EP0793702A2 - Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation - Google Patents

Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation

Info

Publication number
EP0793702A2
EP0793702A2 EP96938004A EP96938004A EP0793702A2 EP 0793702 A2 EP0793702 A2 EP 0793702A2 EP 96938004 A EP96938004 A EP 96938004A EP 96938004 A EP96938004 A EP 96938004A EP 0793702 A2 EP0793702 A2 EP 0793702A2
Authority
EP
European Patent Office
Prior art keywords
stones
refractory lining
claws
lining according
shaped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96938004A
Other languages
German (de)
English (en)
Inventor
Jürgen HEERING
Klaus Köhnen
Duane Brooker
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MAN Gutehoffnungshutte GmbH
Original Assignee
MAN Gutehoffnungshutte GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MAN Gutehoffnungshutte GmbH filed Critical MAN Gutehoffnungshutte GmbH
Publication of EP0793702A2 publication Critical patent/EP0793702A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/86Other features combined with waste-heat boilers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F22B1/1838Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
    • F22B1/1846Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations the hot gas being loaded with particles, e.g. waste heat boilers after a coal gasification plant
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Definitions

  • the invention relates to a refractory lining in the transition section of a carburetor to the waste heat boiler with brackets for fastening refractory shaped bricks.
  • the transition from the carburetor to the waste heat boiler is flowed through both by the hot synthesis gas and by hot slag.
  • the temperatures in this transition section are over 1400 ° C.
  • the transition between the reactor vessel and the synthesis gas cooler is lined with a refractory delivery made of molded bricks from a reactor vessel supplied by the applicant for the Ruhr synthesis gas plant (SAR) of Ruhrchemie in Oberhausen-Holten with a subsequent waste heat boiler of a synthesis gas cooler.
  • SAR Ruhr synthesis gas plant
  • the upper shaped stones are each placed in a ring on cast brackets, which are attached one above the other at the nozzle end of the carburetor and at the nozzle end of the synthesis gas cooler.
  • the shaped stones in the area of the cooling tube cage are on circumferential tube lugs
  • REPLACEMENT BLA ⁇ (RULE 26) Transition from vertical cooling pipes to the horizontal cooling pipe wall.
  • the thermal stresses caused by high temperatures and the resulting ff material movements are directly on the high-pressure parts on the water side , for example the tubes of the cooling tube cage, transferred; Furthermore, the entire weight of the stones weighs on the supports. Furthermore, the upper fixed points (brackets) at the transition between the two vessels are uncooled and are subject to increasing overheating as the ff material wears down.
  • the object of the invention is therefore to design the refractory lining in the transition section between the reactor and the synthesis gas cooler in such a way that the stresses in the ff material are reduced, the dead weight of the stones is distributed over various conditions, a compensation of the relative movements between the ff stones and the Mounts done, rugged
  • brackets are not attached to water-carrying components (boiler pipes) and the so-called main claw is protected from overheating by additional cooling.
  • the refractory area consists of three different, side by side stone layers in the uncooled nozzle as well as different Special shaped stones, shoulder shaped stones and normal stones, which are matched to the conditions of temperature, wear, internal and external pressure and service life.
  • the refractory stone lining is supported on the connection piece and on the cooling tube cage of the synthesis gas cooler by a stone holding system, which consists of consoles arranged one above the other in the area of the cooling tube
  • the supports for the ff-stones are distributed on different levels in order to distribute the stone weights and to keep local stresses low
  • the stone brackets are on the webs between the water-side high-pressure parts (boiler pipes)
  • REPLACEMENT3LATT (RULE26) - Design of a drip nose at the lower exit of the cooling tube cage so that the slag does not crawl along the horizontal wall and slag this as well as the bulkhead walls and the tube cage.
  • Fig. 2 shows a section through the ff material at the transition from the carburetor to the waste heat boiler.
  • an ff lining which consists of a number of normal and shaped stones, is introduced in the transition section between the carburetor (1) and the waste heat boiler (4).
  • the transition section consists on the outside of the uncooled carburetor socket (2) and the cooled pipe cage (5) in the upper part of the waste heat boiler (3, 4).
  • the ff lining is supported in the tube cage (5) by consoles (9) arranged one above the other, which are welded to the webs (tube-web-tube welding) of the tube cage (5).
  • expansion joints (27) are provided below each of the brackets (9), while an annular, ceramic fiberboard (6) is inserted between the ff lining at the transition to the nozzle (2).
  • An ff ramming compound (24) or the like is applied between the upper part of the tube cage (5) and the cooling system (10, 11, 12).
  • FIG. 2 shows the structure of the ff lining in the transition section from the carburetor (2) and inlet connection (3) of the waste heat boiler (4).
  • the ff-lining is held by claws (8), which are protected from overheating by a cooling system (10, 11, 12).
  • a layer of shaped blocks (13, 14) are first placed on the claws (8), and the shaped blocks (18, 19) are used towards the center, circular segments of a horizontally arranged ceramic fiberboard (6) and a vertically arranged fiberboard (28) is inserted between the stones (19) and (14). Above the stones (15, 16) are arranged in one position and above the stones (17). Medium (20) and outer molded blocks (21) and a ceramic mat (22) are also used for insulation.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Thermal Insulation (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Air Supply (AREA)
  • Chimneys And Flues (AREA)
  • Continuous Casting (AREA)
EP96938004A 1995-09-13 1996-09-09 Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation Withdrawn EP0793702A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19533912 1995-09-13
DE19533912A DE19533912C2 (de) 1995-09-13 1995-09-13 Feuerfestauskleidung für eine Synthesegasanlage
PCT/DE1996/001692 WO1997010315A2 (fr) 1995-09-13 1996-09-09 Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation

Publications (1)

Publication Number Publication Date
EP0793702A2 true EP0793702A2 (fr) 1997-09-10

Family

ID=7772052

Family Applications (2)

Application Number Title Priority Date Filing Date
EP96114111A Expired - Lifetime EP0763589B1 (fr) 1995-09-13 1996-09-04 Revêtement réfractaire dans une transition entre un gazéificateur et une chaudière de récupération
EP96938004A Withdrawn EP0793702A2 (fr) 1995-09-13 1996-09-09 Revetement refractaire dans la gaine reliant un gazeificateur a une chaudiere de recuperation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP96114111A Expired - Lifetime EP0763589B1 (fr) 1995-09-13 1996-09-04 Revêtement réfractaire dans une transition entre un gazéificateur et une chaudière de récupération

Country Status (15)

Country Link
US (1) US5873329A (fr)
EP (2) EP0763589B1 (fr)
JP (1) JP4088803B2 (fr)
KR (1) KR100416575B1 (fr)
CN (1) CN1105263C (fr)
AT (1) ATE186070T1 (fr)
AU (1) AU704003B2 (fr)
CA (1) CA2205261C (fr)
CZ (1) CZ294659B6 (fr)
DE (2) DE19533912C2 (fr)
DK (1) DK0763589T3 (fr)
ES (1) ES2140002T3 (fr)
GR (1) GR3032211T3 (fr)
PL (1) PL182793B1 (fr)
WO (1) WO1997010315A2 (fr)

