EP0793702A2 - Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation - Google Patents
Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperationInfo
- Publication number
- EP0793702A2 EP0793702A2 EP96938004A EP96938004A EP0793702A2 EP 0793702 A2 EP0793702 A2 EP 0793702A2 EP 96938004 A EP96938004 A EP 96938004A EP 96938004 A EP96938004 A EP 96938004A EP 0793702 A2 EP0793702 A2 EP 0793702A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- stones
- refractory lining
- claws
- lining according
- shaped
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
- F22B1/1846—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations the hot gas being loaded with particles, e.g. waste heat boilers after a coal gasification plant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Definitions
- the invention relates to a refractory lining in the transition section of a carburetor to the waste heat boiler with brackets for fastening refractory shaped bricks.
- the transition from the carburetor to the waste heat boiler is flowed through both by the hot synthesis gas and by hot slag.
- the temperatures in this transition section are over 1400 ° C.
- the transition between the reactor vessel and the synthesis gas cooler is lined with a refractory delivery made of molded bricks from a reactor vessel supplied by the applicant for the Ruhr synthesis gas plant (SAR) of Ruhrchemie in Oberhausen-Holten with a subsequent waste heat boiler of a synthesis gas cooler.
- SAR Ruhr synthesis gas plant
- the upper shaped stones are each placed in a ring on cast brackets, which are attached one above the other at the nozzle end of the carburetor and at the nozzle end of the synthesis gas cooler.
- the shaped stones in the area of the cooling tube cage are on circumferential tube lugs
- REPLACEMENT BLA ⁇ (RULE 26) Transition from vertical cooling pipes to the horizontal cooling pipe wall.
- the thermal stresses caused by high temperatures and the resulting ff material movements are directly on the high-pressure parts on the water side , for example the tubes of the cooling tube cage, transferred; Furthermore, the entire weight of the stones weighs on the supports. Furthermore, the upper fixed points (brackets) at the transition between the two vessels are uncooled and are subject to increasing overheating as the ff material wears down.
- the object of the invention is therefore to design the refractory lining in the transition section between the reactor and the synthesis gas cooler in such a way that the stresses in the ff material are reduced, the dead weight of the stones is distributed over various conditions, a compensation of the relative movements between the ff stones and the Mounts done, rugged
- brackets are not attached to water-carrying components (boiler pipes) and the so-called main claw is protected from overheating by additional cooling.
- the refractory area consists of three different, side by side stone layers in the uncooled nozzle as well as different Special shaped stones, shoulder shaped stones and normal stones, which are matched to the conditions of temperature, wear, internal and external pressure and service life.
- the refractory stone lining is supported on the connection piece and on the cooling tube cage of the synthesis gas cooler by a stone holding system, which consists of consoles arranged one above the other in the area of the cooling tube
- the supports for the ff-stones are distributed on different levels in order to distribute the stone weights and to keep local stresses low
- the stone brackets are on the webs between the water-side high-pressure parts (boiler pipes)
- REPLACEMENT3LATT (RULE26) - Design of a drip nose at the lower exit of the cooling tube cage so that the slag does not crawl along the horizontal wall and slag this as well as the bulkhead walls and the tube cage.
- Fig. 2 shows a section through the ff material at the transition from the carburetor to the waste heat boiler.
- an ff lining which consists of a number of normal and shaped stones, is introduced in the transition section between the carburetor (1) and the waste heat boiler (4).
- the transition section consists on the outside of the uncooled carburetor socket (2) and the cooled pipe cage (5) in the upper part of the waste heat boiler (3, 4).
- the ff lining is supported in the tube cage (5) by consoles (9) arranged one above the other, which are welded to the webs (tube-web-tube welding) of the tube cage (5).
- expansion joints (27) are provided below each of the brackets (9), while an annular, ceramic fiberboard (6) is inserted between the ff lining at the transition to the nozzle (2).
- An ff ramming compound (24) or the like is applied between the upper part of the tube cage (5) and the cooling system (10, 11, 12).
- FIG. 2 shows the structure of the ff lining in the transition section from the carburetor (2) and inlet connection (3) of the waste heat boiler (4).
