphorus
  • C11D3/361—Phosphonates, phosphinates or phosphonites
• • C—CHEMISTRY; METALLURGY
  • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
  • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
  • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
  • C11D7/02—Inorganic compounds
  • C11D7/04—Water-soluble compounds
  • C11D7/06—Hydroxides

Definitions

• the present invention relates to a method of cleaning glass containers.
• the conventional cleaning solution usually contains about 1% by weight of sodium hydroxide and an anti-foam agent and is applied at a temperature of around 80°C. It is often applied by a soaking stage followed by a spray stage, prior to rinsing, or else by just spraying before rinsing.
• scuffing which produces whitish circles or part-circles around the exterior of the bottle. It is believed that scuffing is produced partly by chemical errosion of the glass surface by the cleaning solution and partly by mechanical abrasion, e.g. between the bottles themselves or between the bottles and parts of the cleaning apparatus.
• a method of cleaning glass containers in a continuous-feed process comprising the step of applying to the containers, an aqueous composition comprising an alkaline agent and a weak sequestrant.
• glass items e.g. drinking glasses
• domestic or industrial warewashing compositions which contain inter alia alkaline agents and sequestrants.
• this is not in a continuous-feed process where the aforementioned scuffing problem occurs (see e.g. CH-A-0-679-311).
• the aqueous composition contains from 0.1% to 10% by weight of the alkaline agent, more preferably from 0.5% to 5% by weight and especially from 0.75% to 1.5% by weight.
• the aqueous composition contains from 50 to 1000 ppm by weight of the weak sequestrant, more preferably from 100 to 500 ppm by weight and especially from 200 to 400 ppm by weight.
• the weak sequestrant may for example comprise one or more agents selected from polyacrylate-type sequestrants and phosphonate sequestrants.
• Preferred polyacrylate-type sequestrants include polyacrylic acids or polyacrylates, especially low molecular weight polyacrylates, e.g. MW ⁇ 10,000, e.g. Sokalan PA15 ex BASF or Norasol LMW45 ex Norso-Haas, and maleic anhydride/(meth)acrylic acid copolymers, e.g. Sokalan CP5 ex BASF.
• Suitable phosphonate sequestrants include the range sold under the "Dequest" Trade Mark, ex Monsanto.
• Suitable alkaline agents include alkali metal hydroxides, e.g. sodium or potassium hydroxides, alkali metal silicates, including metasilicates, e.g. sodium silicate having a mole ratio of SiO 2 :Na 2 O of about 3.3:1 or less, including from about 1.8:1 to about 2.2:1 (normally referred to as sodium disilicate).
• Sodium hydroxide is especially preferred.
• the alkaline agent could comprise two or more different such materials.
• an aqueous composition for continuous-feed cleaning of glass containers comprising from 0.5% to 10% by weight of an alkaline agent and from 50 to 1000 ppm by weight of a weak sequestrant.
• alkaline agent and weak sequestrant for such a composition are as indicated above.
• composition used in the method of the present invention may also contain some non-ionic anti-foam and/or wetting agent, for example in a weight ratio of from 1:50 to 1:10 relative to the weak sequestrant. It is also possible for the composition to contain one or more other minor ingredients which are usual in such compositions. However, often the composition will be substantially free of other ingredients.
• the step applying the aqueous composition to the glass containers will be followed by a rinsing step, preferably using water, optionally including a rinse aid.
• a rinsing step preferably using water, optionally including a rinse aid.
• the aqueous composition itself is conveniently prepared by diluting a pre-concentrated aqueous solution of the weak sequestrant with an aqueous solution of the alkaline agent.
• the latter will normally contain all of the alkaline agent to be present in the final solution and all of the water, except for the amount contained in the pre-concentrated aqueous solution of the sequestrant.
• the method of the present invention can be applied to the continuous-feed cleaning of any glass containers, for example beverage containers but one useful example is in the cleaning of beer bottles.
• aqueous solution of 15% by weight weak sequestrant (being either variant (a) polyacrylate sequestrant, i.e. Sokalan PA15 ex BASF, av MW 1500 or variant (b) phosphonate sequestrant, i.e. Dequest 2000 ex Monsato) was diluted in a bath with a 2% by weight aqueous solution of sodium hydroxide containing non-ionic anti-foam agent, such that the amount of weak sequestrant in final solution was 300 ppm by weight. The amount of anti-foam in final solution was in the weight ratio of 2:15 relative to the sequestrant.
• weak sequestrant being either variant (a) polyacrylate sequestrant, i.e. Sokalan PA15 ex BASF, av MW 1500 or variant (b) phosphonate sequestrant, i.e. Dequest 2000 ex Monsato
• the amount of anti-foam in final solution was in the weight ratio of 2:15 relative to the sequestrant.
• the final solution in each case was applied to beer bottles in an industrial bottle washing machine at a maximum temperature of 80°C, first in a soaking step and then in a spray step. This cleaning process was followed by rinsing using softened water at 40°C as a first rinse step and then cold fresh softened water as a second rinse step.
• 0.3 litre Dutch standard beer bottles were subjected to alternate mechanical and chemical conditions, for both a control bottle batch and a bottle batch subjected to chemical conditions according to the present invention, whereafter the level of scuffing was assessed both visually and by a charge coupled device (CCD) camera.
• CCD charge coupled device
• the CCD camera recorded the number of non reflective pixels on the bottle. On the basis of this figure the bottle was classified into a scuffing category.
• the bottles were subjected to mechanical conditions by placement on a 10 meter conveyor loop for 10 minutes.
• Chemical control conditions consisted of soaking 50 control bottles in a 1% solution of NaOH in soft water ( ⁇ 1° german hardness) at 80°C.
• the chemical conditions consisted of soaking 50 bottles in 1% solution of NaOH plus 0.2% of the formulation A.
• Formulation A Nitrilotrimethylene phosphonic acid 15.0% Sodium cumene sulphonate 3.6% Non ionic surfactant 2.0% Distilled water rest
• Visual level 5 is considered to be the maximum acceptable level for bottles.
• the bottles were put into crates which were put at the beginning of the washing line.
• the bottles followed the standard route of: decrater, bottlewasher, filler, tunnel pasteurizer, labeling machine, crate packer.
• the bottles were collected from the filled crates, emptied and reintroduced at the beginning of the line.
• the chemical treatment consisted of washing the bottles in a regular bottlewasher at the conditions and temperatures prescribed.
• the bottles were also assessed by using the CCD camera to determine scuffing levels as described before.
• the bottlewashing conditions in the control were: 1 ⁇ 0.1% NaOH solution, temperature 80 ⁇ 1°C.