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DE19533912C2 (de) * 1995-09-13 1998-09-24 Gutehoffnungshuette Man Feuerfestauskleidung für eine Synthesegasanlage
DE10138626A1 (de) * 2001-08-13 2003-03-13 Alstom Power Energy Recovery Gmbh Vorrichtung für den Eintritt von Heißgas in ein Heizflächenrohr eines Abhitzekessels
US6725787B2 (en) * 2002-03-11 2004-04-27 Weyerhaeuser Company Refractory vessel and lining therefor
DE102005000873A1 (de) 2005-01-05 2006-07-13 Blohm, Maik Verfahren und Vorrichtung zur Reinigung von SCR-Katalysatoren zwecks Wiedererlangung der Aktivität
EP2248587A1 (fr) 2005-12-16 2010-11-10 Evonik Energy Services GmbH Procédé de traitement d'un catalyseur pour la purification de gaz de combustion
US20070225781A1 (en) * 2006-03-21 2007-09-27 Nidus Medical, Llc Apparatus and methods for altering temperature in a region within the body
EP2024683A2 (fr) * 2006-05-19 2009-02-18 Saint-Gobain Ceramics and Plastics, Inc. Carreaux refractaires pour echangeurs thermiques
BRPI0711810B1 (pt) * 2006-05-22 2019-04-09 Phelps Dodge Corporation Sistema de rastreamento de posição e método para determinar uma posição de um veículo
DE102007020855A1 (de) 2007-05-02 2008-11-06 Evonik Energy Services Gmbh Verfahren zum Reinigen von Rauchgasen aus Verbrennungsanlagen
ATE495812T1 (de) 2007-09-04 2011-02-15 Evonik Energy Services Gmbh Verfahren zum entfernen von quecksilber aus verbrennungsabgasen
CN101451768B (zh) * 2007-11-28 2010-09-22 中国恩菲工程技术有限公司 一种余热锅炉
US7741239B2 (en) 2008-03-11 2010-06-22 Evonik Energy Services Llc Methods of regeneration of SCR catalyst poisoned by phosphorous components in flue gas
US7723251B2 (en) 2008-03-11 2010-05-25 Evonik Energy Services Llc Method of regeneration of SCR catalyst
US8287815B2 (en) * 2008-05-02 2012-10-16 General Electric Company Methods and systems for controlling temperature in a vessel
US20100031570A1 (en) * 2008-08-07 2010-02-11 Wei Chen Method and system for an integrated gasifier and syngas cooler
US20100170157A1 (en) * 2009-01-08 2010-07-08 General Electric Company Support Shelves for Gasifier Dome and Thermocouple
US8597384B2 (en) 2009-09-25 2013-12-03 General Electric Company Gasification cooling system having seal
CN101839651B (zh) * 2010-05-06 2012-03-07 中国瑞林工程技术有限公司 余热锅炉入口密封装置
US9254470B1 (en) * 2014-10-10 2016-02-09 Rec Silicon Inc Segmented liner and transition support ring for use in a fluidized bed reactor
CN108444302A (zh) * 2018-03-29 2018-08-24 中国瑞林工程技术有限公司 冶金炉烟道

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Also Published As

Publication number Publication date
CA2205261A1 (fr) 1997-03-20
JP4088803B2 (ja) 2008-05-21
EP0763589A1 (fr) 1997-03-19
WO1997010315A3 (fr) 1997-05-15
AU7560096A (en) 1997-04-01
KR100416575B1 (ko) 2004-03-18
JPH10510582A (ja) 1998-10-13
AU704003B2 (en) 1999-04-01
DE59603472D1 (de) 1999-12-02
CZ145997A3 (en) 1997-09-17
CN1105263C (zh) 2003-04-09
KR970707261A (ko) 1997-12-01
DK0763589T3 (da) 1999-11-08
GR3032211T3 (en) 2000-04-27
WO1997010315A2 (fr) 1997-03-20
CA2205261C (fr) 2006-11-14
PL320143A1 (en) 1997-09-15
PL182793B1 (pl) 2002-03-29
US5873329A (en) 1999-02-23
ATE186070T1 (de) 1999-11-15
CZ294659B6 (cs) 2005-02-16
DE19533912C2 (de) 1998-09-24
ES2140002T3 (es) 2000-02-16
CN1160836A (zh) 1997-10-01
DE19533912A1 (de) 1997-03-27
EP0763589B1 (fr) 1999-10-27

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