- the ff-lining is held by claws (8), which are protected from overheating by a cooling system (10, 11, 12).
- a layer of shaped blocks (13, 14) are first placed on the claws (8), and the shaped blocks (18, 19) are used towards the center, circular segments of a horizontally arranged ceramic fiberboard (6) and a vertically arranged fiberboard (28) is inserted between the stones (19) and (14). Above the stones (15, 16) are arranged in one position and above the stones (17). Medium (20) and outer molded blocks (21) and a ceramic mat (22) are also used for insulation.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Thermal Sciences (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Thermal Insulation (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Gasification And Melting Of Waste (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Air Supply (AREA)
- Chimneys And Flues (AREA)
- Continuous Casting (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19533912 | 1995-09-13 | ||
DE19533912A DE19533912C2 (de) | 1995-09-13 | 1995-09-13 | Feuerfestauskleidung für eine Synthesegasanlage |
PCT/DE1996/001692 WO1997010315A2 (fr) | 1995-09-13 | 1996-09-09 | Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0793702A2 true EP0793702A2 (fr) | 1997-09-10 |
Family
ID=7772052
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96114111A Expired - Lifetime EP0763589B1 (fr) | 1995-09-13 | 1996-09-04 | Revêtement réfractaire dans une transition entre un gazéificateur et une chaudière de récupération |
EP96938004A Withdrawn EP0793702A2 (fr) | 1995-09-13 | 1996-09-09 | Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96114111A Expired - Lifetime EP0763589B1 (fr) | 1995-09-13 | 1996-09-04 | Revêtement réfractaire dans une transition entre un gazéificateur et une chaudière de récupération |
Country Status (15)
Country | Link |
---|---|
US (1) | US5873329A (fr) |
EP (2) | EP0763589B1 (fr) |
JP (1) | JP4088803B2 (fr) |
KR (1) | KR100416575B1 (fr) |
CN (1) | CN1105263C (fr) |
AT (1) | ATE186070T1 (fr) |
AU (1) | AU704003B2 (fr) |
CA (1) | CA2205261C (fr) |
CZ (1) | CZ294659B6 (fr) |
DE (2) | DE19533912C2 (fr) |
DK (1) | DK0763589T3 (fr) |
ES (1) | ES2140002T3 (fr) |
GR (1) | GR3032211T3 (fr) |
PL (1) | PL182793B1 (fr) |
WO (1) | WO1997010315A2 (fr) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19533912C2 (de) * | 1995-09-13 | 1998-09-24 | Gutehoffnungshuette Man | Feuerfestauskleidung für eine Synthesegasanlage |
DE10138626A1 (de) * | 2001-08-13 | 2003-03-13 | Alstom Power Energy Recovery Gmbh | Vorrichtung für den Eintritt von Heißgas in ein Heizflächenrohr eines Abhitzekessels |
US6725787B2 (en) * | 2002-03-11 | 2004-04-27 | Weyerhaeuser Company | Refractory vessel and lining therefor |
DE102005000873A1 (de) | 2005-01-05 | 2006-07-13 | Blohm, Maik | Verfahren und Vorrichtung zur Reinigung von SCR-Katalysatoren zwecks Wiedererlangung der Aktivität |
EP2248587A1 (fr) | 2005-12-16 | 2010-11-10 | Evonik Energy Services GmbH | Procédé de traitement d'un catalyseur pour la purification de gaz de combustion |
US20070225781A1 (en) * | 2006-03-21 | 2007-09-27 | Nidus Medical, Llc | Apparatus and methods for altering temperature in a region within the body |