Landscapes

• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Engineering & Computer Science (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Oil, Petroleum & Natural Gas (AREA)
• Wood Science & Technology (AREA)
• Life Sciences & Earth Sciences (AREA)
• Inorganic Chemistry (AREA)
• Detergent Compositions (AREA)
• Cleaning By Liquid Or Steam (AREA)
• Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)
• Cleaning Or Drying Semiconductors (AREA)
• Mechanical Treatment Of Semiconductor (AREA)

Applications Claiming Priority (3)

Publications (2)

Family

ID=10764750

Family Applications (1)

Country Status (9)

Families Citing this family (5)

Family Cites Families (1)

• 1994
  • 1994-11-21 GB GB9423495A patent/GB9423495D0/en active Pending
• 1995
  • 1995-11-16 DE DE69516537T patent/DE69516537T2/de not_active Revoked
  • 1995-11-16 ES ES95940201T patent/ES2145937T3/es not_active Expired - Lifetime
  • 1995-11-16 AU AU41735/96A patent/AU4173596A/en not_active Abandoned
  • 1995-11-16 EP EP95940201A patent/EP0793711B1/en not_active Revoked
  • 1995-11-16 BR BR9509693A patent/BR9509693A/pt not_active Application Discontinuation
  • 1995-11-16 WO PCT/EP1995/004537 patent/WO1996016159A1/en not_active Application Discontinuation
  • 1995-11-17 ZA ZA959795A patent/ZA959795B/xx unknown
• 1997
  • 1997-05-19 FI FI972124A patent/FI972124A0/fi unknown

Also Published As

Similar Documents

Legal Events