EP2024683A2 (fr) * | 2006-05-19 | 2009-02-18 | Saint-Gobain Ceramics and Plastics, Inc. | Carreaux refractaires pour echangeurs thermiques |
BRPI0711810B1 (pt) * | 2006-05-22 | 2019-04-09 | Phelps Dodge Corporation | Sistema de rastreamento de posição e método para determinar uma posição de um veículo |
DE102007020855A1 (de) | 2007-05-02 | 2008-11-06 | Evonik Energy Services Gmbh | Verfahren zum Reinigen von Rauchgasen aus Verbrennungsanlagen |
ATE495812T1 (de) | 2007-09-04 | 2011-02-15 | Evonik Energy Services Gmbh | Verfahren zum entfernen von quecksilber aus verbrennungsabgasen |
CN101451768B (zh) * | 2007-11-28 | 2010-09-22 | 中国恩菲工程技术有限公司 | 一种余热锅炉 |
US7741239B2 (en) | 2008-03-11 | 2010-06-22 | Evonik Energy Services Llc | Methods of regeneration of SCR catalyst poisoned by phosphorous components in flue gas |
US7723251B2 (en) | 2008-03-11 | 2010-05-25 | Evonik Energy Services Llc | Method of regeneration of SCR catalyst |
US8287815B2 (en) * | 2008-05-02 | 2012-10-16 | General Electric Company | Methods and systems for controlling temperature in a vessel |
US20100031570A1 (en) * | 2008-08-07 | 2010-02-11 | Wei Chen | Method and system for an integrated gasifier and syngas cooler |
US20100170157A1 (en) * | 2009-01-08 | 2010-07-08 | General Electric Company | Support Shelves for Gasifier Dome and Thermocouple |
US8597384B2 (en) | 2009-09-25 | 2013-12-03 | General Electric Company | Gasification cooling system having seal |
CN101839651B (zh) * | 2010-05-06 | 2012-03-07 | 中国瑞林工程技术有限公司 | 余热锅炉入口密封装置 |
US9254470B1 (en) * | 2014-10-10 | 2016-02-09 | Rec Silicon Inc | Segmented liner and transition support ring for use in a fluidized bed reactor |
CN108444302A (zh) * | 2018-03-29 | 2018-08-24 | 中国瑞林工程技术有限公司 | 冶金炉烟道 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT310915B (de) * | 1971-08-19 | 1973-10-25 | Ziegelwerk Rohr Obermair | Kamin aus Mantelsteinen und Innenrohren |
GB1423989A (en) * | 1972-04-08 | 1976-02-04 | Denton M J | Flue section |
NL7711621A (nl) * | 1977-10-22 | 1979-04-24 | Hoogovens Ijmuiden Bv | Schoorsteenconstructie. |
DE2933514B1 (de) * | 1979-08-18 | 1980-03-27 | Gutehoffnungshuette Sterkrade | Vorrichtung zum Behandeln von durch Kohlevergasung erzeugtem Synthesegas |
CH653360A5 (de) * | 1980-09-19 | 1985-12-31 | Sulzer Ag | Heissgaskuehler an einer kohlevergasungsanlage. |
DE3124263A1 (de) * | 1981-06-19 | 1983-01-05 | Karrena GmbH, 4000 Düsseldorf | Auskleidung fuer einen im querscchnitt zumindest angenaehert runden feuerungsraum |
DE3131310A1 (de) * | 1981-08-07 | 1983-02-24 | Deutsche Babcock Bau GmbH, 4200 Oberhausen | Feuerungsraum fuer eine verbrennungsanlage |
DE3602935A1 (de) * | 1986-01-31 | 1987-08-06 | Steinmueller Gmbh L & C | Verfahren zum abkuehlen von aus einem vergasungsreaktor kommenden prozessgasen und waermetauscher zur durchfuehrung des verfahrens |
CH670501A5 (fr) * | 1986-07-02 | 1989-06-15 | Sulzer Ag | |
US4900249A (en) * | 1987-01-12 | 1990-02-13 | Dresser Industries, Inc. | Aluminum reverberatory furnace lining |
DE3713912C1 (de) * | 1987-04-25 | 1988-07-21 | Babcock Werke Ag | Kuehler fuer durch Vergasung erzeugte Gase |
US4948387A (en) * | 1989-11-24 | 1990-08-14 | Texaco Inc. | Synthesis gas barrier and refractory support |
US5188528A (en) * | 1990-03-20 | 1993-02-23 | Rast James P | Method and apparatus for lining the interior surface of a high temperature chamber with heat insulation material |
US5277580A (en) * | 1993-02-16 | 1994-01-11 | Lea-Con, Inc. | Wall construction system for refractory furnaces |
ES2083787T3 (es) * | 1993-03-16 | 1996-04-16 | Krupp Koppers Gmbh | Aparato de gasificacion para gasificar a presion combustibles finamente divididos. |
DE4325827A1 (de) * | 1993-07-31 | 1995-02-02 | Theodor Vanck Gmbh & Co Kg | Schornsteinauskleidung und Verfahren zur Innensanierung eines Schornsteins |
DE4420450C2 (de) * | 1994-06-10 | 1996-05-15 | Thermoselect Ag | Kühlbare Zustellung für einen Hochtemperatur-Vergasungsreaktor |
DE19533912C2 (de) * | 1995-09-13 | 1998-09-24 | Gutehoffnungshuette Man | Feuerfestauskleidung für eine Synthesegasanlage |
-
1995
- 1995-09-13 DE DE19533912A patent/DE19533912C2/de not_active Expired - Lifetime
-
1996
- 1996-09-04 DK DK96114111T patent/DK0763589T3/da active
- 1996-09-04 EP EP96114111A patent/EP0763589B1/fr not_active Expired - Lifetime
- 1996-09-04 DE DE59603472T patent/DE59603472D1/de not_active Expired - Lifetime
- 1996-09-04 AT AT96114111T patent/ATE186070T1/de active
- 1996-09-04 ES ES96114111T patent/ES2140002T3/es not_active Expired - Lifetime
- 1996-09-09 CA CA002205261A patent/CA2205261C/fr not_active Expired - Lifetime
- 1996-09-09 EP EP96938004A patent/EP0793702A2/fr not_active Withdrawn
- 1996-09-09 JP JP51155897A patent/JP4088803B2/ja not_active Expired - Lifetime
- 1996-09-09 PL PL96320143A patent/PL182793B1/pl not_active IP Right Cessation
- 1996-09-09 AU AU75600/96A patent/AU704003B2/en not_active Expired
- 1996-09-09 CZ CZ19971459A patent/CZ294659B6/cs not_active IP Right Cessation
- 1996-09-09 KR KR1019970703111A patent/KR100416575B1/ko not_active IP Right Cessation
- 1996-09-09 WO PCT/DE1996/001692 patent/WO1997010315A2/fr active IP Right Grant
- 1996-09-11 US US08/710,037 patent/US5873329A/en not_active Expired - Lifetime
- 1996-09-13 CN CN96112027A patent/CN1105263C/zh not_active Expired - Lifetime
-
1999
- 1999-12-22 GR GR990403298T patent/GR3032211T3/el unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9710315A2 * |
Also Published As
Publication number | Publication date |
---|---|
CA2205261A1 (fr) | 1997-03-20 |
JP4088803B2 (ja) | 2008-05-21 |
EP0763589A1 (fr) | 1997-03-19 |
WO1997010315A3 (fr) | 1997-05-15 |
AU7560096A (en) | 1997-04-01 |
KR100416575B1 (ko) | 2004-03-18 |
JPH10510582A (ja) | 1998-10-13 |
AU704003B2 (en) | 1999-04-01 |
DE59603472D1 (de) | 1999-12-02 |
CZ145997A3 (en) | 1997-09-17 |
CN1105263C (zh) | 2003-04-09 |
KR970707261A (ko) | 1997-12-01 |
DK0763589T3 (da) | 1999-11-08 |
GR3032211T3 (en) | 2000-04-27 |
WO1997010315A2 (fr) | 1997-03-20 |
CA2205261C (fr) | 2006-11-14 |
PL320143A1 (en) | 1997-09-15 |
PL182793B1 (pl) | 2002-03-29 |
US5873329A (en) | 1999-02-23 |
ATE186070T1 (de) | 1999-11-15 |
CZ294659B6 (cs) | 2005-02-16 |
DE19533912C2 (de) | 1998-09-24 |
ES2140002T3 (es) | 2000-02-16 |
CN1160836A (zh) | 1997-10-01 |
DE19533912A1 (de) | 1997-03-27 |
EP0763589B1 (fr) | 1999-10-27 |
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Legal Events
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